Термодинамические свойства индивидуальных веществ Т.2. Элементы С, Si, Ge, Sn, Pb и их соединения Кн.2. Таблицы термодинамических свойств - Глушко В.П.

Author: Глушко В.П.
Tags: тепло термодинамика физика математическая физика издательство наука химическая термодинамика
Year: 1979
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Термодинамические свойства индивидуальных веществ Т.2. Элементы С, Si, Ge, Sn, Pb и их соединения Кн.1. Вычисление термодинамических Свойств
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Термодинамические свойства индивидуальных веществ. Том 1. Книга 2
Text
                    АКАДЕМИЯ НАУК СССР
ИНСТИТУТ ВЫСОКИХ ТЕМПЕРАТУР
ГОСУДАРСТВЕННЫЙ ИНСТИТУТ ПРИКЛАДНОЙ ХИМИИ

ТЕРМОДИНАМИЧЕСКИЕ
СВОЙСТВА
ИНДИВИДУАЛЬНЫХ
ВЕЩЕСТВ
СПРАВОЧНОЕ ИЗДАНИЕ
В ЧЕТЫРЕХ ТОМАХ
Издание третье, переработанное и расширенное
Согласовано с Государственной службой
стандартных справочных данных
РЕДАКЦИОННАЯ КОЛЛЕГИЯ:
В. П. ГЛУШКО (ответственный редактор),
Л. В. ГУРВИЧ (зам. ответственного редактора),
Г. А. БЕРГМАН, И. В. ВЕЙЦ, В. А. МЕДВЕДЕВ,
Г. А. ХАЧКУРУЗОВ, В. С. ЮНГМАН
ИЗДАТЕЛЬСТВО «НАУКА» МОСКВА 1979

ТЕРМОДИНАМИЧЕСКИЕ
СВОЙСТВА
ИНДИВИДУАЛЬНЫХ
ВЕЩЕСТВ
Том II
ЭЛЕМЕНТЫ
С, Si, Ge, Sn, Pb
И ИХ СОЕДИНЕНИЯ
Книга 2
ТАБЛИЦЫ
ТЕРМОДИНАМИЧЕСКИХ СВОЙСТВ
ИЗДАТЕЛЬСТВО «НАУКА» МОСКВА 1979

УДК 536+ 541.1
Термодинамические свойства индивидуальных веществ. Справочное издание: В 4-х т./Л.В. Гурвич, И.В. Вейц,
В.А-. Медведев и др. - 3-е изд., перераб. и расширен. - Т. II. Кн. 2. - М.: Наука, 1979. - 344 с.
Издание состоит из четырех томов, каждый том - из двух книг: в первой описаны выбор исходных
постоянных и расчет таблиц термодинамических свойств каждого вещества, во второй книге помещены
таблицы термодинамических свойств.
Во второй книге II тома в 292 основных и 12 дополнительных таблицах представлены
термодинамические свойства веществ, рассчитанные авторами на основании данных, приведенных в первой книге.
Таблицы рассчитаны в интервале температур от 100 до 6000 К, для 18 газов - до 10 000 К, для 10 газов до
20 000 К. Для 52 веществ приведены второй вириальный коэффициент и критические постоянные.
АВТОРЫ
Л.В. ГУРВИЧ
И.В. ВЕЙЦ
В.А. МЕДВЕДЕВ
Г.А. ХАЧКУРУЗОВ
B.C. ЮНГМАН
Г.А. БЕРГМАН
В.Ф. БАЙБУЗ
B.C. ИОРИШ
Г.Н. ЮРКОВ
СИ. ГОРБОВ
НИ. НАЗАРЕНКО
О.В. ДОРОФЕЕВА
Л.Ф. КУРАТОВА
Е.Л. ОСИНА
А.В. ГУСАРОВ
В.Я. ЛЕОНИДОВ
И.Н. ПРЖЕВАЛЬСКИЙ
АЛ. РОГАЦКИЙ
Ю.М. ЕФРЕМОВ
В.Г. РЯБОВА
В.Ю. ЗИЦЕРМАН
Ю.Г. ХАИТ
Е.А. ШЕНЯВСКАЯ
М.Е. ЕФИМОВ
В.А. КУЛЕМЗА
Ю.С.ХОДЕЕВ
С.Э. ТОМБЕРГ
В.Н. ВДОВИН
А.Я. ЯКОБСОН
М.С.ДЕМИДОВА
20503-567
055 @2) -79
Подписное издание 2602040600
© Издательство "Наука", 1979 г.
Эта книга не может быть полностью или частично
воспроизведена или размножена, введена в
информационно-поисковую систему или передана по линиям
связи в любой форме или любыми средствами (в том
числе электронными устройствами и на магнитных
носителях информации), без письменного
разрешения издательства "Наука".

ВВЕДЕНИЕ
Вторая книга II тома, как и первого, состоит из
основного раздела и Дополнения. В основном разделе
приведены 292 таблицы термодинамических свойств
веществ - соединений углерода, кремния, германия,
олова и свинца. В 269 таблицах представлены
свойства газообразных веществ, в 23 таблицах - свойства
веществ в конденсированном состоянии. Таблицы
термодинамических свойств рассчитаны для
температур от 100 К, за исключением заряженных газов, для
которых таблицы даны начиная с 298.15 К. Для 10
газов (С, С*, С2) CJ., СО, СО+, СН, СН*, CN, CN*)
таблицы рассчитаны до 20 000 К, для 18 газов (С2, С3,
С4, С5)СО2,СО^ С2Н, С2Н2) CN", HCN, Si, Sf.Ge,
Ge+, Sn, Sn+, Pb, Pb+) - до 10 000 К и для остальных
241 газов - до 6000 К. Для 23 конденсированных
веществ таблицы рассчитаны до температуры, при
которой давление насыщенного пара (или
суммарное давление продуктов диссоциации) достигает
100 атм.
Уравнения, аппроксимирующие в настоящем
справочнике табличные значения Ф° (Г) и полученные с
помощью метода наименьших квадратов,
воспроизводят эти значения в подавляющем большинстве
случаев с максимальным абсолютным отклонением до
0,02-0,03 Дж-К-моль в указанных диапазонах
температур, т.е. с точностью, которая обеспечивается
принятыми в справочнике значениями
фундаментальных постоянных. Однако для нескольких газов
(например, С3) СН, СН\ CH2F2) C2H2F2, C2H3C1,
Pb в настоящем томе и О3 в томе 1) отклонения
могут быть больше (до.0,2 Дж-К"!-моль"'). Для
улучшения аппроксимации в этих случаях можно
было бы или воспользоваться уравнением с
большим числом членов или разбить аппроксимируемый
диапазон температур на части.
Форма представления данных в таблицах II тома
та же, что и в I томе (см. Введение ко 2-й книге
I тома). Нумерация таблиц продолжает нумерацию
первого тома.
В Дополнении приведены таблицы
термодинамических функций некоторых конденсированных
веществ, включая вещества, у которых давление
насыщенного пара (или суммарное давление продуктов
диссоциации) достигает 100 атм при температурах
ниже 1000К (РЬО2, РЬ2О3, РЬ3О4), неравновесные
модификации (алмаз, тридимит), равновесные в
узком интервале температур модификации (кристоба-
лит, кварц, кубическая модификация SiC,
гексагональная модификация GeO2, ромбическая
модификация РЬО) и вещества в стеклообразном состоянии
(SiO2,GeO2).
В двух таблицах, замыкающих Дополнение книги,
даны константы уравнения, аппроксимирующего
второй вириальный коэффициент (табл. Д. 39) и
критические постоянные (табл. Д. 40) для тех веществ
II тома, для которых имеются соответствующие
данные (см. раздел П 3.7 первой книги этого тома).
Большую помощь при подготовке настоящей
книги оказали сотрудники Отдела
термодинамики ИВТАН АЛ. Гольдштейн и М.Б. Швыряева,
которые провели программирование на ЭВМ ряда
этапов расчета таблиц.

УКАЗАТЕЛЬ ТАБЛИЦ
Номер
таблицы
238
239
240
241
242
243
244
245
246
247
248
249
250
251
252
253
254
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
277
278
279
280
281
Вещество
Углевод С (к, графит; ж) . . . .
Углерод С (г)
Положительный ион углерода С+ (г) .' .
Отрицательный ион углерода С (г) . .
ДиуглеродС2 (г) . . .
Положительный ион диуглерода С2 (г).
Отрицательный ион диуглерода С2 (г) .
Триуглерод С3 (г)
Тетрауглерод С4 (г)
Пентауглерод С5 (г)
Оксид углерода СО (г)
Положительный ион оксида углерода
СО+ (г)
Диоксид углерода СО2 (г)
Положительный ион диоксида
углерода СО2 (г)
Оксид диуглерода С2 О (г)
Диоксид триуглеродаС3О2 (г) .....
Метин СН (г)
Положительный ион метина СН+ (г) . .
Метилен СН2 (г) '
Метил СН3 (г)
Метан СН4 (г)
Гидрид диуглерода С2Н (г)
Ацетилен С2Н2 (г)
Тригидрид диуглерода С2Н3 (г)
Этилен С2Н4 (г)
ЭтилС2Н5 (г)
Этан С2Н6 (г)
Формил НСО (г)
Карбоксил СООН (г)
Формальдегид Н2СО (г)
Муравьиная кислота НСООН (г)
цис-Муравьиная кислота «ыс-НСООН (г)
транс-Муравьиная кислота
гранс-НСООН (г)
Оксид-тригидрид углерода СН3 О (г) • .
Дигидрид-гидроксид углерода
СН2ОН (г)
Метанол СН3ОН (г)
Этанол С2Н5ОН (г)
Фторид углерода CF (г)
Дифторид углерода С F2 (г)
Трифторид углерода CF3 (г)
Тетрафторид углерода CF4 (г)
Фторид диуглерода C2F (г)
Дифторацетилен Сг F2 (г)
Трифторид диуглерода C2F3 (т). . . . .
гр.
10
12
14
16
17
19
21
23
25
27
29
31
33
35
37
38
39
41
43
44
45
46
48
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
Номер
таблицы
II
282
283
284
285
286
287
288
289
290
291
292
293
294
295
296
297
298
299
300
301
302
303
304
305
306
307
308
309
310
311
312
313
314
315
316
317
318
319
320
321
322
323
324
325
326
327
328
Вещество
Стр.
Тетрафторэтилен С2 F4 (г) 71
Пентафторэтил С2 F5 (г) 72
Гексафторэтан C2F6 (г) 73
Оксид-фторид углерода FCO (г) 74
Оксид-дифторид углерода F2CO (г) . . 75
Фторметилен СНГ' (г) 76
Фторметил СН2 F (г) 77
ФторметанСН3Р (г) 78
Дифторметил CHF2 (г) 79.
ДифторметанСН2Р2 (г) 80
Трифторметан CHF3 (г) 81
Фторацетилен C2HF (г) 82
Фторэтилен C2H3F (г) 83
ДифторэтиленС2Н2Р2 (г) 84
1,1-Дифторэтилен 1,1-C2H2F2 (г) .... 85
цис- Дифторэтилен yuc-C2H2F2 (г). : . . 86
гракс-Дифторэтилен гранс-С2Н2Г2 (г) . 87
ТрифторэтиленС2НР3 (г) 88
Оксид-гидрид-фторид углерода HFCO(г) 89
Хлорид углерода СС1 (г) 90
Дихлорид углерода СС12 (г) 91
Трихлорид углерода СС13 (г) 92
Тетрахлорид углерода ССЦ (г) 93
Хлорид диуглерода С2С1 (г) 94
ДихлорацетиленС2С12 (г) 95
Трихлорид диуглерода С2С13 (г) .... 96
Тетрахлорзтилен С2С14 (г) 97
Пентахлорэтил С2С15 (г) 98
Гексахлорэтан С2С16 (г) 99
Оксид-хлорид углерода С1СО (г) . . . , 100
Фосген С12СО (г) 101
Хлорметилен СНС1 (г) 102
Хлорметил СН2а (г) 103
Хлорметан СН3С1 (г) 104
Дихлорметил СНС12 (г) 105
Дихлорметан СН2С12 (г) 106
Трихлорметан СНС13 (г) 107
Хлорацетилен С2 НС1 (г) 108
ХлорэтиленС2Н3С1 (г) 109
ДихлорэтиленС2Н2С12 (г) ПО
1,1-Дихлорэтилен 1,1-С2Н2С12 (г). . . . 111
«нс-Дихлорэтилен и«с-С2Н2С12 (г) ... 112
граис-Дихлорэтилен гранс-С2Н2С12 (г) . 113
ТрихлорэтиленС2НС13 (г) 114
Оксид-гидрид-хлорид углерода
НС1СО (г) 115
Фторхлорметилен CFC1 (г) . . 116
Дифторхлорметил CF2C1 (г) 117

Номер
таблицы
Вещество
Стр.
Номер
таблицы
Вещество
Стр.
329 Трифторхлорметан СТ3С1 (г) 118
330 Фтордихлорметил CFC12 (г) 119
331 Дифтордихяормстан С1'2С12 (г) 120
332 Фтортрихлорметан CFC13 (г) 121
333 Фторхлорацетилен С2 Г'С1 (г) 122
334 Трифторхлорэтилен C2F3C1 (г) 123
335 Дифтордихлорэтилек C2.F2CI2 (г) .... 124
336 1,1-Дифтордихлорэтилен
l,l-C2F2Cl2 (г) 125
337 цис-Дифтордихлорэтилен
цис-С212а2 (г) 126
338 транс- Дифтордихлорэтилен
грднс-С21-2С12 (г) . 127
339 ФтортрихлорэтиленС21ХЛ3 (г) 128
340 Оксид-фторид-хлорид углерода
FC1CO (г) 129
341 Фторхлорметил CHFCI (г) 130
342 ФторхлорметанСН2ГС1 (г) 131
343 Дифторхлорметан CHF2C1 (г) 132
344 Фтордихлорметан СН1С12 (г) 133
345 Фторхлорэтилен C2H2FC1 (г) 134
346 1,1-Фторхлорэтилен 1,1-C2H2FC1 (г) . . 135
347 чис-Фторхлорэтилен «uc-C2H2FCI (г) . 136
348 гранс-Фторхлорэтилен
граис-С2М2РС1 (г) 137
349 ДифторхлорэтиленС2Ш'2С1 (г) 138
350 1,1-Дифторхлорэтилсн1,1-С2Нр2С1 (г). 139
351 чис-Дифторхлорэтилен цыс-С2Н1'2 С1 (г)- 140
352 гранс-Дифторхлорэтилен
rpa«cCjHF2Cl (г) 141
353 Фтордихлорэтилен C2HFCI2 (г) 142
354 грднс-Фтордихлорэтилен
rp<7Hc-C2HFCl2 (г) 143
355 цис-Фтордихлорэтилен цис-С2HFC12 (г) 144
356 и-Фтордихлорэтилени-СгНГ'аг (г) 145
357 Бромид углерода СВг (г) 146
358 Дибромид углерода СВг2 (г) 147
359 Трибромид углерода СВг3 (г) ¦ 148
360 Тетрабромид углерода 0Вг4 (г) 149
361 БромметанСН3Вг (г) 150
362 Дибромметан СН2Вг2 (г) 151
363 Трибромметан СНВг3 (г) 152
364 Трифторбромметан CF3Br (г) 153
365 Дифтордибромметан CF2Br2 (г) .... 154
366 Фтортрибромметан CFBr3 (г) 155
367 Фторбромметан СН2 FBr (г) 156
368 Дифторбромметан CHF2Br (г) 157
369 Фтордибромметан CHFBr2 (г) 158
370 Трихлорбромметан СС13Вг (г) 159
371 Дихлордибромметан СС12Вг2 (г) .... 160
372 Хлортрибромметан СС1Вг3 (г) 161
373 Хлорбромметан СН2С1Вг (г) 162
374 Дихлорбромметан СНС12 Вг (г) 163
375 Хлордибромметан СНС1Вг2 (г) 164
376 Дифторхлорбромметан CF2ClBr (г) . . 165
377 Фтордихлорбромметан CFCl2Br (г) . . 166
378 Фторхлордибромметан CFOBr2 (г)... 167
379 Фторхлорбромметан CHFClBr (г). .... 168
380 Иодид углерода С1(г) 169
381 Дииодид углерода С12 (г) 170
382 Трииодид углерода С13 (г) 171
383 Тетраиодид углерода CI4 (г) 172
384 ИодметанСН31 (г) 173
385 ДииодметанСН212 (г) 174
386 Трииодметан СН13 (г) 175
387 Трифториодметан CF3I (г) 176
388 ДифтордииодметанСР212 (г) 177
389 Фтортрииодметан CFI3 (г) , 178
390 ФториодметанСН2Р1 (г) 179
391 ДифториодметанСНР21 (г) 180
392 Фтордииодметан CHFI2 (г) 181
393 ТрихлориодметанСС131 (г) 182
394 Дихлордииодметан СС1212 (г) 183
395 Хлортрииодметан СС113 (г) 184
396 Хлориодметан СН2СП (г) . 185
397 ДихлориодметанСНС121 (г)....... 186
398 Хлордииодметан СНСИ2 (г) 187
399 Дифторхлориодметан CF2C1I (г) .... 188
400 ФтордихлориодметанСРС121 (г) 189
401 ' Фторхлордииодметан CFC1I2 (г) 190
402 Фторхлориодметан CHFC1I (г) 191
403 ТрибромиодметанСВгэ1 (г) 192
404 ДибромдииодметанСВг212 (г) 193
405 Бромтрииодметан СВг13 (г) 194
406 БромиодметанСН2Вг1 (г) 195
407 Дибромиодметан СНВг21 (г) 196
408 Бромдииодметан CHBrI2 (г) 197
409 ДифторбромиодметанСР2Вг1 (г) .... 198
410 ФтордибромиодметанСРВг21 (г) .... 199
411 Фторбромдииодметан CFBrI2 (г) .... 200
412 Дихлорбромиодметан СС12 Brl (г). ... 201
413 Хлордибромиодметан СС1Вг2! (г) ... 202
414 Хлорбромдииодметан СС1Вг12 (г). . . : 203
415 Фторбромиодметан CHFBrI (г) ..... 204
416 Хлорбромиодметан CHClBrI (г) 205
417 Фторхлорбромиодметан CFClBrI (г) . . 206
418 Сульфид углерода CS (г) Т07
419 Дисульфид углерода CS2 (г) 208
420 Оксид-сульфид углерода COS (г) .... 209
421 Циан CN (г) 210
422 Положительный ион циана CN+(г) . . . 212
423 Отрицательный ион циана СN~ (г) ... 214
424 Динитрид углерода NCN (г) 216
425 Карбид диазота CNN (г). 217
426 Дикарбид азота CNC (г) 218
427 Нитрид диуглерода CCN (г) 219
428 ДицианС2Ы2 (г) 220
429 Оксид-нитрид углерода NCO (г) .... 221
430 Синильная кислота HCN (г) 222
431 Гидрид-карбид азота HNC (г) 224
432 Гидрид-нитрид диуглерода HCCN (г). . _J25_
433 Фторциан FCN (г) .• 226
434 Хлорциан C1CN (г) 227
435 Фосфид углерода СР (г) 228
436 ., Кремний Si (к, ж) 229
437 Кремний Si (г) 230
438 Положительный ион кремния Si+ (г) . . 232
439 Дикремний Si2 (г) 234
440 Трикремний Si3 (г) 235
441 Оксид кремния SiO (г) 236
442 Диоксид кремния SiO2 (к, ж) 237
443 Диоксид кремния SiO2 (г) 238

Номер
таблицы
Вещество
Стр.
Номер
таблицы
Вещество
.Стр.
444 Гидрид кремния SiH (г) 239 495
445 Дигидрид кремния SiH2 (г) 240 496
446 Тригидрид кремния SiH3 (г) 241 497
447 Силан SiH4 (г) 242 498
448 Фторид кремния SiF (г) 243 499
449 Дифторид кремния SiF2 (г) 244 500
450 Трифторид кремния SiF3 (г) 245 501
451 Тетрафторид кремния SiF4 (г) 246 502
452 Гидрид-фторид кремния SjHF (г). . . . 247 503
453 Хлорид кремния SiCl (г) ...:.... 248 504
454 Дихлорид кремния SiCl2 (г) ...... 249 505
455 Трихлорид кремния SiCl3 (г) 250 506
456 Тетрахлорид кремния SiCl4 (г) 251 507
457 Гидрид-хлорид кремния SiHCl (г) . . . 252 508
458 Фторид-хлорид кремния SiFCl (г) . . . 253 509
459 Бромид кремния SiBr (г) 254 510
460 Дибромид кремния SiBr2 (г) 255 511
461 Три бромид кремния SiBr3 (г) 256 512
462 Тетрабромид кремния SiBr4 (г) .... 257 513
463 Иодид кремния Sil (г) 258 514
464 Дииодид кремния Sil^ (г) 259 515
465 Трииодид кремния Sil3 (г) 260 516
466 Тетраиодид кремния Sil4 (г) 261 517
467 Сульфид кремния SiS (к, ж) 262 518
468 Сульфид кремния SiS (г) 263 519
469 Дисульфид кремния SiS2 (к, ж) 264 520
470 Дисульфид кремния SiS2 (г) 265 521
471 Нитрид кремния SiN (г) 266 522
472 Тетранитрид трикремния Si3N4 (к) . . 267 523
473 Карбид кремния SiC (к, ж) . 268 524
474 Карбид кремния SiC (г) 269 525
475 Дикарбид кремния SiC2 (г) 270 526
476 Карбид дикремния Si2C (г) 271 527
477 Германий Ge (к, ж) 272 528
478 Германий Ge (г) 273 529
479 Положительный ион германия Ge (г) 275 Д.27
480 Дигерманий Ge2 (г) 277 Д.28
481 Оксид германия GeO (г) 278 Д.29
482 Диоксид германия GeO2 (к, ж) 279 Д.ЗО
483 Диоксид германия GeO2 (г) 280 Д.31
484 Фторид германия GeF (г) 281 Д.32
485 Дифторид германия GeF2 (г) • 282 Д.ЗЗ
486 Трифторид германия GeF3 (г) 283 Д.34
487 Тетрафторид германия GeF4 (г) .... 284 Д.35
488 Хлорид германия GeCl (г) 285 Д.36
489 Дихлорид германия GeCl2 (г) ..... 286 Д.37
490 Трихлорид германия GeCl3 (г) 287 Д.38
491 Тетрахлорид германия GeCl* (r) .... 288 Д.39
492 Сульфид германия GeS (к, ж) 289
493 Сульфид германия GeS (г) 290
494 Дисульфид германия GeS2 (к, ж) ... 291 Д.40
Дисульфид германия GeS2 (г) 292
V Олово Sn (к, ж) 293
Олово Sn (г) 294
Положительный ион олова Sn+ (г) ... 296
Диолово Sn2 (г) 298
Оксид олова SnO (к, ж) 299
Оксид олова SnO (г) 300
Диоксид олова SnO2 (к, ж) . 301
Диоксид олова SnO2 (г) 302
Фторид олова SnF (г) 303
Дифторид олова SnF2 (к, ж) 304
Дифторид олова SnF2 (г) 305
Хлорид олова SnCl (г) 306
Дихлорид олова SnCl2 (к, ж) 307
Дихлорид олова SnCl2 (г) 308
Сульфид олова SnS (к, ж) 309
Сульфид олова SnS (г) 310
Дисульфид олова SnS2 (к) 311
Дисульфид олова SnS2 (г) 312
Свинец РЬ (к, ж) 313
Свинец РЬ (г) 314
Положительный ион свинца РЬ+ (г). . . 316
ДисвинецРЪ2 (г) 318
Оксид свинца РЬО (к, ж) 319
Оксид свинца РЬО (г) 320
Диоксид свинца РЬО2 (г) 321
Фторид свинца PbF (г) . . 322
Дифторид свинца PbF2 (к, ж) 323
Дифторид свинца PbF2 (г) 324
Хлорид свинца PbCl (г) 325
Дихлорид свинца РЬС12 (к, ж) 326
Дихлорид свинца РЬС12 (г) 327
Сульфид свинца PoS^ (к, ж) 328
Сульфид свинца PbS (г) 329
Дисульфид свинца PbS2 (г) 330
Углерод С (к, алмаз) 332
Диоксид кремния SiO2 (к, кварц) , . . 332
Диоксид кремния SiO2 (к, кристобалит) 333
Диоксид кремния SiO2 (к, тридимит) 333
Диоксид кремния SiO2 (стекл.) .... 334
Карбид кремния SiC (к, куб.) 334
Диоксид германия GeO2 (к, гекс.) . . . 335
Диоксид германия GeO2 (стекл.) . . . 335
Оксид свинца РЬО (к, ромб.) 336
Диоксид свинца РЬО2 (к) 336
Триоксид дисвинца РЬ2О3 (к) 337
Тетроксид трисвинца РЬ3О4 (к) .... 337
Константы аппроксимационного
уравнения для второго вириального
коэффициента 338
Критические постоянные . 340

ТАБЛИЦЫ
ТЕРМОДИНАМИЧЕСКИХ
СВОЙСТВ

Класс точности
IV-С
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4130
4130
4200
4300
4400
4500
4600
4700
4800
С°р(Т)
1.660
4.940
8.536 Л1^-"
8.619
12.179
14.669
16.617
18.212
19.543
20.659
21.590
22.362
22.994
23.505
23.910
24.225
24.464
24.643
24.775
24.875
24.957
25.034
25.121
25.231
25.379
25.577
25.840
26.181
26.615
27.154
27.813
28.605
29.544
30.643
31.917
33.378
35.042
36.920
39.027
41.377
43.984
46.860
47.777
27.000
27.000
27.000
27.000
27.000
27.000
27.000
27.000
К°(Т) = р (С)
Ф°(Г)
Дж • К" . моль"
.342
1.155
Г': 2.218
2.240
3.501
4.862
6.258
7.650
9.020
10.357
11.656
12.916
14.134
15.313
16.453
17.554
18.619
19.649
20.645
21.608
22.540-
23.444
24.319
25.168
25.991
26.792
27.570
28.327
29.065
29.784
30.487
31.175
31.848
32.509
33.158
33.797
34.426
35.048
35.664
36.274
36.881
37.484
37.665
37.665
38.487
39.627
40.730
41.798
42.832
43.834
44.807
УГЛЕРОД
S°(T)
.952
3.090
5.740
5.793
8.798
11.797
14.650
17.335
19.856
22.224
24.451
26.546
28.520
30.381
32.138
33.799
35.371
36.859
38.272
39.614
40.892
42.112
43.278
44.397
45.474
46.514
47.522
48.503
49.463
50.406
51.337
52.262
53,184
54.110
55.043
55.989
56.952
57.937
58.949
59.993
61.073
62.194
62.539
86.752
87.205
87.841
88.461
89.068
89.662
90.242
90.811
С (к, графит
Я°(Г)-|/о@)
кДж . моль"
.061
.387
1.050
1.066
2.119
3.467
5.035
6.779
' 8.669
10.680
12.794
14.993
17.262
19.588
21.960
24.367
26.802
29.258
31.729
34.212
36.703
39.203
41.710
44.228
46.758
49.305
51.876
54.476
57.115
59.802
62.550
65.369
68.275
71.283
74.410
77.673
81.092
84.689
88.484
92.502
96.768
101.308
102.727
202.727
204.617
207.317
210.017
212.717
215.417
218.117
220.817
; ж)
@)= 711.185
о
-365.6878
-179.1549
-117.6033
-116.8290
-85.6111
-66.8570
-54.3433
-45.3996
-38.6893
-33.4693
-29.2932
-25.8768
-23.0303
-20.6226
-18.5595
-16.7723
-15.2093
-13.8308
-12.6062
-11.5110
-10.5259
-9.6351
-8.8258
-8.0872
-7.4106
-6.7885
-6.2146
-5.6836
-5.1908
-4.7323
-4.3047
¦3.9051
-3.5308
-3.1795
-2.8494
•2.538S
-2.2454
-1.9686
-1.7070
-1.4594
-1.2247
-1.0023
-.9375
-.9375
-.8120
-.6396
-.4752
-.3182
-.1681
-.0245
.1130
кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4130
4130
4200
4300
4400
4500
4600
4700
4800
I
о
и
+
н
г*>
VO
о
+
с*
•О
гч
о
I
о
н
•5
<ч
оо
+
.0921
00
II
Таблица
о
II
$
-
О
<
1
й
2
2
—
1
¦
Д
m
с-
*Ч
оо
Г»
н
о
1
X
го
о
II
я
v>
00
о
>
-
'л
о
_
Я i
V rt
\/ <>¦
v I
2 н
00 ?
о ?
« s
¦» II
с
0
•е-
238
-
'й
о
-
•
Ч
2
0 3
i
§
V
V
о
го
1
о
и
а.
10

УГЛЕРОД С (к, графит; ж)
Таблица 238
(окончание)
Ф°(Т)
S°(T)
Дж . К .моль
Н°(Т)-Н°@)
кДж . моль
1$К°(Т)
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
27.000
27.000
27.000
27.000
27.000
27.000
27.000
27.000
27.000
27.000
27.000
27.000
45.752
46.669
47.562
48.430
49.275
50.099
50.901
51.68-!
52.448
53.193
53.921
54.633
91.367
91.913
92.448
92.972
93.486
93.991
94.486
94.973
95.451
95.920
96.382
96.836
223.517
226.217
228.917
231.617
234.317
237.017
239.717
242.417
245.117
247.817
250.517
253.217
.2448
.3712
.4926
.6092
.7214
.8293
.9333
1.0335
1.1300
1.2232
1.3132
1.4002
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
11

Класс точности
I
УГЛЕРОД С (г)
Таблица 239
К
S°(T)
Дж ¦ К . моль
-1
Н°(Т)-Н°@)
кДж • моль
-1
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
21.271
20.904
20.838
20.838
20.815
20.804
20.799
20.795
20.793
20.792
20.791
20.791
20.793
20.796
20.803
20.814
20.829
20.850
20.878
20.912
20.952
20.999
21.052
21.110
21.174
21.241
21.313
21.387
21.464
21.542
21.621
21.701
21.780
21.859
21.936
22.012
22.087
22.159
22.230
22.298
22.363
22.426
22.486
22.544
22.600
22.652
22.702
22.750
22.795
22.838
22.878
22.917
22.953
22.987
23.020
23.050
23.079
23.106
23.132
23.156
23.179
111.216
127.218
136.068
136.203
142.467
147.277
151.182
154.469
157.306
159.803
162.032
164.045
165.880
167.566
169.126
170.577
171.933
173.207
174.407
175.541
176.618
177.642
178.618
179.551
180.444
181.302
182.126
182.919
183.684
184.423
185.137
185.828
186.498
187.148
187.779
188.393
188.990
189.571
190.138
190.690
191.229
191.756
192.270
192.773
193.265
193.747
194.218
194.680
195.133
195.577
196.013
196.440
196.860
197.272
197.677
198.075
198.466
198.851
199.230
199.602
199.969
135.070
149.657
157.989
158.118
164.109
168.752
172.545
175.751
178.528
180.977
183.167
185.149
186.958
188.622
190.164
191.599
192.943
194.206
195.399
196.529
197.602
198.626
199.604
200.541
201.440
202.306
203.141
203.946
204.726
205.480
206.212
206.922
207.612
208.284
208.937
209.574
210.196
210.802
211.394
211.972
212.537
213.090
213.631
214.161
214.680
215.188
215.687
216.176
216.655
217.126
217.587
218.041
218.486
218.924
219.354
219.776
220.192
220.601
221.003
221.398
221.788
2.385
4.488
6.536
6.574
8.657
10.738
12.818
14.898
16.977
19.056
21.135
23.214
25.294
27.373
29.453
31.534
33.616
35.700
37.786
39.876
41.969
44.066
46.169
48.277
50.391
52.512
54.639
56.774
58.917
61.067
63.225
65.391
67.565
69.747
71.937
74.134
76.339
78.552
80.771
82.998
85.231
87.470
89.716
91.967
94.225
96.487
98.755
101.027
103.305
105.586
107.872
110.162
112.455
114.752
117.053
119.356
121.663
123.972
126.284
128.598
130.915
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Я -
i
2
о
+
ё
V
V
II
12

УГЛЕРОД С (г)
Таблица 239
(окончание)
Ф°(Г)
S°(T)
Дж . К • моль
кДж . моль
-1
lgA-°(D
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
23.222
23.260
23.295
23.326
23.355
23.381
23.406
23.429
23.451
23.472
23.493
23.514
23.534
23.554
23.575
23.596
23.617
23.639
23.662
23.686
23.749
23.818
23.895
23.980
24.072
24.172
24.279
24.393
24.513
24.639
24.770
24.904
25.042
25.181
25.322
25.463
25.605
25.744
25.883
26.018
200.685
201.380
202.054
202.710
203.348
203.969
204.574
205.164
205.739
206.301
206.850
207.386
207.910
208.423
208.925
209.416
209.898
210.369
210.832
211.286
212.384
213.434
214.439
215.404
216.332
217.225
218.087
218.919
219.724
220.504
221.259
221.993
222.705
223.398
224.073
224.730
225.370
225.996
226.606
227.2О
22.2.548
223.286
224.003
224.699
225.375
226.033
226.674
227.299
227.908
228.502
229.082
229.648
230.201
230.743
231.272
231.791
232.298
232.796
233.284
233.762
234.919
236.025
237.086
238.104
239.085
240.031
240.945
241830
242.688
243.522
244.332
245.120
245.889
246.638
247.370
248.086
248.785
249.470
250.140
250.797
135.555
140.204
144.859
149.521
154.189
158.863
163.542
168.225
172.913
177.605
182.302
187.003
191.708
196.416
201.129
205.846
210.568
215.293
220.023
224.758
236.616
248.508
260.436
272.404
284.417
296.477
308.589
320.757
345.272
357.624
370.042
382.528
395.084
407.710
420.406
433.173
446.010
458.917
471.892
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
о
1
•1
о
о
о
ч
S
а\
с;
о
2
1
го
4?
0.31
+
"ч
о
о
о
V
V
1000
13

Класс
I
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
точности
-А
С°{Т)
20.974
20.971
20.889
20.851
20.831
20.819
20.811
20.806
20.802
20.799
20.797
20.795
20.794
20.793
20.792
20.791
20.791
20.790
20.790
20.790
20.789
20.789
20.789
20.789
20.788
20.788
20.788
20.788
20.788
20.788
20.788
20.787
20.787
20.787
20.787
20.787
20.787
20.788
20.788
20.788
20.788
20.789
20.789
20.790
20.791
20.792
20.794
20.795
20.797
20.800
20.803
20.806
20.810
20.814
20.819
20.824
20.831
20.838
20.845
ПОЛОЖИТЕЛЬНЫЙ ИОН УГЛЕРОДА С+ (г)
АГ°(Г) = р (С) • р~
Ф°G-)
Дж -К .моль"'
132.250
132.388
138.750
143.623
147.572
150.891
153.753
156.269
158.513
160.539
162.385
164.080
165.648
167.105
168.468
169.746
170.950
172.089
173.168
174.194
175.172
176.106
176.999
177.856
178.679
179.471
180.233
180.969
181.679
182.366
183.031
183.676
184.300
184.907
185.497
186.070
186.628
187.171
187.701
188.217
188.721
189.213
189.693
190.163
190.622
191.072
191.511
191.942
192.364
192.778
193.183
193.581
193.971
194.355
194.731
195.100
195.463
195.820
196.171
1 —I
(е) ¦ Р (С
S°(T)
154.551
154.681
160.701
165.358
169.157
172.367
175.147
177.597
179.789
181.772
183.581
185.246
186.787
188.222
189.564
190.824
192.012
193.137
194.203
195.217
196.184
197.108
197.993
198.842
199.657
200.442
201.198
201.927
202.632
203.314
203.974
204.613
205.234
205.836
206.422
206.992
207.546 .
208.086
208.612
209.126
209.627
210.116
210.594
211.061
211.518
211.965
212.403
212.832
213.252
213.664
214.067
214.464
214.853
215.235
215.610
215.978
216.340
216.696
217.047
1 а о л и
+ ) АгН°@)= -1086.454 кДж- моль
Я°(Г)-Я°@)
кДж . моль
6.649
6.688
8.780
10.867
12.951
15.034
17.115
19.196
21.276
23.356
25.436
27.516
29.595
31.674
33.754
35.833
37.912
39.991
42.070
44.149
46.228
48.307
50.386
52.465
54.544
56.622
58.701
60.780
62.859
64.937
67.016
69.095
71.174
73.252
75.331
77.410
79.489
81.567
83.646
85.725
87.804
89.883
91.962
94.041
96.120
98.199
100.278
102.358
104.437
106.517
108.597
110.678
112.758
114.840
116.921
119.003
121.086 ¦
123.169
125.254
190.5350
189.3544
141.7454
113.1249
94.0081
80.3272
70.0470
62.0362
55.6155
50.3522
45.9580
42.2328
39.0338
36.2562
33.8212
31.6687
29.7519
28.0336
26.4844
25.0801
23.8012
22.6313
21.5570
20.5669
19.6513
18.8020
18.0120
17.2752
16.5862
15.9407
15.3344
14.7639
14.2260
13.7180
13.2374
12.7820
12.3499
11.9392
11.5485
11.1762
10.8210
10.4818
10.1575
9.8471
9.5497
9.2645
8.9908
8.7278
8.4750
8.2317
7.9973
7.7715
7.5537
7.3434
7.1404
6.9442
6.7545
6.5709
6.3931
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
2
о
и
. 5=
J-
7
•л
О
о
1
"Л
о
§
о
о
1
о
»о
г-
d
(N
О
со
О
(N
II
/-^
(-.
0
¦
ноль
On
•¦н '
II
S
^
э
1
Й
1
а.
7
ы
"я
г.
н
<ч
о
1
S
о
+
1
ж
¦
д
X
«л
ч
§
00
~ч
II
ы
"?
00
(N
и
(J
0
Ца 240
'ё
I
s
_
•—t
*0
О
II
1?
Я
о
о
о
V
к,
V
о
о
•о
»'"
!о
<-. .
II
14

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
U500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
20.863
20.885
20.911
20.941
20.975
21.015
21.060
21.109
21.164
21.225
21.291
21.362
21.439
21.521
21.609
21.701
21.799
21.901
22.008
22.119
22.415
22.733
23.070
23.421
23.782
24.151
24.522
24.894
25.262
25.626
25.982
26.328
26.663
26.987
27.297
27.592
27.874
28.140
28.392
28.628
ПОЛОЖИТЕЛЬНЫЙ
Ф°G)
Дж • К ¦ миль
196.856
197.518
198.161
198.784
199.389
199.977
200.550
201.107
201.649
202.179
202.695
203.199
203.692
204.173
204.644
205.105
205.556
205.998
206.432
206.857
207.885
208.868
209.811
210.718
211.590
212.432
213.247
214.035
214.800
215.542
216.265
216.968
217.654
218.323
218.977
219.616
220.241
220.853
221.453
222.041
S°(T)
-1
217.731
218.393
219.036
219.661
220.268
220.860
221.436
221.999
222.548
223.084
223.609
224.123
224.627
225.120
225.605
226.081
226.549
227.009
227.461
227.907
228.993
230.043
231.061
232.050
233.014
233.954
234.872
235.771
236.651
237.513
238.359
239.190
240.005
240.806
241.593
242.366
243.126
243.873
244.607
245.329
ИОН УГЛЕРОДА С+ (г)
Н°(Т)-Н°@)
кДж ¦ миль
129.424
133.599
137.779
141.964
146.155
150.354
154.562
158.779
163.006
167.245
171.496
175.761
180.041
184.337
188.650
192.981
197.331
201.701
206.092
210.504
221.637
232.923
244.373
255.995
267.796
279.779
291.947
304.301
316 840
329.562
342.464
355.542
368.791
382.204
395.775
409.498
423.365
437.369
451.503
465.758
6.0541
5.7352
5.4348
5.1512
4.8830
4.6289
4.3879
4.1588
3.9409
3.7332
3.5350
3.3458
3.1648
2.9915
2.8254
2.6660
2.5130
2.3659
2.2244
2.0882
1.7686
.4759
1.2066
.9578
.7272
.5127
.3125
.1252
-.0506
-.2159
-.3718
-.5192
-.6586
-.7910
-.9167
.0365
.1506
.2596
.3638
.4732
Т
К
6200
6400
Ь600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 240
(окончание)
Тч
00
о —
5 §
+ 2
(N •
1 ¦"
Й 'а
3 * ^
ЧО гЧ О
I « S
. w о
О cn CN
* -• v
8 ° h
о J v
""• г^ °
я м. —.
""> Н 'о
О ~t Pi
«ч m II
II 1 а
с
0
¦&¦
15

Класс точности
I-D
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
ОТРИЦАТЕЛЬНЫЙ ИОН УГЛЕРОДА С" (г)
К°(Т)= р(С) -р(е) р~1 (С~)
Ф°(Г)
S°(T)
Дж > К . моль
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786'
20.786
20.786
20:786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
130.488 151.274
130.617 151.403
136.596 157.383
141.235 162.021
145.025 165.811
148.229 169.015
151.004 171.790
153.453 174.238
155.643 176.428
157.624 1*78.410
159.432 180.218
161.096 181.882
162.636 183.422
164.071 184.856
165.412 186.198
166.672 187.458
167.860 188.646
168.984 189.770
170.050 190.836
171.064 191.850
172.031 192.817
172.955 193.741
173.840 194.626
174.688 195.475
175.504 196.290
176.288 197.074
177.044 197.830
177.774 198.560
178.478 199.264
179.160 199.946
179.820 200.606
180.459 201.245
181.080 201.866
181.682 202.468
182.268 203.054
182.837 203.624
183.392 204.1/8
183.932 204.718
184.458 205.244
184.971 205.757
185.472 206.258
185.961 206.747
186.439 207.225
186.906 207.692
187.363 208.149
187.810 208.596
188.248 209.034
188.676 209.462
189.096 209.882
189.508 210.294
189.912 210.698
190.308 211.093
190.696 211.482
191.077 211.863
191.452 212.238
191.820 212.606
192.181 212.967
192.537 213.323
192.886 213.672
V
Н°(Г)-Н°@)
кДж ¦ моль
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.100
31.179
33.258
35.336
37.415
39.493
41.572
43.651
45.729
47.808
49.886
51.965
54.044
56.122
58.201
60.279
62.358
64.437
66.515
68.594
70.672
72.751
74.830
76.908
78.987
81.065
83.144
85.223
87.301
89.380
91.458
93.537
95.616
97.694
99.773
101,852
103,930
106.009
108.087
110.166
112.245
114.323
116.402
118.480
120.559
122.638
124.716
'°@) = 122.500
-21.1655
-21.0261
-15.3667
-11.9161
-9.5793
-7.8841
-6.59.s3
-5.5741
-4.7468
-4.0599
-3.4793
-2.9811
-2.5480
-2.1675
-1.8301
-1.5283
-1.2565
-1.0102
-.7855
-.5797
-.3902
-.2150
-.0525
.0990
.2405
.3730
.4976
.6150
.7259
.8308
.9303
1.0248
1.1148
1.2007
1.2826
1.3610
1.4361
1.5082
1.5773
1.6439
1.7079
1.7696
1.8291
1.8866
1.9421
1.9958
2.0479
2.0983
2.1471
2.1946
2.2406
2.2854
2.3289
2.3712
2.4124
2.4525
2.4917
2.5298
2.5670
кДж • моль
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 241
-
~ 1
А ^
2 ^ —
5 1
* *• ?
. i
\f-i г- V
^ 00 ОС
о °°' " j§
—1 и a ~
ii ^ 12 "?
;s ° оо ° ¦
гч.
U и. о к
¦—• 1 to
гч [)
0 w
""¦"• "а:
т ¦*<
с о
-• v
'а ь
¦ у
5 «л
g 00
s т-
S 2
S и
II
ь.
w
0
16

Класс точности
11-Е
Г
К
100
200
298.15
3Q0
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
и
29.774
40.500
43.208
43.188
39.687
37.121
35.939
35.532
35.494
35.626
35.983
36.227
36.490
36.768
37.056
37.352
37.654
37.959
38.265
38.570
38.871
39.166
39.453
39.730
39.997
40.253
40.498
40.731
40.953
41.163
41.363
41.553
41.735
41.909
42.075
42.235
42.390
42.539
42.685
42.826
43.115
43.248
43.379
43.508
43.637
43.765
43.892
44.019
44.146
44.274
44.401
44.529
44.658
44.786
44.916
45.045
45.175
45.305
45.435
45.565
45.735
ДИУГЛЕРОД С2 (г)
A"(W(C,-(C,
Ф°G)
S°(T)
Дж . К • моль
129.545 158.653
150.342 182.224
163.800 199.307
164.020 199.585
174.485 211.546
182.779 220.107
189.561 226.769
195.269 232.288
200.188 237.044
204.511 241.247
208.367 244.929
211.850 248.376
215.027 251.546
217.949 254.485
220.657 257.226
223.180 259.799
225.543 262.226
227.768 264.524
229.869 266.708
231.861 268.792
233.756 270.784
235.563 272.693
237.291 274.527
238.947 276.293
240.537 277.995
242.066 279.639
243.540 281.228
244.963 282.766
246.338 284.256
247.669 285.703
248.958 287.108
250.209 288.473
251.424 289.800
252.605 291.092
253.754 292.350
254.872 293.577
255.962 294.773
257.026 295.941
258.063 297.082
259.076 298.196
260.066 299.225
261.035 300.293
261.982 301.339
262.909 302.363
263.817 303.366
264.706 304.350
265.579 305.315
266.434 306.262
267.273 307.192
268.097 308.105
268.906 . 309.002
269.701 309.884
270.481 310.751
271.249 311.604
272.004 312.444
272.747 313.271
273.477 314.085
274.196 314.887
274.904 315.077
275.602 316.456
276.289 317.205
Д А
г
Н°(Г)-И°@)
кДж . Моль
2.9П
6.376
10.586
10.670
14.825
18.664
22.325
25.913
29.484
33.062
36.562
40.179
43.824
47.496
51.197
54.929
58.692
62.486
66.311
70.168
74.055
77.973
81.920
85.896
89.900
93.931
97.987
102.068
106.173
110.300
114.448
118.617
122.803
127.008
131.229
135.467
139.720
143.988
148.271
152.568
156.635
160.961
165.300
169.652
174.017
178.396
182.787
187.191
191.608
196.037
200.480
204.935
209.403
213.884
218.378
222.884
227.404
231.937
236.483
241.042
245.500
Г°@)= 600.000
1рА-°(Г)
-308.5517
-151.2646
-99.4573
-98.8064
-72.5817
-56.8423
-46.3418
-38.8346
-33.1986
-28.8110
-25.2971
-22.4196
-20.0195
-17.9870
-16.2435
-14.7313
-13.4073
-12.2382
-11.1984
-10.2675
-9.4293
-8.6705
-7.9804
-7.3501
-6.7720
-6.2400
-5.7488
-5.2938
-4.8711
-4.4775
-4.1100
-3.7661
-3.4437
-3.1407
-2.8554
-2.5863
-2.3322
-2.0917
-1.8638
-1.6475
-1.4420
-1.2465
-1.0602
-.8826
-.7130
-.5509
-.3958
-.2472
-.1048
.0318
.1630
.2890
.4103
.5269
.6393
.7476
.8521
.9529
1.0502
1.1443
1.2353
кДж ¦ моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 242
—
'л
¦ - °.
о S -°
5 ? |
° й ^
¦ гч .—, ^
-* 00 V <Ч
"ни *
" —ч ~ "¦
5 о со ~ ¦
«- сч "
<¦* I»* • Э
о - ° ^
<Г У ^
а- «
**¦ о
< >-,
+
~н ~
гч В
 ^
о
1 7
2 "* '¦о
О <ч , .
О О4* W
* + v
с « с
— •< о
? з т-
со ^ о
+ ! *
—< X ^
¦ч- со .,
(N ГЧ !|
ЧО *1 —
(N ГО
II +
h.
0
е
17

г
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 А*ъПА
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°(Т)
45.990
46.240
46.486
46.723
46.952
47.170
47.377
47.569
47.748
47.910
48.056
48.185
48.296
48.390
48.465
48.521
48.560
48.581
48.584
48.570
48.463
48.261
47.974
47.613
47.189
46.712
46.191
45.636
*» л- .
44.452
43.837
43.214
42.587
41.960
41.338
40.721
40.114
39.518
38.934
38.363
ДИУГЛЕРОД С2 (г)
Ф°(П
S°(T)
Дж ¦ К .моль
277.633 318.710
278.940 320.175
280.211 321.602
281.449 322.994
282.655 324.352
283.832 325.679
284.980 326.975
286.102 328.241
287.198 329.480
288.270 330.691
289.320 331.876
290.346 333.036
291.352 334.172
292.338 335.284
293.305 336.373
294.252 337.439
295.182 338.484
296.095 339.507
296.991 340.509
297.871 341.490
300.005 343.859
302.050 346.110
304.012 348.249
305.898 350.284
307.712 352.220
309.459 354.062
311.144 355.815
312.769 357.485
Ч1 A 44Q 4**Q Л77
315.855 360.595
317.322 362.043
318.741 363.425
320.115 364.745
321.447 366.008
322.737 367.215
323.989 368.371
325.203 369.479
326.382 370.540
327.528 371.560
328.641 372.538
H°(T)-H°@)
кДж . моль
254.677
263.904
273.182
282.508
291.880
301.298
310.757
320.257
329.794
339.366
348.968
358.597
368.250
377.924
387.615
397.319
407.032
416.751
426.473
436.193
460.464
484.658
508.728
532.635
556.345
579.829
603.063
626.028
648.707
671.090
693.168
714.936
736.392
757.533
778.362
798.881
819.094
839.006
858.622
877.949
\gK°(T)
1.4083
1.5707
1.7231
1.8667
2.0020
2.1297
2.2506
2.3651
2.4737
2.5768
2.6749
2.7682
2.8572
2.9421
3.0232
3.1007
3.1749
3.2460
3.3142
3.3796
3.5321
3.6706
3.7970
3.9129
4.0195
4.1180
4.2093
4.2943
4.3736
4.4478
4.5175
4.5832
4.6452
4.7039
4.7597
4.8127
4.8633
4.9116
4.9578
5.0022
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 242
(окончание)
00
i §
"Г ,
1 7
? * 2
*1 Ц *
1 ъ 1
i i v
? + Г-,
Й "к V
4.39.
i.296
000
*t н ¦*""
© Tfr ®
* г*~ ¦
oo el Ь^
<N -н ^
II + *"—¦'
о
¦е*
18

Класс точности
V-
т
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000.
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
D
29.400
29.409
30.164
31.180
32.225
33.218
34.178
35.150
36.Г76
37.278
38.453
39.683
40.937
42.181
43.379
44.501
45.524
46.430
47.211
47.864
48.391
48.800
49.100
49.302
49.419
49.462
49.444
49.375
49.265
49.123
48.956
48.772
48.575
48.370
48.161
47.952
47.744
47.540
47.341
47.148
46.961
46.783
46.611
46.448
46.293
46.145
46.004
45.871
45.744
45.624
45.509
45.400
45.295
45.195
45.099
45.006
44.916
44.829
44.744
ПОЛОЖИТЕЛЬНЫЙ ИОН ДИУГЛЕРОДА С?
К°(Т)=р2(С) р
Ф°G)
Дж ¦ К .моль
174.938
175.118
183.516
190.079
195.499
200.141
204.217
207.863
211.171
214.207
217.019
219.646
222.115
224.451
226.670
228.787
230.815
232.763
234.637
236.446
238.194
239.886
241.525
243.114
244.658
246.157
247.615
249.033
250.413
251.757
253.067
254.344
255.589
256.804
257.989
259.147
260.278
261.384
262.464
263.520
264.554
265.565
266.556
267.526
268.476
269.407
27.0.320
271.215
272.093
272.954
273.800
274.630
275.445
276.246
277.033
277.807
278.567
279.315
280.050
'(е) -p-'cC
S°(T)
204.066
204.248
212.802
219.640
225.418
230.460
234.959
239.040
242.796
246.295
249.589
252.715
255.701
258.568
261.329
263.993
266.566
269.052
271.454
273.774
276.013
278.174
280.257
282.266
284.202
286.068
287.867
289.601
291.273
292.886
294.444
295.947
297.400
298.805
300.165
301.482
302.758
303.995
305.196
306.363
307.497
308.600
309.673
310.719
311.738
312.732
313.702
314.649
315.575
316.479
317.364
318.230
319.078
319.908
320.721
321.519
322.301
323.068
323.820
2) ДгЯ°@)=-569.630
Я°(П-Я°@)
кДж . моль""
8.685
8.739
11.714
14.780
17.951
21.224
24.594
28.060
31.625
35.297
39.083
42.990
47.021
51.177
55.455
59.850
64.352
68.951
73.634
78.389
83.203
88.063
92.959
97.880
102.817
107.761
112.707
117.648
122.580
127.500
132.404
137.291
142.158
147.005
151.832
156.638
161.422
166.187
170.931
175.655
180.360
185.047
189.717
194.370
199.007
203.629
208.236
212.830
217.411
221.979
226.535
231.081
235.616
240.140
244.655
249.160
253.656
258.143
262.622
104.8686
104.2512
79.3594
64.3998
54.4086
47.2579
41.8832
37.6932
34.3328
31.5761
29.2723
27.3171
25.6357
24.1736
22.8895
21.7522
20.7372
19.8254
19.0012
18.2523
17.5684
16.9412
16.3637
15.8300
15.3351
14.8749
14.4456
14.0442
13.6679
13.3143
12.9815
12.6675
12.3709
12.0900
11.8237
11.5708
11.3304
11.1014
10.8831
106746
10.4754
10.2848
10.1023
3.9273
9.7593
9.5979
9.4428
9.293S
9.1498
9.0113
8.8777
8.7488
8.6242
8.5039
8.3875
8.2748
8.1657
8.0601
7.9577
(г)
кДж • моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а
i
а
о
а
О
гч °-
О ^
11 "
5 о
с
3;
+
—
X
00
00
m
1
rt
'х
СС
ОС
.-о
о
о
+
?
о
о
О
А
б л и
7ё
о
X
оо
II
?
эе
(-Г
+ rJ
w
0
—
'л
§
2
й
m
Н
+
О
—;
VO
~*
И
¦X
35
00
+
Ц а 243
'л
§
-
=1
о S
to
—1
?
О
8
чо
V
*~
V
о
о
«о
¦*"
"о
19

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9?00
9400
9600
9800
10000
J500
11000
11500
12000
12500
13000
13500
14000
1 А*^ЛП
1 40UU
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°(Т)
44.577
44.414
44.251
44.086
43.917
43.742
43.560
43.369
43.170
42.962
42.744
42.518
42.282
42.037
41.785
41.525
41.258
40.985
40.707
40.424
39.704
38.971
38.238
37.513
36.803
36.114
35.451
34.816
¦ о л O!t
OH.Z 1 1
33.637
33.095
32.584
32.104
31.654
31.233
30.839
30.471
30.128
29.808
29.511
ПОЛОЖИТЕЛЬНЫЙ ИОН ДИУГЛЕРОДА С2
Ф°(Т)
Дж ' К • миль
281.486
282.877
284.225
285.534
286.805
288.041
289.242
290.411
291.549
292.659
293.740
294.795
295.824
296.828
297.810
298.768
299.706
300.622
301.518
302.396
304.509
306.516
308.426
310.246
311.982
313.642
315.231
316.752
о | о о 1 О
о lo.z IZ
319.614
320.961
322.258
323.507
324.711
325.872
326.995
328.079
329.128
330.144
331.128
S°(T)
-l
И°(Т)~Н°@)
кДж . миль
325.285 271.554
326.698 280.453
328.062 289.319
329.380 298.153
330.656 306.953
331.891 315.719
333.087 324.449
334.246 333.142
335.370 341.796
336.460 350.409
337.518 358.980
338.545 367.506
339.543 375.985
340.512 384.417
341.454 392.799
342.370 401.130
343.260 409.408
344.125 417.632
344.968 425.800
345.787 433.913
347.742 453.944
-349.572 473.612
351.288 492.912
352.900 511.847
354,416 530.423
355.846 548.649
357.196 566.536
358.474 ' 584.100
лгл ЛП1 fin 1 4^9
оэУ.о84 OUI.ODz
360.834 618.310
361.928 634.990
362.971 651.406
363.965 667.574
364.917 683.510
365.828 699.228
366.702 714.742
367.542 730.065
368.350 745.211
369.128 760.192
369.879 775.018
lgA'°(r)
7.7619
7.5774
7.4032
7.2383
7.0821
6.9338
6.7928
6.6586
6.5306
6.4085
6.2918
6.1802
6.0732
5.9707
5.8724
5.7779
5.6871
5.5997
5.5156
5.4345
5.2442
5.0697
4.9091
4.7609
4.6236
4.4961
4.3774
• 4.2666
4 1 ft1* I
1.1 DO 1
4.0661
3.9751
3.8895
3.8089
3.7330
3.6613
3.5935
3.5294
3.4686
3.4110
3.3466
(г)
т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
• 8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
1 АЧГ\П
15000
15500
16000
16500
17000
17500
18000
18500
19000
. 19500
20000
Таблица 24.1
(окончание)
-
i
j
11
~ 'л
5
+' s
1 , 1
2 - •
^ п С
— v о
о — °
О <~1
1 ¦*• \/
н о V
-S | Е-.
? ^ v
О ГГ —
>о ^ о
CN °Я О
IT) f^l —
+ +
о я Т
С1 ЗС '—,
~ ОС
чС f"i ~~
.
0
20

• Класс точности
V-F
Т
К
298.15
300
400
500
600
. 700
8С0
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
олпл
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
29.241
29.246
29.726
30.518
31.448
32.410
33.377
34.349
35.331
36.313
37.280
38.213
39.093
39.903
40.633
41.277
41.833
42.302
42.689
43.000
43.243
43.427
43.560
43.648
43.701
43.725
43.726
43.709
43.679.
43.640
43.595
43.577
43.500
43.453
43.409
43.369
43.334
43.303
43.278
43.259
43.246
43.239
43.237
43.240
43.249
43.262
43.281
43.303
43.330
43.360
43.393
43.430
43.469
43.510
43.554
43.599
43.646
43.694
43.743
ОТРИЦАТЕЛЬНЫЙ ИОН ДИУГЛЕРОДА Сг
К6(Т) = р2 (С) •
Ф°(П
Дж К . моль
167.387
167.567
175.949
182.480
187.858
192.451
196.476
200.071
203.329
206.316
209.081
211.660
214.080
216.364
218.528
220.588
222.554
224.435
226.239
227.973
229.643
231.253
232.807
234.310
235.764
237.173
239.864
241.152
242.403
243.620
244.805
245.959
247.084
248.180
249.250
250.294
251.314
252.311
253.286
254.239
255.172
256.085
256.980
257.856
258.716
259.558
260.385
261.196
261.993
262.775
263.543
264.299
265.041
265.771
266.489
267.195
267.890
268.575
р(е) p~l(Cl) Arh
S°(T)
l
tf°GV//°@)
кДж . моль
196.487 8.676
196.668 8.730
205.138 11.676
211.852 14.686
217.497 17.784
222.417 20.976
226.808 24.266
230.795 27.652
234.465 31.136
237.878 34.718
241.080 38.398
244.101 42.173
246.965 46.039
249.690 49.989
252.288 54.016
254.773 58.113
257.148 62.269
259.423 66.477
261.603 70.727
263.693 75.012
265.700 79.325
267.626 83.659
269.477 88.008
271.257 92.369
272.970 96.737
274.620 101.108
27fi 211 - 105 481
a#w*^11 IUUi"OI
277.744 109.853
279.226 114.222
280.658 118.588
282.042 122.950
283.375 127.279
284.683 131.660
285.943 136.007
287.166 140.350
288.355 144.689
289.511 149.024
290.636 153.356
291.732 157.685
292.801 162.012
293.843 166.337
294.860 170.661
295.855 174.985
296.826 179.309
297.777 183.633
298.707 187.959
299.618 192.286
300.511 196.615
301.386 200.947
302.244 205.281
303.086 209.619
303.913 213.960
304.725 218.305
305.523 222.654
306.308 227.007
307.073 231.365
307.838 235.727
308.584 240.094
309.319 244.466
(г)
'"@) = 942.000 кДж • моль"
lgAC°(D
-159.5566
-158.5275
-116.9949
•91.9891
-75.2627
-63.2765
-54.2588
-47.2240
-41.5798
-36.9489
-33.0796
-29.7971
-26.9765
-24.5263
¦22.3774
-20.4772
-18.7844
-17.2667
-15.8979
-14.6571
-13.5267
-12.4927
-11.5429
-10.6675
-9.8578
-9.1066
-8.4077
-7.7557
-7.1460
-6.5744
-6.0375
-5.5322
-5.0555
-4.6052
-4.1790 '
-3.7750
-3.3915
-3.0268
-2.6797
-2.3487
. -2.0329
-1.7311
-1.4424
•1.1659
-.9008
-.6465
-.4023
-.1675
.0584
.2759
.4856
.6877
.8828
1.0712
1.2532
1.4293
1.5996
1.7646
1.9244
Т
К
298.15
300
400
500»
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 244
i
J3
й
'а к ~
| «§ ё
¦ х 2
ej t _¦
"* о '
" гл 5-
9 ° " «§
««. ОО ,—». ^
?N "^ & <^
II *О ^
\\ м "-J
5г о оо f-1
* и Я 11
о У,
а; с.
<|
1
1
н
*^
+ §
1 -""
о . ¦ g
К ч §
о * "
н "* V
i J §
00 X
^ -SS *о
+ ¦ ,
00 ^ W
, 1
1 1
о
21

ОТРИЦАТЕЛЬНЫЙ ИОН ДИУГЛЕРОДА С2 (г)
Таблица 244
(окончание)
г
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
с; (D
43.844
43.947
44.051
44.154
44.255
44.354
44.450
44.542
44.629'
44.711
44.787
44-.857
44.920
44.976
45.024
45.064
45.096
45.120
45.134
45.139
Ф°(Г)
Дж . К . моль
269.912
271.211
272.472
273.698
274.891
276.053
277.186
278.290
279.369
280.421
281.450
282.456
283.439
284.402
285.345
286.268
287.173
288.060
288.931
289.785
S°(T)
-1
310.755
312.149
313.503
314.819
316.100
317.348
318.565
319.752
320.910
322.041
323.146
324.226
325.282
326.316
327.327
328.317
329.286
330.236
331.167
332.079
Я°<П-Я°@)
кДж . моль
253.224
262.003
270.803
279.624
288.464
297.326
306.206
315.105
324.023
332.957
341.906
350.871
359.849
368.839
377.839
386.848
395.864
404.885
413.911
422.938
*™
2.2295
2.5167
2.7877
3.0439
3.2864
3.5164
3.7349
3.9428
4.1408
4.3296
4.5101
4.6826
4.8477
5.0060
5.1578
5.3037
5.4438
5.5787
5.7086
5.8337
Г
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
х
о -
3 о
6 2
S
о
о
о
х о
о о
Г; О
? V
Nx V
2 о
S §
ЧО -—<
&
е-
22

Класс точности
VI-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
F
С°(Т)
р
41.687
41.801
42.202
42.218
43.383
44.883
46.406
47.796
48.997
50.006
50.844
51.535
52.106
52.579
52.974
53.307
53.594
53.848
54.079
54.298
54.515
54.737
54.973
55.229
55.509
55.819
56.162
56.541
56.957
57.41
57.905
58.436
59.004
59.608
60.246
60.914
61.610
62.330
63.072
63.830
64.602
65.383
66.169
66.957
67.741
68.518
69.285
70.037
70.771
71.485
72.174
72.836
73.470
74.072
74.641
75.176
75.675
76.138
76.564
76.953
77.304
ТРИУГЛЕРОД С3 (
К°(Т) = Р3 (С) /Г1 (С3»
Ф°(Т)
S°(T)
Дж -К .моль
153.667 191.782
180.799 220.764
196.889 237.501
197.140 237.762
208.899 250.054
218.144 259.893
225.813 268.212
232.399 275.472
238.195 281.935
243.384 287.766
248.092 293.079
252.406 297.959
256.392 302.468
260.100 306.658
263.567 310.569
266.824 314.236
269.896 317.686
272.804 320.943
275.564 324.027
278.193 326.957
280.701 329.747
283.101 332.412
285.400 334.964
287.609 337.413
289.734 339.770
291.781 342.042
293.756 344.238
295.666 346.364
297.513 348.428
299.304 350.435
301.041 352.389
302.728 354.296
304.369 356.160
305.966 357.985
307.522 359.774
309.040 361.530
310.523 363.256
311.971 364.954
313.387 366.626
314.773 368.274
316.131 369.900
317.462 371.504
318.768 373.089
320.049 374.655
321.308 376.204
322.545 377.735
323.761 379.249
324.958 380.748
326.136 382.230
327.296 383.696
328.438 385.147
329.564 386.583
330.674 388.004
331.769 389.409
332.850 390.799
333.916 392.173
334.968 393.532
336.008 394.876
337.034 396.204
338.048 397.516
339.050 398.812
>)
ArH°@)= 1302.555 кДж • моль"
//°(Л-Я°@)
кДж . моль
3.812
7.993
12.109
12.187
16.462
20.874
25.439
30.151
34.992
39.944
44.988
50.108
55.291
60.526
65.804
71.118
76.464
81.836
87.232
92.651
98.092
103.Э55
109.040
114.550
120.087
125.653
131.251
136.886
142.561
148.279
154.044
159.861
165.733
171.663
177.656
183.713
189.839
196.036
202.306
208.651
215.072
221.572
228.149
234.805
241.540
248.353
255.244
262.210
269.250
276.364
283.547
290.797
298.113
305.490
312.926
320.417
327.960
335.551
343.186
350.863
358.576
-670.9731
-329.6955
-217.1608
-215.7454
-158.6803
-124.3908
-101.5003
-85.1299
-72.8384
-63.2686
-55.6055
-49.3303
-44.0966
-39.6646
-35.8630
-32.5658
-29.6789
-27.1298
-24.8625
-22.8326
-21.0045
-19.3495
-17.8439
-16.4685
-15.2069
-14.0456
-12.9729
-11.9791
-11.0558
-10.1957
-9.3924
-8.6406
-7.9355
-7.2728
¦6.6487
-6.0601
-5.5040
-4.9778
-4.4791
-4.0058
-3.5561
-3.1283
-2.7208
-2.3322
-1.9612
-1.6067
-1.2677
-.9431
-.6321
-.3338
-.0475
.2275
.4918
.7461
.9908
1.2266
1.4538
1.6730
1.8845
2.0887
2.2860
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 245
1
л
с:
— о
й • i
о * S
— * к
< Я. О
я Si -
m о ^
Я 2 II Я
И II jo г~-
5 О оо' ""
- ¦ , - ч
,*? ^ О ОС
у. ^ to
о 0
^ 0
1
1
н _
оо t л
m О
_: s
+ -¦
7 '*
X
® »—«
do V
С 1 V
~ гч О
^" Н О
00 v> w>
ОО ГЧ |
"О *о О
*t m ^
П ? II
^ • н
II I
?
о
•б1
23

ТРИУГЛЕРОД С3 (г)
Таблица 245
(окончание)
С°р(Т)
Ф°(Г)
S°(T)
к
Дж . К~ . моль"
Я°G>Яо@)
кДж • моль
\gfC°(T)
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
77.895
78.342
78.651
78.831
7S.893
78.848
78.708
78.484
78.189
77.833
77.427
76.980
76.501
75.996
75.474
74.941
74.400
73.857
73.315
72.777
341.019
342.943
344.825
346.667
348.469
350.234
351.963
353.657
355.317
356.944
358.539
360.103
361.637
363.141
364.618
366.066
367.488
368.883
370.252
371.597
401.357
403.838
406.254
408.605
410.891
413.113
415.272
417.368
419.403
421.378
423.295
425.155
426.961
428.714
430.416
432.069
433.675
435.236
436.753
438,229
374.098
389.724
405.426
421.176
436.950
452.726
468.483
484.204
499.872
515.476
531.002
546.444
561.792
577.042
592.190
607.231
622.165
636.991
651.708
666.317
2.6611
3.0124
3.3420
3.6518
3.9435
4.2186
4.4785
4.7244
4.9574
5.1785
5.3886
5.5885
5.7788
5.9604
6.1338
6.2995
6.4580
6.6099
6.7554
6.8952
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
00
О
8
о*
ч
I
Os
+
V
f-,
V
о
о
о
24

Класс точности
VII-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
38.991
50.989
57.271
57.361
61.446
64.603
67.337
69.819
72.099
74.201
76.147
77.957
79.647
81.227
82.705
84.080
85.354
86.525
87.592
88.556
89.418
90.181
90.850
91.430
91.928
92.351
92.706
93.001
93.241
93.435
93.589
93.708
93.798
93.863
93.908
93.937
93.953
93.958
93.955
93.947
93.935
93.919
93.903
93.885
93.868
93.852
93.836
93.823
93.810
93.800
93.791
93.784
93.779
93.775
93.773
93./73
93.7
93.775
93.778
93.781
93.786
Ф (Т)
Дж . К ¦ моль
167.819
192.220
208.750
209.023
222.257
233.291
242.811
251.219 •
258.775
265.655
271.985
277.857
283.341
288.492
293.355
297.963
302.345
306.526
310.525
314.359
318.043
321.589
325.008
328.309
331.501
334.591
337.585
340.490
343.310
346.050
348.715
351.309
353 835
356.297
358.698
361.040
363.327
365.561
367.744
369.879
371.967
374.010
376.011
377.971
379.891
381.773
383.619
385.430
387.206
388.951
390.663
392.346
393.998
395.623
397.220
398.791
400.336
401.856
403.352
404.825
406.276
ТЕТРАУГЛЕРОД С4 (г)
р''(С4)
S°(T)
1
199.960
231.103
252.746
253.101
270.195
284.256
296.281
306.850
316.324
324.939
332.859
340.203
347.059
353.497
359.572
365.325
370.793
376.003
380.979
385.741
390.306
394.688
398.899
402.950
406.852
410.614
414.243
417.747
421.134
424.410
427.580
430.651
433.627
436.515
439.317
442.040
444.686
447.261
449.767
452.207
454.585
456.905
459.168
461.377
463.535
465.644
467.707
469.725
471.700
473.634
475.529
477.386
479.207
480.994
482.747
484.468
486.157
487.817
489.448
491.051
492.627
Д Я°@) = 1819.740 кДж-моль"
Н°(Г)-Н°@)
кДж . моль"
3.214
7.777
13.117
13.223
19.175
25.483
32.082
38.942
46.039
53.356
60.874
68.580
76.462
84.506
92.704
1С1.044
109.516
118.111
126.818
135.626
144.526
153.506
162.559
171.673
180.842
190.056
199.310
208.596
217.908
227.242
236.594
245 959
255.335
264.718
274.106
283.499
292.893
302.289
311.684
321.080
330.474
339.867
349.258
358.647
368.035
377.421
386.805
396.188
405.570
414.950
424.Ь30
433.708
443.087
452.464
461.842
471.219
480.596
489.974
499.352
508.729
518.108
Т
К
-936.0488 100
-458.7198 200
-301.2802 298.15
-299.3002 300
-219.4728 400
-171.5182 500
-139.5156 600
-116.6367 700
-99.4649 800
-86.1010 900
75.4046 1000
-66.6496 1100
-59.3518 1200
-53.1754 1300
-47.8809 1400
-43.2922 1500
-3J.2772 1600
-35.7349 1700
-32.5868 1800
-29.7707 1900
-27.2368 2000
-24.9450 2100
-22.8622 2200
-20.9612 2300
-19.2193 2400
-.7.6174 2500
-16.1393 2600
-14.7712 2700
1 А р ^Ъ • л ПЛЛЛ
-13.5014 2800
-12.3196 2900
-11.2171 3000
-10.1860 3100
-9.2198 3200
-8.3125 3300
-/.4588 3400
-6.6542 3500
-5.8945 3600
-5.1762 3700
-4.4958 3800
-3.8505 3900
-3.2376 4000
-2.6547 4100
-2.0998 4200
-1.5708 4300
-1.0659 4400
-.5835 4500
-.1222 4600
.3194 4700
.7425 4800
1.1483 4900
1.5378 5000
1.9120 5100
2.2718 5200
2.6179 5300
2.9512 5400
3.2724 5500
3.5820 5600
3.8808 5700
4.1692 5800
4.4479 5900
4.7172 6000
Таблица 246
1
7
А
К
7 1
й : -
1 н '-
. 3 §
? г- S
X °!
_ о 1
2 <*> М
5 о 2
^ N " Ы
ОО Q i*. ^^
.* ° Я s
и и ? 3
5 О оо м
» ¦-" о 5
оВ С? "
° у
IS п
**ч О
< ¦-,
<Х
ГО '„а
С\ В
(S §
\о ^
о ^
г, И
я 5 *
а~ Ч 2
о S *>
Ч "? V
t 1
со о
О\ ГО «-)
Я 3
• , •" i
 i
О 00 "
ОО г»
377.
144.1
(х
и +
0
в
25

ТЕТРАУГЛЕРОД С4 (г)
Таблица 246
(окончание)
Ф°(Г)
S°(T)
Дж . К . моль
кДж • моль
-1
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
93.795
93.805
93.814
93.822
93.827
93.830
93.829
93.824
93.815
93.801
93.783
93.760
93.733
93.702
93.667
93.627
93.584
93.538
93.488
93.435
409.111
411.864
414.539
417.140
419.671
422.136
424.539
426.881
429.167
431.399
433.579
435.709
437.793
439.831
441.826
443.780
445.693
447.569
449.408
451.211
495.702
498.680
501.567
504.368
507.088
509.731
512.302
514.804
517.241
519.616
521.932
524.192
526.397
528.552
530.657
532.716
534.729
536.698
538.627
540.515
536.866
555.626
574.388
593.151
611.916
630.682
649.448
668.213
686.977
705.739
724.497
743.252
762.001
780.745
799.482
818.211
836.932
855.645
874.347
893.040
5.2298
5.7103
6.1616
6.5863
6.9868
7.3650
7.7227
8.0616
8.3831
8.6885
8.9791
9.2558
9.5196
9.7715
10.0122
10.2424
10.4629
10.6742
10.8769
11.0715
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
I
н
•г,
V
г-
V
о
о
о
II
g
л.
1О
00
гч
1
II
26

Класс точности
VII-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
'4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
G
с°рт
46.334
65.350
75.502
75.643
82.022
87,007
91.152
94.579
97.376
99.644
101.483
102.980
104.206
105.218
106.059
106.764
107.360
107.866
108.300
108.674
108.999
109.282
109.530
109.749
109.943
110.115
110.269
110.407
110.532
110.644
110.746
110.838
110.922
110.999
111.069
111.134
111.194
111.249
111.299
111.346
111.390
111.430
111.468
111.503
111.536
111.567
111.595
111.622
111.648
111.672
111.694
111.715
111.735
111.754
111.772
111.789
111.805
111.820
111.834
111.848
111.861
К°(Т) = р5 (С) •
¦Ф°G-)
Дж ¦ К . моль
169.227
197.230
217.257
217.594
234.136
248.189
260.470
271.419
281.323
290.380
298.735
306.495
313.742
320.542
326.950
333.009
338.755
344.220
349.431
354.410
359.177
363.750
368.144
372.372
376.447
380.379
384.178
387.853
391.411
394.860
398.206
401.456
404.614
407.686
410.676
413.589
416.428
419.197
421.899
424.538
427.116
429.637
432.102
434.515
436.876
439.189
441.455
443.677
445.855
447.992
450.089
452.148
454.169
456.155
458.106
460.025
461.910
463.765
465.589
467.385
469.152
ПЕНТАУГЛЕРОД С5
Р~'(С5)
5°(Г)
1
204.905
243.372
271.563
272.031
294.715
313.571
329.812
344.130
356.948
368.553
379.150
388.895
397.910
406.292
414.121
421.463
428.373
434.897
441.076
446.941
452.524
457.849
462.939
467.812
472.488
476.979
481.301
485.465
489.483
493.364
497.116
500.749
504.269
507.684
510.998
514.219
517.351
520.398
523.365
526.257
529.077
531.828
534.513
537.137
539.701
542.207
544.660
547.060
549.410
551.713
553.969
556.181
558.351
560.479
562.568
564.619
566.634
568.613
570.558
572.469
574.350
v
Н°(Т)-Н°{0)
кДж . моль
3.568
9.228
16.191
16.331
24.232
32.691
41.605
50.898
60.500
70.355
80.415
90.640
101.002
111.475
122.040
132.682
143.389
154.151
164.960
175.809
186.693
197.607
208.548
219.512
230.497
241.500
252.520
263.553
274.600
285.659
296.729
307.808
318.896
329.992
341.096
352.206
363.322
374.444
385.572
396.704
407.841
418.982
430.127
441.276
452.428
463.583
474.741
485.902
497.065
508.231
519.400
530.570
541.743
552.917
564.093
575.271
586.451
597.632
608.815
619.999
631.184
(г)
Г°@)= 2515.925
-1293.9574
-634.1586
-416.5842
-413.8480
-303.5627
¦237.3323
-193.1485
-161.5725
-137.8815
-119.4503
-104.7027
-92.6354
-82.5789
-74.0695
-66.7762
-60.4558
-54.9261
-50.0475
-45.7116
-41.8327
-38.3422
-35.1847
-32.3148
-29.6948
-27.2936
-25.0848
-23.0462
-21.1589
-19.4067
-17.7755
-16.2533
-14.8294
-13.4946
-12.2408
-11.0608
-9.9483
-8.8977
-7.9039
-6.9624
-6.0692
-5.2207
-4.4136
-3.6448
-2.9118
-2.2121
-1.5434
-.9037
-.2913
.2957
.8588
1.3994
1.9189
2.4185
2.8992
3.3622
3.8085
4.2388
4.6541
5.0552
5.4427
5.8174
кДж • моль" '
Т
К .
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т a
i
л
к
о
к
о
ю °
§ 3
т ^
§ о
ьГ
m
О
о
_+
X
OS
г-
\О
+
'ч
О
оо
р
о
1
J3
оо
Г)
00
OS
+
OS
oi
II
о
в
б Л И
"л
Q
°
о
II
я
об
о»
и"
(J
0
ч.
<J
1
E-J"
*•>
f-
22
+
od
OS
5
1
X.
о
+
ua 247
-
Л
о
-
•
00
л
Я
о
о
S
V
V
о
¦п
«"¦
1
о
•~ч
^.
II
27

ПЕНТАУГЛЕРОД С5 (г)
Таблица 247
(окончание)
Ф°(Г)
Дж . К • моль
Н°(Т)~Н°@)
кДж ¦ моль
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
111.885
111.907
111.927
111.945
111.962
111.977
11.992
12.005
12.017
12.028
12.038
12.048
12.057
12.065
12.073
12.081
12.087
12.094
12.100
12.106
472.605
475.955
479.208
482.369
485.444
488.437
491.352
494.193
496.964
499.669
502.310
504.890
507.412
509.879
512.293
514.656
516.970
519.238
521.460
523.640
578.018
581.570
585.014
588.356
591.601
594.755
597.824
600.810
603.720
606.556
609.322
612.022
614.659
617.235
619.754
622.217
624.628
626.988
629.299
631.564
653.559
675.938
698.322
720.709
743.100
765.494
787.891
810.290
832.692
855.097
877.504
899.912
922.323
944.735
967.149
989.564
1011.981
1034.399
1056.819
1079.239
6.5306
7.1994
7.8280
8.4198
8.9780
9.5053
10.0044
10.4773
10.9262
11.3529
11.7589
12.1457
12.5147
12.8670
13.2039
13.5263
13.8351
14.1311
14.4152
14.6881
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
+
О
о
О
О
Ы
о
о
о
с
V
f-.
V
28

Класс точности i
I-C 1
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
А'°(Г)=Р(С)
Ф°(Г)
ОКСИД УГЛЕРОДА СО (г)
• р(О) р (СО)
S°(T)
Дж ¦ к . моль
29.104
29.109
29.141
29.! 42
29.340
29.792
30.440
31.170
31.896
32.573
33.178
33 703
34.169
34.568
34.9L
35.213
35.475
35.703
35.905
36.083
36.241
36.383
36.510
36.625
36.730
36.826
36.914
36.995
37.070
37.140
37.205
37.266
37.324
37.378
Ь7.430
37.479
37.526
37.571
37.615
37.657
37.697
37.736
37.775
37.812
Й/.849
37.885
37.921
37.956
37.991
38.027
3*.О62
38.098
18.135
38.173
38.211
38.251
38.293
38.336
38.381
38.429
38.480
136.722
156.857
168.465
168.645
177.016-
.83.521
188.858
193.398
197.361
200.887
204.071
206.977
209.655
212.140
214.460
216.638
218.689
220.630
222.472
224.225
225.898
227.498
229.031
230.503
231.919
233.283
234.598
235.868
237.097
238.287
239.440
240.559
241.645
242.701
243.728
244.728
245.702
246.652
247.578
248.482
249.365
250.228
251.072
251.898
252.706
253.497
254.272
255.032
255.776
256.507
257.224
257.927
258.618
259.297
259.964
260.620
261.264
261.898
262.522
263.136
263.740
165.748
185.923
197.548
197.729
206.134
212.725
218.212
222.958
227.168
230.965
234.429
237.617
240.570
243.321
245.896
248.315
250.596
252.754
254.800
256.747
258.601
260.373
262.068
263.694
265.255
266.756
268.203
269.597
270.944
272.246
273.506
274.727
275.911
277.061
278.177
279.263
280.320
281.348
. 282.351
283.328
284.282
285.214
286.124
287.013
287.883
288.733
289.567
290.383
291.182
291.965
292.734
293.488
294.228
294.955
295.669
296.371
297.060
297.738
298.405
299.062
299.708
А Я°@) = 1071.780
Н°(Г)-Н°@)
кДж . моль"
2.903
5.813
8.671
8.725
11.647
14.602
17.612
20.692
23.846
27.070
30.358
33.703
37.098
40.535
44.010
47.516
51.051
54.610
58.191
61.790
65.407
69.038
72.683
76.340
80.007
83.685
87.372
91.068
ЛЛ 111
94.771
98.482
102.199
105.922
109.652
113.387
117.127
120.873
124.623
128.378
132.137
135.901
139.669
143.440
147.216
150.995
154.778
158.565
162.355
166.149
169.946
173.747
177.552
181.360
185.172
188.987
192.806
196.629
200.456
204.288
208.124
211.964
215.810
-555.2221
-274.7080
-182.2322
-181.0693
-134.1894
-106.0272
-87.2308
-73.7905
-63.7003
-55.8451
-49.5556
-44.4056
-40.1107
-36.4741
-33.3550
-30.6501
-28.2818
-26.1910
-24.3315
-22.6669
-21.1679
-19.8110
-18.5768
-17.4494
-16.4155
-15.4638
-14.5849
-13.7707
1 О Л 1 А Ч
-13.0143
-12.3097
-11.6518
-11.0360
-10.4584
-9.9156
-9.4044
-8.9222
-8.4665
-8.0353
-7.6265
-7.2385
-6.8697
-6.5187
-6.1843
-5.8652
-5.5604
-5.2691
-4.9902
-4.7230
-4.4669
-4.2210
-3.9848
-3.7578
-3.5394
-3.3290
-3.1264
-2.9310
-2.7424
-2.5604
-2.3845
-2.2145
•2.0500
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
'л
-. о
г 'й s
§ s ез
¦ й s
о ^ "
Я ' ¦ м
11 u*l
и Д .2
¦? ° о?
С (N
О ь
В о
"> в
+
7
чо _
S 'л
** 5
ts о
о 2
+ „'
я 5
о пх
о Ц
1 00
и +
00 *
^" ^^
5 о
8 ё
<s о
2 •*
С
О
в
а 248
-а
i
К
ГЦ
О
II
0 К
to
я
о
V
V
о
(О
•о
^.
II
29

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
с; en
38.591
38.718
38.864
39.032
39.226
39.449
39.706
39.999
40.333
40.711
41.135
41.609
42.134
42.712
43.344
44.030
44.770
45.562
46.406
47.297
49.711
52.330
55.061
57.790
60.415
62.818
64.909
66.617
67.895
68.726
69.112
69.080
68.670
67.932
66.922
65.696
64.307
62.804
61.230
59.622
ОКСИД УГЛЕРОДА СО (г)
Ф°(Г)
Дж . К • моль
264.921
266.066
267.180
268.262
269.315
270.341
271.341
272.317
' 273.269
274.200
275.110
276.001
276.873
277.728
278.567
279.390
280.198
280.993
281.775
282.544
284.417
286.228
287.985
289.696
291.365
293.000
294.602
296.176
297.723
299.246
300.743
302.217
303.667
305.093
306.495
307.872
309.223
310.549
311.850
313.125
S°(T)
300.972
302. Г99
303.392
304.555
305.689
306.797
307.881
308.944
309.988
311.013
312.024
313.020
314.006
314.981
315.948
316.908
317.862
318.813
319.761
320.708
323.073
325.445
327.832
330.233
332.646
335.063
337.474
339.867
342.228
344.545
346.806
349.001
351.121
353.161
355.116
356.984
358.766
360.461
362.072
363.602
Н°(Т)-/Г@)
кДж . моль
223.516
231.247
239.005
246.794
254.619
262.486
270.401
278.371
286.404
294.507
302.691
310.965
319.338
327.822
336.427
345.163
354.042
363.075
372.270
381.640
405.882
431.385
458.231
486.447
516.006
546.825
578.771
611.670
645.316
679.490
713.968
748.533
782.985
817.149
850.872
884.035
916.541
948.323
979.334
1009.548
-1.7368
-1.4427
-1.1661
-.9055
-.6594
-.4267
-.2064
.0026
.2011
.3898
.5696
.7409
.9045
1.0607
1.2100
1.3530
1.4899
1.6212
1.7471
1.8680
2.1501
2.4062
2.6394
2.8525
3.0476
3.2266
3.3912
3.5429
3.6828
3.8122
3.9321
4.0433
4.1468
4.2432
4.3332
4.4174
4.4964
4.5706
4.6406
4.7065
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
3000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 248
(окончание)
1
i
я
" |
7 Т
§ к
о 2
п §
О т—ч О
« I
40 ^ \/
(N *-н о
Tj- 00 О
1/1 «-Н 1—1
00 X Т
00 00 2
гЛ О ¦ "
О -н &«ч ¦
II
ii I \li
II 1 ^-^
?
0
30

Класс точности
I-C
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
f
29.137
29.138
29.317
29.741
30.362
31.076
31.795
32.469
33.077
33.613
34.081
34.487
34.840
35.148
35,416
35.652
35.859
36.044
36.209
36.358
36.493
36.617
36.733
36.842
36.947
37.048
37.149
37.250
37.353
37.459
37.569
37.684
37.806
37.935
38.071
38.216
38.370
38.532
38.718
38.900
39.092
39.292
39.502
39.720
39.947
40.181
40.423
40.672
40.928
41.189
41.456
41.728
42.004
42.283
42.565
42.851
43.138
43.426
43.715
ПОЛОЖИТЕЛЬНЫЙ ИОН ОКСИДА
УГЛЕРОДА С0+ (г)
К°(Т)= р(С) р(О) р~\е) р'^СО*) Дг#°@)= -280.347 кДж • моль
Ф°(Г)
Дж • К • моль
174.036
174.216
182.5.86
189.090
194.424
198.960
202.918
206.440
209.618
212.520
215.192
217.673
219.988
222.161
224.209
226.146
227.985
229.735
231.404
233.001
234.532
236.001
237.415
238.776
240.090
241.359
?\ Л 4Ъ V ?% ?Ъ
242.586
243.775
244.927
246.044
247.130
248.186
249.213
250.213
251.188
252.138
253.066
253.972
254.857
255.723
256.570
257.400
258.213
259.009
259.790
260.556
261.308
262.047
262.773
263.486
264.187
264.877
265.556
266.224
266.883
267.531
268.170
268.800
269.422
S°{T)
1
Я°G)-Я°@)
кДж . моль"
203.118 8.671
203.298 8.725
211.700 11.646
218.283 14.596
223.758 17.600
228.491 20.672
232.688 23.816
236.472 27.029
239.925 30.307
243.104 33.642
246.049 37.028
248.793 40.456
251.362 43.923
253.777 47.423
256.054 50.952
258.208 54.505
260.252 58.081
262.196 61.676
264.049 65.289
265.819 68.918
267.514 72.560
269.139 76.216
270.699 79.883
272.201 83.562
273.648 87.252
275.044 90.951
276.394 94.661
277.699 98.381
278.964 102.111
280.190 105.852
281.381 109.603
282.539 113.366
283.666 117.140
284.763 120.927
285.834 124.727
286.879 128.542
287.900 132.371
288.899 136.216
289.879 140.087
290.837 143.968
291.777 147.867
292.699 151.786
293.605 155.726
294.495 159.687
295.371 163.670
296.232 167.676
297.080 171.707
297.917 175.761
298.741 179.841
299.554 183.947
300.356 188.079
301.149 192.238
301.931 196.425
302.704 200.639
303.469 204.882
304.225 209.152
304.972 213.452
305.712 217.780
306.444 222.137
\еК°(Т)
54.3562
54.0516
41.7635
34.3701
29.4264
25.8836
23.2172
21.1355
19.4634
18.0895
16.9397
15.9622
15.1206
14.3876
13.7432
13.1718
12.6614
12.2024
11.7872
11.4097
11.0648
10.7482
10.4566
10.1870
9.9368
9.7041
9.4869
9.2836
9.0930
8.9138
8.7450
8.5856
8.4349
8.2921
8.1566
8.0278
7.9052
7.7884
7.6768
7.5702
7.4682
7.3704
7.2767
7.1867
7.1002
7.0170
6.9369
6.8596
6.7851
6.7132
6.6437
6.5765
6.5114
6.4485
6.3874
6.3282
6.2708
¦ 6.2150
6.1608
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 249
-1
-1
моль"'
л
° а ~
. S6 ' Л
С! S S
m ^ '«
? » II
1 2 Я п
Я и ¦ 2 ^
« о g ^
+ * С "
8 ъ »«
^ 8 **
о ^
5l о
+
7
н —
m Й
«N 1
О —•
+ 1
<-< а
з 5 о
О о
о о V
i °
н 7 v
s "С °
°. ^ т
to о "о
+ 1 •
§ -з- "
3 * s
И +
hs
о
31

ПОЛОЖИТЕЛЬНЫЙ ИОН ОКСИДА УГЛЕРОДА СО* (г)
Т а б л и ц а 249
(окончание)
К
с;
Ф°(Г)
S°(T)
Дж . к • миль
кДж . моль
-1
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
44.292
44.866
45.432
45.986
46.525
47.046
47.545
48.021
48.469
48.890
49.280
49.638
49.962
50.253
50.508
56.727
50.911
51.058
51.170
51.246
51.286
51.123
50.777
50.271
49.630
48.879
48.043
47.143
46.201
45.234
44.256
43.280
42.316
41.371
40.453
39.564
38.708
37.887
37.101
36.353
270.639
271.826
272.982
274.112
275.215
276.294
277.35ft
278.384
279.398
280.392
^281.367
282.324
283.265
284.189
285.097
285.991
286.869
287.734
288.585
289.423
291.463
293.428
295.324
297.154
298.921
300.628
302.279
303.875
305.419
306.914
308.360
309.761
311.118
312.433
313.708
314.944
316.142
317.306
318.435
319.531
307.887
309.303
310.692
312.057
313.397
314.715
316.0Н
317.286
318.539
319.771
320.983
322.175
323.347
324.499
325.631
326.744
327.837
328.910
329.964
330.999
333.501
335.884
338.149
340.300
342.340
344.272
346.101
347.832
349.470
351.020
352.488
353.877
355.195
356.444
357.630
358.756
359.829
360.850
361.824
362.754
230.938
239.854
248.884
258.025
267.277
276.634
286.094
295.651
305.300
315.036
324.854
334.746
344.707
354.729
364.806
374.930
385.094
395.292
405.515
415.757
441.399
467.009
492.492
517.760
542.740
567.372
591.605
615.404
638.741
661.601
683.873
705.857
727.255
748.176
768.631
788.634
808.200
827.347
846.093
864.455
6.0568
5.9583
5.8648
5.7759
5.69I
5.6101
5.5327
5.4585
5.3873
5.3189
5.2531
5.1897
5.1286
5.0696
5.0126
4.9574
4.9040
4.8522
4.8020
4.7532
4.6373
4.5291
4.4277
4.3324
4.2427
4.1580
4.0779
4.0020
3.9301
3.8618
3.7968
3.7350
3.6762
3.6200
3.5665
3.5154
3.4666
3.4199
3.3753
3.3229
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
г- —
fS I
о «3
н
со
q
d
X
?
X
«о
ON
ОС
I
о
о
V
к.
V
"к <->
¦ *5 о
Ъ. 2
I 2
32

Класс точности
II-С
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
29.206
32.360
37.135
37.220
41.328
44.627
47.327
49.569
51.442
53.008
54.320
55.423
56.354
57.144
57.818
58.397
58.898
59.334
59.717
60.054
60.354
60.622
60.862
61.080
61.278
61.458
61.625
61.778
61.921
62.054
62.179
62.298
62.410
62.518
62.623
62.724
62.824
62.923
63.022
63.122
63.223
63.328
63.435
63.547
63.664
63.787
63.917
64.054
64.199
64.353
64.516
64.689
64.873
65.068
65.273
65.491
65.721
65.962
66.217
66.483
66.762
К°(Т)=р(С)
Ф°(Г)
ДИОКСИД
• р2(О) р"Ч(
S°(T)r
Дж .К .моль
149.791
170.092
182.262
182.457
191.773
! 99.440
206.044
211.890
217.162
221.978
226.420
230.549
234.410
238.038
241.462
244.705
247.787
250.722
253.525
256.208
258.781
261.252
263.630
265.922
268.133
270.269
272.336
274.337
276.277
278.160
279.989
281.766
283.495
285.179
286.819
288.418
289.978
291.501
292.988
294.442
295.863
297.254
298.615
299.948
301.254
302.535
303.790
305.021
306.230
307.416
308.582
309.727
310.852
311.958
313.047
314.117
315.171
316.208
317.229
318.235
319.227
178.887
199.854
213.674
213.904
225.196
234.785
243.168
250.637
257.382
263.534
269.189
274.419
279.283
283.826
288.086
292.095
295.880
299.464
302.867
306.105
309.193
312.144
314.970
317.680
320.284
322.789
325.203
327.532
329.781
331.956
334.062
336.103
338.083
340.005
341.873
343.689
345.458
347.181
348.860
350.498
352.098
353.660
355.187
356.681
358.144
359.576
360.979
362.355
363.705
365.030
366.332
367.612
368.869
370.107
371.325
372.525
373.707
374.872
376.021
377.156
378.275
УГЛЕРОДА СО2
(г)
:О2) ДгЛ°@)= 1597
с
Н°(Г)-Н°@)
кДж . моль*"
2.910
5.952
9.365
9.434
13.369
17.673
22.275
27.123
32.176
37.401
42.769
48.258
53.848
59.524
65.273
71.085
76.950
82.862
88.815
94.804
100.825
106.874
112.948
119.045
125.163
131.300
137.455
143.625
149.810
156.009
162.220
168.444
174.680
180.926
187.183
193.451
199.728
206.015
212.313
218.620
224.937
231.264
237.603
243.952
250.312
256.684
263.070
269.468
275.881
282.308
288.752
295.212
301.690
308.187
314.704
321.242
327.802
334.386
340.995
347.630
354.292
о
-824.7723
-406.0478
-267.8957
-266.1579
-196.0894
-153.9882
-125.8876
-105.7960
-90.7148
-78.9766
-69.5804
-61.8887
-55.4761
-50.0479
-45.3936
-41.3588
-37.8274
-34.7107
-31.9398
-29.4602
-27.2282
-25.2084
-23.3721
-21.6952
-20.1579
-18.7435
-17.4377
-16.2286
-15-1057
-14.0602
-13.0843
-12.1713
-11.3153
-10.5111
-9.7541
-9.0404
-8.3662
-7.7284
-7.1241
-6.55б8
-6.0060
-5.4878
-4.9942
-4.5235
-4.0742
-3.6447
-3.2339
-2.8405
-2.4635
-2.1018
-1.7546
-1.4209
-1.1000
-.7912
-.4938
-.2071
.0693
.3360
.5936
.8424
1.0830
.893 кДж ¦ моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
-
А
- l
i й
2 *
" о
X m
3 «?
00 —« '
о gj "
2  Я
5 ¦ ' ¦ *
II ^
" g? 00*
^ - (N
о ¦ «
У о
%* ^
^ 0
< ч
'я —
°о §
•ч 7
X
о Д
1 *
о *"*
о «¦;
я ^*
•? п
оо Э
-1 •
? ' §
+ 1
ON X
00 О
**• S
II +
К
О
ц а 250
i
g
|
i
00
00
о
II
eg
я
§
S
V
V
§
?""
'о
к.
II
33

ДИОКСИД УГЛЕРОДА СО2 (г)
Таблица 250
(окончание)
г
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
С0 <Т)
67.358
68.002
68.693
69.429
70.205
71.018
71.862
72.733
73.624
74.529
75.443
76.360
77.272
78.175
79.062
79.928
80:769
81.580
82.356
83.095
Ф°(Г)
Дж • К"" - моль
321.167
323.054
324.891
326.681
328.428
330.133
331.799
333.429
335.024
336.586
338.118
339.620 .
341.096
342.544
343.968
345.369
346.746
348.102
349.438
350.753
5°(Г)
380.474
382.623
384.726
386.787
388.811
390.800
392.757
394.685
396.586
398.461
400.313
402.142
403.949
405.736
407.503
409.250
410.978
412.687
414.377
416.048
Н°(Т)-Н°@)
кДж . моль
367.704
381.239
394.907
408.719
422.682
436.803
451.09!
465.550
480.185
495.000
509.997
525.178
540.541
556.086
571.810
587.709
603.780
620.015
636.409
652.955
\gK°(T)
1.5409
1.9703
2.3736
2.7531
3.1110
3.4489
3.7684
4.0710
4.3580
4.6304
4.8895
5.1360
5.3708
5.5947
5.8085
6.0127
6.2080
6.3949
6.5739
6.7455
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
I
о
I
о
V
S-.
V
о
о
о
и
ч
34

Класс точности
V-D
ПОЛОЖИТЕЛЬНЫЙ ИОН ДИОКСИДА УГЛЕРОДА СО, (г)
Таблица 251
-Р2(О)
; 267.093 кДж-моль"
Ф°(Г)
5°(Г)
Дж • К . моль
Я°(Г)-Я°@)
кДж ¦ моль
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
41.798
41.871
45.622
48.865
51.487
53.536
55.119
56.347
57.306
58.064
58.671
59.162
59.564
59.896
60.174
60.409
60.608
60.778
60.926
61.053
61.165
61.263
61.350
61.427
61.495
61.557
61.612
61.662
61.707
61.749
61.787
61.822
61.855
61.886
61.915
61.943
61.969
61.995
62.021
62.046
62.071
62.096
62.122
62.148
62.175
62.203
62.231
62.261
62.292
62.324
62.358
62.393
62.430
62.468
62.508
62.549
62.592
62.637
62.684
192.464
192.683
203.177
211.768
219.131
225.619
231.443
236.739
241.603
246.104
250.295
254.218
257.906
261.386
264.680
267.809
270.787
273.629
276.347
278.951
281.451
283.854
286.168
288.399
290.553
292.635
294.650
296.601
298.494
300.331
302.115
303.850
305.537
307.181
308.782
310.343
311.865
313.352
314.804
316.223
317.611
318.968
320.296
321.597
322.872
324.120
325.345
326.546
327.724
328.880
330.016
331.131
332.227
333.303
334.362
335.404
336.428
337.435.
338.427
227.902
228.161
240.730
251.270
260.420
268.517
275.774
282.340
288.328
293.827 .
298.906
303.622
308.022
312.143
316.018
319.673
323.132
326.413
329.535
332.511
335.353
338.075
340.684
343.190
345.600
347.922
350.162
352.325
354.416
356.440
358.401
360.303
362.149
363.943
365.686
367.383
369.036
370.645
372.216
373.747
375.243
376.704
378.131
379.528
380.894
382.231
383.541
384.825
386.083
387.317
388.527
389.716
390.882
392.028
393.154
394.261
395.349
396.419
397.472
10.566
10.643
15.021
19.751
24.773
30.029
35.465
41.041
46.726
52.495
58.333
64.226
70.163
76.136
82.140
88.170
94.221
100.290
106.376
112.475
118.586
124.707
130.838
136.977
143.123
149.276
155.434
161.598
167.766
173.939
180.116
186.296
192.480
198.667
204.857
211.050
217.246
223.444
229.645
. 235.848
242.054
248.263
254.473
260.687
266.903
273.122
279.343
285.568
291.796
298.027
304.261
310.498
316.739
322.984
329.233
335.486
341.743
348.004
354.270
35.2856
34.9935
23.2261
16.1719
11.4799
-8.1398
-5.6454
-3.7148
-2.1787
-.9293
.1055
.9754
1.7161
2.3535
2.9073
3.3924
3.8205
4.2005
4.5400
4.8448
5.1197
5.3687
5.5951
5.8017
5.9909
6.1646
6.3246
6.4724
6.6091
6.7360
6.8539
6.9637
7.0663
7.1621
7.2519
7.3360
7.4151
7.4895
7.5595
7.6256
7.6880
7.7470
7.8028
7.8557
7.9058
7.9534
7.9987
8.0417
8.0826
8.1216
8.1587
8.1942
8.2280
8.2603
8.2912
8.3208
8.3490
8.3761
8.4021
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
Ч о
о
о
V
V
о
о
+
о
357
и
!
гч
Г--
С
+
35

ПОЛОЖИТЕЛЬНЫЙ ИОН ДИОКСИДА УГЛЕРОДА COj (г)
Таблица 2S1
(окончание)
Ф°(Г)
S°(T)
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
Дж . К . моль
Н°(Т)-Н°@)
кДж . моль
62.781
62.886
62.997
63.114
63.236
63.364
63.497
63.634'
63.774
63.918
64:065
64.213
64.364
64.515
64.667
64.819
64.970
65.121
65.270
65.417
340.365
342.246
344.071
345.846
347.572
349.253
350.890
352.486
354.043
355.564
357.049
358.500
359.920
361.309
362.669
364.001
365.307
366.587
367.842
369.074
399.529
401.524
403.461
405.343
407.175
408.958
410.696
412.391
414.046
415.662'
417.242
418.788
420.300
421.782
423.233
424.656
426.052
427.421
428.766
430.086
366.817
379.384
391.972
404.583
417.217
429.877
442.563
455.276
468.017
480.786
493.585
506.412
519.270
532.158
545.076
558.025
571.004
584.013
597.052
610.120
8.4508
8.4956
8.5370
8.5752
8.6105
8.6433
8.6736
8.7018
8.7280
8.7524
8.7751
8.7963
8.8160
8.8344
8.8516
8.8676
8.8825
8.8965
8.9095
8.9217
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
о
V
V
о
о
о
о
¦е-
36

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
31.229
38.573
43.092
43.161
46.434
49.057
51.239
53.078
54.644
55.994
57.171.
58.206
59.122
59.938
60.666
61.317
61.902
62.429
62.907
63.341
63.740
64.106
64.446
64.763
65.059
65.338
65.599
65.846
66.079
66.298
66.505
66.698
66.880
67.049
67.206
67.351
67.485
67.607
67.718
67.818
67.907
67.985
68.054
68.113
68.162
68.203
68.235
68.260
68.276
68.286
68.289
68.285
68.276
68.261
68.242
68.217
68.188
68.156
68.119
68.080
68.037
ОКСИД ДИУГЛЕРОДА С2О
К°(Т) = р2 (С) ¦
Ф°(Т)
Дж ¦ К . моль
163.667
184.893
198.338
198.556
209.026
217.646
225.035
231.537
237.363
242.654
247.511
252.004
256.190
260.112
263.803
267.290
270.598
273.744
276.744
279.613
282.361
285.000
287.537
289.982
292.340
294.618
296.820
298.954
301.022
303.029
304.978
306,873
308.717
310.513
312.262
313.968
315.633
317.258
318.847
32Q.399
321.917
323.402
324.857
326.281
327.676
329.044
330.386
331.702
332.993
334.261
335.506
336.728
337.930
339.111
340.272
341.413
342.537
343.642
344.730
345.800
346.854
(г)
Таблица 25 2
р(О) -р~'(С2О) Af//°@)= 1382.I53 кДж ¦ моль
1
193.156
217.190
233.498
233.765
246.650
257.303
266.446
274.486
281.679
288.195
294.156
299.655
'304.760
309.525
313.994
318.202
322.178
325.947
329.529
332.942
336.202
339.320
342.310
345.182
347.945
350.607
353.174
355.655
358.054
360.376
362.627
364.811
366.932
.368.992
370.996
372.947
374.846
376.696
378.501
380.261
381.979
383.657
385.296
386.898
388.465
389.997
391.496
392.964
394.402
395.809
397.189
398.541
399.867
401.168
402.444
403.696
404.924
406.131
407.316
408.480
409.624
Н°(Г)-Н°@)
кДж . моль
2.949
6.459
10.483
10.563
15.049
19.828
24.846
30.065
35.453
40.986
46.646
52.416
58.283
64.237
70.268
76.367
82.529
88.746
95.013
101.326
107.680
I14.Q73
120.501
126.961
133.452
139.972
146.519
153.092
159.688
166.307
172.947
179.608
186.287
192.983
199.696
206.424
213.166
219.921
226.687
233.464
240.250
247.045
253.847
260.655
267.469
274.288
281.110
287.934
294.761
.301.589
308.418
315.247
322.075
328.902
335.727
342.550
349.371
356.188
363.001
369.812
376.617
Г
К
-712.9398 100
¦350.5870 200
-231.0603 298.15
-229.5571 300
¦168.9496 400
-132.5407 500
-108.2436 600
-90.8741 700
-77.8379 800
-67.6929 900
¦59.5730 1000
-52.9269 1100
-47.3869 1200
-42.6980 1300
-38.6782 1400 •
-35.1939 1500
•32.1449 1600
-29.4545 1700
-27.0630 1800
-24.9234 1900
•22.9977 2000
-21.2556 2100
-19.6720 2200
-18.2263 2300
-16.9012 2400
-15.6822 2500
-14.5572 2600
¦13.5157 2700
-12.5488 2800
-11.6486 2900
-10.8086 3000
-10.0230 3100
-9.2865 3200
-8.5948 3300
-7.9439 3400
-7.3303 3500
-6.7509 3600
-6.2029 3700
-5.6838 3800
-5.1914 3900
-4.7237 '4000
-4.2789 4100
-3.8553 4200
-3.4514 4300
-3.0660 4400
-2.6977 4500
-2.3454 4600
-2.0082 4700
-1.6851 4800
-1.3752 4900
-1.0777 5000
-.7918 5100
-.5170 5200
-.2526 5300
.0021 5400
.2475 5500
.4841 5600
.7124 5700
.9329 5800
1.1458 5900
1.3517 6000
%
— о
* * 1
X гч 2
У. Я
О ""* '
о ^ М
-* О гч "Г
"*¦ г-^ и ы
ГЧ L, Я
Я г-i С Ef
? " * о?
I s ? 2
"* u" <N
II
w Т< ^
о {J
^Z 0
+
т
« т
гч с?
я * я
§ Ъ s
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1 —1 к
s 7 v
•5 о, о
О ^ ""*
О\ ГЧ ^.
о <^ '
1Л СО О
3 I "
и +
0
37

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
оепл
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000-
С°(Т)
и
40.326
51.120
62.181
62.354
70.166
75.949
80.598
84.456
87.677
90.361
92.594
94.454
96.006
97.307
98.403
99.331
100.121
100.797
101.379
101.882
102.320
102.702
103.037
103-332
103.592
103.823
104.029
104.213
104 377
104.525
104.658
104.777
104.886
104.984
105.073
105.154
105.227
105.294
105.355
105.411
105.462
105.509
105.552
105.591
105.627
105.660
105 690
105.718
105.744
1С5.767
105.788
105.808
105.826
105.842
105.857
105.871
105.883
105.895
105.905
105.914
105.923
ДИОКСИД
*°(П=Р3(С).
Ф° (Г)
Дж . К . моль
184.659
212.167
229.760
230.049
244.218
256.242
266.799
276.262
284.871
292.786
300.123
306.968
313.390
319.438
325.158
330.584
335.746
340.669
345.374
349.881
354.205
358.361
362.362
366.218
369.941
373.538
377.018
380.389
386.828
389.908
392.901
395.813
398.649
401.410
404.103
406.729
409.292
411.795
414.241
416.633
418.972
421.260
423.501
425.696
427.847
429.955
432.022
434.050
436.040
437.994
439.913
441.798
443.650
445.470
447.260
449.020
450.752
452.456
454.133
455.784
Р2(О) -р~
S°(T)
1
223415
253.937
276.533
276.918
295.992
312.297
326.568
339.291
350.786
361.272
370.912
379.827
388.114
395.852
403.104
409.926
416.362
422.453
428.231
433.72-7
438.964
443.965
448.751
453.338
457.741
461.975
466.051
469.980
473.773
477.439
480.984
484.418
487.747
490.9У6
494.111
497.158
500.121
503.005
505.814
508.552
511.221
513.826
516.369
518.853
521.281
523.655
525.978
528.251
530.477
532.657
534.794
536.890
538.944
540.960
542.939
544.881
546.789
548.663
550.505
552.316
554.096
ТРИУГЛЕРОДА С3
'(с3о2) Дгя(
Н°(Т)-Н°@)
кДж ¦ моль
3.846
8.354
13.946
14.061
20.710
28.027
35.862
44.121
52.732
61.638
70.789
80.144
89.670
99.337
109.124
119.012
128.986
139.033
149.142
159.306
169.516
179.768
190.055
200.374
210.720
221.092
231.484
241.896
252.326
262.771
273.231
283.702
294.186
304.679
315.182
325.694
336.213
346.739
357.271
367.809
378.353
388.902
399.455
410.012
420.573
431.138
441.705
452.276
462.848
473.424
484.002
494.582
505.164
515.747
526.332
536.918
547.506
558.095
568 685
579.276
589.868
02 (г)
:>@)=2726
1404.6662
-689.8010
-453.9454
-450.9787
-331.3683
-259.5075
-211.5493
-177.2629
-151.5294
-131.5022
-115.4722
-102.3513
-91.4133
-82.1553
-74.2180
-67.3375
-61.3160
-56.0022
-51.2782
-47.0510
-43.2462
-39.8035
-36.6735
-33.8155
-31.1956
-28.7850
-26.5598
-24.4993
-22.5859
-20.8043
-19.14ГЗ
-17.5855
-16.1269
-14.7565
-13.4666
-12.2503
-11.1015
-10.0146
-8.9848
-8.0076
-7.0792
-6.1959
-5.3546
-4.5523
-3.7863
-3.0542
-2.3538
-1.6830
-1.0401
-.4233
.1690
.7382
1.2856
1.8125
2.3200
2.8091
3.2810
3.7364
4.1762
4.6012
5.0122
.835 кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
П _ /Г
1 а о
1
оо
со
О
чо
II
+
'х
12
¦о
+
г»
о
1
о
00
чо
00
409 +
II
о
е
1
\а
о
К
gj
1
II
о
г<
о
0
<
I
К
i
а
i
тн
ю
vd
+
ъ
ГО
ЧО
1
О
оо
^:
+
лица
о
и
о
о
ЧО
Г-'
1
II
я
«о
оо"
i_T
о»
о
ГО
о
а:
253
—
'л
§
_
•
о
<ч"
II
ч
0 ВЦ
to
6000К)
V
V
V
о
о
*о
1
• о
•
II
38

Класс точности
11-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300 .
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
29.252
29.179
29.175
29.175
29.225
29.398
29.743
30.244
30.860
31.547
32.272
33.012
33.748
34.468
35.162
35.825
36.451
37.037
37.582
38.087
38.551
38.976
39.366
39.721
40.046
40.342
40.613
40.861
41.089
41.298
41.491
41.669
41.833
41.984
42.123
42.250
42.366
42.470
42.562
42.642
42.7Л0
42.766
42.809
42.838
42.855
42.857
42.846
42.822
42.783
42.731
42.665 ¦
42.586
42.494
42.390
42.273
42.144
42.004
41.854
41.694
41.524
41.345
К°(Т)=р(С) -р(Н)
Ф°(Т)
Дж • К . моль
122.620
142.470
153.999
154.178
162.510
168.986
174.291
178.792
182.709
186.185
189.317
192.174
194.804
197.247
199.530
201.676
203.704
205.626
207.457
209.204
210.877
212.483
214.027
215.514
216.950
218.337
219.680
220.981
222.243
223.469
224.661
225.820
226.949
228.049
229.122
230.169
231.191
232.190
233.166
234.121
235.056
235.971
236.868
237.746
238.607
239.452
240.280
241.093
241.891
242.675
243.445
244.201
244.945
, 245.675
246.394
247.100
247.796
248.479
249.152
249.815
250.466
МЕТИН СН (г)
•р-'ССН)
S°(T)
151.033
171.279
182.928
183.108
191.506
198.043
203.431
208.052
212.129
215.803
219.164
222.275
225.179
227.909
230.489
232.937
235.270
237.497
239.630
241.676
243.641
245.532
247.355
249.112
250.810
252.451
254.038
255.576
257.066
258.512
259.915
261.279
262.604
263.893
265.149
266.372
267.564
268.726
269.860
270.966
272.047
273.102
274.133
275.141
276.126
277.089
278.031
278.952
279.853
280.735
281.598
282.442
283.268
284.076
284.868
285.642
286.400
287.143
287.869
288.580
289.277
Д
Г
кДж . моль
2.84)
5.762
8.625
8.679
11.598
14.528
17.484
20.482
23.537
26.656
29.847
33.111
36.449
39.860
43.342
46.892
50.506
54.181
57.912
61.696
65.528
69.404
73.322
77.276
81.265
85.285
89.333
93.406
97.504
101.624
105.763
109.921
114.097
118.287
122.493
126.712
130.943
135.184
139.436
143.696
147.964
152.238
156.517
160.799
165.084
169.370
173.655
177.939
182.219
186.495
190.765
195.027
199.281
203.526
207.759
211.980
216.187
220.380
224.558
228.719
232.862
Я°@) = 333.200
-170.9245
-83.3513
-54.4104
-54.0460
-39.3381
-30.4807
-24.5544
-20.3065
-17.1100
-14.6161
-12.6150
-10.9734
-9.6020
-8.4389
-7.4399
-6.5726
-5.8124
-5.1406
-4.5427
-4.0071
-3.5246
-3.0876
-2.6900
-2.3268
-1.9936
-1.6869
-1.4036
-1.1412
-.8975
-.6705
-.4586
-.2603
-.0743
.1004
.2648 ¦
.4199
.5664
.7050
.8364
.9610
.0794
.1920
.2993
.4016
.4993
.5926
.6819
.7674
.8494
.9280
2.0035
2.0761
2.1459
2.2131
2.2778
2.3402
2.4004
2.4586
2.5147
2.5690
2.6215
кДж • моль~
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та б
_
'л
я
о
Т-* О
Я ?
II "
¦§ о
iS
Я
О
о
+ -
-
Я о
2 ?
i _
§ «
о -1
о 2
о* 2
+ —<
5 +
^ "к
о -2
2 00
<"^ iS
(-ч| ГО
+ 1
•* X
« ¦*
СМ 40
m o\
и +
Ь_
о
о
Л И
_
1 л
о
о
¦о
55
н
Я
!?}
ОО
ГЧ
[-Г
X
о
ца 254
_
§
S
-'
i
¦
[—
U
о 5
Я
о
о
с>
V
V
8
л
о
II
39

г
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
с; (D
40.964
40.555
40.123
39.674
39.211
38.738
38.260
37.780
37.300
36.823
36.35!
35.886
35.429
34.982
34.545
34.119
33.705
33.303
32.913
32.535
31.645
30.831
30.087
29.410
28.794
28.234
27.725
27.261
26.838
26.453
26.100
25.778
25.482
25.211
24.961
24.731
24.519
24.323
24.141
23.972
МЕТИН СН (г)
Ф°(Т)
S°(T)
Дж . К~ . моль"
251.740 290.626
252.976 291.920
254.175 293.162
255.339 294.353
256.470 295.496
257.570 296.594
258.639 297.649
259.679 298.663
260.691 299.638
261.676 300.577
262.636 301.480
263.572 302.351
264.483 303.190
265.372 303.999
266.239 304.780
267.085 305.535
267.911 306.264
268.718 306.969
269.505 307.652
270.275 308.313
272.124 309.879
273.873 311.332
275.532 312.686
277.107 313.952
278.604 315.140
280.031 316.258
281.393 317.314
282.694 318.313
283.938 319.263
285.131 320.166
286.275 321.027
287.374 321.851
288.431 322.640
289.448 323.396
290.429 324.123
291.374 324.823
292.288 325.498
293.170 326.149
294.024 326.779
294.851 327.388
Я°(П-//°@)
кДж . моль
241.094
249.246
257.314
265.294
273.183
280.978
288.678
296.282
303.790
311.202
318.520
325.743
332.874
339.915
346.868
353.734
360.516
367.217
373.838
380.383
396.425
412.041
427.268
442.139
456.688
470.943
484.931
498.676
512.199
525.520
538.657
551.625
564.439
577.111
589.653
602.076
614.387
626.597
638.712
650.740
g
2.7215
2.8155
2.9039
2.9873
3.0662
3.1408
3.2117
3.2790
3.3431
3.4042
3.4626
3.5185
3.5720
3.6233
3.6725
3.7199
3.7655
3.8095
3.8519
3.8929
3.9895
4.0788
4.1617
4.2391
4.3117
4.3800
4.4444
4.5055
4.5635
4.6187
4.6715
4.7219
4.7703
4.8168
4.8615
4.9047
4.9463
4.9866
5.0256
5.0634
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
Таблица 254
(окончание)
+
OS -
оо |
гч -о
— О
— к
(N К С
°- о I
о ° <ч
н ~ V
?" "*" Ё-1
¦Ч- *! \ /
О С1 V
00 ГО
- ч §
00 Г- О
го _
+ 1
о я ^
° <N U,
VD r*i ^"
^ -н II
II + •—
0
¦в"
40

Класс точности
IV-D
Т
К
С°р(Т)
298.15 29.154
300 29.155
400 29.212
500 29.387
600 29.726
700 30.210
800 30.787
900 31.406
1000 32.033
1100 32.653
1200 33.266
1300 33.882
1400 34.517
1500 35.186
1600 35.903
1700 36.677
1800 37.514
1900 38.414
2000 39.372
2100 40.382
2200 41.432
2300 42.510
2400 43.604
2500 44.698
2600 45.780
2700 46.839
2800 47.861
2900 48.840
3000 49.765
3100 50.632
3200 51.436
3300 52.173
3400 52.842
3500 53.441
3600 53.972
3700 54.434
3800 54.830
3900 55.161
4000 55.429
4100 55.636
4200 55.785
4300 55.879
4400 55.920
4500 55.910
4600 55.854
4700 55.752
4800 55.609
4900 55.426
5000 55.206
5100 54.952
5200 54.667
53.00 54.353
5400 54.012
5500 53.647
5600 53.260
5700 52.854
5800 52.431
5900 51.992
6000 51.540
ПОЛОЖИТЕЛЬНЫЙ ИОН МЕТИНА СНГ (г)
А'°(Г)=р(С) -р(Н) -р~1(е) -р
Ф°(Г)
Дж • К . моль
j 42.622
142.801
151.135
157.612
162.917
167.417
171.333
174.807
177.936
180.788
183.412
185.846
188.119
190.253
192.267
194.176
195.992
197J28
199.391
200.989
202,530
204.018
205.459
206.858
208.218
209.543
210.834
212.096
213.330
214.537
215.720
216.881
218.019
219.137
220.235
221.314
222.375
223.419
224.446
225.456
226.451
227.431
228.395
229.345
230.280
231.202
232.110
233.004
233.886
234.754
235.610
236.453
237.284
238.103
238.910
239.706
240.490
241.262
242.024
S°(T)
1
171.561
171.741
180.134
186.669
192.054
196.672
200.742
204.404
207.746
210.828
213.695
216,382
218.916
221.320
223.614
225.813
227.933
229.985
231.980
233.925
235.828
237.693
239.525
241.328
243.102
244.850
246.572
248.268
249.940
251.586
253.206
254.800
256.368
257.909
259.422
260.907
262.364
263.793
265.192
266.564
267.907
269.220
270.506
271.762
272.991
274.191
275.363
276.508
277.625
278.716
279.781
280.819
281.832
282.820
283.783
284.722
285.637
286.530
287.400
"'(сн+) Д,л
Я°(Г>-Я°@)
кДж • моль
8.628
8.682
11.600
14.528
17.483
20.479
23.528
26.637
29.809
33.044
36.340
39.697
43.117
46.602
50.156
53.784
57.493
61.289
65.178
69.165
73.256
77.453
81.758
86.173
90.697
95.329
100.064
104.899
109.830
114.851
119.954
125.135
130.387
135.701
141.073
146.494
151.957
157.457
162.987
168.541
174.112
179.696
185.287
190.878
196.467
202.048
207.616
213.168
218.700
224.208
229.689
235.141
240.559
245.942
251.288
256.593
261.858
267.079
272.256
г°@) = -693.800 кДж • моль
126.1035
125.3516
95.0435
76.8365
64.6834
55.9915
49.4637
44.3793
40.3056
36.9672
34.1806
31.8185
29.7900
28.0286
26.4843
25.1187
23.9022
22.8112
21.8268
20.9340
20.1201
19.3749
18.6897
18.0574
17.4719
16.9279
16.4211
15.9474
15.5037
15.0871
14.6950
14.3252
13.9757
13.6448
13.3310
13.0329
12.7493
12.4791
12.2214
11.9751
11.7396
11.5140
11.2978
11.0903
10.8910
10.6994
10.5150
10.3373
10.1661
10.0010
9.8416
9.6876
9.5387
9.3947
9.2553
9.1203
8.9895
8.8627
8.7397
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
?300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 255
-1
'л ?
§ а -
2 3 '¦*
X о |
tf-r чо 2
ON S? 1
• „ S 2 *
2 Я » *
О \?, *-^ Й
ro' —' Ьй r-
-1 и '  ¦*
. ro
11 о °° Ю
5 u rs '
^ „ II
^ о
S '-
ro R
tJ- О
О
¦ i я
^ 4 §
о 5 2
§ » V
+ r"" *"¦¦
¦g i v
^ ГЧ1 О
. ¦-> О
SI „
CN CN *"*
C— QO
Ю 00 "
(N ГО
II +
0
41

ПОЛОЖИТЕЛЬНЫЙ ИОН МЕТИНА СН+ (г)
Таблица 255
(окончание)
Ф°(Г)
S°(T)
к
Дж . К .моль
Н°(Т)-Н°@)
кДж . моль"
\%К°{Т)
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
50.605
49.640
48.657
47.667
46.679
45.702
44.741
43.802
42.888
42.004
41.150
40.328
39.539
38.783
38.060
37.370
36.712
36.085
35.488
34.919
33.618
32.472
31.462
30.571
29.784
29.086
28.467
27.914
27.421
26.978
26.579
26.220
25.894
25.599
25.329
25.083
24.858
24.651
24.460
24.284
243.515
244.964
246.372
24.7.741
249.071
250.365
251.623
252.846
254.037
255.195
256.322
257.420
258.489
259.530
260.545
261.534
262.498
263.438
264.356
265.251
267.396
269.419
271.331
273.140
274.856
276.485
278.036
279.513
280.922
282.270
283.559
284.795
285.980
287.119
288.214
289.269
290.285
291.266
292.213
293.128
289.075
290.666
292.179
293.617
294.984
296.286
297.525
298.705
299.831
300.906
301.932
302.914
303.854
304.754
305.617
306.446
307.243
308.009
308.747
309.458
311.130
312.667
314.087
315.407
316.639
317.793
318.879
319.904
320.875
321.797
322.675
323.513
324.315
325.083
325.821
326.531
327.216
327.876
328.513
329.130
282.471
292.496
302.326
311.958
321.393
330.631
339.675
348.528
357.197
365.686
, 374.001
382.148
390.134
397.965
405.649
413.192
420.599
427.878
435.035
442.075
459.203
475.719
491.698
507.201
522.286
537.000
551.385
565.478
579.309
592.907
606.295
619.493
632.520
645.392
658.123
670.725
683.209
695.586
707.863
720.048
8.5043
8.2823
8.0724
7.8737
7.6852
7.5063
7.3362
7.1742
7.0198
6.8725
6.7317
6.5972
6.4684
6.3450
6.2267
6.1132
6.0042
5.8994
5.7986
5.7016
5.4743
5.2666
5.0760
4.9006
4.7386
4.5887
4.4495
4.3199
4.1991
4.0861
3.9803
3.8810
3.7876
3.6998
3.6169
3.5386
3.4645
3.3944
3.3280
3.2552
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
ON
ON
о
о
1
X
со
jC
(^
m
¦ч-
¦Ч-
On
fN
II
r^
On
+
r*
_H
00
1
X
00
¦4-
oo
CO
+
о
о
о
V
V
о
'о
и
42

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
33.258
33.302
33.763
33.777
34.800
36.090
37.511
39.028
40.605
42.190
43.733
45.194
46.549
47.787
48.905
49.909
50.806
51.606
52.318
52.953
53.519
54.025
54.479
54.887
55.255
55.587
55.888
56.162
56.411
56.639
56.847
57.038
57.214
57.375
57.524
57.661
57.788
57.905
58.013
58.113
S8.205
58.291
58.370
58.443
58.51
58.574
58.632
58.686
58.735
58.781
58.823
58.862
58.897
58.930
58.960
58.988
59.013
59.036
59.057
59.076
59.093
К°G") = р(С) -р2
ФО(Г)
Дж • К . моль
125.108
148.161
161.451
161.658
171.276
178.804
185.032
190.378
195.086
199.312
203.163
206.712
210.011
213.102
216.014
218.770
221.390
223.889
226.279
228.570
230.771
232.890
234.934
236.908
238.816
240.664
242.455
244.194
245.882
247.523
249.120
250.676
252.191
253.669
255.111
256.519
257.895
259.239
260.554
261.841
263.101
264.334
265.543
266.728
267.890
269.030
270.148
271.247
272.325
273.384
274.425
275.448
276.455
277.444
278.417
279.375
280.318
281.246
282,160
283.060
283.947
МЕТИЛЕН СН2 (г)
(Н) /Г'(СН2
S°(T)
158.366
181.423
194.786
194.995
204.842
212.743
219.447
225.342
230.656
235.531
240.056
244.294
248.285
252.061
255.644
259.053
262.303
265.407
268.378
271.224
273.955
276.578
279.102
281.533
283.877
286.139
288.325
290440
292.487
294.470
296.304
298.261
300.075
301.838
303.553
305.223
306.849
308.434
309.979
311.488
312.960
314.398
315.804
317.178
318.523
319.839
321.126
322.388
323.624
324.836
326.024
327.189
328.332
329.454
330.556
331.638
332.701
333.746
334.773
335.783
336.776
) Д,"°
Я°(Г)-Я°@)
кДж • моль
3.326
6.652
9.939
10.601
13.427
16.970
20.649
24.475
28.457
32.597
36.893
41.340
45.928
50.646
55.482
60.424
65.460
70.582
75.778
81.043
86.367
91.744
97.170
102.639
108.146
113.688
119.262
124.865
130.494
136.147
141.821
147.516
153.228
158.958
164.703
170.462
176.235
182.020
187.816
193.622
199.438
205.263
211.096
216.937
222.784
228.639
234.499
240.365
246.236
252.112
257.992
263.876
269.764
275.655
281.550
287.447
293.348
299.250
305.155
311.061
316.970
@)= 753.253
о
-386.7502
-188.8866
-123.4897
-122.6661
-89.4288
-69.4136
-56.0239
-46.4288
-39.2105
-33.5805
-29.0647
-25.3611
-22.2680
-19.6454
-17.3932
-15.4380
-13.7245
-12.2103
-10.8626
-9.6551
-8.5671
-7.5816
-6.6847
-5.8649
-5.1127
-4.4201
-3.7801
-3.1871
-2.6359
-2.1223
-1.6426
-1.1934
-.7720
-.3758
-.0027
.3494
.6822
.9972
1.2958
1.5794
1.8489
2.1055
2.3501
2.5834
2.8063
3.0194
3.2234
3.4189
3.6063
3.7862
3.9591
4.1253
4.2852
4.4391
4.5875
4.7306
4.8686
5.0020
5.1308
5.2553
5.3757
кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл
1
I'
о
2
д
о
00 о
Я го
2 -II
" о
X
У
О
ft;
+
СО ' j)
On н
2 §
о _,*
+ 'j^
***
Н &
«о ^
).003'
.421;
1 **"'
й С*
00 J^
Os -1
oo ¦ °о
+ X
о ¦*
OS u->
258.1
104/;
II +
0
в
и ц а
1
о
д
о
сч
о
Os
СП
II
00
Os
CN
fcT
X
В
0
256
—
'л
о
7
i
%
со
г4
II
оЭ
Я
§
О
\о
V
S-i
V
о
w>
**"
•о
II
><
43

Класс точности
V-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООПА
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
МЕТИЛ СН3 (г)
К°(Т) = р(С) ¦ р3 (Н) ¦ р"' (СН3) Д, А
р
Ф°G-)
5°(Г)
Дж . к . моль
33.360 122.278 155.547
35.401 145.436 179.168
38.453 159.086 193.859
38.513 159.301 194.097
41.857 169.491 205.633
45.122 177.713 215.328
48.204 184.704 223.829
51.128 190.849 231.481
53.911 196.372 238.492
56.538 201.417 244.995
58.983 206.083 251.080
61.229 210.436 256.808
63.268 214.528 262.225
65.104 218.396 267.363
66.748 222.070 272.249
68.215 225.572 276.905
69.522 228.920 281.350
70.686 232.130 285.600
71.723 235.215 289.671
72.648 238.184 293.574
73.475 241.048 297.322
74.215 243.814 300.925
74.879 246.489 304.393
75.476 249.080 307.735
76.014 251.592 310.959
76.500 254.029 314.072
76.941 256.396 317.081
77.341 258.698 319.992
77.705 260.938 322.812
78.037 263.119 325.544
78.341 265.244 328.195
78.619 267.316 330.768
78.874 269.338 333.268
79.109 271.313 335.699
79.326 273.241 338.064
79.526 275.126 340.367
79.711 276.970 342.610
79.883 278.774 344.796
80.042 280.539 346.928
80.190 282.268 349.009
80.328 283.962 351.041
80.457 285.623 353.027
80.577 287.251 354.967
80.690 288.848 356.864
80.795 290.415 358.720
80.894 291.953 360.537
80.987 293.463 362.316
81.074 294.947 364.059
81.156 296.404 365.767
81.233 297.837 367.441
81.306 299.246 369.083
81.375 300.631 370.694
81.441 301.994 372.274
81.502 303.334 373.826
81.561 304.654 375.350
81.616 305.953 376.847
81.669 307.232 378.318
81.719 308.492 379.764
81.766 309.733 381.186
81:811 310.956 382.584
81.854 312.161 383.959
Н°(Г)-Н°@)
кДж . моль
3.327
6.746
10.368
10.439
14.457
18.807
23.475
28.443
33.696
39.220
44.997
51.010
57.236
63.657
70.251
77.000
83.888
90.900
98.021
105.241
112.548
119.933
127.388
134.906
142.481
150.108
157.780
165.494
1 79 ОЛ 7
173.247
181.034
188.853
196.701
204.576
212.476
220.398
228.340
236.302
244.282
252.279
260.290
268.316
276.355
284.407
292.471
300.545
308.629
316.724
324.827
332.938
341.058
349.184
357.319
365.460
373.607
381.760
389.919
398.083
406.252
414.427
422.605
430.789
Таблица 257
Г°@) = 1209.600 кДж ¦ моль
-621.2554
-303.4608
-198.4142
-197.0915
-143.7078
-111.5681
-90.0748
-74.6786
-63.1014
-54.0756
-46.8394
-40.9074
-35.9554
-31.7585
-28.1560
-25.0297
-22.2909
-19.8718
-17.7192
-15.7915
-14.0551
-12.4829
-11.0525
-9.7457
-8.5470
-7.4435
-6.4243
-5.4802
А АП9Л
-4.О0а0
-3.7859
-3.0230
-2.3089
-1.6392
-1.0099
-.4173
.1417
.6698
1.1695
1.6431
2.0926
2.5197
2.9262
3.3134
3.6828
4.0355
4.3726
4.6951
5.0041
5.3002
5.5844
5.8572
6.1195
6.3717
6.6145
6.8484
7.0738
7.2913
7.5011
7.7038
7.8997
8.0891
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
к
т I
л • w
5 Н '¦"
¦Г X о
Л о •
as ^ 7
Г*- •*}¦ Ьч
5 "• V *
m 2 ,—, Ч
О ~ Zy _
«О || ио . СТ\
II g 00 С~
^ (" (N ""*
« II
«Г в
X m OR
Од оз
о (~)
51 о
+
^ 1
1 1
<ч 2
00
+ а
7 i
3 ч Я
40 <•> g
? * S
О оо ^
Я ? V
° t S-,
' + V
3 X О
й о •"
VO .—1 1
оо' • -1 о
I- ЧО *"*
О О ||
^ "*• а
"г- •*
II +
ь
0
в
44

Класс точности
V-C
Т
К
С°р(Т)
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400 1
5500
5600
5700
5800
5900
6000
33.275
33.507
35.695
35.765
40.631
46.627
52.742
58.603
64.084
69.137
73.746
77.919
81.682
85.067
88.112
90.856
93.335
95.585
97.634
99.510
101.235
02.831
04.314
05.699
07.000
08.227
09.390
10.497
11.556
12.572
13.551
14.497
15.416
16.309
17.180
18.033
18.869
19.691
20.500
21.298
22.087
22.868
23.643
24.411
25.175
25.935
26.691
27.445
28.198
28.949
29.699
30.449
31.200
31.950
32.702
33.455
34.209
34.966
35.724
36.485
37.248
К°(Т)=р(С) -р4
Ф°(Г)
Дж • К . моль
116.364
139.349
152.664
152.872
162.674
170.601
177.443
183.588
189.244
194.533
199.533
204.294
208.852
213.233
217.455
221.534
225.481
229.308
233.022
236.630
240.139
243.556
246.884
250.129
253.295
256.386
259.406
262.358
265.246
268.072
270.838
273.548
276.205
278.810
281.365
283.872
286.334
288.753
291.129
293.464
295.761
298.020
300.242
302.430
304.584
306.706
308.796
310.856
312.886
314.888
316.863
318.811
320.734
322.631
324.504
326.354
328.181
329.986
331.770
333.533
335.275
МЕТАН СН4 (г)
(Н)-р(СН4) ДгЯ°@)= 1641.951
S°(T)
149.473
172.568
186.259
186.480
197.389
207.091
216.135
224.710
232.897
240.741
248.268
255.496
262.440
269.114
275.531
281.706
287.650
293.377
298.899
304.229
309.378
314.356
319.175
323.842
328.369
332.762
337.029
341.179
345.216
349.149
352.982
356.721
360.370
363.936
367.421
370.830
374.167
377.435
380.638
383.778
386.859
389.883
392.853
395.772
398.640
401.462
404.238
406.971
409.662
412.31-3
414.926
417.502
420.042
422.548
425.022
427.464
429.875
432.257
434.611
436.938
439.238
Я°(Г)-Я°@)
кДж ¦ моль
3.311
6.644
10.016
10.082
13.886
18.245
23.215
28.785
34.923
41.587
48.735
56.322
64.305
72.646
81.307
90.258
99.470
108.918
118.580
128.439
138.477
148.681
159.039
169.541
180.176
190.938
201.820
212.814
223.917
235.124
246.431
257.833
269.329
280.916
292.590
304.351
316.196
328.124
340.134
352.224
364.393
376.641
388.967
401.370
413.849
426.404
439.036
451.743
464.525
477.382
490.315
503.322
516.404
529.562
542.794
556.102
569.485
582.944
596.479
610.089
623.776
-843.0658
-411.5926
-268.9232
-267.1261
-194.5904
-150.9015
-121.6746
-100.7341
-84.9861
-72.7085
-62.8662
-54.7989
-48.0659
-42.3612
-37.4660
-33.2196
-29.5011
-26.2180
-23.2983
-20.6849
-18.3322
-16.2033
-14.2677
-12.5005
-10.8806
-9.3906
-8.0155
-6.7426
-5.5611
-4.4615
-3.4356
-2.4765
-1.5778
-.7341
.0595
.8072
1.5128
2.1797
2.8110
3.4094
3.9773
4.5170
5.0305
5.5196
5.9859
6.4310
6.8562
7.2629
7.6521
8.0249
8.3823
8.7252
9.0544
9.3708
9.6749
9.9676
10.2493
10.5206
10.7822
11.0344
11.2778
кДж • моль"'
Т
К
100
200
' 298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
'л
rm О
it ^
о ?
5" чо Ч
О чо ,-^
. _" 1 v
ЧО ' нЬ
*-¦ и ¦ »л
11 S ^
? ^" (S
я *
В х
о у,
а; о
< ч
+
\J I
S548;
ноль
"¦* V
+ V,
"х *
о ?2
X сч
\r> о
<— ¦"":
О ¦ —1
"* 1
1 ц
\6 О
СЧ CN
С
о
в
ца258
т
Й
о
1
./->
г—
СП
11
оЭ
с
о
о
о
ЧО
V
f-
V
g
'о
^,
II
45

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700.
! 5800
1 5900
6000
29.748
35.336
39.649
39.710
42.372
44.349
46.075
47.728
49.389
51.075
52.768
54.428
56.015
57.492
58.836
60.033
61.079
61.976
62.734
63.363
63.876
64.289
64.613
64.862
65.048
65.181
65.270
65.322
65.345
65.344
65.324
65.289
65.242
65.186
65.124
65.057
64.986
64.914
64.840
64.767
64.693
64.620
64.549
64.478
64.410
64.343
64.279
64.216
64.156
64.097
64.041
63.987
63.934
63.884
63.835
63.789
63.744
63.701
63.660
63.620
63.582
К°(Т) = Р2 (С) • Р
Ф°(Г)
Дж • К . моль
143.359
163.979
176.697
176.902
186.708
194.725
201.556
207.536
212.875
217.715
222.155
226.269
230.109
233.718
• 237.127
240.362
243.443
246.386
249.205
251.911
. 254.512
257.018
259.436
261.770
264.028
266.214
268.332
270.386
272.379
274.316
276.198
278.030
279.813
281.549
283.242
284.892
286.503
288.075
289.611
291.111
292.579
294.014
295.418
296.792
298.139
299.457
300.750
302.018
303.261
304.480
305.677
306.852
308.007
309.140
310.254
311.350
312.426
313.485
314.527
315.551
316.560
ГИДРИД ДИУГЛЕРОДА
(Н).р"'(с2н) лг
S°(T)
172.549
194.765
209.755
210.000
221.814
231.489
239.729
246.956
253.437
259.352
264.820
269.928
274.733
279.275
283.586
287.687
291.596
295.326
298.891
302.300
305.564
308.691
311.689
314.567
317.332
319.990
322.548
325.013
¦•27.389
329.682
331.897
334.038
336.110
338.117
340.062
341.949
343.781
345.560
347.290
348.974
350.612
352.209
353.766
355.283
356.765
358.212
359.625
361.007
362.358
363.681
364.975
366.243
367.484
368.702
369.895
371.066
372.216
373.343
374.451
375.539
376.608
Я°(Г)-Я°@)
кДж • моль
2.919
6.157
9.856
9.929
14.042
18.382
22.904
27.594
32.450
37.473
42.665
48.025
53.548
59.225
65.042
70.987
77.044
83.198
89.435
95.740
102.103
108.512
114.958
121.432
127.928
134.440
140.963
147.493
154.027
160.561
167.095
173.625.
180.152
186.673
193.189
199.698
206.200
212.695
219.183
225.663
232.136
238.602
245.060
251.512
257.956
264.394
270.825
277.250
283.668
290.081
296.488
302.889
309.285
315.676
322.062
328.443
334.820
341.192
347.560
353.924
360.284
С2Н (г)
Н°@) = 1107.404 кДж • моль
-570.5958
-280.0283
-184.1242
-182.9176
-134.2598
-105.0П7
-85.4813
-71.5105
-61.0187
-52.8489
-46.3065
-40.9490
-36.4813
-32.6988
-29.4552
-26.6432
-24.1822
-22.0105
-20.0799
-18.3526
-16.7982
-15.3919
-14.1137
-12.9467
-11.8772
-10.8934
-9.9855
-9.1449
-8.3645
-7.6381
-6.9601
-6.3260
-5.7315
-5.1731
-4.6476
-4.1522
-3.6843
-3.2417
-2.8223
-2.4245
-2.0465
-1.6869
-1.3445
-1.0179
-.7061
-.4082
-.1231
.1498
.4115
.6625
.9035
1.1351
1.3579
1.5723
1.7788
1.9778
2.1698
2.3552
2.5341
2.7071
2.8743
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
34.00
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
Т s
S гч
о S
О ^
Оч О ^
я " ?
" о 5
ж' и'
о О
^Щ О
+
1 7
3 |
сч ^
<= V
+ а
1 ^
s Ъ
s я
о •
1 1
1 +
о-. ¦ —•
On о
"* !
+ X
О го
00 1О
СО »^1
II +
о
©
ца259
_,
i
о
-'
'ы
CJ
00
<^
"
0 05
о
о
-о
V
V
о
о
„.•"
'о
II
46

ГИДРИД ДИУГЛЕРОДА С2Н (г)
Таблица 259
(окончание)
Ф°(Г)
S°(T)
Дж . К . моль
кДж . моль
\gK°(T)
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
63.509
63.443
63.381
63.325
63.272
63.223
63.178
63.136
63.096
63.060
63.026
62.994
62.965
62.937
62.911
62.887
62.864
62.843
62.823
62.804
318.531
320.443
322.299
324.102
325.855
327.561
329.223
330.842
332.420
333.960
335.464
336.932
338.367
339.770
341.143
342.486
343.801
345.089
346.352
347.589
378.691
380.706
382.658
384.549
386.384
388.166
389.897
391.581
393.221
394.818
396.375
397.893
399.375
400.822
402.236
403.619
404.971
406.294
407.590
408.859
372.993
385.688
398.371
411.041
423.701
436.350
448.990
461.621
474.244
486.860
499.468
512.070
524.666
537.256
549.841
562.421
574.996
587.567
600.133
612.696
К
3.1928
3.4916
3.7724
4.0369
4.2865
4.5224
4.7457
4.9574
5.1584
5.3495
5.5315
5.7049
5.8704
6.0285
6.1797
6.3245
6.4632
6.5963
6.7240
6.8468
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
s
о
о
о
V
2 V
2 §
1-4 ^
47

Класс точности
II-D
Г
К
Ср°(Г)
100 29.345
200- 35.565
298.15 44.036
300 44.174
400 50.388
500 54.751
600 58.121
700 60.970
800 63.511
900 65.831
1000 67.960
1100 69.909
1200 71.686
1300 73.299
1400 74.758
1500 76.077
1600 77.269
1700 78.346
1800 79.321
1900 80.205
2000 81.009
2100 81.743
2200 82.414
2300 83.030
2400 83.598
2500 84.122
2600 84.609
2700 85.063
2800 85.487
2900 85.886
3000 86.262
3100 86.619
3200 86.959
3300 87.284
3400 87.596
3500 87.899
3600 88.193
3700 88.479
3800 88.761
3900 89.039
4000 89.314
4100 89.588
4200 89.861
4300 90.136
4400 90.412
4500 90.690
4600 90.972
4700 91.258
4800 91.549
4900 91.845
5000 92.147
5100 92.455
5200 92.769
5300 93.091
5400 93.419
5500 93.755
5600 94.098
5700 94.448
5800 94.806
5900 95.171
6000 95.544
К°(Т) = р2 (С) ¦
Ф°(Л
~ 1 "¦
Дж . К . моль
134.103
154.540
167.247
167.455
177.610
186.230
193.808
200.607
206.798
212.496
217.787
222.735
227.387
231.784
235.956
239.928
243^720
247.350
250.833
254.182
257.406
260.517
263.522
266.428
269.243
271.971
274.620
277.192
279.694
282.128
284.499
286.809
289.063
291.262
293.410
295.508
297.560
299.567
301.532
303.455
305.340
307.186
308.997
310.774
312.517
314.229
315.910
317.562
319.185
320.781
322.351
323.895
325.414
326.910
328.383
329.834
331.264
332.673
334.062
335.431
336.782
АЦЕТИЛЕН С2Н2 (г)
Таблица 260
Р2(Н) -р (С2Н2) Д Я°@)= 1626.479 кДж- моль
S°(T)
1
163.184
184.982
200.817
201.090
214.706
226.444
236.734
245.912
254.223
261.839
268.887
275.457
281.617
287.420
292.906
298.110
303.058
307.776
312.282
316.594
320.729
324.700
328.518
332.195
335.741
339.164
342.474
345.675
348.776
351.783
354.702
357.536
360.291
362.972
365.583
368.126
370.607
373.027
375.390
377.699
379.957
382.166
384.328
386.446
388.521
390.556
392.552
394.512
396.436
398.327
400.185
402.013
403.812
405.582
407.325
409.042
410.734
412.403
414.049
415.672
417.275
Я°(Г)-Я°@)
кДж. моль
2.908
6.089
10.009
10.091
14.838
20.107
25.756
31.714
37.940
44.409
51.100
57.995
65.076
72.326
79.730
87.273
94.942
102.723
110.607
118.584
126.646 "
134.784
142.992
151.265
159.597
167.983
176.420
184.904
193.431
202.000
210.608
219.252
227.931
236.643
245.387
254.162
262.967
271.800
280.662
289.552
298.470
307.415
316.388
325.387
334.415
343.470
352.553
361.664
370.805
379.975
389.174
398.404
407.665
416.958
426.284
435.642
445.035
454.462
463.924
473.423
482.959
-837.5302
-410.6342
-269.6682
-267.8942
-196.3478
-153.3325
-124.6054
-104.0545
-88.6205
-76.6019
-66.9770
-59.0948
-52.5210
-46.9547
-42.1807
-38.0412
-34.4176
-31.2191
-28.3752
-25.8300
-23.5389
-21.4656
-19.5807
-17.8595
-16.2817
-14.8301
-13.4901
-12.2495
-11.0975
-10.0250
-9.0241
-8.0878
-7.2102
-6.3858
-5.6100
-4.8786
-4.1880
-3.5348
-2.9161
-2.3291
-1.7717
-1.2415
-.7367
-.2554
.2039
.6426
1.0623
1.4639
1.8487
2.2177
2.5719
2.9121
3.2390
3.5536
3.8564
4.1481
4.4292
4.7004
4.9622
5.2149
5.4591
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
'л
— о
'л S
§ X Г
S Ч 'л
к о |
. Ч о *
" г- Т
? ' а *
3 " j ч
\© и «о *^
« ° ? м
;& С гч —1
^ ¦? о 5
У, ^ сп
о 0
^ о"
•0
+
2 §
VO 5
_; _'
i
S а Я
<N „ О
Я х Я
О |Jj V
| ГО Ьч
X + V
? ™н о
2 К °
So "
0
в
48

АЦЕТИЛЕН С2Н2 (г)
Таблица 260
(окончание)
К
С°р{Т)
Ф°(Г)
S°(T)
Дж . К .моль
Я°(Г)-Я°@)
кДж • моль
-1
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
96.310
97.105
97.925
98.768
99.631
100.511
101.404
102.307
103.215
104.126
105.034
105.936
106.828
107.708
108.570
109.412
110.232
111.027
111.794
112.532
339.429
342.008
344.523
346.977
349.374
351.717
354.009
356.252
358.449
360.603
362.715
364.787
366.822
368.820
370.784
372.716
374.615
376.485
378.325
380.137
420.420
423.491
426.491
429.427
432.302
435.121
437.887
440.604
443.273
445.897
448.480
451.022
453.525
455.991
458.421
460.817
463.178
465.508
467.805
470.071
502.144
521.485
540.988
560.656
580.496
600.510
620.701
641.072
661.624
682.358
703.274
724.372
745.648
767.102
788.730
810.528
832.493
854.620
876.902
899.335
К
5.9236
6.3587
6.7669
7.1506
7.5120
7.8528
8.1747
8.4792
8.7675
9.0410
9.3006
9.5474
9.7822
10.0058
10.2190
10.4224
10.6166
10.8023
10.9799
11.1499
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
ЬГ1
О
О
1
1
н
S
г-
5.59
00
+
*п
1
Г4»
о
о
1
1
1.Л
юоо
о
V
Е-,
V
000
**"
'о
g
О
•е-
49

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
33.261
34.432
39.499
39.624
46.881
53.953
60.172
65.553
70.234
74.331
77.926
81.080
83.845
86.268
88.392
90.256
91.894
93.337
94.610
95.738
96.739
97.630
98.425
99.138
99.778
100.355
100.876
101.348
101.777
102.167
102.523
102.849
103.148
103.422
103.675
103.908
104.124
104.323
104.509
104.681
104.841
104.990
105.129
105.260
105.382
105.496
105.604
105.704
105.799
105.889
• 105.973
106.053
106.128
106.199
106.267
106.331
106.391
106.449
106.504
106.556
106.605
ТРИГИДРИД ДИУГЛЕРОДА С2Н3 (г)
К°(Т) = рг (С) •
Ф°(Г)
Дж ¦ К . моль
161.660
184.735
198.240
198.453
208.661
217.138
224.590
231.347
237.586
243.414
248.903
254.103
259.051
263.775
268.299
272.640
276.815
280.837
284.717
288.465
292.091
295.601
299.004
302.305
305.511
308.627
311.658
314.608
317.481
320.281
323.012
325.677
328.280
330.822
333.307
335.737
338.115
340.442
342.721
344.953
347.142
349.287
351.391
353.455
355.481
357.471
359.425
361.344
363.231
365.085
366.909
368.702
370.467
372.203
373.912
375.595
377.253
378.885
380.494
382.079
383.641
Р3(Н) р '(С2Н3) Arh
S°(T)
l
194.918
218.155
232.729
232.974
245.352
256.586
266.987
276.676
285.742
294.256
302.278
309.857
317.033
323.841
330.314
336.478
342.356
347.971
353.343
358.489
363.426
368.168
372.728
377.119
381.352
385.437
389.384
393200
396.893
400.472
403.942
407.309
410.579
413.757
416.848
419.857
422.787
425.643
428.428
431.144
433.797
436.387
438.919
441.394
443.816
446.185
448.505
450.777
453.004
455.186
457.326
459.426
461.486
463.508
465.494
467.444
469.361
471.244
473.096
474.917
476.708
//°(Г)-Я°@)
кДж . моль
3.326
6.684
10.283
10.356
14.676
19.724
25.438
31.731
38.525
45.758
53.375
61.329
69.578
78.086
86.822
95.756
104.865
114.128
123.527
133.046
142.670
152.390
162.193
172.072
182.018
192.025
202.087
212.199
П/1П Л р* /*
222.356
232.553
242.788
253.057
263.357
273.685
284.040
294.420
304.821
315.244
325.685
336.145
. 346.621
357.113
367.619
378.139
388.671
399.215
409.770
420.335
430.910
441.495
452.088
462.689
473.298
483.915
494.538
505.168
515.804
526.446
537.094
547.747
558.405
г°@)= 1805.953
\%К°(Т)
-928.9922
-454.6126
-297.8259
-295.8515
-216.1843
-168.2323
-136.1761
-113.2238
-95.9735
-82.5320
-71.7615
-62.9368
-55.5738
-49.3368
-43.9858
-39.3443
-35.2800
-31.6915
-28.4999
-25.6428
-23.0703
-20.7418
-18.6242
-16.6902
-14.9168
-13.2848
-11.7781
-10.3826
-9.0865
-7.8796
-6.7530 .
-5.6989
-4.7105
-3.7818
-2.9077
-2.0834
-1.3048
-.5682
.1297
.7919
1.4211
2.0197
2.5898
3.1335
3.6525
4.1485
4.6230
5.0774
5.5128
5.9306
6.3317
6.7171
7.0877
7.4444
7.7879
8.1189
8.4382
8.7463
9.0438
9.3312
9.6092
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
i
_ о
1 «i
О К
2 Ч
? о
Ьс о
о
!л ¦* "
s s я.
' II 1/1
го f-i
X
с? яГ
0 ^
а; о"
+
7, 7
1 |
О 2
04 1
+ а
7 ^
г- __,
О 'п-
d "^
— *о
X гм
Г- vo
<П |
ЧО ¦*
Xt ON
0
е
а 261
7
к
i
о
г—
ОС
II
п
о к
Я
о
о
о
V
V
о
<л
1
о
к.
II
50

Класс точности
7"
К
100
200
298
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
V1-C
С°(Т)
33.270
35.358
15 42.882
43.058
53.043
62.477
70.672
77.731
83.867
89.233
93.937
98.060
101.669
104.828
107.593
110.017
112.144
114.015
115.665
117.125
118.420
119.572
120.600
121.520
122.346
123.090
123.762
124.370
4 Л Л S4 rt rt
124.922
125.425
125.883
126.303
126.687
127.040
127.366
127.665
127.943
128.199
128.437
128.658
128.864
129.056
129.235
129.403
129.559
129.706
129.844
129.974
130.096
130.210
130.319
130.421
130.518
130.609
130.695
130.777
130.855
130.929
130.999
131.066
131.130
К°(Т) = р2 (С) • р"
Ф°(Т)
Дж • К . моль
147.194
170.278
183.940
184.158
194.727
203.725
211.807
219.263
226.243
232.838
239.105
245.088
250.816
256.315
261.604
266.701
271.620
276.372
280.968
285.420
289.734
293.919
297.983
301.932
305.772
309.509
313.147
316.693
t\ л л 1 ^ л
320.150
323.522
326.813
330.028
333.169
336.240
339.243
342.182
345.059
347.876
350.636
353.341
355.994
358.596
361.149
363.654
366.114
368.531
370.905
373.237
375.531
377.786
380.004
382.186
384.333
386.447
388.528
390.578
392.596
394.585
396.545
398.476
400.381
ЭТИЛЕН С2Н4 (г)
(Н) -р'1(С2
180.420
203.833
219.206
219.472
233.218
246.089
258.223
269.660
280.450
290.644
300.295
309.446
318.136
326.402
334.274
341.781
348.951
355.807
362.372
368.665
374.707
380.513
386.100
391.481
396.671
401.680
406.521
411.204
415.737
420.130
424.389
428.524
432.540
436.444
440.241
443.938
447.538
451.047
454.469
457.808
461.068
464.253
467.365
470.408
473.384
476.298
479.150
481.944
484.682
487.365
489.997
492.579
495.112
497.599
500.041
502.440
504.797
507.114
509.392
511.632
513.835
у
Н4) АгН°@)= 2225.585
//°(Г>-//°@)
кДж . моль
3.323
6.711
10.515
10.594
15.396
21.182
27.850
35.278
43.365
52.026
61.190
70.794
80.785
91.113
101.737
112.620
123.731
135.040
146.526
158.167
169.946
181.846
193.856
205.963
218.157
230.429
242.772
255.179
267.644
280.162
292.728
305.337
317.987
330.674
343.394
356.146
368.926
381.734
394.566
407.421
420.297
433.193
446.108
459.040
471.988
484.951
497.929
510.920
523.923
536.939
549.965
563.002
576.049
589.105
602.171
615.244
628.326
641.416
654.512
667.615
680.725
-1143.7216
-558.9904
-365.6982
-363.2642
-265.0365
-205.9096
-166.3818
-138.0796
-116.8088
100.2349
-86.9551
-76.0751
-66.9978
-59.3093
¦52.7134
-46.9926
-41.9837
-37.5617
-33.6292
-30.1091
-26.9400
-24.0719
-21.4639
-19.0822
-16.8987
-14.8895
¦13.0347
-11.3171
-9.7221
-8.2370
-6.8508
¦5.5541
-4.3384
-3.1964
-2.1216
-1.1082
-.1511
.7542
1.6119
2.4255
3.1984
3.9336
4.6337
5.3013
5.9384
6.5473
7.1296
7.6871
8.2213
8.7338
9.2256
9.6982
10.1526
10.5898
11.0107
11.4164
11.8075
12.1849
12.5492
12.9011
13.2414
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
-1
7
щ ¦ ®
1 2
л
о X
X
s g
— й
я S Я
p*i ^ —.
II О »
§ :- <-1
¦" а?
0 С
а: <Г
<
+
1 Т
оо ?
— о
Г-4 л
Г-)
+ х
ё &
2 °
О
О г~>
X г*
G X
\?> ОО
 с*
-о 1
+ ч
<У\ СО
Г- TJ-
w> О
ГО Г-1
II +
о
в
да 262
с:
о
_ ¦
¦о
fN
rs
II
о ас
?
о
о
V
f*>
V
о
'о
II
51

Класс точности
VI-
7"
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Е
С°р(Т)
39.334
40.632
46.697
46.859
56.834
67.363
77.057
85.629
93.199
99.941
105.803
110.935
115.417
119.330
122.745
125.730
128.344
130.715
132.737
134.523
136.104
137.509
138.761
139.880
140.884
141.786
142.601
143.338
144.006
144.614
145.168
145.675
146.139
146.565
146.957
147.319
147.653
147.962
148.248
148.514
148.762
148.993
149.208
149.409
149.597
149.773
149.939
150.094
150.241
150.378
150.508
150.631
150.746
150.856
150.959
151.058
151.151
151.239
151.323
151.403
151.479
К°(Т) = р2 (С) /
Ф°(Г)
Дж . К~' . моль
170.176
196.174
211.732
211.979
223.837
233.856
242.755
250.949
258.613
265.857
272.779
279.407
285.769
291.893
297.798
303.501
309.016
314.362
319.540
324.561
329.433
334.164
338.763
343.236
347.591
351.831
355.964
359.994
363.926
367.764
371.512
375.175
378.756
382.258
385.685
389.040
392.325
395.544
398.698
401.791
404.824
407.800
410.721
413.589
416.405
419.172
421.890
424.562
427.189
429.773
432.315
434.816
437.278
439.702
442.088
444.439
446.755
449.037
451.286
453.503
455.689
(Ш Р 1
SV)
206.749
234.493
251.652
251.942
266.804
280.624
293.765
306.320
318.283
329.629
340.476
350.815
360.673
370.080
379.061
387.644
395.853
403.670
411.201
418.428
425.371
432.048
438.476
444.671
450.647
456.419
461.997
467.395
472.622
477.687
482.601
487.371
492.005
496.510
500.893
505.160
509.316
513.367
517.319
521.174
524.939
528.616
532.211
535.725
539.164
542529
545.824
549.051
552.214
555.314
558.355
561.338
564.265
567.139
569.960
572.732
575.456
578.133
580.765
583.354
585.900
ЭТИЛ С2Н5 (г)
(С2Н5) Д,А
П \л )—П \УЗ)
кДж .моль"
3.657
7.664
11.902
11.989
17.187
23.384
30.606
38.760
47.735
57.396
67.697
78.549
89.886
101.643
113.768
126.214
138.940
151.823
164.990
178.348
191.876
205.556
219.368
233.299
247.336
261.468
275.686
289.982
304.348
318.778
333.266
347.807
362.397
377.031
391.706
406.419
421.167
435.947
450.757
465.595
480.458
495.346
510.255
525.186
540.137
555.108
570.096
585.100
.600.119
615.152
630.200
645.260
660.331
675.414
690.508
705.612
720.726
735.849
750.981
766.120
781.268
г°@) = 2383.786
-1223.8432
-597.1938
-389.9654
-387.3552
-281.9965
-218.5486
-176.1109
-145.7125
-122.8568
-105.0412
-90.7630
-79.0620
-69.2973
-61.0248
-53.9266
-47.7691
-42.3770
-37.6164
-33.3820
-29.5915
-26.1783
-23.0890
-20.2796
-17.7137
-15.3611
-13.1962
-11.1975
-9.3465
-7.6275
-6.0269
-4.5328
-3.1351
-1.8246
-.5934
.5653
1.6579
2.6898
3.6660
4.5908
5.4681
6.3016
7.0944
7.8495
8.5694
9.2567
9.9133
10.5414
11.1428
11.7191
12.2719
12.8025
13.3123
13.8025
14.2741
14.7283
15.1659
15.5879
15.9951
16.3882
16.7680
17.1351
кДж ¦ моль
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л
-
-о
О
2
х
чо ,_
о' и
II О
.л
К
г*
О
0
+
1 Г"
5 1
+ ?й
11
° о
1 +
•5 3
ос чо
— —
^ 1
+ X
ЧО ^
ЧО OS
ОО [—
II +
Е-
о
©
И Ц
л
о
'se
о
о
о
—
II
—.
ОС
о-
«Л
X
с*
Э
а 263
i
*
о
о
и
о «
я
о
о
S
V
V
о
V
'о
—•
]|
52

Класс точности
VI- С
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
1 6000
Ср(Т)
35.714
42.306
52.486
52.708
65.437
77.932
89.184
99.127
107.932
115.708
122.554
128.569
133.823
138.407
142.407
145.900
148.956
151.635
153.991
156.139
157.988
159.629
161.090
162.395
163.564
164.670
165.623
166.484
167.265
167.975
168.621
169.212
169.752
170.248
170.704
171.124
171.511
171.934
172.269
172.580
172.869
173.139
173.390
173.625
173.844
174.049
174.242
174.423
174.593
174.753
174.904
175.046
175.180
175.307
175.428
175.541
175.649
175.751
175.848
175.941
176.029
К"(Т) = Р2 (С)
Ф°(П
Дж • К . моль
149.920
174.078
189.192
189.439
201.572
212.119
221.748
230.763
239.293
247.422
255.202
262.703
269.917
276.874
283.593
290.092
296.383
302.481
308.395
314.169
319.752
325.178
330.456
335.592
340.595
345.506
350.263
354.904
Л V Л Л f\ Л
359.432
363.855
368.176
372.399
376.528
380.568
384.523
388.394
392.186
395.933
399.578
403.152
406.658
410.098
413.476
416.791
420.049
423.248
426.393
429.485
432.525
435.515
438.457
441.352
444.202
447.008
449.771
452.493
455.175
457.817
460.422
462.990
465.521
ЭТАН
Р6(Н) -р-'сСгНб
S°(T)
1 -
Я
С2Н6 (г)
, v
°(Г)-Я°@)
кДж • моль
183.759
210.403
229.055
229.381
246.279
262.243
277.456
291.968
305.790
318.964
331.524
343.479
354.891
365.789
376.204
386.161
395.691
404.820
413.572
421.911
429.973
437.727
445.193
452.389
459.333
466.008
472.489
478.760
Л О Л О^ О
484. оо2
490.718
496.428
501.972
507.358
512.594
517.688
522.648
527.479
532.152
536.743
541.223
545.598
549.872
554.048
558.133
562.129
566.040
569.869
573.620
577.296
580.899
584.433
587.900
591.302
594.643
597.922
601.144
604.310
607.422
610.481
613.490
616.450
3.384
7.265
11.885
11.982
17.883
25.062
33.424
42.844
53.198
64.387
76.322
88.854
101.969
115.591
129.655
144.105
158.893
173.976
189.320
204.710
220.442
236.352
252.422
268.633
284.972
301.255
317.786
334.410
351.119
367.904
384.758
401.676
418.653
435.683
452.762
469.887
487.053
504.010
521.228
538.479
555.760
573.070
590.406
607.768
625.152
642.560
659.988
677.435
694.900
712.382
729.880
747.393
764.921
782.462
800.015
817.581
835.159
852.747
870.345
887.954
905.572
'°@)= 2786
о
1429.6606
696.8675
-454.5197
-451.4672
-328.2611
-254.0693
-204.4522
-168.9150
-142.1991
-121.3770
-104.6894
-91.0160
-79.6060
-69.9402
-61.6469
-54.4532
-48.1542
-42.5927
-37.6466
-33.2209
-29.2350
-25.6276
-22.3473
-19.3517
-16.6052
-14.0800
-11.7473
-9.5873
-7.5814
-5.7139
-3.9709
-2.3403
-.8117
.6242
1.9755
3.2495
4.4527
5.5891
6.6670
7.6895
8.6608
9.5846
10.4643
11.3029
12.1034
12.8682
13.5996
14.2998
14.9707
15.6142
16.2318
16.8251
17.3955
17.9443
18.4727
18.9818
19.4726
19.9461
20.4032
20.8448
21.2716
.955 кДж • моль1
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛоОи
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л
_
i
л
сз
о
S
щ
_
х
Tt '*'¦
<7\ '•&
О 1
О ||
г")
и =
^ -*
X
о
5;
+
Т 'л
1 °
X) ^
¦Ч-' 1
+ "^
? °.
О г-
о 2
' +
Н г*
Ю <N
» 3
ОО
+ Я
00 гг
"Ч ""!
г- о)
7 +1
о
©
и
о
Д
о
гг
X
II
?
—.
U
if
«
Э
Ц а 264
|
g
о
s
7
*
Г-
Г-
V)
и
to
2
о
о
чО
V
V
о
•J-,
•»¦"
'о
II
53

Класс точности
IV-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сг)
33.258
33.471
34.586
34.615
36.474
38.627
40.826
42.916
44.809
46.476
47.919
49.157
50.215
51.120
51.896
52.566
53.147
53.653
54.099
54.494
54.846
55.163
55.450
55.711
55.951
56.172
56.377
56.568
56.746
56.914
57.072
57.221
57.362
57.496
57.623
57.744
57.860
57.970
58.075
58.176
58.272
58.365
58.453
58.537
58.619
58.696
58.771
58.843
58.911
58.977
59.040
59.101
59.160
59.216
59.269
59.321
59.371
59.419
59.464
59.509
59.551
ФОРМИЛ НСО (г)
а:°(Г)=р(Н) -рас) -р{0) -р'1
Ф°(Г)
Дж ¦ К ¦ моль
154.347
177.403
190.725
190.932
200.635
208.297
214.699
220.246
225.175
229.631
233.713
237.489
241.008
244.308
247.418
250.360
253.154
255.814
258.354
260.785
263.117
265.356
267.512
269.590
271.596
273.534
275.410
277.228
278.990
280.700
282.362
283.979
285.551
287.083
288.576
290.032
291.454
292.841
294.197
295.523
296.819
298.088
299.330
300.547
301.740
302.909
304.056
305.181
306.285
307.369
308.434
309.480
310.509
311.520
312.514
313.492
314.455
315.402
316.334
317.253
318.157
S°{T)
1
187.605
210.688
224.229
224.443
234.644
243.012
250.249
256.702
262.558
267.935
272.908
277.535
281.858
285.914
289.732
293.336
296.747
299.985
303.064
306.000
308.805
311.488
314.061
316.532
318.908
321.197
323.404
325.535
327.596
329.590
331.522
333.396
335.215
336.982
338.700
340.372
342.001
343.588
345.135
346.645
348.119
349.559
350.966
352.343
353.690
355.008
356.299
357.563
358.803
360.018
361.210
362.380
363.528
364.656
365.763
366.851
367.921
368.972
370.006
371.023
372.023
(НСО) Д Н°@)= 1132.366 кДж-моль
кДж . моль
3.326
6.657
9.989
10.053
13.604
17.357
21.331
25.519
29.907
34.473
39.195
44.050
49.020
54.088
59.240
64.464
69.750
75.091
80.479
85.909
91.376
96.877
102.408
107.966
113.549
119.155
124.783
130.430
136.096
141.779
147.479
153.193
158.923
164.666
170.421
176.190
181.970
187.762
193.564
199.377
205.199
211.031
216.872
222.721
228.579
234.445
240.3 Г8
246.199
252.087
257.981
263.882
269.789
275.702
281.621
287.545
293.475
299.410
305.349
311.293
317.242
323.195
Т
К
-584.0750 100
-287.1374 200
-189.1088 298.15
-187.8750 300
-138.1152 400
-108.1888 500
-88.1952 600
-73.8866 700
-63.1367 800
-54.7626 900
-48.0541 1000
-42.5583 1100
-37.9732 1200
-34.0894 1300
-30.7571 1400
-27.8665 1500
-25.3351 1600
-23.0997 1700
-21.1112 1800
-19.3307 1900
-17.7272 2000
-16.2754 2100
-14.9548 2200
-13.7482 2300
-12.6415 2400
-11.6228 2500
-10.6819 2600
-9.8102 2700
-9.0003 2800
-8.2458 2900
-7.5413 3000
-6.8819 3100
-6.2633 3200
-5.6820 3300
-5.1345 3400
-4.6181 3500
-4.1301 3600
-3.6682 3700
-3.2304 3800
-2.8149 3900
-2.4199 4000
-2.0440 4100
-1.6858 4200
-1.3441 4300
-1.0177 4400
-.7057 4500
-.4071 4600
-.1211 4700
.1532 4800
.4164 4900
.6693 5000
.9123 5100
1.1462 5200
1.3713 5300
1.5882 5400
1.7973 5500
1.9991 5600
2.1939 5700
2.3821 5800
2.5640 5900
2.7400 6000
Таблица 265
-1
—
'л
- о
§ а о
• х 5
ЙЬ «S
п • з \л
оо 2 и *
О -' д 1=1
Я II ' <п О
11 ^ ^ "^
1 •—> 00 чо
* * • Я п ¦
о с "
У о ° §
Б 8 *
0 Щ
< X
+
7
н
о .
00 g
00 И
о\ 2
О 7
+ -
? ц §
^О ^j О
s g v
° Ч К
•S „+ §
О ^Э ^ * *
. ¦ 1
»-« ' ^J" О
^ ' к
? S «
II +
С
о
в
54

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
.1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛЛЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
И
33.440
37.497
43.609
43.723
49.527
54.415
58.409
61.672
64.368
66.625
68.535
70.163
71.560
72.764
73.807
74.713
75.503
76.195
76.803
77.340
77.815
78.237
78.613
78.949
79.251
79.522
79.767
79.989
ОЛ 1 QA
OV. 1 УН
80.374
80.541
80.694
80.834
80.962
81.081
81.190
81.291
81.384
81.471
81.552
81.626
81.696
81.762
81.823
81.880
81.933
81.983
82.031
82.075
82.117
82.156
82.193
82.229
82.262
82.293
82.323
82.352
82.379
82.404
82.428
82.452
КАРБОКСИЛ СООН (г)
а:°(п = р(С) -р2(О) -р(Н) -р"
Ф°(Г)
S°(T)
Дж . К . моль
178.094 211.372
201.345 235.517
215.354 251.622
215.579 251.892
226.376 265.284
235.342 276.879
243.138 287.165
250.100 296.422
256.424 304.839
262.238 312.555
267.631 319.676
272.666 326.286
277.394 332.452
281.854 338.229
286.077 343.661
290.088 348.784
293.909 353.632
297.559 358.231
301.052 362.603
304.402 366.771
307.621 370.750
310.718 374.557
313.704 378.205
316.584 381.707
319.369 385.074
322.062 388.315
324.671 391.438
327.200 394.453
O«)Q ЛКА 1QT "i(\(\
332.037 400.183
334.355 402.911
336.609 405.554
338.804 408.118
340.942 410.608
343.027 413.027
345.061 415.378
347.046 417.667
348.985 419.896
350.880 422.067
352.732 424.184
354.544 426.250
356.318 428.267
358.055 430.236
359.756 432.161
361.423 434.042
363.057 435.883
364.660 437.684
366.232 439.448
367.776 441.176
369.291 442.868
370.779 444.528
372.241 446.155
373.678 447.751
375.091 449.318
376.479 450.856
377.846 452.366
379.190 453.850
380.512 455.308
381.814 456.741
383.096 458.149
384.359 459.535
1 (СООН) ДгЯ°@) = 1630.632 кДж • моль"
Я°(П-Я°@)
кДж ¦ моль
3.328
6.834
10.813
10.894
15.563
20.768
26.416
32.426
38.732
45.285
52.045
58.982
66.070
73.288
80.618
88.045
95.556
103.142
110.793
118.500
126.258
134.061
141.904
149.783
157.693
165.632
173.596
181.584
1 ОО КПД
1ОЭ .О«7Ч
197.622
205.668
213.730
221.806
229.896
237.998
246.112
254.236
262.370
270.512
278.664
286.822
294.989
303.162
311.341
319.526
327.717
335.912
344.113
352.319
360.528
368.742
376.959
385.180
393.405
401.633
409.864
418.097
426.334
434.573
442.815
451.059
hK°(T)
Т
К
-839.6363 100
-411.7634 200"
-270.4592 298.15
-268.6808 300
-196.9523 400
-153.8217 500
-125.0154 600
-104.4075 700
-88.9309 • 800
-76.8795 900
-67.2286 1000
-59.3252 1100
-52.7339 1200
-47.1526 1300
-42.3656 1400 '
-38.2146 1500
-34.5805 1600
-31.3725 1700
-28.5197 1800
-25.9662 1900
-23.6672 2000
-21.5865 2100
-19.6943 2200
-17.9662 2300
-16.3816 2400
-14.9235 2500
-13.5771 2600
-12.3302 2700
111 721 2800
-10.0936 2900
-9.0868 3000
-8.1447 3100
-7.2613 3200
-6.4312 3300
-5.6498 3400
-4.9129 3500
-4.2168 3600
-3.5582 3700
-2.9340 3800
-2.3418 3900
-1.7790 4000
-1.2435 4100
-.7334 4200
-.2470 4300
.2175 4400
.6615 4500
1.0863 4600
1.4931 4700
1.8831 4800
2.2573 4900
2.6166 5000
2.9619 5100
3.2940 5200
3.6138 5300
3.9217 5400
4.2186 5500
4.5049 5600
4.7814 5700
5.0483 5800
5.3063 5900
5.5558 6000
Таблица 266
-
0
'л S
о *
*f 5 7
i л
? я 1
00 ™ 7
о и
? 7 о *
О || u-i ^
^ О 00 \О
* о" 5 "
gO о g
w О to
0 О
а; о
^ а;
+
7
—
+ 7
о * ?
г- с[ §
r~. m О
? <? ^
§ ? v
I О &"•
н 7 v
•S « ¦ о
00 ¦Ч" .а
О fi •_
ЧО w> О
+ i #
VO ОЧ "
*^" ' ч-S
00 —I
СП С"*
и +
о
е
55

Класс точности
V-C
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
33.258
33.499
35.387
35.443
39.240
43.736
48.181
52.280
55.941
59.156
61.951
64.368
66.453
68.251
69.803
71.146
72.313
73.329
74.217
74.997
75.683
76.291
76.830
77.311
77.741
78.128
78.476
78.792
79.079
79.341
79.582
79.804
80.011
80.205
80.387
80.560
80.725
80.884
81.039
81.191
81.340
81.488
81.636
81.785
81.935
82.086
82.240
82.397
82.557
82.721
82.888
83.059
83.234
83.413
83.595
83.782
83.972
84.165
84.362
84.562
84.765
К°(Т) = р2 (Н) •
Ф°(П
Дж . К ¦ моль
148.657
171.712
185.046
185.254
195.035
202.881
209.573
215.503
220.884
225.848
230.476
234.826
238.939
242.845
246.568
250.128
253.539
256.815
259.966
263.003
265.933
268.765
271.504
274.158
276.730
279.225
281.650
284.006
286.299
288.530
290.704
292.823
294.891
296.909
298.879
300.805
302.688
304.529
306.331
308.095
309.823
311.517
313.177
314.805
316.403
317.970
319.510
321.021
322.507
323.966
325.402
326.813
328.202
329.568
330.912
332.236
333.540
334.825
336.091
337.338
338.568
ФОРМАЛЬДЕГИД Н2СО
р(С) -р@) -р~
S°(T)
1
181.915
204.997
218.652
218.871
229.557
238.792
247.163
254.903
262.128
268.907
275.288
281.308
287.001
292.393
297.509
302.372
307.001
311.416
315.633
319.668
323.532
327.240
330.802
334.228
337.527
340.709
343.780
346.748
349.618
352.398
355.092
357.705
360.242
362.707
365.104
367.437
369.709
371.923
374.082
376.189
378.246
380.256
382.222
384.145
386.027
387.870
389.676
391.446
393.182
394.886
396.559
398.202
399.817
401.404
402.964
404.500
406.012
407.499
408.965
410.409
411.832
'(Н2СО) Д^Я0
Я°(Г)-Я°@)
кДж * моль
3.326
6.657
10.020
10.085
13.809
17.956
22.554
27.580
32.995
38.753
44.812
51.131
57.675
64.412
71.317
78.366
85.540
92.823
100.202
107.663
115.198
122.797
130.454
138.161
145.914
153.708
161.539
169.402
177.296
185.217
193.163
201.133
209.124
217.135
225.164
233.212
241.276
249.356
257.452
265.564
273.691
281.832
289.988
298.159
306.345
314.546
322.763
330.995
339.242
347.506
355.787
364.084
372.398
380.731
389.081
397.450
405.838
414.244
422.671
431.117
439.583
(г)
@)= 1494.897
о
-769.4272
-377.0549
-247.4243
-245.7925
-179.9438
-140.3166
-113.8282
-94.8635
-80.6108
-69.5053
-60.6068
-53.3160
-47.2329
-42.0800
-37.6589
-33.8239
-30.4656
-27.5004
-24.8629
-22.5016
-20.3754
-18.4507
-16.7001
-15.1011
-13.6348
-12.2852
-11.0390
-9.8848
.-8.8126
-7.8141
-6.8818
-6.0094
-5.1914
-4.4227
-3.6990
-3.0165
-2.3717
-1.7616.
-1.1835
-.6349
-.1136
.3824
.8549
1.3056
1.7358
2.1470
2.5405
2.9173
3.2785
3.6250
3.9577
4.2774
4.5850
4.8809
5.1660
5.4407
. 5.7057
5.9614
6.2084
6.4470
6.6777
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
"л
о
'л
§ л
s d
* о
гЧ ^
— о
*г ,.
<-. о "
JO — Q
°- II "">
О
О
? S
X гч
~ х
о ^з
"Т" л
**ч 0
^ S:
^\
_+
Ч 'л
О §
оо "*
"~ 1
1 *-.
X *
О^ ЕЙ
<Ч
•* "н
О т.
о IJ
; +
с "к
с« *%
о —
**? о
¦"" 1
m ос
О —
—¦ ОС
I-) ¦*'
m —
и +
0
е
а 267
i
-
о
i
—<
X
0 Ж
to
2
о
о
о
V
р-ч
V
о
Ч"
—
56

Класс точности
V-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
sfioo
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;{Т)
33.422
37.621
45.801
45.973
55.303
63.704
70.602
76.110
80.520
84.098
87.046
89.509
91.589
93.364
94.888
96.206
97.353
98.355
99.236
100.013
100.701
101.313
101.860
102.350
102.790
103.188
103.548
103.875
104.173
104.445
104.694
104.923
105.133
105.328
105.507
105.674
105.829
105.974
106.108
106.234
106.352
106.463
106.567
106.665
106.757
106.845
106.927
107.006
107.080
107.151
107.218
107.282
107.343
107.402
107.458
107.512
107.563
107.612
107.660
107.706
107.750
МУРАВЬИНАЯ КИСЛОТА
А'°(Г)=р(С) -Р2
Ф G~)
~ 1 **
Дж -К . миль
174.917
198.151
212.193
212.419
223.421
232.793
241.166
248.829
255.936
262.583
268.835
274.743
280.344
285.672
290.751
295.605
300.254
304.714
308.999
313.124
317.100
320.937
324.644
328.230
331.703
335.070
338.336
341.508
344.591
347.589
350.508
353.351
356.122
358.825
361.462
364.038
366.554
369.014
371.419
373.773
376.078
378.334
380.546
382.713
384.838
386.923
388.968
390.976
392.948
394.885
396.788
398.659
400.498
402.306
404.086
405.836
407.559
409.256
410.926
412.571
414.192
(Н)р2(О)-
S°(T)
1
208.183
232.296
248.765
249.048
263.558
276.827
289.074
300.387
310.848
320.546
329.564
337.979
345.859
353.262
360.238
366.831
373.078
379.010
384.657
390.044
395.192
400.120
404.846
409.385
413.750
417.955
422.009
425.923
429.706
433.367
436.912
440.348
443.683
446.921
450.068
453.129
456.108
459.010
461.838
464.596
467.287
469.914
472.481
474.990
477.443
479.843
482.192
484.493
486.746
488.955
491.120
493.244
495.328
497.373
499.381
501.354
503.291
505.196
507.068
508.908
510.719
р ' (НСООН)
Н°{Т)~Н
НСООН (г)
АгН°@)= 2008.323
'@)
кДж . миль
3.327
6.829
10.904
10.989
16.055
22.017
28.745
36.091
43.930
52.167
60.729
69.560
78.618
87.868
97.282
106.839
116.518
126.304
136.185
146.148
156.184
166.286
176.445
186.656
196.913
207.212
217.549
227.921
248.755
259.212
269.692
280.196
290.719
301.260
311.820
322.395
332.985
343.589
354.206
364.836
375.477
386.128
396.790
407.461
418.141
428.830
439.527
450.231
460.942
471.661
482.386
493.117
503.854
514.597
525.346
536.100
546.859
557.622
568.390
579.163
-1033.0390
-505.7709
-331.5624
-329.3696
-240.8989
-187.6830
-152.1329
-126.6971
-107.5935
-92.7177
-80.8052
-71.0505
-62.9157
-56.0282
-50.1216
-45.0002
-40.5172
-36.5604
-33.0422
-29.8936
-27.0593
-24.4945
-22.1626
-20.0331
-18.0809
-16.2848
-14.6267
-13.0914
"It .ОООО
-10.3382
-9.0992
-7.9401
-6.8535
-5.8327
-4.8720
-3.9661
-3.1106
-2.3013
-1.5345
-.8072
-.1161
.5412
1.1672
1.7641
2.3339
2.8784
3.3993
3.8979
4.3758
4.8343
5.2743
5.6972
6.1038
6.4951
6.8719
7.2350
7.5852
7.9231
8.2494
8.5647
8.8694
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б
i
л
о
2
Л
К
3
in

1-ГО
с-1 1!
О ^
II
О
о
•Чч
<
+
'с§ '-а
о п
и*) О
ГО S
C~i V
го —
+ 'ьй
1 ¦
ГО г—
о q
О го
X +
С <м
оо с^
ГЧ **О
го О
оо' оо
¦"" 1
+ н
О О\
о —-•
о —
—i О
¦* —i
и +
t»
о
в
л и
-
о
*•
с!
о
о
ОС
об
m
1
II
Я
—
ОС
ON
X
О
и
С-
о
<J
и а 268
-|
О
1
го
ГО
гч
II
п
Я
о
о
о
V
!¦>
V
о
ю
»"
1
о
11
,4
57

Класс точности
V-C
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
Р
33.422
37.577
45.306
45.463
53.846
61.275
67.469
72.591
76.871
80.492
83.586
86.249
88.552
90.553
92.296
93.820
95.157
96.334
97.373
98.293
99.111
99.841
100.494
101.080
101.608
102.084
102.516
102.909
103.266
103.593
103.892
104.167
104.420
104.653
104.869
105.069
105.254
105.427
105.588
105:739
105.880
106.012
106.136
106.253
106.363
106.467
106.565
106.658
106.746
106.830
106.909
106.985
107.057
107.126
107.192
107.255
107.315
107.373
107.428
107.482
107.533
щи -МУРАВЬИНАЯ
а-°(л=р(С)У
Ф°(Г)
Дж -К .моль
174.917
198.151
212.181
212.407
223.360
232.631
240.857
248.341
255.251
261.694
267.744
273.454
278.866
284.013
288.923
293.618
298.117
302.437
306.592
310.594
314.455
318.184
321.790
325.281
328.665
331.947
335.134
338.231
341.243
344.174
347.029
349.81 1
352.325
355.173
357.758
360.284
362.753
365.168
367.530
369.843
372.108
374.327
376.501
378.634
380.725
382.777
384.792
386.770
388.713
390.622
392.499
394.343
396.157
397.942
399.698
401.426
403.127
404.802
406.452
408.077
409.679
(Н)р2(О)-р-
S°(T)
1
208.183
232.291
248.678
248.959
263.198
276.034
287.771
298.569
308.549
317.819
326.463
334.558
342.164
349.332
356.108
362.529
368.628
374.433
379.969
385.259
390.322
395.176
399.836
404.316
408.629
412.787
416.799
42Q.676
424.425
428.054
431.572
434.983
438.294
441.510
444.638
447.681
450.643
453.529
456.343
459.088
461.767
464.383
466.939
469.438
471.882
474.273
476.614
478.907
481.154
483.356
485.515
487.632
489.711
491.750
493.754
495.721
497.654
499.554
501.422
503.259
505.066
КИСЛОТА
(НСООН) Д
Я°G>Я°(
цис-НСООН (г)
Я°@) = 2008.323
0)
кДж . моль
3.327
6.828
10.881
10.965
15.935
21.702
28.149
35.160
42.639
50.512
58.720
67.215
75.958
84.915
94.059
103.367
112.817
122.393
132.079
141.864
151.735
161.683
171.700
181.780
191.914
202.099
212.330
222.601
232.910
243.253
253.628
264.031
274.460
284.914
295.390
305.887
316.404
326.938
337.489
348.055
358.636
369.231
379.838
390.458
401.089
411.730
422.382
433.043
443.714
454.392
465.079
475.774
486.476
497.185
507.901
518.624
529.352
540.087
550.827
561.572
572.323
-1033.0390
-505.7709
-331.5619
-329.3688
¦240.8957
¦187.6746
-152.1168
-126.6716
-107.5577
-92.6712
-80.7482
-70.9831
-62.8385
-55.9416
-50.0261
-44.8963
-40.4056
-36.4415
-32.9164
-29.7614
-26.921 1
-24.3507
-22.0135
-19.8791
•17.9222
-16.1217
-14.4595
¦12.9202
¦11.4908
-10.1598
-8.9175
-7.7553
-6.6656
-5.6420
-4.6785
-3.7700
-2.9120
-2.1004
-1.3314
-.6019
.0912
.7505
1.3785
1.9772
2.5488
3.0949
3.6174
4.1176
4.5970
5.0569
5.4984
5.9226
6.3305
6.7231
7.1011
7.4654
7.8167
8.1558
8.4831
8.7994
9.1052
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
-1
i
ОЛЬ
d
о
гл
1
II
U4 О
Г^1 .
О -
-:§
1
0
ч
<
+
-
о
о
О1
+
1
о "
о
оо
о
о
1
с
ОС
г—
о
^!
VO
ОО
II
0
о
б л и
-
моль
гч
30
ОС
го
1
II
5
ГЧ
8
X
!
3
о
~" 3;
ца 269
_
с;
о
S
-
1
i|
го
го
ч
II
о оч
>->
А
О
¦
d
+
\
о
1л
р
Я,
о
о
о
V
V
§
кп
(
о
1!
58

Класс точности
V-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
.5400
5500
5600
5700
5800
5900
6000
С°р(Т)
33.488
38.058
45.781
45.937
54.214
61.570
67.716
72.804
77.056
80.654
83.729
86.375
88.665
90.655
92.388
93.905
95.235
96.406
97.439
98.356
99.170
99.897
100.547
101.130
101.656
102.131
102.562
102.953
* дп л ЛЛ
103.309
103.635
103.933
104.207
104.460
104.693
104.908
105.108
105.294
105.466
105.627
105.778
105.919
106.051
106.176
106.292
106.403
106.507
106.605
106.699
106.787
106.871
106.951
107.027
107.099
107.169
107.235
107.298
107.359
107.417
107.473
107.527
107.578
гракс-МУРАВЬИНАЯ КИСЛОТА
К°(Т) = Р(С) • р'
Ф°(Г)
Дж ¦ К • моль
174.645
197.923
212.038
212.266
223.302
232.643
240.925
248.455
255.403
261.879
267.956
273.690
279.123
284.289
289.215
293.925
298.437
302.769
306.935
310.946
314.816
318.554
322.168
325.666
329.056
332.345
335.537
338.640
341.656
344.592
347.452
350.239
352.956
355.608
358.197
360.727
363.199
365.617
367.982
370.298
372.565
374.787
376.964
379.099
381.193
383.248
385.264
387.244
389.190
391.101
392.979
394.826
396.642
398.428
400.185
401.915
403.618
405.294
406.946
408.572
410.175
•(Н).р2(О).р~]
S°(T)
1
207.920
232.215
248.802
249.086
263.446
276.356
288.143
298.976
308.983
318.272
326.933
335.040
342.657
349.834
356.617
363.044
369.148
374.957
380.498
385.791
390.857
395.714
400.376
404.859
409.174
413.334
417.348
421.226
\?^.ъП (
428.608
432.126
435.539
438.851
442.069
445.198
448.242
451.205
454.093
456.907
459.653
462.333
464.950
467.507
470.007
472.452
474.844
477.186
479.480
481.727
483.930
486.090
488.208
490.288
492.328
494.332
496.300
498.234
500.135
502.004
503.841
505.649
(НСООН)
Н°(Т)-Н
транс-НСООН (г)
Дг#°@)= 1991.994
"@)
кДж • моль"
3.328
6.859
10.961
11.046
16.058
21.857
28.331
35.365
42.864
50.754
58.977
67.486
76.240
85.209
94.363
103.679
113.137
122.721
132.414
142.205
152.082
162.036
172.058
182.143
192.283
202.472
212.707
222.983
243.644
254.023
264.430
274.864
285.321
295.801
306.302
316.823
327.361
337.916
348.486
359.071
369.669
380.281
390.904
401.539
412.184
422.840
'C3.506
444.180
454.863
465.554
476.253
486.959
497.672
508.393
519.119
529.852
540.591
551.336
562.086
572.841
-1024.4955
-501.4942
-328.6936
-326.5182
-238.7605
-185.9693
-150.6988
-125.4591
-106.4995
-91.7332
-79.9064
-70.2201
-62.1411
-55.2999
-49.4321
-44.3438
-39.8892
-35.9571
-32.4605
-29.3310
-26.5136
-23.9639
-21.6455
-19.5283
-17.5873
-15.8013
-14.1525
-12.6256
1 1 OA7Q
-1 l.zU/o
-9.8875
-8.6553
-7.5024 .
-6.4216
-5.4062
-4.4506
-3.5495
-2.6984
-1.8933
-1.1306
-.4069
.2806
.9345
1.5574
2.1513
2.7182
3.2599
3.7781
4.2743
4.7499
5.2060
5.6439
6.0647
6.4693
6.8586
7.2336
7.5949
7.9434
8.2797
8.6044
8.9181
9.2214
кДж ¦ моль"'
Т
К
100
200
298.15
300
400
500
600-
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
aoUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
О Ъ?
2 §
Ч —<
1
"> II
" я
II io
О 00
? ь" й
S В С
4 § ¦ g
11 ас О
* А в*
' я i
8, g
ь 8.
о ?,
5: о
"•-» ¦>
< X
+
1 Т
ё й
00 "р
«N 7
+ *
г- го
о ^_;
О tJ-
1 +
v <¦*
м ?
S й
* 2
+ ?
ОО 1У\
\q m
и +
К
0
©
а 270
1
о
.
Т.
II
og
to
i
s
V
t-,
V
о
•л
•""
'о
(С
II
59

Класс точности
V-E
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.258
33.748
37.151
37.249
43.618
50.697
57.347
63.272
68.471
73.008
76.955
80.381
83.354
85.934
88.175
90.125
91.828
93.318
94.626
95.779
96.798
97.702
98.506
99.225
99.869
100.447
100.969
101.440
101.868
102.257
102.611
102.935
103.231
103.503
103.754
103.985
104.198
104.395
104.578
104.748
104.905
105.053
105.190
105.318
105.438
105.551
105.656
105.755
105.849
105.937
106.019
106.098
106.171
106.241
106.307
106.370
106.430
106.486
106.540
106.591
106.639
ОКСИД-ТРИГИДРИД УГЛЕРОДА СН3О (г)
К°(Т)= р(С)р
Ф°(Г)
Дж ¦ К . моль
162.388
185.448
198.834
199.043
209.002
217.170
224.307
230.771
236.749
242.350
247.642
252.672
257.473
262.069
266.482
270.726
274.815
278.761
282.573
286.261
289.832
293.293
296.652
299.913
303.082
306.164
309.164
312.085
314.932
317.707
320.416
323.060
325.643
328.166
330.634
333.048
335.410
337.723
339.988
342.207
344.384
346.517
348.610
350.664
352.681
354.661
356.605
358.516
360.395
362.241
364.057
365.843
367.601
369.331
371.034
372.711
374.362
375.989
377.592
379.171
380.728
3(H)p(O)V
S°(T)
1
195.646
218.764
232.751
232.981
244.528
255.023
264.864
274.159
282.955
291.288
299.189
306.688
313.813
320.589
327.041
333.193
339.065
344.678
350.049
355.197
360.136
364.881
369.445
373.840
378.077
382.166
386.116
389.936
393.632
397.214
400.687
404.057
407.329
410.510
413.604
416.615
419.547
422.405
425.192
427.910
430.564
433.156
435.690
438.166
440.589
442.960
445.281
447.554
449.781
451.965
454.106
456.206
458.267
460.290
462.277
464.228
466.145
468.029
469.882
471.704
473.495
(СН3О) Д^Я°@)= 1585.089
Я°(Г)-Я°@)
кДж ¦ моль
3.326
6.663
10.113
10.181
14.211
18.927
24.335
30.372
36.965
44.044
51.547
59.418
67.608
76.075
84.783
93.701
102.800
112.059
121.458
130.979
140.609
150.335
160.146
170.033
179.988
190.005
200.076
210.197
х^пл л у* л
220.363
230.569
240.813
251.090
261.399
271.736
282.099
292.486
302.895
313.325
323.774
334.240
344.723
355.221
365.733
376.258
386.796
397.346
407.906
418.477
429.057
439.646
450.244
460.850
471.464
482.084
492.712
503.346
513.985
524.631
535.283
545.939
556.601
-813.5411
-396.8610
-259.0451
-257.3090
-187.2315
-145.0233
-116.7897
-96.5639
-81.3561
-69.5017
-60.0001
-52.2130
-45.7144
-40.2087
-35.4843
-31.3858
-27.7966
-24.6273
-21.8083
-19.2846
-17.0121
-14.9552
-13.0845
-11.3759
-9.8092
-8.3674
-7.0362
-5.8033
-4.6583
-3.5921
-2.5968
-1.6656
-.7925
.0278
.8000
1.5281
2.2157
2.8663
3.4827
4.0675
4.6231
5.1517
5.6551
6.1351
6.5933
7.0312
7.4501
7.8512
8.2356
8.6043
8.9583
9.2984
9.6255
9.9403
10.2434
10.5355
10.8172
11.0890
11.3515
11.6051
11.8502
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
i
"х i
О !?
' X
Ч о
Y О
00 "¦<
S ™ Я
m ^ —[
И ° о?
§ ""¦-. "¦'
О (н
X О
о ^
^ 0
+
>ч[ 1
00 й
" 1
\О ^*
(N |
+ ьс
СО ^
- тн
СО ОС
Я od
О v>
1 +
н м
ЧО гп
оо o-j
чо "-*
""> 1
+ X
00 ГЧ
*-н ОО
чо m
00 wi
II +
0
в
а 271
-
'л
о
.
1
О
об
—-1
II
о «
to
я
о
о
чо
V
V
о
•»¦"
'о
(Д
II
,х
60

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
33.832
39.543
46.439
46.571
53.513
59.707
65.015
69.585
73.578
77.103
80.226
82.994
85.444
87.611
89.527
91.221
92.720
94.047
95.226
96.274
97.209
98.044
98.793
99.466
100.072
100.619
101.115
101.564
101.974
102.347
102.688
103.001
103.288
103.552
103.795
104.020
104.228
104.421
104.600
104.766
104.921
105.066
105.201
105.327
105.446
105.557
105.661
105.759
105.852
105.939
106.021
106.098
106.171
106.241
106.306
106.369
106.428
106.484
106.537
106.588
106.636
ДИГИДРИД-ГИДРОКСИД УГЛЕРОДА СН2 ОН
К°(Т)=р(С)р3(Щ
Ф°(П
Дж • К • моль
164.447
187.914
202.312
202.544
213.780
223.209
231.489
238.954
245.797
252.142
268.076
263.660
268.943
273.961
278.744
283.316
287.696
291.902
295.949
299.847
303.610
307.245
310.762
314.169
317.472
320.678
323.792
326.819
329.765
332.632
335.427
338.151
340.809
343.404
345.939
348.416
350.837
353.206
355.525
357.796
360.020
362.199
364.336
366.432
368.488
370.506
372.487
374.433
376.344
378.223
380.070
381.885
383.672
385.429
387.158
388.860
390.536
392.186
393.812
395.414
396.992
¦р«».„-
S°(T)
197.783
222.780
239.844
240.132
254.492
267.115
278.483
288.856
298.414
307.288
315.577
323.356
330.684
337.611
344.175
350.411
356.347
362.009
367.418
372.595
377.558
382.321
386.900
391.307
395.553
399.649
403.605
407.430
411.131
414.716
418.192
421.564
424.839
428.021
431.116
434.128
437.062
439.920
442.707
445.426
448.081
450.673
453.207
455.684
458.107
460477
462.799
465.072
467.300
469.483
471.624
473.724
475.786
477.808
479.795
481.746
483.663
485.548
487.400
489.222
491.014
(г)
'(CHjOH) ArH°@)= 1619.167 кДж ¦ моль
Я°(Г)-Я°@)
кДж « моль
3.334
6.973.
11.190
11.276
16.285
21.953
28.196
34.932
42.094
49.632
57.501
65.665
74.089
82.744
91.603
100.642
109.841
119.181
128.645
138.222
147.897
157.660
167.503
177.416
187.393
197.428
207.516
217.650
ЛОТ ОЛ7
227.827
238.043
248.295
258.580
268.894
279.237
289.604
299.995
310.408
320.840
331.291
341.760
352.244
362.744
373.257
383.784
394.322
404.873
415.433
426.005
436.585
447.175
457.773
468.379
478.992
489.613
500.240
510.874
521.514
532.160
542.811
553.467
564.128
-831.4485
-405.8896
-265.1966
-263.4253
-191.9310
-148.8987
-120.1315
-99.5342
-84.0537
-71.9910
-62.3250
-54.4052
-47.7969
-42.1991
-37.3962
-33.2301
-29.5819
-26.3608
-23.4958
-20.9311
-18.6218
-16.5316
-14.6306
-12.8944
- 1~Ъ3025
-9.8375
-8.4849
-7.2322
-6.0688
-4.9855
-3.9742
-3.0281
-2.1409
-1.3075
-.5230
.2168
.9155
1.5765
2.2027
2.7969
3.3614
3.8984
4.4099
4.8976
5.3631
5.8080
6.2336
6.6411
7.0316
7.4063
7.7659
8.1115
8.4438
8.7636
9.0715
9.3683
9.6545
9 9307
10.1974
10.4550
10.7041
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
I а б л и ц
—
'л
о
2
OS
О
3 ^
И L-
§ X
О
X
о
о
<
+
™ -
§ 1
о
<ч' "
+ Ьй
7 ^
i "I
о •
( +
¦5 ?
— —
о —'
45 1
¦л t4-
¦? 2
m —
и +
о
л
о
о
о
о
о
1
It
я
об
С
X
X
у
0
а;
*) *7 1
а 111
-
о
7
к
о
00
•¦*
к
0 «
to
я
§
о
V
V
о
°
1
о
II
61

Класс точности
V-C
Т
К
С°СГ)
100 36.925
200 39.720
298.15 44.129
300 44.248
400 51.796
500 59.930
600 67.451
700 74.121
800 79.993
900 85.164
1000 89.717
1100 93.722
1200 97.243
1300 100.337
1400 103.057
1500 105.449
1600 107.557
1700 109.419
1800 111.066
1900 112.527
2000 113.826
2100
2200
2300
2400
2500
2600
2700
14.986
16.023
16.954
17.792
18.547
19.231
19.851
2800 1 zu.41 ч
2900 120.928
3000 121.398
3100 121.828
3200 122.222
3300 122.585
3400 122.920
3500 123.229
3600 123.514
3700 123.779
3800 124.025
3900 124.254
4000 124.467
4100 124.665
4200 124.851
4300 125.025
4400 125.187
4500 125.340
4600 125.483
4700 125.618
4800 125.745
4900 125.864
5000 125.977
5100 126.084
5200 126.185
5300 126.280
5400 126.370
5500 126.456
5600 126.537
5700 126.615
5800 126.688
5900 126.758
6000 126.825
К°(Т)= р(С)р(О)
Ф°(Г)
Дж . К~1 . моль
161.544
186.412
201.382
201.620
212.975
222.390
230.668
238.187
245.151
251.679
257.848
263.711
269.307
274.666
279.811
284.760
289.531
294.136
298.587
302/894
307.066
311.1J
315.040
318.855
322.564
326.173
329.687
333.110
336.447
339.703
342.880
345.983
349.015
351.979
354.878
357.714
360.491
363.210
365.874
368.486
371.046
373.558
376.022
378.441
380.816
383.148
385.440
387.692
389.906
392.083
394.225
396.332
398.405
400.446
402.456
404.435
406.384
408.304
410.197
412.063
413.902
МЕТАНОЛ СН3ОН (г)
•Р4(Н)-р~'<
196.606
223.207
239.759
240.032
253.754
266.191
277.795
288.704
298.993
308.720
317.934
326.677
334.986
342.894
350.432
357.625
364.499
371.077
377.379
383.424
389.229
394.812
400.185
405.364
410.359
415.183
419.846
424.358
Л ОО 7O7
428.727
432.961
437.069
441.057
444.931
448.698
452.362
455.930
459.405
462.793
466.098
469.322
472.471
475.547
478.553
481.493
484.369
487.184
489.940
492.640
495.287
497.880
500.424
502.920
505.370
507.774
510.135
512.455
514.734
516.975
519.177
521.343
523.475
СН3ОН) Д,ЯС
Н°(Т)-Н°@)
кДж . моль"
3.506
7.359
11.442
11.524
16.312
21.900
28.276
35.362
43.074
51.337
60.086
69.262
78.814
88.697
98.869
109.297
119.950
130.800
141.826
153.007
164.326
175.768
187.319
198.969
210.707
222.525
234.414
246.369
лр л О О А
258.382
270.450
282.566
294.728
306.931
319.172
331.447
343.755
356.092
368.457
380.847
393.261
405.697
418.154
430.630
443.124
455.635
468.161
480.702
493.257
505.826
518.406
530.998
543.601
556.215
568.838
581.471
594.112
606.762
619.419
632.084
644.757
657.436
@)= 2012.
0
-1032.8419
-503.9738
-329.0920
-326.8893
-237.9842
-184.4458
-148.6386
-122.9896
-103.7051
-88.6732
-76.6245
-66.7497
-58.5084
-51.5257
-45.5334
-40.3347
-35.7816
-31.7609
-28.1842
-24.9819
-22.0982
-19.4877
-17.1134
-14.9447
-12.9559
-11.1255
-9.4354
-7.8701
-6.4161
-5.0622
-3.7982
-2.6155
-1.5065
-.4645
.5163
1.4412
2.3149
3.1414
3.9246
4.6676
5.3736
6.0453
6.6850
7.2950
7.8774
8.4339
8.9663
9.4761
9.9647
10.4333
10.8833
11.3157
11.7315
12.1316
12.5169
12.8883
13.2464
13.5920
13.9257
14.2481
14.5598
129 кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб л
ГЧ
о
ГЧ 1
О ^
о °
II <-"
^ X
О
X
W
0
+
н к
\О О
00 _'
S 'а
+
i Ъ
со со
q ?
О +
1 сч
? о
^ ™н
ЧО 1
+ X
ГЧ ГЧ
г~ hi
f^l ГЧ
0
е
и ц
'л
§
О
о
о
о
ГЧ
1
II
я
«л
00
ГЧ
с
X
О
X
L
а 273
i
А
с;
о
i
Ы,
/—Г
СЧ
О
00
ГЧ
II
ч
о К
2
о
о
VO
V
S-
V
о
ю •
¦'"
'о
II
н
62

Класс точности
VI-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
р
ЭТАНОЛ
К. (Т) ~ р (С)' р \\j)' p \ti) • р
Ф (Т")
5°(Г)
Дж • К . моль
41.422
52.041
65.752
66.010
81.174
95.393
107.635
118.117
127.126
135.049
141.918
147.930
153.188
157.868
161.913
165.457
168.567
171.302
173.714
175.846
177.736
179.416
180.915
182.325
183.537
184.628
185.689
186.582
187.392
188.129
188.860
189.480
190.047
190.567
191.046
191.488
191.895
192.272
192.621
192.945
193.247
193.528
193.789
194.034
194.262
194.542
194.745
194.936
195.116
195.285
195.444
195.595
195.737
195.871
195.998
196.118
196.232
196.340
196.442
196.540
196.632
189.685 225,786
216.476 257.855
234.092 281.380
234.393 281.804
248.971 302.942
261.757 322.645
273.452 341.172
284.402 358.616
294.742 374.961
304.504 390.385
313.861 404.974
322.786 418.800
331.328 431.924
339.525 444.342
347.449 456.191
355.084 467.488
362.446 478.277
369.559 488.593
376.439 498.470
383.102 507.937
389.560 517.025
395.826 525.758
401.910 534.160
407.861 542.186
413.616 549.980
419.214 557.504
424.644 564.739
429.959 571.770
435.140 578.578
440. Н6 585.173
445.167 591.548
449.990 597.754
454.702 603.782
459.308 609.642
463.814 615.342
468.222 620.890
472.537 626.295
476.764 631.562
480.905 636.698
484.963 641.711
488.942 646.604
492.845 651.384
496.675 656.055
500.432 660.623
504.120 665.091
507.785 669.432
511.347 673.712
514.847 677.904
518.288 682.012
521.671 686.040
524.998 689.989
528.272 693.863
531.493 697.665
534.664 701.397
537.786 705.062
540.861 708.662
543.889 712.199
546.873 715.676
549.813 719.094
552.711 722.455
555.567 725.762
С2Н5ОН (г)
(С2Н5ОН) Д^А
н°т-н°т
кДж . моль
3.610
8.276
14.099
14.223
21.588
30.444
40.632
51.950
64.176
77.293
91.113
105.616
120.715
136.262
152.238
168.606
185.330
202.359
219.655
237.187
254.928
272.856
290.949
308.946
327.274
345.726
364.247
382.892
401.624
420.436
439.140
458.068
477.056
496.100
515.196
534.339
553.525
572.752
592.016
611.316
630.647
650.009
669.399
688.821
708.269
727.407
746.878
766.369
785.879
805.408
824.953
844.515
861.092
883.683
903.288
922.906
942.536
962.178
981.831
1001.494
1021.167
Таблица 274
'°@)= 3182.411 кДж-моль
-1632.3578
-795.6070
-518.9176
-515.4334
-374.8043
-290.1421
-233.5374
-193.0069
-162.5447
-138.8056
-119.7861
-104.2020
-91.1988
-80.1840
-70.7358
-62.5409
¦55.3651
-49.0298
-43.3957
-38.3524
-33.8118
-29.7024
-25.9656
-22.5550
-19.4266
-16.5479
-13.8893
-11.4286
-9.1435
-7.0159
-5.0321
-3.1746
-1.4332
.2026
1.7421
3.1936
4.5644
5.8610
7.0893
8.2545
9.3614
10.4142
11.4168
12.3728
13.2852
14.1548
14.9885
15.7867
16.5516
17.2851
17.9893
18.6657
19.3161
19.9419
20.5445
21.1250
21.6848
22.2249
22.7463
23.2500
23.7369
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1 2?
-С
i I
=! о 'л
¦* s 1
— '
гм
1 •""*
х 1 Ы х
ос и «¦> ,5
°. о ос jp
II —* t." "¦'
5 о. =* ""
X О "
CJ X о ос
и
0 W
¦5 0
< ч_,
<]
-
^ -с
X о
СГ; 7*
4 I
S ч 2
с 2 ^
6 ^ ¦ V
н " *"
in о 5^
О I— t~
rn ос ||
II +
о
©
63

Класс Точности
1-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
/'
30.980
29.771
30.056
30.070
31.091
32.251
33.278
34.115
34.779
35.305
35.726
36.068
36.348
36.583
36.782
36.953
37.102
37.234
37.353
37.460
37.557
37.647
37.731
37.810
37.884
37.954
38.022
38.086
38.149
38.210
38.269
38.327
38.384
38.441
38.497
38.552
38.607
38.663
38.718
38.774
38.830
38.887
38.944
39.002
39.061
39.121
39.181
39.243
39.305
39.368
39.432
39.497
39.562
39.629
39.695
39.762
39.830
39.898
39.965
40.033
40.101
ФТОРИД УГЛЕРОДА CF (г)
К°(Т)= p(C)p(l-)p"'(CF) Дг//°@) = 548.000
Ф°(Г)
¦" 1 "*
Дж • К . моль
148.854
170.328
182.517
182.705
191.450
198.266
203.891
208.704
212.924
216.690
220.096
223.208
226.075
228.734
231.214
233.539
235.728
237.795
239.754
241.617
243.392
245.087
246.709
248.266
249.760
251.199
252.585
253.923
255.216
256.466
257.677
258.851
259.990
261.097
262.173
263.219
264.238
265.232
266.200
267.144
268.067
268.968
269.848
270.710
271.553
272.378
273.186
273.978
274.754
275.515
276.262
276.995
277.715
278.422
279.116
279.799
280.470
281.131
281.780
282.419
283.048
1
Я°(Г)-Я°@)
кДж . моль**
«V,
180.044 3.119 -282.2787
201.016 6.138 -138.6801
212.922 9.065 -91.2879
213.108 9.121 -90.6915
221.890 12.176 -66.6375
228.953 15.343 -52.1728
234.926 18.621 -42.5109
240.121 21.993 -35.5978
244.722 25.439 -30.4052
248.850 28.944 -26.3610
252.592 32.496 -23.1216
256.014 36.086 -20.4682
259.164 39.708 -18.2547
262.083 43.354 -16.3799
264.802 47.023 -14.7713
267.346 50.710 -13.3760
269.736 54.413 -12.1540
271.989 58.130 -11.0749
274.120 61.859 -10.1149
276.143 65.600 -9.2553
278.067 69.351 -8.4810
279.902 73.111 -7.7799
281.655 76.880 -7.1421
283.334 80.657 -6.5593
284.944 84.442 -6.0247
286.492 88.234 -5.5324
287.982 92.033 -5.0777
289.419 95.838 -4.6564
290.805 99.650 -4.2649
292.144 103.468 -3.9001
293.441 107.292 -3.5594
294.697 111.122 -3.2404
295.914 114.957 -2.9412
297.096 118.798 -2.6599
298.245 122.645 -2.3949
299.361 126.498 -2.1449
300.448 130.356 -1.9085
301.507 134.219 -1.6848
302.539 138.088 -1.4727
303.545 141.963 -1.2714
304.528 145.843 -1.0799
305.487 149.729 -.8977
306.425 153.620 -.7240
307.342 157.518 -.5582
308.239 161.421 -.3999
309.118 165.330 -.2485
309.978 169.245 -.1035
310.821 173.166 .0353
311.648 177.093 .1685
312.459 181.027 .2964
313.255 184.967 .4192
314.037 188.913 .5373
314.804 192.866 .6509
315.559 196.826 .7604
316.300 200.792 .8658
317.029 204.765 .9675
317.746 208.745 1.0656
318.452 212.731 1.1604
319.146 216.724 1.2519
319.830 220.724 1.3404
320.503 224.731 1.4261
кДж • моль '
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 2
i
л
_, о
'л . -
О ^ ' Л
* о
* ГС 2
5 я 7
„. | 5 *
§ о " d
—¦ ¦* с ^
ГЧ ш? ^
m >i ? m
и " -. m.
5 О °° *G
*~ '"t '
У- "". 0 К
W ^ С^
о ^,
а; о
+
ч
^ _
¦* 'л
6 о
+ *
7 "'
Я * §
о "к V
о еп ^
1 <=> V
? + S
00 <Ч *О '
v~> О V
О <"*"> 1
*о Р °
+ 1 к
00 vn II
II +
0
в
64

Класс точности
V-E
Т
К"
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
56С0
5700
5800
5900
6000
с;сг)
ДИФТОРИД УГЛЕРОДА CF2 (г)
К°(Т)=р(С)-р2 (F)-/; (CF2)
¦ Ф°(Т)
S°(T)
Дж -К .моль
33.31 1
35.151
38.9.4R
39.014
43.079 ¦
46.446
49.002
50.897
52.305
53.364
54.174
54.803
55.300
55.698
56.022
56.289
56.513
56.704
56.87!
57.020
57.157
57.288
57.416
57.545
57.678
57.817
57.966
58.124
58.293
58.474
58.667
58.872
59.088
59.315
59.552
59.799
60.053
60.314
60.581
60.851
61.125
61.400
61:676
61.950
62.222
62.491
62.756
63.016
63.269
63.516
63.754
63.985
64.207
64.419
64.622
64.815
64.998
65.171
65.333
65.485
65.627
169.270 202.533
192.396 226.022
206.005 240.729
206.220 240.971
216.428 252.761
224.718 262.751
231.798 271.457
238.024 279.160
243.605 286.053
248.673 292.277
253.321 297.944
257.617 303.138
261.612 307.929
265.348 312.371
268.856 316.511
272.164 320.386
275.293 324.026
278.261 327.458
281.085 330.704
283.779 333.783
286.353 336.711
288.818 339.503
291.183 342.171
293.456 344.726
295.643 347.178
297.752 349.535
299.788 351.806
301.755 353.996
303.659 356.113
305.503 358.162
307.292 360.147
309.028 362.074
310.715 363.947
312.356 365.768
313.953 367.543
315.509 369.273
317.026 370.961
318.506 372.610
319.951 374.222
321.363 375.799
322.743 377.343
324.093 378.856
325.415 380.339
326.709 381.793
327.977 383.220
329.221 384.622
330.440 385.998
331.636 387.351
332.811 388.680
333.964 389.987
335.098 391.273
336.212 392.537
337.307 393.782
338.384 395.007
339.444 396.213
340.487 397.400
341.514 398.570
342.525 399.722
343.521 400.857
344.502 401.975
345.469 403.077
А #°@)= 1046.2:.
Я°(Г)-Я°(П)
кДж . моль
,8г,„
3.326 -537.6518
6.725 -263.2578
10.353 -172.6538
10.425 -171.5136
14.533 -125.5195
19.017 -97.8627
23.795 -79.3920
28.795 -66.1791
33.959 -56.2570
39.244 -48.5315
44.623 -42.3451
50.073 -37.2792
55.579 -33.0543
61.130 -29.4767
66.717 -26.4081
72.333 -23.7470
77.973 -21.4171
83.634 -19.3600
89.313 -17.5305
95.008 -15.8927
100.717 -14.4178
106.439 -13.0827
112.174 -11.8684
117.922 -10.7591
123.683 -9.7417
129.458 -8.8052
135.247 -7.9404
141.051 -7.1393
146.872 -6.3950
152.711 -5.7018
158.567 -5.0544
164.444 -4.4486
170.342 -3.8804
176.262 " -3.3464
182.206 -2.8437
188.173 -2.3695
194.166 -1.9214
200.184 -1.4975
206.229 -1.0957
212.300 -.7144
218.399 -.3521
224.525 -.0074
230.679 .3210
236.860 .6342
243.069 .9333
249.305 1.2191
255.567 1.4925
261.856 1.7543
268.170 2.0052
274.509 2.2459
280.873 2.4770
287.260 2.6991
293.669 2.9126
300.101 3.1181
306.553 3.3160
313.025 3.5067
319.5.6 3.6905
326.024 3.8679
332.549 4.0392
339.091 4.2047
345.646 4.3646
! кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 276
i
~ О
'л s
I Н ~
* => i
X ° -'
S | 'а
-V * 1
00 О ' *й
о ж " d
§ 7 ? ?
u-> ii «2 §
" о ж 21
? ь" *
in С
П. "З
^ гч 0 К
^ и. со
о ^
3; о
"-v >
< >-,
1
л
к
о
2.
i
+ =1
" "х
S jf; |
о 5 V
н f V
S v о
~ ,5 о
Р 00 "> "
о\ •- »"
+ - Т
NO 'Х. ^
>л О
m оо II
00 in
с> •—*
II +
--*
о
©
65

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
ТРИФТОРИД
К°(Т)=р{С)-р:
Ф°GУ
(F)-p(CF3)
5°(Г)
Дж .К~' -моль
33.864
40.968
49.581
49.736
57.309
63.202
67.580
70.798
73.182
74.972
76.340
77.403
78.242
78.914
79.460
79.908
80.28-1
80.593
80.858
81.084
81.279
81.447
81.594
81.722
81.836
81.936
82.026
82.105
82.177
82.242
82.300
82.353
82.401
82.445
82.485
82.522
82.555
82.586
82.615
82.642
82.666
82.689
82.710
82.730
82.749
82.766
82.782
82.797
82.81
82.825
82.837
82.849
82.860
82.871
82.881
82.890
82.899
82.908
82.916
82.923
82.931
187.748
211.272
225.905
226.144
237.756
247.597
256.269
264.075
271.196
277.752
283.831
289.499
294.809
299.805
304.521
308.987
313.227
317.264
321.116
324.799
328.328
331.713
334.968
338.100
341.120
344.035
346.851
349.576
352.214
354.772
357.254
359.665
362.007
364.286
366.504
368.665
370.771
372.826
374.831
376.789
378.702
380.572
382.401
384.191
385.943
387.659
389.340
390.989
392.605
394.191
395.747
397.274
398.774
400.247
401.695
403.118
404.517
405.893
407.246
408.578
409.889
221.086
246.424
264.406
264.713
280.097
293.549
305.479
316.151
325.768
334.496
342.469
349.797
356.569
362.860
368.728
374.226
379.396
384.272
388.887
393.265
397.429
401.398
405.191
408.821
412.301
415.644
418.859
421.957
424.944
427.829
430.618
433.317
435.933
438.469
440.931
443.322
445.648
447.910
450.113
452.259
454.352
456.393
458.386
460.332
462.235
464.094
465.914
467.694
469.438
471.145
472.819
474.459
476.068
477.646
479.196
480.716
482.210
483.677
485.120
486.537
487.931
УГЛЕРОДА CF3 (г)
АгН°ф) = 1412.202 кДж • моль"
Я°(Л-Я°@)
кДж ¦ моль
Т
К
3.334 -723.8586 100
7.031 -353.1362 200
11.479 -230.6678 298.15
11.57) -229.1262 . 300
16.936 -166.9445 400
22.976 -129.5529 500
29.526 -104.5826 600
36.453 -86.7230 700
43.658 -73.3143 800
51.070 -62.8764 900
58.638 -54.5203 1000
66.328 -47.6795 1100
74.112 -41.9761 1200
81.971 -37.1482 1300
89.890 -33.0084 1400
97.859 -29.4195 1500
105.869 -26.2784 1600
113.914 -23.5061 1700
121.987 -21.0412 1800
130.084 -18.8354 1900
138.202 -16.8499 2000
146.339 -15.0531 2100
154.491 -13.4194 2200
162.657 -11.9275 2300
170.835 ,10.5598 2400
179.024 -9.3013 2500
187.222 -8.1395 2600
195.428 -7.0636 2700
203.643 -6.0644 2800
211.864 -5.1340 2900
220.091 -4.2655 3000
228.323 -3.4529 3100
236.561 -2.6910 3200
244.803 -1.9752 3300
253.050 -1.3014 3400
261.300 -.6661 3500
269.554 -.0659 3600
277.811 .5019 3700
286.071 1.0399 3800
294.334 1.5503 3900
302.600 2.0353 4000
310.867 2.4968 4100
319.137 2.9363 4200
327.409 3.3554 4300
335.683 3.7556 4400
343.959 4.1380 4500
352.236 4.5039 4600
360.515 4.8542 4700
368.796 5.1900 4800
377.078 5.5122 4900
385.361 5.8215 5000
393.645 6.1187 5100
401.931 6.4046 5200
410.217 6.6797 5300
418.505 6.9447 5400
426.793 7.2001 5500
435.083 7.4464 5600
443.373 7.6841 5700
451.664 7.9136 5800
459.956 8.1355 5900
468.249 8.3499 6000
Таблица 277
-
л
1-
о
'л ^
к
1*7
& о i
п о
<N СЧ° |
О *> » 5
S '' 2 <=>
\О " JO оо
II О оо' ?
¦^ *¦¦ <ч „
- II
. и? 1 3
Г 1 m 0 Ц
В и? to
0 <_)
*»ч ''¦"'
¦** 0
_+
1
г- _
S '•*
S §
+ -.*
1 'juj
*¦* • * ?
• S "* ч°
°. -< v
* + v
s «v 8
^- О
? 00 'о
¦ * ]
+ 1 •
О\ X f-
оо 2 II
и +
0
©
66

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
34.745
47.365
61.050
61.284
72.399
80.713
86.783
91.212
94.479
96.929
98.799
100.250
101.396
102.314
103.058
103.670
104.179
104.606
104.967
105.275
105.541
105.771
105.971
106.147
106.301
106.439
106.561
106.670
106.767
106.855
106.935
107.007
107.073
107.133
107.187
107.238
107.284
107.326
107.365
107.401
107.435
107.466
107.495
107.522
107.547
107.571
107.593
107.614
107.633
107.651
107.669
107.685
107.700
107.714
107.728
107.741
107.753
107.765
107.776
107.786
107.796
ТЕТРАФТОРИД УГЛЕРОДА CF,
А'°(Г)= р(О-р
Ф°(Г)
Дж • К * моль
178.807
202.849
218.645
218.910
232.064
243.582
253.956
263.434
272.174
280.286
287.853
294.944
301.613
307.907
313.864
319.518
324.897
330.027
334.929
339.621
344.122
348.446
352.605
356.612
360.478
364.212
367.822
371.317
374.703
377.987
381.175
384.272
387.284
390.214
393.068
395.848
398.560
401.205
403.788
406.310
408.775
411.186
413.544
415.852
418.112
420.325
422.495
424.622
426.708
428.754
430.763
432.735
434.672
436.575
438.445
440.283
442.091
443.869
445.618
447.340
449.034
1 (Г)
'(F)-p '(CF4) ДгЯ°@)= 1947.515 кДж • моль'
S°(T)
1
Н°СП-Н°@)
кДж • моль
212.290 3.348
239.807 7.391
261.342 12.730
«261.721 12.843
280.945 19.552
298.041 27.229
313.322 35.620
327.050 44.531
339.454 53.824
350.730 63.400
361.044 73.190
370.531 83.146
379.305 93.230
387.459 103.417
395.069 113.687
402.201 124.025
408.908 134.418
• 415.237 144.858
421.227 155.337
426.911 165.849
432.318 176.391
437.473 186.956
442.398 197.544
447.112 208.150
451.633 218.772
455.976 229.409
460.152 240.060
464.176 250.721
468.057 261.393
471.806 272.074
475.429 282.764
478.937 293.461
482.335 304.165
485.631 314.875
488.830 325.592
491.938 336.313
494.960 347.039
497.900 357.769
500.762 368.504
503.552 379.242
506.271 389.984
508.925 400.729
511.515 411.477
514.044 422.228
516.516 432.982
518.934 443.737
521.298 454.496
523.612 465.256
525.878 476.018
528.098 486.783
530.273 497.549
532.405 508.316
534.496 519.086
536.548 529.856
538.561 540.629
540.538 551.402
542.480 562.177
544.387 572.952
546.261 583.730
548.104 594.508
549.916 605.287
Т
К
-997.0776 100
-485.8112 200
-316.9274 298.15
-314.8019 300
-229.0693 400
-177.5272 500
-143.1150 600
-118.5078 700
-100.0370 800
-85.6620 900
-74.1564 1000
-64.7394 1100
-56.8897 1200
-50.2464 1300
-44.5513 1400
-39.6150 1500
-35.2955 1600
-31.4841 1700
-28.0961 1800
-25.0648 1900
-22.3367 2000
-19.8685 2100
-17.6248 2200
-15.5764 2300
-13.6988 2400
-11.9716 2500
-10.3773 2600
-8.9013 2700
-7.5308 2800
-6.2550 2900
-5.0644 3000
-3.9506 3100
-2.9066 3200
-1.9259 3300
-1.0031 3400
-.1330 3500
.6887 3600
1.4658 3700
2.2020 3800
2.9004 3900
3.5638 4000
4.1947 4100
4.7956 4200
5.3685 4300
5.9153 4400
6.4377 4500
6.9374 4600
7.4158 4700
7.8742 4800
8.3139 4900
8.7359 5000
9.1414 5100
9.5312 5200
9.9063 5300
10.2675 5400
10.6155 5500
10.9511 5600
11.2749 5700
11.5875 5800
11.8894 5900
12.1813 6000
Таблица 278
-
1
'л
7 •*
1 Д т
k 5 1
ЕЗ О ~
О <"*"> 1
c*"j ГО S^
1.0046
-927.
4Дж
оо .. . *** гч
оо " «7 vo
" О 2 Я .
"i и- "
и. S
Г1 ^ О «
*•* U* ^
о ^^
5; о
<
+
-
х
г^ 7
•*"¦ к
 о
го J5
** 1
1 * %
От S
го X чо
Р. «=
о ? V
1 d f-
S ~ V
« "* о
8 -д 'о
i _х f^
го Р II
О 1—
¦*  И
ОО 00
¦Ч- <N
II +
0
в
67

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
30.856
37.991
42.599
42.669
45.926
48 466
50.552
52.291
53.741
54.947
55.949
56.782
57.478
58.060
58.551
58.968
59.322
59.627
59.889
60.117
60.316
60.490
60.643
60.779
60.899
61.007
61.103
61.190
61.268
61.338
61.402
61.461
61.514
61.562
61.607
61.648
61.686
61.721
61.753
61.783
61.810
61.836
61.860
61.883
61.904
61.923
61.941
61.959
61.975
61.990
62.004
62.018
62.031
62.043
62.054
62.065
62.075
62.085
62.094
62.103
62.111
ФТОРИД ДИУГЛЕРОДА C2F
A'°(r)=p2(C)-p(F)p(C2F)
Ф°(Г)
***i ~
Дж • К моль
161.765
182.849
196.151
196.366
206.721
215.245
222.551
228.976
234.731
239.955
244.746
249/174
253.295
257.151
260.775
264.196
267.434
270.509
273.438
276.234
278.908
281.472
283.933
286.300
288.580
290.779
292.903
294.957
296.945
298.871
300.739
302.553
304.316
306.029
307.697
309.322
310.905
312.449
313.955
315.426
316.863
318.268
319.641
320.985
322.301
323.589
324.852
326.089
327.302
328.492
329.660
330.806
331.931
333.037
334.123
335.191
336.240
337.273
338.288
339.288
340.271
S°(T)
1
191.170
214.827
230.921
231.185
243.929
254.460
263.487
271.414
278.494
284.895
290.738
296.111
301.082
305.707
310.028
314.082
317.899
321.505
324.921
328.165
331.254
334.201
337.019
339.717
342.307
344.795
347.190
349.497
351.724
353.875
355.956
357.970
359.923
361.816
363.655
365.441
367.178
368.869
370.515
372.120
373.684
375.211
376.701
378.157
379.580
380.971
382.333
383.665
384.969
386.248
387.500
388.728
389.932
391.114
392.274
393.413
394.531
395.630
396.710
397.771
398.815
(г)
1
Таблица 279
А Я°@)= 1149.645 кДж-моль
Я°(Г)-Я°@)
кДж ¦ моль
2.940
6.396
10.367
10.446
14.883
19.607
24.561
29.706
35.010
40.446
45.993
51.631
57.345
63.122
68.954
74.830
80.745
86.693
92.669
98.670
104.691
110.732
116.789
122.860
128.944
135.039
141.145
147.260
153.383
159.513
165.650
171.793
177.942
184.096
190.254
196.417
202.584
208.754
214.928
221.105
227.284
233.467
239.652
245.839
252.028
258.219
264.412
270.607
276.804
283.002
289.202
295.403
301.606
307.809
314.014
320.220
326.427
332.635
338.844
345.054
351.265
Т
К
-591.4059 100
-289.8197 200
-190.2965 298.15
-189.0445 300
-138.5590 400
-108.2192 500
-87.9657 600
-73 4828 700
-62.6102 800
-54.1470 900
-47.3718 1000
-41.8251 1100
-37.2005 1200
-33.2856 1300
-29.9286 1400
-27.0182 1500
-24.4708 1600
-22.2224 1700
-20.2234 1800
-18.4343 1900
-16.8238 2000
-15.3664 2100
-14.0411, 2200
-12.8309 2300
-11.7213 2400
-10.7002 2500
-9.7576 2600
-8.8845 2700
А А м А *Ш ^\Q f\f\
-8.0737 2800
-7.3186 2900
-6.6137 3000
-5.9541 3100
-5.3356 3200
-4.7545 3300
-4.2073 3400
-3.6914 3500
-3.2039 3600
-2.7427 3700
-2.3056 3800
-1.8908 3900
-1.4966 4000
-1.1215 4100
-.7642 4200
-.4234 4300
-.0980 4400
.2131 4500
.5108 4600
.7959 4700
1.0692 4800
1.3315 4900
1.5833 5000
1.8254 5100
2.0583 5200
2.2825 5300
2.4984 5400
2.7066 5500
2.9074 5600
3.1013 5700
3.2885 5800
3.4695 5900
3.6445 6000
i
'л s
§ L -
2 К 'л
si; ^
^ 2
ч ? •¦ s
« 00
§ 5 i<
S Я g ч
" °. ? 2
». и
и. С
U ^ °сЭ
0 w
^ 9
< <-.
i
1Д 1
^* г:
г* '
о „ §
g s v
* 7 v
Я „ §
Я о
ЧО ^* • •»
Z; г-' i
+ i •
So ? и
о с-а
V) ГО
и +
Р
0
68

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
37.669
52.447
60.113
60.223
65.158
68.768
71.608
73.918
75.823
77.401
78.713
79.807
80.724
81.495
82.147
82.702
83.176
83.585
83.938
84.244
84.513
84.748
84.956
85.140
85.304
85.450
85.581
85.699
85.805
85.901
85.989
86.068
86.141
86.208
86.269
86.325
86.377
86.424
86.468
86.509
86.547
86.583
86.616
86.647
86.675
86.702
86.728
86.751
86.773
86.794
86.814
86.833
86.850
86.867
86.883
86.897
86.912
86.925
86.938
86.950
86.961
ДИФТОРАЦЕТИЛЕН C2F2
Ф°(Г)
Дж . к . моль
164.532
188.405
204.960
205.236
218.717
230.085
239.965
248.732
256.631
263.829
270.449
276.582
282.298
287.652
292.690
297.447
301.954
306.237
310.318
314.215
317.943
321.518
324.951
328.254
331.436
334.505
337.470
340.337
343.113
345.803
348.412
350.946
353.408
355.802
358.133
360.403
362.615
364.772
366.877
368.933
370.942
372.905
374.825
376.703
378.542
380.343
382.108
383.838
385.534
387.198
388.831
390.433
392.007
393.553
395.072
396.565
398.033
399.476
400.896
402.294
403.669
(F)-p(C2F2) A,
5°(Г)
195.752
226.947
249.454
249.827
267.871
282.816
295.614
306.832
316.831
325.855
334.080
341.635
348.620
355.112
361.176
366.864
372.216
377.272
382.059
386.606
390.934
395.063
399.011
402.791
406.418
409.904
413.258
. 416.490
419.608
422.621
425.535
428.356
431.089
433.741
436.316
438.817
441.250
443.617
445.922
448.169
450.360
452.497
454.584
456.622
458.615
460.563
462.469
464.334
466.161
467.950
469.704
471.424
473.110
474.764
476.388
477.982
479.548
481.087
482.599
484.085
485.546
Я°(Л-Я°@)
кДж ¦ моль
3.122
7.708
13.266
13.377
19.661
26.366
33.390
40.670
48.160
55.823
63.631
71.559
79.587
87.699
95.882
104.125
112.419
120.758
129.134
137.544
145.982
154.445
162.931
171.436
179.958
188.496
197.047
205.612
214.187
222.772
231.367
239.970
248.580
257.198
265.821
274.451
283.086
291.726
300.371
309.020
317.673
326.329
334.989
343.652
352.319
360.988
369.659
378.333
387.009
395.687
404.368
413.050
421.735
430.420
439.108
447.797
456.487
465.179
473.872
482.567
491.262
(Г) .
Я°@)= 1723
о
-885.5878
-433.4005
-284.2213
-282.3451
-206.6955
-161.2487
-130.9205
-109.2402
-92.9698
-80.3085
-70.1755
-61.8823
-54.9696
-49.1193
-44.1041
-39.7572
-35.9535
-32.5972
-29.6138
-26.9444
-24.5421
-22.3687
-20.3929
-18.5891
-16.9357
-15.4146
-14.0107
-12.7108
-11.5039
-10.3803
-9.3317
-8.3507
-7.4312
-6.5674
-5.7544
-4.9880
-4.2641
-3.5794
-2.9308
-2.3154
-1.7308
-1.1748
-.6452
-.1402
.3418
.8024
1.2429
1.6648
2.0690
2.4568
2.8291
3.1867
3.5307
3.8617
4.1804
4.4875
4.7837
5.0695
5.3455
5.6121
5.8699
.920 кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
1
л
с
— о
'-» 2
о х
2 Ч
' к
Ч ?>
о *=*¦
о ¦*
О "*
t~ '
» 2 "
о ! Q
^о ^ ' —;
!1 О оо
о ^
а; о
_+
g; 7
чо а
оо 5
г- 2
J" 7.
н
2 *
О m
о ¦*
х +
•5 г.
5! «
V -о
+ 1
О X
сь со
V5 О
oi Я
¦Ч- rf
II +
ь
0
ца 280
i
л
о
2
i
00
OJ
11
0 DEJ
Я
о
о
V
ь^ ¦
V
о
*¦""
'о
II
69

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сл ¦
ТРИФТОРВД ДИУГЛЕРОДА С2
A:°(n=p2(C)-p3(F).p(C2l-3) ДГА
Ф°(Г)
SV)
Дж • К .моль
39.338
54.801
66.176
66.359
74.994
81.678
86.838
90.804
93.860
96.233
98.094
99.572
100.759
101.723
102.514
103.171
103.721
104.186
104.581
104.921
105.214
105.469
105.692
105.888
106.061
106.215
106.352
106.474
106.584
106.684
106.774
106.855
106.930
106.997
107.059
107.116
107.169
107.217
107.261
107.303
107.341
107.376
107.410
107.440
107.469
107.496
107.521
107.545
107.567
107.588
107.607
107.626
107.643
107.660
107.675
107.690
107.704
107.717
107.730
107.742
107.753
206.569 241.269
232.423 273.404
250.024 297.527
250.318 297.937
264.833 318.264
277.308 335.748
288.354 351.116
298.317 364.813
307.412 377.147
315.792 388.345
323.567 398.584
330.821 . 408.006
337.620 416.722
344.021 424.826
350.066 432.395
355.793 439.491
361.235 446.167
366.418 452.469
371.366 458.436
376.099 464.100
380.635 469.489
384.989 474.629
389.176 479.541
393.208 484.243
397.096 488.754
400.850 493.086
404.478 497.255
407.989 501.271
Л 9 1 *Х rt rt F Л F t Л С
411.390 505.145
414.688 508.887
417.888 512.505
420.997 516.008
424.020 519.402
426.960 522.693
429.823 525.888
432.612 528.992
435.332 532.011
437.984 534.948
440.574 537.808
443.103 540.594
445.574 543.312
447.991 545.962
450.354 548.550
452.667 551.078
454.932 553.548
457.151 555.964
459.324 558.327
461.456 560.639
463.546 562.904
465.596 565.122
467.608 567.296
469.584 569.427
471.524 571.517
473.430 573.567
475.303 575.580
477.144 577.556
478.955 579.496
480.736 581.403
482.488 583.276
484.211 585.118
485.908 586.929
Я°G-)-Я°@)
кДж ¦ моль
3.470"
8.196
14.163
14.286
21.372
29.220
37.657
46.548
55.788
65.297
75.017
84.903
94.922
105.047
115.261
125.546
135.891
146.287
156.726
167.202
177.708
188.243
198.801
209.380
219.978
230.592
241.220
251.862
262.515
273.178
283.851
294.533
305.222
315.918
326.621
337.330
348.044
358.764
369.488
380.216
390.948
401.684
412.423
423.166
433.911
444.660
455.411
466.164
476.919
487.677
498.437
509.199
519.962
530.727
541.494
552.262
563.032
573.803
584.575
595.349
606.124
F3 (г)
f°@) = 1881.195 кДж • моль"
Г
К
-964.0053 100
-470.0824 200
-306.9845 298.15
.-304.9320 300
-222.1605 400
-172.4066 500
-139.1906 600
-115.4393 700
-97.6109 800
-83.7355 900
-72.6296 1000
-63.5395 1100
-55.9622 1200
-49.5491 1300
-44.0514 1400
-39.2860 1500
-35.1161 1600
-31.4365 1700
-28.1656 1800
-25.2391 1900
-22.6053 2000
-20.2224 2100
-18.0561 2200
-16.0784 2300
-14.2655 2400
-12.5978 2500
-11.0584 2600
-9.6332 2700
Л *rt ^V ^V Л"" Л СЧ Л f\
-8.3098 2800
-7.0778 2900
-5.9280 3000
-4.8524 3100
-3.8440 3200
-2.8969 3300
-2.0054 3400
-1.1650 3500
-.3712 3600
.3796 3700
1.0908 3800
1.7656 3900
2.4067 4000
3.0165 4100
3.5972 4200
4.1509 4300
4.6795 4400
5.1845 4500
5.6676 4600
6.1302 4700
6.5735 4800
6.9987 4900
7.4070 5000
7.7992 5100
8.1763 5200
8.5393 5300
8.8888 5400
9.2256 5500
9.5504 5600
9.8638 5700
10.1664 5800
10.4588 5900
10.7414 . 6000
Таблица 281
ijj
с;
7 о
1 5
° *
* 3 7,
* * S
=5 ? |
X —' ,
О ос —
О IN 1
° 7
2 .! й к
00 _. — rf
II °. * *'
и? С. "
U а. о ж
ч— гч С^
Г 1
0 ^
^ 0
^ и.
_+
~н ~
й '•*
2 §
—, 2
ГЛ —*
+ '
- ч g
х + V
й "^ §
чо "^ ""*
Я m ¦*"
f- п 'о
Оч I ^ ^
¦ оо ч *С
О О II
чО m. i
о +
С
о
70

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700 ¦
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900 ,
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°{Т)
Р
44.191
65.202
80.458
80.698
91.903
100.373
106.824
111.747
115.524
118.450
120.743
122.561
124.020
125.206
126.179
126.986
127.662
128.233
128.720
129.137
129.498
129.811
130.085
130.326
130.539
130.728
130.896
131.047
131.182
131.305
131.415
131.516
131.607
131.690
131.766
131.836
131.901
131.960
132.015
132.066
132.113
132.156
132.197
132.235
132.270
132.303
132.334
132.363
132.391
132.416
132.440
132.463
132.485
132.505
132.524
132.542
132.559
132.576
132.591
132.606
132.620
ТЕТРАФТОРЭТИЛЕН С
А'°(Г)= рг(С)-р4(
Ф°(Г)
Дж . К . моль
197.290
225.267
245.241
245.580
262.498
277.260
290.456
302.431
313.410
323.557
332.991
341.809
350.087
357.887
365.262
372.254
378.901
385.236
391.287
397.077
402.628
407.959
413.086
418.025
422.788
427.388
431.835
436.139
440.309
444.354
448.279
452.093
455.800
459.408
462.921
466.344
469.681
472.937
476.116
479.221
482.255
485.221
488.124
490.964
493.745
496.469
499.139
501.756
504.323
506.842
509,314
511.741
514.124
516.466
518.767
521.029
523.253
525.441
527.594
529.712
531.797
F)p (C2I'
S°(T)
233.704
270.956
300.013
300.511
325.339
346.800
365.696
382.550
397.729
411.512
424.116
435.712
446.441
456.416
465.732
474.466
482.684
490.441
497.784
504.755
511.389
517.715
523.760
529.548
535.099
540.432
545.562
550.505
555.274
559.879
564.333
568.643
572.820
576.871
580.804
584.624
588.339
591.954
595.474
598.904
602.248
605.511
608.696
611.807
614.847
617.820
620.728
623.57.5
626.362
629.092
631.767
634.390
636.963
639.486
641.963
644.395
646.784
649.130
651.436
653.703
655.931
t)
Н°(Т)-Н
2.F4 (Г)
Д^Я°@)= 2387.550
°@)
кДж ¦ моль
3.641
9.138
16.330
16.479
25.137
34.770
45.144
56.084
67.455
79.160
91.124
103.293
115.625
128.088
140.659
153.318
166.052
178.847
191.695
204.589
217.521
230.487
243.482
256.502
269.546
282.610
295.691
308.788
oZ 1 .Уии
335.024
348.160
361.307
374.463
387.628
400.801
413.981
427.168
440.361
453.560
466.764
479.973
493.186
506.404
519.626
532.851
546.080
559.312
572.547
585.784
599.025
612.267
625.513
638.760
652.009
665.261
678.514
¦ 691.769
705.026
718.284
731.544
744.805
-1222.0808
-595.2606
-388.3005
-385.6962
-280.6790
-217.5629
-175.4325
-145.31 15
-122.7051
-105.1136
-91.0353
-79.5139
-69.9111
-61.7850
-54.8195
-48.7829
-43.5011
-38.8410
-34.6992
-30.9939
-27.6596
-24.6433
-21.9017
-19.3989
-17.1052
-14.9953
-13.0481
-11.2455
Q ?ТОЛ
-У-5/zU
-8.0143
-6.5606
-5.2010
-3.9267
-2.7298
-1.6035
-.5418
.4608
1.4089
2.3071
3.1590
3.9682
4.7377
5.4705
6.1691
6.8359
7.4729
8.0821
8.6653
9.2241
9.7601
10.2745
10.7687
11.2438
11.7009
12.1410
12.5651
12.9740
13.3684
13.7492
14.1171
14.4726
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л
_
с;
с
¦
X
ос
О
- 2
8 ||!
V Ч
>-•
о
-
ч
о 7
3 д
ГО 2
м 1
'я ~
— ?
- ч
S *
° s-
' (—
с Т
00 N^
—< гч
гч —
" 1
ю X
о о
On" °°.
II +
/¦"*¦
S-.
0
©
и ц
I
¦
Ч
с
""!
•/-]
!
II
?
—
ОС
Г-1
'-
.5
Si
а; ¦
а 282
i
s
i
*
—ч
^_
ТГ
II
0 04
я
о
о
5
V
(-,
V
о
. ¦/•>
1
о
«
71

Класс точности
VI-Е
ПЕНТАФТОРЭТИЛ C2F5 (г)
Таблица 283
K°(T)=p2(C)-pS (F)-p'1 (C2FS) Дг#°@)= 2689.510 кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
Ф°(Г)
S°(T)
Дж • К~' . моль
53.461
75.452
93.369
93.672
108.047
1 18.77
126.646
132.315 ¦
136.540
139.653
142.017
143.913
145.361
146.516
147.451
148.218
148.853
149.385
149.834
150.217
150.546
150.830
151.152
151.371
151.564
151.735
151.887
152.023
152.144
152.253
152.352
152.441
152.522
152.596
152.664
152.726
152.782
152.835
152.883
152.927
152.968
153.006
153.042
153.075
153.106
153.135
153.161
153.187
153.210
153.232
153.253
153.273
153.291
153.309
153.325
153.341
153.355
153.369
153.382
153.395
153.407
229.003 272.470
262.365 316.432
285.863 350.027
286.262 350.604
306.070 379.607
323.320 404.977
338.836 427.340
352.905 447.335
365.859 465.273
377.808 481.556
388.920 496.412
399.353 510.024
409.103 522.616
418.286 534.304
426.962 545.204
435.183 555.410
442.995 565.003
450.435 574.050
457.536 582.608
464.328 590.727
470.837 598.447
477.085 605.805
483.131 612.788
488.916 619.513
494.492 625.961
499.875 632.152
505.078 638.108
510.111 643.844
514.986 649.376
519.712 654.718
524.299 659.883
528.753 664.881
533.082 669.724
537,293 674.419
541.393 678.977
545.387 .683.404
549.280 687.709
553.078 691,897
556.784 695.975
560.404 699.948
563.940 703.821
567.397 707.600
570.779 711.289
574.088 714.892
577.327 718.412
580.500 721.855
583.609 725.222
586.657 728.517
589.645 731.744
592.577 734.904
595.454 738.001
598.278 741.037
601.051 744.015
603.775 746.936
606.452 749.803
609.084 752.618
611.671 755.382
614.215 758.097
616.718 760.766
619.181 763.389
621.606 765.968
я°т-я°(о)
кДж . моль
4.347
10.813
19.130
19.303
29.415
40.828
53.103
66.101
79.532
93.373
107.492
121.738
136.215
150.824
165.539
180.340
195.214
210.147
225.130
240.156
255.219
270.313
285.245
300.374
315.525
330.693
345.879
361.079
Л М. Л П -^ П
376.292
391.517
406.753
421.998
437.253
452.515
467.785
483.061
498.343
513.632
528.925
544.223
559.526
574.832
590.143
605.457
620.775
636.096
651.419
666.746
682.075
697.406
712.739
728.075
743.413
758.753
774.094
789.437
804.782
820,128
835.476
850.825
866.176
-1375.5349
-669.3691
-436.1797
-433.2453
-314.9050
-243.7752
-196.2981
-162.3535
-136.8803
-117.0574
-101.1938
-88.2142
-77.3946
-68.2389
-60.3909
-53.5894
-47.6385
-42.3880
-37.7215
-33.5466
-29.7897
-26.3912
-23.3042
-20.4842
-17.8997
-15.5224
-13.3283
-11.2971
-9.4114
. -7.6560
-6.0179
-4.4858
-3.0497
-1.7008
-.4316
.7650
1.8949
2.9635
3.9757
4.9359
5.8479
6.7153
7.5413
8:3287
9.0802
9.7983
10.4850
11.1424
11.7723
12.3764
12.9563
13.5134
14.0490
14.5643
15.0605
15.5386
15.9995
16.4442
16.8736
17.2883
17.6891
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
" О
г g
§ 'х
? «5 г
Ч о |
* 2 -¦
\О OS 1
(X 00 Ч*!
о о . 1 . ¦
2 °° II Ы
о °? —. Й
¦ 1 С
2 и SS "
^н ^ ^ On
II ° °° О\
5 U~ **
**-' С* ^
°а= <Г
+
н
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00 * • s**
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° OS V
1 ,-н Е-
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00
2 ' R 2
+ I
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СТ\ СО II
00 1Л
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Г- fS
чО СО
II 4-
0
0
72

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
*
53.272
82.604
106.193
106.583
124.928
138.336
147.869
154.666
159.588
163.189
165.919
167.996
169.621
170.911
171.960
172.815
173.518
174.10J
174.589
175.001
175.351
175.651
175.908
176.132
176.325
176.565
176.724
176.864
176.988
177.099
177.198
177.287
177.366
177.495
177.564
177.628
177.685
177.738
177.786
177.830
177.870
177.907
177.941
177.373
178.002
178.029
178.054
178.077
178.098
178.118
178.206
178.226
178.245
178.262
178.278
178.294
178.308
178.322
178.335
178.347
178.358
К°(Т) = р2
ФО(Г)
ГЕКСАФТОРЭТАН C2F6 (г)
(C)p6(F)p'1(C2F6) Дг
S°(T)
Дж . К . моль
207.257
239.953
264.339
264.761
286.061
305.109
322.433
338.330
353.007
366.664
379.381
391.324
402.532
413.090
423.109
432.608
441.634
450.232
458.439
466.291
473.815
481.038
487.984
494.671
501.120
507.406
513.432
519.263
524.9Н
530.387
535.701
540.862
545.879
550.796
555.550
560.183
564.698
569.102
573.402
577.600
581.702
585.713
589.636
593.475
597.233
600.914
604.521
608.057
611.524
614.926
618.309
621.588
624.808
627.971
631.079
634.134
637.137
640.092
642.998
645.858
648.672
248.657
294.750
332.342
333.001
366.290
395.691
421.808
445.144
466.137
485.147
502.491
518.398
533.091
546.731
559.425
571.312
582.485
593.024
602.994
612.451
621.445
630.018
638.207
646.044
653.557
660.715
667.646
674.322
680.761
686.978
692.989
698.807
704.443
709.873
715.175
720.325
725.332
730.203
734.946
739.568
744.074
748.469
752.760
756.951
761.046
765.050
768.966
772.800
776.552
780.228
783.796
787.327
790.788
794.185
797.518
800.791
804.004
807.162
810.265
813.314
816.313
я°(Г)-Я°@)
кДж . моль"
4.140
10.959
20.275
20.472
32.092
45.291
59.625
74.770
90.504
106.635
123.109
139.782
156.671
173.733
190.843
208.056
225.362
242.747
260.198
277.705
295.261
312.858
330.492
348.157
365.851
383.271
400.955
418.658
A QR Q7fl
4OU.<3 /о
454.114
471.865
489.628
507.402
524.955
542.722
560.497
578.281
596.072 г-
613.871 -1
631.675
649.485
667.301
685.121
702.947
720.776
738.611
756.448
774.289
792.134
809.982
827.437
845.267
863.100
880.936
898.774
916.614
934.457
952.301
970.147
987.995
1005.845
Я°@)= 3221
-1646.4634
-800.5024
-521.1502
-517.6352
-375.8766
-290.6835
-233.8243
-193.1786
-162.6780
-138.9483
-119.9594
-104.4228
-91.4744
-80.5178
-71.1286
-62.9922
-55.8737
-49.5934
-44.0119
-39.0188
-34.5260
-30.4619
-26.7681
-23.3963
-20.3062
-J 7.4672
-14.8448
-12.4173
-10.1637
-8.0661
-6.1089
-4.2784
-2.5627
-.9534
.5626
1.9915
3.3407
4.6166
5.8251
6.9713
8.0599
9.0952
10.0809 •
11.0206
11.9173
12.7740
13.5932
14.3774
15.1287
15.8492
16.5384
17.2026
17.8410
18.4553
19.0466
19.6164
20.1656
20.6955
21.2070
21.7010
22.1785
.720 кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1 а о л и
о
00
—
II
+
1
х
о
—
+
х
оо
00
о
°
1
X
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о
оо
ОО
и
к
о
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ца 284
7
л
о
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1-И
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О 0?
Я
о
S
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S-.
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о
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1
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II
73

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.341
35.464
38.930
38.995
42.284
45.051
47.318
49.151
50.621
51.799
52.747
53.514
54.140
54.655
55.082
55.440
55.741
55.997
56.217
56.406
56.571
56.715
56.843
56.957
57.060
57.153
57.240
57.320
57.396
57.469
57.540
57.609
57.677
57.745
57.814
57.883
57.953
58.024
58.096
58.170
58.245
58.322
58.400
58.479
58.560
58.641
58.724
58.808
58.892
58.977
59.062
59.148
59.233
59.319
59.404
59.488
59.573
59.656
59.739
59.820
59.901
ОКСИД-ФТОРИД УГЛЕРОДА FCO (г)
*V) = P(F)-P(C
Ф°(Г)
Дж • К . моль
177.348
200.498
214.157
214.373
224.604
232.870
' 239.889
246.032
251.519
256.490
261.044
265.249
269.160
272.816
276.251
279.490
282.555
285.465
288.234
290.877
293.403
295.824
298.148
300.381
302.532
304.606
306.609
308.544
310.417
312.232
313.992
315.700
317.360
318.973
320.543
322.072
323.562
325.015
326.432
327.817
329.169
330.491
331.784
333.049
334.287
335.500
336.689
337.854
338.996
340.118
341.218
342.298
343.359
344.402
345.426
346.434
3471424
348.399
349.358
350.302
351.231
)-р(О)-р"
5°(Г)
210.615
234.215
249.014
249.255
260.936
270.678
279.099
286.536
293.199
299.232
304.740
309.805
314.489
318.843
322.910
326.723
330.311
333.698
336.905
339.950
342.847
345.611
348.252
350.782
353.208
355.539
357.782
359.944
ОАО ftQfl
364.046
365.995
367.883
369.713
371.489
373.214
374.891
376.522
378.111
379.659
381.169
382.643
384.082
385.488
386.864
388.209
389.526
390.816
392.080
393.319
394.534
395.726
396.896
398.046
399.175
400.285
401.375
402.448
403.503
404.541
405.563
406.569
1 (FCO)
Н°(Т)-НС
Д #°@)= 1215
'@)
кДж . моль"
3.327
6.743
10.393
10.465
14.533
18.904
23.526
28.353
33.344
38.468
43.697
49.011
54.395
59.835
65.323
70.850
76.409
81.996
87.607
93.239
98.888
104.552
110.230
115.920
121.621
127.332
133.052
138.780
144.516
150.259
156.009
161.767
167.531
173.302
179.080
184.865
190.657
196.456
202.261
208.075
213.896
219.724
225.560
231.404
237.256
243.116
248.984
254.861
260.746
266.639
272.541
278.451
284.371
290.298
296.234
302.179
308.132
314.093
320.063
326.041
332.027
о
-626.3515
-307.7629
-202.6083
-201.2851
-147.9276
-115.8532
-94.4365
-79.1182
-67.6159
-58.6605
-51.4896
-45.6176
-40.7206
-36.5740
-33.0175
-29.9333
-27.2330
-24.8490
-22.7289
-20.8309
-19.1218
-17.5747
-16.1676
-14.8823
-13.7035
¦12.6185
-11.6165
-10.6883
-9.8260
-9.0227
-8.2727
-7.5707
-6.9123
-6.2935
-5.7109
-5.1612
-4.6419
-4.1504
-3.6845
-3.2423
-2.8220
-2.4220
-2.0408
-1.6772
-1.3300
-.9980
-.6803
-.3759
-.0841
.1959
.4649
.7234
.9722
1.2117
1.4424
1.6648
1.8794
2.0866
2.2868
2.4802
2.6673
.243кДж -моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
7
А
К ¦
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о
о
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СО ОО
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о
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ца 285
'л
к
о
-'
•
|=(
ОО
•¦о
II
п
0 0Q
О
S
V
\/
V
о
о
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1
о
•
II
w
74

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
СЦТ)
33.499
38.984
47.365
47.516
. 54.872
60.569
64.916
68.247
70.821
72.830
74.415
75.680
76.702
77.536
78.223
78.796
79.276
79.684
80.031
80.330
80.588
80.813
81.010
81.184
81.337
81.474
81.595
81.704
81.802
81.890
81.970
82.043
82.109
82.170
82.225
82.276
82.322
82.365
82.405
82.442
82 476
82.508
82.537
82.565
82.591
82.615
82.637
82.658
82.678
82.697
82.714
82.731
82.746
82.761
82.775
82.788
82.801
82.813
82.824
82.834
82.845
ОКСВД-ДИФТОРИД
*V)=p'(F).p
Ф°(Г)
Дж ¦ К~ • моль
183.935
207.250
221.514
221.745
232.980
242.473
250.825
258.339
265.195
271.512
277.376
282.851
287.987
292.825
297.398
301.735
305.857
309.787
313.540
317.132
320.577
323.885
327.068
330.134
333.091
335.948
338.710
341.384
343 975
346.488
348.928
351.298
353.603
355.846
358.031
360.159
362.235
364.260
366.238
368.169
370.057
371.903
373.709
375.477
377.208
378.904
380.566
382.195
383.793
385.361
386.900
388.412
389.896
391.355
392.788
394.197
395.582
396.945
398.286
399.606
400.905
(С).р(О).,
S°(T)
1
217.220
241.726
258.857
259.150
273.868
286.753
298.198
308.466
317.755
326.217
333.976
341.130
347.760
353.934
359.706
365.123
370.224
375.042
379.607
383.942
388.069
392.007
395.771
399.376
402.834
406.158
409.356
412.437
415.410
418.282
421.060
423.749
426.355
428.882
431.336
433.720
436.039
438.295
440.492
442.633
444.721
446.758
448.746
450.689
452.587
454.444
456.260
458.037
459.777
461.482
463.153
464.791
466.398
467.974
469.521
471.040
472.532
473.998
475.438
476.854
478.247
УГЛЕРОДА F2
"'(F2CO) A,
Н°(Т)-Н°@)
кДж . моль"
3.329
6.895
11.134
11.222
16.355
22.140
28.424
35.090
42.048
49.235
56.600
64.107
71.728
79.441
87.231
95.082
102.987
110.935
118.921
126.940
134.986
143.056
151.148
159.258
167.384
175.524
183.678
191.843
200.018
208.203
216.396
224.597
232.805
241.019
249.238
257.463
265.693
273.928
282.166
290.409
298.654
306.904
315.156
323.411
331.669
339.929
348.192
356.456
364.723
372.992
381.263
389.535
397.809
406.084
414.361
422.639
430.919
439.199
447.481
455.764
464.048
СО (г)
Я°@) = 1749.420 кДж- моль
-899.7888
-440.9341
-289.4325
-287.5261
-210.6390
-164.4203
-133.5621
-111.4945
-94.9279
-82.0325
-71.7094
-63.2585
¦56.2128
-50.2486
-45.1346
-40.7011
-36.8207
-33.3960
-30.3511
-27.6262
-25.1733
-22.9536
-20.9355
-19.0925
¦17.4029
-15.8482
-14.4129
-13.0838
-11.8495
-10.7001
-9.6272
-8.6234
-7.6823
-6.7980
-5.9657
-5.1808
-4.4394
-3.7380
-3.0734
-2.4428
-1.8436
-1.2736
-.7306
-.2128
.2816
.7540
1.2061
1.6389
2.0538
2.4518
2.8340
3.2013
3.5545
3.8945
4.2219
4.5375
4.8419
5.1357
5.4194
5.6936
5.9587
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
-1
'л
§
Л
о
NO
(N ГЛ
Г- ЧО
О '
VO "
vo J?-
О
II
8
г»
и*
0
3;
+
5 1
3 s
* ¦
3 й
сч о
о с~-
О *!
1 —<
S +
о "«
Р ел
+ 1
гл гп
II +
с
0
"й
1
S
щ
н
*
о
о
¦»
1
и
2
оо
и
8
W
0
а:
286
?
о
7
*?
m
(N
"~*
II
о 5
s
8
so
v
V
V
о
т
о
II
75

Класс точности
VI-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
13^00
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.258
33.415
34.606
34.640
36.861
39.279
41.505
43.462
45.166
46.649
47.938
49.057
50.030
50.875
51.611
52.252
52.812
53.303
53.735
54.116
54.453
54.753
55.020
55.260
55.475
55.670
55.846
56.007
56.154
56.289
56.414
56.529
56.637
56.738
56.832
56.921
57.005
57.084
57.160
57.232
57.301
57.367
57.431
57.492
57.551
57.608
57.663
57.716
57.768
57.818
57.866
57.914
57.959
58.004
58.047
58.088
58.129
58.168
58.207
58.244
58.280
ФТОРМЕТИЛЕН CHF (г)
К°(Т) = р(С) • р(Н) • p(F) • р"' (CHF) А^ h
Ф°G")
Дж • К . моль
164.909
187.964
201.278
201.485
211.187
218.867
225.302
230.889
235.857
240.349
244.462
248.263
251.802
255.118
258.240
261.192
263.992
266.657
269.201
271.633
273.965
276.205
278.360
280.436
282.439
284.374
286.246
288.059
289.817
291.522
293.179
294.789
296.356
297.881
299.368
300.817
302.230
303.611
304.959
306.276
307.565
308.825
310.059
311.267
312.451
313.611
314.748
315.864
316.959
318.034
319.089
320.125
321.144
322.145
323.130
324.098
325.0.50
325.988
326.910
327.818
328.713
S°(T)
1
198.167
221.239
234.760
234.974
245.230
253.716
261.078
267.627
273.544
278.952
283.935
288.558
292.869
,296.907
300.705
304.288
307.679
310.896
313.955
316.871
319.655
322.319
324.873
327.324
329.680
331.949
334.136
336.247
338.286
340.259
342.169
344.021
345.818
347.562
349.257
350.906
352.510
354.073
355.597
357.082
358.532
359.948
361.331
362.684
364.006
365.300
366.567
367.807
369.023
370.215
371.383
372.529
373.654
374.759
375.844
376.909
377.956
378.985
379.997
380.993
381.972
Я°(Л-Я°@)
кДж . моль
3.326
6.655
9.982
10.046
13.617
17.425
21.466
25.717
30.150
34.742
39.473
44.324
49.280
54.326
59.451
64.645
69.899
75.205
80.557
85.950
91.379
96.840
102.329
107.843
113.380
118.937
124.513
130.106
135.714
141.336
146.972
152.619
158.277
163.946
169.624
175.312
181.008
186.713
192.425
198.145
203.871
209.605
215.345
221.091
226.843
232.601
238.365
244.134
249.908
255.687
261.471
267.260
273.054
278.852
284.655
290.461
296.272
302.087
307.906
313.728
319.555
'"(О) = 899.494
\gK°(T)
-463.0021
-226.9338
-148.9467
-147.9649
-108.3485
-84.5067
-68.5692
-57.1578
-48.5807
-41.-8965
-36.5397
-32.1497
-28.4860
-25.3816
-22.7174
-20.4056
-18.3805
-16.5918
-15.0002
-13.5748
-12.2908
-11.1281
-10.0701
-9.1034
-8.2165
-7.3999
-6.6455
-5.9465
-5.2969
-4.6917
-4.1264
-3.5972
-3.1008
-2.6340
-2.1944
-1.7797
-1.3877
-1.0166
-.6648
-.3308
-.0133
.2889
.5770
.8518
1.1143
1.3654
1.6057
1.8359
2.056?
2.2686
2.4722
2.6679
2.8563
3.0376
3.2124
3.3809
3.5435
3.7005
3.8522
3.9989
4.1408
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 287
I
§
О ^ 1
k vS i
С^ оо
о « '*
О °
го О "~>
^ 5 II *
°- -1 ? о
m ^ 2 ^
II О 00 <N
~ II
zz>> ди со
о О
>• а:
< •-,
_+
'ч -
^ ' .
чо ?
оо К
Ц 2
О ^'
ц. .
- Д о
ЧО О
г- m О
с> Я чо
о Я V
о Ч X
X + ^
с . о
— <¦< о
OS '¦О
s ~ т-
? 2 2
+ i •
¦ч- -* "
оо а\
• о ч^
II +
s~
С-
0
76

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЯПО
2900
3000
3100
3200
-3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5J00
5600
5700
5800
5900
6000
с°рт
33.581
36.577
40.291
40.367
44.644
48.856
52.690
56.100
59.116
61.777
64.114
66.160
67.948
69.507
70.868
72.056
73.097
74.009
74.812
75.521
76.148
76.705
77.201
77.645
78.043
78.401
78.724
79.015
79 280
79.521
79.741
79.942
80.125
80.294
80.450
80.593
80.725
80.848
80.961
81.067
81.165
81.256
81.341
81.421
81.496
81.566
81.631
81.693
81.751
81.806
81.857
81.906
81.952
81.995
82.036
82.075
82.112
82.147
82.181
82.212
82.242
К°(Т) = р(С) ¦ р
Ф°(Г)
Дж ¦ К . моль
163.675
186.955
200.829
201.049
211.509
220.032
227.347
233.830
239.695
245.079
250.073
254.742
259.135
263.287
267.229
270.982
274.567
277.999
281.291
284.456
287.503
290.441
293.279
296.022
298.677
301.249
303.745
306.168
ЧПЯ S99
310.812
313.040
315.211
317.326
319.389
321.403
323.368
325.289
327.166
329.002
330.799
332.558
334.280
335.968
337.621
339.244
340.835
342.396
343.928
345.433
346.912
348.364
349.792
351.196
352.576
353.934
355.270
356.585
357.880
359.155
360.411
361.648
ФТОРМЕТИЛ CH2F (г)
¦(H).p(Y).p~l
S°(T)
l
196.977
221.078
236.355
236.604
248.797
259.217
268.470
276.853
284.546
291.665
298.298
304.507
310.342
315.843
321.045
325.976
330.661
335.120
339.373
343.438
347.328
351.057
354.637
358.079
361.392
364.585
367.666
370.643
373.52!
376.308
379.007
381.625
384.166
386.634
389.034
391.368
393.640
395.854
398.011
400.116
402.169
404.175
406.134
408.048
409.921
411.754
413.547
415.303
417.024
418.710
420.363
421.984
423.576
425.137
426.670
428.176
429.655
431.109
432.537
433.943
435.325
CH:F) Д Н°
Я°(Г)-Я°@)
кДж . моль
3.330
6.825
10.592
10.667
14.915
19.593
24.674
30.117
35.880
41.928
48.225
54.741
61.448
68.323
75.343
82.491
89.750
97.106
104.548
112.065
119.649
127.292
134.988
142.731
150.516
158.338
166.195
174.082
181.997
189.937
197.900
205.884
213.888
221.909
229.946
237.999
246.065
254.143
262.234
270.335
278.447
286.568
294.698
302.836
310.982
319.135
327.295
335.461
343.633
351.811
359.994
368.182
376.375
384.573
392.774
400.980
409.189
417.402
425.619
433.838
442.061
@)= 1249
о
-641.8826
-313.7435
-205.2869
-203.9211
-148.8105
-1 15.6375
-93.4594
-77.5783
-65.6413
-56.3389
-48.8842
-42.7756
-37.6781
-33.3597
-29.6541
-26.4395
-23.6242
-21.1382
•18.9268
-16.9468
-15.1638
-13.5497
-12.0815
-10.7403
-9.5104
-8.3783
-7.3329
-6.3646
-5.4651
-4.6274
-3.8452
-3.1 132
-2.4268
-1.7818
-1.1745
-.6018
-.0607
.4513
.9365
1.3969
1.8344
2.2507
2.6473
3.0255
3.3867
3.7318
4.0621
4.3784
4.6816
4.9725
5.2518
5.5202
5.7784
6.0269
6.2663
6.4970
6.7196
6.9343
7 1418
7.3422
7.5360
.190 кДж -моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2G00
2700
2800
2900
3000
3100
3200
3300
3400
350П
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
~л
к
™* о
'л S
§ L
д о
" о
X О
«N ^
sO !
fN ОО It
s. и ?
О ос
X ^
У я
0 О
а; о
+
н 7
ос §
"~> s
+ '.,
— О
О ?5
О чО
' +
н
~ "ч
о ор
О 00
+ н
1/-) Г-
00 VO
(-. О
С7 OS
t о
II +
О
е
ца 288
7
О
2
1
*
ос
ОС
t-!
ii
0 WI
Q
о
о
чС
V
V
V
о
• г.
t
о
.
11
w
77

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
ФТОРМЕТАН CH3F (г)
к°(Т) = р(О -р3(Н) -р(п -р"'(
Ф°(Г)
S\T)
Дж . к . моль
33.258
33.825
37.504
37.606
44.174
51.289
57.880
63.713
68.819
73.274
77.154
80.529
83.461
86.010
88.229
90.162
91.851
93.332
94.633
95.780
96.795
97.696
98.498
99.215
99.858
100.436
100.957
101.429
101.856
102.245
102.599
102.923
103.220
Ю3.492
103.743
103.974
104.187
104.385
104.568
104.738
104.896
105.044
105.181
105.310
105.430
105.543
105.649
105.748
105.841
105.930
106.013
106.091
106.165
106.235
106.301
106.364
106.424
106.480
106.534
106.585
106.634
152.258 185.515
175.318 208.645
188.719 222.712
188.929 222.944
198.924 234.626
207.140 245.251
214.329 255.196
220.843 264.566
226.866 273.414
232.508 281.783
237.835 289.709
242.895 297.225
247.723 304.360
252.343 311.144
256.775 317.601
261.037 323.756
265.142 329.630
269.101 335.244
272.926 340.616
276.625 345.764
280.206 350.703
283.677 355.448
287.044 360.011
290.313 364.406
293.489 368.643
296.577 372.731
299.582 376.680
302.509 380.499
305.361 384.196
308.141 387.777
310.854 391.249
313.502 394.619
316.088 397.892
318.615 401.072
321.086 404.165
323.503 407.176
325.868 410.108
328.184 412.965
330.452 415.751
332.674 418.470
334.852 421.124
336.988 423.716
339.083 426.249
341.139 428.725
343.158 431.148
345.139 433.518
347.086 435.839
348.998 438.112
350.878 440.340
352.727 442.523
354.544 444.664
356.332 446.764
358.091 448.825
359.822 450.848
361.526 452.834
363.204 454.785
364.856 456.702
366.484 458.586
368.088 460.439
369.669 462.260
371.227 464.052
Таблица 289
CH3F) ДгЯ°@) = 1683.533 кДж • моль
Я°(Л-//°@)
кДж . моль"
3.326
6.665
10.135
10.205
14.281
19.056
24.520
30.606
37.239
44.348
51.874
59.762
67.965
76.442
85.156
94.078
103.181
112.441
121.841
131.363
140.993
150.718
160.529
170.415
180.369
190.384
200.454
210.574
220.739
230.944
241.187
251.463
261.770
272.106
282.468
292.854
303.262
313.691
324.138
334.604
345.086
355.583
366.094
376.619
387.156
397.704
408.264
418.834
429.413
440.002
450.599
461.204
471.817
482.437
493.064
503.697
514.337
524.982
535.633
546.289
556.950
-864.4467
-422.1061
-275.8478
-274.0056
-199.6522
-154.8771
-124.9320
-103.4834
-87.3583
-74.7905
-64.7179
-56.4637
-49.5758
-43.7405
-38.7336
-34.3902
-30.5868
-27.2284
-24.2413
-21.5672
-19.1593
-16.9798
-14.9977
-13.1874
-11.5274
-9.9999
-8.5895
-7.2833
-6.0702
-4.9406
-3.8861
-2.8996
-1.9746
-1.1055
-.2875
.4838
1.2123
1.9014
2.5544
3.1738
3.7624
4.3222
4.8554
5.3638
5.8491
6.3129
6.7565
7.1812
7.5882
7.9787
8.3535
8.7136
9.0598
9.3930
9.7139
10.0231
10.3212
10.6089
10.8866
11.1550
11.4143
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
7 §
'л 5
1 ,§
% о ^
X о 2
г- «л V
os **^ У/
—* Tf li ^
S " *" г
О оо* ^
t-> гч г-)
вс uT п
Г) С! OBJ
*¦ Ж со
о У
а; о
+
i 7*
* Й
^ О
оо ^
(Ч
'« 1
§ пн |
с^ ^ ^
°- оЗ \/
° " к
3 3 ^
00 ч+ *
* —1 I
•л 1 2
+ к
—< * оо Е-*
—< те
О г4* !1
00 1О
ov те' Н
ГЧ Г--
m ^
II +
0
78

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
г
33.692
38.817
45.277
45.398
51.570
56.713
60.798
64.041
66.656
68.801
70.583
72.078
73.343
74.420
75.341
76.134
76.819
77.414
77.934
78.389
78.790
79.144
79.458
79.739
79.989
80.213
80.415
80.598
80,763
80.913
81.050
81.174
81.288
81.393
81.489
81.578
81.660
81.735
81.805
81.870
81.931
81.987
82.040
82:089
82.135
82.178
82.218
82.256
82.291
82.325
82.357
82.386
82.415
82.441
82.466
82.490
82.513
82.535
82.555
82.574
82.593
ДИФТОРМЕТИЛ CHF2 (г)
A:°(D=P(C)-p(H).p2(F).p(
Ф°(Г)
S°(T)
Дж . К . моль
183.678
207.070
221.328
221.558
232.624
241.852
249.900
257.099
263.643
269.660
275.238
280.445
285.331
289.935
294.291
298.425
302.359
306.114
309.704
313.144
316.447
319.622
322.681
325.630
328.478
331.232
333.898
336.480
338.984
341.416
343.778
346.075
348.311
350.488
352.609
354.677
356.696
358.667
360.592
362.473
364.313
366.113
367.875
369.601
371.291
372.948
374.573
376.166
377.730
379.264
380.771
382.251
383.706
385.135
386.540
387.922
389.281
390.619
391.935
393.230
394.506
216.994
241.693
258.393
258.673
272.599
284.680
295.395
305.020
313.748
321.727
329.071
335.871
342.198
348.112
353.662
358.888
363.823
368.499
372.939
377.165
381.196
385.049
388.738
392.276
395.676
398.945
402.096
405.134
408.068
410.905
413.650
416.310
418.889
421.392
423.823
426.187
428.486
430.724
432.905
435.031
437.104
439.128
441.105
443.036
444.923
446.769
448.576
450.345
452.077
453.774
455.438
457.069
458.669
460.239
461.780
463.294
464.780
466.241
467.676
469.088
470.476
CHF2) Arh
Н°(Г)-Н°@)
кДж . моль"
3.332
6.925
11.051
11.135
15.990
21.414
27.297
33.545
40.084
46.861
53.833
60.968
68.241
75.630
83.119
90.694
98.343
106.055
113.823
121.639
129.499
137.396
145.326
153.286
161.273
169.283.
177.315
185.366
193.434
201.518
209.616
217,727
225.851
233.985
242.129
250.282
258.444
266.614
274.791
282.975
291.165
299.361
307.562
315.768
323.980
332.196
340.415
348.639
356.866
365.097
373.331
381.568
389.808
398.051
406.296
414.544
422.795
431.047
439.301
447.558
455.816
Таблица 290
г°@) = 1332.711 кДж • моль
\&К°(Т)
-684.3390
-334.3818
-218.7462
-217.2904
-158.5581
-123.2256
-99.6191
-82.7266
-70.0376
-60.1553
-52.2404
-45.7581
-40.3515
-35.7731
-31.8461
-28.4406
-25.4591
-22.8271
-20.4865
-18.3914
-16.5051
-14.7979
-13.2453
-11.8273
-10.5271
-9.3306
-8.2259
-7.2027
-6.2524
-5.3674
-4.5412
-3.7682
-3.0433
-2.3622
-1.7210
-1.1164
-.5452
-.0048
.5073
.9932
1.4550
1.8943
2.3127
2.7118
3.09.28
3.4570
3.8054
4.1391
4.4589
4.7657
5.0603
5.3434
5.6157
5.8778
6.1302
6.3735
6.6081
6.8346
7.0533
7.2647
7.4690
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
<
'л
7 1
-» ?
О ?
v *3 7
Ко Й
1 § 1
0\ fN vy
d i ~
Г"- *О t| и
s » ? р
й s 2 ч
? и- "
X ™ «
(J ULt OK
о У,
Ч о
S 7
5 §
+ 7
'н
о л 2
«> * 2
§8 V
i ^i ^
х + V
- "х §
п ^ . "^
о «
"> J2 'о
. i
+ t •
3 S "
II +
о
в
79

Класс точности
V-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
33.498
36.694
42.873
43.014
51.123
58.980
65.771
71.459
76.212
80.204
83.574
86.435
88.873
90.959
92.751
94.298
95.638
96.804
97.822
98.716
99.504
100.201
100.819
101.370
101.863
102.306
102.704
103.063
103.389
103.685
103.954
104.200
104.425
104.631
104.821
104.995
105.157
105.306
105.444
105.572
105.692
105.803
105.907
106.003
106.094
106.179
106.259
106.333
106.404
106.470
106.532
106.591
106.647
106.700
106.749
106.797
106.841
106.884
106.924
106.963
106.^9
*°(Г) = Р(С).Р:
Ф°(Л
ДИФТОРМЕТАН CH2F2 (г)
¦(H)-p2(F)-p~l
S°(T)
Дж .К .моль
173.588
1Э6.833
210.734
210.956
221.648
230.629
238.583 "
245.832
252.546
258.826
264.7*2
270.343.
275.665
280.739
285.588
290.232
294.688
298.973
303.097
307.074
310.912
314.622
318.212
321.689
325.060
328.331
331.508
334.595
337.599
340.523
343.371
346.147
348.855
351.497
354.077
356.598
359.063
361.473
363.831
366.139
368.399
370.614
372.785
374.913
377.001
379.049
381.060
383.035
384.974
386.879
388.751
390.592
392.403
394.183
395.935
397.659
399.357
401.028
402.674
404.295
405.893
206.677
230.888
246.597
246.863
260.334
272.602
283.973
294.552
304.413
313.627
322.257
330.360
337.988
345.186
351.994
358.448
364.577
370.411
375.974
381.287
386.371
391.243
395.919
400.413
404.738
408.905
412.926
416.808
420.563
424.196
427.716
431.128
434.440
437.657
440.783
443.824
446.784
449.667
452.478
455.218
457.893
460.504
463.055
465.548
467.986
470.371
472.706
474.992
477.231
479.426
481.577
483.688
485.758
487.790
489.785
491.744
493.669
495.560
497.419
499.248
501.046
(CH2F2) Arh
Я°(Л-Я"@)
кДж . моль
3.329
6.811
10.693
10.772
15.474
20.987
27.234
34.104
41.494
49.321
57.514
66.019
74.787
83.782
92.969
102.324
111.822
121.445
131.178
141.006
150.918
160.903
170.955
181.065
191.227
201.436
211.687
22J.976
ПАЛ f\g\Q
232.298
242.652
253.034
263.442
273.873
284.327
294.799
305.290
315.798
326.321
336.859
347.410
357.973
368.548
379.133
389.729
400.334
410.947
'421.569
432.199
442.836
453.479
464.130
474.786
485.448
496.115
506.788
517.465
528.147
538.833
549.624
560.218
570.916
Таблица 291
'°@) = 1742.353 кДж • моль"'
Т
К
-894.0698 100
-436.3659 200
-285.0587 298.15
-283.1533 300
-206.2581 400
-159.9718 500
-129.0301 600
-106.8782 700
-90.2322 800
-77.2639 900
-66.8748 1000
-58.3644 1100
-51.2651 1200
-45.2527 1300
-40.0953 1400
-35.6227 1500
-31.7068 1600
-28.2500 1700
-25.1760 1800
-22.4246 1900
-19.9475 2000
-17.7057 2100
-15.6673 2200
-13.8057 2300
-12.0990 2400
-10.5286 2500
-9.0788 2600
-7.7362 2700
^ ЛОЛС ЛАЛЛ
-6.4895 2800
-5.3286 2900
-4.2450 3000
-3.2313 3100
-2.2810 3200
-1.3881 3300
-.5478 3400
.2445 3500
.9928 3600
1.7007 3700
2.3713 3800
3.0075 3900
3.6119 4000
4.1868 4100
4.7344 4200
5.2565 4300
5.7548 4400
6.2310 4500
6.6864 4600
7.1225 4700
7.5404 4800
7.9412 4900
8.3260 5000
8.6057 5100
9.0511 5200
9.3932 5300
9.7225 5400
10.0399 5500
10.3459 5600
10.64i2 5700
10.9263 5800
11.2017 5900
11.4679 6000
1ЛЬ
§ *
2 «5
' х 7
«5 о R
* Щ. 1
о <-ч f
5 "
q и to ^
7 с Щ «
3 Ъ о§
^ о
~х •"
¦~- 'л
<""> о
OS S
Н % /-^
(N ^ о
От о
ч-> X О
О оо ^
q S v
s ~: ^
^ го 7
О ON 'о
Г~ | -*
+ н ^
О </-> I'
00 (N ^
ON ГЧ w
00 fS
ГЛ ^н
II +
Р
0
в
80

Класс точности
V-D
Т
К
100
200
Р
ТРИФТОРМЕТАН CHF3 (г)
К°(Т)= p(C)p(H)-p3(F)-p(CHF3) Arh
фО(Т-)
S°{T)
Дж -К .моль
33.894
41.236
298.15 51.069
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
51.258
61.148
69.631
76.453
81.868
86.201
89.719
92.617
95.038
97.084
98.833
100.344
101.660
102.818
103.845
104.763
105.590
106.340
107.026
107.656
108.239
108.782
109.290
109.767
110.218
110.646
111.053
111.443
111.817
112.177
112.525
112.861
113.188
113.506
113.816
114.119
114.415
114.706
114.991
115.271
115.548
115.820
116.089
116.354
116.617
116.876
117.134
117.389
117.641
117.892
118.142
118.389
118.635
118.880
1 19.123
119.366
119.607
119.847
182.548
206.085
220.775
221.015
232.784
242.910
251.984
260.287
267.978
275.158
281.899
288.258
294.277
299.993
305.436
310.631
315.600
320.363
324.936
329.335
333.571
337.657
341.604
345.420
349.114
352.695
356.167
359.539
362.816
366.004
369.106
372.128
375.074
377.948
380.753
383.492
386.169
388.787
391.348
393.854
396.309
398.714
401.071
403.382
405.649
407.874
410.059
412.204
414.312
416.383
418.419
420.421
422.391
424.329
426.237
428.115
429.964
431.786
433.581
435.351
437.095
215.885
241.294
259.565
259.882
276.006
290.593
303.915
316.123
327.348
337.711
347.319
356.263
364.622
372.464
379.845
386.814
393.413
399.677
405.639
411.326
416.762
421.967
426.960
431.759
436.377
440.828
445.124
449.275
453.291
457.181
460.953
464.613
468.169
471.626
474.990
478.267
481.460
484.574
487.613
490.581
493.482
496.318
499.092
501.808
504.467
507.073
509.627
512.132
514.591
517.003
519.372
521.699
523.986
526.234
528.444
530.619
532.759
534.865
536.939
538.982
540.994
Н°{Т)-Н°(Щ
кДж . моль
3.334
7.042
11.565
11.660
17.288
23.841
31.159
39.085
47.496
56.298
65.419
74.806
84.415
94.213
104.173
114.275
124.500
134.834
145.265
155.784
166.381
177.049
187.784
198.579
209.430
220.334
231.287
242.287
253.330
264.415
275.540
286.703
297.903
309.138
320.408
331.710
343.045
354.411
365.808
377.235
388.691
400.176
411.689
423.230
434.798
446.393
458.016
469.664
481.339
493.040
504.766
516.517
528.294
540.095
551.922
563.773
575.649
587.549
599.474
611.422
623.395
Г°@)= 1848.788
-947.9189
-462.4216
-301.9862
-299.9664
-218.4768
-169.4554
-136.7066
-113.2760
-95.6797
-81.9793
-71.0095
-62.0282
-54.5397
-48.2006
-42.7654
-38.0537
-33.9304
-30.2918
-27.0573
-24.1634
¦21.5590
-19.2029
-17.0612
-15.1061
•13.3142
-11.6661
-10.1451
-8.7372
-7.4302
-6.2137
-5.0787
-4.0173
-3.0226
-2.0885
-1.2097
-.3814
.4005
1.1398
1.8399
2.5038
3.1342
3.7335
4.3041
4.8478
5.3665
5.8620
6.3356
6.7888
7.2229
7.6390
8.0383
8.4216
8.7900
9.1443
9.4852
9.8135
10.1299
10.4350
10.7293
11.0135
11.2880
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100 •
4200
4300
4400
4500
4600
4700
4300
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
'й
сз о
744
696.
8
о " "»
"- ©' 5
5 &
* аз
0 5^
"х -J"
00 §
ел «
СП «.*
¦+¦ '
"к *
00 Д
V) *
¦в- <п
\?) >^
CN О
О 00
О с*
н +
в «
Я в
•Ч-" ¦«
00 О
, 1
+ 1
оо X
М 00
00 *™1
СО —t
II +
р
°в
292
I
1
ч'
jj*
VO
СЛ
II
о §
to
s
о
V
к
V
500'
. «
U
о
и
81

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛЛ/.Л
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
и
31.751
43.473
52.261
52.392
58.141
62.105
65.118
67.589
69.707
71.558
73.187
74.623
75.889
77.003
77.985
78.849
79.611
80.285
80.882
81.411
81.882
82.302
82.678
83.016
83.319
83.593
83.841
84.066
ал О7П
84.456
84.626
84.782
84.925
85.056
85.177
85.289
85.392
85.488
85.577
85.659
85.736
85.808
85.875
85.937
85.996
86.051
86.103
86.151
86.197
86.240
86.281
86.319
86.355
86.389
86.422
86.453
86.482
86.510
86.536
86.561
86.585
ФТОР АЦЕТИЛЕН C2HF (г)
*о(Г)=р2(С)-рA
Ф°(Т)
Дж -К .моль
157.183
178.752
193.064
193.302
204.969
214.890
223.582
231.345
238.377
244.816
250.764
256.296
261.472
266.338
270.933
275.286
279.424
283.369
287.137
290.745
294.207
297.534
300.737
303.825
306.806
309.687
312.475
315.176
о 1 7 7Qfi
О 1 1'f9O
320.339
322.809
325.211
327.548
329.824
332.042
334.204
336.315
338.375
340.388
342.355
344.279
346.161
348.004
349.808
351.576
353.308
355.008
356.674
358.309
359.914
361.490
363.038
364.559
366.054
367.524
368.970
370.392
371.791
373.168
374.523
375.858
i)-p(F)-p"'(
S°(T)
186.764
212.324
231.446
231.770
247.687
261.110
272.710
282.939
292.105
300.425
308.050
315.095
321.643
327.763
333.506
338.916
344.030
348.877
353.483
357.871
362.059
366.064
369.902
373.584
377.124
380.531
383.815
386.983
OQO ЛЛЛ
393.004
395.871
398.648
401.342
403.957
406.498
408.969
411.373
413.714
415.995
418.219
420.389
422.507
424.575
426.597
428.573
430.506
432.398
434.250
436.065
437.842
439.585
441.294
442.971
444.616
446.231
447.817
449.375
450.906
452.411
453.890
455.345
C2HF) Д,А
Я°(Г)-Я°@)
кДж ¦ моль
2.958
6.714
11.444
11.540
17.087
23.110
29.477
36.116
42.983
50.048
57.287
64.679
72.206
79.852
87.602
95.445
103.369
111.364
119.423
127.538
135.703
143.913
152.162
160.447
168.764
177.110
185.482
193.878
202.295
210.731
219.185
227.656
236.141
244.640
253.152
261.675
270.209
278.753
287.307
295.869
304.438
313.016
321.600
330.190
338.787
347.389
355.997
364.610
373.227
381.849
390.475
399.105
407.739
416.376
425.017
433.661
442.307
450.957
459.609
468.264
476.921
г°@) = 1674.679
\g,K°(T)
-861.6989
-422.2621
-277.2174
-275.3928
-201.8094
-157.5881
-128.0675
-106.9574
-91.1093
-78.7727
-68.8963
-60.8106
-54.0690
-48.3619
-43.4684
-39.2259
-35.5127
-32.2356
-29.3221
-26.7149
-24.3681
-22.2446
-20.3140
-18.5512
-16.9352
-15.4484
-14.0759
-12.8050
-11.6249
-10.5262
-9.5007
-8.5413
-7.6419
-6.7970
-6.0018
-5.2520
-4.5438
-3.8739
-3.2393
-2.6372
-2.0651
-1.5210
-1.0027
-.5086
-.0368
.4140
.8452
1.2581
1.6538
2.0333
2.3977
2.7479
3.0846
3.4086
3.7206
4.0213
4.3113
4.5912
4.8614
5.1224
5.3748
кДж -моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
|
Й
т §
1
• *3
* 00
О **
О ^J"
p-j О ||
°- II Й
* s- 5
Н и Я
ас
О ч^
а: о
<
1
о Й
^ О
+ 7
со *-<
СО СО*
2 н
о ^
о ^
' сч
? гч+
о JJ
СП ^
4- 1
m X
00 СЛ
О *-<
00 CN
с~ со
II +
с
о
е
ца 293
1
к
00
<-н
IJ
og
о
о
о
V
V
V
§
• •>
т
о
II
82

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
*V)=p'(c
Ф°(Г)
ФТОРЭТИЛЕН C2H3F (г)
)p3(H)-p(F)-p-1
S°(T)
Дж • К~' .моль
33.658
39.646
50.406
50.623
61.985
71.740
79.736
86.331
91.871
96.594
100.657
104.169
107.213
109.858
112.161
114.171
115.930
117.473
118.832
120.031
121.094
122.039
122.882
123.635
124.311
124.920
125.469
125.966
126.417
126.828
127.203
127.545
127.859
128.147
128.413
128.657
128.883
129.093
129.287
129.467
129.635
129.792
129.938
130.074
130.202
130.322
130.434
130.540
130.639
130.733
130.821
130.904
130.983
131.058
131.128
131.195
131.258
131.319
131.376
131.430
131.482
176.743
200.127
214.541
214.777
226.348
236.393
245.482
253.874
261.710
269.083
276.054
282.674
288.980
295.003
300.770
306.302
311.619
316.736
321.669
326.431
331.032
335.483
339.794
343.973
348.027
351.964
355.791
359.514
363.137
366.665
370.105
373.459
376.732
379.928
383.050
386.102
389.086
392.006
394.864
397.662
400.404
403.091
405.725
408.309
410.844
413.332
415.775
418.175
420.532
422,848
425.125
427.365
429.567
431.734
433.867
435.966
438.032
440.068
442.073
444.048
445.995
210.055
234.804
252.562
252.874
269.020
283.934
297.745
310.547
322.447
333.547
343.940
353.702
362.900
371.588
379.816
387.624
395.050
402.126
408.880
415.337
421.522
427.453
433.150
438.630
443.906
448.993
453.904
458.648
463.237
467.681
471.987
476.164
480.218
484.157
487.987
491.713
495.340
498.874
502.320
505.680
508.960
512.163
515.293
518.352
521.343
524.271
527.136
529.943
532.692
535.387
538.029
540.620
543.163
545.659
548.109
550.516
552.880
555.204
557.488
559.735
561.944
(C2H3F) Д Я°@) = 2279.969
г
Я°(Т)-Яо@)
кДж ¦ моль
3.331
6.935
11.336
11.429
17.069
23.771
31.358
39.671
48.589
58.018
67.886
78.131
88.704
99.561
110.664
121.983
133.490
145.162
156.978
168.923
180.980
193.138
205.384
217.711
230.109
242.571
255.091
267.663
280.282
292.945
305.647
318.385
331.155
343.956
356.784
369.637
382.515
395.413
408.333
421.270
434.226
447.197
460.184
473.184
486.198
499.224
512.262
525.311
538.370
551.439
564.516
577.603
590.697
603.799
616.909
630.025
643.147
656.276
669.411
682.551
695.697
-1171.4574
-572.5275
-374.5805
-372.0883
-271.5283
-211.0205
-170.5858
-141.6461
-119.9043
-102.9694
-89.4048
-78.2947
-69.0280
-61.1809
-54.4504
-48.614!
-43.5050
-38.9952
-34.9852
-31.3963
-28.1657
-25.2422
-22.5841
-20.1569
-17.9317
-15.8845
-13.9947
-12.2449
-10 6200
A \J * \& 4tt V V
-9.1072
-7.6953
-6.3745
-5.1363
-3.9733
-2.8787
-1.8467
-.8721
.0498
.9231
1.7515
2.5385
3.2870
3.9999
4.6795
5.3282
5.9480
6.5408
7.1083
7.6521
8.1737
8.6744
9.1555
9.6179
10.0629
10.4914
10.9043
11.3024
11.6865
12.0573
12.4155
12.7617
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5',00
5500
5600
5700
5800
5900
6000
Таблица
i
1
O-t
° Л
\С О
^ »¦
II \
Ж
w
. 0
<
+
7 7
? й
S |
о *
<*> 7
+ Ьй
" к
¦» ч
О\ Н
оо о-.
° Г-*
О u-i
1 +
1 ~!
о •";
•-* о
ео |
+ Н
ft 00
^ t—
¦* -ч
II +
0
е
т»
g
о
о"
II
Я
оо"
СУ".
(N
ьГ
[^
ж
о
294
7
ё
о
i
m
II
0 g
.-^
О
о
чо
V
V
о
о
1
о
.•
II
83

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<л
34.297
45.808
60.235
60.493
73.338
84.100
93.002
100.252
106.064
110.673
114.307
117.176
119.452
121.273
122.747
123.952
124.950
125.785
126.491
127.094
127.614
128.066
128.462
128.810
120.119
129.394
129.641
129.863
1 40 (№4
1 uVivUO
130.245
130.410
130.561
130.699
130.825
130.942
131.049
131.149
131.241
131.326
131.406
131.480
131.549
131.613
131.674
131.730
131.784
131.834
131.881
131.925
131.967
132.006
132.044
132.079
132.112
132.144
132.174
132.203
132.230
132.256
132.281
132.304
ДИФТОРЭТИЛЕН C2H2F2
о 2 2
Ф° (Г)
Дж . К" . моль"
184.764
208.591
224.083
224.342
237.274
248.705
259.132
268.796
277.835
286.340
294.374
301.987
309.220
316.106
322.675
328.953
334.963
340.725
346.259
351.580
356.704
361.643
366.411
371.018
375.475
379.790
383.972
388.030
391.969
395.797
399.520
403.142
406.670
410.107
413.460
416.730
419.923
423.042
426.090
429.070
431.986
434.840
437.633
440.371
443.053
445.682
448.261
450.791
.453.274
456.712
458.106
460.458
462.770
465.042
467.276
469.474
471.635
473.763
475.857
477.919
479.949
(H)-p2(F)-p~
S°(T)
218.170
244.928
265.938
266.312
285.526
303.083
319.230
334.131
347.912
360.681
372.537
383.572
393.869
403.504
412.548
421.059
429.092
436.692
443.903
450.758
457.291
463.528
469.495
475.213
480.702
485.979
491.059
495.956
рал COO
505.249
509.667
513.946
518.093
522.117
526.025
529.822
533.515
537.110
540.611
544.023
547.351
550.598
553.769
556.867
559.894
562.855
565.752
568.588
571.365
574.086
576.752
579.367
581.931
584.447
586.917
589.342
591.724
594.064
596.364
598.625
600.848
l(C2H2F2) V
Я°(Г)-Я°@)
кДж . моль"
3.341
7.267
12.479
12.591
19.301
27.189
36.059
45.734
56.061
66.907
78.163
89.743
101.579
113.618
125.822
138.159
150.605
163.143
175.758
188.438
201.174
213.959
226.785
239.649
252.546
265.472
278.424
291.399
304 39R
317.411
330.444
343.493
356.556
369.632
382.721
395.820
408.930
422.050
435.178
448.315
461.459
474.611
487.769
500.933
514.103
527.279
540.460
553.646
566.836
580.030
593.229
606.432
619.638
632.847
646.060
659.276
672.495
685.717
698.941
712.168
725.397
(г)
'°@)= 2338.471
-1200.2198
-586.0229
-383.0843
-380.5298
-277.4765
-215.4981
-174.1024
-144.4914
-122.2583
-104.9512
-91.0965
-79.7554
-70.3012
-62.2994
-55.4395
-49.4937
-44.2907
-39.6999
-35.6192
-31.9683
-28.6827
-25.7103
-23.0084
-20.5417
-18.2810
-16.2014
-14.2820
-12.5051
-10 Я^^Д
-9.3197
-7.8866
-6.5462
-5.2898
-4.1097
-2.9992
-1.-9523
-.9638
-.0288
.8568
1.6969
2.4949
3.2538
3.9764
4.6654
5.3230
5.9512
6.5520
7.1272
7.6784
8.2070
8.7144
9.2018
9.6704
10.1213
10.5554
10.9737
11.3770
11.7661
12.1417
12.5046
12.8553
кДж • моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб л и
"л
7 5
A S
I 3
00 ГО
¦*. 'V
40 е? —.
¦* ! Q
й II й
о ,2
¦*' о оо"
I! * ^
^ [Г L.
х ^
и х
w_ мм
0 ^^
5: о
к
12 ~
¦о ч
—; о
г» 1
к
го i
о ^
по "н
О о
о xri
1 об
Ч гч
—
го г*
00 ^
— ^О
+ 1
\О X
VO ^
О го
in
II +
О
е
ца 295
_
с
о
-¦
п
о
сч
(Ч
II "
ч
со
Q
о
8
ЧО
V
S-.
V
V
8
о
¦—
84

Класс точности
VIE
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
1,1-ДИФТОРЭТИЛЕН 1,1-С2Н
К°(Т) = Р2(С) ¦ р
Ф°(Г)
2(H)-p2(F)-p"!
5°(Г)
Дж ¦ К • моль
34.297
45.807
60.121
60.374
72.608
82.173
89.633
95.571
100.411
104.431
107.815
110.689
113.145
115.255
117.074
118.651
120.022
121.219
122.268
123.191
124.007
124.730
125.373
125.947
126.462
126.924
127.341
127.717
128.059
128.369
128.652
128.911
129.148
129.365
129.565
129.750
129.920
130.078
130.224
130.359
130.486
130.603
130.713
130.816
130.912
131.002
131.086
131.165
131.240
131.310
131.376
131.439
131.498
131.554
131.607
131.657
131.704
131.749
131.792
131.833
131.872
184.767
208.594
224.084
224.343
237.263
248.649
258.982
268.499
277.345"
285.622
293.405
300.753
307.716
314.334
320.640
326.662
332.427
337.955
343.264
348.373
353.295
358.044
362.631
367.067
371.361
375.523
379.560
383.479
387.287
390.991
394.595
398.105
401.525
404.861
408.115
411.293
414.397
417.431
420.398
423.300
426.141
428.923
431.648
434.319
436.937
439.506
442.026
444.499
446.927
449.312
451.656
453.959
456.223
458.449
460.639
462.793
464.913
467.000
469.056
471.079
473.073
218,173
244.930
265.929
266.301
285.413
302.687
318.356
332.635
345.723
357.789
368.972
379.386
389.126
398.268
406.877
415.009
422.712
430.025
436.984
443.620
449.960
456.028
461.845
467.431
472.803
477.975
482.961
487.774
492.425
496.924
501.281
505.504
509.600
513.578
517.443
521.201
524.859
528.421
531.892
535.276
538.578
541.801
544.950
548.027
551.036
553.978
556.859
559.679
562.441
565.148
567.801
570.404
572.956
575.462
577.921
580.337
582.709
585.041
587.332
589.586
591.802
(C2H2F2) V
Я°G)-Я°@)
кДж • моль
3.341
7.267
12.476
12.587
19.260
27.019
35.624
44.895
54.702
64.950
75.567
86.496
97.691
109.114
120.732
132.521
144.456'
156.519
168.694
180.968
193.329
205:767
218.272
230.839
243.460
256.129
268.843
281.596
294.385
307 207
320.058
332.93ь
345.840
358.766
371.712
384.678
397.662
410.662
423.677
436.706
449.748
462.803
475.869
488.945
502.032
515.127
528.232
541.344
554.465
567.592
580.727
593.867
607.014
620.167
633.325
646.488
659.656
672.829
686.006
699.187
712.372
F2 (г)
Г°@) = 2338.47
-1200.2203
-586.0230
-383.0846
-380.5299
-277.4760
-215.4954
-174.0947
-144.4760
-122.2328
-104.9138
-91.0460
-79.6911
-70.2227
-62.2068
-55.3333
-49.3741
-44.1583
-39.5552
-35.4628
-31.8008
-28.5047
•25.5223
-22.8110
-20.3354
-18.0662
-15.9785
-14.0516
-12.2675
-10.6109
-9.0687
-7.6294
-6.2831
-5.0211
-3.8357 .
-2.7201
-1.6684
-.6752
.2642
1.1541
1.9983
2.8001
3.5628
4.2891
4.9815
5.6424
6.2738
6.8777
7.4559
8.0099
8.5412
9.0513
9.5412
10.0123
10.4656
10.9021
11.3226
11.7281
12.1193
12.4969
12.8618
13.2144
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 296
I
'л
т 1
"> ?
1 1 7
m чо Й
оо **¦* о
ч 7 i
Г« II "'
7 — «
II <л
1 s 2 a
S и Я о
11 N N fN
V = "
3; о
<J ¦*,
<3
+
7 -
<п 'л
00 с^
СО °
СО —
+ '%>
г- m о
*-< сч чо
СО г- '
О о; \/
1 ^
н + V
S "ч §
? 3 •"
со fs T
? 1 2
т)- 00 ?*•
00 ^Н -^
tl +
о
©
85

Класс точности
VI- Е
Г
К
100 '
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9Я0П
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
37.058
46.400
58.348
58.578
70.311
80.070
87.860
94.102
99.190
103.406
106.945
109.942
112.498
114.688
116.575
118.208
119.626
120.863
121.947
122.900
123.742
124.487
125.150
125.742
126.272
126.748
127.178
127.566
127.9! 7
128.237
128.528
128.795
129.038
129.262
129.468
129.657
129.833
129.995
130.145
130.285
130.414
130.535
130.648
130.754
130.852
130.945
131.032
131.113
131.190
131.262
131.330
131.394
131.455
131.513
131.567
131.619
131.667
131.714
131.758
131.800
131.840
цмс-ДИФТОРЭТИЛЕН «wc-C2H2F
Ф G~)
— 1 ~
Дж ¦ К . моль
185.275
210.047
226.012
226.275
239.302
250.639
260.869
270.270
279.003
287.174
294.860
302.122
309.008
315.555
321.798
327.763
333.476
338.957
344.224
349.293
354.178
358.893
363.449
367.857
372.124
376.261
380.275
384.172
ЧЯ7 Qfift
391.645
395.231
398.724
402.128
405.449
408.689
411.853
414.944
417.965
420.920
423.812
426.642
429.413
432.129
434.790
437.400
439.960
442.471
444.937
447.358
449.735
453.072
454,368
456.625
458.845
461.029
463.177
465.292
467.373
469.423
471.442
473.431
2(H)-p2(F)-p '(C2H2F2) Arh
S°(T)
1
219.553
247.895
268.610
268.972'
287.470
304.247
319.561
333.590
346.499
358.433
369.516
379.853
389.532
398.625
407.196
415.296
422.971
430.261
437.201
443.820
450.146
456.202
462.008
467.585
472.948
478.112
483.092
487.899
492.545
¦ 497.039
501.392
505.611
509.704
513.678
517.540
521.295
524.950
528.510
531.979
535.36!
538.661
541.883
545.030
548.105
551.112
554.054
556.933 .
559.752
562.513
565.219
567.872
570.473
573.025
575.529
577.988
580.403
582.775
585.106
587.397
589.650
591.865
Н°(Г)-Н°@)
кДж . моль
3.428
7.569
12.701
12.809
19.267'
26.804
35.215
44.324
53.997
64.133
74.656
85.504
96.629
107.992
119.557
131.298
143.191
155.217
167.359
179.602
191.935
204.347
216.830
229.375
241.976
254.628
267.324
280.062
292.836
305.644
318.483
331.349
344.241
357.156
370.093
383.049
396.024
409.015
422.022
435.044
448.079
461.126
474.186
487.256
500.336
513.426
526.525
539.632
552.748
565.870
579.000
592.136
605.279
618.427
631.581
644.740
657.904
671.074
684.247
697.425
710.607
2 (Г)
Г°@)= 2315.488
-1188.2416
-580.0963
-379.1586
-376.6291
¦274.5810
-213.1982
-172.1923
-142.8534
-120.8187
-103.6608
-89.9214
-78.6711
-69.2897
-61.3471
-54.5362
-48.6312
-43.4628
-38.9013
-34.8459
-31.2169
-27.9505
-24.9950
-22.3080
-19.8547
-17.6058
-15.5369
-13.6272
-11.8590
-10.2173
-8.6889
-7.2624
-5.9282
-4.6774
-3.5026
-2.3969
-1.3546
-.3702
.5608
1.4428
2.2794
3.0741
3.8300
4.5498
5.2361
5.8911
6.516.9
7.1154
7.6885
8.2376
8.7642
9.2697
9.7553
10.2222
10.6715
11.1040
11.5208
11.9227
12.3104
12.6847
13.0463
13.3959
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
-
UOVi
X
о
о
43
со
1
||
о С.
S «Г
и я"
1
3
-3
0
<
+
'« 1
1 l
Г—
со 7
+ ^
7 %
со Й
о ^
О «^
| _(_
гч So
ON r^
00 О
5 i
+ к
13 ^
t— 00
^о со
II +
°©
моль
ON
ГО
ГО
1
>"\
)?.
¦Л
°
О
ua 297
¦
А
О
—'
е|
о
сч
?i
II
о g
to
Q
О
¦§
v
v
V~l
т
О
II
86

Класс точности
VI-E
7"
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
36.641
48.330
60.073
60.292
71.489
80.905
88.489
94.598
99.593
103.741
107.228
110.185
112.707
114.872
116.737
118.351
119.754
120.978
122.050
122.994
123.827
124.565
125.222
125.808
126.333
126.805
127.230
127.614
127.963
128.279
128.568
128.832
129.073
129.295
129.499
129.687
129.861
130.021
130.170
130.308
130.437
130.557
130.669
130.773
130.871
130.963
131.049
131.130
131.206
131.277
131.345
131.409
131.469
131.526
131.580
131.631
131.679
131.725
131.769
131.810
131.850
7рднс-ДИФТОРЭТИЛЕН транс-С2
К°(Т)=Р2(С)- р2
Ф°(Г)
Дж • К~ . моль"
183.379
208.073
224.283
224.552
237.851
249.413
259.821
269.365
278.214
286.481
294.248
301.579
308.523
315.122
321.409
327.415
333.163
338.675
343.970
349.065
353.974
358.711
363.287
367.712
371.996
376.149
380.177
384.088
387 888
391.584
395.181
398.684
402.099
405.428
408.677
411.849
414.948
417.976
420.938
423.836
426.672
429.450
432.172
434.839
437.453
440.018
442.535
445.005
447.430
449.812
452.152
454.452
456.714
458.937
461.124
463.276
465.394
467.479
469.532
471.553
473.545
(H)p2(F)
S°(T)
217.316
246.249
267.735
268.107
287.021
304.021
319.467
333.583
346.552
358.529
369.645
380.007
389.705
398.814
407.397
415.508
423.192
430.489
437.435
444.060
450.390
456.450
462.260
467.840
473.205
478.372
483.354
488.163
492.810
497.306
501.660
505.880
509.975
513.950
517.813
521.569
525.225
528.785
532.255
535.638
538.939
542.161
545.308
548.384
551.392
554.334
557.213
560.032
562.794
565.500
568.153
570.755
573.307
575.812
578.271
580.685
583.058
585.389
587.680
589.933
592.149
р 4C2H2F2) Arh
Я°(Л-Я°@)
кДж • моль
3.394
7.635
12.955
13.067
19.668
27.304
35.787
44.952
54.670
64.843
75.396
86.271
97.419
108.800
120.383
132.139
144.046
156.084
168.237
180.490
192.832
205.252
217.742
230.294
242.901
255.559
268.261
281.003
293.782
306.595
319.437
332.308
345.203
358.121
371.061
384.021
396.998
409.992
423.002
436.026
449.063
462.113
475.175
488.247
501.329
514.421
527.521
.540.630
553.747
566.871
580.002
593.140
606.284
619.434
632.589
645.750
658.915
672.085
685.260
698.439
711.622
H2F2 (г)
Г°@)= 2312
о
-1186.6277
-579.2360
-378.5602
-376.0344
-274.1266
-212.8312
-171.8851
-142.5898
-120.5882
-103.4564
-89.7380
-78.5050
-69.1381
-61.2080
-54.4077
-48.5120
-43.3517
-38.7975
-34.7486
-31.1253
-27.8641
-24.9133
-22.2307
-19.7813
-17.5360
-15.4704
-13.5638
-! 1.7985
. -10.1594
-8.6335
-7.2094
-5.8773
-4.6285
-3.4556
-2.3517
-1.3111
-.3283
.6012
1.4817
2.3170
3.1104
3.8650
4.5837
5.2688
5.9227
6.5475
7.1451
7.7171
8.2653
8.7911
9.2958
9.7806
10.2467
10.6952
11.1271
11.5432
11.9444
12.3315
12.7052
13.0662
13.4151
.588 кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
-4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
-5800
5900
6000
Т а б л и
s
о
о
ГО
О
ГО
1
II
О
^ С
°- [/"
5 х
II «
^ о
а;
|
0
+
1 —
г? 'л
5 о
оо S
VD
1
f jg
00
оо "^
о °1
6 ?
1 +
rs t—
1 О
si 7
+ к
00 00
ч я
II +
-_.
0
: • мо;
я
ГО
О
|'
II
оо'
(N
(N
Г*
и
|
В
0
ч.
о
Ца 298
—
л
о
1
о
CS
II
0 S
to
/^
о
о
V
V
V
о
. „
t
о
•
II
87

Класс точности
IV - Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
К°(Т) =р2
Ф°(Г)
ТРИФТОРЭТИЛЕН C2HF3 (г)
(C)p(H)p3(F)p(C2HF3) Arh
Дж К .моль
39.500
55.122
69.190
69.431
81.121
90.319
97.462
103.040
107.458
111.013
113.913
116.307
118.304
119.982
121.405
122.619
123.662
124.563
125.345
126.028
126.627
127.155
127.622
128.038
128.408
128.740
129.039
129.308
129.551
129.772
129.972
130.155
130.323
130.476
130.617
130.747
130.866
130.977
131.080
131.175
131.263
131.345
131.422
131.494
131.561
131.624
131.682
131.738
131.790
131.839
131.885
131.928
131.969
132.008
132.045
132.080
132.113
132.144
132.174
132.202
132.229
200.893
226.806
244.498
244.795
259.606
272.559
284.210
294.856
304.683
313.821
322.366
330.393
337.965
345.131
351.932
358.405
364.581
370.484
376.139
381.566
386.781
391.801
396.640
401.311
405.825
410.191
414.420
418.520
422.497
426.360
430.114
433.767
437.321
440.785
444.160
447.452
450.666
453.804
456.870
459.867
462.799
465.667
468.475
471.225
473.920
476.562
479.152
481.693
484.18b
486.634
489.037
491.399
493.719
495.999
498.241
500.446
502.615
504.750
506.850
508.918
510.955
235.719
267.841
292.551
292.980
314.619
333.751
350.877
366.337
380.395
393.265
405.116
416.089
426.297
435.835
444.780
453199
. 461.146
468.671
475.814
482.609
489.089
495.280
501.207
506.889
512.346
517.595
522.650
527.525
532.232
536.782
541.185
545.450
549.585
553.598
557.495
561.283
564.968
568.555
572.049
575.456
578.778
582.020
585.186
588.279
591.303
594.260
597.154
599.987
602.761
605.478
608.143
610.755
613.317
615.831
618.299
620.722
623.102
625.441
627.739
629.999
632.221
Я°G)-Я°@)
кДж ¦ моль
3.483
8.207
14.327
14.455
22.005
30.596
40.000
50.037
60.570
71.500
82.751
94.265
105.999
117.916
129.987
142.190
154.505
166.917
179.414
191.983
204.616
217.306
230.045
242.829
255.651
268.509
281.398
294.316
307.259
320.225
333.213
346.219
359.243
372.283
385.338
398.406
411.487
424.579
437.682
450.795
463.917
477.047
490.186
503.332
516.484
529.644
542.809
555.980
569.156
582.338
595.524
608.715
621.910
635.109
648.311
661.517
674.727
687.940
701.156
714.375
727.596
(°@)= 2355
о
-1207.9960
-589.3227
-384.9752
-382.4035
-278.6682
-216.2968
-174.6477
-144.8600
-122.4963
-105.0881
-91.1525
-79.7448
-70.2345
-62.1848
-55.2834
-49.3011
-44.0661
-39.4465
-35.3401
-31.6660
-28.3593
-25.3677
-22.6482
-20.1655
-17.8898
-15.7964
-13.8643
-12.0755
-i 0.4148
-8.8687
-7.4259
-6.0764
-4.8115
-3.6233
-2.5052
-1.4512
-.4559
.4855
1.3773
2.2232
3.0267
3.7908
4.5185
5.2123
5.8744
6.5070
7.1121
7.6913
8.2463
8.7786
9.2896
9.7804
10.2523
10.7064
11.1435
11.5648
11.9709
12.3628
12.7410
13.1065
13.4597
.985 кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
.2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
V
ё
•
д
V)
V)
00
•л "*
см '
о и
S S
и tT
"""¦ <•>
X
с*
W
О
<1
+
1 *
Г— \л
ос 5
00 О
с-> ?
С» |
? ¦=!
го Н
о J°
1 о
н m
? +
Я 2
. 00
Г4- *
о р
о чэ
to •~~|
*п о
in оо
11 +
о
е
~ё
о
2
д
о
о
ON
1
ii
00*
у
0
а;
299
_
:оль~
2
-'
•
г-
о
™.
см
II
О- &\
6000К)
V
V
8
•«.
о
•
II
88

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
. 2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
33.313
35.479
' 40.496
40.603
46.454
51.777
56.284
60.031
63.145
65.742
67.919
69.752
71.303
72.622
73.749
74.716
75.551
76.274
76.904
77.455
77.939
78.367
78.745
79.082
79.383
79.653
79.895
80.113
80.311
80.491
80.654
80.803
80.939
81.064
81.179
81.284
81.382
81.472
81.556
81.634
81.707
81.774
81.838
81.897
81.953
82.005
82.055
82.102
82.147
82.190
82.231
82.270
82.308
82.344
82.379
82.414
82.447
82.480
82.512
82.544
82.575
ОКСВД-ГВДРВД-ФТОРИД УГЛЕРОДА
К°(Т) = p(H)p(F)
Ф°(Г)
Дж ¦ К . моль
174.864
197.996
211.667
211.884
222.254
230.810
238.243
244.894
250.956
256.548
261.754
266.631
271.223
275.567
279.689
283.613
287.358
290.940
294.374
297.671
300.842
303 897
306.844
309.690
312.442
315.107 ,
317.689
320.194
322.625
324.988
327.287
329.523
331.701
333.824
335.894
337.914
339.887
341.813
343.697
345.539
347.341
349.105
350.832
352.525
354.184
355.810
357.406
358.971
360.508
362.017
363.499
364.955
366.386
367.793
369.177
370.538
371.878
373.196
374.493
375.771
377.029
р(С)р(О)
SV)
208.127
231.671
246.713
246.964
259.450
270.402
280.253
289.219
297.445
305.037
312.079
318.641
324.779
330.540
335.964
341.086
345.935
350.537
354.916
359.088
363.074
366.887
370.542
374.050
377.422
380.668
383.797
386.816
389.734
392.555
395.287
397.933
400.501
402.994
405.416
407.770
410.061
412.292
414.466
416.586
418.653
420.672
422.643
424.569
426.453
428.295
430.098
431.864
433.592
435.287
436.948
438.576
440.174
441.742
443.282
444.794
446.279
447.739
449.173
450.584
451.972
p~'(HFCO) ArHc
Я°(Г)-Я°@)
кДж . моль
3.326
6.735
10.449
10.524
14.878
19.796
25.206
31.028
37.191
43.639
50.326
57.212
64.267
71.465
78.785
86.209
93.723
101.316
108.975
116.694
124.464
132.280
140.136
148.027
155.951
163.903
171.880
179.881
187.902
195.943
204.000
212.073
220.160
228.260
236.372
244.496
252.629
260.772
268.923
277.083
285.250
293.424
301.605
309.791
317.984
326.182
334.385
342.593
350.805
359.022
367.243
375.468
383.697
391.930
400.166
408.405
416.649
424.895
433.144
441.397
449.653
HFCO (г)
@)= 1622.277
о
-835.1171 .
-409.4701
-268.8872
-267.1176
-195.7376
-152.8056
-124.1256
-103.6043
-88.1905
-76.1868
-66.5732
-58.6999
-52.1333
-46.5729
-41.8036
-37.6678
-34.0471
-30.8508
-28.0085
-25.4643
-23.1737
-21.1006
-19.2154
-17.4936
-15.9148
-14.4620
-13.1206
-11.8783
-10.7244
-9.6499
-8.6468
-7.7082
-6.8281
-6.0012
-5.2227
-4.4886
-3.7951
-3.1390
-2.5172
-1.9273
-1.3667
-.8333
-.3253
.1593
.6219
1.0640
1.4871
1.8922
2.2805
2.6531
3.0108
3.3546
3.6853
4.0035
4.3101
4.6056
4.8906
5.1656
5.4313
5.6880
5.9362
кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
¦1
1 5
А 7
о X
X
о *
о 7
2 '
г~. г- "
Я II <П
00 •"¦*
"* О 00
" С й
О и
u О
ж ^
&
*¦ <>
¦ +
н ^
(-~ С
~ч О
+ —'
'ч
8. §
О о)
1 *"-
? +
—| "х
сп ч1;
о "^
+ 1
О Ov
JJ о;
СО Г~
II +
(^
*-'
°е
ца 300
7*
g
S
^'
1
а
k
«о
<s
II
§
to
Q
О
О
о
о
V
V
§
*
о
II
89

Класс точности
II-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
9ЯПП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
410.0
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Г)
32.566
31.337
32.268
32.293
33.611
34.657
35.413
35.960
36.365
36.675
36.920
37.120
37.288
37.433
37.560
37.676
37.781
37.880
37.974
38.064
38.151
38.236
38.321
38.405
38.489
38.573
38.658
38.744
OQ ОО 1
ОО.ОО I
38.919
39.008
39.097
39.187
39.278
39.368
39.457
39.545
39.630
39.714
39.794
39.871
39.943
40.011
40.073
40.129
40.179
40.223
40.259
40.289
40.311
40.326
40.334
40.334
40.327
40.313
40.292
40.264
40.230
40.189
40.143
40.091
ХЛОРИД УГЛЕРОДА СС1 (г)
К°(Г)= р(С)-р(С1)р~\сС1)
Ф°G)
Дж • К . моль
158.648
180.380
192.932
193.126
202.239
209.401
215.337
220.423
224.882
228.856
232.443
235.714
238.722
241.506
244.099
246.524
248.804
250.954
252.990
254.922
256.759
258.514
260.192
261.800
263.344
264.828
266.257
267.636
270.255
271.501
272.709
273.881
275.019
276.125
277.201
278.248
279.269
280.264
281.235
282.182
283.108
284.013
284.898
285.764
286.612
287.442
288.256
289.053
289.835
290.602
291.356
292.095
292.821
293.534
294.235
294.924
295.601
296.267
296.923
297.567
S°(T)
l
189.747
211.796
224.444
224.644
234.118
241.736
248.126
253.628
258.457
262.759
266.637
270.165
273.403
276.393
279.172
281.767
284.202
286.496
288.664
290.719
292.674
294.537
296.318
298.023
299.660
301.232
302.747
304.207
ОАС С 1 О
OUO.O 1 О
306.982
308.303
309.584
310.826
312.034
313.208
314.350
315.463
316.548
317.605
318.638
319.647
320.632
321.595
322.537
323.459
324.362
325.246
326.111
326.959
327.790
328.604
329.403
330.186
330.955
331.708
332.448
333.173
333.886
334.585
335.272
335.946
Д/.Я°@)= 395.000
Я°(Г)-Я°@)
кДж • моль
3.110
6.283
9.396
9.455
12.752
16.168
19.673
23.243
26.861
30.513
34.193
37.896
41.616
45.353
49.102
52.864
56.637
60.420
64.213
68.015
71.830
75.649
79.477
83.314
87.158
91.011
94.873
98.743
102.622
106.509
110.406
114.311
118.225
122.148
126.081
130.022
133.972
137.931
141.898
145.873
149.857
153.847
157.845
161.849
165.859
169.875
173.895
177.919
181.947
185.977
190.009
194.042
198.075
202.109
206.141
210.171
214.199
218.224
222.245
226.261
230.273
\g.K°(T)
-202.4662
-98.8508
-64.6475
-64.2170
-46.8540
-36.4106
-29.4327
-24.4382
-20.6853
-17.7613
-15.4183
-13.4984
-11.8961
-10.5386
-9.3735
-8.3625
-7.4768
-6.6944
-5.9982
-5.3746
-4.8127
-4.3039
-3.8409
-3.4177
-3.0295
-2.6719
-2.3416
-2.0354
-1.7508
-1.4857
-1.2379
-1.0060
-.7884
-.5837
-.3910
-.2091
-.0371
.1257
.2800
.4266
.5659
.6986
.8250
.9457
1.0609
1.1712
1.2767
1.3778
1.4748
1.5679
1.6574
1.7434
1.8262
1.9059
1.9827
2.0568
2.1283
2.1974
2.2641
2.3287
2.3911
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 301
i
л
i 2 _
§ • '-
? 5 |
| о -'
^ « Ы
*—' ГО V
¦* 2 "* 5
$ го " „
"* " So 2
II о 2 ""
. Г II
б - <- ч
^ б ^
° У
а; о"""
<Г" *-,
!
<?
о
5- ~
о л
+ о
1
^ Т О
Is? 1
° V
7 "я ь-
к ° V
? го О
о ' °
^ ^ч • ••
ГО -1 2
го + К.
оо ч
ГО -Ч
II 1
°е
90

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
460Q
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ДИХЛОРИД УГЛЕРОДА СС12 (г^
К°(Т)= р(С)-р
Ф°(Г)
Дж • К . моль
35.01 187.804
41.014 211.700
46.475 226.479
46.561 226.717
50.288 238.144
52.616 247.529
54.099 255.548
55.080 262.567
55.755 268.818
56.237 274.456
56.592 279.592
56.860 284.309
57.069 288.672
57.236 292.729
57.376 296.522
57.499 300.083
57.613 303.438
57.726 306.610
57.844 309.619
57.974 312.480
58.118 315.208
58.280 317.814
58.464 320.310
58.669 322.704
58.898 325.005
59.149 327.220
59.422 329.356
59.715 331.418
ВО П28 ЧЧЧ 412
60.357 335.342
60.700 337.213
61.056 339.028
61.420 340.792
61.790 342.507
62.164 344.176
62.539 345.802
62.913 347.388
63.282 348.935
63.646 350.445
64.001 351.921
64.346 353.364
64.680 354.776
65.001 356.159
65.308 357.513
65.599 358.840
65.875 360.141
66.134 361.417
66.377 362.670
66.602 363.900
66.809 365.108
66.999 366.295
67.173 367.462
67.329 368.609
67.468 369.737
67.591 370.847
67.698 371.940
67.791 373.015
67.868 374.074
67.931 375.117
67.981 376.144
68.018 377.157
¦(СЛ)р~1(СС12)
S°(T)
1
221.426
247.474
264.920
265.208
279.154
290.646
300.380
308.798
316.200
322.796
328.740
334.147
339.104
343.679
347.926
351.889
355.603
359.099
362.402
365.533
368.510
371.350
374.065
376.668
379.170
381.579
383.904
386.152
388 330
390.442
392.494
394.490
396.434
398.330
400.180
401.987
403.754
405.483
407.176
408.833
410.458
412.051
413.614
415.147
416.652
418.129
419.580
421.004
422.404
423.780
425.132
426.460
427.766
429.050
430.312
431.553
432.774
433.975
435.155
436.317
437.460
A h
Я°G>Я°@).
кДж . моль
3.362
7.155
11.461
11.547
16.404
21.558
26.899
32.362
37.905
43.506
49.148
54.822
60.519
66.234
71.965
77.709
83.464
89.231
95.010
100.800
106.605
112.425
118.262
124.118
129.996
135.898
141.827
147.783
153.770
159.790
165.842
171.930
178.054
184.214
190.412
196.647
202.920
209.229
215.576
221.958
228.376
234.827
241.311
247.827
254.372
260.946
267.547
274.172
280.822
287.492
294.183
300.892
307.617
314.357
321.110
327.874
334.649
341.432
348.222
355.018
361.818
I
'°@)= 725.425
-370.2482
-179.6960
-116.7641
-115.9721
-84.0290
-64.8219
-51.9931
-42.8142
-35.9196
-30.5498
-26.2485
-22.7251
-19.7857
-17.2960
-15.1599
-13.3068
-11.6840
-10.2508
-8.9759
-7.8342
-6.8059
-5.8749
-5.0279
-4.2540
-3.5442
-2.8907
-2.2871
-1.7280
-1.2085
-.7246
-.2728
.1501
.5467
.9193
1.2702
1.6010
1.9136
2.2093
2.4894
2.7552
3.0078
3.2480
3.4767
3.6948
3.9030
4.1019
4.2921
4.4742
4.6486
4.8159
4.9764
5.1306
5.2788
5.4214
5.5586
5.6908
5.8183
5.9412
6.0598
6.1744
6.2851
кДж • моль
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 302
- '!
'л 2
о '
2 k I •
К * 2
3 я т
О 42
О ГЧ
О с-1 ^
3 " «2 °°-
1) С ОС ^
*-. г* OS
5 ^ <Ч
0 Q_^
а; о" ¦
<^ ^
i
i
о —
о 'л
гл О
_• 2
+ -"
? • Q
S ч о
§ ? V
н 7 V
(-- ГО .*.
о о -е-
гг> *~~ о
1/") fN
^О О*< !)
ГО ГО
vj *~| Н
Tf ГО
и '
-¦-¦
О
в
91

Класс точности
VI Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
39.984
53.564
62.674
62.814
68.977
72.960
75.570
77.332
78.563
79.449
80.107
80.606
80.993
81.299
81.545
81.745
81.910
82.048
82.164
82.262
82.347
82.420
82.483
82.539
82.588
82.631
82.669
82.703
82.734
82.762
82.786
82.809
82.829
82.848
82.865
82.881
82.895
82.908
82.921
82.932
82.942
82.952
82.961
82.969
82.977
82.984
82.991
82.998
83.004
83.009
83.015
83.020
83.024
83.029
83.033
83.037
83.041
83.044
83.048
83.051
83.054
ТРИХЛОРИД УГЛЕРОДА СС13
К°(Т) = Р(О-Р
Ф°(Г)
Дж . К . моль"
209.955
235.953
253.433
253.723
267.884
279.846
290.262
299.507
307:825
315.387
322.321
328.724
334.671
340.223
345.429
350.329
354.958
359.343
363.510
367.478
371.266
374.889
378.361
381.695
384.900
387.987
390.963
393.837
396.614
399.303
401.907
404.432
406.883
409.263
411.578
413.829
416.022
418.158
420.241
422.273
424.257
426.194
428.087
429.938
431.749
433.522
435.257
436.957
438.623
440.256
441.858
443.429
444.971
446.485
447.973
449.434
450.870
452.281
453.669
455.034
456.377
3(С1)р VCC13) ДГА
S°(T)
1
244.796
276.987
300.184
300.572
319.550
335.402
348.951
360.741
371.152
380.459
388.86&
396.525
403.556
410.051
416.086
421.719
427.000
431.970
436.663
441.108
445.330
449.349
453.185
456.853
460.367
463.739
466.980
470.101
473.109
476.013
478.819
481.534
484.164
486.713
489.186
491.588
493.924
496.195
498.406
500.560
502.660
504.708
506.707
508.659
510.567
512.432
514.256
516.041
517.788
519.500
521.177
522.821
524.433
526.014
527.566
529.090
530.586
532.056
533.500
534.920
536.316
Я°G)-Я°@)
кДж . моль
3.484
8.207
13.939
14.055
20.666
27.778
35.213
42.864
50.662
58.565
66.544
74.581
82.662
90.777
98.919
107.084
115.267
123.465
131.676
139.897
148.128
156.366
164.612
172.863
181.119
189.380
197.645
205.914
214.186
222.460
230.738
239.018
247.300
255.584
263.869
272.156
280.445
288.735
297.027
305.320
313.613
321.908
330.204
338.500
346.798
355.096
363.394
371.694
3.79.994
388.295
396.596
404.897
413.200
421.502
429.805
438.109
446.413
454.717
463.022
471.327
479.632
(г)
'°@)= 989.164
-502.8317
-242.7557
-156.8534
-155.7724
-112.1738
-85.9631
-68.4609
-55.9423
-46.5424
-39.2242
-33.3646
-28.5669
-24.5663
-21.1792
-18.2745
-15.7560
-13.5515
-11.6056
-9.8753
-8.3267
-6.9326
-5.6709
-4.5237
-3.4759
-2.5153
-1.6313
-.8151
-.0593
.6427
1.2964
1.9067
2.4777
3.0131
3.5162
3.9897
4.4363
4.8582
5.2574
5.6356
5.9945
6.3356
6.6601
6.9692
7.2639
.5454
7.8144
8.0718
8.3183
8.5545
8.7812
8.9989
9.2081
9.4093
9.6029
9.7894
9.9692
10.1426
10.3100
10.4716
10.6278
10.7788
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
. 2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 303
i
л
к
~ о
I s —
1 * 'I
?s О ^
С5 О I
_ з S i
°° °° Я 3
^ II Ю о\
/—¦• • 00
II О 00 rt
m и "
Л в %?
"*¦ о.
+
1
S 7
л
+ §
^н Ч ^
О m \/
"? ¦* f-ч
1 00
V. "* \/
Н V
? *""* о
я п* Т.
ЧО ^ •»
+ .
00 ?**
r ё и
О vo
о\ ^ ~
"* ""
II +
г
Г"»
о
в
92

Класс точности
VI-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
*
47.076
69.603
82.888
83.082
91.244
96.225
99.376
101.458
102.892
103.915
104.667
105.236
105.675
106.021
106.298
106.523
106.709
106.863
106.993
107.104
107.199
107.280
107.351
107.413
107.468
107.516
107.559
107.597
107.631
107.662
107.689
107.715
107.737
107.758
107.777
107.795-
107.810
107.825
107.839
107.851
107.863
107.874
107.884
107.893
107.902
107.910
107.917
107.925
107.931
107.938
107.944
107.949
107.954
107.959
107.964
107.968
107.973
107.977
107.980
107.984
107.987
ТЕТРАХЛОРИД
К°(Т)= р(С)р
Ф°(Т)
Дж • К • моль
201.752
230.751
251.794
252.150
269.818
285.002
298.344
310.248
320.992
330.781
339.768
348.074
355.794
363.005
369.768
376.136
382.153
387.854
393.271
398.431
403.357
408.068
412.584
416.920
421.089
425.103
428.975
432.712
ДОС ЧО<\
439.822
443.209
446.493
449.681
452.777
455.788
458.717
461.569
464.348
467.057
469.700
472.280
474.800
477.262
479.670
482.025
484.330
486.587
488.798
490.965
493.089
495.172
497.216
499.222
501.191
503.126
505.026
506.893
508.729
510.534
512.309
514:056
* (С1) р~1(СС
S°(T)
1
238.634
278.862
309.342
309.856
334.973
355.913
373.756
389.242
402.889
415.070
426.059
436.063
445.239
453.712
461.580
468.921
475.802
482.276
488.388
494.176
499.672
504.904
509.897
514.670
519.243
523.631
527.848
531.908
535.822
539.600
543.250
546.781
550.202
553.517
556.734
559.859
562.896
565.850
568.725
571.527
574.257
576.921
579.521
582.059
584.540
586.965
589.337
591.658
593.930
596.155
598.336
600.474
602.570
604.626
606.644
608.625
610.571
612.482
614.360
616.206
618.021
УГЛЕРОДА СС1
Я°(П-Я°@)
кДж . моль""
3.688
9.622
17.158
17.312
26.062
35.455
45.247
55.295
65.517
75.860
86.291
96.787
107.334
117.919
128.536
139.177
149.839
160.518
171.211
181.916
192.631
203.355
214.087
224.825
235.569
246.318
257.072
267.830
97ft ^Ql
Л 1 O.iJj 1
289.356
300.124
310.893
321.666
332.441
343.218
353.996
364.776
375.559
386.342
397.126
407.912
418.699
429.487
440.275
451.065
461.856
472.647
483.439
494.232
505.026
515.820
526.614
537.409
548.205
559.001
569.798
580.595
591.392
602.190
612.988
623.787
4 (Г)
'@)= 1283.013
lgAT°(r)
-649.5573
-312.1405
-200.7242
-199.3224
-142.7980
-108.8311
-86.1589
-69.9487
-57.7Й15
-48.3121
-40.7329
-34.5293
-29.3580
-24.9814
-21.2293
-17.9771
-15.1313
-12.6202
-10.3881
-8.3910
-6.5937
-4.9677
-3.4896
-2.1402
-.9034
.2344
1.2845
2.2567
3 1593
3.9996
4.7837
5.5171
6.2047
6.8504
7.4581
8.0310
8.5720
9.0836
9.5683
10.0281
10.4648
10.8801
11.2756
11.6527
12.0126
12.3565
12.6853
13.0002
13.3018
13.5912
13.8689
14.1357
14.3922
14.6390
14.8767
15.1056
15.3264
15.5394
15.7451
15.9437
16.1357
кДж ^моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
-1
7 2
¦Й ?
О „
7 EJ
* о
л О
оо ^
со °?
ГО > С
W) II ™
It 00
% j
w и
0 В
"^ 0
< ч
+
I
'*
VO
ГО .-.
+ й'
? I
ч —-
Р Т
оо М
о „
1 ^
е °
гч +
й ?
+ ¦*
*?> '
гч ч
г-: о
гч °
3 п
II +
J~
•-*
о
е
ца 304
'л
с:
о
S
—*
а
ел
о
IS
II
и
to
о
о
V
К
V
V
о
о
•о
1
о
ь.
II
93

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
31.889
40.035
45.045
45.118
48.330
50.633
52.454
53.949
55.186
56.209
57.054
57.754
58.336
58.822
59.230
59.575
59.869
60.121
60.337
60.525
60.688
60.832
60.958
61.069
61.168
61.256
61.335
61.405
61.469
61.527
61.579
61.627
61.670
61.710
61.746
61.780
61.811
61.839
61.865
61.890
61.912
61.933
61.953
61.971
61.988
62.004
62.019
62.033
62.046
62.059
62.070
62.081
62.092
62.102
62.111
62.120
62.128
62.136
62.143
62.151
62.157
ХЛОРИД ДИУГЛЕРОДА С2С1
К°.(Т) = р2(С) • р(С1) • Р~\С2С1)
Ф°(Г)
Дж • К . моль
170.421
191.908
205.676
205.900
216.695
225.606
233.241
239.948
245.944
251.376
256.347
260.933
265.192
269.171
272.905
276.424
279.750
282.906
285.907
288.770
291.505
294.124
296.637
299.052
301.376
303.617
305.779
307.869
309.890
311.848
313.746
315.588
317.376
319.115
320.807
322.454
324.058
325.622
327.147
328.637
330.091
331.512
332.902
334.261
335.591
336.893
338.169
339.419
340.645
341.847
343.026
344.183
345.319
346.435
347.531
348.608
349.667
350.708
351.733
352.740
353.732
S°(T)
1
200.071
224.832
241.833
242.112
255.562
266.606
276.004
284.206
291.493
298.054
304.021
309.493
314.544
319.233
323.608
327.706
331.561
335.198
338.640
341.908
345.017
347.981
350.814
353.526
356.128
358.626
361.030
363.347
365.581
367.739
369.826
371.846
373.803
375.701
377.544
379.334
381.075
382.769
384.419
386.026
387.593
389.122
390.615
392.073
393.498
394.891
396.254
397.588
398.894
400.173
401.427
402.657
403.862
405.045
406.206
407.346
408.465
409.565
410.646
411.708
412.753
v
Я°(Г)-Я°@)
кДж • моль
2.965
6.585
10.780
10.864
15.547
20.500
25.658
30.980
36.439
42.010
47.675
53.416
59.222
65.080
70.983
76.924
82.897
88.897
94.920
100.963
107.024
113.100
119.190
125.291
131.403
137.524
143.654
149.791
155.935
162.085
168.240
174.400
180.565
186.734
192.907
199.083
205.263
211.445
217.631
223.818
230.008
236.201
242.395
248.591
254.789
260.989
267.190
273.392
279.596
285.802
292.008
298.216
304.424
310.634
316.845
323.056
329.269
335.482
341.696
347.911
354.126
(г)
г°@)= 1051.990 кДж-моль
-540.4432
-264.3934
-173.3059
-172.1602
-125.9604
-98.1984
-79.6663
-66.4141
-56.4652
-48.7206
-42.5204
-37.4443
-33.2119
-29.6288
-26.5563
-23.8924
-21.5607
-19.5027
-17.6728
-16.0351
-14.5608
-13.2266
-12.0133
-10.9054
-9.8895
-8.9548
-8.0917
-7.2924
R eef\f\
-О.5500
-5.8586
-5.2132
-4.6092
-4.0429
-3.5107
-3.0097
-2.5372
-2.0908
-1.6684
-1.2681
-.8882
-.5272'
-.1836
.1437
.4558
.7539
1.0389
1.3116
1.5728
1.8232
2.0634
2.2942
2.5160
2.7294
2.9348
3.1327
3.3234
3.5075
3.6851
3.8568
4.0226
4.1831
Т
К
100
200
298.15
300
400
500
600
700
800
900 -
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
.2000
2100
2200
2300
2400
2500
2600
2700
лвии
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 305
1
§
1 X
Й • Т
О * Л
* i
ji о
сз on **
в Я ¦
О )*? •
° %
$ f g «
Л о оо ^
^ b" (N
С "I "
й Ч,
^ о"
Э; 0
+
7
о
00 *"*
+ — ¦
о ¦ Ь4
g n S
S s v
ч ^ V
? "о ®
+ 1
(N4 Ь"
"О 00
Г- —ч II
00 Tt"
VO *О ^
II +
о
©
94

Класс точности
VI-С,
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
42.956
58.012
65.373
65.475
69.886
72.900
75.182
77.006
78:498
79.728
80.746
81.593
82.300
82.893
83.394
83.818
84.181
84.492
84.761
84.994
85.198
85.377
85.534
85.673
85.797
85.908
86.007
86.096
86.176
86.249
86.315
86.375
86.430
86.480
86.526
86.568
86.607
86.643
86.676
86.707
86.735
86.762
86.787
86.810
86.832
86.852
86.871
86.889
86.905
86.921
86.936
86.950
86.963
86.975
86.987
86.998
87.009
87.019
87.029
87.038
87.046
К°(Т)=р2(С)р
Ф°(Г)
Дж ¦ К . моль
178.681
204.809
223.054
223.357
238.144
250.535
261.236
270.676
279.135
286.807
293.831
300.314
306.334
311.957
317.232
322.201
326.899
331.353
335.589
339.627
343.485
347.178
350.721
354.124
357.399
360.555
363.601
366.544
369.390
372.146
374.818
377.410
379.927
382.373
384.753
387.069
389.325
391.525
393.670
395.764
397.808
399.806
401.759
4U3.670
405.539
407.369
409.162
410.918
412.640
414.328
415.984
417.610
419.206
420.773
422.312
423.825
425.312
426.774
428.212
429.627
431.019
ДИХЛОРАЦЕТИЛЕН С2С12
2(С1)-/Г'(С2С12) АгН°
S°(T)
1
212.291
247.315
271.996
272.401
291.888
307.824
321.325
333.057
343.440
352.759
361.214
368.950
376.081
382.693
388.855
394.623
400.045
405.157
409.995
414.584
418.949
423.110
427.086
430.891
434.540
438.044
441.416
444.663
447.796
450.821
453.746
456.578
459.321
461.981
464.563
467.072
469.512
47Г.885
474.196
476.448
478.644
480.786
482.877
484.919
486.915
488.867
490.776
492.644
494.474
496.266
498.022
499.744
501.432
503.089
504.715
506.311
507.879
509.419
510.932
512.420
513.883
#°(Г)-Я°@)
кДж . моль
3.361
8.501
14.592
14.713
21.497
28.645
36.053
43.666
51.444
59.357
67.382
75.500
83.696
91.957
100.272
108.633
117.033
125.467
133.930
142.418
150.928
159.457
168.003
176.563
185.137
193.722
202.318
210.923
219.537
228.158
236.787
245.421
254.061
262.707
271.357
280.012
288.671
297.333
305.999
314.668
323.340
332.015
340.693
349.372
358.055
366.739
375.425
384.113
392.803
401.494
410.187
418.881
427.577
436.274
444.972
453.671
462.372
471.073
479.775
488.479
497.183
(г)
@)= 1464.922
о
-750.2304
-365.8248
-239.0326
-237.4381
-173.1542
-134.5396
-108.7714
-90.3504
-76.5253
-65.7665
-57.1555
-50.1076
-44.2327
-39.2606
-34.9981
-31.3035
-28.0704
-25.2176
-22.6818
-20.4128
-18.3709
-16.5235
-14.8441
-13.3108
-11.9054
-10.6126
-9.4192
-8.3144
-7.2885
-6.3335
-5.4422
-4.6084
-3.8268
-3.0926
-2.4017
-1.7502
-1.1350
-.5530
-.0017
.5214
1.0183
1.4909
1.9410
2.3702
2.7799
3.1714
3.5459
3.9044
4.2481
4.5777
4.8941
5.1981
5.4905
5.7718
6.0428
6.3039
6.5556
6.7986
7.0332
7.2599
7.4790
кДж ¦ моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4ГО0
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
т
Л
К
О
ОО
ОС О*\
fN •—*
о\ ,—.
II °„
О
В
о
4;
<
+
'х
ГЧ
X
гч
о
О
О
1
*
00 Г
о
о
00
+
00
ГЧ
v>
II
0
б л и
-
'л
о
. 7
а
о
о
о
о
о
II
я
!2
оо'
ГЧ
с
п
С
и
о"^
ч.
<1
1
*°.
+
?s
г~~
1
m
о
ГО
+
ца 306
1
¦
i^i
гл
го
11
Н
о В!
^-.
О
О
V
V
О
Т.
1
о
7
95

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
'3000
<3!00
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
45.589
64.105
76.031
76.213
84.323
89.928
93.906
96.792
98.929
100.541
101.780
102.748
103.515
104.133
104.636
105.05.1
105.397
105.688
105.935
106.146
106.328
106.485
106.623
106.744
106.850
106.945
107.029
107.104
107.172
107.233
107.288
107.338
107.383
107.424
107.462
107.497
107.529
107.558
107.586
107.611
107.634
107.656
107.676
107.695
107.712
107.728
107.744
107.758
107.772
107.784
107.796
107.807
107.818
107.828
107.837
107.846
107.855
107.863
107.871
107.878
107.885
ТРИХЛОРИД ДИУГЛЕРОДА С
K°G-)=P2(C)-F
Ф°(Л
Дж ¦ К ¦ моль
225.508
253.904
273.882
274.217.
290.772
304.940
317.394
328.531
338.617
347.837
356.332
364.209
371.553
378.431
384.899
391.003
396.782
402.269
407.492
412.475
417.239
421.803
426.183
430.392
434.444
438.350
442.120
445.763
449.288
452.702
456.011
459.222
462.341
465.373
468.321
471.192
473.989
476.715
479.374
481.970
484.504
486.981
489.402
491.770
494.088
496.357
498.579
500.756
502.891
504.984
507.038
509.053
511.032
512.975
514.884
516.759
518.602
520.415
522.198
523.952
525.678
2C13 (г)
3(С1)-р~1(С2С13) ДгЯ°@)= 1591.230
S°(T)
i
262.350
300.069
328.049
328.520
351.630
371.085
387.852
402.556
415.627
427.377
438.037
447.785
456.759
465.070
472.806
480.040
486.831
493.230
499.278
505.011
510.461
515.652
520.609
525.352
529.897
534.260
538.457
542.497
546.394
550.156
553.792
557.311
560.719
564.024
567.232
570.347
573.376
576.323
579.192
581.987
584.711
587.369
589.964
592.497
594.974
597.394
599.762
602.080
604.348
606.571
608.748
610.883
612.977
615.030
617.046
619.025
620.968
622.877
624.753
626.597
628.411
Я°(Г)-Я°@)
кДж • моль"
3.684
9.233
16.150
16.291
24.343
33.072
42.275
51.817
61.609
71.5в6
81.704
91.933
102.247
112.631
123.070
133.555
144.078
154.633
165.214
175.818
186.442
197.083
207.739
218.407
229.087
239.777
250.476
261.182
271.896
282.616
293.342
304.074
314.810
325.550
336.295
347.043
357.794
368.548
379.306
390.065
400.828
411.592
422.359
433.127
443.898
454.670
4,65.443
476.218
486.995
497.773
508.552
519.332
530.113
540.895
551.679
562.463
573.248
584.034
594.820
605.608
616.396
\gK°(T)
-812.3173
-394.2893
-256.2918
-254.5558
-184.5482
-142.4775
-114.3950
-94.3159
-79.2444
-67.5145
-58.1258
-50.4410
-44.0350
-38.6132
-33.9651
-29.9362
-26.4105
-23.2994
-20.5340
-18.0596
-15.8326
-13.8178
-11.9863
-10.3140
-8.7812
-7.3711
-6.0696
-4.8645
-3.7456
-2.7039
-1.7317
-.8223
.0302
.8311
1.5848
2.2954
2.9665
3.6013
4.2027
4.7732
5.3152
5.8308
6.3218
6.7900
7.2369
7.6640
8.0725
8.4636
8.8384
9.1980
9.5431
9.8748
10.1937
10.5006
10.7961
11.0809
11.3556
11.6206
11.8765
12.1238
12.3628
кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
700
- 800
900
1000
1100
1200
1300
1400
1500
160С
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
i
л
к
о
о
о
Я 2
* i
г \
С»
о
О
<
+
о
i т
СЧ О
+ А
^ *ч *
'к '^
о »
¦ч- х
Я Ч
о пн
о °^
W О)
1 VO
н ^
? +
о о
' 00
й г-'
о ^
+ 1
—с X
О ОО
\о *о
~< V)
* 1Л
VO •
so о
II +
g
о
в1
л
¦з
о
ОО
о
II
»п
00
О\
гч
(_Г
С)
и
П
307
0ЛЬ~
— ¦
'а
ГЛ
IO
О**
¦»
о Я
§
о
о
*о
V
f~,
V
о
о
<»
о
к
II
96

Класс точности
VI-D
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
55.080
80.123
94.919
95.141
105.036
111.817
116.580
120.000
122.511
124.391
125.828
126.945
127.828
128.537
129.113
129.587
129.982
130.313
130.594
130.834
131.040
131.219
131.376
131.513
131.633
131.740
131.836
131.921
131.997
132.066
132.128
132.185
132.236
132.283
132.326
132.365
132.401
132.434
132.465
132.493
132.519
132.544
132.567
132.588
132.607
132.626
132.643
132.659
132.675
132.689
132.702
132.715
132.727
132.738
132.749
132.759
132.769
132.778
132.786
132.794
132.802
К°(Т)=р\с)-р
Ф°(Г)
— 1 -¦
Дж ¦ К ¦ моль
218.437
251.146
275.164
275.572
295.772
313.169
328.507
342.247
354.699
366.088
376.584
386.317
395.391
403.889
411.880
419.420
426.558
433.335
439.785
445.938
451.820
457.454
462.860
468.055
473.056
477.876
482.528
487.024
491.373
495.584
499.667
503.623
507.475
511.214
514.852
518.392
521.841
525.203
528.482
531.682
534.807
537.861
540.846
543.766
546.623
549.420
552.159
554.844
557.475
560.055
562.587
565.071
567.509
669:904
572.256
574.568
576.840
579.074
581.271
583.432
585.559
ТЕТРАХЛОРЭТИЛЕН С2С14
\ci)-p~\c2cu) . Дгя°
S°(T)
1
259303
305.956
340.921
341.509
370.327
394.540
415.372
433.614
449.809
464.353
477.536
489.584
500.669
510.930
520.477
529.402
537.778
545.668
553.125
560.192
566.909
573.307
579.414
585.257
590.857
596.233
601.402
606.379
611.178
615.811
620.289
624.623
628.820
632.890
633.840
640.676
644.406
648.034
651.566
655.007
658.362
661.634
664.829
667.948
670.997
673.977
676.892
679.745
682.538
685.274
687.955
690.583
693.160
695.688
698.169
700.605
702.997
705.348
707.657
709.927
712.159
Н°(Г)-И°@)
кДж • моль
4.087
10.962
19.605
19.781
29.822
40.685
52.119
63.957
76.089
88.438
100.952
113.593
126.333
139.153
152.036
164.972
177.951
190.966
204.012
217.084
230.178
243.291
256.421
269.565
282.723
295.892
309.070
322.258
335.454
348.658
361.867
375.083
388.304
401.530
414.769
427.995
441.233
454.475
467.720
480.968
494.219
507.472
520.727
533.985
547.245
560.507
/ 573.770
587.035
боезо:
613.570
626.840
640.111
653.383
666.656
679.930
693.205
706.482
719.759
733.037
746.317
759.596
(г)
@)= 1910.995
о
-972.6389
-470.5702
-304.8557
-302.7709
-218.7168
-168.2133
-134.5075
-110.4115
-92.3278
-78.2558
-66.9943
-57.7781
-50.0967
¦43.5965
-38.0248
-33.1961
¦28.9712
-25.2439
-21.9310
-18.9674
-16.3006
-13.8883
-11.6957
-9.6943
-7.8600
-6.1729
-4.6159
-3.1745
¦ 1.8365
-.5910
.5711
1.6580
2.6768
3.6335
4.5338
5.3825
6.1838
6.9416
7.6594
8.3402
8.9869
9.6019
10.1875
10.7457
11.2784
11.7874
12.2742
12.740!
13.18S6
13.6148
14.0257
14.4205
14.8000
15.1652
15.5167
15.8555
16.1820
16.4971
16.8012
17.0950
17.3790
кДж ¦ моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
§
ОО j
11 с
и
о
<3
-
ч- м
г! В
г*1 О
+ 2
'к '
1 "*
1 сч
J5 ¦*¦
!? о
Г-1
о- *
f—4 *¦"*
+¦ '
*О Н
Ct\ ОО
О\ СО
CJ\ 1—ч
ь
о
в
i
О
о
о
о
II
2
^'
t>
-?
у
0
<3
308
'л
§
2
—'
¦
R
VO
VJD
чо
II
0 3
to
я
о
V
к.
V
8
'о
sC
ii
97

Класс точности
VII-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
ПЕНТАХЛОРЭТИЛ С2С15 (г)
К G") = р (С) • р (С1) • р (C2G
S°{T)
Дж.К-'.моль
67.348
99.140
118.786
119.079
131.498
138.872
143.335
146.150
148.001
149.267
150.165
150.824
151.333
151.721
152.022
152.257
152.444
152.593
152.714
152.811
152.891
153.025
153.090
153.145
153.191
153.231
153.264
153.292
153.375
153.401
153.424
153.444
153.461
153.476
153.490
153.502
153.512
153.521
153.529
153.536
153.542
153.547
153.621
153.628
153.635
153.641
153.646
153.651
153.655
153.659
153.663
153.666
153.669
153.672
153.674
153.676
153.678
153.680
153.682
153.683
153.684
249.192 296.841
288.119 354.298
317.342 397.845
317.841 398.581
342.666 434.678
364.179 464.887
383.168 490.636
400.152 512.958
415.502 532.603
429.516 550.106
442.379 565.883
454.251 580.238
465.324 593.370
475.656 605.492
485.339 616.747
494.449 627.248
503.050 637.088
511.197 646.345
518.935 655.083
526.302 663.357
533.333 671.212
540.122 678.633
546.576 685.757
552.770 692.568
558.725 699.093
564.458 705.353
569.986 711.371
575.322 717.163
580.517 722.710
585.511 728.095
590.348 733.298
595.038 738.332
599.589 743.207
604.009 747.933
608.306 752.519
612.486 756.972
616.556 761.300
620.520 765.510
624.385 769.609
628.156 773.601
631.836 777.493
635.431 781.288
638.986 784.957
642.422 788.573
645.783 792.106
649.072 795.560
652.292 798.938
655.446 802.244
658.537 805.480
661.567 808.650
664.538 811.756
667.454 814.800
670.314 817.785
673.123 820.714
675.881 823.588
678.591 826.410
681.254 829.180
683.872 831.902
686.445 834.576
688.977 837.205
691.467 839.790
s) Д,А
H°(T)-H°@)
кДж - моль
4.765
13.236
24.002
24.222
36.805
50.354
64.481
78.964
93.681
108.532
123.504
138.586
153.655
168.786
183.971
199.198
214.460
229.752
245.067
260.403
275.757
290.874
306.199
321.535
336.882
352.237
367.600
382.970
А^\Л 4 A^V
398.139
413.492
428.850
444.213
459.580
474.950
490.324
505.701
521.081
536.464
551.848
567.236
582.625
598.016
613.076
628.447
643.820
659.195
674.570
689.948
705.326
720.705
736.086
751.467
766.849
782.232
797.616
813.001
828.387
843.773
859.160
874.547
889.935
г°@) = 1979.978 кДж • моль
Т
К
-1003.9440 100
-483.4306 200
-311.6205 298.15
-309.4592 300
-222.3258 400
-169.9854 500
-135.0626 600
-110.1021 700
-91.3731 800
-76.8022 900
-65.1424 1000
-55.6004 1100
-47.6501 1200
-40.9224 1300
-35.1556 1400
-30.1579 1500
-25.7851 1600
-21.9272 1700
-18.4983 1800
-15.4309 1900
-12.6706 2000
-10.1770 2100
-7.9081 2200
-5.8369 2300
-3.9387 2400
-2.1928 2500
-.5815 2600
.9101 2700
2.2928 2800
3.5815 2900
4.7840 3000
5.9087 3100
6.9629 3200
7.9529 3300
8.8845 3400
9.7627 3500
10.5919 3600
11.3761 3700
12.1189 3800
12.8235 3900
13.4927 4000
14.1291 4100
14.7328 4200
15.3104 4300
15.8617 4400
16.3883 4500
16,8920 4600
17.3741 4700
17.8361 4800
18.2791 4900
18.7043 5000
19.1128 5100
19.5056 5200
19.8834 5300
20.2472 5400
20.5977 5500
20.9356 5600
21.2616 5700
21.5764 5800
21.8804 5900
22.1742 6000
Таблица 309
-1
_
- 1
¦- ? -
§ и '*
s  §
М о ?
| 8 Т
г*- ч? it ^
<*> о ~ <3
• "* 2С pvj
О " 2 ?
О ^® ^
11 " ?} °°
^ " С
.-ч -
+
о
л,
ГЛ
ч -
+ §
Т S
О "'
1.0191
Дж-
: боос
1 00 К,
X "» . ,
? ^ V
о + 8
in ">
О _><
12 Sj 'о
+ о "
О -Н ||
1Л ГО
г- о
II +
о
98

Класс точности
VII-
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5S00
6000
Е
С°(Т)
76.095
113.868
136.346
136.681
151.138
160.250
166.136
170.078
172.816
174.783
176.237
177.339
178.192
178.866
179.407
179.847
180.210
180.512
180.767
180.984
181.169
181.330
181.469
181.591
181.698
18L792
181.876
181.951
182.019
182.079
182.134
182.183
182.228
182.269
182.306
182.340
182.372
182.401
182.428
182.452
182.475
182.496
182.516
182.534
182.552
182.568
182.582
182.596
182.610
182.622
182.634
182.645
182.655
182.665
182.674
182.683
182.691
!82.699
182.706
182.713
182.720
К°(Т)=р2(С)-р(
Ф°(Г)
Дж ¦ К . моль
232.067
274.689
307.526
308.090
336.252
360.739
382.425
401.882
419.519
435.641
450.484
464.234
477.036
489.012
500.261
510.865
520.894
530.405
539.451
548.072
556.308
564.191
571.751
579.011
585.996
592.724
5Э9.215
605.484
611.547
617.415
623.101
628.617
633.971
639.174
644.233
649.156
653.950
658.622
663.178
667.6S4
671.964
676.203
680.347
684.399
688.364
692.244
696.044
699.766
703.415
706.992
710.501
713.943
717.322
720.640
723.899
727.10!
730.248
733.342
736.384
739.376
742.321
ГЕКСАХЛОРЭТАН С2
\С1)-р~1(С2С16) Лг
S°(T)
1
282:913
348.536
398.517
399.361
440.822
475.603
505.378
531.303
554.203
574.677
593.172
610.023
625.491
639.782
653.058
665.451
677.070
688.005
698.330
708.110
717.398
726.241
734.680
742.749
750.480
757.899
765.031
771.896
778.515
784.903
791.077
797.050
802.834
808.443
813.884
819.169
824.307
829.304
834.168
838.907
843.527
848.033
852.431
856.726
860.923
865.025
869.038
872.965
876.809
880.575
884.264
887.881
891.428
894.907
898.321
901.673
904.965
908.199
911.376
914.500
917.571
Я°(Л-Я°@]
кДж . моль
5.085
14.769
27.129
27.381
41.828
57.432
73.772
90.595
107.747
125.132
142.687
160.368
178.146
196.001
213.915
231.879
249.882
267,919
285.983
304.071
322.179
340.304
358.444
376.597
394.762
412.936
431.120
449.311
467.510
485.715
503.925
522.141
540.362
558.587
576.816
595.048
613.284
631.522
649.764
668.008
686.254
704.503
722.753
741.006
759.260
777.516
795.774
8! 4.033
832.293
850.554
868.817
887.081
905.346х
923.612
941.879
960.147
978.416
996.685
1014.956
1033.227
1051.498
С16 (г)
Я°@)= 2279
о
-1152.9459
-553.7570
-355.9838
-353.4963
-253.1995
-192.9528
-152.7567
-124.0296
-102.4769
-85.7107
-72.2970
-61.3227
-52.1787
-44.4431
-37.8144
-32.0713
-27.0479
-22.6173
-18.6806
-15.1599
-11.9927
-9.1286
-6.5261
-4.1512
-1.9753
.0255
1.8713
3.5796
5.1649
S.6401
8.0162
9.3028
10.5083
11.6402
12.7049
13.7082
14.6553
15.5507
16.3985
17.2024
17.9657
•18.6914
19.3822
20.0405
20.6685
21.2683
21.8418
22.3905
22.9161
23.4200
23.9036
24.3679
24.8141
25.2433
25.6563
26.0542
26.4376
26.8074
27.1643
27.5089
27.8419
.079 кДж • моль"'
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
'л
п
оо
ON
о m
***. 1
II °„
В
О
Н
Г-
"* "л
¦*' о
+ I
ч ^
о
§ t§
о "м
о
»5 ¦+•
ЧЭ <N
ГО X
00 О
г- о
О\ О
ЧО ГЧ
00 *н
II +
,_^
f-^
о
©
о
о
о
_'
2!
I
и
Я
со
г^
О
0
<г
а 310
'л
к
о
-¦
<*.
II
0 К
И)
2
О
8
V
(-*
V
о
о
»'"
'о
^.
I!
99

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
35.882
41.634
45.072
45.120
47.265
48.908
50.301
51.488
52.484
53.312
53.996
54.560
55.028
55.417
55.743
56.018
56.251
56.450
56.622
56.771
56.901
57.016
57.118 '
57.210
57.294
57.371
57.443
57.512
57.578
57.642
57.706
57.769
57.833
57.897
57.963
58.030
58.099
58.169
58.241
58.315
58.391
58.468
58.547
58.628
58.710
58.793
58.877
58.962
59.047
59.133
59.220
59.306
59.392
59.478
59.564
59.649
59.733
59.816
59.898
59.979
60.059
ОКСВД-ХЛОРИД
К°(Т)= p(Cl)i
Ф°(Т)
Дж . К . моль"
187.131
211.354
226.340
226.580
238.003
247.240
255.036
261.807
267.807
273.204
278.115
282.625
286.796
290.680
294.313
297.727
300.948
303.997
306.892
309.648
312.277
314.792
317.202
319.514
321.738
323.880
325.945
327.939
329.866
331.732
333.539
335.292
336.994
338.647
340.255
341.819
343.343
344.828
346.276
347.689
349.069
350.417
351.735
353.024
354.265
355.520
356.730
357.916
359.078
360.218
361.336
362.434
363.512
364.571
365.611
366.634
367.639
368.628
369.601
370.559
371.501
э(С)-р(О)-р~
S°(T)
1
221.007
247.752
265.081
265.360
278.652
289.381
298.425
306.270
313.213
319.444
325.097
330.271
335.039
339.459
343.579
347.434
351.057
354.473
357.705
360.770
363.686
366.465
369.120
371.661
374.097
376.438
378.689
380.858
ЛАА Л С 1
382.951
384.973
386.928
388.821
390.656
392.437
394.166
395.848
397.483
399.076
400.628
402.142
403.619
405.062
406.472
407.851
409.199
410.520
411.813
413.080
414.322
415.541
416.736
417.910
419.062
420.194
421.307
422.400
423.476
424.534
425.575
426.600
427.608
УГЛЕРОДА
'(С1СО) Д
П \1 }—П \
кДж . моль
3.388
7.280
11.551
11.634
16.260
21.071
26.033
31.124
36.324
41.615
46.982
52.411
57.891
63.414
68.972
74.560
80.174
85.809
91.463
97.133
102.817
108.513
114.220
119.936
125.661
131.395
137.135
142.883
148.638
154.399
160.166
165.940
171.720
177.507
183.300
189.099
194.906
200.719
206.539
212.367
218.203
224.045
229.896
235.755
241.622
247.497
253.380
259.272
265.173
271.082
277.000
282.926
288.861
294.804
300.756
306.717
312.686
318.664
324.649
330.643
336.645
С1СО (г)
гЯ»=.1О95
0)
-'
о
-563.7317
-276.5722
-181.8269
-180.6350
-132.5789
-103.6986
-84.4172
-70.6266
-60.2715
-52.2088
-45.7524
-40.4651
-36.0554
-32.3212
-29.1182
-26.3403
-23.9080
-21.7606
-19.8506
-18.1407
-16.6008
-15.2069
-13.9390
-12.7807
-11.7184
-10.7405
-9.8374
-9.0008
-8.2235
-7.4994
-6.8233
-6.1904
-5.5968
-5.0389
-4.5135
-4.0179
-3.5495
-3.1062
-2.6860
-2.2872
-1.9081
-1.5473
-1.2035
-.8754
-.5622
-.2627
.0240
.2986
.5619
.8146
1.0574
1.2907
1.5152
1.7314
1.9396
2.1404
2.3341
2.5212
2.7019
2.8765
3.0455
.158 кДж -моль
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
-1
"_„
к
о
si
о
¦ч- "")-
чо -Г
"*. '
го II
II
О
0
<
__+
1^
§ 'й
3 1
о
о Ч
оо m
О О\
1 2
с +
f "к
2 —.
"+ 1
чо Ч
00 (N
cv .о
ос о>
гл ~^
II +
0
©
i
л
с;
0
кДж
о
о
о
\6
~
II
я
00
'—
о"
О
D
о
ц а 311
-
i
л
§
1
—
и
О X
со
?
о
о
чО
V
f-
V
о
о
'о
к.
II
и
100

Класс точности
VI-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
D
С°(Т)
Р
36.550
48.432
57.761
57.900
63.986
68.103
71.074
73.301
75.008
76.336
77.383
78.219
78.893
79.443
79.897
80.274
80.592
80.860
81.090
81.287
81.458
81.606
81.736
81.851
81.952
82.042
82.122
82.194
82.259
82.317
82.370
82.418
82.461
82.501
82.538
82.571
82.602
82.630
82.657
82.681
82.703
82.724
82.744
82.762
82.779
82.795
82.810
82.824
82.837
82.849
82.861
82.871
82.882
82.891
82.901
82.909
82.918
82.925
82.933
82.940
82.947
к-(г,.Лс>.
Ф°(Г)
— 1 —
Дж . К ¦ моль
199.570
224.258
240.445
240.712
253.796
264.861
274.516
283.110
290.866
297.943
304.454
310.485
316.105
321.366
326.312
330.980
335.398
339.594
343.588
347.398
351.041
354.532
357.881
361.102
364.202
367.191
370.076
372.864
375.562
378.175
380.709
383.167
385.556
387.877
390.136
392.334
394.477
396.565
398.602
400.591
402.533
404.431
406.287
408.102
409.878
411.617
413.321
414.990
416.627
418.232
419.806
421.352
422.869
424.359
425.822
427.261
428.675
430.065
431.432
432.778
434.102
ФОСГЕН С12СО (г)
р(С)-р(О)-р"'(С12СО) ДГА
S°(T)
1
Я°(Г>-Я°@)
кДж . моль
233.533 3.396
262.433 7.635
283.639 12.878
283.997 12.985
301.550 19.;01
316.297 25.718
328.990 32.684
340.121 39.908
350.026 47.327
358.940 54.897
367.039 62.585
374.455 70.367
381.291 78.223
387.628 86.141
393.533 94.109
399.058 102.118
404.250 110.162
409.144 118.235
413.772 126.333
418.162 134.452
422.336 142.589
426.314 150.742
430.113 158.910
433.749 167.089
437.235 175.279
440.582 183.479
443.801 191.687
446.902 199.903
449.892 208.126
452.780 216.355
455.572 224.589
458.273 232.828
460.891 241.072
463.429 249.321
465.892 257.572
468.285 265.828
470.612 274.087
472.875 282.348
475.080 290.612
477.227 298.880
479.320 307.149
481.363 315.420
483.357 323.694
485.304 331.969
487.207 340.246
489.067 348.525
490.887 356.805
492.668 365.086
494.412 373.370
496.120 381.654
497.794 389.939
499.435 398.226
501.044 406.514
502.623 414.802
504.172 423.092
. 505.694 431.382
507.188 439.674
508.655 447.966
510.098 456.259
51.1.516 464.552
512.910 472.847
Г°@)= 1415.015 кДж- моль
Г
К
-725.1205 100
-353.6955 200
-231.0765 298.15
-229.5338 300
-167.3233 400
-129.9348 500
-104.9747 600
-87.1254 700
¦73.7253 800
¦63.2944 900
-54.9436 1000
-48.1070 1100
-42.4068 1200
-37.5813 1300
-33.4434 1400
-29.8560 1500
-26.7159 1600
-23.9445 1700
-21.4803 1800
-19.2750 1900
-17.2898 2000
-15.4933 2100
-13.8598 2200
-12.3680 2300
-11.0003 2400
-9.7418 2500
-8.5800 2600
-7.5040 2700
-6.5047 2800
-5.5742 2900
-4.7056 3000
-3.8929 3100
-3.1308 3200
-2.4149 3300
-1.7409 3400
-1.1053 3500
-.5050 3600
.0630 3700
.6013 3800
1.1120 3900
1.5972 4000
2.0589 4100
2.4987 4200
2.9181 4300
3.3186 4400
3.7013 4500
4.0675 4600
4.4181 4700
4.7543 4800
5.0767 4900
5.3864 5000
5.6840 5100
5.9702 5200
6.2457 5300
6.5111 5400
6.7669 5500
7.0136 5600
7.2517 5700
7.4817 5800
7.7039 5900
7.9188 6000
Т а б л и ц а 312
-1
1
л
7 |
л *
с;
i *
 'л
л <=> §
1 Ц i
о ~^ "Г
ОО <N t^
°i II ^ >?>
ОО Хч ОО
° °^ r-i
11 С Я m
О t-" ii
* -?* ^
о {j
5: o"
+
V
oo 'Л
 О
+ „¦
"к '*
2 e| 8
is v
« V
c S
00 . ¦
\0 O-y О
+ 1 *
—< X ^
OO Tf "
\O ЧО w
^ о о
II +
у—-
к
о
А
101

Класс точности
IN -F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
33.267
34.184
36.733
36.788
39.648
42.069
44.032
45.662
47.058
48.277
49.360
50.335
51.230
52.068
52.871
53.654
54.428
55.201
55.977
56.755
57.532
58.306
59.071
59.820
60.549
61.252
61.924
62.561
63.159
63.716
64.229
64.698
65.122
65.501
65.837
66.129
66.381
66.594
66.770
66.912
67.02!
67.100
67.152
67.179
67.183
67.166
67.131
67.080
67.014
66.936
66.846
66.746
66.639
66.524
66.403
66.278
66.148
66.016
65.881
65.744
65.606
:
ХЛОРМЕТИЛЕН СНС1 (г)
К°(Т) = р(С) • р(Н) ¦ р(С1) ¦ р'\(.
Ф°(Т)
— 1 ~
Дж ¦ К . моль
164.192
187.269
200.713
200.924
210.864
218.823
225.538
231.385
236.588
241.290
245.588
249.554
253.240
256.689
259.931
262.992
265.895
268.656
271.29!
273.812
276.23!
278.556
280.796
282.958
285.048
287.072
289.035
290.941
292.793
294.595
296.350
298.061
299.730
301.360
302.952
304.509
306.032
307.522
308.981
310.411
311.812
313.185
314.532
315.853
317.150
318.424
319.674
320.902
322.109
323.295
324.460
325.607
326.734
327.843
328.934
330.008
331.065
332.106
333.131
334.140
335.134
1
197.450
220.678
234.771
234.998
245.980
255.096
262.946
269.860
276.050
281.665
286.808
291.559
295.978
300.112
304.000
307.675
31 1.162
314.485
317.662
320.709
323.640
326.466
329.196
331.839
334.400
336.886
339.301
341.651
343.937
346.163
348.332
350.445
352.507
354.516
356.477
358.390
360.256
362.078
363.856
365.592
367.288
368.944
370.561
372.142
373.686
375.196
376.672
378.115
379.527
380.908
382.259
383.582
384.877
386.145
387.388
388.605
389.798
390.968
392.115
393.240
394.343
НС!) Aftf°@)= 73S.839
Я°(Г)-Я°@)
кДж . моль
3.326
6.682
10.154
10.222
14.046
18.137
22.44с
26.932
31.570
36.338
41.221
46.206
51.285
56.450
61.697
67.024
72.428
77.909
83.468
89.105
94.819
100.611
106.480
112.425
118.443
124.534
130.693
136.917
143.204
149.548
155.945
162.392
168.883
175.415
181.982
188.580
195.206
201.856
208.524
215.208
221.905
228,612
235.324
242.041
248.759
255.477
262.! 92
268.903
275.607
282.305
288.994
295.674
302.343
309.001
315.648
322.282
328.903
335.511
342.106
348.687
355.255
-378.6418
-184.5438
-120.3917
-1 19.5839
-86.9850
-67.3609
-54.2390
-44.8408
-37.7746
-32.2662
-27.8504
¦24.2305
-21.2087
-18.6477
-16.4492
-14.5413
¦12.8697
-11.3931
¦10.0793
-8.9026
-7.8427
-6.8831
-6.0102
-5.2128
-4.4815
-3.8085
-3.1871
-2.6116
-2.0772
-1.5796
-1.1 152
-.6808
-.2737
.1088
.4686
.8078
1.1280
1.4309
1.7176
1.9896
2.2479
2.4935
2.7274
2.9502
3.1629
3.3660
3.5602
3.7461
3.9242
4.0949
4.2588
4.4162
4.5675
4.7131
4.8532
4.9882
5.1184
5.2439
5.3651
5.4822
5.5954
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 313
-
А
- О
1 S
* 1
S о 2
^~5 ^ ,-i*
§ § '«
о ^ 1
_ оо " Д
t— О ,—, ^
оо " ? 5
И „ О\ <^>
У -" "и
о У ° *
w X с^а
о U
а; о
"-. а;
_+
ч
гч —
О\ 1
+
""> * О
О m °
§ g v
1 >
с Т ^
гч °° •<-
m °*' °
+ 1 7
¦ф X (-.
¦* —1 II
II +
ъ.
0
в
102

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
34.172
38.548
43.172
43.260
47.845
51.887
55.349
58.351
60.994
63.337
65.413
67.248
68.865
70.287
71.537
72.635
73.600
74.451
75.203
75.868
76.459
76.984
77.454
77.874
78.252
78.592
78.899
79.177
79.430
79.660
79.870
80.062
80.238
80.400
80.549
80.686
80.813
80.930
81.039
81.141
81.235
81.323
81.405
81.481
81.553
81.621
81.684
81.743
81.799
81.852
81.901
81.948
81.992
82.034
82.074
82.111
82.147
82.181
82.213
82.244
82.273
К°(Т) = р(С)-р2п
Ф° (Т)
Дж ¦ К • моль
168.569
192.111
206.386
206.613
217.516
226.464
234.164
240.985
247.145
252.784
258.000
262.863
267.425
271.727
275.800
279.672
283.362
286.889
290.267
293.510
296.628
299.632
302.528
305.327
308.033
310.652
313.192
315.656
318.048
320.373
322.635
324.837
326.982
329.073
331.113
333.103
335.048
336.947
338.805
340.622
342.400
344.140
345.846
347.516
349.154
350.761
352.337
353.884
355.402
356.893
358.359
359.798
361.214
362.605
363.974
365.320
366.646
367.950
369.235
370.499
371.745
ХЛОРМЕТИЛ СН2С1 (г)
i)-p(Cl)-p~\
201.986
226.963
243.212
243.479
256.562
267.684
277.458
286.220
294.188
301.510
308.293.
314.615
320.537
326.107
331.363
336.336
341.056
345.544
349.821
353.905
357.812
361.555
365.148
368.600
371.923
375.124
378.212
381.196
384.080
386.871
389.575
392.197
394.742
397.214
399.616
401.953
404.228
406.443
408.603
410.709
412.765
414.772
416.733
418.649
420.523
422.357
424.151
425.909
427.630
429.317
430.971
432.594
434.185
435.748
437.281
438.788
440.268
441.722
443.152
444.557
445.940
СН2С1) АгНс
Я°(Г)-Я°@)
кДж ¦ моль
3.342
6.970
10.980
11.060
15.618
20.610
25.976
31.664
37.634
43.853
50.293
56.928
63.735
70.694
77.787
84.997
92.309
99.713
107.196
114.751
122.367
130.040
137.762
145.529
153.336
161.178
169.053
176.957
184.888
192.842
200.819
208.816
216.831
224.863
232.910
240.972
249.047
257.134
265.233
273.342
281.461
289.589
297.725
305.870
314.021
322.180
330.345
338.517
346.694
354.876
363.064
371.256
379.454
387.655
395.860
404.069
412.283
420.499
428.719
436.942
445.167
@)= 1142.873
о
-586.1989
-285.8510
-186.5714
-185.3213
-134.8735
-104.5066
-84.2035
-69.6639
-58.7341
-50.2157
-43.3885
-37.7934
-33.1240
-29.1678
-25.7728
-22.8273
-20.2474
-17.9691
-15.9424
-14.1276
-12.4932
-11.0135
-9.6676
-8.4381
-7.3104
-6.2725
-5.3139
-4.4260
-3.6012
-2.8329
-2.1156
-1.4444
-.8148
-.2232
.3338
.8591
1.3554
1.8250
2.2701
2.6925
3.0938
3.4757
3.8396
4.1866
4.5179
4.8346
5.1376
5.4278
5.7060
5.9730
6.2293
6.4756
6.7125
6.9406
7.1603
7.3720
7.5762
7.7734
7.9638
8.1477
8.3256
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
470G
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б
оль"
2
Ч
о
о
00 О
г- ~*
¦* II
¦* о
и С
я
¦ и
+
\j I
?\ 1
m g
2 о
¦ч-
—< 7
н
§; "Ys
О ffj
1 m
е м
о
т-Н V4
5 2
CN 00
00 CN
Г- Г^
V) <Ч
[-- т—
VI О
ГО <-Н
и +
V
0
А
лица
'л
к
о
2
Л
1
•
II
??
00*
fN
ьГ
и
я
У-
314
—
'л
о
V
Л
Jo
00*
о g
1
V /
V
*"*
V
о
о
«о
1
о
II
103

Класс точности
V-C
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
50СК?
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ер)
33.284
35.155
40.740
40.869
48.173
55.171
61.320
66.650
71.293
75.354
78.909
82.018
84.735
87.108
89.181
90.996
92.586
93.983
95.214
96.301
97.265
98.122
98.886
99.570
100.183
100.735
101.233
101.684
102.094
102.466
102.806
103.116
103.401
103.662
103.903
104.125
104.330
104.520
104.696
104.859
105.011
105.153
105.286
105.409
105.525
105.634
105.735
105.831
105.921
106.006
106 086
106.162
106.233
106.300
106.364
106.425
106.482
106.537
106.589
106.638
106.685
Ф°(Г)
Дж ¦ К . моль
162.620
185.728
199.349
199.566
209.935
218.573
226.174
233.064
239.423
245.360
250.947
256.236
261.265
266.064
270.656
275.060
279.294
283.369
287.300
291.094
294.763
298.314
301.755
305.092
308.331
311.478
314.539
317.516
320.416
323.241
325.996
328.683
331.307
333.869
336.373
338.822
341.217
343.561
345.856
348.103
350.306
352.465
354.583
356.660
358.699
360.700
362.665
364.596
366.493
368.358
370.191
371.994
373.768
375.513
377.23!
378.923
380.588
382.228
383.844
385.436
387.006
ХЛОРМЕТАН СН3С1 (г)
'(Н)р(С1)-
S°(T)
1
195.880
219.304
234.285
234.537
247.286
258.802
269.417
279.280
288.490
297.127
305.254
312.924
320.180
327.058
333.591
339.807
345.732
351.387
356.795
361.973
366.937
371.704
376.287
380.698
384.948
389.049
393.010
396.840
400.545
404.134
407.614
410.990
414.268
417.454
420.552
423.568
426.504
429.365
432.154
434.876
437.533
440.128
442.663
445.142
447.567
449.939
452.262
454.537
456.766
458.951
461.094
463.195
465.257
467.282
469.269
471.221
473.140
475.025
476.878
478.701
480.493
р~'(СН3С1) ДгЯ°@)= 1552.851
Я°(Г>-Я°@)
кДж • моль
3.326
6.715
10.416
10.492
14.941
20.114
25.946
32.351
39.253
46.590
54.307
62.357
70.698
79.293
88.109
97.120
106.301
115.631
125.092
134.669
144.348
154.118
163.969
173.893
183.881
193.927
204.026
214.172
224.362
234.590
244.854
255.150
265.476
275.829
286.208
296.609
307.032
317.475
327.936
338.413
348.907
359.416
369.937
380.472
391.019
401.577
412.146
422.724
433.312
443.908
454.513
465.125
475.745
486.372
497.005
507.644
518.290
528.941
539.597
550.258
560.924
-796.3219
-388.1246
-253.1290
-251.4285
-182.7947
-141.4622
-113.8176
-94.0155
-79.1270
-67.5220
-58.2204
-50.5973
-44.2355
-38.8456
-34.2205
-30.2081
-26.6943
-23.5916
-20.8317
-18.3609
-16.1361
-14.1222
-12.2906
-10.6177
-9.0838
-7.6721
-6.3688
-5.1617
-4.0406
-2.9966
-2.0221
-1.1103
-.2554
.5478
1.3038
2.0166
2.6899
3.3269
3.9303
4.5029
5.0468
5.5643
6.0571
6.5270
6.9755
7.4042
7.8142
8.2067
8.5829
8.9438
9.2902
9.6231
9.9431
10.2511
10.5476
10.8334
11.1089
11.3748
11.6315
11.8795
12.1193
кДж ¦ моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та б л
-1
_
'л
с:
о
2
_ ГО
Ч и
U0 о
и с
5 —
о
m
X
о
¦»,
J"
"я "л
00 С
"~> 2
•* _¦
СЧ 1
+
Г*~ ^^
OS 00
г- го
гч го
1 +
ч «„
s s
оо Я
го го
"¦> 1
О\ «О
00 ¦*
го ^*
II +
о
и ца
"л
с:
о
•3
X
00
1
II
%
оо
OS
гч
и"
а
[ 1
W
а;
>^
315
7
5
О
¦-*"
1
.
CTv
О
го
II
0 К
to
Я
О
V
V
§
•о
»'"
'о
II
104

Класс точности
VI -Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
36.673
45.570
52.665
52.784
58.421
62.580
65.672
68.063
¦ 69.990
71.587
72.934
74.082
75.068
75.917
76.651
77.289
77.844
78.330
78.756
79.132
79.464
79.758
80.020
80.254
80.464
80.652
80.822
80.976
81.115
81.242
81.357
81.463
81.559
81.648
81.730
81.805
81.874
81.939
81.998
82.054
82.105
82.153
82.198
82.240
82.279
82.316
82.350
82.383
82.413
82.442
82.469
82.494
82.518
82.541
82.563
82.583
82.603
82.621
82.639
82.655
82.671
К°(Т) = р(С)
Ф°(Г)
ДИХЛОРМЕТИЛ СНС12
•р(Н)р2(С1)-
S°(T)
Дж • К . моль
195.905
220.518
236.264
236.521
248.964
259.364
268.392
276.407
283.637
290.234
296.308
301.941
307.197
312.127
316.769
321.158
325.320
329.280
333.055
336.663
340.119
343.435
346.621
349.690
352.648
355.503
358.263
360.933
363.520
366.029
368.464
370.828
373.128
375.365
377.544
,379.666
381.736
383.755
385.727
387.652
389.534
391.374
393.174
394.936 '
396.662
398.352
400.008
401.632
403.225
404.788
406.323
407.829
409.308
410.762
412.191
413.595
414.976
416.335
417.671
418.987
420.282
229.894
258.155
277.719
278.045
294.041
307.548
319.244
329.554
338.773
347.112
354.726
361.732
368.222
374.265
379.918
385.229
390.235
394.969
399.459
403.728
407.795
411.679
415.396
418.958
422.378
425.667
428.833
431.886
434.834
437.683
440.439
443.108
445.696
448.207
450.646
453.016
455.322
457.566
459.752
461.883
463.960
465.988
467.969
469.904
471.794
473.644
475.454
477.225
478.960
480.659
482.325
483.958
485.560
487.132
488.676
490.191
491.679
493.141
494.578
495.991
497.380-
р~\снс12) Д,
Н°(Т)-Н°т
кДж ¦ моль
3.399
7.527
12.360
12.457
18.031
24.092
30.512
37.203
44.109
51.190
58.418
65.770
73.229
80.779
88.409
96.106
103.864
111.673
119.528
127.423
135.353
143.314
151.303
159.317
167.353
175.409
183.483
191.573
199.678
207.796
215.926
224.067
232.218
240.378
248.547
256.724
264.908
273.099
281.295
289.498
297.706
305.919
314.137
322.359
330.584
338.814
347.048
355.284
363.524
371.767
380.012
388.260
396.511
404.764
413.020
421.277
429.536
437.797
446.060
454.325
462.591
(г)
Я°@)= 1090.459
-557.6286
-271.0251
-176.3261
-175.1341
-127.0424
-98.1125
-78.7827
-64.9487
-54.5554
¦46.4595
-39.9743
-34.6618
-30.2302
-26.4769
-23.2570
-20.4643
-18.0191
-15.8602
-13.9401
-12.2213
-10.6736
-9.2726
-7.9985
-6.8348
-5.7676
-4.7855
-3.8786
-3.0387
-2.2585
-1.5318
-.8535
-.2187
.3766
.9359
1.4625
1.9591
2.4283
2.8722
3.2929
3.6921
4.0714
4.4323
4.7761
5.1041
5.4172
5.7164
6.0027
6.2769
6.5398
6.7920
7.0341
7.2669
7.4907
7.7062
7.9137
8.1137
8.3066
8.4929
8.6727
8.8465
9.0145
кДж ¦ моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а 6л и ц а
'л
— о
'й S
О К
 И
Ё. «5
*? 00
о ">'
О г-
^ о к
2 " s
00 О ¦ оо
" с а
б Д
О 0
° у,
*ц ¦ о
+
7
з т
«о Й
3 |
00 К
оо Ч
о °
"О г*
1 J^
X +
m н
О rt
со сч
•* ю
II +
°
316
_,
'й
I
S
1
¦
ч
о
оо
II
оЗ
«о
я
о
\с
V
V
о
о
>л
г""
'о
II
105

Класс точности
VI-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
35.802
42.424
50.950
51.116
59.612
66.694
72.380
76.996
80.825
84.056
86.812
89.177
91.215
92.976
94.504
95.831
96.990
98.003
98.894
99.678
100.372
100.988
101.536
102.026
102.465
102.860
103.216
103.538
¦ ЛЛ ЛЛ Л
103.830
104.095
104.337
104.558
104.761
104.947
105.118
105.276
105.422
105.557
105.682
105.798
105.906
106.007
106.101
106.189
106.271
106.348
106.420
106.488
106.552
106.613
106.669
106.723
106.773
106.821
106.867
106.910
106.950
106.989
107.026
107.061
107.094
*-<n-P<cw
Ф° (Г)
Дж • К • моль
191.164
215.359
230.494
230.740
242.728
252.911
26 i.926
270.091
277.592
284.549
291.050
297.159
302.926
308.390
313.585
318.538
323.271
327.804
332.154
336.335
340.360-
344.241
347.988
351.610
355.115
358.510
361.802
364.998
368.102
371.120
374.057
376.916
379.702
382 418
385.068
387.655
390.183
392.652
395.066
397.428
399.740
402.004
404.221
406.394
408.525
410.614
412.664
414.676
416.651
418.591
420.497
422.370
424.211
426.021
427.802
429.554
431.278
432.975
434.646
436.292
437.912
ДИХЛОРМЕТАН СН2С12 (г)
2(Н) ¦ р2(С1) • р
S°(T)
-1
225.034
251.759
270.252
270.568
286.464
300.555
313.236
324.752
335.291
345.002
354.005
362.393
370.242
377.614
384.562
391.128
397.351
403.262
408.889
414.257
419.388
424.301
429.012
433.536
437.888
442.079
446.120
450.021
453.792
457.440
460.974
464.398
467.721
470.948
474.083
477.133
480.101
482.991
485.808
488.554
491.234
493.851
496.406
498.904
501.346
503.735
506.073
508.363
510.605
512.803
514.958
517.070
519.143
521.178
523.175
525.136
527.063
528.956
530.817
532.647
534.447
(сн2а2) Д,.л
Н°(Г)-Н°@)
кДж • моль
3.387
7.280
11.854
11.948
17.494
23.822
30.786
38.263
46.159
54.408
62.955
71.757
80.779
89.991
99.367
108.885
118.527
128.278
138.124
148.053
158.057
168.125
178.252
188.430
198.655
208.922
219.226
229.564
Л^УЧ Лпл
239.932
250.329
260.751
271.196
281.662
292.147
302.651
313.170
323.705
334.255
344.817
355.391
365.976
376.572
387.177
397.792
408.415
419.046
429.684
440.329
450.982
461.640
472.304
482.974
493.649
504.328
515.013
525.702
536.394
547.092
557.792
568.496
579.204
f°@) = 1470.649 кДж • моль
-752.2546
-365.5827
-237.7309
-236.1208
-171.1440
-132.0311
-105.8830
-87.1612
-73.0909
-62.1278
-53.3439
-46.1475
-40.1436
-35.0583
-30.6957
-26.9119
-23.5990
-20.6742
-18.0730
-15.7447
-13.6485
-11.7513
-10.0261
-8.4505
-7.0059
-5.6767
-4.4495
-3.3131
-2.2578
-1.2751
-.3579
.5002
1.3047
2.0605
2.7719
3.4426
4.0761
4.6753
5.2430
5.7816
6.2933
6.7800
7.2435
7.6854
8.1073
8.5104
8.8960
9.2652
9.6189
9.9582
10.2840
10.5969
10.8978
11.1874
11.4662
11.7349
11.9939
12.2439
12.4852
12.7184
12.9437
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л
i
А
О
^2
оо'
32*
3 ©
ч ^
v> <ч
и
о
<
+
V 1
*^ ' ч
со А
5 i
¦^ s
*"* i
+ U
С1* •
2 «
00 Ч
о **1
0 m
i «С
ГЧ СП
С— i
1 1
СЧ ЧО
00 ОО
ОО СЧ
<N •—1
¦* —1
II +
0
и
о
о
о
о
U")
]
II
Я
.15
оо
сч
Ч*
X
:*.
Ца 317
i
i
,_¦
'а
j|
СП
00
<п
II
Ч
0 В!
Я
о
V
V
g
'о
II
106

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
40.466
55.004
66.846
67.047
76.539
83.702
89.166
93.486
97.034
100.043
102.655
104.963
107.032
108.908
110.626
112.213
113.692
115.080
116.392
117.638
118.829
119.973
121.077
122.146
123.185
124.197
125.187
126.157
127.110
128.047
128.971
129.883
130.784
131.676
132.560
133.436
134.306
135.169
136.028
136.881
137.731
138.576
139.419
140.258
141.094
141.928
142.759
143.589
144.416
145.242
146.067
146.890
147.712
148.533
149.353
150.172
150.990
151.808
152.625
153.442
154.258
*-G->-„(О.р
Ф°(Г)
1
— 1 ~
Дж • К . моль
204.272
230.483
248.275
248.572
263.242
275.883
287.108
297.253
306.535
315.103
323.071
330.524
337.531
344.146
350.416
356.376
362.059
367.492
372.697
377.695
382.502
387.135
391.607
395.929
400.112
404.166
408.099
411.919
415.633
419.248
422.768
426.201
429.550
432.819
436.014
439.138
442.194
445.185
448.116
450.988
453.803
456.566
459.277
461.940
464.556
467.127
469.654
472.140
474.586
476.994
479.364
481.699
484.000
486.267
488.503
490.707
492.881
495.026
497.144
499.234
501.298
ТРИХЛОРМЕТАН СНС13
СН>-*<!>.,->(
S°(T)
1
239.311
271.999
296.244
296.658
317.308
335.194
350 959
365.040
377.762
389.369
400.048
409.942
419.166
427.808
435.943
443.630
450.920
457.854
464.470
470.796
476.861
482.686
488.293
493.699
498.919
503.969
508.859
513.602
518.207
522.684
527.041
531.285
535.422
539.460
543.404
547.260
551.031
554.723
558.339
561.883
565.360
568.771
572.120
575.411
578.645
581.825
584.953
588.032
591.064
594.050
596 993
599.894
602.754
605.575
608.359
611.107
613.820
616.500
619.148
621.764
624.349
[г)
СНС13) АгЯ°@)= 1384
н°(П-н°@)
кДж . моль
3.504
8.303
14.302
14.426
21.626
29.655
38.310
47.451
56.982
66.840
76.977
87.360
97.962
108.760
119.738
130.881
'42.177
153.617
165.191
176.893
188.716
200.657
212.710
224.871
237.138
249.507
261.976
274.544
287.207
299.965
312.816
325.759
338.792
351.916
365.127
378.427
391.814
405.288
418.848
432.494
446.224
460.040
473.939
487.923
501.991
516.142
530.376
544.694
559.094
573.577
588.142
602.790
617.520
632.332
647.227
662.203
677.261
692.401
707.622
722.926
738.311
о
-705.0734
-341.1291
-220.8610
-219.3470
-158.2748
-121.5448
-97.0118
-79.4620
-66.2844
-56.0262
-47.8145
-41.0932
-35.4909
-30.7503
-26.6875
-23.1673
-20.0883
-17.3730
-14.9610
-12.8044
-10.8651
-9.1121
-7.5200
-6.0681
-4.7386
-3.5171
-2.3910
-1.3499
-.3845
.5130
1.3492
2.1302
2.8611
3.5465
4.1903
4.7962
5.3672
5.9063
6.4159
6.8983
7.3556
7.7896
8.2019
8.5940
8.9674
9.3233
9.6628
9.9869
10.2967
10.5930
10.8767
11.1483
11.4088
11.6586
11.8984
12.1287
12.3501
12.5630
12.7678
12.9650
13.1549
.027 кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
37С0
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
-
i
.с
о
— о
li С
¦? <~'
С
о
0
+
те
г^
о
+
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+
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-
'л
о
2
—
II
0 к
to
0
0
0
V
Ь>
V
о
о
«""
1
с
II
107

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
32.752
45.078
54.318
54.454
60.226
64.016
66.824
69.103
71.050
72.750
74.248
75.569
76.735
77.762
78.667
79.465
80.170
80.793
81.345
81.835
82.271
82.660
83.009
83.322
83.603
83.857
84.087
84.295
84.485
84.658
84.815
84.960
85.093
85.214
85.327
85.431
85.527
85.615
85.698
85.775
85.846
85.913
85.975
86.033
86.088
86.139
86.187
86.232
86.274
86.314
86.352
86.388
86.422
86.453
86.484
86.512
86.539
86.565
86.590
86.613
86.635
ХЛОРАЦЕТИЛЕН С2НС1 (г)
а:°(Г)=р2(О-р(Н)р(С1)-
Ф°(Г)
—1 -
Дж • К f . моль
165.703
187.645
202.347
202.592
214.629
224.876
233.850
241.855
249.096
255.717
261.822
267.494
272.793
277.769
282.462
286.904
291.122
295.139
298.974
302.642
306.160
309.538
312.788
315.920
318.942
321.861
324.685
327.419
330.070
332.642
335.140
337.567
339.929
342.228
344.468
346.652
348.782
350.861
352.892
354.876
356.816
358.714
360.572
362.390
364.172
365.917
367.629
369.307
370.954
372.570
¦ 374.157
375.716
377.247
378.751
380.230
381.685
383.115
384.523
385.908
387.272
388.614
S°(T)
1
195.552
222.025
241.885
242.221
258.742
272.614
284.544
295.021
304.379
312.848
320.592
327.732
334.358
340.542
346.338
351.793
356.945
361.824
366.458
370.870
375.079
379.102
382.956
386.652
390.205
393.623
396.916
400.094
403.163
406.131
409.003
411.787
414.486
417.107
419.652
422.127
424.535
426.880
429.164
431.391
433.564
435.684
437.755
439.779
441.757
443.693
445.587
447.441
449.256
451.036
452.780
454.490
456.168
457.815
459.431
461.018
462.577
464.109
465.615
467.095
468.551
/Г'(С2НС1) АгН?@)= 1546.024
Я°(Г)-Я°@)
кДж . моль
2.985
6.876
11.788
11.889
17.645
23.869
30.416
37.216
44.226
51.418
58.770
66.262
73.878
81.604
89.426
97.334
105.316
113.365
121.473
129.632
137.838
146.085
154.368
162.685
171.032
179.405
187.802
196.221
204.661
213.118
221.592
230.080
238.583
247.099
255.626
264.164
272.712
281.269
289.834
298.408
306.989
315.577
324.172
332.772
341.378
349.989
358.606
367.227
375.852
384.482
393.115
401.752
410.392
419.036
427.683
436.333
444.985
453.641
462.299
470.959
479.621
-794.5365
-388.7309
-254.7834-
-253.0982
-185.1462
-144.3093
-117.0472
-97.5513
-82.9143
-71.5199
-62.3973
-54.9285
-48.7009
-43.4288
-38.9081
-34.9887
-31.5583
-28.5307
-25.8389
-23.4301
-21.2618
-19.2999
-17.5161
-15.8874
-14.3942
-13.0205
-11.7524
-10.5782
-9.4878
-8.4726
-7.5251
-6.6387
-5.8077
-5.0270
-4.2922
-3.5994
-2.9451
-2.3261
-1.7397
-1.1833
-.6548
-.1520
.3269
.7835
1.2194
1.6359
2.0344
2.4159
2.7815
3.1322
3.4690
3.7925
4.1036
4.4031
4.6914
4.9693
5.2372
5.4958
5.7455
5.9868
6.2200
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
т
А
К
О
К
о
о
ON r^*
г^ —<
ОО *j
2 "
о
II
и
Зн
(N1
О
о
'ч -
й 'л
Ч 5
+ Т
'& *
о
—1 ОО
О чо
о 'Ч
1 гч
с +
t^ "ч
и-> О
J2 [^
+ i
5 <?
00 ¦*
OS (N
СП Г~
II +
0
Q
*
У.
S
оо
—
II
«л
ОС
гч
и
У
о
Ц;
ч.
ца 319
7
л
о
1
оо
о
гп
II
о К

я
о
о
о
V
V
о
о
•"*
'о
II
108

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900 .
2000
2100
2200
2300
* 2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
34.300
42.279
53.680
53.899
65.085
74.427
82.006
88.245
93.496
97.987
101.861
105.219
108.137
110.676
112.889
114.823
116.517
118.004
119.314
120.471
121.497
122.409
123.222
123.950
124.603
125.190
125.721
126.201
126.637
127.034
127.396
127.727
128.030
128.309
128.565
128.802
129.021
129.223
129.411
129.585
129.747
129.899
130.040
130.172
130.295
130.411
130.520
130.622
130.718
130.808
130.894
130.974
131.051
131.123
131.191
131.255
131.317
131.375
131.430
131.483
131.533
f-(W(c>.
Ф°(Г)
Дж • К . моль
185.652
209.346
224.269
224.514
236.616
247.136
256.632
265.370
273.501
281.124
288.312
295.120
301.591
307.760
313.656
319.303
324.724
329.935
334.953
339.792
344.464
348.980
353.351
357.585
361.691
365.676
369.548
373.311
376.973
380.539
384.012
387.399
390.702
393.927
397.076
400.154
403.163
406.105
408.985
411.805
414.567
417.273
419.926
422.527
425.079
427.583
430.041
432.456
434.827
437.157
439.448
441.700
443.915
446.093
448.237
450.347
452.424
454.470
456.485
458.470
460.426
ХЛОРЭТИЛЕН С2Н3С1 (г)
S°(T)
-'
219.084
244.943
263.912
264.244
281.319
296.882
311.145
324.269
336.405
347.683
358.213
368.082
377.366
386.124
394.409
402.265
409.730
416.840
423.622
430.105
436.311
4*2.261
447.975
453.469
458.758
463.857
468.777
473.531
478.129
482.580
486.893
491.075
495.135
499.080
502.914
506.644
510.276
513.813
517.262
520.626
523.909
527.114
530.246
533.308
536.302
539.231
542.099
544.907
547.658
550.354
552.998
555.591
558.134
560.632
563.083
565.491
567.857
570.181
572.466
574.714
576.924
Р~\С2ЩС\) А, А
H°(T)-H°@)
кДж • моль
3.343
7.119
11.819
11.919
17.881
24.873
32.707
41.229
50.324
59.903
69.900
80.258
90.930
101.873
113.054
124.442
136.011
147.738
159.605
171.596
183.695
195.891
208.174
220.533
232.961
245.451
257.997
270.594
283.236
295.920
308.642
321.398
334.186
347.003
359.847
372.716
385.607
398.519
411.451
424.401
437.368
450.350
463.347
476.358
489.381
502.416
515.463
528.520
541.587
554.664
567.749
580.842
593.943
607.052
620.168
633.290
646.419
659.553
672.694
685.839
698.990
Г°@)= 2159.519
-1108.6018
-541.1562
-353.6070
-351.2458
-255.9685
-198.6384
-160.3261
-132.9039
-112.3011
-96.2525
-83.3971
-72.8675
-64.0845
-56.6467
-50.2672
-44.7350
-39.8920
-35.6170
-31.8157
-28.4136
-25.3510
-22.5795
-20.0597
-17.7587
-15.6493
-13.7085
-11.9169
-10.2580
-8 7176
-7.2835
-5.9450
-4.6929
-3.5191
-2.4164
-1.3787
-.4004
.5235
1.3975
2.2253
3.0107
3.7567
4.4663
5.1.421
5.7863
6.4013
6.9888
7.5508
8.0888
8.6043
9.0988
9.5735
10.0294
10.4678
10.8897
11.2959
11.6872
12.0646
12.4287
12.7802
13.1198
13.4480
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000 ,.
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
-1
с
т 1
О 7s
S ?—I
* о
со ?)
g я я
¦* II JO
3 о • «>'
II 1- «Ч
* с $
" ж
0 В
**3 о
'—> S;
< --,
i 7
с? ^
f~ S
СП _'
+
1 56
1/1
S "*
со с^*
« ¦*
СЛ CTN
1 +
? *
\О 00
¦* оо'
m -н
ОО |
00 Г^
? —
II +
0
а 320
7
о
__•
1
.
о
о
vq
m
и
0 К
§
о
SO
V
tx
V
о
о
ч"
'о
II
а
109

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
6700
5800
5900
6000
С°р(Т)
43.308
57.003
68.843
69.052
79.325
87.519
93.976
99.156
103.411
106.973
109.993
112.573
114.789
116.700
118.354
119.791
121.044
122.139
123.101
123.948
124.697
125.362
125.954
126.483
126.957
127.383
127.768
128.115
128.431
128.717
128.979
129.218
129.436
129.638
129.822
129.993
130.150
130.296
130.431
130.557
130.674
130.782
130.884
130.979
131.068
131.151
131.229
131.302
131.371
131.437
131.498
131.556
131.610
131.662
131.711
131.758
131.802
131.843
131.883
131.921
131.957
ДИХЛОРЭТИЛЕН С2Н2С12 (г)
К°(Т) = р2(С)-р2(Н)
Ф°(П
Дж ¦ К~ . моль"
200.951
228.424
246.998
247.307
262.547
275.671
287.344
297.924
307.632
316.620
325.001
332.859
340.261
347.260
353.901
360.221
366.249.
372.014
377.538
382.840
387.938
392.848
397.583
402.155
406.575
410.854
414.999
419.019
422.922
426.713
430.400
433.988
437.367
440.886
444.206
447.445
450.608
453.697
456.716
459.669
462.558
465.385
468.153
470.866
473.524
476.131
478.6*7
481.196
483.657
486.075
488.449
490.782
493.075
495.329
497.545
499.725
501.871
503.982
506.060
508.106
510.122
•р2(С1)-р(С2Н2С12) Д^.Я°@)= 2085.402
S°(T)
237.514
271.906
296.915
297.341
318.664
337.281
353.831
368.720
382.248
394.639
406.070
416.678
426.570
435.836
444.546
452.762
460.534
467.906
474.915
481.594
487.971
494.072
499.917
505.528
510.921
516.113
521.116
525.945
530.610
535.122
539.490
543.723
547.720
551.815
555.688
559.454
563.118
566.686
570.163
573.552
576.859
580.087
583.240
586.321
589.333
592.289
595.163
597.986
600.751
603.461
606.117
608.721
611.276
613.784
616.245
618.663
621.037
623.370
625.664
627.918
630.136
Н°(Т)~Н°@)
кДж . моль"
3.656
8.696
14.883
15.010
22.447
30.805
39.892
49.558
59.693
70-.217
81.069
92.201
103.572
115.149
126.903
138.812
150.855
163.016
175.279
187.632
200.065
212.569
225.135
237.757
250.430
263.147
275.905
288.700
301.527
314.385
327.270
340.180
353.130
366.066
379.040
392.030
405.038
418.060
431.097
444.146
457.208
470.281
483.364
496.457
509.560
522.671
535.789
548.916
562.050
575.190
588.337
601.490
614.648
627.812
640.980
654.154
667.332
680.514
693.700
706.891
720.085 •
-1068.0664
-520.1750
-339.1862
-336.9082
-245.0150
-189.7490
-152.8322
-126.4193
-106.5820
¦91.1348
-78.7647
-68.6354
-60.1884
-53.0367
-46.9039
-41.5866
¦36.9326
-32.8250
-29.1731
-25.9052
-22.9637
-20.3022
-17.8826
-15.6733
-13.6482
-11.7851
-10.0655
-8.4733
-6.9949
-5.6186
-4.3342
-3.1327
-2.0005
-.9486
.0469
.9855
1.8718
2.7101
3.5042
4.2575
4.9730
5.6535
6.3016
6.9195
7.5092
8.0726
8.6115
9.1273
9.6217
10.0958
10.5509
10.9880
11.4084
11.8128
12.2022
12.5774
12.9392
13.2882
13.6251
13.9506
!4.2653
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т аб л и
-1
г5
5 "
ON -л,
ON ?
и ^
% с
С )
W
3;
„+
'н -
ОО м
5 |
+ 1
Н ¦ Ъ?
оо _,
s а
О rj
1 m
ч +
•^ к
оо "Т
°) <о
t— 00
+ н
00 Г~-
О но
II +
Ь-
0
~?
о
И
00
о>
ь-~
¦^
я
и
ч
ц а 321
_
'л
к
о
S
—
•
R
•о
°!
0 «
to
?
о
о
V
V
S
¦*¦
'о
II
ПО

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
к
1
V)=p2(C)
Ф°(Г)
,1-ДИХЛОРЭТИЛЕН 1,1-С2Н2
р2(Н)р2(С1)-р"'(С2Н2С12) Агн'
S°(T)
Дж . К . моль
37.123
52.685
67.123
67.365
78.752
87.345
93.941
99.167
103.436
107.000
110.018
112.595
114.808
116.716,
118.368
119.803
121.054
122.148
123.109
123.955
124.704
125.368
125.959
126.488
126.961
127.387
127.771
128.119
128.434
128.720
128.981
129.220
129.439
129.640
129.824
129.995
130.152
130.298
130.433
130.558
130.675
130.784
130.885
130.980
131.069
131.152
131.230
131.303
131.372
131.437
131.499
131.557
131.611
131.663
131.712
131.758
131.802
131.844
131.884
131.921
131.957
199.870
224.883
241.857
242.143
256.408
268.913
280.167
290.446
299.929
308.743
316.984
324.728
332.036
338.955
345.527
351.788
357.765
363.484
368.967
374.233
379.298
384.178
388.886
393.434
397.832
402.089
406.216
410.218
414.104
417.881
421.553
425.128
428.609
432.002
435.311
438.540
441.692
444.772
447.783
450.727
453.608
456.427
459.189
461.894
464.546
467.146
469.697
472.200
474.656
477.068
479.438
481.766
484.054
486.303
488.515
490.691
492.832
494.940
497.014
499.057
501.069
233.897
264.222
288.049
288.464
309.480
328.020
344.553
359.441
372.971
385.366
396.800
407.409
417.304
426.570
435.282
443.499
451.271
458.644
465.653
472.333
478.710
484.811
490.657
496.268
501.661
506.853
511.857
516.685'
521.351
525.863
530.231
534.464
538.570
542.557
546.429
550.195
553.860
557.427
560.904
564.294
567.601
570.829
573.982
577.062
580.075
583.021
585.905
588.728
591.493
594.202
596.858
599.463
602.018
604.525
606.987
609.404
611.779
614.112
616.405
618.660
620.878
Н°(Т)~Н°@)
кДж ¦ моль
3.403
7.868
13.772
13.897
21.229
29.554
38.632
48.296
58.433
68.960
79.815
90.949
102.322
113.900
125.657
137.567
149.611
161.772
174.036
186.390
198.824
211.328
223.895
236.518
249.191
261.909
274.667
287.462
300.289
313.147
326.033
338.943
351.876
364.830
377.803
390.794
403.802
416.824
429.861
442.911
455.972
469.045
482.129
495.222
508.325
521.436
534.555
547.682
560.815
573.956
587.103
600.256
613.414
626.578
639.747
652.920
666.098
679.280
692.467
705.657
718.851
С12 (г)
3@)= 2085.402
о
-1068.0104
-519.9901
-338.9179
-336.6386
-244.6944
-189.3960
-152.4574
-126.0288
-106.1797
-90.7234
-78.3460
-68.2107
-59.7587
-52.6030
-46.4665
-41.1461
¦36.4894
-32.3794
-28.7254
-25.4556
-22.5124
-19.8494
-17.4283
-15.2178
-13.1915
-11.3274
-9.6067
-8.0136
-6.5343
-5.1572
-3.8721
-2.6699
-1.5430
-.4846
.5116
1.4507
2.3375
3.1763
3.9708
4.7245
5.4405
6.1214
6.7699
7.3881
7.9781
8.5419
9.0811
9.5972
10.0919
10.5662
11.0216
11.4590
11.8796
12.2843
12.6739
13.0493
13.4113
13.7605
14.0977
14.4233
14.7381
кДж ¦ моль
Т
К
100
20С
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
-
'ё
"¦ О
'л S
О Ьй
" X
R о
^ и
И Й
00 О 00
* с* ?
* и ^
" х и
0 X
I N
3 '
a; ow
¦-, а;
+
н _
ос о
РО 5
• «С
СО
+ 7
г* J>
1 .
о <*¦*
° S
н +
t^. оо
ГО О*ь
О «N
^ ЧЭ
+ ?
т)- 00
р ^
О C7N
О -н
"° rt
II +
0
а 322
'л
о
S
-"
t§
¦ч-
Os
"
о 5
to
§
V
V
§
ю
«*"
'о

II
111

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
. 4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
39.397
51.375
64.890
65.131
76.789
85.828
92.795
98.293
102.757
106.461
109.582
112.236
114.508
116.463
118.151
119.615
120.890
122.003
122.980
123.840
124.600
125.274
125.874
126.410
126.890
127.322
127.711
128.063
128.382
128.672
128.937
129.178
129.400
129.603
129.790
129.962
130.121
130.269
130.405
130.532
130.650
130.760
130.863
130.959
131.048
131.132
131.211
131.285
131.355
131.421
131.483
131.541
131.597
131.649
131.698
131.745
131.790
131.832
131.872
131.910
131.946
цыс-ДИХЛОРЭТИЛЕН цис-С2Н2С12 0)
°(Г) =р2(С)-р2(Н)-
ф'(т-)
Дж К .моль
200.412
226.278
243.394
243.679
257.833
270.173
281.265
291.400
300.760
309.468
317.619
325.285
332.524
339.384
345.904
352.118
358.054
363.736
369.185
374.421
379.459
384.314
388.999
393.525
397.904
402.143
406.252
410.239
414.111
417.873
421.533
425.095
428.565
431.947
435.246
438.465
441.609
444.680
447.683
450.619
453.492
456.305
459.060
461.759
464.405
466.999
469.544
472.041
474.493
476.900
479.264
481.588
483.871
486.116
488.324
490.496
492.634
494.737
496.808
498.848
500.856
P2(ci).p-
S°(T)
235.709
266.425
289.487
289.889
310.288
328.438
344.729
359.462
372.888
385.211
396.594
407.166
417.032
426.277
434.971
443.174
450.935
458.298
465.300
471.973
478.345
484.440
490.282
495.890
501.280
506.469
511.470
516.297
520.960
525.470
529.837
534.069
538.173
542.159
546.030
549.795
553.459
557.026
560.502
563.891
567.197
570.424
573.577
576.657
579.669
582.615
585.498
588.320
591.085
593.794
696.450
599.054
601.609
604.116
606.578
608.995
611.369
613.702
615.995
618.249
620.467
'(С2Н2С12) Arh
Н°(Г)-Н°@)
кДж • моль
3.530
8.029
13.743
13.863
20.982
29.133
38.078
47.643
57.703
68.169
78.975
90.070
101.410
112.961
124.694
136.584
148.610
160.756
173.006
185.348
197.771
210.266
222.824
235.438
248.104
260.815
273.567
286.356
299.178
312.031
324.912
337.818
350.747
363.697
376.667
389.654
402.659
415.678
428.712
441.759
454.818
467.889
480.970
494.061
507.162
520.270
533.388
546.513
559.645
572.784
585.929
599.080
612.237
625.399
638.567
651.739
664.916
678.097
691.282
704.471
717.664
Г°@)= 2083.573
-1067.0834
-519.5854
-338.6776
-336.4005
-244.5301
-189.2707
-152.3555
-125.9422
-106.1037
-90.6551
-78.2836
-68.1529
-59.7046
-52.5519
-46.4179
-41.0997
-36.4447
32.3364
-28.6838
-25.4151
-22.4731
-19.8110
-17.3908
¦15.1810
-13.1554
-11.2919
-9.5718
-7.9793
-6.5005
-5.1239
-3.8392
-2.6374
-1.5109
-.4527
.5430
1.4818
2.3684
3.2069
4.0012
4.7547
5.4704
6.1511
6.7994
7.4174
8.0072
8.5708
9.1098
9.6259
10.1203
10.5945
11.0498
11.4871
11.9075
12.3120
12.7015
13.0769
13.4387
13.7878
14.1249
14.4505
14.7652
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
Т-
Т *¦ о
Й ?
о „
%
* о
? о
2 и
2 2
и ">
,—, ^
<& и ^
°i * и
сг\ О **•
11 ЕВ %
* г? ВС
\ ?
3 '
о 3
^ 0
О V
х "
S 'й
s; §
+ 1
г*
s з
О СЛ
х ^+
S "ц
г-: оч
"*" Н
OS Оч
•о- «
II +
?
ца 323
0
?
т
¦ч-
II
о 5
«о
-ч
я
О
8
V
V
8
¦'"
'о
ь.
II
is
112

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(.Т)
р
41.456
54.624
66.560
66.778
77.616
86.300
93.098
98.507
102.917
106.586
109.683
112.319
114.578
116.522
118.202
119.660
120.929
122.038
123.011
123.868
124.625
125.297
125.895
126.429
126.908
127.338
127.726
128.077
128.395
128.684
128.948
129.189
129.409
129.612
129.798
129.970
130.129
130.276
130.412
130.539
130.656
130.766
130.868
130.964
131.053
131.137
131.216
131.290
131.360
131.425
131.487
131.545
131.600
131.652
131.702
131.748
131.793
131.835
131.875
131.913
131.949
гранс-ДИХЛОГОТИЛЕН транс-С2Н2С12 (г)
к°(Т)=р\о-р
Ф°(Г)
Дж - К . моль
197.453
223.998
241.880
242.177
256.873
269.583
280.938
291.269
300.779
309.606
317.854
325.600
332.906
339.824
346.393
352.651
358.624
364.340
369.820
375.082
380.145
385.022
389.727
394.272
398.667
402.922
407.046
411.046
414.930
418.704
422.375
425.947
429.427
432.818
436.125
439.352
442.503
445.582
448.591
451.534
454.413
457.232
459.992
462.696
465.347
467.946
470.496
472.997
475.453
477.864
480.233
482.560
484.847
487.096
489.307
491.483
493.623
495.729
497.803
499.845
501.857
2(Н)-Р2(С1)-р!(с2н2а2) Лг
S°<T)
1
Я°(Г)-Я°@)
кДж . моль
232.908 3.545
265.893 8.379
289.940 14.329
290.352 14.453
311.096 21.689
329.388 29.903
345.748 38.886
360.520 48.476
373.971 58.554
386.312 69.035
397.706 79.853
408.287 90.956
418.159 102.304
427.409 113.861
436.107 125.600
444.313 137.494
452.078 149.525
459.443 161.675
466.446 173.928
473.121 186.273
479.494 198.698
485.591 211.195
491.434 223.756
497.042 236.372
502.433 249.040
507.623 261.752
512.625 274.506
517.452 287.296
522.116 300.120
526.626 312.974
530.993 325.856
535.225 338.763
539.331 351.693
543.316 364.644
547.188 377.615
550.953 390.603
554.617 403.608
558.184 416.629
561.660 429.663
565.049 442.711
568.356 455.770
571.583 468.842
574.736 481.924
577.816 495.015
580.828 508.116
583.774 521.226
586.657 534.343
589.480 547.469
592.245 560.601
594.954 573.740
597.610 586.886
600.214 600.038
602.769 613.195
605.276 626.358
607.738 639.525
610.155 652.698
612.529 665.875
614.862 679.057
617.155 692i242
619.410 705.431
621.627 718.624
1
Таблица 324
Я°@)= 2082.159 кДж-моль !
Г
К
-1066.1904 100
-519.0971 200
-338.3510 298.15
-336.0758 300
-244.2954 400
-189.0922 500
-152.2153 600
-125.8298 700
-106.0123 800
-90.5802 900
-78.2220 1000
-68.1022 1100
-59.6631 1200
-52.5180 1300
-46.3907 1400
-41.0783 1500
-36.428* 1600
-32.3245 1700
-28.6759 1800
-25.4108 1900
-22.4719 2000
-19.8128 2100
-17.3952 2200
-15.1879 2300
-13.1645 2400
-11.3031 2500
-9.5849 2600
-7.9941 2700
^* t" * *у Л Л Л f\ f\
-6.51/0 2800
-5.1418 2900
-3.8585 3000
-2.6581 3100
-1.5328 3200
-.4758 3300
.5189 3400
1.4566 3500
2.3422 3600
3.1798 3700
3.9732 3800
4.7258 3900
5.4408 4000
6.1207 4100
6.7683 4200
7.3856 4300
7.9748 4400
8.5378 4500
9.0762 4600
9.5916 4700
10.0855 4800
10.5592 4900
11.0139 5000
11.4508 5100
11.8707 5200
12.2748 5300
12.6639 5400
13.0388 5500
13.4002 5600
13.7490 5700
14.0856 5800
14.4109 5900
14.7252 6000
'л °
о
?3 о
ко™
—' чс г^
—-" 2
т i т'
о за
ОС 1-Г ГЧ %
^ х з 5
" о" X ¦*¦
^ ' г"
о О II
Si ч
р. в ° *
^1 0
+
Т -.
m ^
! 1
—< ^ о
00 m О
2 <-. v
ч + V
5 ^ §
5 ^ **"
Si S 2
¦ч- —i
о о а
to —«
п +
о
113

Класс точности
VI-E
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛАЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300.
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
46.713
65.882
80.071
80.302
91.054
98.932
104.768
109.206
112.676
115.457
117.726
119.605
121.178
122.506
123.636
124.603
125.436
126.158
126.786
127.336
127.819
128.245
128.623
128.959
129.260
129.529
129.771
129.990
1 ЧЛ 1Я7
IJU. Ю/
130.367
130.530
130.679
130.816
130.941
131.056
131.162
131.259
131.350
131,433
131.511
131.583
131.650
131.713
131.772
131.827
131.878
131.926
131.971
132.014
132.054
132.092
132.127
132.161
132.193
132.223
132.251
132.278
132.304
132.328
132.351
132.374
ТРИХЛОРЭТИЛЕН С2НС1
1 (Г)
ЛГ°(Г)=р2(С)р(Н)-р3(С1)р~1(С2НС13) Дг#°@)= 1997.870 кДж • моль
Ф°(Г)
Дж • К . моль"
219.812
248.696
269.143
269.488
286.618
301.465
314.670
326.602
337.505
347.552
356.875
365.573
373.729
381.408
388.663
395.540
402.077
408.306
414.256
419.950
425.410
430.654
435.700
440.561
445.250
449.780
454.161
458.402
АЛО 41 9
466.499
470.370
474.132
477.790
481.351
484.819
488.198
491.495
494.71!
497.852
500.920
503.919
506.852
509.722
512.532
515.283
517.979
520.621
523.212
525.753
528.247
530.695
533.098
535.459
537.779
540.059
542.301
544.506
546.675
548.808
550.909
552.976
1
257.165
295.776
324.853
325.349
350.002
371.212
389.791
406.289
421.107
434.545
446.831
458.142
468.618
478.372
487.493
496.057
504.126
511.752
518.981
525.852
532.395
538.642
544.617
550.342
555.837
561.119
566.204
571.106
Ч7Ч ЯЧ7
\Л О,ОО1
580.409
584.831
589.114
593.265
597.292
601.203
605.003
608.700
612.297
615.801
619.216
622.547
625.797
628.970
632.070
635.100
638.063
640.962
643.800
646.579
649.301
651.970
654.586
657.152
659.669
662.140
664.567
666.950
669.292
671.533
673.855
676.080
Н°(Г)-Н°@)
кДж • моль
3.735
9.416
16.610
16.758
25.354
34.873
45.072
55.781
66.881
78.293
89.956
101.825
113.867
126.053
138.361
150.775
163.278
175.858
188.506
201.213
213.971
226.774
239.618
252.498
265.409
278.348
291.314
304.302
417 41 1
Oil .О 1 1
330.339
343.384
356.444
369.5)9
382.607
395.707
408.818
421.939
435.069
448.209
461.356
474.511
487.672
500.841
514.015
527.195
540.380
553.570
566.765
579.964
593.168
606.375
619.586
632.800
646.018
659.239
672.463
685.689
698.918
712.150
725.384
738.620
lgK°(T)
-1020.7096
-495.7523
-322.3845
-320.2029
-232.2126
-179.3149
-143.9936
-118.7314
-99.7646
-85.0000
-73.1801
-63.5038
-55.4366
-48.6081
-42.7536
-37.6787
-33.2375
-29.3185
-25.8348
-22.7178
-19.9126
-17.3746
-15.0676
-12.9613
-11.0308
-9.2550
-7.6160
-6.0986
-A RRQS
*T.WO*TO
-3.3784
-2.1546
-1.0099
.0630
1.0708
2.0191
2.9131
3.7572
4.5556
5.3119
6.0293
6.7107
7.3587
7.9758
8.5641
9.1256
9.6620
10.1750
10.6662
11.1368
11.5881
12.0213
12.4375
12.8376
13.2226
13.5932
13.9503
14.2946
14.6268
14.9475
15.2573
15.5567
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
2000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 325
-
i
" О
'в *
S Д 1
к 1 §
* t _¦
о Т '
й I 2 й
11 1/1 ^
2 о оо °
^ U о §
° w
4; о
'и
m. о
П 1
& ^ ~
« Ч §
о 5 V
Л + V
*О in
Zh ""» ^
+ 1
г- X fr-
3 ю it
Г- V")
00 ^ w
Г" С*^
II +
ь
о
в
114

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
к
С°р(Т)
33.780
38.557
44.678
44.791
50.482
55.266
59.221
62.496
65.226
67.516
69.445
71.076
72.461
73.642
74.653
75.523
76.274
76.926
77.494
77.992
78.429
78.816
79.158
79.463
79.735
79.979
80.198
80.396
80.575
80.738
80.886
81.021
81.144
81.257
81.361
81.457
81.545
81.627
81.702
81.773
81.838
81.899
81.955
82.008
82.058
82.104
82.148
82.188
82.227
82.263
82.297
82.329
82.360
82.388
82.415
82.441
82.466
82.489
82.511
82.532
82.552
¦
ОКСИЦ-ГИДРИД-ХЛОРИД УГЛЕРОДА НС1СО (г)
°(П=Р(Н).Р(С1)
Ф°(Г)
Дж К .моль
184.407
207.814
222.041
222.270
233.269
242.404
250.342
257.425
263.854
269.762
275.240
280.353
285.153
289.679
293.964
298.033
301.908
305.608
309.148
312.542
315.803
318.939
321.961
324.877
327.693
330.418
333.055
335.612
ЛУЧА АЛА
338.092
340.501
342.842
345.119
347.335
349.494
351.598
353.65С
355.653
357.609
359.520
361.388
363.216
365.003
366.754
368.468
370.148
371.794
373.409
374.993
376.547
378.073
379.572
381.044
382.490
383.912
385.309
386.684
388.037
389.367
390.677
391.967
393.237
•р(С)-р(О)
S°(T)
217.742
242.420
258.956
259.233
272.918
284.714
295.151
304.534
313.062
320.881
328.097
334.795
341.040
346.888
352.384
357.564
362.463
367.107
371.521
375.724
379.736
383.572
387.247
390.772
394.160
397.420
400.561
403.592
406.519
409.349
412.089
414.743
417.318
419.816
422.244
424.603
426.899
429.135
431.313
433.436
435.507
437.528
439.503
441.432
443.318
445.162
446.967
448.735
450.465
452.161
453.823
455.453
457.052
458.621
460.162
461.674
463.160
464.620
466.054
467.465
468.852
p'^hcico) Д;
Н°(Г)-Н°@)
кДж ¦ моль
3.334
6.921
11.006
11.089
15.860
21.155
26.885
32.976
39.366
46.007
52.858
59.886
67.065
74.371
81.787
89.297
96.888
104.549
112.270
120.045
127.867
135.729
143.628
151.560
159.520
167.506
175.515
183.544
191.593
199.659
207.740
215.836
223.944
232.064
240.195
248.336
256.486
264.645
272.812
280.985
289.166
297.353
305.545
313.744
321.947
330.155
338.368
346.584
354.805
363.030
371.258
379.489
387.724
395.961
404.201
412.444
420.689
428.937
437.187
445.439
453.694
Я°@) = 1454.622 кДж • моль"
-747.6376
-365.8016
-239.6776
-238.0902
-174.0525
-135.5367
-109.8058
-91.3937
-77.5631
-66.7914
-58.1639
-51.0978
-45.2040
-40.2129
-35.9317
-32.2190
-28.9685
-26.0989
-23.5470
-21.2627
-19.2060
-17.3445
-15.6517
-14.1055
-12.6878
-11.3832
-10.1785
-9.0628
-8.0266
-7.0615
-6.1606
-5.3176
-4.5271
-3.7844
-3.0852
-2.4258
-1.8028
-1.2135
-.6550
-.1250
.3786
.8577
1.3142
1.7495
2.1651
2.5624
2.9424
3.3064
3.6554
3.9901
4.3116
4.6205
4.9177
5.2037
5.479i
5.7447
6.0008
6.2480
6.4868
6:7175
6.9406
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
430Q
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
1
о
Ji on
Сч. о
о т
о ^о
5 7
«*> i2 "
^ " Я
ч » *
40 О об
5 О и
% о
X У
С. о
о Я
^ О
+
о 7
•л е;
-I .
+ 1
1 .
2 *?
о ю
О ***!
Я +
2 ¦«?
ON ?
^ 1Л
ц. 1
<п X
«Л О
¦*' Я
И +
0
ца 326
-
'а
о
S
i
Дж-
го
гч
гч
II
о'З
¦Я
о
8
V
V
§
«л
'о
1!
115

Класс точности
V-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(п
ФТОРХЛОРМЕТИЛЕН CFC1
К°(Г) = r(C)-p(T)-p(Cl)-p~\CFCl) Д,А
Ф°(Г)
S°(T)
Дж • К • моль
33.846
38.325
43.156
43.238
47.109
49.891
51.846
53.230
5^.230
54.967
55.523
55.951
56.287
56.555
56.775
56.959
57.119
57.263
57.399
57.533
57.669
57.813
57.968
58.136
58.320
58.519
58.735
58.967
59.215
59.478
59.754
60.042
60.339
60.644
60.954
6..268
61.584
61.899
62.212
62.522
62.825
63.122
63.410
63.688
63.956
64.212
64.457
64.688
64.906
65.111
65.302
65.480
65.643
65.793
65.930
66.053
66.163
66.261
66.346
66.419
66.482
Я°(Г)-Я°@)
кДж • моль
184.650 217.998 3.335
208.076 242.696 6.924
222.268 258.922 10.929
222.495 259.189 11.008
233.348 272.186 15.536
242.228 283.015 20.394
249.818 292.295 25.486
256.477 300.3^7 30.744
262.424 307.573 36.119
267.804 314.005 41.581
272.720 319.827 47.107
277.248 325.140 52.681
281445 330.023 58.294
285.357 334.539 63.937
289.022 338.739 69.603
292.46У 342.662 75.290
295.722 346.344 80.994
298.803 '349.811 86.714
301.728 353.088 92.447
304.514 356.195 98.193
307.172 359.149 103.953
309.715 361.966 109.728
312.152 364.659 115.517
314.491 367.240 121.322
316.741 369.718 127.144
318.908 372.103 132.986
320.999 374.402 138.849
323.018 376.623 144.734
324.971 378.772 150.643 •
326.862 380.854 156.577
328.696 382.875 162.539
330.476 384.840 168.528
332.204 386.750 174.547
333.885 388.612 180.596
335.522 390.427 186.676
337.116 392.198 192.787
338.670 393.929 198.930
340.187 395.620 205.104
341.667 397.275 211.310
343.114 398.895 217.546
344.528 400.482 223.814
345.912 402.037 230.111
347.267 403.561 236.438
348.593 405.057 242.793
349.893 406.524 249.175
351.168 407.964 255.584
352.418 409.378 262.017
353.645 410.767 268.475
354.849 412.131 274.954
356.032 413.472 281.455
357.194 414.789 287.976
358.336 416.084 294.515
359.458 417.357 301.072
360.563 418.609 307.644
361.649 419.840 314.230
362.718 421.051 320.829
363.770 422.242 327.440
364.807 423.414 334.061
365.827 424.567 340.692
366.832 425.702 347.330
367.823 426.819 353.975
(г)
Г°@)= 883.080
-452.8392
-221.0766
•144.5441
-143.5809
-104.7333
-81.3751
-65.7751
-54.6152
¦46.2341
¦39.7077
-34.4810
-30.2004
-26.6300
-23.6064
-21.0126
-18.7630
-16.7932
¦15.0539
-13.5068
-12.1217
-10.8743
-9.7450
¦8.7177
-7.7793
-6.9185
-6.1262
-5.3945
-4.7166
-4.0868
-3.5002
-2.9525
¦2.4399
-1.9591
-1.5073
-1.0820
-.6808
-.3018
.0568
.3966
.7190
1.0254
1.3169
1.5945
1.8592
2.1119
2.3534
2.5844
2.8056
3.0175
3.2208
3.4160
3.6034
3.7837
3.9571
4.1241
4.2850
4.4401
4.5898
4.7342
4.8738
5.0087
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
170и
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 327
3
1 2
,—, ly-) i?
2 ° " 4
^ II УО чС
~ —. ч
j, О ОС ГМ
•11 " ^ "^
* - [1
0 \^
*^щ 0
W ~
¦* ' J
г- о
Ч ^
— —
^ ё. ^
tri ^ S
— ^ 2
I ^ Y.-
i —
i I v
С С
о _: 'о
\С го —•
+ +
ос V: ^ч
О r-j
II |
^,
о
116

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3«00
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.652
46.040
55.119
55.270
62.309
67.409
71.038
73.634
75.522
76.922
77.983
78.801
79.444
79.956
80.371
80.712
80.994
81.230
81.430
81.600
81.746
81.873
81.983
82.080
82.165
82.241
82.308
82.367
82.421
82.470
82.513
82.553
82.589
82.622
82.652
82.679
82.704
82.728
82.749
82.769
82.787
82.804
82.820
82.835
82.849
82.862
82.874
82.885
82.896
82.906
-82.915
82.924
82.932
82.940
82.948
82.955
82.961
82.968
82.974
82.979
82.985
Ф°(Л
Дж • К . моль
205.544
229.844
245.533
245.792
258.405
269.100
278.484
286.882
294.497
301.472
307.907
313.881
319.458
324.686
329.608
334.256
338.659
342.843
346.827
350.630
354.268
357.753
361.099
364.317
367.415
370.402
373.286
376.073
378.770
381.383
383.917
386.376
388.764
391.086
393.345
395.544
397.687
399.776
401.813
403.803
405.746
407.644
409.500
411.316
413.093
414.833
416.537
418.207
419.844
421.450
423.025
424.572
426.089
427.580
429.044
430.483
431.898
433.289
434.657
436.003
437.328
ДИФТОРХЛОРМЕТИЛ CF;
о,.р(сп.р-(
5°(Л
1
239.242
267.066
287.210
287.552
304.467
318.951
331.580
342.737
352.699
361.679
369.841
377.313
384.199
390.579
396.520
402.077
407.295
412.212
416.861
421.268
425.458
429.449
433.261
436.907
440.402
443.758
446.985
450.092
453.089
455.982
458.779
461.485
464.106
466.648
469.115
471.51 ¦
473.841
476.107
478.314
480.464
482.559
484.604
486.599
488.548
490.453
492.315
494.136
495.919
497.664
499.373
501.048
502.690
504.300
505.880
507.431
508.952
510.447
511.916
513.359
514.777
516.172
п,сп Д,
Я°(Г)-Я°@)
кДж . моль
3.370
7.444
12.426
12.528
18.425
24.925
31.858
39.098
46.561
54.187
61.934
69.775
77.689
85.659
93.677
101.731
109.817
117.928
126.062
134.213
142.381
150.562
158.755
166.958
175.171
183.391
191.618
199.852
208.092
216.336
224.685
232.839
241.096
249.356
257.620
265.886
274.156
282.427
290.701
298.977
307.255
315.534
323.816
332.099
340.383
348.668
356.955
365.243
373.532
381.822
390.113
398.405
406.698
414.992
423.286
431.581
439.877
448.173
456.470
464.768
473.066
С1 (г)
Я°@)= 1258
.о
-644.0021
-313.5211
-204.3538
-202.9798
-147.5607
-114.2399
-91.9900
-76.0766
-64.1292
-54.8289
-47.3834
-41.2880
-36.2060
-31.9039
-28.2150
-25.0168
-22.2177
-19.74/1
-17.5506
-15.5848
-13.8153
-12.2139
-10.7579
-9.4283
-8.2093
-7.0877
-6.0522
-5.0932
-4.2026
-3.3733
-2.5992
-1.8749
-1.1958
-.5577
.0429
.6092
1.1442
1.6504
2.1300
2.5850
3.0174
3.4288
3.8206
4.1943
4.5511
4.8920
5.2182
5.5306
5.8300
6.1173
6.3931
6.6581
6.9130
7.1583
7.3946
7.6224
7.8420
8.0540
8.2587
8.4566
8.6478
.316 кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
420П
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб
-I
1
о
—
1 7
Ч II
х Q
11 С
5 _г
о
¦—
о
а;
+
-
к
m -
<N- о
Z
V '
гч 1.
г-
Я ?
о —¦
1 "**•
Ja +
го in
+ !
гч н
Оч чо
00
-о -ч-
¦* —'
II +
0
лица
i
л
3
.
о
о
о
г-1
1
00
гч
0
и- ¦
у.
а;
328
_
t
о
_'
i
о о:
Я
1
ЧО
V
"
V
о
о
u-l
«в
[
О
*7
"
117

Класс точности
VI-D
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
36.878
53.078
66.886
67.111
77.528
85.013
90.329
94.132
96.898
98.952
100.507
101.708
102.651
103.404
104.013
104.513
104.927
105.274
105.567
105.818
106.033
106.219
106.381
106.523
106.648
106.759
106.858
106.946
107.025
107.096
107.160
107.218
107.271
107.319
107.363
107.404
107.44!
107.475
107.507
107.536
107.563
107.588
107.611
107.633
107.653
107.672
107.690
107.707
107.722
107.737
107.751
107.764
107.776
107.788
107.799
107.809
107.819
107.828
107.837
107.845
107.853
ТРИФТОРХЛОРМЕТАН CF3C1 (г)
Ф° G)
Дж • К . моль
197.094
222.056
239.056
239.342
253.601
266.043
277.177
287.285
296.549
305.103
313.047
320.461
327.411
333.950
340.124
345.970
351.521
356.805
361.846
366.665
371.281
375.710
379.966
384.063
388.011
391.821
395.502
399.063
402.511
405.853
409.095
412.244
415.303
418.279
421.176
423.997
426.747
429.429
432.046
434.601
437.098
439.538
441.925
444.260
446.546
448.785
450.978
453.128
455.236
457.304
459.333
461.325
463.281
465.202
467.089
468.945
470.769
472.563 .
474.327
476.064
477.772
(F)-p(CU-p'
S°(T)
l
231.023
261.419
285.309
285.724
306.536
324.687
340.684
354.910
367.670
379.207
389.717
399.355
408.247
416.494
424.180
431.374
438.133
444.504
450.530
456.245
461.678
466.856
471.801
476.534
481.070
485.426
489.615
493.649
497.540
501.297
504.929
508.444
511.848
515.150
518.355
521.468
524.494
527.438
530.304
533.097
535.820
538.476
541.069
543.602
546.076
548.496
550.863
553.179
555.447
557.668
559.845
561.978
564.071
566.124
568.139
570.117
572.060
573.968
575.844
577.687
579.500
'(CF3C1) ДгЯ°@)= 1765.343
Я°(Г)-Н°@)
кДж . моль
3.393
7.873
13.791
13.914
21.174
29.322
38.104
47.338
56.896
66.694
76.670
86.784
97.003
107.307
117.679
128.106
138.579
149.089
159.632
170.201
180.794
191.407
202.037
212.683
223.341
234.012
244.693
255.383
266.081
276.788
287.500
298.219
308.944
319.673
330.407
341.146
351.888
362.634
373.383
384.135
394.890
405.648
416.408
427.170
437.934
448.700
459.468
470.238
481.010
491.783
' 502.557
513.333
524.110
534.888
545.667
556.448
567.229
578.012
588.795
599.579
610.364
-902.4718
-438.8418
-285.6987
-283.7714
-206.0381
-159.3093
-128.1124
-105.8052
-89.0612
-76.0302
-65.6004
-57.0640
-49.9484
-43.9263
-38.7637
-34.2891
-30.3736
-26.9187
•23.8476
-21.0999
-18.6270
¦16.3897
-14.3560
-12.4993
-10.7974
-9.2318
-7.7868
-6.4490
-5.2068
-4.0505
-2.9713
-1.9619
-1.0156
-.1268
.7096
1.4981
2.2428
2.9471
3.6143
4.2472
4.8484
5.4203
5.9648
6.4840
6.9795
7.4529
7.9057
8.3393
8.7547
9.1531
9.5356
9.9030
10.2562
10.5961
10.9234
11.2388
11.5429
11.8362
12.1195
12.3931
12.6576
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та б
-1
\а
с;
2
кДж •
Г-
W) t—
о* "
""" о
4 и'
с
и
w
о
+
1
s -
? '-о
с
го о
+ S
12
й ё
Я *
О rri
I CTn
J3 +
S ГО
"> й
2 2
+ i
00 [5
On 00
II +
0
V
ЛИЦ
А
О
о
о
ОО
г^
о
1
II
in
00
о
и?
а 329
'л
с^
Q
1
го
"
О К
to
Я
о
о
о
V
S-,
V
о
о
„¦*
'о
II
118

Класс точности
VI-F
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<п
37.671
50.121
59.120
59.264
65.805
70.318
73.417
75.578
77.123
78.255
79.104
79.755
80.263
80.667
80.992
81.259
81.479
81.663
81.819
81.951
82.065
82.163
82.248
82.323
82.389
82.447
82.499
82.546
82.587
82.624
82.658
82.689
82.716
82.742
82.765
82.786
82.806
82.824
82.840
82.855
82.870
82.883
82.895
82.906
82.917
82.927
82.936
82.945
82.953
82.961
82.968
82.975
82.981
82.987
82.993
82.998
83.004
83.008
83.013
83.017
83.022
ФТОРДИХЛОРМЕТИЛ CFC1
К°(Т) = р(С) • p(F) • р2(С1) • р~\
Ф°(Г)
Дж -К ¦ моль
212.741
237.855
254.472
254.747
268.171
279.530
289.455
298.296
306.280
313.562
320.260
326.459
332.230
337.628
342.699
347.479
352.001
356.290
360.370
364.260
367.977
371.535
374.947
378.225
381.380
384.419
387.352
390.184
392.924
395.577
398.147
400.641
403.062
405.415
407.703
409.930
412.099
414.213
416.274
418.286
420.250
422.169
424.045
425.879
427.674
429.431
431.152
432.837
434.490
436.110
437.699
439.258
440.789
442.292
443.768
445.219
446.645
448.047
449.425
450.781
452.115
S°(T)
1
246.913
277.020
298.801
299.168
317.169
332.369
345.481
356.970
367.169
376.321
384.612
392.183
399.146
405.587
411.577
417.174
422.426
427.371
432.043
436.471
440.677
444.684
448.508
452.165
455.671
459.035
462.270
465.384
468.387
471.286
474.087
476.798
479.424
481.970
484.440
486.840
489.172
491.441
493.650
495.802
497.900
499.946
501.944
503.894
505.801
507.664
509.487
511.271
513.017
514.728
516.404
518.047
519.658
521.239
522.790
524.313
525.808
527.277
528.721
530.140
531.536
CFClj) Дг#
кДж • моль
3.417
7.833
13.217
13.326
19.599
26.420
33.616
41.072
48.711
56.483
64.353
72.297
80.299
88.346
96.430
104.543
112.680
120.837
129.011
137.200
145.401
153.613
161.833
170.062
178.297
186.539
194.787
203.039
211.296
219.556
227.820
236.088
244.358
252.631
260.906
269.184
277.464
285.745
294.028
302.313
310.599
318.887
327.176
335.466
343.757
352.049
360.342
368.636
376.931
385.227
393.523
401.820
410.118
418.417
426.716
435.015
443.315
451.616
459.917
468.219
476.521
г (г)
°@)= 1131.274
-577.6126
-280.3646
-182.1840
-180.9483
-131.1135
-101.1527
-81.1467
-66.8381
-56.0951
-47.7319
-41.0363
-35.5545
-30.9839
-27.1145
-23.7964
-20.9197
-18.4017
-16.1793
-14.2033
-12.4348
-10.8428
-9.4022
-8.0922
-6.8959
-5.7991
-4.7898
-3.8581
-2.9952
О 1 OOQ
-2.1938
-1.4475
-.7509
-.0991
.5120
1.0862
1.6267
2.1365
2.6180
3.0735
3.5052
3.9147
4.3039
4.6742
5.0269
5.3633
5.6844
5.9913
6.2850
6.5662
6.8357
7.0943
7.3426
7.5813
7.8108
8.0316
8.2444
8.4495
8.6472
8.8381
9.0225
9.2006
9.3728
кДж • моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
полл
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб л и
~ §
a s
1 *
кДж
000 1
t"~ О
^ л "Т
^ ' Я
о " "¦>
О оо
II - О\
*** fN
^ ТЧ г*
г \ г\
0 У-
*С 0
i^
00
00
о 7
°5 а
гч О
С* _*
ч ^
Р Н
О <N
1 <П
? +
in ^
m 00
о Гч*-
оо оо
+ 1
ОО V
О ЧО
ОС О
II +
о
ца 330
§
»о
00*
II
"to5
я
о
о
V
V
8
V
•о
(Д
и
119

Класс точности
VI-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
380U
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сл
39.663
58.666
72.476
72.69!
82.408
89.063
93.635
96.832
99.121
100.800
102.062
103.030
103.787
104.388
104.874
105.271
105.599
105.874
106.106
106.304
106.474
106.621
106.748
106.860
106.959
107.046
107.123
107.193
107.255
107.310
107.361
107.406
107.448
107.486
107.520
107.552
107.581
107.608
107.633
107.656
107.677
107.696
107.715
107.732
107.748
107.763
107.776
107.789
107.802
107.813
107.824
107.834
107.844
107.853
107.861
107.870
107.877
107.885
107.891
107.898
107.904
ДИФТОРДИХЛОРМЕТАН
К°(Т)= р(С)
Ф°(Т)
Дж . К . мол
206.522
232.621
250.896
251.205
266.584
279.946
291.830
302.554
312.329
321.311
329.618
337.344
344.563
351.338
357.719
363.749
369.464
374.896
380.069
385.009
389.735
394.264
398.612
402.793
406.820
410.702
414.451
418.075
421.581
424.978
428.272
431.469
434.574
437.593
440.530
443.389
446.176
448.892
451.542
454.128
456.654
459.123
461.537
463.898
466.209
468.471
470.687
472.859
474.988
477.076
479.124
481.135
483.108
485.047
486.951
488.822
490.662
492.471
494.250
496.000
497.722
p2(F).p2(Cl)-p~
S°(T)
-1
ь
241.176
274.645
300.806
301.255
323.585
342.736
359.403
374.092
387.179
398.956
409.644
419.419
428.418
436.750
444.504
451,754
458.559
464.969
471.028
476.770
482.227
487.425
492.389
497.136
501.686
506.054
510.254
514.299
518.198
521.963
525.601
529.122
532.533
535.840
539.049
542.167
545.197
548.145
551.015
553.811
556.537
559.196
561.791
564.326
566.803
569.225
571.593
573.911
576.181
578.404
580.582
582.717
584.81!
586.866
588.882
590.861
592.805
594.714
596.591
598.435
600.248
(CF2C12)
CF2C12 (г)
Д Я°@)= 1586.801 кДж-моль
Ч0)
кДж . моль
3.465
8.405
14.881
15.015
22.800
31.395
40.544
50.076
59.880
69.880
80.026
90.283
100.625
111.035
121.499
132.007
142.551
153.125
163.725
174.345
184.984
195.639
206.308
216.988
227.680
238.380
249.088
259.804
270.527
281.255
291.988
302.727
313.469
324.216
334.966
345.720
356.477
367.236
377.998
388.763
399.529
410.298
421.069
. 431.841
442.615
453.391
464.167
474.946
485.725
496.506
507.288
518.071
528.855
539.640
550.425
561.212
571.999
582.787
593.576
604.366
615.156
-809.2990
-392.3688
-254.6582
-252.9253
-183.0341
-141.0235
-112.9782
-92.9251
-77.8734
-66.1593
-56.7836
-49.1099
-42.7134
-37.2999
-32.6591
-28.6366
-25.1168
-22.0110
-19.2503
-16.7803
-14.5574
-12.5463
-10.7181
-9.0491
-7.5193
-6.1120
-4.8131
-3.6106
-2.4941
•1.4547
-.4847
.4226
1.2731
2.0719
2.8237
3.5324
4.2017
4.8348
5.4344
6.0032
6.5436
7.0575
7.5469
8.0134
8.4588
8.8842
9.2912
9.6808
10.0541
10.4121
10.7558
11.0860
11.4035
11.7089
12.0030
12.2864
12.5596
12.8233
13.0778
13.3236
13.5613
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
™
'л 2
§ я
¦ *
п §
X о
Сч) ОО
2 Т
ОО СО ||
2- " ?
2 О оо'
^ <"* и
Ч, л
и Ч,
*Ч 0
<! ч
s _
1> '
'х '^
го
r~ j|
о н
1 1
с +
лз *
о ^
s 5
+ 1
OS' X
о *>
и +
0
©
ца 331
о
|
[^
СП
т?
II
0 К
«О
2
о
V
V
о
•Л
*""
1
О
^
II
120

Класс точности
VI-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сп
г
43.287
64.448
78.069
78.274
87.200
92.975
96.787
99.381
101.204
102.524
103.506
104.254
104.835
105.296
105.666
105.968
106.217
106.425
106.600
106.750
106.878
106.988
107.0S4
107.168
107.242
107.308
107.366
107.418
107.464
107.506
107.544
107.578
107.609
107.638
107.664
107.687
107.709
107.729
107.748
107.765
107.781
107.795
107.809
107.822
107.834
107.845
107.855
107.865
107.874
107.883
107.891
107.898
107.906
107.912
107.919
107.925
107.931
107.936
407.941
107.946
107.951
ФТОРТРИХЛОРМЕТАН CFC13
*V)*PCQ-P
Ф°{Т)
Дж ¦ К ¦ моль
208.569
236.098
255.795
256.128
272.703
287.026
299.684
311.036
321.329
330.743
339.415
347.452
354.941
361.950
368.537
374.749
380.627
386.204
391.509
396.567
401.401
406.029
410.468
414.732
418.836
422.790
426.605
430.290
433.854
437.305
440.649
443.893
447.043
450.104
453.081
455.978
458.800
461.550
464.232
466.849
469.404
471.901
474.341
476.728
479.062
481.348
483.586
485.779
487.929
490.036
492.103
494.132
496.123
498.078
499.999
501.886
503.740
505.564
507.357
509.121
510.856
(F).p3(C1).p
S°(T)
1
244.275
281.206
309.671
310.155
333.989
354.113
371.425
386.551
399.948
411.948
422.803
432.705
441.802
450.213
458.030
465.331
472.178
478.624
484.712
490.480
495.958
501.176
506.155
510.917
515.480
519.859
524.069
528.122
532.029
535.801
539.446
542.973
546.389
549.701
552.915
556.036
559.070
562.021
564.894
567.694
570.422
573.084
575.681
578.218
580.697
583.121
585.491
587.811
590.082
592.306
594.486
596.622
598.718
600.773
602.790
604.770
606.715
608.626-
610.503
612.348
614.162
(г)
"VCFCla) Д/.Я°@)= 1429.151
Я°(Г)-Я°@)
кДж . моль"
3.571
9.022
16.063
16.208
24.514
33.544
43.044
52.861
62.895
73.085
83.389
93.778
104.234
114.741
125.290
135.872
146.482
157.114
167.766
178.433
189.115
199.808
210.512
221.225
231.945
242.673
253.407
264.146
274.890
285.639
296.391
307.147
317.907
328.669
339.434
350.202
360.972
371.744
382.517
393.293
404.070
414.849
425.629
436.411
447.194
457.977
468.763
479:548
490.336
501.124
511.912
522.702
533.492
544.283
555.074
565.866
576.659
587.452
598.246
609.044
619.835
lgAT°(r)
-726.6533
-350.9819.
-226.9154
-225.3542
-162.3997
-124.5638
-99.3076
-81.2495
-67.6955
-57.1470
-48.7043
-41.7940
-36.0339
-31.1590
-26.9798
-23.3575
-20.1878
-17.3910
-14.9049
-12.6806
-10.6788
-8.8678
-7.2216
-5.7186
-4.3411
-3.0738
-1.9042
-.8214
.1840
1.1199
1.9933
2.8103
3.5760
4.2953
4.9722
5.6104
6.2130
6.7829
7.3228
7.8349
8.3214
8.7841
9.2247
9.6448
10.0457
10.4287
10.7951
11.1458
11.4819
11.8043
12.1137
12.4109
12.6967
12.9717
13.2364
13.4915
13.7375
13.9748
14.2039
14.4252
14.6391
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
И00
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2ё00
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл
-
-
о
_
ОО
¦* —'
ОО ОО
го 1
<~- II
"" о
п. '
о
а;
<J
-
+ i
4 -f
1 '*
О m
1 5
^ о5
о "
"* 00
s й
•О О\
II +
о
о
И Ц
•
i.000
ОО
гч
II
«о
ОО
С"»
и
m
р
6
4;
а 332
i
л
с;
о
7
к
сч
чг*
>/")
It
о g
§
о
о
о
V
&-,
V
о
о
«*"
о
II
121

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(л
40.141
55.034
62.626
62.734
67.487
70.852
73.440
75.517
77.217
78.619
79.781
80.747
81.554
82.232
82.805
83.292
83.707
84.065
84.373
84.641
84.875
85.081
85.262
85.422
85.565
85.692
85.807
85.909
86.002
86.086
86.162
86.231
86.294
86.352
86.405
86.454
86.499
86.540
86.579
86.614
86.647
86.678
86.707
86.733
86.758
86.782
86.804
86.824
86.843
86.862
86.879
86.895
86.910
86.924
86.938
86.951
86.963
86.975
86.986
86.996
87.006
ФТОРХЛОРАЦЕТИЛЕН C2FC1 (г)
K°(T) = p2(C)-p(F)-p(Cl)-
Ф°(Г)
S°(T)
Дж • К . моль
177.530
202.404
. 219.730
220.018
234.105
245.953
256.224
265.315
273.485
280.913
287.731
294.036
299.902
305.389
310.544
315.406
320.008
324.377
328.535
332.501
336.295
339.929
343.417
346.770
349.998
353.111
356.116
359.021
361.832
364.556
367.196
369.759
372.249
374.669
377.025
379.318
381.552
383.730
385.856
387.931
389.957
391.938
393.875
395.769
397.624
399.439
401.218
402.961
404.670
406.346
407.991
409.605
411.190
412.747
414.276
415.779
417.256
418.709
420.139
421.545
422.929
209.762
242.741
266.271
266.658
285.402
300.841
313.997
325.479
335.678
344.856
353.202
360.852
367.914
374.469
380.585
386.315
391.704
396.790
401.604
406.173
410.521
414.667
418.629
422.423
426.061
429.557
432.920
436.160
439.286
442.306
445.225
448.052
450.791
453.447
456.026
458.531
460.967
463.338
465.646
467.895
470.089
472.229
474.318
476.358
478.352
480.302
482.210
484.077
485.905
487.696
489.451
491.172
492.859
494.515
496.140
497.735
499.302
500.841
502.354
503.841
505.303
p~l(C2FCl) Д,А
Я°(Г)-Я°@)
кДж • моль
3.223
8.067
13.876
13.992
20.519
27.444
34.664
42.115
49.755
57.549
65.470
73.498
81.615
89.805
98.058
106.363
114.714
123.103
131.525
139.976
148.452
156.950
165.467
174.002
182.551
191.114
199.689
208.275
216.871
225.475
234.088
242.707
251.334
259.966
268.604
277.247
285.894
294.546
303.202
311.862
320.525
329.191
337.860
346.532
355.207
363.884
372.5б"з
381.245
389.928
398.613
407.300
415.989
424.679
433.371
442.064
450.759
459.454
468.151
476.849
485.548
494.248
г°@) = 1588.265 кДж • моль
-815.0040
-398.3083
-260.8478
-259.1189
-189.4178
-147.5460
-119.6039
-99.6292
-84.6383
-72.9726
-63.6361
-55.9946
-49.6250
-44.2344
-39.6131
-35.6076
-32.1026
-29.0098
-26.2607
-23.8009
-21.5873
-19.5845
-17.7639
-16.1017
-14.5781
-13.1765
-11.8828
-10.6851
-9.5729
-8.5376
-7.5713
-6.6674
-5.8201
-5.0241
-4.2751
-3.5688
-2.9018
-2.2709
1.6732
•1.1062
-.5675
-.0551
.4329
.8981
1.3423
1.7667
2.1727
2.5614
2.9339
3.2912
3.6342
3.9638
4.2807
4.5857
4.8794
5.1625
5.4354
5.6988
5.9531
6.1988
6.4363
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
_
О
•" ?
2 ?
¦ 3
о ^
Tf ° "
Ч » !л
" о ' »'
" с S
5 _• и-
U. -Г
г* О
^ с*
*> ¦-¦
^ а;
„+
о 7 ¦
2 1
о „
о 3
1 д
к +
оо Н
^ го
+ 1
00 Н
О ГО
V> ^
4fr ОО
тГ го
II +
о -
а 333
"л
о
_•
1
о
го
СЧ
II
0 05
to
я
§
V
V
о
о
»""
о
II
122

Класс точности
Т
К
100
200
298.
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
VI-F
с°пт
46.923
68.807
15 83.915
84.151
95.060
103.163
109.236
113.812
117.290
119.963
122.046
123.690
125.005
126.070
126.942
127.664
128.268
128.778
129.211
129.582
129.903
130.181
130.425
130.638
130.827
130.995
131.144
131.277
131.397
131.506
131.603
131.692
131.773
131.847
131.914
131.976
132.033
132.085
132.134
132.179
132.220
132.259
132.295
132.328
132.359
132.389
132.416
132.442
132.466
132.488
132.510
132.530
132.549
132.567
132.584
132.600
132.615
132.629
132.643
132.656
132.668
ТРИФТОРХЛОРЭТИЛЕН C2F3C1
К°(Т) = р2(С) • р
Ф°(Г)
Дж • К . моль
214.703
243.861
264.825
265.181
282.896
298.296
312.012
324.415
335.754
346.204
355.899
364.942
373.416
381.388
388.914
396.042
402.811
409.256
415.405
421.285
426.919
432.325
437.521
442.524
447.346
452.001
456.499
460.851
465.066
469.152
473.117
476.967
480.710
484.350
487.894
491.347
494.712
497.994
501.198
504.327
507.384
510.372
513.295
516.155
518.955
521.698
524.385
527.019
529.602
532.136
534.623
537.064
539.461
541.816
544.130
546.405
548.641
550.840
553.004
555.133
557.229
3(F)-P(C1).
S°(T)
i
252.253
291.796
322.272
322.792
348.575
370.702
390.074
407.272
422.707
436.683
449.435
461.147
471.968
482.017
491.393
500.176
508.436
516.228
523.601
530.597
537.252
543.597
549.659
555.461
561.025
566.369
571.510
576.462
— а л Л А Л
581.238
585.851
590.311
594.628
598.810
602.866
606.803
610.628
614.347
617.965
621.488
624.921
628.268
631.533
634.721
637.834
640.877
643.852
646.762
649.610
652.398
655.130
657.807
660.431
663.004
665.530
668.008
670.441
672.830
675.177
677.484
679.752
681.981
p~l(C2F3Cl) Arh
кДж . моль
3.755
9.587
17.128
17.283
26.272
36.203
46.837
58.000
69.563
81.431
93.536
105.826
118.263
130.819
143.471
156.202
169.000
181.852
194.752
207.692
220.667
233.672
246.702
259.756 .
272.829
285.920
299.027
312.148
f\ Ар ЛЛ Л
325.282
338.428
351.583
364.748
377.921
391.102
404.290
417.485
430.685
443.892
457.102
470.318
483.538
496.762
509.9*90
523.221
536.455
549.693
562.933
576.176
589.421
602.669
615.919
629.171
642.425
655.681
668.938
682.197
695.458
708.720
721.984
735.249
748.515
(г)
1°@)= 2261.009
-1156.4885
-562.7888
-366.7749
-364.3088
-264.8531
-205.0822
-165.1862
-136.6627
-115.2555
-98.5972
-85.2658
-74.3556
-65.2623
-57.5673
-50.9714
-45.2551
-40.2536
-35.8409
-31.9189
-28.4103
-25.2530
-22.3969
-19.8009
-17.4311
-15.2592
-13.2614
-11.4177
-9.7110
-8.1264
-6.6515
-5.2752
-3.9879
-2.7813
-1.6481
-.5818
.4234
1.3726
2.2703
3.1206
3.9271
4.6932
5.4217
6.1155
6.7768
7.4081
8.0111
8.5878
9.1399
9.6690
10.1763
10.6633
11.1311
11.5809
12.0136
12.4302
12.8316
13.2187
13.5921
13.9525
14.3007
14.6373
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600 ,
5700
5800
5900
6000
Т а б
-1
. i
д
с?
fN ОС
О ^f
5 '
чс' "
Z Q
и t-
5 г-
r-t
У
о
<
-
i 7
+ ~
7 7
"* к
1 ^
о ос
1 *~-
в +
Ж г)
О Н
— 00
гч •"".
4- 1
^ 1
гч ><
Г- 1"^
2 =?
*/->
Till +
о
©
л и
_
о
о
о
еК
\
it
ос
с-
_¦
m
0
ч
3 1Л
ц а 334
-
3
"""
о)
II
о з:
«о
2
о
\й
V
ь~
V
о
о
«'"
'о
II
123

Класс точности
VII—
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500'
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100.
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
F
С°(Т)
Р
49.143
72.420
89.504
89.788
103.082
112.452
118.619
122.587
125.166
126.891
128.086
128.946
129.586
130.077
130.463
130.774
131.028
131.239
131.418
131.570
131.700
131.814
131.913
132.000
132.077
132.146
132.208
132.263
132.313
132.358
132.399
132.436
132.470
132.501
132.530
132.556
132.581
132.603
132.624
132.643
132.661
132.678
132.694
132.708
132.722
132.735
132.747
132.758
132.769
132.779
132.789
132.798
132.806
132.814
132.822
132.829
132.836
132.842
132.848
132.854
132.860
ДИФТОРДИХЛОРЭТИЛЕН C2F2
к^-Ао-р
Ф°(Г)
Дж • К . моль
220.118
250.119
271.976
272.348
290.988
307.339
321.996
335.295
347.463
358.668
369.044
378.699
387.723
396.191
404.164
411.696
418.831
425.609
432.063
438.222
444.112
449.754
455.169
460.374
465.384
470.214
474.875
479.380
483.737
487.958
492.049
496.018
499.873
503.620
507.265
510.812
514.268
517.636
520.922
524.128
527.260
530.319
533.310
536.235
539.097
541.899
544.644
547.333
549.969
552.554.
555.089
557.577
560.020
562.419
564.775
567.090
569.366
571.603
573.803
575.968
578.098
2(F)'P2(C1)
S°(T)
1
258.262
299.893
332.132
332.686
360.434
384.511
405.599
424.205
440.754
455.603
469.037
481.288
492.536
502.929
512.583
521.595
530.044
537.994
545.500
552.610
559.362
565.790
571.925
577.791
583.410
588.803
593.987
598.978
603.789
608.433
612.921
617.263
621.468
625.545
629.501
633.343
637.077
640.710
644.247
647.692
651.050
654.326
657.524
660.646
663.697
666.680
669.598
672.452
675.248
677.985
680.668
683.298
685.876
688.406
690.889
693.326
695.720
698.071
700.381
702.652
704.885
p~l(C2F2Cl2) ДгА
H°(T)-H°@)
кДж . моль
3.814
9.955
17.935
18.101
27.778
38.586
50.162
62.237
74.633
87.241
99.994
112.848
125.776
138.760
151.788
164.850
177.940
191.054
204.187
217.337
230.500
243.676
256.863
270.059
283.262
296.474
309.691
322.915
336.144
349.377
362.615
375.857
389.102
402.351
415.602
428.857
442.114
455.373
468.634
481.898
495.163
508.430
521.698
534.969
548.240
561.513
574.787
588.062
601.339
614.616
627.894
641.174
654.454
667.735
681.017
694.300
707.583
720.867
734.151
747.436
760.722
С12 (г)
(°@)= 2151
о
-1099.3464
-534.2109
-347.6445
-345.2973
-250.6538
-193.7907
-155.8481
-128.7306
-108.3851
-92.5575
¦79.8941
-69.5328
¦60.8988
-53.5936
-47.3328
-41.9076
¦37.1613
-32.9743
-29.2532
-25.9246
-22.9296
-20.2204
-17.7581
-15.5105
-13.4508
-11.5563
-9.8080
-8.1896
-6.6872
-5.2887
-3.9838
-2.7634
-1.6195
-.5453
.4656
1.4185
2.3182
3.1691
3.9750
4.7395
5.4656
6.1561
6.8136
7.4404
8.0386
8.6102
9.1567
9.6799
10.1812
10.6620
11.1235
11.5668
11.9930
12.4030
12.7978
13.1781
13.5448
13.8986
14.2402
14.5701
14.8890
Т а б л и
.848 кДж • моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-
'л
о
СО
ОС
1О
го
ОС го
¦* 1
СЧ
го О
II
5 р1
см
см
о
°а:
i
i^
г-
+ °
сч ^
'* т'
? к
О ^
. | . 00
X """.
? см
со" On
—' -Ч-
гч +
О "ч
VN ОО
S in
II 1
О
е
-
1
СО
со
г-
го
1
и
я
<ч
•-*
о"
>.
*<|
ч.
ц а 335
"л
с;
о
i
.-'
г-',
*—ч
On
°\
"*'
11
О DS
Я
о
о
о
V
f—
V
о
о
...
1
—
II
124

Класс точности
VI-F
Т
К
100
200
' 298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
330G
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
СЧТ)
49.143
72.005
86.974
87.207
97.842
105.580
111.287
115.539
118.745
121.196
123.098
124.595
125.790
126.755
127.545
128.198
128.744
129.204
129.594
129.929
130.218
130.469
130.688
130.881
131.051
131.201
131.336
131.456
131.564
131.661
131.749
131.829
131.901
131.968
132.028
132.084
132.135
132.182
132.226
132.266
132.303
132.338
132.370
132.400
132.428
132.454
132.479
132.502
132.524
132.544
132.563
132.581
132.598
132.614
132.629
132.644
132.657
132.670
132.682
132.694
132.705
1,1-ДИФТОРДИХЛОРЭТИЛЕН 1,1-C2F2C12 (г)
Ф°(Г)
— 1 -
Дж • К . моль
214.357
244.352
266.126
266.496
284.882
300.826
314.986
327.756
339.400
350.109
360.025
369.258
377.897
386.014
393.668
400.910
407.781
414.317
420.549
426.504
432.207
437.676
442.930
447.986
452.858
457.558
462.099
466.490
470.742
474.863
478.860
482.741
486.512
490.180
493.750
497.227
500.615
503.919
507.144
510.292
513.368
516.374
519.314
522.191
525.007
527.764
530.466
533.114
535.710
538.257
540.756
543.209
545.618
547.984
550.308
552.593
554.840
557.048
559.221
561.359
563.464
2(F)-p:(Cl)-p
S°(T)
1
262.502
294.074
325.805
326.344
352.972
375.680
395.460
412.950
428.597
442.731
455.603
467.409
478.303
488.411
497.834
506.657
514.949
522.768
530.164
537.180
543.852
550.212
556.287
562.100
567.674
573.027
578.176
583.134
587.917
592.536
597.001
601.322
605.508
609.568
613.509
617.337
621.059
624.679
628.205
631.640
634.989
638.257
641.446
644.561
647.605
650.582
653.493
656.343
659.132
661.865
664.543
667.168
669.743
672.269
674.748
677.182
679.572
681.920
684.228
686.496
688.726
(C2F2CI2) Дг#°@)= 2151.
Н°(Г)-Н°@)
кДж . моль
3.814 -1099.0448
9.944 -533.9093
17.793 -347.3387
17.954 -344.9914
27.236 -250.3347
37.427 -193.4504
48.285 -155.4819
59.636 -128.3367
71.358 -107.9639
83.360 -92.1104
95.579 -79.4229
107.966 -69.0396
120.488 -60.3855
133.116 -53.0620
145.833 -46.7846
158.621 -41.3442
171.469 -36.5841
184.367 -32.3844
197.307 -28.6518
210.284 -25.3125
223.291 -22.3077
236.326 -19.5895
249.384 -17.1188
262.463 -14.8635
275.560 -.12.7965
288.672 -10.8952
301.799 -9.1406
314.939 -7.5163
ifia ллл f* /\/\q л
328.090 -6.0084
341.251 -4.6047
354.422 -3.2949
367.60! -2.0699
380.787 -.9217
393.981 .1568
407.181 1.1715
420.386 2.1281
• 433.597 3.0313
446.813 3.8856
460.033 4.6947
473.258 5.4622
486.487 6.1912
499.719 6.8845
512.954 7.5447
526,192 8.1740
539.434 8.7746
552.678 9.3485
565.925 9.8973
579.174 10.4226
592.425 10.9260
605.679 11.4088
618.934 11.8721
632.191 12.3173
645.450 12.7452
658.711 13.1570
671.973 13.5534
685.236 13.9353
698.502 14.3036
711.768 14.6589
725.036 15.0019
738.304 15.3332
751.574 15.6534
Таблица 336
848 кДж - моль '
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
_а
• МОЛ1
3 X1
* о
х °- -
00 1
ОС fi Л
00 i^, П
vO | О
? 11 .
fi — ~*
ос "¦;
^. S °° ?
s ° я • 5
" иГ % ^ .
~t ! OR
С- М- ^
0 •*"'
**» 0
^ а;
-
X.
S -
"° с
m
+ ,¦
м I
° к Я
О OV V
17 v
0
¦* гч О
О? - ^
* 00 *t
Я о 'о
+1 Т ~
? о? н
О W}
чо m
и +
0
125

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Л
р
49.048
72.478
87.604
87.835
98.426
106.116
111.772
115.972
119.127
121,532
123.393
124.854
126.018
126.958
127.725
I2&359
128.888
129.334
129.713
130.037
130.316
130.559
130.771
130.957
131.121
131.266
131.396
131.512
131.616
131.710
131.795
131.872
131.942
132.006
132.064
132.118
132.167
132213
132.255
132.294
132.330
132.363
132.394
132.423 .-
132.450
132.475
132.499
132.521
132.542
132.562
132.580
132.598
132.614
132.629
132.644
132.658
132.671
132.683
132.695
132.706
132.717
цис-ДИФТОРДИХЛОРЭТИЛЕН
G*) = р (С) ¦ р (F
Дж ¦ К • моль
214.446
244.593
266.478
266.850
285.344
301.384
315.624
328.464
340.168
350.929
360.890
370.163
378.837
386.985
394.668
401.934
408.828
415.384
421.635
' 427.608
433.325
438.809
444.076
449.144
454.028
458.738
463.289
467.690
471.950
476.079
480.084
483.972
487.750
491.424
495.000
498.482
501.876
505.186
508.415
511.568
514.648
517.659
520.603
523.484
526.303
529.065
531.770
534.421
537.021
539.570
542.072
544.528
546.940
549.308
551.635
553.923
556.171
558.382
560.558
562.698
564.804
)V<ci)-P-'
5°(Г)
252.906
294.531
326.496
327.039
353.842
376.676
396.549
414.110
429.812
443.988
456.893
468.725
479.640
489.766
499.203
508.038
516.339
524.167
531.570
538.592
545.270
551.634
557.712
563.530
569.107
574.462
579.613
584.574
589.359
593.979
598.446
602.769
606.957
611.018
614.959
618.788
622.511
626.133
629.659
633.095
636.445
639.713
642.903
646.019
649.063
652.040
654.952
657.802
660.592
663.325
666.004
668.629
671.204
673.730
676.209
678.644
681.034
683.382
685.690
687.958
690.189
(C2F2C12)
цис-С2?2С12 (г)
ДгЯ°@)= 2139.160 кДж-моль
Я°G>Я°@)
кДж • моль
3.846
9.988
17.895
18.057
27.399
37.646
48.555
59.952
71.715
83.753
96.003
108.418
120.964
133.614
146.350
159.155
172.018
184.930
197.883
210.871
223.888
236.932
249.999
263.086
276.190
289.309
302.443
315.588
328.744
341.911
355.086
368.270
381.460
394.658
407.861
421.071
434.285,
447.504
460.728
473.955
487.186
500.421
513.659
526.900
540.143
553.389
566.638
579.889
593.143
606.398
619.655
632.914
646.174
659.436
672.700
685.965
699.232
712.499
725.768
739.039
752.309
-1092.4221
-530.6083
-345.1342
-342.8006
-248.7019
-192.1541
-154.4107
-127.4270
-107.1756
-91.4169
-78.8054
-68.4844
-59.8823
-52.6030
-46.3634
-40.9559
-36.2246
-32.0503
-28.3403
-25.0213
-22.0348
-19.3331
-16.8775
-14.6358
-12.5814
-10.6918
-8 9479
-7.3335
-5.8348
-4.4397
-3.1379
-1.9204
-.7792
.2926
1.3011
2.2518
3.1495
3.9985
4.8027
5.5655
6.2900
6.9790
7.6351
8.2606
8.8575
9.4278
9.9732
10.4954
10.9956
11.4754
11.9359
12.3783
12.8036
13.2128
13.6068
13.9864
14.3524
14.7055
15.0463
15.3756
15.6938
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5i00
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
i
2
1
g
о
со
CS
СО
1
II
00 ^
S! °"
?! J*
-1 и
II [?*
^ и
1
3
•-'
0
+
7
3 к
+
с» Т
00 •
ч ?
О "*5
? +
о ^
5 Ц
+ i
S 3
О ГЛ
II +
0
-
МОЛ1
*
—1
ГЦ
VI
ел
|
II
-;
00
и
г*
1-4
и
1
а
ч.
ц а 337
Л
5
о
(У*
•*'
0-К
to
ЪА
о
о
о
V
*¦"
V
о
о
1
о
II
126

Класс точности
VI-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛЛЛЛ
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°
С°(Т)
49.731
72.547
87.570
87.802
98.403
106.098
111.756
115.956
119.113
121.519
123.381
124.844
126.009
126.949
127.717
128.352
128.882
129.328
129.707
130.032
130.312
130.555
130.767
130.953
131.118
131.263
131.393
131.510
1 О 1 Л 1 А
131.614
131.708
131.793
131.870
131.940
132.004
132.063
132.117
132.166
132.21
132.253
132.292
132.328
132.362
132.393
132.422
132.449
132.475
132.498
132.520
132.541
132.561
132.579
132.597
132.613
132.629
132.643
132.657
132.670
132.683
132.695
132.706
132.717
транс-ДИФТОРДИХЛОРЭТИЛЕН
G) = p2(C)p2(F)
Ф°G-)
Дж ¦ К ¦ моль
214.700
245.155
267.169
267.542
286.100
302.176
316.441
329.297
341.014
351.784
361.752
37-1.031
379.710
387.862
395.548
402.817
409.713
416.272
422.525
428.499
434.218
439.703
444.972
450.041
454.925
459.637
464.188
468.590
<7Q QR 1
472.551
476.980
480.986
484.874
488.653
492.328
495.904
499.387
502.781
506.091
509.321
512.474
515.555
518.566
521.510
524.391
527.211
529.973
532.678
535.329
537.929
540.479
542.982
545.438
547.849
550.218
552.545
554.832
557.081
559.293
561.468
563.608
565.715
р2(С1)-р'
5°(Г)
253.585
295.483
327.446
327.989
354.784
377.613
397.483
415.042
430.742
444.916
457.820
469.651
480.565
490.690
500.127
508.961
517.262
525.089
532.492
539.514
546.191
552.555
558.633
564.450
570.027
575.383
580.534
585.495
594.90Ц
599.366
603.689
607.877
611.938
615.879
619.708
623.431
627.053
630.579
634.015
637.365
640.632
643.823
646.938
649.983
652.960
655.872
658.721
661.512
664.244
666.923
669.548
672.124
674.650
677.129
679.563
681.953
684.302
686.609
688.878
691.108
'(C2F2C12)
Н°(Т)-Н°
транс—С2 F2C1
ДгЯ°@)= 2138
@)
кДж . моль"
3.888
10.066
17.972
18.134
27.474
37.719
48.626
60.021
71.782
83.819
96.068
108.482
121.027
133.676
146.411
159.215
172.078
184.989
197.941
210.929
223.946
236.990
250.056
263.142
276.246
289.365
302.498
315.643
328.800
341.966
355.141
368.324
381.515
394.712
407.915
421.124
434.338
447.557
460.781
474.008
487.239
500.474
513.711
526.952
540.196
553.442
566.691
579.941
593.195
606.450
619.707
632.965
646.226
659.488
672.752
686.017
699.283
712.551
725.820
739.090
752.361
lgAT°G-)
-1091.9134
-530.3766
-344.9954
-342.6630
-248.6109
-192.0910
-154.3663
-127.3959
-107.1545
-91.4035
-78.7982
-68.4823
-59.8844
-52.6086
-46.3721
-40.9672
-36.2382
-32.0660
-28.3578
-25.0404
-22.0553
-19.3549
-16.9005
-14.6600
-12.6065
-10.7178
-8.9748
-7.3612
(- Q?<> 1
-O.8OOI
-4.4688
-3.1676
-1.9507
-.8100
.2612
1.2693
2.2195
3.1168
3.9654
4.7692
5.5316
6.2557
6.9444
7.6002
8.2254
8.8220
9.3920
9.9372
10.4590
10.9591
11.4386
11.8989
12.3411
12.7662
13.1752
13.5690
13.9484
14.3142
14.6671
15.0078
15.3369
15.6550
2 (г)
160 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ООАП
28U0
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
-
-
оль"
2
к
о
О
о
гч
гч
го
1
II
00 °
11 5*
^ 1
>ь
о
+
-
'я
00 1
• о
гО у
w Т
8408'
' Дж
о .?
О оо
' г4
¦5 +
О ***
|? о5
ел •
¦ 1
Т 1
оо X
w> rs
о <*.
VO ГО
II +
о
е
1
2
го
¦*¦
1
1
ы
00*
о
О
а;
0
338
i
А
О
__•
1
.
ON

Till
0 К
to
2
0
0
0
VD
V
V
0
«о
...
У-»
^,
и
127

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
лалл
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
п
ФТОРТРИХЛОРЭТИЛЕН С2ГС1:
К°(Т) = р2(С) • p(F) ¦ р3(С1) • р
Ф°G)
S°(T)
Дж • К . моль
52.206
76.171
91.030
91.257
101.511
108.781
114.025
117.863
120.718
122.878
124.541
125.841
126.873
127.704
128.381
128.940
129.405
129.797
130.129
130.414
130.659
130.871
131.057
131.220
131.363
131.491
131.604
131.706
131.797
131.879
131.953
132.020
132.081
132.137
132.188
132.235
132.278
132.318
132.354
132.388
132.420
132.449
132.476
132.501
132.525
132.547
132.567
132.587
132.605
132.622
132.638
132.653
132.668
132.681
132.694
132.706
132.717
132.728
132.738
132.748
132.757
225.273 264.933
256.714 309.092
279.654 342.480
280.043 343.044
299.366 370.789
316.059 394.266
336.825 414.588
344.094 432.468
356.155 448.403
367.215 462.751
377.43,1 475.788
386.922 487.721
395.786 498.716
404.101 508.906
411.930 518.395
419.326 527.272
426.336 535.609
432.997 543.466
439.343 550.895
445.401 557.939
451.196 564.634
456.751 571.015
462.085 577.107
467.213 582.936
472.152 588.524
476.915 593.889
481.514 599.049
485.960 604.017
490.262 608.809
494.430 613.435
498.472 617.907
502.395 622.235
506.206 626.428
509.911 630.493
513.516 634.438
517.026 638.271
520.445 641.997
523.780 645.621
527.033 649.151
530.208 652.589
533.310 655.941
536.341 659.211
539.305 662.404
542.204 665.521
545.041 668.567
547.820 671.546
550.541 674.459
553.208 677.310
555.823 680.102
558.387 682.837
560.903 685.516
563.372 688.143
565.796 690.719
568.177 693.246
570.516 695.726
572.815 698.161
575.075 700.552
577.297 702.902
579.482 705.210
581.633 707.479
583.749 709.710
C2FC13) АгП
Я°(Г)-Я°@)
кДж ¦ моль
3.966
10.476
18.732
18.900
28.569
39.104
50.258
61.862
73.798
85.983
98.357
110.879
123.516
136.247
149.052
161.919
174.837
187.797
200.794
213.822
226.876
239.952
253.049
266.163
279.292
292.435
305.590
318.756
331.931
345.114
358.306
371.505
384.710
397.921
411.137
424.358
437.584
450.814
464.048
477.285
490.525
503.768
517.015
530.264
543.515
556.768
570.024
583.282
596.541
609.803
623.066
636.331
649.596
662.864
676.133
689.403
702.674
715.946
729.219
742.494
755.769
, (г)
°@) = 2022.954 кДж • моль
ЫК°(Т)
Т
К
-1031.8835 100
-500.4970 200
-325.0846 298.15
-322.8779 300
-233.8923 400
-180.4206 500
-144.7319 600
-119.2173 700
-100.0687 800
-85.1679 900
-73.2431 1000
-63.4840 1100
-55.350! 1200
-48.4670 1300
-42.5670 1400
-37.4538 1500
-32.9801 1600
-29.0331 1700
-25.5250 1800
-22.3867 1900
-19.5627 2000
-17.0082 2100
-14.6863 2200
-12.5668 2300
-10.6243 2400
-8.8376 2500
-7.1887 2600
-5.6623 2700
Л Aid ООА/Ъ
-4.2453 2800
-2.9263 2900
-1.6955 3000
-.5444 3100
.5346 3200
1.5479 3300
2.5014 3400
3.4002 3500
4.2489 3600
5.0516 3700
5.8118 3800
6.5330 3900
7.2179 4000
7.8693 4100
8.4895 4200
9.0808 4300
9.6451 4400
10.1843 4500
10.6998 4600
11.1934 4700
11.6663 4800
12.1199 4900
12.5552 5000
12.9734 5100
13.3754 5200
13.7622 5300
14.1346 5400
14.4934 5500
14.8394 5600
15.1732 5700
15.4954 5800
15.8066 5900
16.1074 6000
?
СТч
—|
II
Таблица 339
i
с
— о
'a s
О м
* о Т
1 I S
И о о
3 ~ "С
чо |1 Л
II Jo d
О ¦ со сг\
^ <ч ю*
^ m "
% U о g
0 ^J
<
+
-
н
г^- '
Ч о
+
S и °
" ^^ о
§•"* s
о 5 v
Л 7 v
° ? ¦"
гл то
0
128

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°{Т)
34.405
43.300
52.396
52.545
59.407
64.390
68.086
70.879
73.021
74.684
75.993
77.036
77.876
78.561
79.125
79.594
79.987
80.320
80.605
80.849
81.060
81.244
81.405
81.546
81.672
81.783
81.882
81.971
82.051
82.123
82.188
82.247
82.301
82.350
82:396
82.437
82.475
82.510
82.542
82.572
82.600
82.626
82.650
82.673
82.693
82.713
82.731
82.749
82.765
82.780
82.794
82.808
82.820
82.832
82.844
82.854
82.865
82.874
82.883
82.892
82.900
ОКСЙД-ФТОРИД-ХЛОРИД УГЛЕРОДА FC1CO (г)
K-Cn-lXF).,
Ф°G-)
Дж • К . моль
197.801
221.589
236.668
236.915
248.985
259.208
268.176
276.206
283.497
290.184
296.364
302.112
307.486
312.533
317.291
321.791
326.061
330.123
333.996
337.697
341.241
344.641
347.907
351.050
354.080
357.002
359.826
362.558
f\ Г? Г ПАП
365.203
367.766
370.253
372.668
375.015
377.297
379.519
381.683
383.792
385.849
387.857
389.817
391.732
393.605
395.436
397.227
398.981
400.699
402.382
404.031
405.649
407.236
408.793
410.321
411.822
413.296
414.745
416.169
417.569
418.946
420.300
421.633
422.944
(Cl)-p(Q-p(O)
S°(T)
1
231.237
257.537
276.593
276.917
293.027
306.847
318.930
329.645
339.256
347.956
355.895
363.189
369.929
376.191
382.034
387.509
392.659
397.518
402.118
406.483
410.635
414.595
418.378
422.000
425.473
428.809
432.019
435.111
438.093
440.974
443.759
446.455
449.067
451.600
454.060
456.448
458.771
461.032
463.232
465.377
467.468
469.508
471.499
473.444
475.345
477.204
479.022
480.801
482.543
484.250
485.923
487.562
489.171
490.748
492.296
493.817
495.310
496.776
498.218
499.635
501.028
/f'(FClCO) Д
Я°(Г)-Я°@)
кДж ¦ моль
3.344
7.190
11.904
12.001
17.617
23.820
30.452
37.407
44.606
51.995
59.532
67.185
74.932
82.755
90.640
98.577
106.556
114.572
122.619
130.692
138.787
146.903
155.035
163.183
171.344
179.517
187.700
195.893
204.094
212.303
220.519
228.740
236.968
245.200
253.438
261.679
269.925
278.174
286.427
294.683
302.941
311.203
319.466
327.733
336.001
344.271
352.543
360.818
369.093
377.370
385.649
393.929
402.211
410.493
418.777
427.062
435.348
443.635
451.923
460.212
468.501
Я°@)= 1581.863 кДж моль
о
7"
К
-812.5856 100
-397.5270 200
-260.4896 298.15
¦258.7653 300
-189.2272 400
-147.4300 500
-119.5252 600
-99.5699 700
-84.5890 800
-72.9279 900
-63.5927 1000
-55.9503 1100
-49.5786 1200
-44.1848 1300
-39.5597 1400
-35.5501 1500
-32.0406 1600
-28.9431 1700
-26.1892 1800
-23.7246 1900
-21.5061 2000
-19.4984 2100
-17.6730 2200
-16.0060 2300
•14.4777 2400
-13.0714 2500
-11.7732 2600
-10.5709 2700
-9.4543 2800
-8.4146 2900
¦7.4441 3000
-6.5361 3100
-5.6847 3200
-4.8847 3300
-4.13)8 3400
-3.4217 3500
-2.7510 3600
-2.1164 3700
-1.5152' 3800
-.9447 3900
-.4026 4000
.1132 4100
.6044 4200
1.0729 4300
1.5202 4400
1.9477 4500
2.3567 4600
2.7484 4700
3.1238 4800
3.4839 4900
3.8298 5000
4.1621 5100
4.4818 5200
4.7894 5300
5.0858 5400
5.3714 5500
5.6469 5600
5.9128 5700
6.1695 5800
6.4177 5900
6.6576 6000
оо
II
<
Таблица 340
о ^
S г-}
i - 'й
О On
О Tf I
-а- " i
,: ? *
,-, — °
О од чО
о с
о - "
ь а *
о ц.
г-j S
х •
3 * *
"* о
§ ? V
1 6 *-
* 7 v
Я ^ ^
40 го
* I
[^- ГЧ
I 1
т 1 •
оо X К
t— m II
Tt ОО
II +
129

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°1Т)
*°(П = Р(О
Ф°(Г)
ФТОРХЛОРМЕТИЛ CHFC1
•p(H)p(F)-p(Cl)
S°(T)
Дж • К . моль
34.334
39.253
45.075
45.190
51.225
56.393
60.532
63.825
66.480
68.656
70.462
71.977
73.256
74.345
75.276
76.076
76.768
77.369
77.893
78.353
78.757
79.114
79.431
79.713
79.966
80.192
80.396
80.580
80.746
80.897
81.035
81.160
81.275
81.381
81.478
81.567
81.649
81.725
81.796
81.861
81.922
81.979
82.032
82.081
82.128
82.171
82.212
82.250
82.286
82.319
82.351
82.381
82.410
82.436
82.462
82.486
82.509
82.530
82.551
82.571
82.589
192.977
216.592
231.009
231.241
242.375
251.628
259.681
266.877
273.416
279.425
284.997
290.197
295.076
299.674
304.024
308.153
312.082
315.832
319.418
322.855
326.154
329.326
332.382
335.328
338.174
340.925
343.588
346.169
348.671
351.101
353.461
355.756
357.990
360.166
362.286
364.353
366.370
368.339
370.263
372.144
373.983
375.782
377.543
379.268
380.957
382.613
384.237
385.829
387.392
388.926
390.432
391.912
393.305
394.794
396.198
397.580
398.938
400.275
401.591
402.886
404.161
226.429
251.659
268.392
268.671
282.511
294.516
305.178
314.766
323.468
331.428
338.758
345.547
351.866
357.774
363.319
368.540
373.473
378.145
382.582
386.807
390.836
394.687
398.375
401.912
405.310
408.580
411.729
414.766
417.700
420.536
423.281
425.940
428.519
431.021
433.452
435.815
438.114
440.352
442.533
444.659
446.732
448.756
450.732
452.662
454.550
456.396
458.203
459.971
461.703
463.400
465.063
466.695
468.295
469.864
471.406
472.919
474.405
475.866
477.301
478.713
480.101
•p-'tCBFCl) Д
H°(T)-H°(G)
кДж . моль
3.345
7.013
11.146
11.229
16.055
21.444
27.298
33.522
40.042
46.803
53.761
60.885
68.149
75.530
83.012
90.581
98.224
105.932
113.695
121.508
129.364
137.258
145.186
153.143
161.127
169.135
177.165
185.214
193.280
201.362
209.459
217.569
225.691
233.824
241.967
250.119
258.280
266.448
274.625
282.808
290.997
299.192
307.392
315.598
323.808
332.024
340.243
348.466
356.692
364.923
373.156
381.393
389.632
397.875
406.120
414.367
422.617
430.869
439.123
447.379
455.637
(г)
,.Я°@) = 1204.114 кДж-моль'
-617.2482
-300.8986
-196.3430
-195.0266
-141.9073
-109.9419
-88.5785
-73.2867
-61.7970
-52.8466
-45.6766
-39.8032
-34.9036
-30.7539
-27.1941
-24.1067
-21.4034 ¦
-19.0168
-16.8941
-14.9940
-13.2830
-11.7344
-10.3260
-9.0396
-7.8600
.-6.7744
-5.7720
-4.8436
-3.9812
-3.1781
-2.4284
-1.7268
-1.0689
-.4507
.1313
.6801
1.1986
1.6892
2.1540
2.5952
3.0144
3.4132
3.7931
4.1554
4.5014
4.8321
5.1484
5.4514
5.7418
6.0204
6.2880
6.5451
6.7924
7.0304
7.2596
7.4806
7.6937
7.8994
8.0981
8.2901
8.4757
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л
1
-
1 ja
§
о
о
— о
о =°
Г- 1
•«t ||
vO о
II , U*
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к!
У
о
<
+
1
V) —
ЯЭ 1
о "
(N 7
'* *
О
ГЧ —f
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сч
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3 —
+ !
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5 ' %¦.
II +
о
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И Ц
л
г^
о
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го
[
II
to
ОС
CN
^1
_^
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X
О
а 341
7
о
2
1
.
1—1
ОО
If
ч
о •к:]
/—¦
О
о
о
чо
V
S-,
V
о
II
Ч
130

Класс точности
VI-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
F
к
34.287
39.576
47.045
47.200
55.571
63.062
69.287
74.410
78.669
82.251
85.289
87.881
90.103
92.014
93.664
95.093
96.336
97.422
98.372
99.209
99.947
100.601
101.183
101.703
102.168
102.585
102.962
103.302
103.610
103.891
104.146
104.379
104.593
104.789
104.969
105.136
105.289
105.431
105,563
105.685
105.799
105.904
106.003
106.096
106.182
106.263
106.339
106.410
106.477
106.541
106.600
106.656
106.710
106.760
106.807
106.852
106.895
106.936
106.974
107.011
107.046
ФТОРХЛОРМЕТАН CH2FC1 (г)
Ф°(Г)
— 1 "*
Дж • К . миль
188.495
21 2.100
226.574
226.808
238.137
247.72!
256.216
263.935
271.054
277.684
283.904
289.768
295.321
300.598
305.626
310.431
315.031
319.444
323.686
327.769
331.704
335.503
339.175
342.727
346.167
349.502
352.739
355.883
358.939
361.911
364.805
367.624
370.373
373.053
375.670
378.225
380.722
383.163
385.550
387.886
390.173
392.413
394.608
396.760
398.869
400.939
402.970
404.964
406.921
408.844
410.734
412.592
414.418
416.214
417.981
419.719
421.431
423.115
424.774
426.408
428.017
¦p(F)-p(Cl)V(CH2FCl) Afl
s°m
i
я°(л-//°@)
кДж . моль
221.936 3.344
247.182 7.016
264.314 11.252
264.605 11.339
279.338 16.481
292.566 22.423
304.633 29.050
315.711 36.243
325.933 43.904
335.412 ¦ 51.955
344.239 60.336
352.493 68.998
360.237 77.900
367.527 87.008
374.408 96.294
380.920 105.733
387.097 115.306
392.971 124.995
398.567 134.786
403.909 144.666
409.016 154.624
413.909 164.653
418.603 17 4.7 42
423.112 184.887
427.451 195.081
431.630 205.319
435.661 215.597
439.553 225.910
443.316 236.256
446.956 246.631
450.483 257.033
453.902 267.460
457.219 277.909
460.441 288.378
463.572 298.866
466.617 309.371
469.581 319.892
472.468 330.429
475.281 340.978
478.025 351.541
480.702 362.115
483.316 372.700
485.869 383.296
488.364 393.900
490.804 404.515
493.191 415.137
495.528 425.767
497.816 436.404
500.057 447.049
502.253 457.700
504.406 468.357
506.517 479.020
508.589 489.688
510.622 500.361
512.618 511.040
514.578 521.723
516.504 532.410
518.396 543.102
520.256 553.798
522.085 564.497
523.884 575.200
Ч°@)= 1602.880 кДж-моль
Т
К
-821.5910 100
-400.3424 200
-261.0720 298.15
-259.3181 300
-188.5390 400
-145.9341 500
-117.4528 600
-97.0616 700
-81.7378 800
-69.7990 900
-60.2340 1000
-52.3983 1100
-45.8615 1200
-40.3252 1300
-35.5759 1400
-31.4570 1500
-27.8508 1600
-24.6672 1700
-21.8360 1800
-19.3019 1900
-17.0204 2000
-14.9556 2100
-13.0780 2200
-11.3633 2300
-9.7912 2400
-8.3447 2500
-7.0092 2600
-5.7725 2700
-4.6241 2800
-3.5547 2900
-2.5566 3000
-1.6228 3100
-.7473 3200
.0751 3300
.8492 3400
1.5791 3500
2.2684 3600
2.9205 3700
3.5382 3800
4.1243 3900
4.6811 4000
5.2107 4100
5.7151 4200
6.1960 4300
6.6551 4400
7.0937 4500
7.5133 4600
7.9150 4700
8.3000 4800
8.6692 4900
9.0237 5000
9.3642 5100
9.6917 5200
10.0067 5300
10.3101 5400
10.6025 5500
10.8844 5600
11.1564 5700
11.4190 5800
11.6727 5900
11.9180 6000
Таблица 342
-1
-
7 °
3 i
? 5
* ~ "л
r-f О -О
^ о ч
* о о
СЧ г~> «Ь
«~1 4 -—. *
?2 м ^ Ч
з с ? °
11 Л oi з
S О с-
5 Ч* о g
°-~ У..
3s Ч,
_+
{н -
•Л 1
г-1 Л
ос S
r-i
+ 1
КЗ 2
~ч О
ГО t*i о
СЧ О §
§ 2 у
2 + v
- "х §
г. О О
г.; as i
^ i 2
Г-4 ОО ||
•* о а
¦5- 2
и +
о
е
131

Класс точности
V1-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с°т-
р
А'°(Л=р(С)
Ф°(Г)
ДИФТОРХЛОРМЕТАН CHF2
p(H)-p2(F)-p(Cl)-p"'(CHF2Cl) &rh
S°(T)
Дж • К . моль
35.309
45.557
55.853
56.039
65.395
73.008
78.940
83.551
87.185
90.100
92.475
94.433
96.065
97.438
98.601
99.593
100.445
101.181
101.820
102.378
102.867
103.298
103.680
104.019
104.321
104.592
104.835
105.055
105.253
105.433
105.597
105.746
105.882
106.007
106.122
106.228
106.325
106.416
106.499
106.577
106.649
106.716
106.778
106.836
106.891
106.942
106.990
107.035
107.077
107.М7
107.155
107.190
107.224
107.255
107.285
107.314
107.341
107.366
107.390
107.413
107.435
199.584
223.752
239.328
239.585
252.206
263.057
272.729
281.519
289.606
297.108
304.112
310.684
316.876
322.732
328.288
333.572
338.611
343.426
348.038
352.461
356.712
360.803
364.746
368.551
372.228
375.784
379.227
382.565
385.803
388.948
392.004
394.977
397.870
400.689
403.436
406.115
408.730
41 1.283
413.778
416.216
418.601
420935
423.219
425.457
427.649
429.798
431.904
433.971
436.000
437.990
439.945
441.865
443.752
445.607
447.430
449.223
450.988
452.723
454.432
456.113
457.769
233.202
260.677
280.808
281.154
298.594
314.038
327.897
340.426
351.829
362.273
371.892
380.801
389.090
396.835
404.100
410.937
417.393
423.505
429.307
434.827
440.091
445.120
449.935
454.551
458.985
463.249
467.356
471.317
475.141
478.838
482.415
485.880
489.239
492.499
495.666
498.744
501.737
504.652
507.491
510.258
512.957
515.592
518.164
520.677
523.134
525.537
527.888
530.189
532.443
534.652
536.816
538.938
541.020
543.063
545.068
547.036
548.970
550.871
552.738
554.574
556.380
кДж . моль
3.36-2
7.385
12.367
12.471
18.555
25.491
33.101
41.235
49.779
58.648
67.781
77.129
86.656
96.333
106.137
116.048
126.051
136.133
146.284
156.495
166.757
177.066
187.415
197.800
208.218
218.664
229.135
239.630
250.145
260.680
271.231
281.799
292.380
302.975
313.581
324.199
334.827
345.464
356.110
366.763
377.425
388.093
398.768
409.448
420.135
430.827
441.523
452.224
462.930
473.640
484.353
495.071
505.791
516.515
527.242
537.972
548.705
559.440
570.178
580.918
591.661
Cl (г)
'°@)= 1670.057
-855.0448
-416.2702
-271.2634
-269.4376
-195.7843
-151.4760
-121.8742
-100.6933
-84.7850
-72.3974
-62.4775
-54.3547
-47.5810
-41.8461
-36.9282
-32.6642
-28.9321
-25.6380
-22.7093
-20.0884
-17.7293
-15.5945
-13.6537
-11.8815
-10.2568
-8.7621
-7.3824
-6.1048
-4.9185
-3.8141
-2.7832
-1.8189
-.9149
-.0657
.7335
1.4870
2.1986
2.8717
3.5093
4.1142
4.6889
5.2355
5.7560
6.2523
6.7260
7.1786
7.6116
8.0260
8.4232
8.8042
9.1699
9.5212
9.8590
10.1841
10.4970
10.7986
11.0894
11.3700
11.6409
11.9026
12.1555
кДж • моль
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
i
5 c5
^ о
cj о
00 */~'
vO ¦*
Ж '
*O II
[— ^1"
oo 1 О
чо as
4 12
oo ° °°
и u ^'
^ 4, u-
? G
x iT
~^ 3"^
0 О
^ 0
<1 4
+
7
2 T
~ о
+ 7
ГЧ r^
*-? 00
¦S ^
о ^
¦4- 
""¦ ON
CO "">
+ 1
—I OS
\Q ГЧ
0
e
ца 343
-
'л
о
¦
о
о
о
1
о tx
Я
О
о
V
к.
V
о
о
¦'"
'о
к".
II
132

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
и
37.673
50.188
61.009
61.196
70.241
77.196
82.441
86.454
89.600
92.124
94.186
95.894
97.325
98.532
99.560
100.440
101.197
101.853
102.424
102.923
103.362
103.749
104.092
104.398
104.670
104.915
105.134
105.333
105.512
105.675
105.823
105.958
106.082
106.195
106.299
106.395
106.484
106.566
106.641
106.712
106.777
106.838
106.895
106.948
106.998
107.044
107.088
107.129
107.167
107.203
107.238
107.270
107.300
107.329
107.356
107.382
107.407
107.430
107.452
107.473
107.493
К\Т)=р(О-
Ф°(Г)
ФТОРДИХЛОРМЕТАН CHFC1
p(H)p(F)- p2(Cl)-p~\CHFCl2) ArH'
S°(T)
Дж • К . моль
206.844
231.959
248.599
248.875
262468
274.148
284.513
293.884
302.457
310.372
317.729
324.605
331.062
337.151
342.911
348.378
353.580
358.542
363.286
367.830
372.191
376.382
380.417
384.307
388.062
391.692
395.203
398.604
401.902
405.101
408.210
411.231
414.171
417.033
419.821
422.539
425.190
427.779
430.307
432.776
435.192
437.554
439.866
442.129
444.347
446.519
448.649
450.738
452.788
454.799
456.773
458.712
460.617
462.489
464.330
466.139
467.919
469.670
471.393
473.089
474.759
241.082
271.077
293.188
293.566
312.461
328.918
343.478
356.501
368.259
378.963
388.780
397.839
406.246
414.085
421.426
428.325
434.832
440.988
446.826
452.377
457.668
462.721
467.555
472.189
476.638
480.916
485.035
489.007
492.840
496.546
500.131
503.603
506.969
510.235
513.407
516.490
519.488
522.407
525.250
528.021
530.724
533.361
535.936
538.452
540.911
543.316
545.670
547.973
550.229
552.439
554.605
556.729
558.812
560.856
562.863
564.833
566.768
568.669
570.538
572.375
574.182
Я°(Л-Я°@)
кДж > моль
3.424
7.824
13.294
13.407
19.997
27.385
35.379
43.832
52.641
61.732
71.050
80.557
90.220
100.014
109.920
119.922
130.004
140.158
150.372
160.640
170.955
181.311
191.703
202.128
212.581
223.061
233.564
244.087
254.629
265.189
275.764
286.353
296.955
307.569
318.194
328.828
339.473
350.125
360.785
371.453
382.128
392.808
403.495
414.187
424.884
435.587
446.293
457.004
467.719
478.437
489.159
499.885
510.613
521.345
532.079
542.816
553.556
564.297
575.041
585.788
596.536
2 (Г)
'@)= 1518
kA'of7")
-775.6723
-376.6307
-244.7552
-243.0950
-176.1165
-135.8260
-108.9090
-89.6492
-75.1834
-63.9187
-54.8978
-47.5108
-41.3505
-36.1349
-31.6621
-27.7840
-24.3895
-21.3934
-18.7296
-16.3457
-14.1999
-12.2582
-10.4928
-8.8808
-7.4031
-6.0436
-4.7886
-3.6265
-2.5475
-1.5428
-.6052
.2719
1.0941
1.8665
2.5935
3.2788
3.9261
4.5383
5.1183
5.6685
6.1911
6.6883
7.1617
7.6131
8.0440
8.4556
8.8494
9.2263
9.5876
9.9341
10.2667
10.5862
10.8934
11.1890
11.4737
11.7480
12.0124
12.2676
12.5139
12.7519
12.9820
Т а б л и
.152 кДж -моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
л
к
о
'
со
Ч
m ^
°i II
сч
2 °
и t-
ы,
X
и
0
+
7
(й -
чо ^
00 2
гч 7
+ 7
2 k
1 (N
К +
2 -
О\ m
СО "^
+ 1
m X
О О
гН °°.
ON Ч-'
Tt ЧО
II +
g
о
©
ОЛЬ
2
О
о
ОС
1
II
я
-*.
СО*
и
X
У-
ца 344
_
'л
с
о
2
г*'
(§
о
с--
Tf
0 g
со
я
о
о
ЧО
V
К
V
о
о
'о
^.
II
133

Класс точности
VI- F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
i 5300
: 5400
5500
5600
5700
5800
5900
6000
р
35.483
50.806
68.334
68.634
82.304
91.520
97.855
102.542
106.257
109.338
111.958
114.214
116.170
117.871
119.356
120.654
121.793
122.794
123.678
124.459
125.152
125.769
126.320
126.814
127.257
127.657
128.018
128.345
128.642
128.912
129.159
129.385
129.592
129.782
129.958
130.120
130.269
130.408
130.536
130.656
130.767
130.871.
130.968
131.058
131.143
131.223
131.297
131.368
131.434
131.496
131.555
131.610
131.662
131.712
131.759
131.803
131.846
131.886
131.924
131.960
131.995
ФТОРХЛОРЭТИЛЕН C2H2FC1
К°(Т) = p2(C>p2(H)-p(F)-p(Cl)
Ф°(П
— 1 *"
Дж • К . моль
198.389
222.782
239.251
239.531
253.626
266.198
277.635
288.137
297.849
306.880
315.321
323.247
330.717
337.783
344.488
350.868
356.953
362.770 .
368.343
373.691
378.831
383.780
388.551
393.157
397.610
401.918
406.091
410.137
414.064
417.879
421.588
425.196
428.710
432.133
435.470
438.726
441.904
445.008
448.042
451.008
453.910
456.750
459.531
462.255
464.924
467.541
470.107
472.625
475.097
477.523
479.906
482.247
484.548
486.809
489.033
491.221
493.373
495.491
497.576
499.«28
501.650
S°(T)
1
232.018
260.800
284.426
284.850
306.587
326.011
343.290
358.742
372.685
385.384
397.043
407.822
417.846
427.213
436.004
444.284
452.108
459.522
466.566
473.274
479.676
485.798
491.661
497.288
502.694
507.897
512.911
517.749
— АЛ Ж Л {\
522.422
526.941
531.316
535.554
539.666
543.656
547.533
551.303
554.971
558.542
562.021
565.413
568.723
571.953
575.108
578.191
581.205
584.153
587.038
589.862
592.629
595.339
597.996
600.602
603.158
605.667
608.129
610.547
612.923
615.256
617.550
619.806
622.024
(г)
р'\с2Н2УС1) ДгЯ°@)= 2210.333
Я°G>-Яо@)
кДж . моль
3.363
7.604
13.469
13.596
21.184
29.906
39.393
49.423
59.869
70.653
81.722
93.033
104.S54
116.258
128.121
140.123
152.247
164.477
176.802
189.209
201.691
214.237
226.842
239.499
252.203
264.949
277.733
290.552
303.401
316.279
329.183
342.110
355.059
368.028
381.015
394.019
407.039
420.073
433.120
446.180
459.251
472.333
485.425
498.526
511.636
524.755
537.880
551.014
564.154
577.300
590.453
603.611
616.775
629.944
643.117
656.295
669.478
682.664
695.855
709.049
722.247
-1133.5952
-552.9037
-361.0485
-358.6338
-261.2306
-202.6656
-163.5576
-135.5854
-114.5827
-98.2320
-85.1412
-74.4235
-65.4872
-57.9223
-51.4358
-45.8124
-40.8909
-36.5475
-32.6863
-29.2312
-26.1214
-23.3077
-20.7498
-18.4144
-16.2737
-14.3043
-12.4866
-10.8036
-9.2410
-7.7863
-6.4287
-5.1589
-3.9685
-2.8504
-1.7982
-.8062
.1305
1.0165
1.8557
2.6519
3.4081
4.1274
4.8123
5.4653
6.0885
6.6840
7.2535
7.7987
8.3211
8.8222
9.3032
9.7652
10.2094
10.6368
11.0484
11.4449
11.8272
12.1961
12.5522
12.8962
13.2287
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
- о
1 2
с;
о х
i i
Ч о
о ^
§ т
о ° ?
оо ь. ?5
" С- и*
О Я
а; о"
-
н
+ —
О m
о Ч
1 3i
с +
° 22
§ «
+ X
О\ 00
СТ\ ОО
чс г^
о о
о
©
ца 345
—
'л
¦ о
1
¦
00
ГО
II
0 К
03
2
о
о
VO
V
t-l
V
о
•о
«""
'о
к,
II
,х
134

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
35.476
49.672
64.214
64.462
76.234
85.264
92.259
97.824
102.367
106.150
109.338
112.048
114.365
116.354
118.070
119.555
120.846
121.972
122.959
123.826
124.592
125.271
125.874
126.413.
126.895
127.328
127.718
128.071
128.390
128.681
128.945
129.187
129.409
129.612
129.799
129.971
130.130
130.277
130.414
130.540
130.658
130.768
130.870
130.966
131.056
131.140
131.218-
131.292
131.362
131.427
131.489
131.547
131.602
131.655
131.704
131.751
131.795
131.837
131.877
131.915
131.951
1,1- ФТОРХЛОРЭТИЛЕН
1,1-C2H2FC1 (г)
К°(Т) =p2(C)-p2(H)p(F)p(Cl)p(C2H2FCl) ДгЯ°@) = 2210.333 кДж • моль"
Ф°(Г)
Дж ¦ К ¦ моль
198.393
222.759
239.028
239.302
252.963
264.977
275.834
285.788
295.004
303.594
311.647
319.231
326.400
333.200
339.669
345.837
351.733
357.379
362.797
368.004
373.017
377.849
382.513
387.020
391.380
395.603
399.698
403.671
407.529
411.280
414.929
418.481
421.941
425.314
428.604
431.815
434.951
438.015
441.011
443.941
446.808
449.615
452.364
455.058
457.698
460.288
462.828
465.321
467.768
470.171
472.532
474.852
477.132
479.373
481.578
483.747
485.881
487.982
490.050
492.086
494.092
S°(T)
1
232.021
260.601
283.229
283.627
303.857
321.882
338.072
352.727
366.096
378.378
389.731
400.283
410.134
419.369
428.056
436.254
444.012
451.373
458.373
465.045
471.416
477.512
483.353
488.961
494.351
499.540
504.542
509.369
514.032
518.543
522.910
527.142
531.247
535.232
539.104
542.870
546.533
550.100
553.577
556.966
560.272
563.500
566.652
569.733
572.745
575.691
578.574
581.397
584.162
586.871
589.527
592:132
594.686
597.194
599.655
602.072
604.446
606.780
609.073
611.328
613.545
Я°(Г)-Я°@)
кДж . моль
3.363
7.569
13.178
13.297
20.358
28.452
37.343
46.857
56.874
67.305
78.084
89.157
100.480
112.019
123.742
135.625
147.647
159.789
172.036
184.376
196.798
209.292
221.850
234.465
247.131
259.842
272.594
285.384
298.207
311.061
323.943
336.850
349.780
362.731
375.701
388.690
401.695
414.716
427.750
440.798
453.858
466.929
480.011
493.103
506.204
519.314
532.432
545.558
558.691
571.830
584.976
598.128
611.285
624.448
637.616
650.789
663,966
677.148
690.333
703.523
716.716
-1133.5954
-552.9026
-361.0368
-358.6218
-261.1960
-202.6019
-163.4635
-135.4627
-114.4341
-98.0604
-84.9493
-74.2138
-65.2617
-57.6830
-51.1840
-45.5496
-40.6182
-36.2659
-32.3966
-28.9342
-25.8177
-22.9979
-20.4344
-18.0938
¦15.9483
-13.9745
-12.1526
-10.4658
-8.8997
-7.4416
-6.0809
-4.8081
-3.6149
-2.4942
-1.4396
-.4453
.4937
1.3818
2.2230
3.0210
3.7791
4.5001
5.1866
5.8412
6.4659
7.0628
7.6337
8.1802
8.7039
9.2062
9.6883
10.1515
10.5968
11.0253
11.4378
11.8353
12.2186
12.5883
12.9453
13.2902
13.6235
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 346
о *
2 et
§ 2 V-
5 ' о
Т 2 ™'
& о\ S
ОО ^" (Ч п
^: -.
? о u- ?
11 я % *
"^ г \ Он .,
V сч 'I
-1 О «
С -1 to
о *"*
Э; о
< ^L
+
7 _
m -'
+ 'j^
I
5 Й i
S mx о
CO \r\
q S V
° 2 *""
н + v
s "g 8
о 1 V"
r-l ' &• о
+ X (•
s s »
"
с
о
о
135

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
к
С°р(Т)
38.158
48.773
61.529
61.765
73.502
82.925
90.316
96.193
100.973
104.936
108.267
111.094
113.508
115.581
117.368
118.916
120.263
121.438
122.468
123.374
124.175
124.885
125.516
126.080
126.584
127.038
127.447
127.817
128.152
128.457
128.735
128.989
129.221
129.434
129.631
129.812
129.979
130.133
130.277
130.410
130.534
130.649
130.757
130.857
130.952
131.040
131.123
131.200
131.274
131.342
131.407
131.469
131.527
131.582
131.633
131.683
131.729
131.774
131.816
131.856
131.894
цыс-ФТОРХЛОРЭТИЛЕН цис-С2Н2
W(cMh).p
Ф°(Г)
Дж • К . моль
198.792
224.060
240.565
240.839
254.405
266.225
276.873
286.632
295.671
304.105
312.020
319.480
326.539
333.241
339.620
345.708
351.531
357.111
362.468'
367.619
372.580
377.364
381.984
386.450
390.772
394.960
399.021
402.963
406.792
410.515
414.138
417.665
421.102
424.452
427.722
430.913
434.030
437.077
440.055
442.968
445.820
448.612
451.347
454.027
456.655
459.232
461.760
464.241
466.677
469.069
471.420
473.729
476.000
478.232
480.428
482.588
484.714
486.806
488.867
490.896
492.894
S°(T)
233.506
262.976
284.822
285.203
304.632
322.088
337.887
352.267
365.434
377.562
388.796
399.251
409.024
418.193
426.826
434.977
442.696
450 023
456.994
463.640
469.989
476.065
481.890
487.482
492.858
498.035
503.026
507.843
512.497
517.000
521.359
525.585
529.684
533.664
537.530
541.291
544.950
548.513
551.986
555.372
558.675
561.899
565.049
568.127
571.136
574.080
576.961
579.782
582.545
585.253
587.907
590.509
593.063
595.569
598.029
600.445
602.818
605.150
607.442
609.696
611.912
FC1 (г)
"'(CjHjFCl) Д/.Я°@)= 2200
Я°(Г)-Я°@)
кДж . моль
3.471
7.783
13.195
13.309
20.091
27.931
36.608
45.944
55.810
66.111
76.776
87.748
98.981
110.438
122.088
133.904
145.864
157.951
170.147
182.440
194.818
207.272
219.793
232.373
245.007
257.688
270.413
283.176
295.975
308.806
321.665
334.552
347.462
360.395
373.348
386.321
399.310
412.916
425.337
438.371
451.418
464.478
477.548
490.629
503.719
516.819
529.927
543.043
556.167
569.298
582.435
595.579
608.729
621.884
635.045
648.211 -
661.382
674.557
687.736
700.920
714.107
о
-1128.3928
-550.3589
-359.3651
-356.9608
-259.9653
-201.6224
-162.6472
-134.7606
-113.8161
-97.5067
-84.4464
-73.7519
-64.8337
-57.2832
-50.8084
-45.1947
-40.2812
-35.9446
-32.0892
-28.6391
-25.5337
-22.7238
-20.1693
-17.8369
-15.6989
-13.7319
-11.9164
-10.2354
-8.6746
-7.2215
-5.8654
-4.5970
-3.4079
-2.2910
-1.2399
-.2489
.6869
1.5720
2.4104
3.2058
3.9613
4.6798
5.3641
6.0165
6.6391
7.2341
7.8031
8.3478
8.8697
9.3704
9.8509
10.3125
10.7564
11.1834
11.5946
11.9908
12.3728
12.7414
13.0972
13.4409
13.7731
.333 кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
. 1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
7ё
о
п
о
о
о-
2
1
и
оо
"*¦ —1
о <->
°° ^
1! 3?
1
3
о
+
S s
2 -"
+
° m
g» 5
s °.
q —'
О
1 +
О с-
¦"": о
& 7
+ X
ГЛ ОО
00 ГЦ
II +
о
в
о
1
vn
!
II
?
оо'
'¦{
0
Я?
О*
1
а
а 347
'л
с
о
_¦
I
k
оо
СП
II
0 (К
О}
?
о .
о
V
к
V
о
о
¦""
'о
II
136

Класс точности
VI-F
Т
¦К
100
200
298.15
¦ 300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
39.211
51.722
63.372
63.588
74.525
83.556
90.750
96.520
101.235
105.154
108.455
111.258
113.653
115.711
117.485
119.022
120.359
121.525
122.548
123.448
124.242
124.947
125.574
126.133
126.634
127.084
127.490
127.857
128.190
128.492
128.768
129.020
129.250
129.462
129.657
129.836
130.002
130.155
130.298
130.430
130.553
130.667
130.774
130.874
130.967
131.055
131.137
131.214
131.287
131.355
131.419
131.480
131.538
131.592
131.644
131.692
131.739
131.782
131.824
131.864
131.902
грянс-ФТОРХЛОРЭТИЛЕН TpaHC-C2H2FCl (г)
3(Т) =р2(С)-р2(Н)
Ф°(Г)
Дж • К . моль
196.548
222.219
239.323
239.607
253.640
265.796
276.689
286.634
295.818
304.369
312.380
319.920
327.047
333.807
340.238
346.370
352.232
357.848
363.236
368.416
373.403
378.211
382.852
387.338
391.678
395.883
399.959
403.916
407.759
411.494
415.129
418.667
422.114
425.475
428.754
431.954
435.079
438.133
441.119
444.040
446.898
449.697
452.438
455.124
457.757
460.339
462.873
465.359
467.800
470.197
472.551
474.865
477.140
479.376
481.575
483.739
485.869
487.965
490.028
492.060
494.062
•p(F)-p(Cl)-p~
S"(T)
1
231.249
262.392
285.218
285.611
305.441
323.078
338.973
353.411
366.617
378.774
390.029
400.501
410.287
419.467
428.109
436.268
443.994
451.326
458.302
464.952
471.305
477.384
483.211
488.806
494.185
499.364
504.356
509.175
513.831
518.334
522.695
526.921
531.021
535.002
538.870
542.631
546.291
549.855
553.328
556.714
560.018
563.243
566.393
569.471
572.481
575.425
578.307
581.128
583.891
586.599
589.253
591.856
594.410
596.916
599.376
601.792
604.165
606.497
608.790
611.044
613.260
(C2H2FC1)- ArH°@)= 2197.833
Я°(Г)-Я°@)
кДж . моль
3.470
8.035
13.684
13.801
20.721
28.641
37.370
46.744
56.639
66.964
77.649
88.639
99.887
111.358
123.020
134.847
146.818
158.913
171.118
183.419
195.804
208.264
220.791
233.377
246.016
258.702
271.431
284.199
297.001
309.836
322.699
335.589
348.502
361.438
374.394
387.369
400.361
413.369
426.392
439.428
452.477
465.538
478.610
491.693
504.785
517.886
530.996
544.113
557.238
570.370
583.509
596.654
609.805
622.962
636.123
649.290
662.462
675.638
688.818
702.003
715.191
-1 126.9691
-549.6096
-358.8622
-356.4611
-259.5987
-201.3387
-162.4199
-134.5741
-1 13.6605
-97.3754
-84.3346
-73.6561
-64.7514
-57.2124
-50.7474
-45.1422
-40.2362
-35.9063
-32.0568
-28.6120
-25.5114
-22.7059
¦20.1553
-17.8265
-15.6918
-1-3.7279
-i 1.9152
-10.2368
-8.6785
-7.2276
-5.8737
-4.6072
-3.4200
-2.3048
-1.2554
-.2660
.6683
1.5521 L
2.3892
3.1833
3.9376
4.6550
5.3382
5.9896
6.6112
7.2052
7.7733
8.3172
8.8383
9.3381
9.8179
10.2788
10.7219
11.1483
11.5589
11.9544
12.3358
12.7038
13.0590
13.4022
13.7339
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
иоль
X
о
-2
;*
7
it
о
,_-
S -
О м
" О
§ 1
ж
1
0
о
-
ri
+
[
X
3
О f
о
о
1
о
+
—
о ¦
©
б л и
§
X
г~
ее
<о
1
II
—
wo
—:
OV
fN
U-
3?
N
I
д;
<г
л
3
—<
1
—
+
ц! 348
1
я
О
!
Г-
ОС
гО
II
о 5
2
о
О
О
V
V
о
»'"
1
о
II
137

Класлточности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
41.822
59.008
76.647
76.951
90.890
100.246
106.459
110.802
114.034
116.564
118.614
120.313
121.743
122.959
124.000
124.898
125.677
126.355
126.948
127.470
127.930
128.338
128.701
129.025
129.315
129.575
129.810
130.023
130.215
130.391
130.550
130.696
130.830
130.953
131.066
131.170
131.266
131.355
131.438
131.514
131.586
131.652
131.714
131.772
131.826
131.877
131.925
131.970
132.012
132.052
132.090
132.125
132.158
132.190
132.220
132.249
132.276
132.301
132.325
132.349
132.371
ДИФТОРХЛОРЭТИЛЕН C2HF
A'V)-V(C).P(
Ф°(Г)
Дж ¦ К . моль
207.401
234.269
252.935
253.252
269.171
283.27Q
296.017
307.661
318.376
328.296
337.530
346.164
354.271
361.912
369.138
375.991
382.508
388.721
394.656
400.339
405.788
411.023
416.060
420.914
425.597
430.121
434.496
438.732
л л л л t\ ж\
442.838
446.820
450.688
454.446
458.101
461.658
465.123
468.500
471.794
475.008
478.146
481.212
484.209
487.140
490.008
492.816
495.565
498.260
500.900
503.489
506.029
508.521
510.968
513.370
515.730
518.049
520.328
522.568
524.772
526.940
529.073
531.172
533.239
H)/?2(F)-p(Cl)p
S°(T)
1
243.120
277.209
304.125
304.600
328.766
350.126
З68.*988
385.743
400.760
414.342
426.733
438.120
448.652
458.446
467.597
476.184
484.270
491.910
499.149
506.027
512.578
518.829
524.808
530.536
536.034
541.318
546.405
551.308
556.040
560.613
565.036
569.319
573.471
577.498
581.409
585.210
588.907
592.504
596.009
599.424
602.754
606.004
609.178
612.277
615.308
618.271
621Л70
624.008
626.786
629.509
632.177
634.793
637.359
639.877
642.348
644.774
647.157 .
649.499
651.800
654.062
656.287
Я°(П-"°@)
кДж • моль
3.572
8.588
15.262
15.404
23.838
33.428
43.783
54.658
65.907
77.441
89.203
101.152
113.257
125.494
137.843
150.289
162.819
175.421
188.087
200.808
213.579
226.393
239.245
252.132
„ 265.049
277.993
290.963
303.955
316.967
329.997
343.044
356.107
369.183
382.272
395.373
408.485
421.607
434.738
447.878
461.026
474.181
487.342
500.511
513.685
526.865
540.050
553.240
566.435
579.634
592.838
606.045
619.256
632.470
645.687
658.908
672.131
685.357
698.586
711.818
725.051
738.287
2С1 (г)
_Я°@)= 2241.
-1148.2670
-559.4861
-365.0253
-362.5781
-263.8845 '
-204.5635
-164.9643
-136.6507
-115.3990
-98.8597
-85.6218
-74.7868
-65.7550
-58.1110
-51.5581
-45.8783
-40.9082
-36.5227
-32.6246
-29.1370
-25.9984
-23.1589
-20.5779
-18.2215
-16.0618
-14.0752
-12.2417
-10.5442
-8.9682
-7.5012
-6.1322
-4.8517
-3.6514
-2.5241
-1.4633
-.4632
.4811
1.3743
2.2203
3.0228
3.7850
4.5100
5.2003
5.8585
6.4866
7.0867
7.6607
8.2101
8.7366
9.2415
9.7262
10.1918
10.6394
11.0701
11.4847
11.8843
12.2695
12.6412
13.0000
13.3465
13.6815
Таблица 349
760 кДж • моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-
- • о
1 „ ?
1 *
X
М Р 'л
« S. 5
оо гг'
Ы ' 1
ГЧ 1) V
| .! !. ?
ocJ О со ^
* ? и" S
п. и "
с* ^
о tj
а; о"'
-
•ч- |§
V) о
+
« т
о * *
1 П §
о ё S
° 2 V
¦ 1 о S-
? + V
° ? °
+ 1
On О
"О ^О
1
о
©
138

Класс точности
VI-
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600 '
5700
5800
5900
6000
Е
К°(
С°р(Т)
41.812
57.711
72.062
72.307
84.008
92.954
99.759
105.009
109.141
112.455
115.156
117.386
119.246
120.812
122.140
123.274
124.248
125.090
125.822
126.461
127.022
127.516
127.954
128.343
128.691
129.002
129.282
129.534
129.762
129.969
130.158
130.330
130.487
130.631
130.763
130.885
130.997
131.101
131.197
131.287
131.370
131.447
131.519
131.586
131.649
131.708
131.764
131.816
131.864
131.910
131.954
131.995
132.033
132.070
132.104
132.137
132.168
132.197
132.225
132.252
132.277
1,1-ДИФТОРХЛОРЭТИЛЕН 1,1—С
П-„'(С).р(Н)-1*
Ф°(Г)
Дж • К~' . моль
207.405
234.240
252.679
252.989
268.421
281.891
293.976
304.987
315.123
324.525
333.297
341.522
349.267
356.584
363.521
370.115
376.398
382.400
388.143
393.650
398.939
404.027
408.929
413.657
418.224
422.640
426.914
431.057
435.074
438.975
442.765
446.450
450.037
453.530
456.933
460.252
463.491
466.653
469.742
472.760
475.713 '
478.601
481.428
484.196
486.908
489.566
492.172
494.728
497.236
499.698
502.115
504.490
506.822
509.115
511.368
513.585
515.765
517.909
520.020
522.098
524.144
Рже».,
S°(T)
243.123
276.974
302.773
303.220
325.695
345.448
363.025
378.813
393.116
406.169
418.162
429.245
439.541
449.150
458.152
466.619
474.607
482.165
489.336
496.157
502.658
508.'867
514.810
520.506
525.976
531.236
536.301
541.185
545.900
550.457
554.867
559.137
563.277
567.295
571.197
574.989
578.678
582.268
585.766
589.175
592.500
595.745
598.913
602.009
605.035
607.994
610.889
613.724
616.499
619.219
621.884
624.497
627.061
629.576
632.045
634.469
636.851
639.190
641.490
643.750
645.973
"'(CjHFjCl) ArH°
Н°(Т)-Н°@)
кДж . моль
3.572
8.547
14.936
15.069
22.910
31.778
41.429
51.679
62.394
73.480
84.865
96.495
108.329
120.335
132.484
144.756
157.133
169.601
182.148
194.762
207.437
220.164
232.938
245.754
258.606
271.491
284.405
297.346
310.311
323.298
336.304
349.329
362.370
375.426
388.496
401.578
414.672
427.777
440.892
454.016
467.149
480.290
493.438
506.594
519.756
532.924
546.097
559.276
572.460 .
585.649
598.842
612.040
625.241
638.446
651.655
664.867
678.082
691.300
704.521
717.745
730.972
2HF2C1 (г)
@)= 2241.760
о
1148.2672
-559.4845
-365.0118
-362.5643
-263.8454
-204.4915
-164.8577
-136.5110
-115.2291
-98.6627
-85.4007
-74.5443
-65.4936
-57.8327
-51.2647
-45.5713
-40.5891
-36.1926
-32.2844
,28.7877
-25.6406
-22.7935
-20.2053
-17.8425
-15.6767
-13.6844
-11.8456
-10.1433
-8.5627
-7.0914
-5.7183
-4.4341
-3.2302
-2.0995
-1.0355
-.0324
.9148
1.8107
2.6593
3.4642
4.2288
4.9561
5.6485 •
6.3087
6.9388
7.5408
8.1 65
8.6677
9.1958
9.7024
10.1886
10.6556
11.1047
11.5367
11.9527
12.3535
12.7400
13.1128
13.4728
13.8205
14.1566
кДж • моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
'>0
о
el
00
j
II
г- °_
Ч —"
оо О
С* гч
5S %
I
-1
w
О
+
|
гч _^
"^ А
^ О
"> 2
« i
о ъс
s Чй
<= я
' оо
К гч
я +
го «Ч,
я я
8 3
+ |
О »/}
гч ^
v> оо
о
о
i§
о
о
о
II
~-.
ОО
сч
X
г \
1
-1
а 350
~л
§
i
ТГ
<о
СП
II
0 «
t<a
о
о
чо
V
к .
V
о
•о
•-
1
о
f^.
II
139

Класс точности
VI-F
Т
К
100
200
298.15
300'
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
41.927
59.437
73.153
73.385
84.547
93.241
99.933
105.127
109.228
112.522
115.210
117.430
119.282
120.842
122.165
123.295
124.266
125.106
125.835
126.473
127.032
127.526
127.963
128.351
128.698
129.008
129.288
129.539
129.767
129.974
130.162
130.333
130.490
130.634
130.766
130.888
131.000
131.104
131.200
131.289
131.372
131.449
131.521
131.588
131.651
131.710
131.765
131.817
131.866
131.912
131.955
131.996
132.034
132.071
132.105
132.138
132.169
132.198
132.226
132.253
132.278
цмс-ДИФТОРХЛОРЭТИЛЕН цис-Сг\№гС\ (г)
К°(Т) = p2(C)-p(H)-p2(F)-p(Cl)-p""]
Ф°(Г)
Дж • К~' . моль"
207.760
234.659
253.377
253.692
269.362
283.005
295.215
306.320
316.529
325.988
334.808
343.072
350.848
358.194
365.155
371.770
378.072
384.089
389.847
395.367
400.668
405.767
410.678
415.415
419.990
424.414
428.696
432.844
436.868
440.774
444.569
448.260
451.851
455.348
458.756
462.079
465.321
468.486
471.578
474.600
477.555
480.446
483.276
486.047
488.761
491.422
494.030
496.588
499.098
501.562
503.981
506.357
508.691
510.985
513.241
515.459
517.640
519.787
521.899
523.978
526.026
5°(Г)
1
243.262
277.907
304.292
304.745
327.449
347.291
364.908
380.720
395.035
408.098
420.097
431.185
441.484
451.095
460.100
468.568
476.557
484.117
491.289
498.110
504.612
510.822
516.764
522.461
527.931
533.192
538.257
543.141
547.856
552.413
556.823 .
561.094
565.234
569.252
573.154
576.946
580.635
584.225
587.723
591.132
594.457
597.702
600.871
603.966
606.992
609.951
612.847
615.681
618.457
621.176
623.842
626.455
629.019
631.534
634.003
636.427
638.808
641.148
643.448
645.708
647.931
(C2HF2C1) A^°@)= 2231.574
Я°(Г)-Я°@)
кДж . моль
3.550
8.650
15.180
15.316
23.234
32.143
41.816
52.079
62.805
73.898
85.289
96.925
108.763
120.771
132.923
145.198
157.577
170.047
182.595
195.211
207.886
220.615
233.390
246.206
259.059
271.944
284.859
297.801
310.766
323.753
336.760
349.785
362.826
375.883
388.953
402.036
415.130
428.235
441.351
454.475
467.608
480.749
493.898
507.053
520.215
533.383
546.557
559.736
572.920
586.109
599.302
612.500
625.702
638.907
652.116
665.328
678.543
691.762
704.983
718.207
731.433
о
-1142.9650
-556.8461
-363.2638
-360.8275
-262.5643
-203.4856
-164.0357
-135.8206
-114.6374
-98.1479
-84.9476
-74.1416
-65.1328
-57.5075
-50.9700
-45.3031
-40.3439
-35.9678
-32.0779
-28.5973
-25.4649
-22.6310
-20.0549
-17.7030
-15.5473
-13.5643
-11.7341
40.0396
-8.4664
-7.0019
-5.6353
-4.3569
-3.1587
-2.0333
-.9742
.0242
.9670
1.8587
2.7034
3.5046
4.2656
4.9894
5.6787
6.3358
6.9629
7.5621
8.1352
8.6838
9.2094
9.7136
10.1975
10.6624
11.1094
11.5394
11.9534
12.3524
12.7370
13.1081
13.4664
13.8125
14.1470
кДж ¦ моль"'
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
оопп
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
т- 3
1 1
о со
О CN
О СП
~н II
II "О
о" оо
¦* -Г и
" в? ' 0
II t-i-i <N
Si J Я
1 А
0 5J-
"¦^ О
+
-
X
ЧО _
О к
со' 2
с* 1
Н
СЛ J5
CN m
^ со
° со
1 00
Н <"¦*
2 о
о\ <¦•">
оо ¦
о оо
+. 1
°^ ?
00 ЧО
^ го
Ю 00
и ^
0
е
ца 351
А
К
1
1
•
СО
и
о§
to
Я
о
§
V
V
о
'о
К,
II
140

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К
Ср°(Г)
41.115
58.793
73.161
73.400
84.747
93.462
100.138
105.311
109.392
112.670
115.343
117.551
119.392
120.942
122.257
123.379
124.343
125.177
125.901
126.533
127.088
127.577
128.01
128.396
128.740
129.047
129.324
129.574
129.799
130.004
130.190
130.360
130.516
130.658
130.789
130.909
131.020
131.123
131.218
131.307
131.389
131.465
131.536
131.603
131.665
131.723
131.778
131.829
131.878
131.923
131.966
132.006
132.045
132.081
132.115
132.147
132.178
132.207
132.235
132.261
132.286
грякс-ДИФТОРХЛОРЭТИЛЕН
°G-)=p2(C)-p(H)p2(F)
Ф°G-)
Дж • К~ . моль
208.016
234.656
253.170
253.482
269.044
282.631
294.812
305.900
316.100
325.555
334.372
342.635
350.413
357.760
364.722
371.339
377.643
383.662
389.422
394.944
400.247
405.347
410.260
415.000
419.576
424.00-1
428.285
432.435
436.460
440.368
444.164
447.856
451.448
454.946
458.355
461.679
464.922
468.089
471.182
474.204
477.160
480.052
482.883
485.654
488.370
491.031
493.640
496.199
498.710
501.174
503.594
505.970
508.305
510.600
512.855
515.074
517.256
519.403
521.516
523.595
525.643
¦р(С1)-р '(СУ
5°(Г)
243.381
277.366
303.634
304.088
326.828
346.718
364.375
380.216
394.555
407.636
419.650
430.750
441.059
450.679
459.691
468.165
476.159
483.723
490.899
497.724
504.228
510.441
516.386
522.085
527.557
532.819
537.885
542.771
547.488
552.046
556.456
560.728
564.869
568.888
572.790
576.583
580.273
583.864
587.362
590.772
594.097
597.342
600.511
603.607
606.633
609.593
612.489
615.323
618.099
620.819
623.484
626.098
628.662
631.177
633.647
636.071
638.452
640.792
643.092
645.352
647.576
»F2C1)
Н°(Т)-Н
ipaHC-C2HF2Cl (г)
АгН°@)= 2230.974
°@)
кДж • моль
3.537
8.542
15.046
15.182
23.113
32.043
41.738
52.021
62.764
73.873
85.278
96.926
108.776
120.795
132.956
145.240
157.627
170.104
182.659
195.281
207.963
220.696
233.476
246.297
259.154
272.043
284.962
297.907
310.876
323.867
336.876
349.904
362.948
376.007
389.079
402.164
415.261
428.368
441.485
454.612
467.746
480.889
494.039
507.196
520.360
533.529
546.704
559.884
573.070
586.260
599.455
612.653
625.856
639.062
652.272
665.485
678.701
691.920
705.143
718.367
731.595
-1142.6653
-556.6891
-363.1478
-360.7120
-262.4694
-203.4034
-163.9623
-135.7539
-114.5759
-98.0905
-84.8935
-74.0903
-65.0839
-57.4607
-50.9250
-45.2597
-40.3019
-35.9271
-32.0382
-28.5587
-25.4272
-22.5942
-20.0188
-17.6676
-15.5126
-13.5302
-11.7005
-10.0066
-8.4339
-6.9699
-5.6036
-4.3257
-3.1279
-2.0028
-.9441
.0540
.9965
1.8879
2.7323
3.5333
4.2941
5.0176
5.7067
6.3636
6.9905
7.5895
8.1624
8.7108
9.2363
9.7403
10.2240
10.6888
11.1356
11.5655
11.9794
12.3782
12.7627
13.1337
13.4918
13.8378
14.1722
кДж • моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл
Тё
о
S
о
о
Ч
СО
1
II
<* я
11 с*
^ 1
В.
w
О
+
-
ч
о у
СЧ jS
г": о
со 2
<Ч |
s а
о
О g
1 00
в +
со К
О\ СО
-ч 00
о г~
¦* х
5 *i
^" CS
«О 00
II +
о
и ц а
§
со
о
*"^
•3
СО
II
оо
X
о
о
1
X
1
352
о
г
-'
•
;*
со
о §
я
о
о
чо
V
&->
V
о
о
•""
о
II
141

Класс точности
VI- F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
35G0
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
46.596
62.679
77.323
77.572
89.379
98.120
104.520
109.289
112.942
115.816
118.126
120.015
121.582
122.895
124.005
124.950
125.762
126.462
127.071
127.601
128.067
128.477
128.840
129.163
129.451
129.709
129.940
130.149
t АЛ ЛЛ^Ъ
130.338
130.509
130.665
130.807
130.937
131.056
131.165
131.266
131.358
131.444
131.524
131.597
131.666
131.729
131.789
131.844
131.896
131.945
131.990
132.033
132.073
132.111
132.147
132.181
132.212
132.242
132.271
132.298
132.323
132.347
132.370
132.392
132.413
ФТОРДИХЛОРЭТИЛЕН C2HFC12
К°(Т) =р2(СЖН)-р(]
Ф°(П
Дж . к . моль
215.950
245.398
265.543
265.881
282.624
297.151
310.114
321.866
332.635
342.582
351.828
360.468
368.578
376.220
383.447
390.300
396.818
403.032
408.969
414.652
420.103
425.340
430.379
435.235
439.920
444.446
448.823
453.062
457.169
461.154
465.024
468.784
472.441
476.001
479.468
482.847
486.143
489.359
492.499
495.567
498.566
501.499
504.369
507.178
509.929
512.625
515.267
517.858
520.399
522.893
525.341
527.745
530.106
532.426
534.706
536.948
539.153
541.322
543.456
545.557
547.625
S°(T)
255.041
292.238
320.076
320.555
344.568
365.502
383.987
400.474
415.316
428.791
441.117
452.467
462.979
472.764
481.913
490.502
498.592
506.238
513.484
520.369
526.926
533.185
539.170
544.905
550.408
555.698
560.790
565.698
570.434
575.011
579.438
583.725
587.880
591.911
595.825
599.629
603.328
606.928
610.435
613.852
617.185
620.437
623.612
626.713
629.745
632.710
635.610
638.449
641.229
643.953
646.622
649.240
651.807
654.325
656.798
659.225
661.603
663.951
666.253
668.516
670.74!
,HFCl2) Д,Я«
H°(T)-H°(fl)
кДж . моль"
(г)
@)= 2119.919
о
3.909 -1084.6646
9.368
16.259
16.402
24.777
34.175
44.324
55.025
66.144
77.588
89.289
101.199
113.281
125.507
137.853
150.302
162.839
175.451
188.128
200.862
213.646
226.474
239.340
252.241
265.172
278.130
291.112
304.117
317.-142
330.184
343.243
356.317
369.404
382.504
395.615
408.736
421.868
435.008
448.156
461.312
474.475
487.645
500.821
514.003
527.190
540.382
553.579
566.780
579.985
593.195
606.407
619.624
632.843
646.066
659.292
672.520
685.751
698.985
712.221
725.459
738.699
-527.8507
-343.9584
-341.6442
-248.3093
-192.1998
-154.7371
-127.9461
-107.8338
-92.1792
-79.6480
-69.3905
-60.8394
-53.6020
-47.3972
-42.0190
-37.3126
-33.1598
-29.4684
-26.1657
-23.1935
-20.5045
-18.0602
-15.8287
-13.7835
-11.9021
-10.1657
-8.5582
Т AARQ
-7.ЦЪ5о
-5.6765
-4.3800
-3.1674
-2.0308
-.9632
.0414
.9884
1.8827
2.7285
3.5296
4.2895
5.0113
5.6978
6.3515
6.9747
7.5695
8.1378
8.6813
9.2015
9.7000
10.1782
10.6371
11.0779
11.5018
11.9096
12.3022
12.6805
13.0453
13.3972
13.7369
14.0651
14.3823
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
JrOUv
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл
-1
_
о
2
8
О
го ^_,
m i
^ II
«-и О^
и %
^ о
Ц.
X
о*
О
+
-
'х
ОО ~*
40 О
+ -г
? а
X *
О Ёч
00 nv
ГЧ ой
о <5\
О **
• | ОО
2 +
оо ™g
S ¦*
S г~
+ 1
ОО Ч
00 СО
Tt ЧО
О СТ\
К ЧО
II +
о
иц
-
о
¦
*
00
со
о
7
II
00*
с-Г
с*
и
?
а 353
_
'л
о
—
¦
°i

till
о 0!
<*>
Я
О
g
vo
V
f-.
V
g
'о
II
142

Класс точности
tfl-F
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
грякс-ФТОРДИХЛОРЭТИЛЕН транс-С2НГС12 (г)
К°(Т) =р2(С)-Р(Н).
с;(г)
Ф°(Г)
Дж • К • моль
44.861 213.706
62.131 241.808
76.182 261.395
76.419 261.724
87.624 278.090
96.055 292.304
102.388 304.990
107.233 316.494
111.027 327.040
114.065 336.786
116.540 345.852
118.584 354.331
120.292 362.295
121.730 369.806
122.951 376.913
123.995 383.659
124.893 390.078
125.670 396.201
126.346 402.055
126.936 407.663
127.455 413.04.3
127.913 418.215
128.318 423.194
128.678 427.993
129.000 432.625
129.289 437.102
129.548 441.434
129.782 445.630
129.994 449.697
130.186 453.644
130.361 457.477
130.520 461.204
130.666 464.829
130.799 468.358
130.922 471.796
131.035 475.148
131.140 478.417
131.236 481.609
131.326 484.725
131.409 487.770
131.486 490.748
131.558 493.660
131.625 496.510
131.687 499.301
131.746 502.034
131.801 504.712
131.852 507.338
131.900 509.912
131.946 512.438
131.988 514.917
132.029 517.351
132.067 519.741
132.103 522.088
132.137 524.396
132.169 526.664
132.199 528.894
132.228 531.087
132.255 533.245
132.281 535.368
132.306 537.458
132.330 539.516
р(Р)-р\С1)-р-\С
S°(T)
l
250.509
287.101
314.622
315.094
338.686
359.190
377.290
393.452
408.029
421.288
433.438
444.644
455.038
464.725
473.792
482.311
490.343
497.939
505.141
511.989
518.513
524.743
530.703
536.415
541.898
547.170
552.246
557.140
561.864
566.429
570.845
575.122
579.269
583.291
587.198
590.995
594.688
598.282
601.783
605.196
608.524
611.771
614.942
618.040
621.068
624.029
626.927
629.763
632.540
635.262
637.929
640.543
643.108
645.625
648.095
650.521
652.903
655.244
657.544
659.805
662.029
^jHFCl2) Д/.Я°@) = 2119.919
Я°(Г)-Я°@>
кДж • моль
3.680 -1084.5483
9.059 -527.6635
15.870 -343.7419
16.011 -341.4272
24.238 -248.0725
33.443 -191.9467
43.380 -154.4696
53.871 -127.6655
64.791 -107.5416
76.051 -91.8764
87.586 -79.3359
99.345 -69.0699
111.291 -60.5113
123.394 -53.2669
135.630 -47.0559
147.979 -41.6721
160.424 -36.9606
172.953 -32.8031
185.555 -29.1073
198.220 -25.8006
210.940 -22.8247
223.709 -20.1325
236.521 -17.6848
249.371 -15.4504
262.255 -13.4025
275.170 -11.5185
288.112 -9.7797
301.078 -8.1700
314.067 -6.6754
327.076 -5.2841
340.104 -3.9858
353.148 -2.7714
366.207 -1.6331
379.281 -.5640
392.367 .4421
405.465 1.3906
418.574 2.2862
431.692 3.1333
444.821 3.9357
457.958 4.6968
471.102 5.4197
484.255 6.1073
497.414 6.7620
510.580 7.3862
523.751 7.9819
536.928 8.5511
550.111 9.0955
563.299 9.6166
576.491 10.1159
589.688 10.5948
602.889 11.0545
616.093 11.4960
629.302 11.9206
642.514 12.3290
655.729 12.7223
668.948 13.1013
682.169 13.4666
695.393 13.8191
708.620 14.1594
721.849 14.4881
735.081 14.8058
кДж ¦ моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 354
1
- '!
g И
\у О
я 7 •*
2 1 1
о to y
Q ОС **«
СО * —о ,-
|| ? X ?
S | г?
? 1. '•
а ч> d
Р- ? о о;
о ?,
^ о
< ¦-,
+
-
ч
i "л
»о о
+ _|-
<s 1
'я *
'5 к С
» ч §
1 д s
о S v
1 + v
3 » °
OS JO
+ 1
oo к fc-ч
О m II
- Щ Ц
Ex
о
е
143

Класс точности
VI-
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
F
К
С°р(Т)
43.596
61.675
76.296
76.536
87.821
96.231
102.534
107.353
111.130
114.154
116.618
118.653
120.353
121.786
123.002
124.041
124.935
125.708
126.381
126.969
127.485
127.940
128.343
128.702
129.022
129.309
129.567
129.800
130.011
130.202
130.376
130.534
130.679
130.812
130.934
131.047
131.151
131.247
131.336
131.418
131.495
131.566
131.633
131.695
131.753
131.808
131.859
131.907
131.952
131.994
132.034
132.072
132.108
132.142
132.174
132.204
132.233
132.260
132.286
132.310
132.334
цмс-ФТОРДИХЛОРЭТИЛЕН цис-
°(r)=p2(C)-p(H).p(F)
Ф°(Г)
Дж • К . моль
214.014
241.700
261.045
261.372
277.620
291.775
304.426
315.909
326.441
336.178
345.238
353.712
361.673
369.182
376.287
383.031
389.450
395.572
•401.426
407.033
412.413
417.585
422.564
427.363
431.996
436.473
440.805
445.000
449.068
453.015
456.849
460.575
464.201
467.730
471.168
474.520
477.790
480.981
484.098
487.144
490.121
493.034
495.884
498.675
501.408
504.086
506.712
509.287
511.813
514.292
516.726
519.116
521.464
523.771
526.039
528.269
530.463
532.620
534.744
• 536.834
538.892
PW
S°(T)
250.443
286.305
313.777
314.250
337.892
358.438
376.567
392.750
407.342
420.612
432.771
443.984
454.384
464.075
473.146
481.669
489.703
497.301
504.506
511.355
517.881
524.112
530.074
535.787
541.271
546.544
551.621
556.515
561.240
565.805
570.222
574.500
578.647
582.670
586.577
590.374
594.067
597.662
601.163
604.576
607.904
611.152
614.323
617.421
620.449
623.411
626.308
629.145
631.922
634.644
637.310
639.925
642.490
645.007
647.477
649.903
652.285
654.626
656.927
659.188
661.412
-C2HFC12
(C2HFC12) Д^Я°(О)^2118
Н°(Г)~Н°@)
кДж • моль
3.643
8.921
15.722
15.863
24.109
33.332
43.285
53.789
64.721
75.990
87.533
99.300
111.252
123.361
135.602
147.956
160.406
172.939
185.544
198.212
210.935
223.707
236.522
249.374
262.261
275.178
288.121
301.090
314.081
327.092
340.121
353.166
366.227
379.302
392.389
405.488
418.598
431.718
444.847
457.985
471.131
484.284
497.444
510.610
523.783
536.961
550.144
563.332
576.525
589.723
602.924
616.129
629.339
642.551
655.767
668.985
682.207
695.432
708.659
721.889
735.121
о
-1084.041 1
-527.3965
-343.5483
-341.2346
-247.9173
-191.8146
-154.3530
-127.5603
-107.4449
-91.7866
•79.2515
-68.9901
-60.4352
-53.1941
-46.9859
-41.6045
-36.8951
. -32.7395
-29.0454
-25.7402
¦22.7657
¦20.0745
-17.6282
-15.3948
-13.3478
-11.4648
-9.7268
•8.1178
-6.6239
¦5.2333
-3.9356
-2.7217
-1.5840
-.5153
.4903
1.4383
2.3335
3.1802
3.9821
4.7429
5.4655
6.1527
6.8072
7.4311
8.0265
8.5954
9.1395
9.6604
10.1594
10.6381
11.0975
11.5389
11.9632
12.3715
12.7646
13.1434
13.5085
13.8609
14.2010
14.5296
14.8471
(г)
.919 кДж -моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
i
о
i S
л
о X
1 °
СО
О ч?
О —.
9 I
S и
1 Я
11 ~
<"! ¦"* об
— У -^
" Ч, -
о 3
""*ч 0
**—» >¦
< ч
+
ел
о ™
гл О
(N ¦ —
fx 'v
г- *
i д
О К
О OS
| ГЧ
В +
? &
2 ' ?>
+ i
о н
OS гл
— гл
? .?
!1 +
0
©
ц a 3j5
о
-'
OS
*Т
I!
о о;
я
о
о
о
V
S-,
V
о
о
«о
»""
1
о
II
144

Класс точности
VI-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЙПП
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
F
со
43.806
62.729
76.595
76.824
87.646
95.881
102.144
106.978
110.787
113.847
116.346
118.413
120.140
121.5Э6
122.832
123.889
124.798
125.585
126.268
126.866
127.391
127.854
128.264
128.629
128.955
129.247
129.509
129.746
1 9Q ОАП ¦
1 ХЭ.УОи
130.154
130.331
130.492
130.640
130.775
130.899
131.014
131.119
131.217
131.307
131.391
131.469
131.542
131:609
131.673
131.732
131.787
131.839
131.888
131.934
131.977
132.018
132.056
132.093
132.127
132.159
132.190
132.219
132.247
132.273
132.298
132.322
1,1-ФТОРДИХЛОРЭТИЛЕН 1,1-C2HFC12 (r)
(Т) = р2(С)-р(Н)-
Ф°(Г)
Дж ¦ К . моль
213.988
241.654
261.159
261.489
277.849
292.063
304.743
316.237
326.771
336.505
345.559
354.025
361.978
369.478
376.576
383.312
389.723
395.839
401.685
407.286
412.661
417.827
422.800
427.595
432.223
436.695
441.023
445.214
АЛЛ ОТО
453.222
457.052
460.775
464.398
467.924
471.360
474.709
477.976
481.165
484.280
487.323
490.298
493.209
496.057
498.846
501.577
504.254
506.878
509.451
511.976
514.453
516.886
519.274
521.621
523.927
526.194
528.423
530.615
532.772
534.894
536.983
539.040
n(F)-p2(Cl).p""
S°(T)
1
250.070
286.571
314.322
314.797
338.449
358.934
376.994
393.118
407.661
420.893
433.022
444.211
454.590
464.266
473.323
481.835
489.860
497.450
504.648
511.491
518.012
524.239
530.197
535.907
541.388
546.658
551.733
556.625
(чЛ 1 ЧЛ7
565.911
570.327
574.603
578.748
582.770
586.676
590.472
594.164
597.758
601.259
604.671
607.998
611.246
614.416
617.514
620.541
623.503
626.400
629.236
632.013
634.734
637.400
640.015
642.580
645.096
647.566
649.991
652.373
654.714
657.014
659.276
661.499
'(C2HFC12) Arh
Я°(Г)-//о@)
кДж . моль
3.608
8.983
15.851
15.992
24.240
33.435
43.351
53.817
64.712
75.949
87.463
99.204
111.134
123.223
135.446
147.784
160.219
172.739
185.332
197.990
210.703
223.466
236.272
249.117
261.997
274.907
287.845
300.808
о 1 ¦> 7Q4.
О I О, / У^
326.800
339.824
352.865
365.922
378.993
392.076
405.172
418.279
431.396
444.522
457.657
470.800
483.951
497.108
510.272
523.443
536.618
549.800
562.986
576.177
589.373
602.573
615.776
628.984
642.195
655.409
668.627
681.847
695.070
708.296
721.525
734.756
г°@)= 2109.919
-1079.3395
-525.0437
-341.9778
¦339.6738
-246.7541
-190.8894
-153.5861
-126.9059
-106.8746
-91.2814
-78.7982
-68.5791
-60.0594
-52.8480
-46.6652
-41.3057
-36.6156
-32.4769
-28.7978
-25.5061
-22.5435
-19.8633
-17.4269
-15.2025
-13.1638
-11.2883
-9.5574
•7.9548
с ДА7П
¦D.1D / U
-5.0820
-3.7895
-2.5805
-1.4473
-.3830
.6186
1.5628
2.4544
3.2976
4.0964
4.8541
5.5738
6.2583
6.9101
7.5315 ,
8.1245
8.6911
9.2330
9.7518
10.2489
10.7256
11.1832
11.6228
12.0454
12.4521
12.8436
13.2208
13.5845
13.9355
14.2742
14.6015
14.9178
кДж • моль '
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
оолл
ZOUU
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица J3b
i
л
о
2
d
х
о
о
7
II
сп °
¦*' с"!
5 «
О
_,
;?
о
\__
<J
+
-
го
NO (
v> О
со 2
см 1
'¦$ ^
NO %
3 "й
° 3
? +
СО с*
2 ¦*
О О\
»—< On
о °5
NO Г—
A +
0
©
i
R
О
2
•з
г*-
о ^
J Q
И <?
Я "
—•
ОО ±?
On Q
б 3
Ц.
и а
1 0 К
0
я
о
о
о
NO
V
V
1
2
/
II
н
10
145

Класс точности
IV-G
Г
К
100
200
298.15
300
400
500
600
70С
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
30.612
34.055
35.534
35.553
36.313
36.762
37.057
37.267
37.428
37.559
37.671
37.771
37.862
37.948
38.030
38.110
38.189
38.268
38.346
38.426
38.507
38.589
38.673
38.759
38.847
38.938
39.030
39.125
39.221
39.319
39.418
39.516
39.614
39.710
39.803
39.893
39.979
40.059
40.132
40.198
40.255
40.304
40.342
40.370
40.387
40.392
40.385
40.367
40.336
40.293
40.238
40.171
40.093
40.003
39.902
39.791
39.669
39.538
39.398
39.249
39.093
БРОМИД УГЛЕРОДА СВг
А'°(Г)= р(С)р(Вг)-/Г' (СВг)
Ф°(Г)
Дж • К . моль
168.756
189.585
202.200
202.400
211.818
219.301
225.522
230.852
235.518
239.667
243.405
. 246.806
249.927
252.811
255.492
257.996
260.346
262.560
264.653
266.638
268.526
270.326
272.046
273.692
275.272
276.790
278.251
279.659
281.019
282.333
283.605
284.837
286.032
287.192
288.320
289.416
290.483
291.522
. 292535
293.524
294.488
295.430
296.351
297.251
298.132
298.994
299.838
300.664
301.475
302.269
303.048
303.812
304.562
305.298
306.021
306.731
307.428
308.114
308.788
309.450
310.101
S°(T)
1
198.120
220.540
234.450
234.670
245.012
253.168
259.898
265.627
270.614
275.030
278.993
282.588
285.879
288.913
291.728
294.355
296.817
299.134
301.324
303.399
305.372
307.253
309.050
310.771
312.423
314.010
315.539
317.014
318.439
319.817
321.151
322.445
323.702
324.922
326.109
327.264
328.389
329.485
330.555
331.598
332.617
333.611
334.583
335.532
336.461
337.368
338.256
339.124
339.974
340.805
341.619
342.415
343.194
343.957
344.704
345.435
346.151
346.852
347.538
348.210
348.869
V
Я°(Г)-Я°@)
кДж . моль
2.936
6.191
9.615
9.681
13.278
16.933
20.625
24.342
28.077
31.827
35.588
39.360
43.142
46.933
50.732
54.539
58.354
62.176
66.007
69.846
73.692
77.547
81.410
85.282
89.162
93.051
96.950
100.857
104.775
108.702
112.639
116.585
120.542
124.508
128.484
132.469
136.462
140.464
144.474
148.490
152.513
156.541
160.573
164.609
168.647
172.686
176.725
180.762
184.797
188.829
192.856
196.876
200.889
204.894
208.889
212.874
216.846
220.807
224.753
228.685
232.602
(г)
Г°@)= 335
1?К°(Г)
-171.1250
-83.1327
-54.0939
-53.7286
-38.9990
-30.1472
-24.2374
-20.0104
-16.8360
-14.3638
-12.3835
-10.7611
-9.4073
-8.2602
-7.2756
-6.4211
-5.6723
-5.0106
-4.4216
-3.8938
-3.4181
-2.9870
-2.5945
¦2.2357
-1.9062
-1.6027
-1.3221
-1.0619
-.8200
-.5944
-.3836
-.1861
.0000
.1738
.3381
.4933
.6401
.7791
.9109
1.0362
1.1553
1.2688
1.3770
1.4803
1.5790
1.6734
1.7639
1.8506
1.9338
2.0137
2.0905
2.1644
2.2355
2.3040
2.3701
2.4339
2.4955
2.5550
2.6125
2.6682
2.7221
.000 кДж ¦ моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
i
л
с
о
00
¦/¦> -1
ON ON
t> II
II ^-.
со
L>
1
к
о "
л
^ с;
о о
-L. S
+ *
СЧ -ч
00 %
On p—r
О m
О >(
О ^н
1 ?
х *>¦
JB 1
On d
(N X
\о оо
1/-) СЧ
оо- ^
ГО <Ч
ю +
—< ЧО
00 1О
S 2
II 1
Е-
о
©
i
с
О
•
3
го
"*.
О
ON
II
оо'
On
гч
(_^
ч
О
ца 357
'л
о
t
-¦
J|
о
4D
00
"
0 Ж
to
я
о
I
V
Е^
V
о
о
•""
1
о
и
is
146

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
470»
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<п
37.901
44.285
49.303
49.377
52.429
54.217
55.313
56.023
56.504
56.844
57.0.95
57.287
57.444
57.582
57.716
57.855
58.0J0
58.188
58.394
58.631
58.901
59.203
59.537
59.899
60.286
60.694
61.118
61.555
62.000
62.447
62.892
63.333
63.763
64.182
64.584
64.969
65.333
65.676
65.996
66.291
66.563
66.809
67.031
67.229
67.402
67.552
67.680
67.786
67.871
67.937
67.984
68.014
68.028
68.026
68.011
67.983
67.942
67.891
67.830
67.760
67.683
ДИБРОМИД УГЛЕРОДА СВг2 (г)
К°(Т)=р(Ор''
Ф°(Г)
Дж • К~ . моль"
206.646
231.711
247.423
247.676
259.818
269.742
278.175
285.520
292.031
297.883
303.196
308.064
312.555
316.724
320.613
324.260
327.691
330.932
334.004
336.923
339.704
342.361
344.905
347.345
349.690
351.948
354.126
356.229
358.264
360.235
362.146
364.002
365.805
367.560
369.268
370.933
372.558
374.143
375.692
377.206
378.686
380.135
381.554
382.944
384.307
385.642
386.952
388.238
389.501
390.741
391.958
393.155
394.332
395.488
396.626
397.745
398.846
399.930
400.997
402.048
403.083
(Вг)-р(СВг2) &гН°@)= 597.031
S°(T)
1
241.411
269.640
288.330
288.635
303.298
315.206
325.196
333.779
341.293
347.969
353.972
359.423
364.415
369.018
373.290
377.277
381.016
384.538
387.870
391.033
394.047
•396.928
399.690
402.344
404.902
407.371
409.760
412.074
414.321
416.504
418.629
420.698
422.716
424.684
426.606
428.484
430.320
432.114
433.870
435.588
437.270
438.917
440.529
442.109
443.657
445.173
446.659
448.116
449.544
450.944
452.317
453.664
454.984
456.280
457.552
458.800
460.024
461.226
462.407
463.566
464.704
Я°(Л-Я°@)
кДж . моль"*
3.476 -303.1088
7.S86 -146.1509
12.197 -94.3118
12.288 -93X595
17.392 -67.3542
22.732 -51.5441
28.213 -40.9895
33.782 -33.4415
39.410 -27.7743
45.078 -23.3619
50.776 -19.8283
56.495 -16.9340
62.232 -14.5196
67.983 -12.4743
73.748 -10.7191
79.527 -9.1962
85.320 -7.8619
91.129 -6.6832
96.958 -5.6342
102.809 -4.6944
108.686 -3.8476
114.591 -3.0804
120.527 -2.3822
126.499 -1.7440
132.508 -1.1583
138.557 -.6189
144.647 -.1205
150.781 .3414
156.959 .7706
163.181 1.1706
169.448 1.5442
175.759 1.8939 «
182.114 2.2220
188.511 2.5303
194.950 2.8206
201.428 3.0945
207.943 3.3532
214.494 3.5980
221.077 3.8299
227.692 4.0500
234.335 4.2591
241.004 4.4581
247.696 4.6475
254.409 4.8282
261.140 5.0006
267.889 5.1653
274.650 5.3229
281.424 5.4737
288.207 5.6183
294.997 5.7569
301.794 5.8899
308.594 6.0177
315.396 6.1406
322.199 6.2588
329.001 6.3726
335.800 6.4823
342.597 6.5880
349.389 6.6899
356.175 6.7884
362.955 6.8835
369.727 6.9754
кДж ¦ моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 358
'л
тл |
о ¦ 7
^ о
X * 2
И <N —'
8 « «
§ Я ¦
S ° " 5
2 7 2 »
"ii* °. 5 ?
5 и. rs
¦ : с "
CJ Г) о «
w « ^
о О
"*ч 0
i
^ 'й
го °
О "^
-ч «'
+ 'trf
1
to Ч о
\О m О
00 к О
vo О VO
О rt
Я Ч V
1 ^ *""
н ' V
С сч О
¦^ ч о
""! оо 1
(S <Л О
\О + -"
о "ч *-
¦Ч- го
II 1
о
147

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
ТРИБРОМИД
УГЛЕРОДА СВг3 (г)
К°(Т)= р(С)-р3(Вг)-р(СВг3) Д;.Яо@)= 807.706 кДж • моль"
Ф°(Г)
S°{T)
Дж • К~' . моль
48.242
59.726
67.438
67.555
72.584
75.697
77.674
78.982
79.882
80.524
80.997
81.354
81.630
81.847
82.021
82.163
82.279
82.376
82.458
82.527
82.586
82.638
82.682
82.721
82.755
82.786
82.812
82.836
82.858
82.877
82.894
82.910
82.925
82.938
82.949
82.960
82.970
82.980
82.988
82.996
83.003
83.010
83.016
83.022
83.028
83.033
83.038
83.042
83.046
83.050
83.054
83.057
83.061
83.064
83.067
83.070
83.072
83.075
83.077
83.079
83.081
233.049 271.756
262.470 309.058
282.177 334.440
282.501 334.857
298.203 355.038
311.276 371.596
322.525 385.585
332.416 397.664
341.249 408.272
349.230 417.720
356.512 426.230
363.207 433.968
369.403 441.059
375.170 447.601
380.563 453.673
385.628 459.337
390.403 464.644
394.918 469.635
399.201 474.346
403.274 478.806
407.158 483.040
410.868 487.071
414.420 490.916
417.826 494.593
421.099 498.114
424.247 501.493
427.281 504.740
430.208 507.866
433.036 510.879
435.770 513.787
438.418 516.597
440.984 519.315
443.473 521.948
445.890 524.500
448.239 526.976
450.523 529.380
452.746 531.718
454.911 533.991
457.022 536.204
459.080 538.360
461.088 540.461
463.049 542.511
464.965 544.511
466.838 546.465
468.669 548.374
470.461 550.240
472.216 552.065
473.933 553.851
475.617 555.599
477.267 557.311
478.884 558.989
480.471 560.634
482.028 562.247
483.557 563.829
485.058 565.38!
486.532 566.906
487.981 568.403
489.404 569.873
490.804 571.318
492.181 572.738
493.535 574.134
Я°(Г)-Я°@)
кДж - моль
3.871
9.318
15.582
15.707
22.734
30.160
37.836
45.673
53.619
61.641
69.718
77.836
85.986
94.160
102.354
110.564
118.786
127.019
135.261
143.510
151.766
160.027
168.293
176.563
184.837
193.114
201.394
209.676
217.961
226.248
234.536
242.827
251.118
259.411
267.706
276.001
284.298
292.595
300.894
309.193
317.493
325.794
334.095
342.397
350.699
359.002
367.306
375.610
383.914
392.219
400.524
408.830
417.136
425.442
433.748
442.055
450.362
458.670
466.977
475.285
483.593
-407.6677
-195.1627
-124.9858
-124.1028
-88.5008
-67.1107
-52.8372
-42.6346
-34.9784
-29.0206
-24.2522
-20.3489
-17.0945
-14.3393
-11.9764
-9.9272
-8.1330
-6.5488
-5.1396
-3.8778
-2.7413
-1.7122
-.7759
.0796
.8645
1.5872
2.2549
2.8736
3.4485
3.9843
4.4847
4.9533
5.3929
5.8062
6.1954
6.5628
6.9100
7.2387
7.5503
7.8461
8.1274
8.3952
8.6504
8.8939
9.1265
9.3489
9.5618
9.7658
9.9614
10.1492
10.3296
10.5030
10.6699
10.8306
10.9854
11.1347
11.2787
11.4178
11.5522
11.6821
11.8078
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 359
1
-
'л
- 9
К " I
о * л
? 3 |
! 1 v
00 "> ^
Н ^ !L ri
И ° * "^
ей m ч
о ? ° «
w CQ Со
о U
0 ¦w'
Jr* %
+
•*•
m
2
* 'i
• л
•ч R
+ jg
I24х
: К"
300К]
§5 *
°. m v
он ь,
н « V
я - 8
°° Is ¦»'"
S '§ -
tl +
К.
о
в
148

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
63.574
81.229
90.956
91.095
96.892
100.316
102.434
103.812
104.751
105.416
105.903
106.269
106.551
106.773
106.950
107.094
107.212
107.311
107.393
107.464
107.524
107.576
107.621
107.660
107.695
107.725
107.753
107.777
107.798
107.818
107.835
107.851
107.866
107.879
107.891
107.902
107.912
107.922
107.930
107.938
107.945
107.952
107.959
107.964
107.970
107.975
107.980
107.984
107.989
107.993
107.996
108.000
108.003
108.006
108.009
108.012
108.015
108.017
108.020
108.022
108.024
ТЕТРАБРОМВД УГЛЕРОДА СВг4
К°(Т)=р(С)-р
Ф°(Г)
Дж • К . моль"
228.050
264.162
289.640
290.063
310.685
327.936
342.796
355.858
367.513
378.037
387.629
396.442
404.592
412.171
419.255
425.905
432.169
438.091
443.706
449.044
454.132
458.990
463.640
468.099
472.381
476.500
480.468
484.295
487.992
491.566
495.027
498.380
501.632
504.789
507.856
510.840
513.742
516.569
519.324
522.011
524.632
527.192
529.692
532.136
534.526
536.864
539.152
541.393
543.589
545.741
547.85!
549.920
551.951
553.944
555.901
557.823
559.712
561.568
563.393
565.188
566.954
4(Вг)-р'1(СВг4) А, Л
5°(Г)
1
273.251
323.536
357.943
358.506
385.581
407.602
426.093
441.994
455.922
468.300
479.433
489.545
498.804
507.341
515.261
522.645
529.560
536.063
542.199 -
548.008
553.521
558.769
563.774
568.559
573.142
577.539
581.764
585.831
589.751
593.534
597.190
600.726
604.151
607.470
610.691
613.818
616.858
619.815
622.693
625.497
628.230
630.895
633.496
636.037
638.519
640.945
643.319
645.641
647.914
650.141
652.323
654.462
656.559
658.616
660.635
662.617
664.563
$66.475
668.354
670.200.
672.016
Н°(Т)-И°@)
кДж • моль
4.520
11.875
20.365
20.533
29.958
39.833
49.979
60.295
70.726
81.237
91.804
102.413
113.055
123.721
134.408
145.110
155.826
166.552
177.287
188.030
198.780
209.535
220.294
231.059
241.826
252.597
263.371
274.148
284.926
295.707
306.490
317.274
328.060
338.847
349.636
360.426
371.216
382.008
392.801
403.594
414.388
425.183
435.979
446.775
457.572
468.369
479.167
489.965
500.763
511.562
522.362
533.162
543.962
554.762
565.563
576.364
587.166
597.967
608.769
619.571
630.373
(г)
Г°@)= 1033
о
-518.3011
-246.5136
-156.8218
-155.6938
-110.2231
-82.9210
-64.7128
-51.7047
-41.9479
-34.3592
-28.2882
-23.3208
-19.1810
-15.6777
-12.6743
-10.0708
-7.7922
-5.7810
-3.9927
-2.3921
-.9510
.3535
1.5398
2.6234
3.6172
4.5319
5.3766
6.1590
6.8859
7.5630
8.1952
8.7868
9.3417
9.8632
10.3542
10.8174
11.2549
11.6690
12.0614
12.4339
12.7878
13.1246
13.4455
13.7515
14.0437
14.3230
14.5903
14.8462
15.0916
15.3270
15.5530
15.7703
15.9792
16.1803
16.3740
16.5607
16.7408
16.9146
17.0824
17.2446
17.4014
.151 кДж -моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
—
'а
о
ГО ||
И О
^ 'i
2
Р0
о
<
+
(
*п
*> -
+ 1
г5 "'
§ й
о Ч
о «
1 О
« X
¦ *^ о
S 2
*-¦ +
О $?
1Г °*
i '
00 OS
? «
SO (N
II +
О
_
'а
3
г
§
о
о
II
Я
00*
(N
С
2
8
360
'§
(§
г~
VO
с §
to
я
о
¦-о
V
V
о
о
•'*
о
II
149

Класс точности
V-C
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
33.359
36.227
42.449
42.582
49.941
56.751
62.655
67.754
72.201
76.101
79.527
82.534
85.169
87.476
89.497
91.269
92.824
94.192
95.398
96.465
97.412
98.254
99.005
99.678
100.282
100.825
101.316
101.761
102.164
102.532
102.867
103.173
103.454
103.712
103.950
104.169
104.371
104.559
104.733
104.894
105.045
105.185
105.316
105.438
105.552
105.660
105.760
105.855
105.944
106.028
106.107
106.182
106.252
106.319
106.382
106.442
106.499
106.553
106.604
106.653
106.699
*V) = p(O.<
Ф°(Г)
Дж • К • моль
173.235
196.408
210.212
210.432
221.034
229.901
237.707
244.776
251.289
257.358
263.059
268.447
273.563
278.438
283.097
287.562
291.848
295.972
299.946
303.780
307.485
311.069
314.540
317.904
321.169
324.340
327.422
330.421
333.339
336.182
338.954
341.657
344.296
346.872
349.390
351.851
354.257
356.612
358.918
361.176
363.388
365.557
367.683
369.769
371.815
373.824
375.797
377.735
379.639
381.510
383.350
385.159
386.938
388.689
390.412
392.109
393.779
395.424
397.045
398.642
400.216
БРОММЕТАН
?3(Н).р(Вг).р"'
5°(Г)
-1
206.504
230.255
245.806
246.069
259.328
271.220
282.102
292.152
301.496
310.231
318.430
326.154
333.451
340.361
346.919
353.156
359.097
364.766
370.185
375.372
380.344
385.118
389.706
394.122
398.378
402.483
406.447
410.279
413.987
417.579
421.060
424.438
427.719
430.906
434.006
437.022
439.960
442.822
445.612
448.335
450.993
453.588
456.125
458.604
461.029
463.403
465.726
468.002
470.231
472.417
474.560
476.661
478.724
480.748
482.736
484.689
486.607
488.493
490.347
492.169
493.962
[ СН3Вг (г)
(СН3Вг) Д^Я°@)= 1498
Я°(Г)-Я°@)
кДж . моль
3.327
6.769
10.612
10.691
15.318
20.659
26.637
33.164
40.166
47.586
55.371
63.477
71.865
80.500
89.351
98.391
107.597
116.949
126.430
136.024
145.719
155.503
165.367
175.302
185.300
195.356
205.463
215.618
225.814
236.049
246.319
256.621
266.953
277.312
287.695
298.101
308.528
318.975
329.439
339.921
350.418
360.930
371.455
381.992
392.542
403.102
413.673
424.254
434.844
445.443
456.050
466.664
477.286
487.915
498.550
509.191
519.838
530.491
541.149
551.812
562.479
о
-767.8058
-373.8830
-243.5973
-241.9562
-175.7189
-135.8331
-109.1592
¦90.0545
-75.6918
-64.4975
-55.5255
-48.1729
-42.0370
-36.8383
-32.3773
-28.5071
-25.1176
-22.1245
-19.4619
-17.0780
-14.9312
-12.9878
-11.2201
-9.6054
-8.1247
-6.7619
-5.5035
-4.3379
-3.2552
-2.2469
-1.3056
-.4248
.4011
1.1771
1.9076
2.5965
3.2473
3.8630
4.4463
4.9998
5.5257
6.0261
6.5026
6.9570
7.3909
7.8055
8.2021
8.5818
8.9458
9.2949
9.6301
9.9522
10.2619
10.5599
10.8469
11.1235
11.3902
11.6476
11.8961
12.1362
12.3683
.210 кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
. 1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
"л
о
1 .
i &
н ?
§ 7
с- °- »
S 7 Я
Tt i| "-*,
*> /~. 00
II . гч
!§¦-&«"
Ч, «*
о у.
X Т.
5466
МОЛ]
СО ^'
м 'ж
с*
чо го
О й
1 +
3 Ъ
О ?Q
чо о
О со
о ¦ ~*
^О j
+ rt
о о\
¦о <-"
СО т*
II +
0
Ца 361
"а
g
i
_-*
¦ -!
«о
со
и
0 К
to
§
о
о
ЧО
V
V
о
о
¦""
'о
f—I
II
150

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
54Э0
5500
5600
5700
5800
5900
6000
С°(Т)
38.618
45.702
54.583
54.749
63.026
69.667
74.886
79.087
82.569
85.518
88.047
90.229
92.119
93.759
95.187
96.433
97.522
98.478
99.319
100.061
100.719
101.303
101.824
102.290
102.708
103.084
103.423
103.730
104.009
104.262
104.493
104.705
104.899
105.076
105.240
105.391
105.531
105.660
105.780
105.891
105.994
106.091
106.181
106.265
106.344
106.418
106.487
106.552
106.614
106.671
106.726
106.777
106.826
106.872
106.915
106.956
106.995
107.032
107.068
107.101
107.133
К°(Т)= р(С)-р
Ф°(Г)
"* 1 ~*
Дж • К . моль
209.455
234.876
250.962
251.224
264.000
274.827
284.372
292.977
300.844
308.112
314.877
321.214
327.178
332.816
338.164
343.252
348.106
.352.748
357.196
361.466
365.573
369.528
373.343
377.028
380.591
384.040
387.383
390.625
393.773
396.832
399.807
402.702
405.522
408.270
410.951
413.566
416.120
418.615
421.055
423.440
425.774
428.059
430.296
432.488
434.637
436.744
438.811
440.839
442.830
444.785
446.705
448.592
450.446
452.269
454.063
455.827
457.562
459.270
460..952
462.608
464.239
ДИБРОММЕТАН СН2Вг2
2(Н) • р2(Вг) • р
S°(T)
1
244.664
273.431
293.322
293.661
310.581
325.388
338.569
350.440
361.234
371.134
380.279
388.776
396.709
404.149
411.151
417.762
424.021
429.962
435.616
441.006
446.155
451.084
455.809
460.345
464.708
468.908
472.958
476.867
480.645
484.299
487.838
491.267
494.595
497.825
500.964
504.017
506.988
509.882
512.701
515.450
518.132
520.751
523.308
525.808
528.252
530.643
532.982
535.273
537.517
539.716
541.872
543.985
546.060
548.095
550.093
552.055
553.983
555.877
557.738
559.569
561.369
(сн2вГ2) Дг
Н°(Т)-Н°@)
кДж • моль
3.521
7.71 1
12.630
12.731
18.632
25.281
32.518
40.224
48.312
56.720
65.402
74.318
83.438
92.733
102.182
111.765
121.464
131.265
141.156
151.125
161.165
171.267
181.423
191.629
201.880
212.170
222.495
232.853
243.240
253.654
264.092
274.552
285.032
295.531
306.047
316.579
327.125
337.684
348.256
358.840
369.435
380.039
390.652
401.275
411.905
422.544
433.189
443.841
454.499
465.164
475.833
486.508
497.189
507.873
518.563
529.256
539.954
550.655
561.360
572.069
582.781
(г)
Я°@)= 1347.691
-687.9259
-333.4315
-216.2061
-214.7299
-155.1581
-119.3056
-95.3433
-78.1907
¦65.3026
-55.2625
-47.2192
-40.6302
-35.1333
-30.4775
-26.4832
-23.0186
-19.9848
-17.306 Г
-14.9235
-12.7904
-10.8695
-9.1307
-7.5492
-6.1046
-4.7797
-3.5604
¦2.4345
-1.3915
-.4228
.4794
1.3218
2.1100
2.8492
3.5437
4.1976
4.814-2
5.3967
5.9478
6.470!
6.9656
7.4365
7.8845
8.3112
8.7181
9.1066
9.4779
9.8331
10.1733
10.4993
10.8120
11.1123
11.4008
11.6783
11.9453
12.2024
12.4503
12.6893
12.9199
13.1426
13.3578
13.5658
кДж ¦ моль~'
Т
К
100
200
298.15
300
400
500
600
700
800 .
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2309
2400
2500
i600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
i
-н О
R si
о s
5 i
х •
ос 2
о
оо Ч "
s « я
m *""!
7 ь-* ^
ДЭ сч
X, ^
0 'W
*"Ц О
1
¦<*• 2
^ т
fN ^ *
4- 1
i ¦
— с|
Оч "н
г-1 §?
О о
О 1У^
1 "¦'
X +
•S "х
о °
оо —:
v^ 00
¦"" 1
+ X
\О О
00 00
ЧО &¦
п- оо
458.
106.
II +
0
1^.
V
ц а 362
_
i
о
-'
i
л
о
о
It
0 К
со
я
о
о
о
V
V
о
о
»"¦
1
о
~~
^,
II
151

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
ТРИБРОММЕТАН СНВг3 (г]
К°(Т)= р(С)-р(Н)-р3(Вг)-р~1
Ф°(Г)
S°(T)
Дж • К . моль
48.481
61.141
70.989
71.152
78.668
84.066
87.985
90.942
93.267
95.153
96.718
98.035
99.153
100.110
100.933
101.644
102.262
102.800
103.272
103.686
104.052
104.376
104.665
104.922
105.152
105.359
105.546
105.714
105.867
106.006
106.133
106.248
106.354
106.451
106.541
106.623
106.699
106.770
106.835
106.895
106.952
107.004
107.053
107.099
107.142
107.182
107.220
107.255 "
107.289
107.320
107.349
107.377
107.404
107.429
107.452
107.475
107.496
107.516
107.535
107.553
107.571
227.624 266.508
257.219 304.236
277.209 330.561
277.540 331.001
293.683 352.557
307.322 370.724
319.227 386.416
329.831 400.211
339.411 412.512
348.160 423.610
356.218 433.719
363.691 443.000
370.662 451.580
377.197 459.555
383.348 467.005
389.161 473.993
394.671 480.573
399.908 486.790
404.900 492.679
409.668 498.274
414.233 503.602
418.611 508.687
422.816 513.549
426.863 518.207
430.763 522.678
434.526 526.975
438.162 531.111
441.679 535.097
л л с л о л с о о а л л
445.084 538.944
448.385 542.662
451.588 546.258
454.698 549.740
457.721 553.115
460.662 556.389
463.524 559.568
466.313 562.658
469.031 565.663
471.682 568.587
474.270 571.435
476.797 574.211
479.267 576.918
481.681 579.560
484.042 582.139
486.353 584.659
488.615 587.121
490.831 589.529
493.002 591.886
495.131 594.192
497.218 596.450
499.266 598.663
501.276 600.831
503.249 602.957
505.186 605.043
507.090 607.089
508.960 609.097
510.799 611.069
512.607 613.006
514.385 614.909
516.134 616.779
517.856 618.617
519.550 620.425
(CHBr3) A^/i
Н°(Г)-Н°@)
кДж • моль
3.888
9.403
15.907
16.038
23.549
31.701
40.314
49.266
58.481
67.905
77.501
87.241
97.101
107.066
117.119
127.249
137.445
147.698
158.003
168.351
178.738
189.160
199.612
210.092
220.596
231.122
241.667
252.230
262.809
273.403
284.010
294.629
305.260
315.900
326.549
337.208
347.874
358.547
369.228
379.914
390.607
401.304
412.007
422.715
433.427
444.143
454.864
465.587
476.314
487.045
497.778
508.515
519.254
529.995
540.739
551.486
562.234
572.985
583.737
594.492
605.248
Таблица 363
'°@) = 1 194.833 кДж ¦ моль
-605.8814
¦291.5270
-187.6477
-186.3402
-133.5979
-101.8845
-80.7069
-65.5596
-54.1866
-45.3325
¦ -38.2435
-32.4390
-27.5987
-23.5005
-19.9857
-16.9377
•14.2693
-11.9136
-9.8185
-7.9430
¦6.2543
-4.7256
-3.3353
-2.0653
-.9007
.1712
1.1611
2.0780
2.9298
3.7231
4.4638
5.1569
5.8069
6.4178
6.9929
7.5353
8.0477
8.5325
8.9920
9.4280
9.8423
10.2365
10.6120
10.9702
1 1.3121
11.6389
11.9516
12.2510
12.5380
12.8134
13.0777
13.3318
13.5761
13.8113
14.0377
14.2560
14.4665
14.6697
14.8658
15.0554
15.2386
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
'л
- о
'л f
О 56 Т
ж • м
М0Л1
CJ О _•
•л => 'ы
OS V) ^°
о ^ if ^
|~-1 || i^-j r^i
Гч' о эо fN.
|| л ON °С
* " и
р* аа ° *
о о
"^ 0
+
i
,5 -
гч °
+ 1
1 "^
5 * %
О \Г) \/
° оо ^
* Г v
с о
^ Tf о
О Ч *""
f ™ 1)
OS ^f "
—4 О —
о
е
152

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Л '
39.196
56.318
69.268
69.478
79.227
86.268
91.284
94.877
97.493
99.436
100.909
102.045
102.938
103.651
104.228
104.701
105.094
105.422
105.700
105.937
106.141
106.317
106.471
106.606
106.724
106.829
106.922
107.006
107.081
107.148
107.209
107.264
107.314
107.360
107.401
107.440
107.475
107.507
107.537
107.565
107.590
107.614
107.636
107.657
107.676
107.694
107.711
107.727
107.742
107.755
107.769
107.781
107.792
107.803
107.814
107.824
107.833
107.842
107.850
107.858
107.866
ТРИФТОРБРОММЕТАН CF3Br
Ф° (Г)
Лж • К . моль
205.477
231.315
249.145
249.445
264.332
277.239
288.726
299.109
308.594
317.327
. 325.420
332.959
340.016
346.648
352.903
358.820
364.434
369.774
374.865
379.730
384.387
388.854
393.144
397.272
401.249
405.086
408.793
412.377
415.846
419.208
422.470
425.636
428.712
431.704 '
434.615
437.450
440.213
442.907
445.536
448.103
450.611
453.061
455.458
457.802
460.097
462.344
464.546
466.704
468.820
470.895
472.931
474.929
476.892
478.819
480.712
482.573
484.403
486.202
487.972
489.713
491.427
(г)
}(F)-p(Br)-p1(CF3Br) Д/_Я°@)= 1697.630 кДж • моль
5°(Г)
1
Я°(ГЫ/°«»
кДж . моль
239.998 3.452
272.564 8.250
297.589 14.444
298.018 14.572
319.414 22.033
337.893 30.327
354.091 39.219
368.447 48.537
381.296 58.162
392.897 68.013
403.453 78.034
413.126 88.184
422.045 98.435
430.314 108.765
438.017 119.160
445.225 129.608
451.995 140.098
458.376 150.624
464.410 161.181
470.132 171.763
475.571 182.367
480.754 192.990
485.703 203.630
490.439 214.284
494.979 224.950
499.338 235.628
503.529 246.316
507.566 257.012
fit Л С f\ Л J4 Т Т 1 /*
51 1.459 267.716
515.218 278.428
518.852 289.146
522.368 299.870
525.774 310.599
529.077 321.332
532.283 332.070
535.397 342.812
538.424 353.558
541.369 364.307
544.236 375.060
547.030 385.815
549.754 396.572
552.411 407.333
555.004 418.095
557.537 428.860
560.0.12 439.626
562.432 450.395
564.800 461.165
567.116 471.937
569.384 482.711
571.606 493.485
573.783 504.262
575.917 515.039
578.010 525.818
580.064 536.598
582.079 547.378
584.057 558.160
586.000 568.943
587.909 579.727
589.784 590.511
591.628 601.297
593.441 612.083
Г
К
¦867.0112 100
-421.1117 200
-273.8366 298.15
-271.9830 300
-197.2360 400
-152.3077 500
-122.3168 600
-100.8746 700
-84.7818 800
-72.2588 900
-62.2364 1000
¦54.0339' 1100
-47.1969 1200 -
-41.4107 1300
-36.4505 1400
-32.1511 1500
-28.3889 1600
-25.0690 1700
-22.1179 1800
-19.4773 1900
-17.1008 2000
-14.9505 2100
-12.9957 2200
-11.2109 2300
-9.5748 2400
-8.0696 2500
-6.6802 2600
-5.3937 2700
-4.1991 2800
-3.0870 2900
-2.0490 3000
-1.0780 3100
-.1677 3200
.6874 3300
1.4922 3400
2.2510 3500
2.9676 3600
3.6454 3700
4.2876 3800
4.8968 3900
5.4755 4000
6.0260 , 4100
6.5503 4200
7.0502 4300
7.5273 4400
7.9832 4500
8.4193 4600
8.8368 4700
9.2369 4800
9.6207 4900
9.9891 5000
10.3430 5100
10.6833 5200
11.0108 5300
11.3261 5400
11.6300 5500
11.9230 5600
12.2057 5700
12.4786 5800
12.7423 5900
12.9972 6000
Таблица 364
-1
" 1
Л *¦
О id
Д я §
'-ч о г
У. оо 2
г— оо „,*
S ч?> 'v>
ГЧ ^ '
О ГО || у.
2 чо к ¦
OS 1 О" ^
об II и-, OS
" ° °°" и->'
оа и. и
О , m ° «
° У
¦^ 0
+
-
X
г-- ^
m 'л
СП О
+¦: ?
X ^
—' ¦ ?
О х
*-> On V
1 'п S-.
2 + v
\О ",, О
о н ~
+ 1 *
ГО V>
On О И
со О
II +
Ь
0
в
153

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
1 2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
45.469
64.927
76.998
77.185
85.607
91.401
95.394
98.194
100.201
101.676
102.784
103.635
104.300
104.830
105.257
105.6U6
105.896
106.138
106.342
106.516
106.666
106.795
106.908
107.006
107.093
107.170
107.238
107.299
107.353
107.403
107.447
107.487
107.524
107.557
107.588
107.616
107.641
107.665
107.687
107.707
107.725
107.743
107.759
107.774
107.788
107.801
107.813
107.825
107.836
107.846
107.855
107.864
107.873
107.881
107.888
107.895
107.902
107.909
107.915
107.921
107.926
ДИФТОРДИБРОММЕТАН CF2
К°(Т) = р (С) • p2(F) ¦ Р2(Вг) • p~\CF2Bi2) Ar h
Ф°(Г)
S°(T)
Дж • К . моль
Я°(Л-Я°@)
кДж . моль
222.170 258.936 3.677
250.588 296.971 9.277
270.698 325.300 16.280
271.036 325.777 16.422
287.740' 349.210 24.588
302.062 368.975 33.456
314.667 386.015 42.808
325.948 400.942 52.496
336.166 414.192 62.421
345.508 426.084 72.518
354.113 436.856 82.744
362.088 446.694 93.066
369.521 455.741 103.465
376.479 464.112 113.922
383.020 471.896 124.427
389.190 479.171 134.971
395.029 485.996 145.546
400.572 492.423 156.148
405.844 498.496 166.773
410.874 504.250 177.416
415.680 509.718 188.075
420.283 514.925 198.748
424.699 519.896 209.433
428.942 524.651 220.129
433.026 529.206 230.834
436.961 533.580 241.548
440.758 537.785 252.268
444.427 541.833 262.995
447.976 545.736 273.728
451.412 549.504 284.465
454.743 553.146 295.208
457.975 556.670 305.955
461.112 560.083 316.705
464.162 563.392 327.459
467.128 566.603 338.216
470.015 569.723 348.977
472.827 572.755 359.739
475.568 575.704 370.505
478.241 578.576 381.272
480.850 581.373 392.042
483.397 584.100 402.814
485.886 586.761 413.587
488.319 589.357 424.362
490.698 591.893 435.139
493.026 594.371 445.917
495.305 596.793 456.696
497.537 599.163 467.477
499.724 601.482 478.259
501.868 603.752 489.042
503.970 605.975 499.826
506.032 608.154 510.611
508.055 610.290 521.397
510.041 612.385 532.184
511.992 614.440 542.972
513.908 616.456 553.760
515.790 618.436 564.549
517.641 620.380 575.339
519.460 622.290 586.130
521.249 624.167 596.921
523.009 626.011 607.713
524.741 627.825 618.505
Вг2 (г)
Г°@) = 1463.466
-744.6349
-360.0381
-233.0325
-231.4344
-166.9927
-128.2690
-102.4260
-83.9530
-70.0909
-59.3052
-50.6741
-43.6107
-37.7235
-32.7413
-28.4702
-24.7681
-21.5284
-18.6696
-16.1281
-13.8538
-11.8068
-9.9545
-8.2705
-6.7327
-5.3230
-4.0259
-2.8284
-1.7196
-.6899
.2689
1.1639
2.0012
2.7862
3.5237
4.2178
4.8724
5.4906
6.0754
6.6295
7.1552
7.6547
8.1298
8.5823
9.0138
9.4257
9.8194
10.1959
10.5564
10.9019
11.2334
11.5515
11.8573
12.1512
12.4341
12.7065
12.9690
13.2222
13.4665
13.7023i
13.9302-^
14.1505
кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
'¦• /f* ^ f С
1 а о л и ц а 365
1
'л
V 1
М0Л1
Дж-
X 1
м§ 5
 о §
8 I т'
°°. 7 ы
00 ЧО "
s s ¦ « *>.
Й ^ "
? м 0 g
й- fcu "*
"а; о4""
¦-, >.
< «-,
+
оо _
г 7
2.67
юль
+ 7
С* w
1 1
СП * уу
о * °
о "W
° I У
s * v
Я "х °
5 " *'"
2 ¦= 'о
+ i Т
¦* х S-.
о «о
(N Г- II
On ГЧ
оо' ". Ц
чо го
II +
0
в
154

Класс точности
VI-Г
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
53.559
73.242
84.255
84.419
91.526
96.107
99.128
101.184
102.628
103.674
104.453
105.046
105.507
105.872
106.166
106.405
106.603
106.768
106.907
107.026
107.127
107.215
107.291
107.358
107.417
107.469
107.515
107.556
107.593
107.626
107.656
107.683
107.708
107.730
107.751
107.770
107.787
107.803
107.818
107.831
107.844
107.856
107.866
107.877
107.886
107.895
107.903
107.911
107.918
107.925
107.931
107.937
107.943
107.948
107.953
107.958
107.963
107.967
107.971
107.975
107.979
ФТОРТРИБРОММЕТАН CFBr
*V) = p(O-p
Ф°(Г)
Дж . К~1 . моль"
229.987
261.764
284.404
284.783
303.391
319.158
332.887
345.060
356.002
365.940
375.045
383.445
391.242
398.516
405.333
411.748
417.804
423.540
428.988
434.175
439.125
443.859
448.394
452.748
456.932
460.962
464.847
468.597
472.221
475.729
479.126
482.420
485.616
488.721
491.739
494.675
497.534
500.319
503.034
505.683
508.268
510.793
513.260
515.673
518.032
520.342
522.603
524.818
526.988
529.116
531.202
533.249
535.258
537.231
539.168
541.071
542.941
544.780
546.587
548.365
550.114
(F) • р3(Вг) • р
S°(T)
1
270.183
314.127
345.591
346.112
371.447
392.399
410.207
425.652
439.263
451.414
462.379
472.364
481.525
489.984
497.842
505.175
512.048
518.516
524.623
530.407
535.899
541.128
546.117
550.888
555.458
559.845
564.060
568.119
572.031
575.807
579.456
582.987
586.406
589.721
592.937
596.061
599.097
602.051
604.926
607.727
610.457
613.120
615.719
618.257
620.737
623.162
625.534
627.854
630.126
632.352
634.532
636.669
638.765
640.821
642.839
644.820
646.766
648.676
650.554
652.400
654.215
CFBr3) Arh
Я°(Г)-Я°@)
кДж . моль"
4.020
10.473
18.243
18.399
27.222
36.620
46.392
56.414
66.609
76.927
87.335
97.811
108.340
118.909
129.512
140.141
150.791
161.460
172.144
182.841
193.548
204.266
214.991
225.724
236.462
247.207
257.956
268.709
279.467
290.228
300.992
311.759
322.528
333.300
344.075
354.851
365.629
376.408
387.189
397.972
408.755
419.540
430.326
441.113
451.902
462.691
473.481
484.271
495.063
505.855
516.648
527.441
538.235
549.030
559.825
570.620
581.416
592.213
603.010
613.807
624.605
3 (Г)
'°@)= 1238.230 кДж-мол!
Т
К
-626.4584 100
-300.8728 200
-193.3827 298.15
-192.0304 300
-137.5101 400
-104.7594 . 500
-82.9090 600
-67.2939 700
-55.5788 800
-46.4649 900
-39.1727 1000
-33.2055 1100
-28.2322 1200
-24.0234 1300
-20.4154 1400
-17.2879 1500
-14.5509 1600
-12.1355 1700
-9.9880 1800
-8.0661 1900
-6.3360 2000
-4.7704 2100
-3.3467 2200
-2.0465 2300
-.8544 2400
.2426 2500
1.2554 2600
2.1935 2700
3.0647 2800
3.8761 2900
4.6335 3000
5.3422 3100
6.0068 3200
6.6312 3300
7.2190 3400
7.7734 3500
8.2970 3600
8.7925 3700
9.2620 3800
9.7074 3900
10.1307 4000
10.5334 4100
10.9170 , 4200
11.2828 4300
11.6320 4400
11.9658 4500
12.2851 4600
12.5909 4700
12.8839 4800
13.1651 4900
13.4350 5000
13.6944 5100
13.9438 5200
14.1839 5300
14.4151 5400
14.6379 5500
14.8527 5600
15.0601 5700
15.2603 5800
15.4538 5900
15.6408 6000
Таблица 366
-1
>
'а
§
7А ?
§ *
щ. ° §
О _/
3 Я L,
о 1 ™
2 " й §
R s 5 °
11 С °* So
^ ГП г"
м и "
jr* i; о о?
CJ РЧ гл.
w A. Г>
о о
а: о~
< V
<3
+
i
гч' 'л
+ §
2 "и ?
2 • §
о „ V
1 -Ч- Pi
е °°. V
^ ГЧ о
оо + 55
¦-1 * »'"
« S i
О |л ^
8 ё
<3\ "*.
II +
0
в
155

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6П00
С°р(Т)
35.223
41.447
49.088
49.242
57.430
64.639
70.592
75.486
79.560
82.995
85.916
88.414
90.561
92.411
94.011
95.398
96.607
97.663
98.589
99.404
100.124
100.762
101.330
101.837
102.292
102.700
103.068
103.401
103.702
103.976
104.226
104.454
104.663
104.855
105.032
105.195
105.345
105.484
105.613
105.732
105.844
105.948
106.044
106.135
106.219
106.299
106.373
106.443
106.509
106.571
106.629
106.684
106.736
106.786
106.832
106.877
106.918
106.958
106.996
107.032
107.066
ФТОРБРОММЕТАН CH2FBr
К°(Т) = p(C)-p2(H).p(F).p(Br)-p(
Ф°G-)
Дж ¦ К . моль
198.312
222.289
237.188
237.429
249.145
259.056
267.821
275.765
283.072
289.861
296.216
302.197
307.851
313.216
318.323
323.197
327.859
332.328
336.620
340.748
344.725
348.562
352.269
355.853
359.323
362.686
365.948
369.116
372.194
375.188
378.101
380,939
383.704
386.402
389.033
391.603
394.114
396.568
398.968
401.315
403.614
405.865
408.070
410.231
412.350
414.429
416.468
.- 418.471
420.436
422.367
424.264
426.129
427.962
429.765
431.538
433.282
435.000
436.690
438.354
439.993
441.608
S°(T)
1
231.992
258.240
276.169
276.473
291.773
305.386
317.716
328.977
339.331
348.905
357.805
366.114
373.901
381.225
388.133
394.667
400.864
406.753
412.362
417.715
422.832
427.733
432.434
436.950
441.293
445.478
449.513
453.409
457.175
460.819
464.348
467.769
471.089
474.313
477.446
480.493
483.458
486.347
489.161
491.906
494.585
497.199
499.754
502.250
504.691
507.079
509.416
511.704
513.946
516.143
518.296
520.409
522.481
524.514
526.511
528.472
530.398 •
532.290
534.151
535.980
537.780
CH2FBr) A,*
Я°G>Я°@)
кДж ¦ моль
3.368
7.190
11.622
11.713
17.051
23.165
29.937
37.248
45.007
53.139
61.589
70.308
79.260
88.411-
97.734
107.206
116.807
126.522
136.336
146.236
156.213
166.258
176.363
186.522
196.729
206.979
217.268
227.591
237.947
248.331
258.741
269.175
279.631
290.107
300.602
311.113
321.640
332.182
342.737
353.304
363.883
374.473
385.072
395.681
406.299
416.925
427.559
438.199
448.847
459.501
470.161
480.827
491.498
502.174
512.855
523.540
534.230
544.924
555.622
566.323
577.028
[г)
г°@)= 1538.883
-788.1462
-383.6317
-249.8882
-248.2040
-180.2366
-139.3279
-111.9836
-92.4086
-77.6997
-66.2408
-57.0610
-49.5411
-43.2679
-37.9548
-33.3970
-29.4440
-25.9830
-22.9273
-20.2097
-17.7771
-15.5868
-13.6044
-11.8015
-10.1550
-8.6452
7.2558
-5.9730
-4.7849
-3.6815
-2.6540
-1.6949
-.7975
.0440
.8345
1.5787
2.2804
2.9431
3.5702
4.1642
4.7279
5.2634
5.7729
6.2581
6.7208
7.1624
7.5845
7.9882
8.3748
8.7453
9.1007
9.4419
9.7697
10.0849
10.3882
10.6803
10.9618
11.2333
11.4952
11.7481
11.9924
12.2286
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
-1
[ОЛЬ
ГЧ
О
О
о
ГЧ ГЧ
Я '
О\ II
о! <—¦
~н О
II '-'
5 в*
Я
W
0.
+
i
х ,
ГЛ °
t-. Z
гч -,'
+ '^
1
(N м-
° m
R 2
q S
О os
1 <^
I
н
гл On
+ Н
О СЧ
00 -ч
О 1О
О Г"~
II +
0
о
i
ОЛЬ
о
о
•о
гч
1
II
я
.15
ОС
гч
и_
в"
и.
X
у.
0
о4"
367
7
с
о
1
¦ч-
—,
ГЛ
II
0 <К
to
я
о
8
V
б**
V
8
•""
•о
ь.
II
is
156

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°(Т)
С°р(Т)
38.531
49.259
58.766
58.939
67.653
74.781
80.349
84.687
88.117
90.876
93.129
94.991
96.547
97.858
98.970
99.920
100.736
101.442
102.055
102.590
103.060
103.475
103.841
104.167
104.458
104.719
104.953
105.164
105.355
105.529
105.686
105.830
105.961
106.082
106.192
106.294
106.388
106.475
106.556
106.630
106.700
106.764
106.825
106.881
106.933
106.983
107.029
107.072
107.113
107.152
107.188
107.222
107.254
107.285
107.314
107.341
107.367
107.392
107.415
107.437
107.458
ДИФТОРБРОММЕТАН CHF2Br
= р(С)р(Н)р2
Ф°(Г)
Дж • К • моль
208.968
234.342
250.948
251.221
264.615
276.047
286.166
295.310
303.683
311.420
318.621
325.360
331.696
337.676
343.340
348.721
353.846
358.738
363.418
367.904
372.212
376.355
380.345
384.194
387.910
391.504
394.982
398.352
401.620
404.793
407.876
410.873
413.790
416.630
419.398
422.097
424.730
427.301
429.812
432.267
434.667
437.015
439.313
441.564
443.768
445.929
448.048
450.125
452.164
454.165
456.130
458.060
459.956
461.819
463.651
465.452
467.224
468.967
470.683
472.372
474.035
(F)-p(Br)p"
S°(T)
l
243.558
273.659
295.118
295.482
313.664
329.557
343.704
356.430
367.971
378.514
388.210
397.176
405.510
413.291
420.585
427.446
433.922
440.050-
445.866
451.399
456.673
461.712
466.534
471.157
475.597
479.866
483.978
487.943
491.771
495.471
499.052
502.520
505.881
509.144
512.313
515.392
518.388
521.304
524.145
526.913
529.614
532.250
534.823
537.337
539.795
542.199
.544.551
546.853
549.108
551.317
553.482
555.605
557.687
559.730
561.736
563.705
565.640
567.540
569.408
571.244
573.050
'(CHF2Br) ArH°
Я°(Г)-Я°@)
кДж . моль
3.459
7.863
13.169
13.278
19.619
26.755
34.523
42.784
51.430
60.385
69.589
78.998
88.577
98.299
108.142
118.087
128.121
138.231
148.407
158.639
168.922
179.249
189.616
200.016
210.448
220.907
231.391
241.897
252.423
262.967
273.528
284.104
294.694
305.296
315.910
326.534
337.168
347.812
358.463
369.122
379.789
390.462
401.142
411.827
422.518
433.214
443.914
454.619
465.328
476.042
486,759
497.479
508.203
518.930
529.660
540.393
551.128
561.866
572.607
583.349
594.094
(г)
@)= 1608.492
о
-822.8478
-400.2155
-260.5581
-258.8000
-187.8726
-145.2104
-116.7124
-96.3242
-81.0132
-69.0919
-59.5462
-51.7303
-45.2128
-39.6949
-34.9631
-30.8604
-27.2693
-24.0997
-21.2814
-18.7592
-16.4886
-14.4340
-12.5658
-10.8597
-9.2957
-7.8565
-6.5280
-5.2977
-4.1552
-3.0914
-2.0984
-1.1694
-.2985
.5197
1.2898
2.0160
2.7018
3.3506
3.9652
4.5484
5.1024
5.6294
6.1313
6.6099
7.0667
7.5032
7.9208
8.3206
8.7037
9.0712
9.4240
9.7630
10.0889
10.4026
10.7046
10.9956
11.2763
11.5470
11.8085
12.0611
12.3052
кДж • моль"
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т аб л и
'л
к
о
¦
d
X
о
о
оо
ОО
2- !
°^ п
2 о
II ^
. <: оа
а
W
0
+
х «
00 ,
Os °
гч
¦*" 1
х ¦
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О 5
О °i
в +
•Я с)
чо *
СТ\ ^
оо ,**
t-; °°.
оо "¦>
+ 1
"* m
00 О
и +
0
в
i
о
2
о
гч
(N
1
II
2"
•Я
00
Г1
'I
m
l?
X
--'
ч
ца 368
С
о
S
-'
Ы
*-;
II
«О
я
о
о
О'
V
f-
V
о
о
«9-
'о
II
157

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сп
ФТОРДИБРОММЕТАН CHFBr2 (г)
^°G-)=p(C)p(H).p(F).p2(Br).p(CHFBr2) Д^
Ф°(Г)
S°(T)
Дж • К . моль
41.956
54.876
64.914
65.085
73.307
79.595
84.333
87.967
90.829
93.137
95.033
96.611
97.939
99.063
100.023
100.847
101.558
102.175
102.713
103.184
103.598
103.964
104.289
104.578
104.836
105.068
105.276
105.465
105.635
105.789
105.930
106.059
106.176
106.284
106.383
106.474
106.559
106.637
106.709
106.776
106.838
106.896
106.950
107.001
107.048
107.092
107.134
107.173
107.209
107.244
107.277
107.307
107.336
107.364
107.390
107.414
107.438
107.460
107.481
107.501
107.520
223.786 259.701
250.642 292.966
268.650 316.812
268.948 317.214
283.572 337.112
296.027 354.179
306.990 369.129
316.834 382.414
325.790 394.354
334.020 405.190
341.64,0 415.105
348.739 424.238
355.388 432.703
361.642 440.588
367.547 447.965
373.142 454.895
378.457 461.427
383.521 467.603
388.356 473.459
392.983 479.025
397.419 484.328
401.679 489.392
405.777 494.236
409.724 498.878
413.533 503.335
417.211 507.619
420.768 511.744
424.212 515.721
427.549 519.560
430.786 523.269
433.929 526.858
436.983 530.333
439.953 533.703
442.844 536.971
445.659 540.146
448.403 543.231
451.079 546.232
453.690 549.152
456.240 551.997
458.731 554.770
461.166 557.474
463.547 560.113
465.877 562.689
468.158 565.206
470.392 567.667
472.580 570.073
474.725 572.427
476.828 574.732
478.892 576.989
480.916 579.200
482.904 581.366
484.855 583.491
486.772 585.575
488.656 587.620
490.507 589.627
492.327 591.598
494.117 593.533
495.878 595.435
497.611 597.304
499.316 599.142
500.995 600.949
Н°(Т)~Н°{0)
кДж . моль
3.592
8.465
14.359
14.480
21.416
29.076
37.283
45.906
54.851
64.053
73.465
83.049
92.779
102.630
112.586
122.631
132.752
142.939
153.184
163.479
173.819
184.197
194.610
205.054
215.525
226.020
236.538
247,075
257.630
268.201
278.787
289.387
299.999
310.622
321.255
331.898
342.550
353.210
363.877
374.551
385.232
395.919
406.611
417.308
428.01 1
438.718
449.429
460.145
470.864
481.587
492.313
503.042
513.774
524.509
535.247
545.987
556.730
567.475
578.222
588.971
599.722
Таблица 369
//°@) = 1395.483 кДж • моль
-711.4235
-344.51 12
-223.2592
-221.7328
-160.1594
-123.1287
-98.3960
¦80.7035
-67.4181
-57.0745
-48.7925
-42.0113
-36.3566
-31.5691
-27.4633
¦23.9033
-20.7869
-18.0360
-15.5899
¦13.4004
¦1 1.4293
-9.6453
-8.0230
-6.5414
-5.1829
-3.9327
¦2.7785
-1.7095
-.7166
.2080
1.071 1
1.8786
2.6358
3.3473
4.0170
4.6486
5.2451
5.8095
6.3442
6.8516
7.3337
7.7923
8.2291
8.6457
9.0434
9.4234
9.7870
10.1351
10.4687
10.7887
1 1.0960
11.3912
11.6751
11.9483
12.21 15
12.4650
12.7095
12.9455
13.1733
13.3934
13.6062
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
-
- о
'л S
S *
S С ' J
12 о о
V) 11
С1 ¦—
? ' 2 Д
CV" II if. i—J.
ОС 11 **)
Q\ О ЭС ~^
II -*. ^1 ^
и. ?
Г" U- о ц
w х ^
S. а:
+
1
^ 1
~" О
<Ч ^ 2
—* r-f 2
On —^ О
О гч V
* ? v
J3 « g
Г-Н "Л
CTv ° О
ОО ""> —
-г ' '
1-2 "
II +
0
158

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
51.170
72.898
85.203
85.381
92.871
97.407
100.262
102.141
103.431
104.351
105.026
105.536
105.930
106.'240
106.488
106.689
106.855
106.994
107.110
107.209
107.293
107.366
107.430
107.485
107.534
107.577
107.615
107.64.9
107.680
107.707
107.732
107.754
107.775
107.793
107.810
107.826
107.840
107.853
107.865
107.877
107.887
107.897
107.906
107.914
107.922
107.929
107.936
107.942
107.948
107.954
107.959
107.964
107.969
107.973 .
107.977
107.981
107.985
107.989
107.992
107.995
107.998
ТРИХЛОРБРОММЕТАН СС13
К°(Т)=р(С).ръ
Ф°(Г)
~ 1 *¦
Дж ¦ К . моль
220.371
250.993
273.154
273.528
291.965
307.696
321.443
333.657
344.646
354.633
363.784
372.228
380.064
387.375
394.225
400.67.0
406.754
412.515
417.986
423.195
428.164
432.917
437.469
441.838
446.038
450.081
453.979
457.741
461.377
464.894
468.302
471.605
474.810
477.923
480.949
483.893
486.759
489.551
492.273
494.927
497.519
500.049
502.522
504.940
507.305
509.619
511.884
514.104
516.278
518.410
520.501
522.551
524.564
526.540
528.481
530.387
532.260
534.101
35.912
537.693
539.445
Вг (г)
Таблица 370
Cl)-p(Bi)-p~l (CCl^Br) Дг#°@)= 1221.872 кДж • моль '
SV)
1
Н°(Т)-И°@)
кДж . моль
258.936 3.856
301.872 10.176
333.473 17.984
334.001 18.142
359.681 27.087
380.933 36.619
398.964 46.513
414.570 56.639
428.298 66.921
440,536 77.313
451.568 87.783
461.603. 98.313
470.803 108.887
479.295 119.496
487.177 130.133
494.531 140.792
501.422 151.469
507.905 162.162
514.024 172.867
519.8.18 183.583
525.319 194.308
530.556 205.042
535.552 215.781
540.328 226.527
544.904 237.278
549.295 248.034
553.515 258.793
557.577 269.557
561.492 280.323
565.271 291.092
568.923 301.864
572.456 312.639
575.877 323.415
579.194 334.194
582.412 344.974
585.538 355.756
588.575 366.539
591.530 377.324
594.407 388.110
597.209 398.897
599.940 409.685
602.604 420.474
605.204 431.264
607.744 442.055
610.224 452.847
«12.650 463.640
615.022 474.433
617.343 485.227
619.616 496.021
621.842 506.816
624.023 517:612
626.161 528.408
628.257 539.205
630.314 550.002
632.332 560.799
634.314 571.597
636.260 582.396
638.171 593.194
640.049 603.993
641.895 614.793
643.710 625.592
«•а,
-618.0646
-296.7008
-190.6022
-189.2675
-135.4505
-103.1167
-81.5388
-66.1137
-54.5377
-45.5296
-38.3204
-32.4201
-27.5019
-23.3396
-19.7713
-16.6783
-13.9717
-11.5833
-9.4601
-7.5603
-5.8504
-4.3033
-2.8969
-1.6127
-.4355
.6475
1.6472
2.5729
3.4324
4.2326
4.9795
5.6781
6.333!
6.9484
7.5274
8.0734
8.5890
9.0767
9.5388
9.9771
10.3935
10.7896
11.1668
11.5265
11.8698
12.1978
12.5116
12.8120
13.0998
13.3759
13.6410
13.8956
14.1405
14.3761
14.6030
14.8216
15:0324
15.2358
15.4321
15.6218
15.8052
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
— о
i 2
о % _
So о
ЕЗ О 5
i? о
¦* ^ т'
° Т а
о* II
? ' 2 ч
ОО " "> <=
— о оо' "ч.
И и ?! Jg
ВД " - II
г"^ *!+ 0 Vt
«- О ^
2; ?*
+
|
н
чО
О
X —'
s '« i
оо • о
3 « *"
о <"> V
1 г- f~,
2 " V
¦* + о
^ <м ">
°. о5 »'"
VD о 1
О о О
rf "Э- —'
_ 1 f^
? ? II
t^ ОО
00 .
II +
0
©
159

Класс точности
V1-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Л
с;(т-)
•G-,-рЮ.
Ф°G)
ДИХЛОРДИБРОММЕТАН
р2(С1)-/Лвг)-/Г1(СС12В1-2) Д
S°(T)
Дж - К . моль
54.763
75.562
87.052
87.217
94.162
98.341
100.959
102.677
103.855
Ш4.692
105.307
105.77!
106.129
106.411
106.636
106.819
106.970
107.095
107.201
107.291
107.367
107.434
107.491
107.541
107,586
107.625
107.659
107.690
107.718
107.743
107.765
107.786
107.804
107.821
107.836
107.850
107.863
107.875
107.886
107.896
107.906
107.914
107.923
107.930
107.937
107.944
107.950
107.956
107.961
107.966
107.971
107.976
107.980
107.984
107.988
107.991
107.995
107.998
108.001
108.004
108.007
230.395
262.519
285.651
286.040
305.131
321.321
335.407
347.880
359.073
369.224
378.51 1
387.067
395.000
402.393
409.316
415.824
421.963
427.774
433.289
438.538
443.544
448.328
452.91 1
457.308
461.533
465.600
469.519
473.301
476.956
480.491
483.915
487.233
490.453
493.580
496.619
499.574
501452
505.255
507.987
510.651
513.252
515.791
518.273
520.698
523.071
525.392
527.665
529.891
532.072
534.210
536.307
538.363
540.381
542.363
544.308
546.220
548.098
549.944
551.759
553.544
555.300
270.646
315.841
348.343
348.882
375.01 1
396.509
414.688
430.388
444.181
456.464
467.528
477.587
486.807
495.313
503.207
510.571
517.470
523.959
530.083
535.882
541.387
546.627
551.626
556.406
560.984
565.376
569.598
573.662
577.579
581.359
585.012
588.546
591.968
595.286
598.505
601.631
604.670
607.625
610.502-
613.305
616.036
618.701
621.302
623.841
626.322
628.748
631.121
633.442
635.715
637.941
640.123
642.261
644.358
646.414
648.433
650.414
652.360
654.272
656.150
657.996
659.812
СС1гВгг (г)
Я°@)= 1160.212
Н°(Т)-Н°@)
кДж • моль
4.025
10.665
18.692
18.853
27.952
37.594
47.569
57.756
68.086
78.516
89.017
99.572
1 10.168
120.795
i 31.448
142.121
152.81 1
163.514
174.229
184.954
195.687
206.427
217.173
227.925
238.681
249.442
260.206
270.974
281.744
292.517
303.292
314.070
324.850
335.631
346.414
357.198
367.984
378.771
389.559
400.348
411.138
421.929
432.721
443.514
454.307
465.101
475.896
486.691
497.487
508.283
519.080
529.877
540.675
551.473
562.272
573.071
583.870
594.670
605.470
616.270
627.070
1
-585.8515
-280.6701
-179.9262
-178.6590
-127.5660
-96.8744
-76.3963
-61.7601
-50.7779
¦42.2332
-35.3955
-29.7997
-25.1357
-21.1885
-17.8046
-14.8714
•12.3045
-10.0392
-8.0254
-6.2232
-4.6010
¦3.1331
•1.7985
-.5798
.5376
1.5656
2.5148
3.3937
4.2099
4.9700
5.6794
6.3432
6.9655
7.5502
8.1006
8.6195
9.1097
9.5734
10.0127
10.4296
10.8256
I 1.2024
1 1.5612
1 1.9034
12.2300
12.5422
12.8408
13.1267
13.4007
13.6636
13.9159
14.1584
14.3915
14.6159
14.8319
15.0401
15.2409
15.4347
15.6217
15.8025
15.9772
кДж • моль '
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
[—

-rill
*
Т а б л
i
2
X
о-
р
II
о
«ч
>г
С
о
0
<
„+
1
X
гч
О
г- _
р "J*
+ i
' О
n 2
1
н -
ЧО |
о *
© d
о <•>
1 г--
х ?!
? -;
ОО +
о "*
О 1/-)
+ 1
» я
О С1
о °?
II +
о
е
и и
о
2
=1
^
о
о
о
II
Я
ОС
C'i
•N
*\
J^1
СО
гч
О
О
а 371
t
с;
о
i
ОС
о
I—
¦
li
о в:
Я
о
о
45
V
V
о
vt
'о
II
160

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сп
59.234
78.695
89.298
89.450
95.763
99.510
101.836
103.354
104.391
105.126
105.664
106.070
106.382
106.628
106.825
106.984
107.-115
107.225
107.317
107.395
107.462
107.519
107.569
107.613
107.651
107.685
107.715
107.742
107.766
107.788
107.808
107.825
107.841
107.856
107.869
107.882
107.893
107.903
107.913
107.921
107.930
107.937
107.944
107.951
107.957
107.963
107.968
107.973
107.978
107.982
107.986
107.990
107.994
107.997
108.001
108.004
108.007
108.010
108.012
108.015
108.017
ХЛОРТРИБРОММЕТАН СС1Вг3
*V) = p(C).p(c
Ф°(Г)
Дж . К . моль
233.433
267.523
291.866
292.273
312.174
328.932
343.437
356.231
367.677
378.032
387.487
396.184
404.237
411.733
418.745
425.331
431.540
437.412
442.983
448.281
453.332
458.158
462.779
467.209
471.466
475.562
479.508
483.316
486.994
490.551
493.995
497.332
500.570
503.714 .
506.769
509.740
512.632
515.448
518.192
520.870
523.482
526.032
528.524
530.960
533.342
535.673
537.954
540.189
542.378
544.524
546.628
548.691
550.717
552.704
554.657
556.574
558.458
560.310
562.130
563.921
565.682
1) • Р3(Вг)
5°(Г)
276.037
323.921
357.497
358.050
384.729
406.535
424.899
440.719
454.592
466.932
478.038
488.128
497.372
505.897
513.806
521.182
528.091
534.588
540.720
546.524
552.035
557.279
562.282
567.065
571.645
576.041
580.265
584.331
588.249
592.031
595.686
599.221
602.645
605.963
609.183
612.310
615.350
618.306
621.184
623.987
626.719
629.384
631.985
634.526
637.008
639.433
641.807
644.129
646.402
648.628
650.810
652.948
655.045
657.102
659.121
661.103
663.049
664.961
666.839
668.686
670.501
p"l(CClBi3) &rh
Я°(П-Я°@)
кДж • моль
4.260
11.280
19.568
19.733
29.022
38.801
48.877
59.142
69.532
80.010
90.551
101.138
111.762
122.413
133.086
143.776
154.481
165.199
175.926
186.661
197.404
208.153
218.908
229.667
240.430
251.197
261.967
272.740
283.516
294.293
305.073
315.855
326.638
337.423
348.209
358.997
369.785
380.575
391.366
402.158
412.950
423.744
434.538
445.332
456.128
466.924
477.720
488.517
499.315
510.113
520.911
531.710
542.509
553.309
564.109
574.909
585.710
596.510
607.312
618.113
628.914
(г)
'°@)= 1096
о
-552.3173
-263.8210
-168.6016
-167.4040
-119.1226
-90.1268
-70.7846
-56.9633
-46.5945
-38.5285
-32.0747
-26.7936
-22.3921
-18.6672
•15.4739
-12.7059
-10.2834
-8.1454
-6.2445
¦4.5433
-3.0118
-1.6258
-.3655
.7855
1.8410
2.8122
3.7090
4.5396
5.311!
6.0295
6.7003
7.3279
7.9165
8.4695
8.9901
9.4811
9.9449
10.3837
10.7995
11.1941
11.5691
11.9258
12.2656
12.5897
12.8991
13.1947
13.4776
13.7485
14.0082
14.2573
14.4964
14.7263
14.9473
15.1600
15.3648
15.5623
15.7527
15.9364
16.1138
16.2852
16.4510
.722 кДж • моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
1
Л
К
_ о
'л ?
I a
X
* о
<^ 12
«л
и К ^
оо -¦¦¦. <~™<
N О «j
11 и S
Н Э
*¦*¦> а;
^\
н
о _
« 'л
+ 3
« ?
X ч'
«¦ 'iiS
in
О ^"*
i ъ
с
—1 t—(
C-i +
*1 4?
О оо
г- '
го «о
VD *°
чо го
11 +
с
0
а372
с;
„,*
i
00*
II
О 0?
><1
й
о
о
V
V
о
о
••п
О
*7
п
161

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<г>
ХЛОРБРОММЕТАН СН2С1Вг |
[г)
Таблица 373
Т) = р(С)-р2(Н)-р(С1)-р(Вг)-р~1(СН2С1Вг) ДгЯ°@) = 1411.619 кДж • моль
Ф°(П
S°(T)
Дж • К . моль
36.827
43.998
52.725
52.891
61.263
68.122
73.581
77.998
81.663
84.761
87.410
89.688
91.656
93.360
94.840
96.129
97.254
98.239
99.106
99.870
100.546
101.146
101.681
102.159
102.587
102.973
103.321
103.635
103.920
104.180
104.417
104.633
104.831
105.013
105.180
105.335
105.477
105.610
105.732
105.846
105.951
106.050
106.142
106.228
106.308
106.384
106.455
106.521
106.584
106.643
106.698
106.751
106.800
106.847
106.891
106.934
106.973
¦ 107.011
107.047
107.082
107.114
206.142 240.393
230.758 268.001
246.288 287.176
246.541 287.502
258.879 303.896
269.354 318.332
278.612 331.253
286.981 342.939
294.652 353.600
301.753 363.403
308.377 372.474
314.592 380.914
320.452 388.805
325.997 396.210
331.264 403.184
336.280 409.773
341.070 416.013
345.655 421.940
350.051 427.580
354.274 432.959
358.338 438.099
362.254 443.020
366.033 447.738
369.684 452.268
373.217 456.625
376.637 460.821
379.954 464.867
383.171 468.772
386.296 472.546
389.334 476.197
392.288 479.733
395.165 483.161
397.967 486.486
400.698 489.715
403.363 492.852
405.964 495.903
408.503 498.873
410.985 501.764
413.411 504.582
415.784 507.331
418.106 510.012
420.380 512.629
422.607 515.186
424.789 517.684
426.928 520.127
429.026 522.517
431.084 524.856
433.104 527.146
435.086 529.390
437.033 531.588
438.946 533.743
440.826 535.856
442.673 537.930
444.490 539.964
446.276 541.962
448.034 543.924
449.763 545.851
451.466 547.745
453.142 549.606
454.792 551.436
456.418 553.236
Я°(Г)-Я°@)
кДж • моль"
3.425
7,449
12.191
12.288
18.007
24.489
31.585
39.171
47.159
55.485
64.096
72.954
82.024
91.277
100.688
110.238
119.909
129.684
139.553
149.502
159.524
169.609
179.751
189.943
200.181
210.459
220.774
231.122
241.500
251.905
262.335
272.788
283.261
293.754
304.263
314.789
325.330
335.884
346.451
357.030
367.620
378.220
388.830
399.449
410.075
420.710
431.352
442.001
452.656
463.318
473.984
484.657
495.335
506.017
516.704
527.395
538.091
548.790
559.493
570.199
580.909
-721.6746
-350.4416
-227.6882
-226.1422
-163.7590
-126.2107
-101.1118
-83.1432
-69.6405
-59.1206
-50.6923
-43.7876
-38.0271
-33.1481
-28.9624
-25.3319
-22.1530
-19.3463
-16.8501
-14.6156
-12.6035
-10.7824
-9.1261
-7.6134
-6.2263
-4.9498
-3.7712
-2.6797
-1.6659
-.7218
.1595
.9841
1.7573
2.4837
3.1675
3.8123
4.4213
4.9975
5.5434
6.0614
6.5535
7.0216
7.4675
7.8927
8.2986
8.6864
9.0575
9.4127
9.7532
10.0798
10.3933
10.6946.
10.9843
11.2630
11.5315
11.7902
12.0396
12.2804
12.5128
12.7373
12.9544
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4-700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ОЛЬ
л
О ?5
О ^л
ч 1 §
3 | ? х
СО |( ^н f-Ч
ON ,—v 00* —•
<""Ч О - Os '•f
И ^" lT ""*
Ч. Ё \
X n о к
О Я со
"т. w
¦^ 0
+
1 _
чО 'j,
к 1
о! „'
+ 'biS
? 5 |
5 тн 1
¦^0 чО
О <N V
1 m *"*
х + V
В "н 8
1- ^ ю
00 ^ * "*
^* оо ^
^ °° о
Г- | «
g й ** ¦
то II
OV О
оо' о ?
¦Ч- "Н
II Ч-
ь^
о
©
162

Класс точности
VI-T
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
к°
С°р(Т)
42.856
56.741
67.394
67.571
75.827
81.836
86.229
89.546
92.144
94.238
95.963
97.404
98.620
99.654
100.540
101.302
101.962
102.535
103.036
103.475
103.862
104.205
104.509
104.779
105.022
105.239
105.435
105.612
105.772
105.918
106.050
106.171
106.282
106.383
106.477
106.563
106.642
106.716
106.784
106.847
106.906
106.961
107.012
107.059
107.104
107.146
107.185
107.222
107.257
107.289
107.320
107.349
107.377
107.403
107.427
107.450
107.473
107.493
107.513
107.532
107.550
ДИХЛОРБРОММЕТАН СНС12Вг
(Г) =р(С)р(Н)р2(С1)-р(Вг)-р
Ф°(Г)
Дж . К . моль"
221.408
248.550
266.957
267.263
282.294
295.120
306.407
316.527
325.719
334.150
341.944
349.194
355.974
362.343
368.351
374.037
379.435
384.572
389.474
394.162
398.652
402.963
407.108
411.098
414.946
418.661
422.253
425.728
429.095
432.360
435.529
438.608
441.602
444.514
447.351
450.114
452.809
455.438
458.004
460.511
462.962
465.357
467.701
469.995
472.242
474.442
476.599
478.714
480.788
482.823
484.820
486.781
488.707
490.600
492.460
494.288
496.086
497.855
499.595
501.307.
502.993
S°(T)
1
257.410
291.638
316.360
316.777
337.408
355.009
370.338
383.891
396.024
407.002
417.023
426.239
434.768
442.704
450.122
457.085
463.645
469.844
475.719
481.302
486.619
491.695
496.550
501.202
505.666
509.958
514.089
518.072
521.916
525.630
529.223
532.702
536.075
539.347
542.524
545.612
548.615
551.538
554.385
557.159
559.865
562.506
565.084
567.602
570.064
572.472
574.827
577.132
579.390
581.602
583.770
585.896
587.980
590.026
592.034
594.005
595.941
597.844
599.714
601.552
603.359
(СНС12Вг) Д h
Я°(Г)-Я°@)
кДж • моль
3.600
8.618
14.730
14.855
22.045
29.945
38.359
47.155
56.244
65.567
75.080
84.750
94.553
104.468
114.479
124.572
134.736
144.961
155.240
165.566
175.934
186.337
196.773
207.238
217.728
228.241
238.775
249.328
259.897
270.482
281.080
291.691
302.314
312.947
323.590
334.242
344.903
355.571
366.246
376.927
387.615
398.308
409.007
419.711
430.419
441.131
451.848
462.568
473.292
484.020
494.750
505.483 ¦
516.220
526.959
537.700
548.444
559.190
569.939
580.689
591.441
602.195
(г)
г°@)= 1317
о
-670.6310
-324.1398
-209.6357
-208.1942
-150.0476
-115.0754
-91.7144
-75.0007
-62.4481
-52.6735
-44.846!
-38.4364
-33.091!
-28.5652
-24.6836
-21.3180
-18.3718
-15.7712
-13.4587
-11.3891
-9.5259
-7.8397
-6.3065
-4.9064
-3.6227
-2.4415
-1.3511
-.3412
.5966
1.4698
2.2849
3.0474
3.7624
4.4340
5.0662
5.6624
6.2254
6.7580
7.2626
7.7413
8.1962
8.6288
9.0409
9.4338
9.8088
10.1672
10.5100
10.8383
11.1528
11.4546
11.7442
12.0225
12.2901
12.5476
12.7956
13.0345
13.2650
13.4873
13.7020
13.9093
14.1098
.388 кДж • моль
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
. 4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
1 „
л
к
_ о
i 2
с; L.
О *
¦й О
ч §
А •
О |
о '
о-. " -~-
°° ||' й
m S °°
-ч (^ ГЧ
II м- ?
О "
0 ^,
>¦ ' _
"•ч О
ч 1
!
! *
О »?
О \Q
1 2
н +
? ¦?
_|_ 1
00 О
С*) Г^
II +
о
374
->
А
О
.
1
О\
ОС
""
It
1?
я
о
о
о
V
V
о
о
«'"
'о
к.
II
163

Класс точности
VI- F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°
С°р(Т)
•
45.524
58.898
69.148
69.318
77.218
82.935
87.102
90.248
92.716
94.711
96.359
97.740
98.908
99.904
100.758
101.494
102.132
102.687
103.172
103.598
103.974
104.306
104.601
104.865
105.100
105.312
105.502
105.674
105.830
105.972
106.101
106.219
106.326
106.425
106.516
106.600
106.678
106.749
106.816
106.877
106.935
106.988
107.038
107.084
107.128
107.169
107.207
107.243
107.277
107.309
107.339
107.367
107.394
107.419
107.443
107.466
107.487
107.508
107.527
107.546
107.563
ХЛОРДИБРОММЕТАН СНС1Вг2
(Л =р(С)р(Н).р(С1)
Ф° (Г)
Дж • К~ . моль"
229.205
257.474
276.632
276.950
292.513
305.730
317.314
327.668
337.048
345.633
353.556
360.914
367.788
374.239
380.317
386.065
391.518
396.705
401.651
406.379
410.906
415.250
419.425
423.444
427.317
431.057
434.670
438.166
441.552
444.835
448.021
451.116
454.124
457.051
459.900
462.676
465.383
468.023
470.600
473.117
475.577
477.982
480.335
482.637
484.892
487.100
489.264
491.386
493.466
495.508
497.512
499.479
501.411
503.308
505.174
507.008
508.810
510.584
512.328
514.046
515.736
•Р2(вг).р-
S°(T)
266.481
302.413
327.919
328.347
349.429
367.309
382.817
396.491
408.709
419.748
429.815
439.066
447.622
455.579
463.015
469.992
476.563
482.772
488.655
494.245
499.569
504.650
509.509
514.165
518.633
522.928
527.062
531.047
534.893
538.609
542.204
545.685
549.059
552.332
555.511
558.600
561.604
564.528
567.375
570.151
572.857
575.498
578.077
580.596
583.059
585.467
587.822
590.129
592.387
594.599
596.767
598.893
600.978
603.024
605.032
607.004
608.941
610.843
612.713
614.551
616.359
'(СНСШгг) Д
(г)
гЯ°@)= 1253.582
Н°(Т)-Н°@)
кДж . моль"
3.728
8.988
15.291
15.419
22.766
30.790
39.302-
48.176
57^329
66.704
76.260
85.967
95.801
105.742
115.777
125.890
136.072
146.314
156.607
166.946
177.325
187.739
198.185
208.658
219.157
229.678
240.219
250.778
261.353
271.943
282.547
293.163
303.790
314.428
325.075
335.731
346.395
357.066
367.744
378.429
389.120
399.816
410.517
421.223
431.934
442.649
453.368
464.090
474.816
485.546
496.278
507.013
517.751
528.492
539.235
549.980
560.728
571.478
582.230
592.983
603.739
1
-637.1803
-307.4128
' -198.4363
-197.0646
-141.7289
-108.4513
-86.2254
-70.3260
-58.3864
-49.0902
-41.6465
-35.5513
-30.4683
-26.1647
-22.4737
-19.2731
-16.4712
-13.9979
-11.7984
-9.8297
-8.0572
-6.4529
-4.9940
-3.6616
-2.4398
-1.3154
-.2773
.6842
1.5772
2.4089
3.1852
3.9117
4.5928
5.2328
5.8353
6.4034
6.9401
7.4478
7.9289
8.3854
8.8191
9.2317
9.6248
9.9995
10.3573
10.6993
11.0264
11.3396
11.6398
11.9278
12.2042
12.4699
12.7254
12.9712
13.2080
13.4361
13.6562
13.8685
14.0735
14.2716
14.4630
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900 .
6000
Таб л
_
'л
о
2
со
о
OS OS
OS <ч
fS "
«j о
о
<"•< и
11
^ СО
о
S: ¦
О
+
7
+ i
й «
3 ч
О 5
1 °®
X +
JS с
о ^
О ?
. j
о гч
г-^ ^
со \о
»Л vs
II +
о
в
и ц а
к
о
¦с
О
о
о
о
II
Ь4
оо
(Ч
и
гч
щ
О
375
i
А
О
.
1
О
Г*
II
о ее
со
2
о
о •
о
V
к,
V
о
о
«о
»'"
'о
к.
II
164

Класс точности
VI-1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
АГ°
С°р(Т)
42.303
61.647
74.649
74.851
83.959
90.203
94.497
97.501
99.653
101.232
102.418
103.329
104.041
104.607
105.063
105.437
105.746
106.005
106.223
106.409
106.569
106.707
106.827
106.933
107.025
107.107
107.180
107.245
107.304
107.356
107.404
107.447
107.486
107.521
107.554
107.584
107.611
107.636
107.659
107.681
107.701
107.719
107.737
107.753
107.768
107.782
107.795
107.807
107.819
107.829
107.840
107.849
107.858
107.867
107.875
107.882
107.890
107.896
107.903
107.909
107.915
ДИФТОРХЛОРБРОММЕТАН
(Г) = p(C)-p2(F)-p(Cl)-p(Br)-p~1
ФО(Г)
Дж • К . моль
220.325 "
247.434
266.550
266.872
282.868
296.679
308.903
319.889
329.874
339.026
347.475
355.319
362.640
369.502
375.959
382.056
387.830
393.314
398.535
403.517
408.282
412.846
417.227
421.437
425.491
429.399
433.171
436.816
440.343
443.758
447.070
450.283
453.404
456.438
459.389
462.261
465.060
467.788
470.449
473.046
475.582
478.060
480.483
482.853
485.172
487.443
489.666
491.845
493.981
496.076
498.131
500.148
502.127
504.072
505.981
507.858
509.703
«11.516 .
513.300
515.055
516.782
5°(Г)
1
255.818
291.433
318.631
319.093
341.955
361.405
378.254
393.060
406.228
418.061
428.791
438.597
447.619
455.970
463.740
471.002
477.816
484.235
490.301
496.049
501.511 .
506.714
511.681
516.432
520.985
525.356
529.558
533.604
537.506
541.272
544.912
548.435
551.847
555.155
558.365
561.483
564.514
567.463 '
570.334
573.131
575.857
578.517
581.113
583.648
586.125
588.548
590.916
593.235
595.505
597.728
599.906
602.042
604.136
606.191
608.207
610.187
612.131
614.040
615.917
617.762
619.575
(CFjClBr)
Н°(Т)-Н
CF2OBr (г)
ДгЯ°@)= 1527.081 кДж моль
"@)
кДж . моль"
3.549
8.800
15.528
15.666
23.635
32.363
41.611
51.219
61.083
71.131
81.316
91.606
101.975
112.409
122.893
133.419
143.978
154.566
165.178
175.810
186.459
197.123
207.800
218.488
229.186
239.892
250.607
261.328
272.056
282.789
293.527
304.269
315.016
325.766
336.520
347.277
358.036
368.799
379.564
390.331
401.100
411.871
422.644
433.418
444.194
454.972
465.751
476.531
487.312
498.094
508.878
519.662
530.448
541.234
552.021
562.809
573.597
584.387
595.177
605.967
616.758
-778.2958
-377.0163
-244.4870
-242.8192
-175.5656
-135.1461
-108.1669
-88.8788
-74.4031
-63.1386
-54.1235
-46.7454
-40.5956
-35.3910
-30.9292
-27.0620
-23.6778
-20.6916
-18.0371
-15.6618
-13.5241
-11.5899
-9.8315
-8.2261
-6.7544
-5-.4004
-4.1506
-2.9935
-1.9189
-.9185
.0151
.8885
1.7074
2.4765
3.2004
3.8830
4.5275
5.1373
5.7149
6.2629
6.7834
7.2786
7.7502
8.1998
8.6290
9.0390
9.4313
9.8068
10.1667
10.5119
10.8433
11.1616
11.4678
11.7623
12.0459
12.3192
12.5828
12.8370
13.0825 .
13.3197
13.5490
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
Ь0
1500
1600
1700
1800
. 1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800 .
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
-
с;
_ О
'л *
о Д
* О
«* , О
i *
m
r-i "
x -ч- —
II "^
2 . ^
" I' -'
!§¦ » I' '
С 2
? S^
o ^
^Z о
+
-
4
00 'j
*"¦ о
+ 2
гч _'
ч 'ьй
—
с "ч
1 г—
X ¦*
5 +
г- X
о "
/ ОС
о -
~" Т
u-i ч
00 ?-
»л ^"
II +
о
а 376
i
3
.
i
—
1/-.
II
с!
о ж
2
о
о
S
V
*"
V
о
,¦"
1
о
^
II
165

Класс точности
VI-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°
С°(Т)
46.310
67.316
80.106
80.298
88.630,
94.013
97.564
99.980
101.678
102.907
103 821
104.518
105.059
105.488
105.832
106.113
106.346
106.539
106.703
106.842
106.961
107.064
107.153
107.232
107.301
107.362
107.416
107.464
107.507
107.546
107.581
107.613
107.642
107.669
107.693
107.715
107.735
107.754
107.771
107.787
107.802
107.815
107.828
107.840
107.851
107.861
107.871
107.880
107.889
107.897
107.904
107.911
107.918
107.924
107.930
107.936
107.941
107.946
107.951
107.956
107.960
ФТОРДИХЛОРБРОММЕТАН CFCi
(Л = p(C>p(F)-p2
Ф°(Г)
Дж • К • моль
225.250
253.957
274.540
274.887
292.090
306.863
319.857
331.468
341.966 .
351.546
360.355
368.508
376.094
383.187
389.848
396.124
402.059
407.686
413.037
418.136
423.007
427.669
432.139
436.432
440.561
444.539
448.376
452.082
455.666
459.135
462.496
465.756
468.921
471.996
474.986
477.895
480.729
483.490
486.183
488.810
491.375
493.880
496.329
498.724
501.067
503.360
505.606
507.806
509.962
512.076
514.149
516.184
518.181
520.141
522.067
523.959
525.819
527.647
529.445
, 531.213
532.953
(С„.р(ВГ).р
S°(T)
1
262.069
301.205
330.653
331.150
355.479
375.877
393.353
408.585
422.053
434.104
444.996
454.925
464.043
472.470
480.301
487.612
494.468
500.922
507.016
512.789
518.272
523.493
528.476
533.241
537.806
542.188
546.400
550.454
554.364
558.137
561.783
565.312
568.728
572.041
575.256
578.378
581.412
584.365
587.238
590.038
592.767
595.429
598.028
600.565
603.044
605.468
607.839
610.159
612.430
614.655
616.835
618.67? ,
621.067
623.123
625.140
627.120
629.066
630.976
632.853
634.699
636.513
"'(CFCljBr) А.Н
Я°(Г)-Я°@)
кДж . моль
3.682
9.450
16.730
16.879
25.356
34.507
44.098
53.982
64.070
74.302
84.641
95.059
105.539
116.067
126.634
137.232
147.855
158.500
169.162
179.839
190.530
201.231
211.942
222.661
233.388
244.121
254.860
265.604
276.352
287.105
297.861
308.621
319.384
330.150
340.918
351.688
362.461
373.235
384.011
394.789
405.569
416.350
427.132
437.915
448.700
459.485
470.272
481.060
491.848
502.637
513.427
524.218
535.010
545.802
556.595
567.388
578.182
588.976
599.771
610.566
621.362
2Вг (г)
D@)= 1370.451 кДж-моль
-о
-696.3339
-336.0550
-217.0843
-215.5874
-155.2266
-118.9551
-94.7471
-77.4411
-64.4534
-54.3468
-46.2585
-39.6389
-34.1212
-29.4516
-25.4485
-21.9787
-18.9423
-16.2630
-13.8813
-11.7501
-9.8320
-8.0966
-6.5189
-5.0783
-3.7579
-2.5430
-1.4217
-.3834
.5808
1.4784
2.3161
3.0998
3.8345
4.5246
5.1742
5.7866
6.3649
6 9120
7.4303
7.9220
8.3891
8.8333
9.2565
9.6599
10.0450
10 4129
10.7648
11.1018
11.4247
11.7344
12.0317
12.3174
12.5920
12.8563
13.1108
13.3560
13.5924
13.8206
14.0409
14.2537
14.4594
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб
_
§
s
\?
ОО
•
on !
оо "
оо о
V "„
§ «
у
О
-
с--
—. ^
• 1
+ g
о ^
о ">
1 -5
о м+
оо X
О ^с
i 1
г- ^
UO 00
II +
о
л и
1
о
f
о
о
о
1О
О|
1
II
я,
оо
OS
03
с
г .
ч-'
<]
ца 377
__
'¦д
с;
о
-'
'be!
ОО
оо
II
о си
to
я
о
о
о
V
?¦*
V
о
о
•""
'о
II
.is
166

Класс точности
V1-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с°(Т)
49.889
70.429
82.337
82.514
90.213
95.170
98.434
100.653
102.21
103.339
104.177
104.816
105.312
105.705
106.021
106.279
106.491
106.669
106.819
106.946
107.055
107.150
107.232
107.303
107.367
107.422
107.472
107.516
107.556
107.592
107.624
107.653
107.680
107.704
107.726
107.746
107.765
107.782
107.798
107.812
107.826
107.838
107.850
107.861
107.871
107.880
107.889
107.898
107.905
107.913
107.920
107.926
107.932
107.938
107.943
107.949
107.954
107.958
107.963
107.967
107.971
ФТОРХЛОРДИБРОММЕТАН CFClBr2 (г)
7") =p(Qp(F)p(ClVp2(Br)
Ф°(Г)
Дж • К . моль
232.434
262.619
284.235
284.598
302.518
317.805
331.180
343.085
353.815
363.583
372.548
380.831
388.529
395.718
402.461
408.811
414.810
420.495
425.897
431.043
435.956
440.656
445.161
449.485
453.645
457.650
461.512
465.242
468.847
472.337
475.717
478.995
482.176
485.267
488.272
491.196
494.043
496.817
499.521
502.160
504.736
507.252
509.711
512.115
514.467
516.768
519.022
521.230
523.394
525.515
527.596
529.637
531.640
533.607
535.539
537.437
539.302
541.136
542.939
544.712
546.457
1
270.808
312.403
342.922
3'43.432
368.306
389.009
406.669
422.020
435.568
447.675
458.608
468.568
477.711
486.156
494.002
501.326
508.192
514.653
520.755
526.534
532.022
537.248
542.234
547.003
551.571
555.955
560.169
564.226
568.137
571.912
575.560
579.089
582.507
585.821
589.037
592.160
595.196
598.148
601.023
603.823
606.553
609.216
611.814
614.352
616.832
619.256
621.627
623.948
626.219
628.444
630.625
632.762
634.858
636.913
638.931
640.912
642.857
644.768
646.645
648.491
650.306
р~'(СГСШгг>
Н°{Т)-Н
Д Я°@)= 1301.852
'@)
кДж . моль"
3.837
9.957
17.498
17.650
26.315
35.602
45.293
55.254
65.402
75.682
86.060
96.511
107.019
117.570
128.157
138.772
149.411
160.070
170.744
181.432
192.133
202.843
213.562
224.289
235.023
245.762
256.507
267.256
278.010
288.767
299.528
310.292
321.059
331.828
342.599
353.373
364.148
374.926
385.705
396.485
407.267
418.050
428.835
439.620
450.407
461.195
471.983
482.772
493.562
504.353
515.145
525.937
536.730
547.524
558.318
569.112
579.907
590.703
601.499
612.296
623.092
-660.3478
-318.0627
-205.0462
-203.6245
-146.2929
-111.8477
-88.8626
-72.4336
-60.1р59
-50.5143
-42.8389
-36.5576
-31.3223
-26.8917
-23.0935
-19.8013
¦16.9202
-14.3778
-12.1175
-10.0950
-8.2744
-6.6271
-5.1293
-3.7617
-2.5078
-1.3542
-.2891
.6971
1.6130
2.4658
3.2619
4.0066
4.7049
5.3609
5.9784
6.5606
7.1105
7.6308
8.1237
8.5914
9.0357
9.4583
9.8609
10.2448
10.6112
Г0.9614
11.2963
11.6171
i 1.9245
12.2193
12.5024
12.7744
13.0359
13.2876
13.5299
13.7635
13.9887
14.2060
14.4159
14.6186
14.8146
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
§
2
L
С[
¦"¦
с-*
г-
2. !L
fN °
э
о
о
о
<*•
+
-
К
00
гч
+ §
<ч 2
X —'
rs
2 *
§ «н
J3 °.
°. о
ч?> СО
О З-ч
г- ¦
О ^-О
ОО Г-
II +
0
в
-
о
|
О
о
¦•¦О
с-
11
2
¦¦о
ОО
о
U*
гч
CQ
О
о
378
'л
с;
о
§
'а
д
.041.
I—
о 5
to
2
|
V
*-¦
V
§
в*'"
'о
ii
167

Класс точности
VI -F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
¦000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
580С
5900
6000
кс
С°р(Т)
39.606
52.442
62.868
63.047
71.686
78.318
83.321
87.154
90.166
92.588
94.572
96.220
97.602
98.771
99.768
100.622
101.358
101.996
102.552
103.038
103.466
103.844
104.179
104.477
104.743
104.982
105.196
105.390
105.566
105.725
105.870
106.002
106.123
106.234
106.336
106.430
106.516
106.596
106.671
106.739
106.804
106.863
106.919
106.971
107.019
! 07.055
107.108
107.148
107.185
107.221
107.254
107.286
107316
107 344
107.371
107.396
107.420
107.443
107.464
107.485
107.505
ФТОРХЛОРБРОММЕТАН CHFClBr
(Г) = p(C)-p(H)-p(F>
Ф°(Г)
Дж . К . моль
215.439
241.303
258.570
258.857
272.928
284.969
295.613
305.204
313.956
322.017
329.496
336.476
343.023
349.188
355.016
360.541
365.796
370.805
375.592
380.174
384.569
388.793
392.857
396.773
400.553
404.205
407.737
411.158
414.474
417.691
420.815
423.852
426.805
429.68»
432.481
435.211
437.874
440.473
443.011
445.490
447.915
450.286
452.606
454.878
457.102
459.282
461.419
463.515
465.570
467.588
469.568
471.513
473.424
475.301
477.146
478.961
480.745
482.501
484.228
485.928
487.602
р(С1)-р(Вг)
S°(T)
250.329
281.871
304.812
305.202
324.572
341.315
356.058
369.202
381.044
391.808
401.670
410.763
419.196
427.056
434.413
441.326
447.844
454.009
459.855
465.413
470.709
475.767
480.605
485.243
489.695
493.976
498.098
502.072
505.907
509.615
513.201
516.675
520.042
523.310
526.483
529.566
532.566
535.485
538.329
541.101
543.804
546.442
549.018
551.534
553.994
556.400
558.753
561.057
563.313
565.524
567.690
569.815
571.898
573.943
575.949
577.920
579.855
581.756
583.65
585.463
587.269
p-'(CHFClBr) Д^
Я°(Г)-Я°@)
кДж • моль
3.489
8.114
13.787
13.903
20.657
28.173
36.267
44.798
53.670
62.812
' 72.173
81.715
91.408
101.229
111.157
121.177
131.277
141.446
151.674
161.954
172.279
182.645
193.047
203.480
213.941
224.427
234.936
245.466
256.014
266.579
277.158
287.752
298.358
308.976
319.605
330.243
340.890
351.546
362.209
372.880
383.557
394.241
404.930
415.624
426.324
437.028
447.737
458.449
469.166
479.886
490.610
501.337
512.067
522.800
533.536
544.275
555.015
565.758
576.504
587.251
598.001
(г)
tf°@)= 1459.
о
-744.8395
-361.2138
-234.4354
¦232.8395
-168.4544
-129.7282
-103.8595
-85.3519
-71.4527
-60.6301
-51.9639
-44.8677
-38.9501
-33.9400
-29.6433
-25.9179
-22.6569
-19.7785
-17.2192
-14.9286
-12.8666
-11.0005
-9.3038
-7.7543
-6.3338
-5.0267
-3.8200
-2.7025
-1.6648
-.6986
.2033
1.0471
1.8382
2.5814
3.2809
3.9405
4.5635
5.1528
5.7111
6.2408
6.7441
7.2228
7.6787
8.1134
8.5284
8.9249
9.3042
9.6674
10.0154
10.3493
10.6697
10.9777
11.2737
11.5586
11.8330
12.0974
12.3523
12.5983
12.8358
13.0652
13.2870
278 кДж • моль"
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
-
-
_ о
7 «
1 &
Х О
*-¦ со
ч* ГЧ
ГЧ I
. 1
г- II
ГО »-Н "
^ N ,-s
С— 1 V
" II 2
—' ° а\
" м U
5 а с
о а
Я в.
О ч
Н «-4
ГЦ
+ 1
I .
8 "-
О -и
о Ч
1 J^
¦В м
°^ О
«о °.
<* К
оо "
+ 1
.** X
Г- OJ
II +
0
в
ца 379
о
. —"
i
•
ГЧ
"
я
о
ЧО
V
S-.
V
§
«О
**"
'о
^.
и
а,
168

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300.
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
ИОДИД УГЛЕРОДА CI (г)
К°(Т)=р(С)рA)р~1(.С1)
Ф°(Г)
5°(Г)
Дж . К . моль
29.368
33.411
36.908
36.951
38.348
38.748
38.802
38.757
38.696
38.647
38.616
38.603
38.607
38.625
38.655
38.697
38.748
38.808
38.876
38.952
39.035
39.124
39.217
39.314
39.414
39.513
39.611
39.705
39.794
39.874
39.945
40.004
40.050
40.081
40.096
40.094
40.075
40.037
39.982
39.909
39.818
39.710
39.585
39.445
39.290
39.121
38.939
38.745
38.540
38.326
38.103
37.872
37.635
37.392
37.145
36.893
36.639
36.382
36.124
35.866
35.607
176.620 205.721
197.018 227.132
209.363 241.206
209.560 241.434
218.942 252.292
226.504 260.903
232.844 267.975
238.301 273.953
243.088 279.124
247.350 283.679 '
251.190 287.749
254.684 291.429
257.888 294.788
260.847 297.879
263.595 300.742
266.162 303.410
268.568 305.909
270.835 308.260
272.976 310.480
275.006 312.584
276.936 314.584
278.774 316.491
280.530 318.313
282.211 320.059
283.823 321.734
285.372 323.345
286.862 324.897
288.299 326.393
289.685 327.839
291.025 329.237
292.322 330.590
293.578 331.900
294.795 333.171
295.977 334.404
297.125 335.601
298.241 336.763
299.327 337.892
300.384 338.990
301.414 340.057
302.418 341.095
303.398 342.104
304.354 343.086
305.287 344.041
306.199 344.971
307.091 345.876
307.963 346.757
308.815 347.615
309.650 348.451
310.467 349.264
311.267 350.057
312.050 350.828
312.818 351.581
313.570 352.314
314.308 353.028
315.032 353.725
315.741 354.404
316.438 355.067
317.121 ,355.713
317.792 356.343
318.451 356.959
319.097 357.559
Д/.Я°@) = 250.000
Н°СГ)-Н°@)
кДж . моль
2.910
6.023
9.494
9.562
13.340
17.199
21.078
24.957
28.829
32.696
36.559
40.420
44.280
48.142
52.006
55.873
59.745
63.623
67.507
71.399
75.298
79.206
83.123
87.049
90.986
94.932
98.888
102.854
106.829
110.813
114.804
118.801
122.804
126.811
130.820
134.829
138.838
142.844
146.845
150.839
154.826
158.802
162.767
166.719
170.656
174.576
178.479
182.363
186.228
190.071
193.892
197.691
201.466
205.217
208.944
212.646
216.322
219.973
223.599
227.198
230.771
-126.8356
-61.0202
-39.2752
-39.0016
-27.9701
-21.3423
-16.9187
-13.7555
-11.3805
-9.5312
-8.0500
-6.8367
-5.8244
-4.9669
-4.2310
-3.5925
-3.0331
-2.5389
-2.0991
-1.7052
-1.3501
-1.0285
-.7358
-.4682
-.2225
.0038
.2129
.4069
.5872
.7553
.9125
1.0597
1.1980
1.3280
1.4506
1.5664
1.6760
1.779.8
1.8783
1.9719
2.0610
2.1459
2.2270
2.3044
2.3785
2.4495
2.5175
2.5828
2.6455
2.7059
2.7639
2.8199
2.8738
2.9259
2.9762
3.0248
3.0718
3.1173
3.1615
3.2042
3.2457
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300-
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 380
—
л
О
1 . 1*
й * й
*е Сч О
* J -'
R -i 'v
И d .
оч « и б
ОО °° /-^ OS
—" "¦> to **
II II -J «X
w_ /~-ч 00 *~*
«5 О O\
- <N II
и
П ~ ° **
w П ^
О *-—'
^ О
1
1
H ^
Si л
¦* з
о ^
7+ T*
^ Д §
OS R о
о •* V
О os ^
+ d у
17 8
8 Ъ „"
со Ч <=>
го со *""
CO (Й "
00* ° ^
00
ft cO
11 1
о
169

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
сцг>
39.438
46.228
50.944
51.009
53.624
55.087
55.963
56.522
56.898
57.162
57.356
57.505
57.629
57.74.1
57.854
57.977
58.119
58.287
58.485
58.717
58.985
59.287
59.622
59.987
60.380
60.795
61.227
61.673
62.127
62.584
63.040
63.490
63.930
64.357
64.768
65.160
65.530
65.878
66.201
66.500
66.772
67.019
67.239
67.435
67.605
67.751
67.873
67.978
68.052
68.110
68.149
68.171
68.176
68.165
68.140
68.102
68.053
67.992
67.921
67.842
67.755
ДИИОДИД УГЛЕРОДА С12 (г)
К°(Г)= Р(С)р
Ф°(Г)
Дж . К . моль
219.639
245.476
261.759
262.021
274.594
284.839
293.514
301.048
307.711
313.686
319.102
324.055
328.619
332.851
336.796
340.490
343.965
347.244
350.350
353.300
356.110
358.792
361.359
363.820
366.186
368.462
370.657
372.777
374.827
376.812
378.736
380.605
382.420
384.186
385.906
387.581
389.216
390.811
392.369
393.892
395.381
396.839
398.266
399.664
401.033
402.376
403.694
404.987
406.256
407.502
408.726
409.929
411.112
412.274
413.417
414.542
415.648
416.737
417.809
418.865
419.904
\1)-р-\С12)
S°(T)
1
255.302
284.739
304.163
304.479
319.549
331.687
341.814
350.486
358.060
364.777
370.810
376.284
381.293
385.911
390.194
394.189
397.936
401.464
404.801
407.969
410.988
413.872
416.638
419.296
421.858
424.331
426.724
429.043
431.294
433.482
435.611
437.686
439.708
441.682
443.610
445.493
447.334
449.134
450.895
452.619
454.306
455.958
457.575
459.160
460.712
462.233
463.724
465.184
466.616
468.020
469.396
470.746
472.070
473.369
474.643
475.892
477.119
478.323
479.505
480.665
481.805
A h
Я°(Л-Я°@)
кДж ¦ моль
3.566
7.853
12.643
12.737
17.982
23.424
28.980
34.606
40.279
45.982
51.709
57.452
63.209
68.977
74.757
80.548
86.353
92.173
98.011
103.871
109.756
115.669
121.614
127.595
133.613
139.671
145.772
151.917
1 СО I tV7
1 5о. 107
164.343
170.624
176.951
183.322
189.736
196.193
202.689
209.224
215.795
222.399
229.034
235.698
242.388
249.101
255.835
262.587
269.355
276.136
282.929
289.730
296.538
303.351
310.167
316.985
323.802
330.618
337.430
344.238
351.040
357.836
364.624
371.404
Г°@)= 455.511
-229.2635
-109.3065
-69.6646
-69.1656
-49.0429
-36.9456
-28.8679
-23.0900
-18.7510
-15.3723
-12.6663
-10.4499
-8.6010
-7.0349
-5.6912
-4.5254
-3.5044
-2.6025
-1.8001
-1.0814
-.4340
.1524
.6860
1.1736
1.6210
2.0329
2.4135
2.7662
п ЛПЛЛ
3.U940
3.3993
3.6845
3.9515
4.2019
4.4373
4.6589
4.8679
5.0655
5.2524
5.4295
5.5976
5.7573
5.9092
6.0540
6.1920
6.3238
6.4497
6.5702
6.6855
6.7961
6.9021
7.0039
7.1018
7.1958
7.2864
7.3735
7.4575
7.5386
7.6168
7.6923
7.7652
7.8357
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 381
V
1
7 * —
й ' 1
о Д с
v * i
5 <?• 'v
8200
.000]
= 468
Цж-1
• о ^
к ? .
II . О
/"^ 00 С1
S О ON
* <N л
* iS *+
« . э
D j V
f о
>-> а;
i
О\ 2
о 7
1
i * 1
о 5 °
о оо V
1 S *""
^ «' §
S3 '°
чо m il
Tf СО
0
е
170

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
53.813
63.692
70.549
70.650
74.875
77.393
78.956
79.975
80.669
81.162
81,523
81.794
82.004
82.168
82.300
82.406
82.494
82.567
82.629
82.681
82.726
82.764
82.798
82.827
82.853
82.875
82.895
82.913
82.929
82.944
82.957
82.969
82.980
82.989
82.998
83.006
83.014
83.021
83.027
83.033
83.039
83.044
83.048
83.053
83.057
83.061
83.064
83.068
83.071
83.074
83.077
83.079
83.082
83.084
83.086
83.088
83.090
83.092
83.094
83.096
83.097
ТРИИОДИД УГЛЕРОДА С13 (г)
К°(Т)= р(С)-р
Ф°(Г)
Дж . к . моль"
250.449
283.041
304.491
304.840
321.695
335.577
347.424
357.773
366.968
375.241
382.764
389.661
396.028
401.943
407.464
412.642
417.516
422.120
426.482
430.627
434.575
438.345
441.950
445.406
448.724
451.915
454.988
457.951
460.812
463.578
466.255
468.849
471.364
473.805
476.177
478.483
480.727
482.911
485.040
487.116
489.141
491.118
493.049
494.936
496.781
498.587
500.353
502.084
503.779
505.439
507.068
508.665
510.232
511.770
513.281
514.764
516.221
517.053
519.061
520.446
521.807
3A)-р~\С13)
S°iT)
1
293.618
334.135
360.943
361.380
382.336
399.338
413.597
425.850
436.577
446.109
454.679
462.463
469.589
476.160
482.254
487.936
493.257
498.260
502.982
507.451
511.693
515.730
519.581
523.262
526.788
530.170
533.421
536.550
539.566
542.476
545.288
548.009
550.643
553.196
555.674
558.080
560.419
562.693
564.907
567.064
569.166
571.217
573.218
575.172
577.082
578.948
580.774
582.560
584.309
586.022
587.700
589.346
590.959
592.541
594.094
595.619
597.116
598.587
600.032
601.452
602.849
ДгЯ°@) = 622.674 кДж • моль"
Я°(Л-Я°@)
кДж . моль"
4.317 -311.0229
10.219 -147.0084
16.831 -92.8308
16.962 -92.1491
24.256 -64.6614
31.880 -48.1461
39.704 -37.1255
47.653 -29.2483
55.688 -23.3374
63.781 -18.7382
71.91G -15.0576
80.082 -12.0455
88.273 -9.5348
96.482 -7.4100
104.705 -5.5883
112.941 -4:0093
121.186 -2.6273
129.439 -1.4077
137.699 -.3234
145.964 .6471
154.235 1.5207
162.509 2.3115
170.788 3.0306
179.069 3.6875
187.353 4.2899
195.639 4.8444
203.928 5.3566
212.218 5.8311
220.510 6.2720
228.804 6.6828
237.099 7.0666
245.395 7.4258
253.693 7.7629
261.991 8.0799
270.290 8.3785
278.591 8.6603
286.892 8.9267
295.194 9.1790
303.496 9.4182
311.799 9.6455
320.103 9.8616
328.407 10.0674
336.711 10.2636
345.016 10.4509
353.322 10.6300
361.628 10.8012
369.934 10.9653
378.241
386.548
394.855
403.162
411 470
419.778
428.086
.1225
.2734
.4183
.5576
.6915
.8205
.9448
436.395 12.0646
444.704 12.1802
453.013 12.2918
461.322 12.3997
469.631 12.5039
477.940 12.6048
486.250 12.7024
Т ¦
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300-
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 382
¦
7
•м О
1 S
к „ 1
§ п 3
* \> о
S
ж* • \?
г- d " с!
гч -; Q m
О\ ~ мм \Q
«II "> <N
II ,-. • >Л
;§ . 3; ^ •
t- ^ II
о У,
It «
**» 0
< ^
<
_+
i
X
r-
oo
CO
+ 1
¦ s
x T _
S « i
О m
1 — *"*
x °°. V
¦S ? о
_* + о
СГ\ ^» •«
<N GO ',~i
оо *
+ 7 Т
1 *
_* ^> н
il +
0
©
171

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
.С°р(Т)
72.543
87.430
95.704
95.816
100.298
102.794
104.285
105.235
105.873
106.321
106.647
106.891
107.078
107.225
107.342
107.437
107.515
107.579
107.634
107.680
107.719
107.753
107.783
107.809
107.831
107.851
107.869
107.885
107.899
107.912
107.923
107.934
107.943
107.952
107.959
107.967
107.973
107.979
107.985
107.990
107.995
107.999
108.003
108.007
108.011
108.014
108.017
108.020
108.023
108.026
108.028
108.030
108.033
108.035
108.037
108.038
108.040
108.042
108.043
108.045
108.046
ТЕТРАИОДИД УГЛЕРОДА С1<
Ф°(Г)
Дж • К . моль
247.509
288.660
316.892
317.355
339.785
358.295
374.080
387.848
400.059
411.030
420.990
430.111
438.522
446.327
453.606
460.426
466.842
472.898
478.633
484.080
489.265
494.213
498.945
503.478
507.828
512.011
516.038
519.920
523.668
527.289
530.794
534.189
537.480
540.674
543.776
546.792
549.726
552.583
555.366
558.079
560.725
563.309
565.832
568.297
570.708
573.066
575.374
577.633
579.846
582.015
584.141
586.226
588.272
590.280
592.251
594.186
596.088
597.957
599.794
601.600
6С3.377
*(I)-P-(CI4) V
S°(T)
1
Я°(Г)-Я°@)
кДж • моль
299.802 5.229
355.172 13.303
391.789 22.331
392.381 22.508
420.625 32.336
443.300 42.502
462.184 52.862
478.336 63.341
492.432 73.899
504.930 84.510
516.150 95.159
526.326 105.837
535.635 116.535
544.212 127.251
552.163 137.979
559.572 148.718
566.508 159.466
573.028 170.221
579.179 180.982
585.000 191.747
590.524- 202.517
595.780 213.291
600.794 224.068
605.586 234.848
610.174 245.630
614.577 256.413
618.807 267.200
622.878 277.987
626.802 288.776
630.588 299.567
634.247 310.359
637.786 321.152
641.213 331.945
644.535 342.740
647.757 353.536
650.887 364.332
653.929 375.129
656.887 385.927
659.767 396.725
662.572 407.524
665.306 418.323
667.973 429.123
670.575 439.923
673.117 450.723
675.600 461.524
678.027 472.326
680.401 483.127
682.724 493.929
684.998 504.731
687.226 515.534
689.408 526.336
691.548 537.139
693.645 547.942
695.703 558.746
697.723 569.549
699.705 580.353
701.652 591.157
703.564 601.961
705.443 612.765
707.290 623.570
709.106 634.374
(г)
Г°@) = 794.725
-393.5730
-184.3181
-115.2691
-1 14.4008
-79.4028
-58.3935
-44.3850
-34.3793
¦26.8762
-21.0418
-16.3757
-12.5592
-9.3799
-6.6908
-4.3867
-2.3905
-.6445
.8956
2.2641
3.4882
4.5897
5.5861
6.4917
7.3186
8.0765
8.7737
9.4174
10.0135
10.5670
11.0826
11.5638
12.0142
12.4365
12.8334
13.2072
13.5597
13.8928
14.2081
14.5070
14.7906
15.0603
15.3170
15.5616
15.7950
16.0179
16.2311
16.4352
16.6307
16.8182
16.9981
17.1711
17.3373
17.4973
17.6513
17.7998
17.9429
18.0811
18.2145
18.3434
18.4680
18.5886
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1206
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 383
Т i
л ¦ -
§ пЗ ^
1 1 §
X °- ~
*>. « " 5
О"- ^ Q _
? 7 й -
" ^ 5 °'
* и _,
о ^,
< "V
+
-
н
ON _
С") ¦
+ о
н —*
\О , О
°
=> \ v
! m i~.
* «о V
Tt 4- О
2 гч ""
S 2 !о
. ? 1 К.
П ? II
и +
о
172

Класс точности
V-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
,4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
33.494
37.332
44.074
44.212
51.583
58.204
63.883
68.777
73.053
76.815
80.130
83.047
85.610
87.859
. 89.832
91.563
93.084
94.424
95.607
96.653
97.582
98.409
99.147
99.808
100.401
100.936
101.419
101.856
102.253
102.614
102.944
103.245
103.522
103.776
104.010
104.226
104.425
104.610
104.781
104.940
105.088
105.226
105.355
105.476
105.588
105.694
105.793
105.887
105.974
106.057
106.135
106.209
106.278
106.344
106.406
106.465
106.521
106.574
106.625
106.673
106.719
Ф°(П
Дж • К ¦ моль
180.264
203.525
217.524
217.749
228.584
237.674
245.677
252.916
259.576
265.770
271.580
277.063
282.261
287.209
291.933
296.455
300.793
304.963
308.979
312.851
316.591
320.206
323.707
327.099
330.389
333.583
336.687
339.705
342.643
345.504
348.292
351.011
353.664
356.254
358.785
361.258
363.677
366.043
368.359
370.627
372.849
375.027
377.162
379.256
381.311
383.328
385.308
387.252
389.163
391.041
392.887
394.702
396.487
398.244
399.972
401.674
403.350
405.000
406.625
408.227
409.805
ИОДМЕТАН СН31 (г)
О-,(.>¦,-'(
5°(Г)
213.552
237.685
253.796
254.070
267.807
280.047
291.174
301.398
310.867
319.693
327.962
335.739
343.077
350.020
356.605
362.863
368.822
374.507
379.938
385.136
390.117
394.899
399.494
403.916
408.177
412.286
416.255
420.091
1ЛЛ ЛЛ Л
423.802
427.397
430.881
434.262
437.544
440.734
443.835
446.853
449.792
452.656
455.448
458.172
460.831
463.427
465.964
468.445
470.871
473.245
475.569
477.845
480.076
482.262
484.405
486.508
488.570
490.596
492.584
494.537
496.456
498.342
500.196
502.019
503.812
:нэ1) Д^я0
Я°(Л-Я°@)
кДж • моль
3.329
6.832
10.815
10.896
15.689
21.187
27.298
33.937
41.033
48.531
56.381
64.543
72.979
81.655
90.541
99.613
108.847
118.224
127.727
137.341
147.053
156.854
166.732
176.680
186.691
196.759
206.877
217.041
227.247
237.490
247.768
258.078
268:416
278.782
289.171
299.583
310.016
320.468
330.937
341.423
351.925
362.441
372.970
383.511
394.065
404.629
415.203
425.787
436.380
446.982
457.592
468.209
478.833
489.464
500.102
510.745
521.395
532.049
542.709
553.374
564.044
@)= 1442.515
о
-738.7800
-359.4074
-233.9205
-232.3398
-168.5390
-130.1194
i 04.4255
-86.0225
-72.1871
-61.4037
-52.7612
-45.6786
-39.7682
-34.7609
-30.4643
-26.7370
-23.4729
-20.5906
-18.0269
-15.7318
-13.6650
-11.7942
-10.0928
-8.5387
-7.1137
-5.8022
-4.5913
-3.4697
О Л ООП
•J.42oi)
-1.4579
-.5522
.2951
1.0897
1.8363
2.539!
3.2018
3.8279
4.4202
4.9814
5.5139
6.0199
6.5013
6,9598
7.3971
7.8145
8.2134
8.5951
8.9606
9.3108
9.6469
9.9695
10.2795
10.5776
10.8645
11.1408
11.4071
11.6640
11.9118
12.1511
12.3823
12.6059
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
T а б л и
-1
i
л
с;
о
.
О^ го
¦* II
II О
5; с
X
в
0
<
I Y
? I
+ "L
+ нЬ
С* *
г- Щ.
2 ***
ON X
00 t<
g Я
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ца384
i
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II
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Я
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173

Класс точности
VI-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сг)
К°(Т) = р (С)
Ф°(Г)
ДИИОДМЕТАН СН212 (г)
•р2(Н)-р2A)-р"
5°(Г)
Дж • К .моль
40.266
48.287
57.721
57.891
66.095
72.394
77.216
81.053
84.228
86.927
89.251
91.268
93.021
94.550
95.884
97.052
98.075
98.974
99.766
100.467
101.088
101.641
102.133
102.575
102.971
103.327
103.649
103.940
104.205
104.446
104.665
104.866
105.050
105.220
105.375
105.519
105.652
105.774
105.888
105.994
106.093
106.185
106.270
106.351
106.426
106.496
106.562
106.624
106.682
106.737
106.789
106.838
106.884
106.928
106.970
107.009
107.046
107.082
107.115
107.147
107.178
222.219
248.602
265.421
265.696
279.107
290.469
300.463
309.444
317.630
325.168
332.165
338.703
344.842
350.634
356.118
361.328
366.292
371.032
375.568
379.920
384.100
388.124
392.001
395.743
399.360
402.858
406.247
409.532
412.720
415.816
418.827
421.755
424.606
427.384
430.092
432.735
435.314
437.832
440.294
442.701
445.056
447.360
449.616
451.826
453.992
456.116
458.198
460.241
462.247
464.216
466.149
468.049
469.916
471.751
473.556
475.331
477.077
478.796
480.488
482.153
483.794
258.646
288.785
309.838
310.196
328.020
343.478
357.121
369.323
380.359
390.440
399.722
408.325
416.343
423.851
430.908
437.564
443.860
449.834
455.514
460.927
466.097
471.042
475.782
480.332
484.706
488.917
492.976
496.893
500.678
504.339
507.884
511.319
514.651
517.887
521.030
524.087
527.061
529.958
532.780
535.532
538.217
540.838
543.397
545.899
548.345
560.737
553.079
555,371
557.616
559.817
561.974
564.089
566.164
568.200
570.199
572.163
574.091
575.986
577.848
579.680
581.481
(CH2I2) ArJh
И°(Т)-Н°@)
кДж . моль"
3.643
8.037
13.243
13.350
19.565
26.504
33.995
41.915
50.184
58.745
67.557
76.585
85.801
95.182
104.705
114.353
124.110
133.964
143.902
153.914
163.992
174.129
184.318
194.554
204.832
215.147
225.496
235.876
256.716
267.172
277.648
288.144
298.658
309.188
319.733
330.291
340.862
351.446
362.040
372.644
383.258
393.881
404.512
415.151
425.797
436.450
447.П0
457.775
466.448
479.122
489.804
500.490
511.180
521.875
532.574
543.277
553.983
564.693
575.406
586.122
Г°@)= 1227.
о
-625.0040
-302.0530
-195.2331
-193.8878
-139.5980
-106.9228
-85.0835
-69.4504
-57.7040
-48.5535
-41.2231
-35.2185
-30.2097
-25.9677
-22.3289
-19.1733
-16.4106
-13.9717
'11.8028
-9.8614
-8.1136
-6.5317
-5.0932
-3.7794
-2.5748
-1.4664
-.4429
.5050
1 .«JW54
2.2053
2.9706
3.6868
4.3583
4.9893
5.5833
6.1435
6.6728
7.1735
7.6480
8.0982
8.5261
8.9332
S.3210
9.6909
10.0440
10.3815
10.7044
11.0137
11.3102
11.5946
11.8677
12.1302
12.3827
12.6256
12.8597
13.0853
13.3029
13.5128
13.7157
13.9116
14.1011
108 кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
JrtSvV
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табли
-1
00
v>
г*ч
00
t-^
<s
II
§J
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<-)
+
•3-
¦?
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о
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S
о
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об
+
s>
со
оо
II
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0
в
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§
с~
о
X
о
о""
<
_
1
о
2
1
¦
m
Ч
+
г*
о
[^
1
X
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со
On
+
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л
1
о
о
II
Я
00
ON
"?)
X
у,
о
ца 385
¦
§
S
k
00
ON
II
S
о
о
V
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V
о
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чг
О
II
174

Класс точности
VI-F
ТРИИОДМЕТАН СН13 (г)
Таблица 386
К°(Г)= p(Q-p(H)-p3(i)-p~\cm3) ДгЯ°@)= 1020.743 кДж-моль
Т
К
С°р(Т)
100 53.319
200 65.459
298.15 74.816
300 74.966
400 81.796
500 86.568
600 89.982
700 92.551
800 94.578
900 96.237
1000 97.625
1100 98.803
1200 99.812
1300 100.679
1400 101.430
1500 102.081
1600 102.649
1700 103.145
1800 103.581
1900 103.966
2000 104.305
2100 104.607
2200 104.875
2300 105.115
2400 105.330
2500 105.524
2600 105.698
2700 105.856
2800 105.999
2900 106.129
3000 106.248
3100 106.356
3200 106.455
3300 106.547
3400 106.631
3500 106.708
3600 106.779
3700 106.846
3800 106.907
3900 106.964
4000 107.017
4100 107.066
4200 107.112
4300 107.156
4400 107.196
4500 107.234
4600 107.269
4700 107.303
4800 107.334
4900 107.363
5000 107.391
5100 107.418
5200 107.442
5300 107.466
5400 107.488
5500 107.509
5600 107.529
5700 107.548
5800 107.566
5900 107.583
6000 107.600
Ф°(Т)
Дж • К~ . моль
244.174
276.436
298.042
298.398
315.688
330.175
342.729
353.845
363.839
372.928
381.271
388.985
396.162
402.876
409.184
415.135
420.768
426.115
431.205
436.063
440.708
445,160
449.433
453.542
' 457.499
461.315
465.000
468.563
472.01 Г
475.352
478.592
481.738
484.794
487.766
490.657
493.474
496.218
498.894
501.506
504.056
506.546
508.981
511.362
513.691
515.971
518.204
520.392
522.536
524.638
526.701
528.724
530.710
532.661
534.577
536.459
538.309
540.128
541.917
543.677
545.408
547.112
5°(Г)
1
286.640
327.468
355.439
355.903
378.463
397.259
413.360
427.432
439.928
451.166
461.380
470.741
479.383
487.407
494.896
501.917
508.523
514.762
520.670
526.281
531.622
536.719
541.592
546.259
550.737
555.041
559.183
563.175
^ f* *9 Л А Л
567.028
570.749
574.349
577.835
581.213
584.490
587.672
590.765
593.772
596.698
599.548
602.326
605.035
607.678
610.258
612.780
615.243
617.653
620.010
622.318
624.577
626.790
628.960
631.087
633.172
635.219
637.228
639.201
641.138
643.042
644.912
646.751
648.56Р
Я°G>-Я°@)
кДж • моль
4.247
10.206
17.113
17.251
25.110
33.542
42.378
51.511
60.871
70.414
80.109
89.932
99.864
109.890
119.996
130.172
140.409
150.700
161.037
171.414
181.828
192.274
202.748
213.248
223.771
234.313
244.875
255.452
266.045
276.652
287.271
297.901
308.541
319.192
329.851
340.517
351.192
361.873
372.561
383.255
393.954
404.658
415.367
426.080
436.798 .
447.519
458.244
468.973
479.705
490.440
501.177
511.918
522.661
533.406
544.154
554.904
565.656
576.410
587.165
597.923
608.682
T
К
-514.9078 100
-246.1597 200
-157.3325 298.15
-156.2143 300
-111.1097 400
-83.9873 500
-65.8748 600
-52.9197 700
-43.1926 800
-35.6202 900
-29.5578 1000
-24.5946 1100
-20.4566 1200
-16.9537 1300
-13.9502 1400
-11.3465 1500
-9.0678 1600
-7.0567 1700
-5.2689 1800
-3.6690 1900
-2.2288 2000
-.9257 2100
.2591 2200
1.3410 2300
2.3330 2400
3.2457 2500
4.0883 2600
4.8687 2700
5.5935 2800
6.2685 2900
6.8986 3000
7.4882 3100
8.0411 3200
8.5607 3300'
9.0498 3400
9.5112 3500
9.9470 3600
10.3595 3700
10.7504 3800
11.1214 3900
11.4739 4000
11.8094 4100
12.1291 4200
12.4340 4300
12.7252 4400
13.0035 4500
13.2699 4600
13.5250 4700
13.7696 4800
14.0044 4900
14.2298 5000
14.4465 5100
14.6549 5200
14.8556 5300
15.0489 5400
15.2353 5500
15.4151 5600
15.5887 5700
15.7563 5800
15.9184 5900
16.0751 6000
j
i
о Й "л
2 3 о
к <=> s
Д- О *
9 я 7
о ^
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™ ° ? «
^ и- гм ' •
п «-* "
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7
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+ 7
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175

Класс точности
VI-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<п
41.979
58.809
70.992
71.191
80.486
87.230
92.036
95.477
97.980
99.837
101.243
102.328
103.181
103.861
104.411
104.862
105.236
105.549
105.814
106.040
106.234
106.402
106.549
106.677
106.790
106.890
106.978
107.058
107.129
107.193
107.251
107.303
107.351
107.395
107.434
107.471
107.504
107.535
107.564
107.590
107.614
107.637
107.658
107.678
107.696
107.713
107.729
107.744
107.758
107.771
107.784
107.796
107.807
107.817
107.827
107.836
107.845
107.854
107.862
107.869
107.876
*°(Г)=Р(С)-Р3
Ф°(Г)
Дж • К • моль
211.805
238.667
257.273
257.585
273.018
286.317
298.099
308.710
318.377
327.258
335.474
343.118
350.264
356.972
363.294
369.270
374.936
¦ 380.322
385.456
390.358
395.050
399.547
403.866
408.021
412.022
415.881
419.608
423.211
426.699
430.078
433.355
436.536
439.626
442.631
445.554
448.401
451.175
453.880
456.518
459.095
461.611
464.070
466.475
468.827
471.130
473.384
475.593
477.757
479.879
481.960
484.002
486.006
487.974
489.906
491.805
493:670
495.504
497.308
499.082
500.828
502.546
ТРИФТОРИОДМЕТАН CF3I
_
S°{T)
1
247.236
281.804
307.667
308.106
329.927
348.653
365.007
379.467
392.388
404.041
414.636
424.339
433.280
441.567
449.285
456.504
463.284
469.674
475.715
481.442
486.886
492.073
497.027
501.766
506.308
510.670
514.864
518.903
522.798
526.558
530.193
533.711
537.118
540.422
543.629
546.744
549.772
552.717
555.586
558.380
561.104
563.762
566.356
568.889
571.365
573.786
576.153
578.470
580.739
582.961
585.138
587.273
589.366
591.419
593.435
595.413
597.357
599.266
601.141
602.985
604.798
(г)
CF3I) Дг#°@)= 1633.513
H°(T)-H°@)
кДж • моль
3.543
8.627
15.025
15.156
22.764
31.168
40.145
49.530
59.209
69.105
79.162
89.343
99.620
109.973
120.387
130.852
141.357
151.897
162.466
173.059
183.672
194.304
204.952
215.614
226.287
236.971
247.665
258.366
269.076
279.792
290.514
301.242
311.975
322.712
333.454
344.199
354.948
365.700
376.455
387.212
397.973
408.735
419.500
430.267
441.035
451.806
462.578
473.352
484.127
494.903
505.681
516.460
527.240
538.021
548.804
559.587
570.371
581.156
591.942
602.728
613.515
-833.5494
-404.4491
-262.7270
-260.9435
-189.0157
-145.7824
-116.9232
-96.2905
-80.8054
-68.7556
-59.1123
-51.2203
-44.6425
-39.0760
-34.3045
-30.1690
-26.5505
-23.3578
-20.5199
-17.9809
-15.6960
-13.6288
-11.7496
-10.0341
-8.4616
-7.0150
-5.6798
-4.4436
-3.2957
-2.2271
-1.2298
-.2969
.5777
1.3992
2.1724
2.9014
3.5898
4.2410
4.8580
5.4433
5.9993
6.5282
7.0319
7.5122
7.9706
8.4087
8.8277
9.2289
9.6134
9.9822
10.3363
10.6765
11.0036
11.3184
11.6215
11.9136
12.1952
12.4670
12.7295
12.9830
13.2281
кДж . моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2Э00
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
i
к
о
•
о
с— ^
2 00
от т
II О
ft
BY
У-
+
г-
r- T
<"¦ 1
+ *
т т
>3458
1 Дж-
<=> н
° 3
¦з +
от «
00 ^
• 'О
о 2
+ !
г- m
13.25
5.047
ОТ -н
и +
о
-
1
•
§
<Ч
00
|
II
Я
00
(Ч
—"
В.
387
'л
§
S
„"
i
•
1
00
f;
ГО
с g
Я
О
о
о
чо
V
V
8
?
«—<
¦ 176

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1H0
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Л
г
52.112
69.899
80.473
80.639
88.146
93.318
96.875
99.361
101.139
102.444
103.422
104.173
104.759
105.225
105.601
105.909
106.163
106.376
106.556
106.709
106.840
106.953
107.052
107.139
107.215
107.282
107.342
107.396
107.444
107.487
107.526
107.561
107.593
107.622
107.649
107.674
107.696
107.717
107.736
107.754
107.770
107.785
107.799
107.813
107.825
107.836
107.847
107.857
107.867
107.875
107.884
107.892
107.899
107.906
107.913
107.919
107.925
107.931
107.936
107.941
107.946
ДИФТОРДИИОДМЕТАН CF2I2
Ф°G")
Дж -К . моль
234.199
265.428
287.358
287.723
305.654
320.844
334.093
345.870
356.480
366.141
375.009
383.206
390.828
397.949
404.631
410.926
416.875
422.515
427.876
432.985
437.863
442.532
447.008
451.306
455.440
459.422
463.262
466.972
470.558
474.030
477.393
480.655
483.822
486.899
489.891
492.802
495.637
498.399
501.093
503.722
506.288
508.794
511.244
513.640
515.983
518.277
520.523
522.724
524.881
526.995
529.069
531.104
533.102
535.063
536.989
538.882
540.742
542.570
544.369
546.137
547.878
S°(T)
274 .1 10
316.396
346.402
346.900
371.192
391.453
408.801
423.932
437.3-23
449.314
460.161
470.055
479.145
487.549
495.362
502.658
509.502
515.944
522.030
527.796
533.272
538.488
543.466
548.226
552.788
557.166
561.375
565.427
569.333
573.105
576.749
580.276
583.691
587.002
590.216
593.336
596.370
599.321
602.194
604.993
607.721
610.382
612.980
615.516
617.995
620.418
622.789
625.108
627.379
629.603
631.783
633.919
636.014
638.070
640.087
642.067
644.011
645.922
647.799
649.644
651.458
¦\CF2l2) ArH
Я°(Г>-Я°@)
кДж • моль
3.991
10.194
17.604
17.753
26.215
35.305
44.825
54.644
64.674
74.856
85.152
95.533
105.981
116.481
127.023
137.599
148.203
158.830
169.477
180.140
190.818
201.508
212.208
222.918
233.636
244.360
255.092
265.828
276.571
287.317
298.068
308.822
319.580
330.341
341.104
351.871
362.639
373.410
384.182
394.957
405.733
416.511
427.290
438.071
448.852
459.636
470.420
481.205
491.991
502.778
513.566
524.355
535.144
545.935
556.726
567.517
578.309
589.102
599.896
610.690
621.484
(г)
D@) = 1334.594 кДж • моль
lg АГ°(Г)
-677.3454
-326.5530
-210.7224
-209.2651
-150.4970
-1 15.1844
-91.6188
¦74.7746
-62.1355
-52.3019
-44.4335
-37.9950
-32.6293
-28.0891
-24.1977
-20.8253
-17.8748
-15.2716
-12.9579
-10.8880
-9.0253
-7.3402
-5.8084
-4.4099
-3.1281
-1.9489
-.8604
.1473
1.0831
1.9543
2.7674
3.5281
4.2413
4.9112
5.5418
6.1364
6.6980
7.2293
7.7327
8.2103
8.6640
. 9.0957
9.5069
9.8990
10.2734
10.6311
10.9734
11.3011
11.6152
11.9166
12.2059
12.4839
12.7513
13.0087
13.2565
13.4954
13.7258
13.9481
14.1629
14.3703
14.5709
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
N00
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1 а о л и
ОО
2
го
11
+
1
4
ГА
00
+
1
X
ГА
гч
1О
.-ч
о
о
1
м
СО
о
+
5>
II
/—
о
¦©
i
к
о
1 2
§ а
S о
3 §
* S
. !
Ю "
II in
?" оо'
. On
Ц. J?
_w О
0 ^/
7
s
о
i
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о
+
Is
OS
1
C1
ЧО
IT)
Hi
Ц a 388
V
О
1
.
C-}
00
?
II
о в?
to
?
о
о
о
V
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V
о
о
«о
¦""
о
II
177

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
Р
60.879
78.841
88.313
88.451
94.424
98.258
100.774
102.477
103.667
104.525
105.160
105.642
106.016
106.31 1
106.548
106.741
106.900
107.033
107.145
107.240
107.321
107.391
107.452
107.506
107.553
107.594
107.631
107.664
107.693
107.720
107.744
107.766
107.785
107.803
107.820
107.835
107.848
107.861
107.873
107.884
107.894
107.903
107.912
107.920
107.927
107.934
107.941
107.947
107.953
107.958
107.963
107.968
107.973
107.977
107.981
107.985
107.988
107.992
107.995
107.998
108.001
ФТОРТРИИОДМЕТАН CF13
*-<7-)-Р<С).,(Р
Ф°(Т)
Дж • К . моль
246.357
281.772
306.597
307.009
327.078
343.872
358.359
371.1 14
382.515
392.825
402.237
410.895
418.912
426.375
433.357
439.915
446.099
451.949
457.498
462.777
467.81 1
472.620
477.225
481.642
485.886
489.969
493.904
497.701
501.369
504.917
508.352
51 1.681
514.911
518.047
521.095
524.060
526.944
529.755
532.494
535.165
537.772
540.318
542.805
545.236
547.614
549.940
552.218
554.448
556.634
558 776
560.876
562.937
564.959
566.944
568.892
570.807
572.688
574.537
576.355
578.143
579.902
>.р>(П.р-'(
S°(T)
291.192
339.687
373.089
373.636
399.964
421.477
439.630
455.300
469.066
481.328
492.376
502.422
511.631
520.129
528.016
535.374
542.268
548.753
554.874
560.670
566.173
571.411
576.408
581.185
585.762
590.153
594.374
598.437
602.353
606.132
609.785
613.318
616.740
620.057
623.275
626.401
629.439
632.394
635.270
638.073
640.804
643.468
646.069
648.608
651.089
653.515
655.887
658.208
660.481
662.707
664.888
667.026
669.123
671.180
673.198
675.179
677.125
679.036
680.915
682.761
684.576
(Г)
СП3) Д/.Я°@)= 1059.516
Н°(Т)-Н°(О)
кДж . моль
4.484
1 1.583
19.825
19.988
29.154
38.802
48.762
58.930
69.241
79.653
90.138
100.680
1 1 1.263
121.880
132.524
143.188
153.871
164.568
175.276
185.996
196.724
207.460
218.202
228.950
239.703
250.460
261.221
271.986
282.754
293.525
304.298
315.073
325.85 1
336.631
347.412
358.194
368.978
379.764
390.551
401.339
4 12.127
422.917
433.708
444.499
455.292
466.085
476.879
487.673
498.468
509.264
520.060
530.856
541.653
552.451
563.249
574.047
584.846
595.644
606.444
617.244
628.044
-533.0600
-254.3392
¦162.3283
-161.1709
-1 14.5059
-8'6.4764
-67.7773
-54.4154
¦44.3917
-36.5948
-30.3573
-25.2542
-21.0020
-17.4046
-14.3217
1 1.6503
-9.3133
-7.2516
-5.4193
-3.7802
-2.3053
-.9710
.2418
1.3491
2 3641
3.2977
4.1596
4.9576
5.6987
6.3887
7.0328
7.6353
8.2003
8.7312
9.2309
9.7022
10.1474
10.5686
10.9678
1 1.3466
1 1.7065
12.0490
12.3753
12.6866
12.9838
13.2678
13.5397
13.8000
14.0496
14.2891
14.5191
14.7402
14.9528
15.1575
15.3547
15.5448
15.7282
15.9052
16.0762
16.2414
16.4012
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
-
?•
2
rv с"}
~ л
11 с
¦^ и"
ЕГ.
0
а;
+
1
г-
+
1
О
:?
о
о
1
с
\О
m ,
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чс
о
¦—'
0
^\
б л и и а 389
—
С
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in *
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о
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1
Л
О
. О1
? ?
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ее t--.
Ч V
t с
1 К,
<п
+
J78

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
t
36.882
42.491
50.300
50.455
58.614
65.692
71.499
76.262
80.226
83.572
86.419
88.858
90.953
92.760
94.323
95.680
96.861
97.894
98.799
99.596
100.300
100.924
101.4*0
101.976
109.420
102.819
103.179
103.504
103.799
104.067
104.312
104.535
104.739
104.927
105.100
105.259
105.406
105.542
105.668
105.785
105.894
105.995
106.090
106. i 78
106.261
106.339
106.411
106.480
106.544
106.605
106.662
106.716
106.766
106.815
106.860
106.903
106.944
106.983
107.020
107.055
107.089
К°(Т) = р(С)-р
Ф°(Г)
Дж • К . моль
205.842
230.656
246.016
246.265
258.317
268.488
277.463
285.579
293.028
299.938
306.395
312.465
318.196
323.629
328.796
333.724
338.434
342.946
347.277
351.441
355.451
359.318
363.052
366.662
370.155
373.540
376.823
380.010
383.106
386.1 16
389.045
391.898
394.677
397.388
400.032
402.614
405.135
407.600
410.010
412.368
414.675
416.935
419.148
421.318
423.445
425.531
427.577
429.586
431.559
433.496
435.399
437.269
439.108
440.916
442.694
444.444
446.166
447.861
449.530
451.173
452.792
ФТОРИОДМЕТАН CH2F1 (г)
S°{T)
-1
240.700
267.775
286.157
286.469
302.1 18
315.982
328.490
339.881
350.331
359.979
368.935
377.289
385.113
392.466
399.399
405.954
412.167
418.072
423.693
429.057
434.184
439.092
443.801
448.323
452.672
456.861
460.901
464.801
468.571
472.218
475.751
479.175
482.497-
485.723
488.858
491.907
494.874
497.764
500.580
503.326
506.006
508.622
511.177
513.675
516.117
518.506
520.844
523.133
525.375
527.573
529.727
531.840
533.912
535.947
537.944
539.905
541.832
543.725
545.586
547.416
549.215
"'(CHjFI)
Дг#°@)= 1484.
'@)
кДж • моль
3.486
7.424
1 1.968
12.061
17.520
23.747
30.616
38.012
45.842
54.036
62.540
71.307
80.300
89.488
98.844
108.345
1 17.974
127.713
137.548
147.469
157.464
167.526
177.647
187.820
198.040
208.303
218.603
228.937
239.303
249.696
260.115
270.558
281.022
291.505
302.007
312.525
323.058
333.606
344.166
354.739
365.323
375.917
386.522
397.135
407.757
418.387
429.025
439.669
450.320
460.978
471.641
482.310
492.984
503.663
514.347
525.035
535.728
546.424
557.124
567.828
578.535
lgAT°(r)
-759.6390
-369.4677
-240.4558
-238.8310
-173.2645
-133.7995
-107.4194
•88.5344
-74.3438
-63.2887
-54.4325
-47.1779
¦41.1262
¦36.0010
-31.6047
-27.7921
-24.4541
-21.5074
-18.8870
¦16.5415
-14.4299
-12.5188
-10.7810
-9.1940
-7.7389
-6.4000
-5.1638
-4.0191
-2.9559
-1.9659
-1.0418
-.1773
.6334
1.3950
2.1 119
2.7879
3.4264
4.0304
4.6027
5.1458
5.6617
6.1525
6.6200
7.0658
7.4913
7.8980
8.2871
8.6596
9.0166
9.3591
9.6880
10.0039
10.3077
10.6001
10.8817
11.1531
11.4148
! 1.6673
11.9112
12.1468
12.3746
131 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400.
5500
5600
5700
5800
5900
6000
Т а б л и
i
л
о
S
%
I— чс
'О
X
и
о
<!
+
¦2 'л
2 ~
** о
<n —'
1
2 |
5 оо
О гч
О ос
j. +
— "ч
¦? Ч
+ *
О <^1
гЗ °
5 —
II +
о
i
А
О
f
^
О
о
о
—
ОС
(^-
F
0
ч
<J
ц a 390
i
Л
с:
о
i
13 Дж
НС
р-
ГЧ
II
О R
со
Я
О
ЧО
V
V
о
о
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о
I—"
II
179

Класс точности
VI-1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
4 1.1 25
52.671
60.962
61.115
69.049
75.750
81.058
85.223
88.530
91.200
93.387
95.200
96.718
97.999
99.088
100.019
100.821"
101.515
102.118
102.646
103.109
103.518
103.880
104.202
104.490
104.748
104.979
105.188
105.377
105.549
105.705
105.847
105.977
106.097
106.206
106.307
106.401
106.487
106.566
106.641
106.709
106.773
106.833
106.889
106.941
106.990
107.036
107.079
107.120
107.158
107.194
107.228
107.260
107.290
107.319
107.346
107.372
107.396
107.419
107.441
107.462
ДИФТОРИОДМЕТАН CHF2
К°(Т) = р (С)-р (И)-р2(П-р (I) -р~'
Ф°(Г)
— 1 -
Дж • К . моль
215.453
241.81 1
259.311
259.599
273.641
285.535
295.996
305.40!
313.979
321.882
329.219
336.072
342.504
348.568
354.304
359.747
364.927
369.868
374.592
379.118
383.461
387.636
391.656
395.532
399.273
402.890
406.389
409.779
413.065
416.255
419.354
422.366
425.297
428.150
430.931
433.641
436.286
438.867
441.388
443.852
446.261
448.618
450.924
453.182
455.394
457.562
459.688
461.772
463.817
465.824
467.794
469.730
471.631
473.499
475.336
477.142
478.919
480.666
482.386
484.079
485.746
S°(T)
1
250.743
283.200
305.790
306.167
324.857
341.012
355.312
368.132
379.736
390.323
- 400.049
409.037
417.388
425.181
432.484
439.353
445.835
451.968
457.788
463.324
468.601
473.642
478.466
483.091
487.532
491.803
495.916
499.881
503.710
507.41 1
510.992
514.461
517.823
521.086
524.255
527.335
530.332
533.248
536.089
538.858
541.559
544.194
546.768
549.283
551.740
554.144
556.496
558.799
561.054
563.263
565.428
567.551
569.633
571.677
573.683
575.652
577.587
579.487
581.355
583.192
584.997
(CH1-2I) &rHc
Я°(Г)-Я°@)
кДж . моль
3.529
8.278 .
13.858
13.971
20.486
27.738
35.590
43.912
52.606
61.597
70.830
80.262
89.860
99.597
109.453
119.410
129.453
139.570
149.753
159.991
170.280
180.61 1
190.982
201.386
21.1.821
222.283
232.770
243.278
253.807
264.353
274.916
285.493
296.085
306.688
317.304
327.929
338.565
349.209
359.862
370.522
381.190
391.864
402.545
413.231
423.922
434.619
445.320
456.026
•466.736
477.450
488.167
498.889
509.613
520.340
531.071
541.804
552.540
563.278
574.019
584.762
595.507
I (г)
@)= 1547.083
о
-790.8088
-384.2661
-249.9352
-248.2442
-180.0237
-138.9894-
-11 1.5785
-91.9677
-77.2404
-65.7735
-56.5919
-49.0742
-42.8056
-37.4987
-32.9480
-29.0027
-25.5496
-22.5020
¦19.7924
-17.3677
-15.1852
-13.2103
-11.4148
-9.7753
-8.2723
-6.8894
-5.6129
-4.4308
-3.3332
¦2.3112
-1.3573
-.4649
.3717
1.1577
1.8974
2.5949
3.2537
3.8769
4.4674
5.0276
5.5598
6.0660
6.5482
7.0080
7.4469
7.8663
8.2675
8.6516
9.0198
9.3729
9.7120
10.0377
10.3510
10.E524
10.9427
11.2225
11.4923
11.7526
12.0040
12.2469
12.4816
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
-
'л
6
V
гч СО
о <п
СЧ ^
Г— ||
— <~N
II Я.
!§ и-
?
у
0
+ V
1 *
° и
ГЧ 00
О с*1
о ¦":
к +
5 „
2 о?
3 °
00 ^
00 ">
"t" I
^о н
о> °°.
? S
II +
о
i
о
о
о
о
m
1
!1
ОО
1_г
U-
X
О
о
ч
<1
ц а 391
л
К
о
1—Г
R.
г»
г-
г^*
го
II
о 5
со
я
о
о
V
V
о
«л
"о
ь.
II
180

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<п
43.708
55.345
67.212
67.408
76.349
82.562
86.944
90.169
92.656
94.646
96.283
97.653
98.812
99.803
100.654
101.390
102.029
102.587
103.075
103.505
103.884
104.221
104.520
104.787
105.027
105.242
105.436
105.611
105.770
105.915
106.047
106.167
106.277
106.379
106.472
106.558
106.637
106.710
106.779
106.842
106.901
106.955
107.007
107.054
107.099
107.141
107.180
107.217
107.252
107.285
107.316
107.345
107.372
107.398
107.423
107.447
107.469
107.490
107.510
107.529
107.547
ФТОРДИИОДМЕТАН CHFI
*V)= p(C)-p(H)
Ф°G)
Дж • К . моль
236.520
264.598
283.109
283.416
298.476
. 311.342
322.680
332.853
342.096
350.574
358.410
365.697
372.511
378.910
384.943
390.652
396.070
401.226
406.144
410.847
415.351
419.674
423.829
427.830
431.687
435.411
439.011
442.494
445.867
449.139
452.314
455.398
458.397
461.315
464.155
466.923
469.622
472.255
474.825
477.335
479.789
482.188
484.535
486.832
489.081
491.284
493.443
495.560
497.636
499.673
501.673
503.636
505.564
507.458
509.320
511.150
512.950
51-4.720
516.462
518.176
519.863
S°(T)
274.620
308.219
332.612
333.029
353.721
371.468
386.930
400.586
412.795
423.827
433.887
443.130
451.678
459.627
467.055
474.025
480.589
486.792
492.670
4S8.255
503.574
508.651
513.506
518.158
522.623
526.915
531.046
535.029
538.872
542.587
546.180
549.659
553.031
556.303
559.480
562.568
565.571
568.494
571.340
574.115
576.820
579.461
582.039
584.557
587.019
589.426
591.782
594.087
596.345
598.557
600.724
602.850
604.934
606.980
608.988
610.959
612.895
614.798
616.667
618.505
620.312
"'(CHFI,) Д
т
Я°(Г)-Я°@)
кДж • моль
3.810
8.724
14.759
14.884
22.098
30.063
38.550
47.413
56.559
65.928
75.477
85.176
95.000
104.932
114.956
125.059
135.231
145.463
155.746
166.076
176.445
186.851
197.288
207.754
218.245
228.758
239.292
249.845
260.414
270.998
281.597
292.207
302.829
313.463
324.105
334.756
345.416
356.084
366.758
377.439
388.126
398.819
409.517
420.221
430.928
441.640
452.356
463.076
473.800
484.527
495.257
505.990
516.725
527.464
538.205
548.949
559.695
570.443
581.192
591.944
602.698
2 (Г)
Я°@) = 1275.686 кДж • моль"
о
-648.9114
-313.3501
-202.4240
-201.0275
-144.6915
-110.8111
-88.1837
-71.9985
-59.8458
-50.3849
-42.8105
-36.6093
-31.4389
-27.0621
-23.3093
-20.0559
-17.2085
-14.6955
-12.4615
-10.4623
-8.6628
-7.0345
-5.5541
-4.2023
-2.9630
-1.8228
-.7702
.2045
1.1097
1.9526
2.7394
3.4755
4.1656
4.8141
5.4244
6.0000
6.5437
7.058!
7.5455
8.0080
8.4475
8.8655
9.2638
9.6436
10.0062
10.3528
10.6843
11.0018
11.3062
11.5982
11.8785
12.1480
12.4071
12.6565
12.8967
13.1282
13.3515
13.5670
13.7751
13.9762
14.1706
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб л и
-1
§
1 к
X
« 1
S ^°
С> ¦ и
N «1 Q,
<Х и *2
00 ¦ .
гч ?¦ оо
" и Я
я Е
В я
°а; о""
00 7
Я -»
2 §
Ч 2
+ т
1
J . .
н „
^ сз
оо ^
О\ m
О »о
о °1
1 ?
J3 +
m "я
•о *
>2 -1.
+ 1
§ а
5 **'
II +
0
ца 392
т
I
о
о
^!
к
о 5
to
g
о
о
VO
V
V
о
о
»'"
'о
II
181

Класс точности
VI- F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(л
52.204
74.292
86.499
86.673
93.898
98.194
100.868
102.616
103.812
104.660
105.282
105.751
106.113
106.397
106.624
106.809
106.96!
107.088
107.194
107.285
107.362
107.429
107.487
107.537
107.582
107.621
107.656
107.687
107.715
107.740
107.763
107.783
107.802
107.819
107.835
107.849
107.862
107.874
107.885
107.895
107.904
107.913
107.921
107.929
107.936
107.943
107.949
107.955
107.960
107.965
107.970
107.975
107.979
107.983
107.987
107.991
107.994
107.997
108.000
108.003
108.006
К°(Г)=Р(С)-Р
Ф°(Г)
Дж ¦ К~' .моль"
225.615
256.652
279.180
279.560
298.293
314.254
328.182
340.540
351.645
361.728
370.959
. 379.470
387.365
394.726
401.621
408.104
414.223
420.015
425.514
430.747
435.740
440.513
445.084
449.471
453.686
457.744
461.656
465.431
469.079
472.608
476.025
479.339
482.553
485.675
488.709
491.661
494.534
497.333
500.061
502.723
505.320
507.856
510.335
512.757
515.127
517.446
519.716
521.940
524.119
526.254
528.349
530.404
532.420
534.399
536.343
538.252
540.129
541.973
543.787
545.570
547.325
ТРИХЛОРИОДМЕТАН СС1.,
(С1) • р A) ¦ р
S°(T)
1
264.548
308.349
340.500
341.036
367.052
388.506
406.663
422.352
436.138
448.417
459.477
469.535
478.753
487.258
495.151
502.514
509.412
515.901
522.025
527.823
533.328
538.568
543.567
548.346
552.924
557.316
561.538
565.602
569.518
573.299
576.952
580.485
583.908
587.225
590.444
593.570
596.609
599.564
602.441
605.244
607.976
610.640
613.241
615.780
618.261
620.687
623.060
625.381
627.654
629.880
632.062
634.200
636.296
638.353
640.372
642.353
644.299
646.211
648.089
649.935
651.750
(СП3П Д h
Я°(Г)-Я°@)
кДж . моль
3.893
10.339
18.282
18.443
27.503
37.126
47.089
57.269
67.594
78.020
88.518
99.071
109.665
120.291
130.943
141.615
152.303
163.006
173.720
184.444
195.177
205.916
216.662
227.413
238.169
248.930
259.694
270.461
281.231
292.004
302.779
313.556
324.335
335.116
345.899
356.683
367.469
378.256
389.044
399.833
410.622
421.413
432.205
442.998
453.791
464.585
475.380
486.175
496.970
507.767
518.564
529.361
540.159
550.957
561.755
572.554
583.353
594.153
604.952
615.753
626,553
i (Г)
!°@) = 1164.072 кДж • моль"
it,K°(T)
Т
К
-587.8459 100
-281.5995 200
-180.4894 298.15
¦179.2174 300
-127.9319 400
-97.1198 500
-76.5576 600
-61.8589 700
-50.8283 800
-42.2449 900
-35.3757 1000
¦29.7541 1100
-25.0686 1200
-21.1034 1300
-Г.7045 1400
•14.7587 1500
-12.1811 1600
-9.9068 1700
-7.8854 1800
-6.0769 1900
-4.4493 2000
-2.9769 2100
¦1.6385 2200
-.4166 2300
.7034 2400
1.7337 2500
2.6846 2600
3.5650 2700
4.3825 2800
5.1435 2900
5.8538 3000
6.5182 3100
7.1410 3200
7.7260 3300
8.2766 3400
8.7958 3500
9.2860 3600
9.7498 3700
10.1891 3800
10.6059 3900
11.0019 4000
11.3785 4100
11.7373 4200
12.0793 4300
12.4058 4400
12.7178 4500
13.0162 4600
13.3019 4700
13.5757 4800
13.8384 4900
14.0906 5000
14.3329 5100
14.5658 5200
14.7900 5300
15.0059 5400
15.2140 5500
15.4146 5600
15.6082 5700
15.7951 5800
15.9757 5900
16.1503 6000
I
| Таблица 393
-I
'л
„ о
1 2
о ? 1*
s  §
* "Ь О
Ъс О S
А о
Рч о -
* о '^
\О ^Н •**
3 " 2 $
II ° OS o-i
Ч-. t-T *"^ ^
.-Г иГ ||
р. 3 о §
У. О со
О ^,
а; о
S. а;
'к
ON
^ "л
+ о
'н —'
3 'а §
s * 1
о « V
1 <N *-
н 5 V
? _ч' о
о
о' Я S
•* ' **¦ ¦
ОН ||
г- "¦> ¦""
ON °°.
II +
0
182

Класс точности
VI-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
57.329
78.892
89.964
90.118
96.413
100.048
102.267
103.699
104.670
105.355
105.856
106.231
106.520
106.747
106.928
107.075
107.196
107.296
107.381
107.453
107.514
107.567
107.613
107.653
107.688
107.719
107.747
107.771
107.793
107.813
107.831
107.847
107.862
107.876
107.888
107.899
107.909
107.919
107.927
107.936
107.943
107.950
107.956
107.962
107.968
107.973
107.978
107.983
107.987
107.991
107.995
107.999
108.002
108.005
108.008
108.011
108.014
108.016
108.019
108.021
108.023
К°(Т)= р(С)-р
Ф°(П
~ 1 ~
Дж • К • моль
239.810
272.880
296.879
297.282
317.062
333.781
348.277
361.075
372.530
382.897
392.363
401.072
409.135
416.642
423.663
430.257
436.474
442.353
447.930
453.234
458.291
463.122
467.747
472.183
476.444
480.543
484.493
488.304
491.985
495.546
498.992
502.333
505.573
508.719
511.776
514.750
517.644
520.462
523.208
525.887
528.501
531.053
533.547
535.984
538.368
540.700
542.983
545.218
547.409
549.556
551.661
553.725
555.752
557.741
559.694
561.612
563.497
565.350
567.171
568.963
570.724
ДИХЛОРДИИОДМЕТАН СС1
(С1) * р \\)' р
S°(T)
1
280.794
328.144
361.916
362.472
389.346
411.285
429.737
445.617
459.532
471.902
483.029
493.137
502.393
510.928
518.846
526.229
533.143
539.645
545.780
551.588
557.101
562.348
567.353
572.138
576.720
581.117
585.342
589.409
593.329
597.112
600.767
604.303
607.728
611.047
614.268
617.395
620.435
623.392
626.269
629.073
631.806
634.471
637.073
639.613
642.095
644.522
646.895
649.217
651.490
653.717
655.899
658.037
660.135
662.192
664.211
666.193
668.139
670.051
671.929
673.776
675.592
(СС1212) ЛгИ°
Я°(Г)-Я°@)
кДж • моль
4.098
11.053
19.391
19.557
28.913
38.752
48.876
59.180
69.601
80.104
90.666
101.271
111.909
122.573
133.257
143.958
154.671
165.396
176.130
186.872
197.620
208.374
219.133
229.897
240.664
251.434
262.207
272.983
283.762
294.542
305.324
316.108
326.894
337.681
348.469
359.258
370.048
380.840
391.632
402.425
413.219
424.014
434.809
445.605
456.402
467.199
477.996
488.794
499.593
510.392
521.191
531.991
542.791
553.591
564.392
575.193
585.994
596.796
607.597
618.399
629.202
2h (Г)
@)= 1045.715
о
-525.9342
-250.7056
-159.8510
-158.7081
-112.6349
-84.9613
-66.4982
-53.3031
-43.4029
-35.7007
-29.5379
-24.4951
-20.2926
-16.7367
-13.6890
-11.0478
-8.7370
-6.6983
-4.8863
-3.2653
-1!8066
-.4869
.7126
1.8077
2.8115
3.7349
4.5873
5.3764
6.1092
6.7915
7.4282
8.0239
8.5824
9.1071
9.6009
10.0666
10.5065
10.9226
11.3168
11.6909
12.0464
12.3846
12.7067
13.0139
13.3071
13.5874
13.8556
14.1124
14.3585
14.5947
14.8214
15.0393
15.2489
15.4506
15.6449
15.8321
16.0127
16.1870
16.3554
16.5180
16.6753
кДж ¦ моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т аб л и
X
гп
О
О —'
2 "
ГО О
11 С
"^ Г)
0
+
-
'к
чО
2 %
+ §
I
I •
О") V-
00975
Дж.:
о *•»
00
g °5
& о
^ 1^
Г"* Г-
© <"Ч
""* <ч*
+¦ ,
(N >^
f*"l 00
2 ?-
II +
0
в
"л
6
S
й
О
"О
11
ОС
rN
sS
ь
ч>
ца 394
т
л
R
О
1
чо
чО
¦
A
to
§
о
о
ЧО
V
V
о
о
«""
'о
1—1
II
183

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
66.177
82.995
92.537
92.669
98.069
101.180
103.081
104.310
105.143
105.732
106.163
106.486
106.735
106.930
107.087
107.213
107.318
107.404
107.477
107.539
107.592
107.638
107.677
107.712
107.742
107.769
107.793
107.814
1 Л*У О О О
107.833
107.851
107.866
107.880
107.893
107.904
107.915
107.925
107.933
107.942
107.949
107.956
107.963
107.969
107.974
107.979
107.984
107.989
107.993
107.997
108.001
108.004
108.007
108.011
108.014
108.016
108.019
108.021
108.024
108.026
108.028
108.030
108.032
ХЛОРТРИИОДМЕТАН ССН3
К°(Т) = .р(С)р(С
Ф°(П
Дж • К . моль
250.251
288.364
314.802
315.239
336.483
354.167
369.345
382.651
394.497
405.176
• 414.895
423.814
432.054
439.711
446.863
453.571
459.888
465.856
471.513
476.888
482.009
486.899
491.577
496.061
500.367
504.508
508.496
512.343
516.057
519.648
523.124
526.491
529.756
532.926
536.006
539.001
541.914
544.751
547.516
550.212
552.842
555.410
557.918
560.369
562.766
565.111
567.406
569.653
571.855
574.013
576.128
578.203
580.239
582.237
584.199
586.126
588.020
589.880
591.709
593.508
595.277
l)-p\l)-p'
S°(T)
298.691
350.281
385.376
385.949
413.422
435.670
454.299
470.287
484.274
496.694
507.857
517.99f
527.268
535.819
543.750
551.142
558.065
564.574
570.715
576.528
582.045
587.296
592.304
597.091
601.676
606.075
610.302
614.371
618.292
622.076
625.733
629.270
632.695
636.016
639.237
642.365
645.406
648.363
651.242
654.046
656.779
659.445
662.047
664.588
667.070
669.497
671.871
674.193
676.467
678.694
680.876
683.015
685.112
687.170
689.189
691.171
693.117
695.029
696.908
698.755
700.570
'(CC1I3) A,
Я °(Т)-Н ° @)
кДж • моль
4.844
12.383
21.042
21.213
30.776
40.752
50.972
61.346
71.821
82.366
92.962
103.595
114.257
124.940
135.642
146.357
157.083
167.820
178.564
189.315
200.071
210.833
221.599
232.368
243.141
253.916
264.695
275.475
286.257
297.042
307.827
318.615
329.404
340.193
350.984
361.776
372.569
383.363
394.157
404.953
415.749
426.545
437.342
448.140
458.938
469.737
480.536
491.335
502.135
512.936
523.736
534.537
545.338
556.140
566.942
577.744
588.546
599.348
610.151
620.954
631.757
(г)
Я°@)= 922.901
\%,К°(Т)
-461.4982
-218.6088
-138.4433
-137.4350
-96.7899
-72.3820
-56.1016
-44.4690
-35.7431
-28.9558
-23.5261
-19.0839
-15.3826
-12.2512
-9.5677
-7.2424
-5.2082
-3.4137
-1.8189
-.3922
.8916
2.0529
3.1086
4.0723
4.9557
5.7684
6.5185
7.2132
7.8582
8.4588
9.0194
9.5440
10.0358
10.4980
10.9330
11.3433
11.7309
¦12.0976
12.4452
12.7751
13.0885
13.3868
13.6710
13.9421
14.2009
14.4484
14.6852
14.9120
15.1294
15.3381
15.5385
15.7311
15.9164
16.0948
16.2667
16.4323
16.5922
16.7465
16.8955
17.0396
17.1789'
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
16D0
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
21 D0
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
i
л
_ а
Т 5
'л .
? °
\/ О
го гч
? ** |!
* t fsj -—s
00 It ""*
Tj- ^ ¦ I-
u ® S
^ ^1 fN~
P Я
~ 8
>. ^
«ч О
< 4.
+
-
К
—1
го ^
2 'л
+ §
ГО |
« и
§ 5
о «
1 !>
С °^
л о
s ¦§
? "
^ °^
3 oi
и +
0
в
ца 395
'л
§
k
го
II
я
§
ЧО
V
f-,
V
о
•т"
'о
II
2$.
184

Класс точности
VI-F
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т
37.869
45.428
54.220
54.384
62.593
69.243
74.512
78.773
82.313
85.313
87.883
90.098
92.014
93.675
95.119
96.377
97.476
98.440
99.287
100.035
100.697
101.284
101.808
102.276
102.696
103.073
103.414
103.722
104.002
104.256
104.488
104.700
104.894
105.073
105.237
105.388
105.528
105.657
105.777
105.889
105.993
106.089
106.179
106.264
106.343
106.417
106.486
106.551
106.613
106.670
106.725
106.776
106.825
106.871
106.914
106.956
106.995
107.032
107.067
107.101
107.133
ХЛОРИОДМЕТАН СН2СН
К°(Т)= р(С).р2(В)-}
)
ФО(Г)
Дж . к . моль
212.501
237.573
253.488
253.748
266.406
277.142
286.612
295.153
302.968
310.191
316.918
323.222
329.158
334.771
340.098
. 345.167
350.004
354.631
359.066
363.324
367.420
- 371.365
375.171
378.848
382.403
385.845
389.181
392.417
395.559
398.613
401.583
404.474
407.289
410.033
412.710
415.322
417.872
420.364
422.800
425.183
427.514
429.796
432.031
434.221
436.367
438.472
440.536
442.563
444.552
446.505
448.423
450.308
452.16(
453.983
455.774
457.537
459.271
460.978
462.658
464.313
465.943
з(С1)-рA)-р '
S°CT)
247.218
275.669
295.439
295.775
312.578
327.289
340.397
352.214.
362.971
372.844
381.969
390.451
398.375
405.807
412.803
419.410
425.666
431.605
437.256
442^644
447.793
452.720
457.444
461.980
466.342
470.542
474.592
478.500
482.277
485.932
489.470
492.900
496.227
499.457
502.597
505.649
508.620
511.513
514.333
517.082
519.764
522.383
524.940
527.440
529.884
532.274
534.614
536.904
539.148
541.347
543.503
545.617
547.691
549.726
551.724
553.686
555.614
557.508
559.370
561.200
563.000
(СН2С11) Аг
Я°(Г)-Я°@)
кДж . моль
3.472
7.619
12.508
12.608
18.469
25.074
32.271
39.943
48.002
56.387
65.050
73.952
83.060
92.346
101.788
111.364
121.058
130.855
140.742
150.709
160.746
170.846
181.001
191.205
201.454
211.743
222.068
232.425
242.811
253.224
263.662
274.121
284.601
295.100
305.615
316.146
326.692
337.252
347.823
358.407
- 369.001
379.605
390.219
400.841
411.471
422.109
432.754
443.406
454.064
464.729
475.398
486.074
496.754
507.438
518.128
528.821
539.519
550.220
560.925
571.633
582.345
(?)
Я°@) = 1356.838 кДж • моль
-693.0910
¦336.1890
-218.1656
-216.6792
-156.6972
-120.5933
-96.4592
-79.1811
-66.1970
-56.0812
-47.9767
-41.3374
-35.7986
-31.1075
-27.0833
-23.5932
-20.5375
-17.8398
-15.4408
-13.2933
¦11.3600
-9.6102
-8.0190
-6.5658
-5.2335
-4.0074
-2.8755
-1.8272
-.8536
.0530
.8992
1.6910
2.4334
3.1309
3.7874
4.4065
4.9913
5.5445
6.0686
6.5660
7.0385
7.4880
7.9162
8.3245
8.7143
9.0868
9.4431
9.7844
10.1114
10.4251
10.7263
11.0157
11.2940
11.5619
11.8198
12.0684
12.3081
12.5394
12.7628
12.9786
13.1873
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3590
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
Т §
о
i s
О
ОО •
го —; II
^ го ^
? ~ м
vO " 2
[ s—v .
—< О оо
11 С-Г (N
¦? S3 С
О —*
сч Е2
X ^
У X
lit
+
*~? 1
ГО _Q
Ч 1
+ (
гч ^
? к
О"\ г-Г
ЧО ^
ГО ><
О <П
+ '
1 1
iO О
II +
0
396
i
i
о
—
го
"
о К
я
о
о
о
ЧО
V
К*
V
о
о
«¦""
'о
II
185

Кла
Т
К
100
200
298
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
"С ТОЧНОСТИ
VI-Г
С°р(Т)
42.792
57.236
.15 68.954
69.145
77.812
83.802
88.000
91.079
93.450
95.349
96.909
98.214
99.319
100.261
101.071
101.769
102.376
102.904
103.367
103.773
104.132
104.450
104.732
104.985
105.211
105.413
105.596
105.761
105.911
106.047
106.171
106.285
106.388
106.484
106.571
106.652
106.727
106.796
106.860
106.919
106.974
107.026
107.074
107.119
107.161
107.200
107.237
107.272
107.304
107.335
107.364
107.391
107.417
107.442
107.465
107.487
107.507
107.527
107.546
107.564
107.581
К°(Т) = р(С)-
Ф°(П
ДИХЛОРИОДМЕТАН СНС121
р(Н)-р2(С1)-рA)-р-'
S°(T)
Дж • К . моль
227.939
255.416
274.000
274.309
289.556
302.6 ГО
314.113
324.431
333.799
342.385
350.315
357.685
364.572
371.036
377.129
382.890
388.356
393.555
398.513
403.251
407.789
412.143
416.327
420.354
424.236
427.983
431.603
435.106
438.499
441.788
444.980
448.080
451.094
454.025
456.879
459.660
462.371
465.015
467.596
470.117
472.580
474.989
477.345
479.650
481.908
484.119
486.286
488.410
490.494
492.537
494.543
496.513
498.447
500.347
502.215
504.050
505.855
507.630
509.377
511.096
512.788
264.676
298.856
323.995
324.422
345.575
363.623
379.294
393.102
405.425
416.545
426.675
435.974
444.568
452.556
460.017
467.014
473.602
479.825
485.720
491.320
496.662
501.741
506.606
511.268
515.740
520.040
524.178
528.166
532.015
535.734
539.331
542.814
546.191
549.466
552.646
555.736
558.742
561.667
564.516
567.292
570.000
572.642
575.222
577.742
580.205
582.614
584.970
587.277
589.536
591.748
593.917
596.044
598.129
600.176
602.184
604.156
606.093
607.996
609.866
611.705
613.513
(г)
(CHC12D Д Я°@) = 1262.466
Я°(Г)-Я°@)
кДж . моль"
3.674
8.688
14.906
15.034
22.407
30.507
39.108
48.070
57.301
66.744
76.359
86.117
95.995
105.976
116.043
126.186
136.394
146.659
156.973
167.330
177.726
188.155
198.615
209.101
219.611
230.142
240.693
251.261
261.844
272.442
283.053
293.676
304.310
314.954
325.606
336.268
346.937
357.613
368.296
378.984
389.679
400.379
411.084
421.794
432.508
443.226
453.948
464.673
475.402
486.134
496.869
507.607
518.347
529.090
539.835
550.583
561.333
572.084
582.838
593.594
604.351
-641.9829
-309.8531
-200.0802
-198.6984
-142.9536
-109.4276
-87.0343
-71.0140
-58.9830
-49.6154
-42.1143
-35.9724
¦30.8508
-26.5147
-22.7964
-19.5727
-16.7510
-14.2606
-12.0465
-10.0651
-8.2815
-6.6676
-5.2003
-3.8605
-2.6322
-1.5021
-.4589
.5071
1.4041
2.2393
3.0189
3.7482
4.4319
5.0743
5.6789
6.2489
6.7873
7.2967
7.7792
8.2370
8.6720
9.0858
9.4799
9.8556
113.2144
10.5572
10.8851
11.1991
11.5000
11.7887
12.0658
12.3321
12.5881
12.8346
13.0719
13.3005
13.521 1
13.7339
13.9394
14.1379
14.3298
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб
1
1
\а
с^
о
1
2 «
сч о
|| С
5; —"
с"
as
у
0
_+
i
X „
О 'j
Гч* о
+1 "'
я
оо Ч
ОО i^
0 г~
0 0
1 ^
* +
о ^
«о °)
™ 5
+ i
ГО ><
сч г-
О") ГЧ
II +
о
л и
л
о
¦
X
о
о
о
II
2"
оо
"А
г]
X
у.
о
ч
ца 397
-
о
.
1
О
го
II
0 К
о
о
о
V
*¦"
V
о
о
¦""
1
о
к
II
186

Класс точности
VI- F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
46.953
61.025
71.649
71.819
79.568
84.955
88.779
91.625
93.848
95.648
97.141
98.398
99.468
100.385
101.174
101.858
102.452
102.970
103.425
103.825
104.178
104.491
104.770
105.019
105.241
105.442
105.622
105.785
105.933
106.068
106.190
106.303
106.405
106.499
106.586
106.666
106.740
106.808
106.871
106.930
106.985
107.036
107.083
107.128
107.169
107.208
107.245
107.279
107.31
107.342
107.371
107.398
107.423
107.447
107.470
107.492
107.513
107.532
107.551
107.568
107.585
К°{Т) = р(Ор(Н
Ф°G)
— 1 -
Дж -К . моль
240.585
269.810
289.623
289.952
306.056
319.716
331.664
342.318
351.948
360.744
368.845
376.357
383.364
389.931
396.1 1 1
401.950
407.484
412.743
417.755
422.541
427.122
431.516
435.736
439.796
443.708
447.483
451.129
454.656
458.071
461.381
464.592
467.710
470.741
473.688
476.557
479.352
482.076
484.733
487.327
489.859
492.333
494.752
497.118
499.433
501.699
503.919
506.094
508.227
510.317
512.369
514.381
516.358
518.298
520.204
522.078
523.919
525.730
527.510
529.262
530.986
532.683
ХЛОРДИИОДМЕТАН СНСН2 (г)
)-р(С1Ур2(П-р~
S°(T)
1
279.199
316.247
342.«97
343.140
364.929
383.299
399.144
413.053
425.439
436.600
446.757
456.076
464.685
472.684
480.153
487.157
493.750
499.977
505.876
51 1.479
516.814
521.904
526.772
531.435
535.909
540.209
544.348
548.337
552.187
555.907
559.505
562.989
566.365
569.641
572.822
575.912
578.919
581.844
584.693
587.470
590.178
592.820
595.400
597.921
600.384
602.793
605.149
607.456
609.715
611.928
614.097
616.224
618.309
620.356
622.364
624.336
626.274
628.177
630.047
631.886
633.694
<CHCU2) AfJ-
//°<гы/°(о)
кДж . моль.
3.861
9.287'
15.824
15.957
23.549
31.791
40.488
49.515
58.793
68.270
77.912
87.691
97.585
107.579
117.658
127.81 1
138.027
148.298
158.619
168.981
179.382
189.816
200.279
210.769
221.282
231.816
242.370
252.940
263.526
274.126
284.739
295.364
306.000
316.645
327.299
337.962
348.632
359.309
369.994
380.684
391.379
402.080
412.786
423.497
434.212
444.931
455.653
466.380
477.109
487.842
498.578
509.316
520.057
530.800
541.546
552.295
563.045
573.797
584.551
595.307
606.065
1°(()) = 1143
-579.8907
-278.8136
-179.3000
-178.0472
-127.5133
¦97.1229
-76.8255
-62.3057
-51.4024
-42.9134
-36.1 164
-30.5513
-25.9109
-21.9826
-18.6140
-15.6936
-13.1376
-10.8817
-8.8761
-7.0813
-5.4657
-4.0039
¦2.6747
-1.4610
-.3483
.6754
1.6206
2.4958
3.3086
4.0654
4.7719
5.4329
6.0527
6.6350
7.1831
7.7000
8.1883
8.6503
9.0880
9.5034
9.8981
10.2736
10.6313
10.9724
П.2981
11.6094
11.9073
12.1925
12.4659
12.7282
12.9801
13.2222
13.4550
13.6790
13.8948
14.1029
14.3035
14.4971
14.6841
14.8648
15.0396
.919 кДж -моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300-
1400
1500
1600
1700
1800
1900
2000
21 НО
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
-4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
'л
о
' л 2
§ ?
* о
<ы О
чо О
On <-' "
° s g
11 (^ ГЧ
;—• гч
х С
В ж
О W
^ 0
+
t
^ 7
!
1 _
*° ^
^1 ГО
О эо
о °i
X ^
00 Н
оо [2
гл ™
ГЧ Q*
+ 1
го х
ГЧ 00
II +
0
а 398
1 j
о
1
5
о «
я,
о
о
Z
V
Ь-
V
с
о
ч-
t
о
^.
II
187

Класс точности
VI-F
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
45.603
64.591
76.586
76.774
85.278
91.141
95.187
98.026
100.063
101.561
102.687
103.552
104.229
104.768
105.203
105.559
105.853
106.100
106.308
106.486
106.638
106.770
106.884
106.985
107.073
107.152
107.221
107.283
107.339
107.389
107.434
107.475
107.513
107.547
107.578
107.606
107.632
107.656
107.679
107.699
107.718
107.736
107.752
107.768
107.782
107.795
107.808
107.820
107.831
107.841
107.851
107.860
107.868
107.877
107.884
107.892
107.898
107.905
107.911
107.917
107.923
ДИФТОРХЛОРИОДМЕТАН
K°(T)=p(C)-p\F)
Ф°(Г)
Дж • К . моль
226.326
254.618 "
274.646
274.983
291.6f2
305.872
318.426
329.666
339.851
349.164
357.745
365.700
373.115
380.058
386.585
392.744
398.572
404.104
409.369
414.390
419.190
423.786
428.196
432.434
436.512
440.443
444.236
447.901
451.446
454.879
458.206
461.434
464.569
467.616
470.579
473.464
476.273
479.012
481.683
484.289
486.835
489.322
491.753
494.131
496.457
498.735
500.965
503.15i
505.293
507.394
509.455
511.477
513.462
515.411
517.326
519.208
521.057
522.875
524.664
526.423
528.154
•p(Cl)-pd)
5°(Г)
1
262.809
300.839
329.006
329.480
352.805
372.505
389.502
404.401
417.631
429.507
440.269
450.098
459.139
467.504
475.284
482.555
489.377
495.802
501.873
507.625
513:092
518.298
523.267
528.021
532.576
536.948
541.152
545.200
549.103
552.870
556.512
560.035
563.448
566.757
569.968
573.087
576.118
579.068
581.939
584.736
587.463
590.124
592.720
595.255
597.733
600.155
602.525
604.843
607.113
609.337
611.516
613.652
615.746
617.801
619.818
621.797
623.741
625.651
627.528
629.372
631.186
p~4CF2Cll)
Н°(Т)-Н1
CF2C1I (г)
Д Я°@)= 1467.662
'@)
кДж . моль"
3.648
. 9.244
16.207
16.349
24.478
33.317
42.645
52.314
62.224
72.309
8'2.524
92.838
103.228
113.679
124.178
134.717
145.288
155.886
166.507
177.147
187.803
198.474
209.156
219.850
230.55о
241.264
251.983
262.708
273.439
284.176
294.917
305.663
316.412
327.165
337.921
348.680
359.442
370.207
380.974
391.742
402.513
413.286
424.060
434.837
445.614
456.393
467.173
477.955.
488.737
499.520
510.305
521.091
531.877
542.664
553.452
564.241
575.031
585.821
596.612
607.403
618.195
-747.2717
-361.5720
-234.1989
-232.5962
-167.9618
-129.1176
-103.1903
-84.6545
-70.7436
-59.9189
-51.2561
-44.1665
-38.2576
-33.2572
-28.9708
-25.2559
-22.0054
-19.1373
-16.5881
-14.3073
-12.2548
-10.3979
-8.7100
-7.1689
-5.7564
-4.4570
-3.2577
-2.1473
-1.1162
-.1564
.7394
1.5774
2.3629
3.1009
3.7Э53
4.4501
5.0685
5.6534
6.2075
6.7332
7.2327
7.7077
8.1602
8.5916
9.0033
9.3968
9.7732
10.1336
10.4789
10.8102
11.1282
11.4338
11.7276
12.0104
12.2826
12.5450
12.7980
13.0422
13.2779
13.5057
13.7258
кДж - моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5^00
5300
54Q0
5500
5600
5700
5800
5900
6000
Таблиц
_
'л
- 2
'л
1 |
•<¦ о
ж о
Е[ О
V fС
2 7
m in II
in ^
>о <*> О
ГЧ II —<
Д g Ж
II .. Сч
¦5: - ^
о ^^
^1 0
+
i
к
•о
СЧ —
00 V
чо Я
сч О
+ S
С* -ч"
OS f*
г-- *
S ч
о пн
° 2
in
? +
я s
о -
+ 1
—| Я
сч in
Л ^>
in 2
и +
о
а 399
"л
i
^*
Щ
-н
Tf
II
о §
Я
о
чО
V
(-,
V
о
о
Щ
ч-'"
'о
к
II
а.
188

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400-
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
ФТОРДИХЛОРИОДМЕТАН CFC12I (г)
К°(Т) = p(C)-p(F)-p2(Cl)-p(I)-p"
Ф°(Г)
S°(T)
Дж • К . моль
49.596
69.796
81.754
81.934
89.765
94.830
98.172
100.447
102.046
103.204
104.066
104.722
105.232
105.636
105.961
106.226
106.445
106.628
106.782
106.913
107.025
107.122
107.206
107.280
107.345
107.403
107.454
107.499
107.540
107.577
107.610
107.640
107.668
107.692
107.715
107.736
107.755
107.773
107.789
107.804
107.818
107.831
107.843
107.854
107.865
107.874
107.883
107.892
107.900
107.908
107.915
107.921
107.928
107.934
107.939
107.945
107.950
107.954
107.959
107.963
107.967
231.565 269.962
261.681 311.231
283.175 341.498
283.536 342.005
301.345 366.730
316.541 387.345
329.845 404.950
341.692 420.265
352.376 433.788
362.105 445.878
371.037 456.799
379.293 466.749
386.967 475.884
394.135 484.324
400.860 492.164
407.194 499.484
413.179 506.347
418.851 512.806
424.242 518.905
429.378 524.682
434.281 530.169
438.973 535.393
443.470 540.379
447.787 545.146
451.940 549.713
455.939 554.096
459.796 558.309
463.520 562.366
467.120 566.276
470.605 570.050
473.981 573.698
477.255 577.227
480.433 580.645
483.520 583.958
486.522 587.174
489.442 590.296
492.286 593.332
495.057 596.284
497.759 599.159
500.395 601.959
502.968 604.688
505.482 607.351
507.938 609.949
510.340 612.487
512.690 614.967
514.990 617.391
517.242 619.762
519.448 622.082
521.610 624.354
523.730 626.579
525.808 628.759
527.848 630.896
529.850 632.991
531.816 635.047
533.746 637.065
535.643 639.046
537.507 640.991
539.339 642.901
541.140 644.779
542.913 646.624
544.656 648.439
"VcFCljI) ДгЯ°@) = 1311.011 кДж • моль"
Я°(Г)-Я°@)
кДж • моль
3.840
9.910
17.389
17,541
26.154
35.402
45.063
55.001
65.130
75.396
85.761
96.202
106.701
117.245
127.825
138.435
149.069
159.723
170.394
181.079
191.776
202.483
213.200
223.924
234.655
245.393
256.136
266.883
277.635
288.391
299.151
309.913
320.679
331.446
342.217
352.989
363.764
374.540
385.319
396.098
406.879
417.662
428.445
439.230
450.016
460.803
471.591
482.380
493.170
503.960
514.751
525.543
536.335
547.128
557.922
568.716
579.511
590.306
601.102
611.898
622.695
-665.3146
-320.6333
-206.8205
-205.3885
-147.6467
-112.9497
-89.7929
-73.2385
-60.8151
-51.1479
-43.4115
-37.0801
-31.8031
-27.3374
-23.5094
-20.1918
-17.2889
-14.7276
-12.4511
-10.4143
-8.5813
-6.9230
-5.4157
-4.0395
-2.7781
-1.6178
-.5468
.4448
1.3655
2.2226
3.0226
3.7708
4.4723
5.1312
5.7514
6.3360
6.8882
7.4105
7.9054
8.3748
8.8208
9.2450
9.6490
10.0342
10.4019
10.7533
11.0894
11.4112
11.7196
12.0154
12.2994
12.5722
12.8346
13.0871
13.3302
13.5645
13.7905
14.0085
14.2190
14.4224
14.6190
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
' 4800
4900
5000
5100
5200
5300
5400
з500
5600
5700
5800
5900
6000
Таблица 400
1
в
— о
1 а
х 7
л § s
3 о §
2 S -'
ЧТ , , ~*
"~* I V
On i— II
8.81
15К
2Д:
fN о" ОО Tf
11 <-"' « ?
л? ~ "
у "А „
ft О ° «
У ь ^
о CJ
< X
+
—
ё
00
+ §
X -"
о ^ Ьй
1Л • О
2 * о
° "я V
? 2 V
<N + g
я « °
Г- Г-
*О 00
II +
ь
0
©
189

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
54.521
74.436
85.016
85.173
91.976
96.361
99.269
101.261
102.670
103.697
104.464
105.050
105.507
105.869
106.162
106.400
106.598
106.763
106.902
107.021
107.122
107.210
107.287
107.354
107.413
107.465
107.511
107.553
107.590
107.623
107.653
107.681
107.705
107.728
107.749
107.768
107.785
107.801
107.816
107.829
107.842
107.854
107.865
107.875
107.884
107.893
107.902
107.909
107.917
107.924
107.930
107.936
107.942
107.947
107.952
107.957
107.962
107.966
107.970
107.974
107.978
ФТОРХЛОРДИИОДМЕТАН
К°(Т)= p(C)p(F)-p(Cl)p2(I)
Ф°(П
¦* X "
Дж • К . моль
242.523
274.323
297.183
297.565
316.352
332.250
346.075
358.320
369.318
379.300
388.440
396.869
404.690
411.985
418.820
425.250
431.319
437.067
442.525
447.721
452.680
457.421
461.963
466.323
470.5J4
474.548
478.438
482.192
485.821
489.332
492.733
496.030
499.230
502.337
505.358
508.297
511.158
513.946
516.663
519.314
521.901
524.428
526.897
529.312
531.673
533.984
536.246
538.463
540.634
542.763
544.851
546.899
548.910
550.883
552.821
554.725
556.596
558.436
560.244-
562.023
563.773
S4T)
1
282.233
327.132
358.985
359.511
385.019
406.048
423.892
439.353
452.971
46S.127
476.094
486.079
495.240
503.700
511.557
518.889
525.763
532.230
538.337
544.120
549.612
554.841
559.830
564.600
569.171
573.557
577.772
581.831
585.743
589.519
593.168
596.698
600.117
603.432
606.648
609.772
612.808
„15.762
618.637
621.437
624.168
626.831
629.430
631.968
634.448
636.873
оЗЭ.244
641.565
643.837
646.062
648.242
650.380
652.476
654.532
656.550
658.531
660.476
662.387
664.265
666.110
667.925
p~'(CFCU2)
Н°(Т)-Н
CFC1I2 (г)
Д/.Я°(О)=1187
Ч0)
кДж • моль
3.971
10.562
18.426
18.584
27.467
36.899
46.690
56.723
66.923
77.244
87.654
98.131
108.659
119.229
129.831
140.459
151.110
161.778
172.461
183.158
193.865
204.582
215.307
226.039
236.777
247.521
258.270
269.023
279.780
290.541
301.305
312.071
322.840
333.612
344.386
355.162
365.940
376.719
387.500
398.282
409.066
419.851
430.636
441.423
452.211
463.000
473.790
484.580
495.372
506.164
516.957
527.750
538.544
549.338
560.133
570.929
581.725
592.521
603.318
614.115
624.913
о
-600.5850
-288.2275
-185.1006
-183.8032
-131.4910
-100.0621
-79.0901
-64.1002
-52.8527
-44.1018
-37.0997
-31.3700
-26.5950
-22.5546
-19.0915
-16.0903
¦13.4646
-11Л479
-9.0889
-7.2469
-5.5892
-4.0896
-2.7264
-1.4819
-.3411
.7083
1.6769
2.5737
3.4065
4.1818
4.9054
5.5824
6.2171
6.8133
7.3745
7.9037
8.4035
8.8764
9.3244
9.7495
10.1534
10.5376
10.9036
11.2526
11.5859
11.9043
12.2090
12.5007
12.7804
13.0486
13.3062
13.5537
13.7918
14.0209
14.2416
14.4543
14.6594
14.8574
15.0486
15.2333
15.4119
.584 кДж • моль"
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл
1
и ц а
'л
§
¦з
? ч>
О II
f> о
11 С
я
и ¦
0
<
+
+ §
г» S
1
'к -•
§ 5
О m
1 -3
1 5
О о
О 00
¦ 00
о
ЧО 00
II +
0
л
с-
о
?
*g
о
о
о
о
1
II
Я ¦
00
(N
!-"
г)
и
Э
401
-1
А
О
.
1
i
CN
чо
If
0 0?
to
я
о
40
V
V
8
•""
'о
*"Н
11
190

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°
С°р(Т)
39.964
53.476
65.098
65.291
74.252
80.729
85.426
88.942
91.675
93.864
95.657
97.149
98.404
99.469
100.379
101.161
101.837
102.424
102.936
103.386
103.781
104.131
104.441
104.717
104.965
105.186
105.386
105.566
105.730
105.878
106.013
106.136
106.249
106.353
106.448
106.535
106.616
106.691
106.761
106.825
106.885
106.941
106.993
107.041
107.087
107.129
107.169
107.207
107.242
107.275
107.307
107.336
107.364
107.391
107.416
107.439
107.462
107.483
107.503
107.523
107.541
ФТОРХЛОРИОДМЕТАН CHFC1I
(Г) = p(C)-p(H)-p(F)
Ф°(Г)
Дж • К .моль
221.954
248.195
265.743
266.035
280.430
292.792
303.731
313.583
322.563
330.823
338.476
345.607
352.287
358.570
364.503
370.123
375.462
380.548
385.403
390.049
394.502
398.778
402.891
406.852
410.674
414.364
417.933
421.387
424.735
427.981
431.133
434.196
437.174
440.073
442.895
445.646
448.329
450.946
453.502
455.999
458.439
460.826
463.161
465.446
467.684
469.878
472.027
474.134
476.201
478.230
480.221
482.176
484.096
485.983
487.838
489.661
491.454
493.217
494.953
496.661
498.342
Р(С1).РA).р-
S°(T)
257.495
289.299
312.906
313.310
333.387
350.691
365.847
379.291
391.353
402.282
412.267
421.456
429.965
437.884
445.290
452.243
458.794
464.986
470.855
476.432
481.746
486.818
491.670
496.318
500.780
505.070
509.199
513.180
517.022
520.735
524.327
527.805
531.176s
534.447
537.624
540.711
543.713
546.635
549.482
552.256
554.961
557.601
560.179
562.697
565.158
567.565
569.920
572.225
574.483
576.694
578.862
580.987
583.072
585.117
587.125
589.096
591.032
592.934
594.804
596.642
598.449
(CHFCI) Д,Я°
Я°(Г)-Я°@)
кДж . моль"
3.554
8.221
14.062
14.182
21.183
28.950
37.269
45.996
55.032
64.313
73.791
83.434
93.213
103.108
113.102
123.180
133.331
143.544
163.813
164.130
174.488
184.884
195.313
205.771
216.256
226.763
237.292
247.840
258.405
268.985
279.580
290.187
300.807
311.437
322.077
332.726
343.384
354.049
364.722
375.401
386.087
396.778
407.475
418.177
428.883
439.594
450.309
461.028
471.750
482.476
493.205
503.937
514.672
525.410
536.150
546.893
557.638
568.385
579.135
589.886
600.639
(г)
@) = 1399.455 кДж • моль
о
-713.6307
-345.6483
-224.0282
-222.4971
-160.7329
-123.5859
-98.7742
-81.0243
¦67.6952
¦57.3173
-49.0078
-42.2043
-36.5313
-31.7286
-27.6104
-24Ю400
-20.9150
-18.1571
-15.7051
¦13.5108
-11.5358
-9.7486
-8.1238
-6.6401
-5.2800
-4.0286
-2.8735
-1.8039
-.8106
.1142
.9774
1.7849
2.5420
3.2532
3.9226
4.5538
5.1499
5.7138
6.2481
6.7550
7.2366
7.6947
8.1310
8.5471
8.9443
9.3238
9.6868
10.0344
10.3676
10.6872
10.9940
11.2888
11.5722
11.8450
12.1077
12.3609
12.6050
12.8406
13.0681
13.2879
13.5003
Т .
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1о00
1700
1800
1900
2000
2100
2200
2300
2400
.2500
2600
2700
2800
2900
3000 -
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
00
ГО
—<
II
Т" г.
1 а
i
к
о
?
ОО
—;
1
"
О
и
1-Г
О
0
0
Д;
it
<
+
ё ¦
Р*1
+
оо
сч
о
сэ
оо
s
+
го
00
<о
II
-—'
0
в
блиц
1
г-
а\
"~*
ч
X
р
1
я
о.
+
ч
о
С}'
X
о
р
i
и
«п
ОО
ГЧ
с"
—'
О
it;
Л Л1
а 4 02
Т
—'
1
СО
II
0 0Q -
§
о
о
40
V
v;
о:
о
V
'о
—1
II
191

Класс точности
VI-F
7"
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
65.910
82.839
92.175
92.308
97.763
100.948
102.906
104.174
105.037
105.646
106.092
106.427
106.685
106.888
107.050
107.181
107.289
107.379
107.455
107.519
107.574
107.621
107.662
107.698
107.730
107.757
107.782
107.804
107.824
107.842
107.858
107.872
107.885
107.897
107.908
107.919
107.928
107.936
107.944
107.951
107.958
107.964
107.970
107.975
107.980
107.985
107.989
107.994
107.997
108.001
108.005
108.008
108.01 1
108.014
108.016
108.019
108.021
108.024
108.026
108.028
108.030
ТРИБРОМИОДМЕТАН СВг
К°(Т)= р(С)р3(
Ф°(Г)
Дж • К . моль
244.737
282.143
308.332
308.766
329.854
347.429
362.528
375.771
387.569
398.208
407.895
416.787
425.004
432.641
439.775
446.469
452.772
458.729
464.374
469.740
474.853
479.734
484.405
488.883
493.183
497.318
501.301
505.142
508.852
512.439
515.910
519.274
522.536
525.703
528.780
531.771
534.682
537.516
540.279
542.972
545.600
548.165
550.672
553.121
555.516
557 859
560.152
562.398
564.598
566.755
568.869
570.942
572.977
574.974
576.934
578.860
580.752
582.612
584.440
586.237
588.006
Вг,.,A,.,
S°(T)
291.745
343.360
378.337
378.908
406.283
428.470
447.062
463.027
476.997
489.406
500.561
510.689
519.961
528.509
536.436
543.827
550.747
557.255
563.394
569.206
574.722
579.972
584.979
589.766
594.350
598.749
602.976
607.044
610.964
614.748
618.405
621.942
625.367
628.687
631.908
635.036
638.076
641.034
643.912
646.716
649.449
652.1 15
654.717
657.257
659.740
662.167
664.540
666.862
669.136
671.363
673.545
675.684
677.781
679.839
681.858
683.840
685.786
687.698
689.577
691.424
693.239
"'(СВг31). Дг/
Н°(Т)-Н°@)
кДж . моль
4.701
12.243
20.872
21.043
30.571
40.521
50.721
61.079
71.542
82.078
92.666
103.293
I 13.949
124.628
135.325
146.037
156.760
167.494
178.-236
188.984
199.739
210.499
221.263
232.031
242.803
253.577
264.354
275.133
285.915
296.698
307.483
318.269
329.057
339.847
350.637
361.428
372.220
383.014
393.808
404.602
415.398
426.194
436.991
447.788
458.586
469.384
480.183
490.982
501.782
512.581
523.382
534.182
544.983
555.785
566.586
577.388
588.190
598.992
609.795
620.597
631.400
,1 (г)
!°@) = 978.561
-490.3568
-232.8942
-147.9330
-146.8645
-103.7944
-77.9350
¦60.6897
-48.3701
-39.1301
-31.9438
-26.1950
-21.4916
-17.5722
-14.2557
-1 1.4129
-8.9488
-6.7925
-4.8895
-3.1976
-1.6834
-.3204
.9133
2.0351
3.0597
3.9992
4.8638
5.6623
6.4019
7.0889
7.7288
8.3262
8.8853
9.4097
9.9026
10.3666
10.8042
11.2178
11.6091
I 1.9800
12.3320
12.6665
12.9849
13.2882
13.5775
13.8538
14.1 179
14.3706
14.6126
14.8447
15.0674
15.2812
15.4867
15.6844
15.8747
16.0580
16.2346
16.405!
16.5696
16.7285
16.8820
17.0305
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таб
-
О
""' $
ОС ~~
II О
<*>
03
У
_
г- _
" .в
+ о
'ч -'
ос ?
° "*
1 »°
. Н с-
о °
¦* ^+
"*¦ (N
^ чС
О _-
о ч
о' ¦*
<-1 **
II +
о
Л*
л и
1
J!
О
с
о
о
—
1
2
—¦
ос
rL
U
SS
У
5;
<\
ца403
i
S
s
_'
i
0 се;
Я
О
О
о
V
f-
V
о
о
t"
1
о
192

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
ДИБРОМДИИОДМЕТАН СВг212
K°(J)=p(C)-p\bi)-p\l)-p~l
Ф°(Г)
S°(T)
Дж • К . моль
64.368
84.954
94.311
94.437
99.537
102.421
104.127
105.189
105.884
106.360
106.698
106.946
107.134
107.278
107.393
107.484
107.559
107.620
107.672
107.715
107.752
107.783
107.811
107.835
107.855
107.874
107.890
107.905
107.917
107.929
107.940
107.949
107.958
107.965
107.972
107.979
107.985
107.990
107.995
108.000
108.004
108.008
108.012
108.016
108.019
108.022
108.025
108.027
108.030
108.032
108.034
108.036
108.038
108.040
108.042
108.044
108.045
108.047
108.048
108.049
108.051
251.627 297.797
288.598 349.758
314.925 385.624
315.363 386.208
336:703 414.146
354.520 436.696
369.829 455.533
383.253 471.670
395Л04 485.765
405.974 498.265
415.774 509.490
424.764 519.671
433.066 528.985
440.779 537.566
447.980 545.521
454.732 552.933
461.089 559.873
467.094 566.395
472.783 572.548
478.188 578.371
483.337 583.897
488.252 589.155
492.953 594.170
497.459 598.963
501.784 603.552
505.944 607.956
509.949 612.187
513.812 616.259
Р 17 f J 1 С АЛ 1 О J
517.541 020.184
521.146 623.971
524.635 627.630
528.015 631.169
531.292 634.597
534.473 637.919
537.563 641.142
540.568 644.272
543.491 647.314
546.337 650.273
549.110 653.153
551.814 655.958
554.452 658.692
557.027 661.359
559.542 663.962
562.000 666.504
564,404 668.987
566.755 671.414
569.056 673.789
571.309 676.112
573.516 678.386
575.679 680.614
577.800 682.796
579.880 684.936
581.920 687.034
583.923 689.092
585.889 691.111
587.820 693.094
589.718 695.040
591.582 696.953
593.416 698.832
595.218 700.679
596.991 702.495
(Г)
[СВг212) Д/.Я°@) = 923.67ОкДж • моль
Н°(Т)-Н°@)
кДж . моль"
4.617
12.232
21.079
21.253
30.977
41.088
51.423
61.892
72.448
83.062
93.716
104.398
115.103
125.824
136.558
147.301
158.054
168.813
179.577
190.347
201.120
211.897
222.677
233.459
244.244
255.030
265.818
276.608
287.399
298.191
308.985
319.779
330.574
341.371
3S2.167
362.965
373.763
384.562
395.361
406.161
416.961
427.762
438.563
449.364
460.166
470.968
481.771
492.573
503.376
514.179
524.983
535.786
546.590
557.394
568.198
579.002
589.807
600.611
611.416
622.221
633.026
-461.7435
-218.5941
-138.3594
-137.3504
-96.6828
¦72.2696
¦55.9911
-44.3636
-35.6439
-28.8629
-23.4391
-19.0022
-15.3053
-12.1775
-9.4969
-7.1738
-5.1412
-3.3476
-1.7534
-.3268
.9573
2.1192
3.1756
4.1404
5.0249
5.8389
6.5905
7.2866
7.9332
8.5354
9.0976
9.6238
10.1172
10.5810
11.0176 .
11.4294
11.8186
12.1868
12.5359
12.8671
13.1820
13.4816
13.7672
14.0395
14.2996
14.5482
14.7862
15.0141
15.2327
15.4424
15.6438
15.8374
16.0236
16.2029
16.3757
16.5422
16.7028
16.8579
17.0077
17.1525
17.2925
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 404
i
?
5
7 2
к 8 |
^ О V
Г— °| 1
ОО (S Ж
5.628(
= 237.
15К) =
ЗДж
TJ- g* 00 OS
" С " 3>
и "? о к
<г 8 • *°
¦5 о.
1
'н
i2 -
.585
оль"
+ S
« -.'
'н ьй
о • ?
? « S
§ тн *
О о *
1 О К
1 * Y,
00 => 7
О о О
+ х tL.
ON 00 "
VO О "
On о ^
S |
II
с
0
о
193

Класс точности
¦ VI-G
7'
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
70.301
85.880
94.517
94.636
99.446
102.174
103.822
104.879
105.593
106.095
106.461
106.736
106.946
107.112
107.244
107.351
107.439
107.512
107.574
107.626
107.670
107.709
107.742
107.771
107.797
107.820
107.840
107.858
107.874
107.888
107.901
107.913
107.924
107.933
107.942
107.950
107.958
107.965
107.971
107.977
107.983
107.988
107.992
107.997
108.001
108.004
108.008
108.011
108.015
108.017
108.020
108.023
108.025
108.028
108.030
108.032
108.034
108.036
108.037
108.039
108.041
БРОМТРИИОДМЕТАН CBrl3 (г)
А-°G-) = р(С)-р(Вг)-р3A)-/Г1(
Ф°(Г)
Дж • К . моль
254.484
294.375
321.918
322.372
344.349
362.545
378.099
391.690
403.762
414.621
424.490
433.533
441.879
449.627
456.858
463.635
470.013
476.036
481.741
487.161
492.321
497.247
501.958
506.473
510.806
514.973
518.985
522.853
526.588
530.198
533.692
537.076
540.358
543.542
546.636
549.644
552.570
555.419
558.195
560.901
563.542
566.119
568.636
571.097
573.502
575.855
578.158
580.413
582.621
584.786
586.908
588.989
591.031
593.035
595.003
596.935
598.834
600.699
602.533
604.337
606.111
S°(T)
1
305.004
359.103
395.167
395.752
423.704
446.215
465.001
481.090
495.144
507.612
518.810
528.970
538.267
546.834
554.777
562.180
569.1 1 1
575.627
581.774
587.591
593.1 13
598.367
603.379
608.168
612.756
617.157
621.386
625.456
629.379
633.165
636.822
640.361
643.787
647.108
650.331
653.459
656.501
659.459
662.338
665.143
667.877
670.543
673.145
675.686
678.169
680.596
682.970
685.293
687.567
689.794
691.977
694.116
696.213
698.271
700.290
702.273
704.219
706.132
708.010
709.857
711.673
CBrI,) Д Я°@)= 864.332
//°GV//°@)
кДж . моль
5.052 -430.5971
12.946 -203.0973
21.839 -128.0277
22.014 -127.0837
31.742 -89.0322
41.835 . -66.1885
52.141 -50.9560
62.580 -40.0753
73.106 -31.9155
83.691 -25.5700
94.320 -20.4946
104.981 -16.3429
115.665 -12.8839
126.368 -9.9578
137.086 -7.4501
147.816 -5.2773
158.556 -3.3763
169.304 -1.6993
180.058 -.2087
190.818 1.1248
201.583 2.3249
212.352 3.4108
223.124 4.3979
233.900 5.2992
244.679 6.1256
255.460 6.8859
266.243 7.5879
277.028 8.2380
287.814 8.8418
298.602 9.4041
309.392 9.9291
320.182 10.4204
330.974 10.8812
341.767 11.3142
352.561 11.7219
363.355 . 12.1064
374.151 12.4698
384.947 12.8137
395.744 13.1397
406.541 13.4491
417.339 13.7432
428.138 14.0231
438.937 14.2898
449.736 14.5442
460.536 14.7872
471.336 15.0196
482.137 15.2420
492.938 15.4550
503.739 15.6593
514.541 15.8553
525.343 16.0436
536.145 16.2247
546.947 16.3989
557.750 16.5666
568.553 16.7282
579.356 16.8840
590.159 17.0343
600.963 17.1794
611.766 17.3196
622.570 17.4552
633.374 17.5863
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1109
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 405
-
л
К
- О
1 *?
3 •
1 д ~-
2 Е{ g
X О
д. § s
п о
• 1
^ ^ 5s -
S ^ II J*S
*•© оо ^ П.
<^» rvl ?а- г-»
*— It UT) 1У)
,. О 00 ГЧ
Us ^ ^
1 -S - ° §
w да ^
О {J
**ч О
-
О
ON ^
+ о
<s S
1ё т"
§ ч «
° 1 ^
^** ^о \/
ON + О
S "ч -
о' Й То
-f- *
О О*\ "
О Оч .
2? "^
и +
0
е
194

Класс точности
VI-F
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
550р
5600
5700
5800
5900
6000
к°
С°(Т)
р
39.333
47.075
56.112
56.276
64.354
70.748
75.759
79.801
83.163
86.021
88.479
90.605
92.448
94.051
95.447
96.666
97.732
98.668
99.492
100.219
100.864
101.436
101.947
102.403
102.813
103.181
103.514
103.815
104.088
104.337
104.564
104.771
104.961
105.135
105.296
105.444
105.581
105.707
105.825
105.934
106.035
106.130
106.218
106.301
106.378
106.450
106.518
106.582
106.642
106.699
106.752
106.803
106.850
106.895
106.938
106.978
107.017
107.053
107.088
107.120
107.152
БРОМИОДМЕТАН СН2Вг1
G-) = р(С)р2(Н)
Ф СГ)
¦¦ 1 *¦
Дж • К . моль
221.391
247.201
263.632
263.900
276.979
288.056
297.805
306.575
314.580
321.963
328.826
335.246
341.284
346.985
352.389
357.527
362.426
367.108
371.593
375.896
380.033
384.016
387.857
391.565
395.150
398.619
401.980
405.240
408.404
411.478
414.468
417.377
420.209
422.970
425.661
428.288
430.852
433.357
435.805
438.199
440.541
442.834
445.080
447.279
449.435
451.548
453.622
455.656
457.653
459.613
461.539
463.431
465.291
467.119
468.917
470.685
472.425
474.138
475.823
477.483
479.118
•р(Вг)-рA) .р~ i
sV)
1
257.037
286.491
306.980
307.327
324.663
339.740
353.099
365.092
375.973
385.938
395.132
403.667
411.631
419.096
426.118
432.746
439.019
444.973
450.636
456.0.36
461.193
466.128
470.859
475.401
479.768
483.973
488.026
491.938
495.719
499.376
502.917
506.349
509.678
512.911
516.052
519.106
522.079
524.973
527.794
530.544
533.228
535.847
538.405
540.906
543.351
545.742
548.082
550.374
552.618
554.818
556.974
559.088
561.163
563.199
565.197
567.160
569.088
570.982
572.844
574.675
576.476
(г)
CH2BrI) ДгЯ°@)= 1292.257 кДж. моль
Н°(Г)-Н°@)
кДж « моль
3.565
7.858
12.924
13.028
19.073
25.842
33.177
40.962
49.115
57.577
66.306
75.262
84.417
93.744
103.220
112.827
122.549
132.370
142.278
152.265
162.320
172.435
182.605
192.823
203.084
213.384
223.719
234.086
244.481
254.902
265.348
275.814
286.301
296.806
307.328
317.865
328.416
' 338.980
349.557
360.145
370.744
381.352
391.969
402.595
413.229
423.871
434.519
445.175
455.836
466.503
477.175
487.853
498.536
509.223
519.915
530.611
541.310
552.014
562.721
573.431
584.145
Т
К
-659.2926 100
-319.2963 200
-206.8549 298.15
-205.4389 300
-148.2958 400
-113.9042 500
-90.9177 600
-74.4632 700
-62.0995 800
-52.4680 900
-44.7520 1000
-38.4313 1100
-33.1584 1200
-28.6925 1300
-24.8615 1400
-21.5387 1500
-18.6293 1600
-16.0607 1700
-13.7762 1800
-11.7312 1900
-9.8898 2000
-8.2231 2100
-6.7073 2200
-5.3228 2300
-4.0533 2400
-2.8849 2500
-1.8061 2600
-.8068 2700
.1213 2800
.9856 2900
1.7926 3000
2.5476 3100
3.2557 3200
3.9210 3300
4.5474 3400
5.1380 3500
5.6960 3600
6.2240 3700
6.7243 3800
7.1990 3900
7.6501 4000
8.0792 4100
8.4881 4200
8.8780 4300
9.2502 4400
9.6060 4500
9.9463 4600
10.2723 4700
10.5847 4800
10.8844 4900
! 1.1722 5000
11.4488 5100
11.7148 5200
11.9708 5300
12.2173 5400
12.4549 5500
12.6841 5600
12.9052 5700
13.1188 5800
13.3252 5900
13.5247 6000
Таблица 406
-1
i .
Л
^ о
1 ч 7Л
* Ж R
s ° i
Ч о _•
О4 ^о уу
00 ,, **•
m о II
S ^ * ч
О ¦ " ^н Оч
Я S »¦ °
и с Я ^
§ .-Г й
я ~ "
X «. о §
?¦ 5 "
О W
< ч-.
К 1
О о .
со *
CN —
, 1
1 *
? d g
Os H О
-н го чо
О V) \/
О ^" L^.
ч + V
ю °°. ••
<- ¦* 1
^ со "о
+ и •
5 2 s
Г~- О
и +
w
О
А
195

Класс точности
VI-F
Т
л
100
200
298.15
300
400
500
600
700
800
900
1000
1100
.1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Л
с;(п
ДИБРОМИОДМЕТАН СНВг2]
Г)= р(С)-р(Н)-р2(Вг)рA)^~1(СНВг21) Afh
Ф°G)
S°G)
Дж .К .моль
49.4П4
62.353
72.599
72.766
80.409
85.711
89.441
92.194
94.332
96.059
97.491
98.698
99.726
100.609
!01.370
102 030
102.604
103.106
103.546
103.934
104.277
104.581
104.852
105.093
105.310
105.50?
105.681
105.840
105.984
106.115
106.235
106.344
106.444
106.536
106.620
106.698
106.770
106.837
106.899
106.956
107.010
107.059
107.106
107.149
107.190
107.228
107.263
Ю7.297
107.329
107.358
107.386
107.413
107.438
107.462
107.484
107.505
107.525
107.544
107.563
107.580
107.596
242.104
272.271
292.651
292.988
309.463
323.388
335.538
346.352
356.113
365.017
373.209
380.799
387.873
394.498
400.730
406.Ы4
412.188
417.484
422.528
427.344
431.952
436.371
440.613
444.694
448.625
452.418
456.080
459.623
463.052
466.375
469.599
472.729
475.771
478.729
481.608
484.412
487.145
489.810
492.412
494.951
497.433
499.859
502.231
50^.552
506.825
509.050
511.231
513.369
515.464
517.520
519.538
521.519
523.464
525.374
527.252
529.097
530.911
532.696
534.451
536.178
537.878
Н°(Т)-Н°(Р)
кДж . моль
281.769 3.966
320.182 9.582
347.072 16.226
347.522 16.360
369.566 24.041
388.115 32.364
404.091 41.132
418.094 50.220
430.550 59.550
441.764 69.072
451.961 78.752
461.311 88.563
469.944 98.486
477.962 108.504
485.447 118.603
492.464 128.774
499.067 139.007
505.303 149.293
511.209 159.626
516.818 170.000
522.158 180.411
527.253 190.854
532.125 201.326
536.791 . 211.823
541.268 222.344
545.572 232.885
549.713 243.444
553.704 254.020
557.556 264.612
561.278 275.216
564.877 285.834
568.362 296.463
571.740 307.103
575.017 317.752
578.199 328.410
581.291 339.076
584.298 349.749
587.224 360.429
590.074 371.116
592.851 381.809
595.560 392.507
598.203 403.211
600.783 413.919
603.304 424.632
605.768 435.349
608.177 446.070
610.534 456.794
612.841 467.522
615.101 478.254
617.314 488.988
619.483 499.725
621,610 510.465
623.696 521.208
625.743 531.953
627.752 542.700
629.724 553.449
631.661 564.201
633.565 574.955
635.435 585.710
637.274 596.467
639.082 607.226
(г)
'°@)= 1140.052 кДж-моль
-577.7224
-277.7048
-178.5557
-177.3077
-126.9672
-96.6995
-76.4885
-62.0336
-51.1811
-42.7329
-35.9693
-30.4317
-25 8144
-21.9054
-18.5531
-15.6466
-13.1022
-10.8562
-8.8590
-7.0714
-5.4619
-4.0052
-2.6805
-1.4705
-.3610
.6601
1.6029
2.4762
3.2874
4.0429
4.7482
5.4082
6.0272
6.6089
7.1565
7.6729
8.1609
8.6225
9.0601'
9.4753
9.8698
10.2452
10.6029
10.9440
11.2697
11.5810
11.8788
12.1641
12.4375
12.6999
12.9518
13.1939
13.4268
13.6509
13.8667
14.0748
14.2755
14.4692
14.6562
14.8370
15.0117
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300 /
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
400Q
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 407
-1
'л
с:
_ о
i X
* j/ Л
i о о
Щ о S
т
¦¦ х " L
-. © *
? 2 Я S
* II "^ »-Н
2 " — гч
Я S » °°.
11 с * ?
о* •. м
В ас «о
% оВ
**ч О
< ^
+
1
с- 'л
2 1
¦ А
ГЧ
+ 7
со i Я
° Й о
55 "\. S
ой V
о  (-,
н 7 v
S „+ §
I i f
c-i ° °
On ^* ^
он *""
»-« 00
S 6
II +
0
0
196

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2иОО
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
БРОМДИИОДМЕТАН CHBrI2
К°(Т)= р(С)р(Н)р(
С°(Т)
п
У
51.077
63.909
73.629
73.786
80.945
85.949
89.520
92.195
94.297
96.010
97.439
98.648
99.680
100.566
101.332
101.995
102.573
103.078
103.521
103.912
104.256
104.562
104.835
105.078
105.296
105.492
105.669
105.829
105.974
106.106
106.226
106.336
106.436
106.528
106.613
106.692
106.764
106.831
106.893
106.951
107.005
107.055
107.101
107.145
107.186
107.224
107.260
107.294
107.325
107.355
107.383
107.410
107.435
107.459
107.481
107.503
107.523
107.542
107.560
107.578
107.594
Ф°(Г)
Дж -К .моль
247.360
278.361
299.280
299.625
316.464
330.635
342.958
353.898
363.753
372.730
380.981
388.618
395.730
402.388
408.647
414.555
420.150
425.463
430.524
430.354
439.975
444.404
448.657
452.748
456.688
460.488
464.158
467,707
471.143
474.472
477.701
480.836
483.882
486.845
489.728
492.536
495.273
497.942
500.546
503.089
505.573
508.002
510.377
512.701
514.976
517.204
519.387
521.526
523.624
525.682
527.702
529.684
531.631
533.543
535.422
537.269
539.085
540.870
542.627
544.356
546.057
*>.pW
S°(T)
288.052
327.609
355.028
355.484
377.752
396.385
412.388
426.397
438.850
450.059
460.251
469.596
478.225
486.239
493.721
500.739
507.337
513.571
519.475
525.083
530.422
535.516
540.387
545.052
549.529
553.832
557.973
561.964
565.815
569.536
573.135
576.620
579.998
583.275
586.456
589.548
592.554
595.480
598.330
601.108
603.816
606.459
609.039
611.560
614.024
616.433
618.790
621.097
623.356
625.569
627.739
629.865
631.951
633.998
636.007
637.979
639.916
641.820
643.690
645.529
647.337
(г)
М(СНВг12) ДгЯ°@)= 1080.349
Я°(Г)-//°@)
кДж . моль"
4.069
9.850
16.621
16.758
24.515
32.875
41.658
50.749
60.078
69.596
79.270
89.076
98.994
109.007
119.103
129.270
139.499
149.782
160.113
170.485
180.894
191.335
201.805
212.301
222.820
233.359
243.918
254.493
265.083
275.687
286.303
296.932
307.570
318.218
328.876
339.541
350.214
360.894
371.580
382.272
392.970
403.673
414.381
425.093
435.810
446.530
457.254
467.982
478.713
489.447
500.184
510.924
521.666
532.411
543.158
553.907
564.658
575.411
586.166
596.924
607.682
lgAT°(r)
-546.5102
-262.1288
-168.1410
-166.9580
119.2352
-90.5396
-71.3772
-57.6715
-47.3810
-39.3701
-32.9564
-27.7055
-23.3273
-19.6209
-16.4426
-13.6871
-11.2752
-9.1464
-7.2536
-5.5595
-4.0345
-2.6544
-1.3994
-.2532
.7977
1.7647
2 6576
3.4846
4.2527
4.9681
5:6359
6.2609
6.8469
7.3976
7.9161
8.4051
8.8671
9.3042
9.7185
10.1117
10.4853
10.8408
11.1795
11.5026
11.8111
12.1060
12.3882
12.6584
12.9175
13.1661
13.4048
13.6342
13.8549
14.0674
14.2720
14.4693
14.6595
14.8432
15.0206
15.1920
15.3578
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900,
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
•
7
-. о
1
§ i
L
% 8
_ tri
s - *
s s ¦ «¦
2 *?
и s
о п
>. f
*^t О
<J ч
m |Э
Ч §
*"* •
«+ «
'ч •
m ас
§ а
>о *
о Ч
1 ?
X +
? м
*¦" i>
<s *•«
+ 1
СО П*1
о <«¦
6 -1
Г1» fN
(О W)
II +
?
0
ца 408
7
1
1
^-"
i
О
5
«о
II
°*?
V
V
8
"О
V*
о .
II
197

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
50.069
67.125
78.249
78.425
86.405
91.936
95.769
98.467
100.407
101.836
102.912
103.739
104.387
104.903
105.320
105.661
105.943
106.180
106.379
106.549
106.696
106.822
106.932
107.029
107.113
107.189
107.255
107.315
107.368
107.417
107.460
107.499
107.535
107.568
107.598
107.625
107.650
107.673
107.695
107.714
107.733
107.750
107.766
107.780
107.794
107.807
107.819
107.830
107.841
107.851
107.860
107.869
107.877
107.885
107.892
107.899
107.906
107.912
107.918
107.924
107.929
ДИФТОРБРОМИОДМЕТАН CF2BrI
K°(r)=P(C).pV
Ф°(Г)
Дж • К . моль
234.174
264.395
285.532
285.885
303.222
317.966
330.870
342.374
352.765
362.243
370.959
379.027
386.537
393.562
400.160
406.380
412.263
417.844
423.152
428.212
433.047
437.675
442.114
446.379
450.482
454.435
458.249
461.933
465.497
468.947
472.290
475.533
478.682
481.742
484.717
487.614
490.434
493.183
495.864
498.480
501.035
503.530
505.969
508.355
510.689
512.974
515.211
517.403
519.552
521.658
523.725
525.753
527.743
529.698
531.617
533.504
535.358
537.180
538.973
540.736
542.471
)-р(Вг)-рA)-р
5°(Г)
273.036
313.512
342.510
342.994
366.717
386.630
403.752
418.729
432.011
443.924
454.712
464.561
473.616
481.993
489.783
497.061
503.889
510.320
516.394
522.151
527.620
532.828
537.800
542.556
547.113
551.487
555.692
559.741
563.645
567.414
571.056
574.580
577.994
581.303
584.515
587.634
590.667
593.617
596.488
599.286
602.013
604.674
607.270
609.806
612.284
614.707
617.077
619.395
621.666
623.890
626.068
628.204
630.299
632.354
634.371
636.351
638.295
640.205
642.081
643.926
645.740
-№ВГ1) Д,Я<
Н°(Г)-Н°@)
кДж • моль
3.886
9.823
16.988
17.133
25.398
34.332
43.729
53.448
63.397
73.513
83.753
94.087-
104.495
114.960
125.472
136.022
146.602
157.209
167.837
178.484
189.146
199.822
210.510
221.208
231.915
242.630
253.352
264.081
274.815
285.555
296.298
307.046
317.798
328.553
339.312
350.073
360.837
371.603
382.371
393.142
403.914
414.688
425.464
436.241
447.020
457.800
468.581
479.364
490.147
500.932
511.717
522.504
533.291
544.079
554.868
565.658
576.448
587.239
598.030
608.822
619.615
(г)
@) = 1404
lgAT°G-)
-713.9389
-344.9469
-223.1013
-221.5682
-159.7446
-122.5940
-97.8007
-80.0780
-66.7791
-56.4317
-48.1516
-41.3757
-35.7284
-30.9495
-26.8531
-23.3027
-20.1960
-17.4547
-15.0180
¦12.8378
-10.8756
-9.1003
-7.4863
-6.0126
-4.6618
-3.4189
-2.2717
-1.2094
-.2229
.6955
1.5528
2.3548
3.1067
3.8131
4.4780
5.1049
5.6971
6.2573
6.7880
7.2916
7.7700
8.2251
8.6586
9.0720
9.4666
9.8437
10.2045
10.5499
10.8810
11.1986
11.5035
11.7965
12.0782
12.3494
12.6105
12.8622
13.1048
13.3390
13.5652
13.7837
13.9949
.076 кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
1
'а
-я О
I S
А
К
О S
2 (=1
к °
й 7
гг. 2 II
5 i Q
°°. || -О
CN О ' °°
¦^ "Н 1"Г
оз —"
У- ь.
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1
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+ 1
ГО
ЧО
оо X
? R
оо ^^
о т><
о «
1 о
Я vi
Я +
ГО М^
3 -
1—1 " ¦
181 +
38*-
ОО 00
оо го
•О ¦"-<
II +
0
е
ц а 409
i
А
о
.
1
а
i
00
¦>*
If
ч
-ч
я
§
S
V
V
...
"о
к,
II
198

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(т-)
57.843
75.564
85.714
85.867
92.519
96.817
99.654
101.586
102.945
103.930
104.662
105.221
105.655
105.999
106.276
106.501
106.688
106.843
106.974
107.086
107.182
107.265
107.337
107.399
107.455
107.504
107.547
107.586
107.621
107.652
107.681
107.706
107.729
107.751
107.770
107.788
107.804
107.819
107.833
107.846
107.858
107.869
107.879
107.889
107.897
107.906
107.914
107.921
107.928
107.934
107.940
107.946
107.951
107.956
107.961
107.966
107.970
107.974
107.978
107.982
107.985
ФТОРДИБРОМИОДМЕТАН CFBr2I (г)
(Г)= p{C)-p(F)-p2
Ф°G-)
Дж - К . моль
245.116
278.786
302.490
302.884
322.161
338.381
352.436
364.855
375.988
386.080
395.311
403.816
411.701
419.051
425.935
432.407
438.514
444.295
449.783
455.006
459.989
464.753
469.315
473.694
477.902
481.952
485.857
489.625
493.267
496.789
500.201
503.509
506.718
509.835
512.865
515.812
518.681
521.476
524.200
526.858
529.452
531.984
534.460
536.879
539.246
541.562
543.829
546.050
548.226
550.360
552.452
554.504
556.518
558.495
560.437
562.344
564.218
566.061
567.672
569.654
571.407
(Br)-p(I)
S°(T)
287.672
333.957
366.164
366.695
392.378
413.519
431.439
446.955
460.614
472.799
483.788
493.791
502.966
511.437
519.303
526.643
533.523
539.995
546.106
551.893
557.388
562.620
567.612
572.384
576.956
581.344
585.561
589.620
593.534
597.311
600.961
604.492
607.912
611.228
614.444
617.569
620.605
623.560
626.435
629.236
631.967
634.630
637.230
639.768
642.249
644.673
647.045
649.366
651.638
653.864
656.044
658.182
660.278
662.334
664.352
666.333
668.279
670.190
672.068
673.914
675.728
p-'CCFB^I) L
H°(T)-H°
кДж . моль
4.256
11.034
18.984
19.143
28.087
37.569
47.402
57.470
67.700
78.046
88.478
98.973
109.518
120.101
130.715
141.355
152.014
162.691
173.382
184.085
194.799
205.521
216.251
226.988
237.731
248.479
259.231
269.988
Л Л f\ *m л л
280.748
291.512
302.279
313.048
323.820
334.594
345370
356.148
366.928
377.709
388.491
399.275
410.060
420.847
431.634
442.423
453.212
464.002
474.793
485.585
496.377
507.170
517.964
528.758
539.553
550.348
561.144
571.941
582.737
593.535
604.332
615.130
625.929
\rH°@)= 1183
@)
-l
o
-598.5539
-287.2638
-184.5029
-183.2101
-131.0908
-99.7835
-78.8966
-63.9704
-52.7725
-44.0614
-37.0917
-31.3887
-26.6360
-22.6142
-19.1668
-16.1789
-13.5643
-11.2572
-9.2062
-7.3709
-5.7190
-4.2242
-2.8651
-1.6241
-.4863
.5607
1.5272
2.4223
3.2536
4.0278
4.7504
5.4266
6.0606
6.6564
7.2172
7.7460
8.2456
8.7183
9.1662
9.5912
9.9951
10.3793
10.7453
11.0944
11.4277
11.7462
12.0510
12.3428
12.6226
12.8909
13.1486
13.3963
13.6344
13.8636
14.0844
14.2972
14.5024
14.7005
14.8918
15.0766
15.2553
.873 кДж • моль
T
К
100
200
298.15
300
400
500
600
700
800
900 '
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
збоо
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б
§
О
S и
m о
5 —"
и.
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0
ч^
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1 .
И -
1 '*
о "=f
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Я.
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V
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ЧГ
1
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II
199

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
58.636
77.291
87.126
87.271
93.573
97.638
100.311
102.121
103.386
104.298
104.974
10S.487
105.884
106.198
106.450
106.655
106.825
106.966
107.085
107.186
107.272
107.347
107.412
107.469
107.519
107.563
107.602
107.637
107.668
107.697
107.722
107.745
107.766
107.785
107.802
107.818
107.833
107.847
107.859
107.871
107.881
107.891
107.900
107.909
107.917
107.924
107.931
107.938
107.944
107.950
107.955
107.960
107.965
107.970
107.974
107.978
107.982
107.986
107.989
107.992
107.996
ФТОРБРОМДИИОДМЕТАН CFBrI2 (г)
Л'°(Г)= p(C)-p(F)-p(Br)-p2(I)-p(CFBrl2) Arh
Ф°(П
S°(T)
Дж • К~' .моль
249.988
284.144
308.280
308.682
328.300
344.779
359.034
371.612
382.875
393.073
402.393
410.974
418.925
426.332
433.265
439.781
445.927
451.743
457.263
462.515
467.523
472.311
476.895
481.293
485.520
489.588
493.508
497.291
500.946
504.482
507.906
511.225
514.445
517.572
520.611
523.567
526.445
529.248
531.980
534.644
537.245
539.785
542.266
544.692
547.064
549.386
551.658
553.884
556.065
558.203
560.300
562.356
564.374
566.356
568.301
570.213
572.091
573.936
575.751
577.536
579.292
293.050
340.274
373.124
373.663
399.699
421.049
439.103
454.711
468.435
480.667
491.692
501.723
510.919
519.407
527.287
534.638
541.528
548.008
554.125
559.918
565.418
570.654
575.649
580.425
585.000
589.390
593.610
597.671
601.586
605.365
609.016
612.549
615.970
619.287
622.504
625.630
628.667
631.622
634.498
637.300
640.031
642.G95
645.295
647.834
650.315
652.740
655.112
657.434
659.706
661.932
664.113
666.251
668.347
670.404
672.422
674.404
676.349
678.260
680.138
681.984
683.800
Н°(Т)-Н°@)
кДж • моль
4.306
11.226
19.333
19.494
28.560
38.135
48.041
58.169
68.448
78.834
89.299
99.824
110.393
120.998
131.631
142.286
152.960
163 650
174.353
185.066
195.789
206.520
217.259
228.003
238.752
249.506
260.264
271.026
281.792
292.560
303.331
314.104
324.880
335.657
346.437
357.218
368.000
378.784
389.570
400.356
411.144
421.932
432.722
443.512
454.304
465.096
475.889
486.682
497.476
508.271
519.066
529.862
540.658
551.455
562.2е 2
573.050
583.848
594.646
605.445
616.244
627.043
о
-567.2982
-271.6381
-174.0365
-172.8086
-123.3079
-93.5745
-73.7384
-59.5638
-48.9300
-40.6582
-34.0404
-28.6258
-24.1138
-20.2961
-17.0240
-14.1883
-11.7072
-9.5182
-7.5725
-5.8316
-4.2649
-2.8473
-1.5587
-.3820
.6966
1.6890
2.6051
3.4535
4.2413
4.9749
5.6597
6.3004
6.9012
7.4657
7.9971
8.4982
8.9715
9.4194
9.8438
10.2466
10.6293
10.9934
11.3403
11.6712
11.9870
12.2890
12.5779
12.8545
13.П98
13.3742
13.6186
13.8534
14.0793
14.2967
14.5061
14.7080
14.9027
15.0906
15.2721
15.4475
15.6171
.124 кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 411
1
1
А
О
&
m о
" uT
5? ^
СО
в
0
_+
к
ч Г
СЧ Й
'х -'
)? '
ГО
ц а
о ">
1 ё
? +
8 2
к 1
«о г*
ГЧ О
я °°.
II +
^,
0
©
'к
о
к
О
О
О
>х
1
II
я
«о
00
|-Г
—•
0
§
1
*
ОС
¦*.
ГО
•Л
II
о§
to
2
о
S
V
V
§
'о
tl.
II
200

Класс точносги
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
J6.328
77.176
88.480
88.640
95.275
99.188
101.609
103.186
104.261
105.023
105.581
106.001
106.324
106.578
106.782
106.947
107.083
107.196
107.291
107.371
107.440
107.500
107.552
107.597
107.637
107.672
107.703
107.731
107.756
107.778
107.798
107.816
107.833
107.848
107.862
107.875
107.886
107.897
107.907
107.916
107.924
107.932
107.939
107.946
107.953
107.959
107.964
107.969
107.974
107.979
107.983
107.987
107.991
107.994
107.998
108.001
108.004
108.007
108.010
108.012
108.015
ДИХЛОРБРОМИОДМЕТАН СС1
К°(Т) = РЮ-Р2(С\
Ф°(Г)
Дж . К . моль"
241.346
274.160
297.793
298.189
317.657
334.129
348.432
361.076
372.407
382.671
392.051
400.687
408.687
416.139
423.113
429.666
435.845
441.692
447.239
452.516
457.548
462.358
466.962
471.379
475.622
479.706
483.641
487.438
491.107
494.655
498.091
,501.420
504.651
507.788
510.836
513.801
516.686
519.497
522.237
524.909
527.516
530.062
532.550
534.982
537.360
539.687
541.965
544.196
546.382
548.524
550.625
552.686
554.709
556.694
558.643
560.558
562.440
564.289
566.108
567.896
569.655
S°(T)
1
282-.358
328.668
361.788
362.335
388.831
410.548
428.862
444.652
458.505
470.832
481.927
492.011
501.249
509.769
517.676
525.048
531.955
538.451
544.580
550.384
555.893
561.136
566.138
570.920
575.500
579.895
584.119
588.184
5!)«> 1 v?
595.884
599.538
603.073
606.496
609.815
613.035
616.162
619.201
622.157
625.034
627.837
630.570
633.235
635.836
638.376
640.857
643.283
645.656
647.978
650.251
652.478
654.659
656.798
658.895
660.952
662.970
664.952
666.898
668.810
670.688
672.535
674.350
СС12Вг1) А Н°
Я°(Г)-Я°@)
кДж . моль""
4.101
10.902
19.080
19.244
28.470
38.209
48.258
58.503
68.879
79.345
89.877
100.457
111.074
121.719
132.388
143.074
153.776
164.490
175.214
185.948
196.688
207.435
218.188
228.946
239.707
250.473
261.241
272.013
282.788
293.564
304.343
315.124
325.906
336.690
347476
358.263
369.051
379.840
390.630
401.421
412.213
423.006
433.800
444.594
455.389
466.184
476.980
467.777
498.574
509.3?2
520.170
530.969
541.768
552.567
563.366
574.166
584.966
595.767
606.568
617.369
628.170
2Вг1 (г)
@)= 1105.503
о
-557.5453
-266.6886
-170.6744
-169.4667
-120.7747
-91.5267
-72.0126
-58.0658
-47.6012
-39.4596
-32.9448
-27.6136
-23.1704
-19.4105
-16.1875
-13.3941
-10.9498
-в.'^ЭЗО
-6.8758
-5.1604
-3.6165
-2.2196
-.9.Э7
.2098
1.2727
2.2507
3.1534
3.9893
4.7656
5.4883
6.1629
6.7941
7.3858
7.9417
8.4650
8.9584
9.4244
9.8653
10.2831
10.6794
11.0560
11.4143
11.7555
12.0809
12.3916
12.6885
12.9725
13.2444
13.5051
13.7551
13.9952
14.2259
14.4478
14.6613
14.8669
15.0t.51
15.2562
15.4406
15.6187
15.7908
15.9572
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
•
'л
_ О
ц ' Л
О *
2 <=t
X
?ё О
* §
00 о
о
о »
Г-; || ^
00 о g
II ил ™
-^ CQ
у, 0 '
о ^
Г? л
•"*ч 0
+
-
к
? ¦
t-4 Л
+ о
" S
X -'
^ i
о ?g
о Ч
о «
1 ON
ч S
с
00 +
о N
гч *
Г- 00
О 00
f—I *
^ 1
• vO
—t "
11 +
О
a 412
i
л
4
о
1
. ¦
r-
o
•
II
og
to
я
о
.о
ЧО
V
f^
V
¦ о
'о
II
201

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
I960
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3360
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4960
5600
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°(
суп
Р
ХЛОРДИБРОМИОДМЕТАН (
Г) = р(С)-р(а).р2(Вг).рA).р~1(СС1Вг21) Д, h
Ф°(Г)
S°(T)
Дж -К .моль
60.451
80.060
90.460
90.607
96.652
100.182
102.350
103.756
104.710
105.386
105.879
106:250
106.536
106.760
106.939
107.084
107.204
107.304
107.387
107.458
107.519
107.571
107.617
107,657
107.691
107.722
107.750
107.774
107.796
107.816
107.833
107,849
107.864
107.877
107.889
107.901
107.911
107.920
107.929
107.937
107.944
107.951
107.958
107.963
107.969
107.974
107.979
107.984
107.988
107.992
107.996
107.999
108.003
108.006
108.009
108.012
108.014
108.617
168.619
108.021
108.024
247.165
281.755
306.494
306.907
327.108
344.093
358.771
371.701
383.256
393.701
403.231
411.991
420.098
427.641
434.693
441.315
447.556
453.457
459.053
464.374
469.446
474.291
478.928
483.375
487.646
491.756
495.715
499.534
503.223
506.790
510.244
513.591
516.837
519.988
523.051
526.029
528.927
531.750
534.501
537.184
539.801
542.357
544.854
547.294
549.681
552.016
554.302
556.540
558.733
560.883
562.990
565.057
567.086
569.077
571.032
572.952
574.839
576.694
578.517
580.310
582.073
290.256
339.074
373.164
373.724
400.698
422.678
441.150
457.040
470.961
483.335
494.465
504.575
513.833
522.369
530.288
537.671
544.586
551.088
557.224
563.032
568.546
573.793
5Z&.798
583.583
588.165
592.562
596.788
600.855
604.775
608.558
612,213
615.749
619.173
622.493
625.713
628.841
631.881
634.838
637.716
640.520
643.252
645.918
648.519
651.060
653.542
655.968
658.341
660664
662.937
665.164
667.345
669.484
671.581
673.639
675.657
677.639
679.585
681.497
683.376
685.223
687.038
Я°(Г)-#°@)
кДж ¦ моль
4.309
11.464
19.878
20.045
29.436
39.293
49.427
59.738
70.164
80.670
91.235
101.842
11,2.482
123.147
133.832
144.534
155.248
165.974
176.709
187.451
198.200
208.954
219.714
230.478
241.245
252.016
262.789
273.566
284.344
295.125
305.907
316.691
327.477
338.264
349.052
359.842
370.632
381.424
392.216
403.010
413.804
424.599
435.394
446.190
456.987
467.784
478.581
489.380
500.178
510.977
521.776
532.576
543.376
554.177
564.977
575.779
586.580
597.381
608.183
618.985
629.788
СС1Вг21 (г)
Г°@)= 1041.933
]еК°(Т)
-524.1149
-249.9538
-159.4656
-158.3275
-112.4467
-84.8936
-66.5144
-53.3817
-43.5299
-35.8663
-29.7349
-24.7179
-20.5369
-16.9989
-13.9662
-11.3377
-9.0375
-7.0078
-5.2034
-3.5887
-2.1354
-.8202
.3756
1.4675
2.4687
3.3899
4.2404
5.0281
5.7596
6.4409
7.0769
7.6720
8.2300
8.7543
9.2479
9.7134
10.1531
10.5692
10.9635
11.3376
11.6932
12.0314
12.3537
12.6610
12.9545
13.2349
13.5033
13.7602
14.0066
14.2429
14.4698
14.6879
14.8977
15.0995
15.2940
15.4814
15.6622
15.8366
16.0051
16.1679
16.3253
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
•
Та
i
g
2
00
t? m
Tf II
Я о
ii С
«
о
+
-
00
00
+
г*
1
'н
о
.0095'
о
1
X
с-

г-
о
•"*
is
с*}
II
Р
О
блиц
о
2
¦3
'000
«о
II
¦ оо'
ГЦ
ьГ
с*
аэ
я
В
О
'в
§
2
'а
»>
о
+
ч
го
(S
1
S
+
а 413
т
§
Д
ЧО
1-4
о 3
я
о
VO
V
V
8
¦""
к.
II
а.
202

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сг)
ХЛОРБРОМДИИОДМЕТАН СС1Вг12 (г)
[7-)=р(С)р(С1).
Ф°(П
p(Bi).p2(l)-p~l(COBil2) Arh
Дж • К • моль
62.694
81.611
91.647
91.787
97.504
100.801
102.813
104.111
104.991
105.612
106.065
106.406
106.667
106.873
107.037
107.170
107.280
107.371
107.447
107.512
107.568
107.616
107.657
107.694
107.726
107.754
107.779
107.801
107.821
107.839
107.855
107.870
107.883
107.895
107.907
107.917
107.926
107.935
107.942
107.950
107.957
107.963
107.969
107.974
107.979
107.984
107.988
107.993
107.996
108.000
108.004
108.007
108.010
108.013
108.016
108.018
108.021
108.023
108.025
108.027
108.029
252.606
288.457
313.884
314.307
334.960
352.259
367.169
380.275
391.969
402.527
412.148
420.985
429.157
436.756
443.858
450.522
456.801
462.735
468.361
473.710
478.806
483.673
488.331
492.797
497.085
501.211
505.184
509.017
512.719
516.298
519.763
523.120
526.376
529.536
532.608
535.594
538.500
541.330
544.088
546.777
549.401
551.963
554.466
556.912
559.303
561.644
563.934
566.177
568.374
570.528
572.640
574.711
576.743
578.737
580.696
582.620
584.510
586.368
588.194
589.990
591.756
Я°(Г>-Я°@)
кДж • моль
297.471 4.487
347.560 11.821
382.202 20.369
382.769 20.539
410.036 30.030
432.179 39.960
450.749 50.148
466.702 60.499
480.665 70.957
493.069 81.489
504.222 92.074
514.347 102.698
523.618 113.352
532.164 124.030
540.090 134.725
547.480 145.436
554.400 156.159
560.907 166.891
567.046 177.632
572.857 188.380
578.373 199.134
583.623 209.894
588.630 220.657
593.416 231.425
598.000 242.196
602.399 252.970
606.625 263.747
610.693 • 274.525
614.614 285.307
618.398 296.089
622.054 306.874
625.591 317.661
629.016 328.448
632.336 339.237
635.557 350.027
638.685 360.819
641.725 371.611
644.683 382.404
647.561 393.197
650.365 403.992
653.098 414.788
655.764 425.583
658.366 436.380
660.906 447.177
663.389 457.975
665.815 468.773
668.189 479.572
670.511 490.371
672.785 501.170
675.012 511.970
677.194 522.770
679.332 533.571
681.430 544.372
683.487 555.173
685.506 565.974
687.488 - 576.776
689.435 587.578
691.346 598.380
693.225 609.182
695.072 619.985
696.887 630.788
Г°@) = 982.327
-492.9630
-234.4352
-149.1077
-148.0345
-104.7719
-78.7919
-61.4626
-49.0805
-39.7922
-32.5671
-26.7869
-22.0577
-18.1168
-14.7824
-11.9244
-9.4477
-7.2807
-5.3688
-3.6693
-2.1488
-.7803
.4578
.1.5834
2.6112
3.5533
4.4202
5.2205
5.9615
6.6498
7.2907
7.8889
8.4487
8.9735
9.4667
9.9310
10.3688
10.7825
11.1739
11.5447
11.8967
12.2312
12.5494
12.8526
13.1418
13.4179
13.6818
13.9343
14.1762
14.4081
14.6306
14.8442
15.0495
15.2470
15.4372
15.6203
15.7968
15.9671
16.1315
16.2902
16.4436
16.5919
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 414
— о
'л *
с:
х 7
a s g
х ч s
t^ о .
г- -1 1
о о » ^
ас, ?> • v>
~ О 00 QQ
,- °^ г-
w г* U ЧО .
Й н? "
О 02 "^
pj -н 0 Of
w C_) ^3
о У,
а: о
+
-
ё
¦ о
m —
D 'л
+ §
г*.
i * I
1 ъ Y,
я 1 v
- ? §
? (N II
ЧО <N
II +
0
203

Класс точности
VI-F
Г
К
юо-
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
АГ°
С°р(Т)
42.868
56.607
67.360
67.538
75.851
81.897
86.305
89.623
92.215
94.301
96.018
97.451
98.661
99.690
100.571
101.329
101.985
102.556
103.054
103.492
103.877
104.218
104.521
104.790
105.032
105.248
105.443
105.620
105.779
105.924
106.056
106.177
106.287
106.388
106.481
106.567
106.646
106.720
106.788
106.851
106.909
106.964
107.015
107.062
107.107
107.149
107.188
107.224
107.259
107.292
107.322
107:351
107.379
107.404
107.429
107.452
107.474
107.495
107.515
107.534
107.552
ФТОРБРОМИОДМЕТАН CHFBrI
(Т) =p(C)-p(H)-p(F)
Ф°(Г)
Дж . К~' . моль
229.792
257.192
275.656
275.963
291.020
303.863
315.162
325.293
334.495
342.935
350.736
357.992
364.779
371.154
377.166
382.856
388.257
393.399
398.304
402.994
407.488
411.800
415.947
419.940
423.789
427.507
431.100
434.577
437.945
441.211
444.382
447.462
450.456
453.370
456.207
458.972
461.667
464.297
466.864
469.372
471.823
474.220
476.564
478.859
481.106
483.307
485.464
487.580
489.654
491.690
493.687
495.649
497.576
499.468
501.329
503.158
504.956
506.725
508.465
510.178
511.864
р(В:).рA).р~
5°(Л
266.388
300.475
325.166
325.583
346.212
363.824
379.165
392.729
404.873
415.859
425.886
435.107
443.639
451.578
458.999
465.964
472.525
478.725
484.602
490.186
495.504
500.581
505.436
510.088
514.553
518.845
522.977
526.960
С rt Л П П А
530.804
534.519
538.112
541.592
544.964
548.236
551.414
554.502
557.505
560.428
563.275
566.049
568.756
571.396
573.974
576.493
578.955
581.362
583.718
586.023
588.281
590.493
592.661
594.787
596.871
598.917
600.925
602;896
604.832
606.735
608.605
610.443
612.250
'(CHFB.) Д,Я°
н°т-н°(о)
кДж • моль"
3.660
8.657
14.761
14.886
22.077
29.980
38.402
47.205
56.302
65.632
75.150
84.826
94.633
104.552
114.566
124.662
134.828
145.056
155.337
165.665
176.034
186.439
196.876
207.342
217.833
228.347
238.882
249.435
260.005
270.591
281.190
291.801
302.425
313.059
323.702
334.355
345.015
355.684
366.359
377.041
387.729
398.423
409.122
419.826
430.504
441.247
451.964
462.684
473.408
484.136
494.867
505.600
516.337
527.076
537.818
548.562
559.308
570.057
580.807
591.560
602.314
(г)
@) = 1335
о
-680.2542
-328.9611
-212.8654
-211.4040
-152.4517
-117.0004
-93.3246
-76.3896
-63.6740
-53.7748
-45.8492
-39.3604
-33.9499
-29.3696
-25.4420
-22.0367
-19.0562
-16.4255
-14.0866
-11.9933
-10.1089
-8.4036
-6.8531
-5.4372
-4.1390
-2.9444
-1.8416
-.8203
.1282
1.0114
1.8358
2.6072
3.3305
4.0100
4.6497
5.2529
5.8227
6.3617
6.8725
7.3572
7.8176
8.2557
8.6730
9.0709
9.4508
9.8139
10.1612
10.4938
10.8126
11.1184
11.4121
11.6942
11.9656
12.2267
12.4782
12.7206
12.9543
13.1799
13.3977
13.6082
13.8117
.787 кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл
1
\«
Е
•
а
X
с-
о
00 О
Ц '
оо "
Я о
и С
§ т?
оа
и.
и
о
>¦
1
оо 7
Г- ' j»
чо В
оо д
" S
1
1 .
(N Я
00 m
s й
О оч
| 2
х +
•5 <ч
00 «5
JQ m
t-J ЧО
+ |
О\ X
2.70*
.098'
m г-
II +
С
0
¦ **
и
i
•
о
8
о
(S
7
II
Я
¦л
оо'
гч
и
>д"
(Я
tL
'(CHI
11
ч
ца 415
т
§
i
.
А
чо
II
0 3
to
Я
о
VO
V
Ь-
V
8
«о
»'"
о
^.
II
204

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°
С°р(Т)
47.515
61.1.24
72.386
72.554
80.129
85.367
89.087
91.865
94.042
95.810
97.279
98.519
99.575
100.480
101.260
101.935
102.522
103.035
103.484
103.879
104.228
104.537
104.812
105.058
105.278
105.476
105.654
105.815
105.961
106.094
106.215
106.326
106.427
106.520
106.606
106.685
106.757
106.825
106.887
106.945
106.999
107.050
107.097
107.140
107.181
107.220
107.256
107.290
107.322
107.352
107.380
107.407
107.432
107.456
107.479
107.500
107.520
107.540
107.558
107.575
107.592
ХЛОРБРОМИОДМЕТАН
(Г) =р(С)р(Н)-р(С1)-
Ф°(П
Дж . К . моль™1
235.200
264.454
284.430
284.761
301.012
314.789
326.828
337.555
347.245
356.089
364.231
371.778
378.815
385.407
391.611
397.469
403.021
408.296
413.322
418.122
422.716
427.120
431.350
435.419
439.340
443.122
446.776
450.310
453.731
457.047
460.264
463.387
466.423
469.375
472.249
475.048
477.776
480.437
483.034
485.569
488.047
490.469
492.838
495.156
497.425
499.647
501.825
503.960
506.053
508.106
510.121
512.100
514.042
515.950
517.826
519.669
521.481
523.263
525.016
526.742
528.440
Р(Вг).рA).р-'
S°(T)
273.540
311.206
337.984
338.432
360.409
378.887
394.798
408.749
421.163
432.345
442.518
451.850
460.468
468.475
475.951
482.961
489.559
495.790
501.692
507.298
512.635
517.728
522.598
527.262
531.738
536.040
540.180
544.171
548.022
551.743
555.341
558.826
562.203
565.480
568.661
571.752
574.759
577.685
580.534
583.312
586.020
588.663
591.243
593.763
596.227
598.636
600.993
603.300
605.559
607.772
609.942
612.068
614.154
616.201
618.210
620.182
622.119
624.022
625.893
627.732
629.540
(CHClBrI)
Н°(Т)-Н
CHClBrI (г)
Дг//°@)= 1199
"@)
кДж . моль"
3.834
9.351
15.967
16.101
23.759
, 32.049
40.782
49.835
59.135
68.630
78.287
88.078
97.985
107.989
118.076
128.237
138.461
148.739
159.065
169.434
179.840
190.278
200.746
211.240
221.757
232.294
242.851
253.425
264.014
274.616
285.232
295.859
306.497
317.144
327.801
338.465
349.137
359.817
370.502
381.194
391.891
402.594
413.301
424.013
434.729
445.449
456.173
466.900
477.631
488.364
499.101
509.840
520.582
531.327
542.073
552.822
563.573
574.327
585.081
595.838
606.596
о
-608.7648
-293.2624
-189.0077
-187.6955
-134.7647
-102.9377
-81.6832
-66.4802
¦55.0646
-46.1770
-39.0611
-33.2348
-28.3766
-24.2636
, -20.7365
-17.6784
-15.0016
-12.6390
-10.5382
-8.6580
-6.9655
-5.4338
-4.0410
-2.7691
-1.6029
-.5298
.4609
1.3784
2.2305
3.0240
3.7647
4.4578
5.1076
5.7182
6.2929
6.8349
7.3469
7.8312
8.2902
8.7257
9.1395
9.5332
9.9081
10.2658
10.6072
10.9334
11.2456
11.5445
11.8310
12.1059
12.3698
12.6234
12.8673
13.1020
13.3281
13.5459
13.7560
13.9588
14.1546
14.3438
14.5267
.160 кДж -моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т аб л
_
'л
с?
о
2
•О
'804
= 72.:
">' S
™ Ь
а;
+
i
к _
* 'л
? §
+ т
О m
О г^
о ">.
1 ^
с +
+ 1
оо н
S I
Г"* ОО
ON О
*П «N
U1 W)
II +
о
А
и
"л
§
2
к
§
о
я
00
-
а
и
j
а:
ца 416
~л
S
w*
к
in
\о
¦о
о К
to
я
1
ЧО
V •
V
о
с-
¦л
с
II
205

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
К°
С°(Т)
¦ р
53.438
72.730
83.762
83.928
91.154
95.829
98.917
101.019
102.497
103.568
104.365
104.972
105.444
105.818
106.119
106.364
106.567
106.736
106.878
107.000
107.104
107.193
107.272
107.340
107.400
107.453
107.501
107.543
107.581
107.615
107.645
107.673
107.699
107.722
107.743
107.762
107.780
107.796
107.81
107.825
107.838
107.850
107.861
107.871
107.881
107.890
107.899
107.906
107.914
107.921
107.927
107.934
107.939
107.945
107.950
107.955
107.960
107.964
107.968
107.972
107.976
ФТОРХЛОРБРОМИОДМЕТАН CFClBrI (г)
(Г) =p(C)-p(F)-p(Cl)
Ф°(Г)
Дж • К . моль
238.352
270.028
292.559
292.936
311.447
327.137
340.804
352.929
363.831
373.737
382.814
391.191
398.968
406.225
413.028
419.429
425.474
431.199
436.637
441.816
446.758
451.485
456.014
460.361
464.541
468.565
472.445
476.191
479.812
483.315
486.708
489.999
493.192
496.294
499.309
502.243
505.099
507.881
510.594
513.241
515.824
518.347
520.813
523.224
525.581
527.889
530.149
532.362
534.531
536.657
538.743
540.788
542.796
544.768
546.703
548.605
550.474
552.312
554.1 18
555.895
557.643
•p(Br)-pd)
S°(T)
278.432
322.173
353.427
353.946
379.156
400.036
417.799
433.215
446.806
458.944
469.899
479.876
489.030
497.486
505.339
512.669
519.540
526.006
532.111
537.893
543.384
548.612
553.600
558.371
562.940
567.326
571.541
575.599
579.51 1
583.286
586.935
590.465
593.884
597.199
600.415
603.538
606.574
609.528
612.403
615.203
617.933
620.596
623.195
625.733
628.213
630.638
633.009
635.330
637.602
639.827
642.007
644.144
646.240
648.296
650.314
652.295
654.240
656.151
658.029
659.875
661.689
p-'CCFClBrl)
Н°(Т)-Н°
Д //°@)= 1247.404
@)
кДж . моль"
4.008
10.429
18.148
18.303
27.083
36.449
46.197
56.200
66.380
76.686
87.085
97.553
108.074
1 18.638
129.236
139.860
150.507
161.172
171.853
182.547
193.252
203.967
214.691
225.421
236.159
246.901
257.649
268.401
279.157
289.917
300.680
31 1.446
322.215
332.986
343.759
354.534
365.312
376.090
386.871
397.652
408.436
419.220
430.006
440.792
451.580
462.368
473.158
483.948
494.739
505.531
516.323
527.1 16
537.910
548.704
559.499
570.294
581.090
591.886
602.683
613.480
624.277
-631.9152
-303.9282
-195.6408
-194.2784
-139.3479
-106.3457
-84.3239
-68.5837
-56.7730
-47.5839
-40.2308
-34.2137
-29.1988
-24.9551
-21.3174
¦18.1647
-15.4059
-12.9717
•10.8079
-8.8719
-7.1294
-5.5529
-4.1197
-2.81 1 1
-1.61 15
-.5079
.5109
1.4542
2.3302
3.1459
3.9072
4.6194
5.2871
5.9145
6.5049
7.0617
7.5876
8.0851
8.5564
9.0037
9.4286
9.8328
10.2178
10.5849
10.9354
1 1.2704
11.5908
1 1.8976
12.1917
12.4738
12.7446
13.0049
13.2552
13.4960
13.7280
13.9515
14.1671
14.3751
14.5760
14.7701
14.9578
кДж ¦ моль
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
1
i
J3
к
— о
о ^ .
s <§
1 §
5 ~
S 1 д
t— о QQ
II ^ ^_
G as
U- ~
У ?
"•Ц О
+
m
Tj- _
+ 3
2 ?
о ~<
о "
1 о
с ^
m ГА
"°- 4?
С г-
Z> '
>/ ¦"¦"
о '¦Ч
м +
о
в
а 417
i
х
с
i
о
о в:
to
g4
о
V
V
^>
¦у
1
о
1—'
II
а,
206

Класс точности
I-C
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(л
29.105
29.184
29.801
29.818
30.969
32.179
33.219
34.052
34.705
35.216
35.621
35.945
36.209
36.427
36.609
36.764
36.898
37.014
37.117
37.208
37.291
37.366
37.435
37.499
37.559
37.615
37.669
37.721
37.772
37.823
37.873
37.925
37.978
38.033
38.092
38.155
38.223
38.297
38.378
38.468
38.566
38.675
38.796
38.928
39.074
39.234
39.410
39.601
39.810
40.036
40.281
40.544
40.827
41.129
41.452
41.794
42.157
42.540
42.943
43.365
43.807
СУЛЬФИД УГЛЕРОДА CS (г)
К°(Т)= р(С)-р
Ф°(Г)
"~ 1 "*
Дж • К . моль
149.457
169.615
181.248
181.429
189.868
196.494
201.990
206.709
210.858
214.568
217.928
221.001
223.834
226.464
228.919
231.220
233.388
235.436
237.377
239.223
240.982
242.663
244.271
245.814
247.296
248.722
250.096
251.423
252.704
253.944
255.144
256.308
257.437
258.533
259.600
260.637
261.646
262.631
263.590
264.526
265.440
266.333
267.206
268.060
268.895
269.713
270.515
271.300
272.071
272.827
273.568
274.297
275.013
275.717
276.409
277.090
277.760
278.420
279.070
279.710
280.342
(S).p-(TS)
sV)
1
178.527
198.712
210.456
210.640
219.370
226.412
232.374
237.560
242.152
246.270
250.002
253.413
256.552
259.459
262.166
264.697
267.074
269.315
271.433
273.443
275.353
277.175
278.914
280.580
282.177
283.711
285.188
286.610
ал ¦« АЛЛ
287.983
289.309
290.593
291.835
293.040
294.210
295.346
296.451
297.527
298.575
299.598
300.596
301.571
302.524
303.458
304.372
305.269
306.149
307.013
307.862
308.698
309.521
310.333
311.133
311.923
312.703
313.475
314.239
314.995
315.745
316.488
317.226
317.958
Аг Я°@) = 709.600 кДж ¦ моль '
Я°(Г)-Я°@)
кДж . моль"
2.907 -366.2821
5.819 -180.4054
8.708 -119.0830
8.764 -118.3115
11.801 -87.1994
14.959 -68.4975
18.231 -56.0095
21.596 -47.0770
25.035 -40.3694
28.532 -35.1466
32.075 -30.9642
35.654 -27.5390
39.262 -24.6822
42.894 -22.2630
46.546 -20.1877
50.215 -18.3878
53.898 -16.8117
57.594 -15.4201
61.301 -14.1822
65.017 -13.0739
68.742 -12.0758
72.475 -11.1720
76.215 -10.3499
79.962 -9.5988
83.714 -8.9097
87.473 -8.2754
91.237 -7.6894
95.007 -7.1464
АО 7ОП А ^ jfl 1 Г\
98.782 -6.6419
102.561 -6.1718
106.346 -5.7326
110.136 -5.3215
113.931 -4.9358
117.732 -4.5732
121.538 -4.2316
125.350 -3.9092
129.169 -3.6045
132.995 -3.3161
136.829 -3.0425
140.671 -2.7828
144.523 -2.5359
148.385 -2.3008
152.258 -2.0766
156.144 -1.8628
160.044 -1.6584
163.960 -1.4630
167.892 -1.2759
171.842 -1.0967
175.812 -.9247
179.804 -.7597
183.820 -.6011
187.861 -.4486
191.930 -.3019
196.027 -.1606
200.156 -.0245
204.318 .1068
208.516 .2334
212.751 .3557
217.024 .4738
221.340 .5880
225.698 .6984
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 418
§
с: • 1
о м \я
¦ 1 §
* * S
Ч — -'
? g Д й
5 ? « х
|| " — "*•
§ о °°
с Я "
г" Ч
00 '"¦' о BJ
В и ^
о о
а; о"'
+
i
о
+ т
ё а я
СТ\ Й О
00 ^ О
о S ^
о ^ ^,
1 Z1
н 7 V
о ^
(NX t-
? о и
П °° 22.
II +
0
207

Класс точности
III—D
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4390
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
30.975
39.527
45.483
45.571
49.465
52.255
54.351
55.950
57.181
58.141
58.899
59.507
60.003
60.412
60.754
61.044
61.294
61.511
61.701
61.870
62.022
62.159
62.285
62.401
62.510
62.613
62.711
62.806
62.900
62.994
63.090
63.189
63.293
63.403
63.521
63.648
63.787
63.938
64.103
64.284
64.481
64.696
64.929
65.182
65.455
65.749
66.065
66.401
66.759
67.138
67.538
67.959
68.400
68.860
69.338
69.833
70.345
70.871
71.411
71.962
72.525
ДИСУЛЬФИД УГЛЕРОДА CS2 (г)
К°(Т)= p(C)-f
Ф G")
— 1 ~
Дж • К . моль
167.268
188.441
202.005
202.227
212.952
221.876
229.573
236.370
242.468
248.007
' 253.086
257.776
262.137
266.212
270.036
273.640
277.049
280.281
283.356
286.288
289.089
291.771
294.344
296.817
299.196
301.489
303.703
305.841
307.910
309.914
311.856
313.742
315.572
317.352
319.084
320.770
322.413
324.016
325.579
327.105
328.597
330.055
331.481
332.876
334.243
335.582
336.894
338.181
339.445
340.684
341.902
343.099
344.274
345.431
346.569
347.688
348.791
349.877
350.946
352.000
353.040
2(S)p '(CS2)
S°(T)
1
196.689
22J.785
237.773
238.055
251.733
263.086
272.807
281.311
288.866
295.659
301.825
307.468
312.668
317.488
321.977
326.179
330.127
333.849
337.370
340.712
343.889
346.918
349.813
352.584
355.242
357.796
360.254
362.622
364.908
367.117
369.254
371.324
373.332
375.282
377.176
379.019
380.814
382.564
384.271
385.938
387.569
389.164
390.725
392.256
393.757
395.232
396.680
398.104 .
399.505
400.886
402.247
403.589
404.912
406.220
407.510
408.788
410.051
411.301
412.538
413.762
414.97/
Д #°@)= 1144.84.
Н°(Г)-Н°@)
кДж • моль
2.942 -588.1910
6.469 -287.9267
10.664 -188.8250
10.748 -187.5782
15.512 -137.3021
20.605 -107.0887
25.940 -86.9215
31.459 -72.5023
37.118 -61.6794
42.886 -53.2564
48.740 -46.5145
54.661 -40.9960
60.637 -36.3957
66.659 -32.5020
72.717 -29.1637
78.808 -26.2699
84.925 -23.7374
91.065 -21.5024
97.226 -19.5154
103.405 -17.7374
109.599 -16.1370
115.809 -14.6888
122.031 -13.3721
128.265 -12.1697
134.511 -11.0674
140.767 -10.0531
147.033 -9.1167
153.309 -8.2495
159.595 -7.4441
165.889 -6.6941
172.193 -5.9940
178.507 -5.3388
184.831 -4.7245
191.166 -4.1473
197.512 -3.6039
203.871 -3.0914
210.242 -2.6073
216.628 -2.1492
223.030 -1.7151
229.450 -1.3031
235.888 -.9117
242.347 -.5392
248.828 -.1844
255.333 Л540
261.865 .4772
268.425 .7860
275.015 1.0814
281.638 1.3644
288.296 1.6356
294.991 1.8958
301.724 2.1456
308.499 2.3857
315.317 2.6166
322.180 2.8387
329.089 3.0526
336.048 3.2587
343.057 3.4575
350.117 3.6493
357.231 3.8344
364.400 4.0133
371.624 4.1861
Таблица 419
) кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
V
о
k I ?
х <-. 7
2 2 и ¦
? 2 7 к
г- II ir> 5
1 о со ¦«*¦*
^ II
w СЛ ^
п t i
О ^J
а; о*
о X
ОО ^а
2 R
+ т
1
s «f §¦
й Д W
§ 2 V
х + V
¦s - 8
г^ уд "">
^ ?' о
«о ^ *-
+ 1 •
ОО X ^
& 5 "
6  ?
к +
0
е
208

Класс точности
II-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
оопл
хоиО
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
ОКСИД-СУЛЬФИД УГЛЕРОДА COS (г)
КО(Г) =р (С) ¦ р @) ¦ р (S) • р~ J(C
ФР(Л
5°(Г)
Дж . К~' . моль
29.630
35.546
41.548
41.642
45.851
48.850
51.157
53.006
54.512
55.747
56.766
57.612
58.319
58.915
59.421
59.856
60.232
60.559
60.848
61.103
61.332
61.537
61.724
61.894
62.050
62.194
62.328
62.454
СО С7 1
62.571
62.682
62.787
62.887
62.982
63.074
63.161
63.246
63.328
63.408
63.486
63.561
63.636
63.708
63.780
63.850
63.919
63.988
64.056
64.124
64.191
64.258
64.325
64.391
64.458
64.525
64.592
64.659
64.727
64.795
64.864
64.933
65.003
164.875 194.038
185.448 216Г161
198.191 231.535
198.398 231.792
20--.371 244.386
216.659 254.956
223.819 264.075
230.155 272.104
235.855 279.284
241.047 285.779
245.821 291.706
250.244 297.158
254.366 302.202
258.228 306.894
261.862 311.279
265.295 315.394
268.549 319.269
271.641 322.931
274.588 326.400
277.402 329.697
280.096 332.838
282.679 335.835
285.161 338.702
287.549 341.450
289.851 344.087
292.071 346.623
294.216 349.065
296.292 351.420.
298.301 353.693
300.249 355.891
302.140 358.017
303.976 360.078
305.760 362.076
307.496 364.016
309.186 365.900
310.833 367.732
312.439 369.515
314.005 371,251
315.534 372.943
317.027 374.593
318.486 376.203
319.913 377.776
321.309 379.312
322.676 380.813
324.014 382.282
325.325 383.719
326.609 385.126
327.869 386.504
329.105 387.855
330.317 389.179
331.508 390.478
332.676 391.753
333.825 393.004
334.953 394.232
336.062 395.439
337.152 396.625
338.224 397.790
339.280 398.937
340.318 400.064
341.340 401.173
342.346 402.266
OS) Д,.^
Я°(Г)-Я°@)
кДж ¦ моль
2.916
6.142
9.941
10.018
14.406
19.149
24.154
29.365
34.743
40.258
45.886
51.606
57.403
63.266
69.183
75.148
81.152
87.192
93.263
99.361
105.483
111.626
117.790
123.971
130.168
136.380
142.606
148.846
• ее AQ7
155.0У7
161.360
167.633
173.917
180.210
186.513
192.825
199.145
205.474
211.811
218.156
224.508
230.868
237.235
243.609
249.991
256.379
262.775
269.177
275.586
282.002
288.424
294.853
301.289
307.731
314.181
320.636
327.099
333.568
340.045
346.528
353.017
359.514
Г°@) = 1374.59
-708.4963
-348.1515
-229.2413
-227.7454
-167.4304
-131.1885
-106.9990
-89.7043
-76.7230
-66.6198
-58.5327
-51.9130
-46.3944
-41.7232
-37.7182
-34.2463
-31.2078
-28.5262
-26.1422
-24.0088
-22.0885
-20.3509
-18.7711
•17.3284
-16.0059
-14.7890
-13.6656
-12.6253
1 1 R?OQ
-1 1.05Уо
-10.7597
-9.9200
-9.1344
-8.3977
-7.7057
-7.0542
-6.4399
-5.8596
-5.3106
-4.7904
-4.2967
-3.8277
-3.3815
-2.9564
-2.5510
-2.1640
-1.7941
-1.4402
-1.1013
-.7764
-.4647
-.1654
.1222
.3989
.6651
.9216
1.1688
1.4072
1.6373
1.8595
2.0743
2.2820
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
палл
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 420
1
1
'л
-1 О
'л s
о %
¦ ss Т
S о К
С( о 2
X t-. S
00 •—* „'
со <—' w
S "*¦ " i
о Т1 ^ Л
2 и ¦ Й г-
ч—% ГО
11 о оо" *°.
"^ Еч (~ч)
, °* II
О - о g
В о ^
О {_)
¦^ о"'
+
я е
.—i ,
+ V
V """
•3 ¦« Я
"""* Й О
fN ^"* О
о о V
Т °" ^
н 7 v
я « g
1Л ОО ^
• ' 1
Tt- ^ О
+ 1 •
О СО ..
ГО ГО
II +
р
о
е
209

Класс точности
1-Е
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
29.105
29.110
29.156
29.158
29:410
29.939
30.653
31.426
32.174
32.855
33.458
33.988
34.458
34.882
35.277
35.656
36.030
36.407
36.794
37.194
37.608
38.035
38.474
38.922
39.375
39.831
40.284
40.732
41.171
41.599
42.011
42.407
42.784
43.140
43.476
43.790
44.082
44.352
44.600
44.828
45.035
45.222
45.391
45.543
45.678
45.799
45.905
45.999
46 081
46.154
46.217
46.272
46.386
46.354
46.399
46.432
46.461
46.488
46.513
46.537
46.559
ЦИАН CN (г)
К°(Т) = Р (С) • р (N) ¦ р~\СН) Дг //°@) = 745.003
Ф°G-)
Дж . К . моль"
141.703
161.838
173.448
173.628
182.000
188.510
193.855
198.405
202.381
205.920
209.118
212.039
214.730
217.229
219.562
221.753
223.818
225.773
227.630
229.398
231.088
232.707
234.261
235.755
237.196
238.587
239.932
241.236
242.499
243.727
244.920
246.082
247.214
248.317
249.395
250.447
251.475
252.481
253.466
254.430
255.375
256.301
257.209
258.100
258.975
259.834
260.678
261.507
262.321
263.123
263.911
264.686
265.449
266.200
266.939
267.667
268.384
269.091
269.787
270.473
271.149
S°(T)
1
Н°(Г)-Н°@)
кДж ¦ моль
170.731 2.903
190.906 5.813
202.534 8.672
202.714 8.726
211.130 11.652
217.745 14.617
223.264 17.646
228.048 20.750
232.293 23.930
236.123 27.182
239.617 30.499
242.831 33.872
245.809 37.294
248.584 40.762
251.184 44.270
253.630 47.817
255.944 51.401
258.139 55.023
260.231 58.683
262.231 62.382
264.149 66.122
265.995 69.904
267.774 73.729
269.494 77.599
271.160 81.514
272.777 85.474
274.348 89.480
275.876 93.531
277.366 97.626
278.818 101.765
280.235 105.945
281.619 110.166
282.972 114.426
284.294 118.723
285.587 123.054
286.852 127.417
288.089 131.811
289.301 136.233
290.487 140.681
291.648 145.152
292.786 149.645
293.900 154.158
294.992 158.689
296.062 163.236
297.111 167.797
298.139 172.371
299.146 176.956
300.135 181.552
301.104 186.156
302.055 190.768
302.988 195.386
303.904 200.011
304.803 204.640
305.685 209.275
306.552 213.913
307.404 218.554
308.241 223.199
309.064 227.846
309.872 232.496
310.668 236.383
311.450 241.804
-385.0067
-189.8981
-125.5562
-124.7469
-92.1161
-72.5054
-59.4111
-50.0444
-43.0099
-37.5317
-33.1441
-29.5503
-26.5525
-24.0135
-21.8353
-19.9460
-18.2915
-16.8306
-15.5311
-14.3677
-13.3200
-12.3715
-11.5089
-10.7209
-9.9983
-9.3333
-8.7192
-8.1505
-7.6223
-7.1305
-6.6714
-6.2419
-5.8392
-5.4609
-5.1049
-4.7693
-4.4523
-4.1524
-3.8684
-3.5990
-3.3430
-3.0996
-2.8678
-2.6468
-2.4359
-2.2343
-2.0416
-1.8570
-1.6802
-1.5106
-1.3477
-1.1913
-1.0408
-.8960
-.7566'
-.6222
-.4926
-.3676
-.2468
-.1301
-.0172
кДж • моль"!
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 421
1
л
1
'§ I V-
S * °
i оо 7
R сЗ Т
о °' *
?: о 5 i
о ° " «
* ?Г% ^^ (SJ
II " -ч 0°.
IS S °°" ^
S5 С. о 5
О 2ч ^
Оч **
=> 'л
<*1 о
о 2
Г* |
s a §
О Ц
О CJ W
о ~? /
«2 V
•а ' §
3 1 т"
СЛ С— t—t
+ *""' •
J + ь
^2 ^
(S On
II +
^,
О
210

ЦИАН CN (г)
Таблица421
(окончание)
S°(T)
К
Дж
К .моль
Я°(Г)-Я°@)
кДж . моль"
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
46.605
46.663
46.719
46.781
46.853
46.934
47.027
47.129
47.242
47.366
47.498
47.639
47.788
47.944
48.105
48.270
48.439
48.610
48.783
48.955
49.380
49.785
50.160
50.494
50.781
51.015
51.194
51.316
51.379
51.384
51.332
51.224
51.064
50.854
50.596
50.295
49.953
49.575
49.165
48.725
272.474
273.766
275.021
276.243
277.435
278.598
279.733
280.842
281.926
282.987
284.024
285.039
286.034
287.008
287.964
288.901
289.820
290.723
291.610
292.481
294.595
296.623
298.573
300.452
302.264
304.016
305.710
307.351
308.942
310.485
311.985
313.443
314.860
316.240
317.584
318.893
320.170
321.414
322.629
323.814
312.977
314.448
315.885
317.281
318.638
319.959
321.246
322.501
323.727
324.925
326.096
327.242
328.365
329.465
330.544
331.603
332.644
333.665
334,669
335.656
338.055
340.362
342.583
344.725
346.793
348.789
350.718
352.582
354.384
356.126
357.810
359.438
361.012
362.534
364.004
365.425
366.799
368.126
369.409
370.648
251.120
260.367
269.705
279.055
288.418
297.797
307.193
316.608
326.045
335.506
344.992
354.506
364.048
373.621
383.226
392.864
402.535
412.240
421.979
431.753
456.337
481.129
506.117
531.282
556.603
582.054
607.609
633.238
658.914
684.607
710.288
735.930
761.504
786.985
812.350
837.574
862.638
887.521
912.208
936.681
.1976
-3991
.5886
.7671
.9356
1.0949
1.2457
1.3888
1.5247
1.6540
1.7771
1.8946
2.0067
2.1139
2.2164
2.3147
2.4088
2.4992
2.5860
2.6695
2.8647
3.0426
3.2056
3.3554
3.4935
3.6212
3.7398
3.8500
3.9527
4.0488
4.1387
4.2232
4.3026
4.3774
4 4480
4.5148
4.5780
4.6380
4.6950
4.7493
Ь200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
н
о
I
X
S
К
3
v
V
р
о
о
II
с
+ *
211

Класс точности
VI-E
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
540Q
5500
5600
5700
5800
5900
6000
с;(г)
29.463
29.480
31.367
35.048
39.360
43.001
45.348
46.430
46.583
46.179
45.503
44.742
44.000
43.330
42.752
42.270
41.880
41.574
41.340
41.170
41.053
40.982
40.948
40.946
40.970
41.014
41.075
41.148
41.230
41.320
41.414
41.511
41.609
41.706
41.803
41.897
41.988
42.076
42.161
42.241
42.317
42.388
42.456
42.519
42.577
42.632
42.682
42.729
42.772
42.811
42.847
42.880
42.910
42.938
42.963
42.985
43.006
43.024
43.041
ПОЛОЖИТЕЛЬНЫЙ
Г>(Г)=р(С).р
Ф°(Г)
_ j _
Дж ¦ К . моль
167.704
167.884
176.291
182.923
188.517
193.450
197.917
202.021
205.820
209.353
212.646
215.725
218.611
221.321
223.873
226.283
228.563
230.725
232.781
234.739
236.609
238.397
240.110
241.755
243.336
244.858
246.326
247.744
249.114
250.440
251.724
252.971
254.180
255.356
256.500
257.613
258.697
259.754
260.785
261.792
262.775
263.736
264.675
265.594
266.494
267.376
268.239
269.085
269.915
270.729
271.528
272.313
273.083
273.840
274.583
275.315
276.033
276.740
277.436
№-р-\е)
S°(T)
1
196.822
197.004
205.696
213.065
219.838
226.193
232.103
237.518
242.424
246.848
250.839
254.451
257.739
260.751
263.446
266.106
268.510
270.766
272.892
274.905
276.817
278.640
280.384
282.055
283.662
285.208
286.701
288.144
289.540
290.893
292.207
293.483
294.723
295.931
297.107
298.254
299.372
300.464
301.530
302.573
303.592
304.588
305.563
306.518
307.453
308.370
309.268
310.148
311.012
311.859
312.691
313.508
314.309
315.097
315.871
316.631
317.379
318.114
318.838
ИОН ЦИАНА CN+
Я°(Г)-Я°@)
кДж • моль
8.682
8.736
11.762
15.071
18.792
22.920
27.349
31.947
36.604
41.245
45.831
50.343
54.780
59.146
63.449
67.699
71.906
76.078
80.223
84.348
88.459
92.560
96.656
100.751
104.846
108.946
113.050
117.161
121.280
125.407
129.544
133.690
137.846
142.012
146.187
150.372
154.567
158.770
162.982
167.202
171.430
175.665
179.907
184.156
188.411
192.671
196.937
201.208
205.483
209.762
214.045
218.331
222.621
226.913
231.208
235.506
239.805
244.107
248.410
(г)
@) = -608
о
1 11.9516
1 11.2913
84.6708
68.6705
57.9788
50.3189
44.5534
40.0513
36.4348
33.4636
30.9775
28.8657
27.0486
25.4680
24.0801
22.8513
21.7553
20.7715
19.8833
19.0771
18.3419
17.6685
17.0494
16.4781
15.9492
15.4580
15.0006
14.5734
14.1735
13.7984
13.4456
13.1133
12.7996
12.5031
12.2221
11.9557
11.7025
11.4617
11.2322
11.0134
10.8044
10.6046
10.4134-
10.2302
10.0545
9.8858
9.7238
9.5680
9.4180
9.2736
9.1344
9.0001
8.8705
8.7453
8.6243
8.5073
8.3941
8.2845
8.1783
.997 кДж -моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
'д
о
2
К
V
о
о
CS ^'
Г- -н
О Р-
<N II
11 S
-
о
0
<
1
1 7
г- Е
со о
щ „¦
m 'v
+ X
оо "
ON Н
ON fN
СЛ «/}
О >/")
1 1
X !Ч
С X
ГЛ S
8 R
ГЛ ~-1
*"~ +
+ X
989
117
ЧТ> С*"}
II 1
О
в1
о
^;
%
ON
О
00
II
,—-
¦л
оо
сч
и
+z
0
ч
о
ц а 422
_
'л
К
о
-'
К
•4
п
On
°°.
ON
И
ci
0 D4
to
-->
i
о
vo
V
(-,
V
о
о
1
о
^,
II
212

т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
11000
11500
12000
12500
13000
13500
1.4000
14500
15000
15500
16000
16500
17000
17500
18000
18500
19000
19500
20000
С°(Т)
43.069
43.092
43.111
43.125
43.136
43.144
43.149
43.152
43.151
43.148
43.141
43.131
43.116
43.098
43.075
43.047
43.013
42.973
42.928
42.876
42.716
42.512
42.262
41.968
41.631
41.256
40.846
40.406
39.942
39.458
38.960
38.452
37.938
37.421
36.906
36.395
35.891
35.395
34.910
34.436
ПОЛОЖИТЕЛЬНЫЙ ИОН ЦИАНА CN+ (г)
Ф°(Г)
Дж . К . моль
278.794
280.111
281.389
282.631
283.837
285.011
286.153
287.267
288.352
289.41 1
290.444
291.453
292.439
293.404
294.346
295.269
296.173
297.058
297.925
298.775
300.828
302.788
304.661
306.455
308.175
309.827
31 1.415
312.944
314.417
315.838
317.210
318.535
319.816
321.056
322.256
323.419
324.547
325.640
326.702
327.732
S°(T)
-1
320.249
321.617
322.944
324.231
325.481
326.696
327.879
329.029
330.150
331.243
332.308
333.347
334.362
335.353
336.321
337.268
338.193
3^9.099
339.984
340.851
342.939
344.922
346.806
348.598
350.305
351.930
353.480
354.957
356.367
357.713
358.998
360.227
361.402
362.527
363.604
364.636
365.627
366.577
367.490
368.368
Н°(Т)~Н°@)
кДж ¦ моль
1нА'°(Г)
257.021 7.9756
265.637 7.7847
274.258 7.6048
282.881 7.4347
291.508 7.2738
300.136 7.1213
308.765 6.9766
317.395 6.8389
326.026 6.7080
334.656 6.5831
343.285 6.464!
351.912 6.3503
360.536 6.2415
369.158 6.1374
377-775 6.0376
386.387 5.9419
394.993 5.8500
403.592 5.7617
412.182 5.6768
420.76Д 5.5951
442.162 5.4036
463.470 5.2285
484.665 5.0677
505.723 4.9194
526.624 4.7823
547.346 4.6551
567.872 4.5366
588.184 4.4261
608.271 4.3227
628.120 4.2258
647.723 4.1347
667.074 4.0490
686.169 3.9682
705.007 3.8918
723.586 3.8196
741.908 3.7512
759.977 3.6863
777.795 3.6246
795.368 3.5660
812.700 3.5005
Т
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
10500
1 1000
1 1500
12000
12500
13000
13500
14000
1 4500
15000
155Л0
16000
16500
1 7000
17500
18000
18500
19000
19500
20000
Таблица 42Z
(окончание)
;
+
i
'Э- —
r-i |
О J
г*-) —
О
7 s
"* "а '
гч
¦ ON , ~
ос ¦* v
ON —f ^
ON "^ ~
1/"; <"*¦> Ж
о ч -=;
г- ¦—;
О ^ <~1
t 2 v
С 4- Ь-
¦о2 ^ \ /
* ? v
? =» S
"*** г<-* °
+' 1
X ^ Т
О! гп ~
on r~\ ?¦-
II 4- -^
S
О
213

Класс точности
IV-E
Т
К
298.15
300
400
500
600
700
800
900
1000
; юо
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<л
29.150
29.152
29.382
29.882
30.571
31.329
32.069
32.747
33.348
33.871
34.323
34.71.2
35.048
35.338
35.591
35.812
36.007
36.178
36.331
36.468
36.591
36.702
36.804
36.896
36.982
37.060
37.133
37.201
37.265
37.325
37.382
37.435
37.486
37.535
37.581
37.626
37.669
37.711
37.751
37.790
37.828
37.865
37.901
37.937
37.972
38.006
38.040
38.073
38.106
38.139
38.171
38.203
38.235
38.266
38.298
38.329
38.360
38.391
38.423
ОТРИЦАТЕЛЬНЫЙ ИОН
К°(Т)= p{C)-p(N)p(e)p~l
Ф°(Г)
Дж ¦ К моль
167.379
167.559
175.931
182.439
187.780
192.327
196.297
199.832
203.024
205.939
208.625
211.119
213.447
215.631
217.690
219.637
221.485
223.244
224.923
226.528
228.066
229.542
230.962
232.330
233.650
234.924
236.156
237.349
238.506
239.628
240.717
241.776
242.805
243.808
244.784
245.736
246.665
247.572
248.457
249.322
250.168
250.995
251.805
252.598
253.375
254.137
254.883
255.615
256.334
257.039
257.731
258.412
259.080
259.737
260.383
261.018
261.643
262.258
262.863
S°(T)
1
196.464
196.644
205.056
211.661
217.168
221.937
226.169
229.987
233.469
236.672
239.639
242.402
244.987
247.415
249.704
251.869
253.921
255.873
257.733.
259.508
261.208
262.837
264.401
265.905
267.354
268.751
270.100
271.405
272.667
273.890
275.076
276.227
277.345
278.433
279.491
280.521
281.525
282.504
283.459
284.392
285.303
286.194
287.065
287.917
288.751
289.568
290.368
291.153
291.923
292.677
293.418
294.146
294.860
295.562
296.252
296.930
297.597
298.253
298.898
(CN")
H°(T)-H
ЦИАНА СРГ(г)
Д Яс@)= 1113.603 кДж моль"
°@)
кДж ¦ моль
8.671
8.725
11.650
14.611
17.633
20.727
23.898
27.139
30.445
33.806
37.216
40.669
44.157
47.677
51.223
54.794
58.385
61.994
65.620
69.260
72.913
76.578
80.253
83.938
87.632
91.335
95.044
98.761
102.484
106.214
109.949
113.690
117.436
121.187
124.943
Г 28.704
132.468
136.237
140.010
143.787
147.568
151.353
155.141
158.933
162.729
166.528
170.330
174.136
177.944
181.757
185.572
189.391
193.213
197.038
200.866
204.697
208.532
212.369
216.210
«V,
-189.8112
-188.5971
-139.6093
-110.1295
-90.4194
-76.3009
-65.6830
-57.4026
-50.7610
-45.3132
•40.7621
-36.9017
-33.5848
-30.7034
-28.1763
-25.9414
-23.9502
-22.1646
-20.5539
-19.0933
-17.7626
-16.5449
-15.4263
-14.3948
-13.4406
-12.5552
-11.7312
-10.9624
-10.2432
-9.5690
-8.9355
-8.3392
-7.7767
-7.2451
-6.7420
-6.2651
-5.8122
-5.3817
-4.9717
-4.5809
-4.2079
-3.8514
-3.5104
-3.1837
-2.8706
-2.5701
-2.2815
-2.0040
-1.7370
-1.4799
-1.2321
-.9931
-.7624
-.5396
-.3242
-.1159
.0857
.2810
.4702
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1 аЬл и
_
§
Е(
Ж
г~]
2 1
о оо
|
Z
о
О
ч_.
+
i
*~~ et
п о
о S
+ _'
о •
S ,§
О ГО
о °°
СЧ
' On
Н +
§ ~«
о ~*
+ 1
¦* X
t5 Оч
CN CN
II +
К,
О
-
о
о
vi
>О
II
Я
00*
СЧ
1
Z
и
ч
., Л ~) 1
ц a mi
1
л
о
1
сл
II
о ос
to
->
я
о
V
V
о
о
VI
'о
II
214

ОТРИЦАТЕЛЬНЫЙ ИОН ЦИАНА CN" (г)
Таблица 423
(окончание)
с; сп
Ф°(Т>
S°(T)
к
Дж . К . моль
Но(Т)-И°@)
кДж . моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
38.485
38.547
38.610
38.673
38.737
38.802
38.867
38.933
38.999
39.067
39.135
39.203
39.272
39.342
39.412
39.481
39.551
39.620
39.689
39.757
264.046
265.194
266.308
267.392
268.446
269.473
270.473
271.447
272.399
273.328
274.235
275.121
275.989
276.837
277.668
278.482
279.279
280.060
280.827
281.579
300.159
301.382
302.569
303.723
304.845
305.937
307.001
308.038
309.050
310.039
31 1.004
31 1.948
312.871
313.775
314.660
315.527
316.377
317.210
318.028
318.830
223.901
231.604
239.320
247.048
254.789
262.543
270.310
278.090
285.883
293.690
301.510
309.344
317.191
325.053
332.928
340.818
348.721
356.638
364.569
372.513
.8316
1.1721
1.4935
1.7975
2.0855
2.3589
2.6189
2.8664
3.1024
3.3277
3.5432
3.7494
3.9470
4.1366
4.3187
4.4938
4.6622
4.8245
4.9809
5.1318
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
о"
q
о
оо
g
О
¦е-
о
I
о
+
о
I
V
V
v
I
215

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
30.508
37.347
42.417
42.504
47.006
51.028
54.339
56.894
58.784
60.145
61.110
61.785
62.251
62.570
62.783
62.923
63.011
63.063
63.089
63.097
63.093
63.081
63.063
63.042
63.019
62.994
62.969
62.944
62.920
62.896
62.873
62.851
62.830
62.810
62.791
62.773
62.755
62.739
62.724
62.709
62.695
62.682
62.669
62.657
62.646
62.635
62.625
62.616
62.606
62.598
62.589
62.582
62.574
62.567
62.560
62.554
62.547
62.542
62.536
62.530
62.525
ДИНИТРИД УГЛЕРОДА NCN
К°(Т)= p2(N)-p(
Ф°(Г)
_ ..— 1 — 1
Дж ¦ К ..моль
157.624
178.571
191.726
191.939
202.206
210.731
218.120
224.695
230.643
236.087
241.112
245.778
250.136
254.223
258.069
261.703
265.144
268.412
271.524
274.492
277.329
280.047
282.654
285.160
287.570
289.893
292.134
294.299
296.393
298.419
300.383
302.288
304.137
305.933
307.680
309.380
311.035
312.648
314.220
315.755
317.252
318.715
320.145
321.543
322.910
324.249
325.559
326.842
328.100
329.334
330.543
331.729
332.894
334.037
335.160
336.263
337.347
338.412
339.460
340.490
341.504
С)-р '(NCN)
S°(T)
186.955
210.222
226.120
226.383
23S.236
250.168
259.776
268.353
276.080
283.087
289.477
295.335
300.732
305.729
310.374
314.711
318.775
322.596
326.202
329.613
332.850
335.928
338.862
341.665
344.347
346.919
349.389
351.765
354.054
356.262
358.393
360.455
362.450
364.383
366.258
368.078
369.846
371.565
373.238
374.867
376.455
378.002
379.513
380.987
382.427
383.835
385.212
386.559
387.877
389.167
390.432
391.67!
392.887
394.078
395.248
396.396
397.523
398.630
399.717
400.786
401.837
АгН°
Я°(Г)-Я°@)
кДж - моль
2.933
6.330
10.255
10.333
14.812
19.719
24.993
30.561
36.350
42.300
48.366
54.513
60.716
66.958
73.226
79.512
85.809
92.113
98.421
104.730
111.040
117.349
123.656
129.961
136.264
142.565
148.863
155.159
161.452
167.743
174.031
180.317
186.602
192.884
199.164
205.442
211.718
217.993
224.266
230.538
236.808
243.077
249.344
255.611
261.876
268.140
274.403
280.665
286.926
293.186
299.445
305.704
311.962
318.219
324.475
330.731
336.986
343.240
349.494
355.748
362.000
(Г)
@)= 1352.821
ЫК°(Т)
-697.5958
-343.0331
-226.0806
-224.6098
¦165.3083
-129.6862
-105.9179
-88.9303
-76.1844
-66.2683
-58.3340
-51.8418
-46.4313
-41.8532
-37.9292
-34.5284
-31.5529
-28.9275
-26.5940
-24.5062
-22.6272
-20.9273
-19.3820
-17.971!
-16.6777
-15.4879
-14.3896
-13.3727
-12.4284
-11.5492
-10.7286
-9.9609
-9.2411
-8.5649
-7.9284
-7.3282
-6.7613
-6.2249
-5.7167
-5.2344
-4.7762
-4.3402
-3.9249
-3.5288
-3.1505
-2.7890
-2.4430
-2.1! 16
-1.7939
-1.4890
-1.1962
-.9147
-.6439
-.3831
-.1319
.1104
.3442
.5699
.7881
.9989
1.2030
кДж • моль '
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
i
Q
.о
о
"* я
я S
¦ч- "
II Q
^ с-Г
?-
и
0
1
ё
СО
о ¦
i *
' СО
t- +
VO Я
? +
00 H
1Л ^
en c--
II I
о
о
л
о
2
Й
ГО
VI
О
О
го
И
я
00
гч
с
z"
¦~-
5;
ч
<1
ц а 424
i
л
к
о
_•
1
1
fS
rs
ON
К
О Ц
со
я
о
о
VO
V
*"•
V
о
о
»'"
'о
II
216

Класс точности
VI-G
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
30.975
38.075
42.282
42.344
45.214
47.454
49.375
51.134
52.784
54.328
55.747
57.028
58.163
59.153
60.005
60.730
61.340
61.849
62.270
62.616
62.896
63.123
63.303
63.445
63.555
63.639
63.700
S3.743
63.772
63.788
63.794
63.792
63.784
63.770
63.753
63.732
63.708
63.683
63.656
63.629
63.600
63.572
63.543
63.514
63.485
63.457
63.429
63.402
63.375
63.349
63.324
63.299
63.274
63.251
63.228
63.206
63.184
63.163
63.143
63.123
63.104
К G*) — р (С) • р i
Ф G*)
Дж . К~' . моль
162.726
183.854
197.183
197.398
207.741
216.224
223.468
229.822
235.503
240.656
245.383
249.758
253.836
257.660
261.262
264.671
267.906
270.986
273.926
276.739
279.436
282.025
284.516
286.915
289.230
291.465
293.626
295.717
OQ7 ТА Л
2\) 1.144
299.710
301.618
303.471
305.273
307.026
308.732
310.395
312.016
313.597
315.140
316.648
318.120
319.560
320.968
322.345
323.694
325.014
326.308
327.577
328.820
330.040
331.236
332.411
333.564
334.697
335.810
• 336.904
337.979
339.036
340.076
341.099
342.106
КАРБИД
N).p-4CN
5°(Г)
192.157
215.921
231.978
232.240
244.835
255.173
263.998
271.743
278.680
-284.987
290.786
296.160
301.172
305.867
310.283
314.448
318.388
322.122
325.670
329.046
332.266
335.340
338.281
341.098
343.800
346.397
348.894
351.299
QCQ А 1 Й
оОо.и 1 о
355.856
358.018
360.110
362.135
364.098
366.001
367.849
369.644
371.390
373.088
374.741
376.351
377.921
379.453
380.948
382.408
383.834
385.228
386.592
387.927
389.233
390.513
391.767
392.995
394.200
395.383
396.542
397.681
398.799
399.898
400.977
402.037
ДИАЗОТА CNN
N) Д Л
Я°(Г)-Я°@)
кДж • моль
2.943
6.413
10.374
10.452
14.838
19.475
24.318
29.344
34.541
39.898
45.402
51.042
56.803
62.670
68.629
74.667
80.771
86.932
93.138
99.383
105.659
111.961
118.282
124.620
130.970
137.330
143.697
150.070
1 К А А Л А
1 56.446
162.824
169.203
175.582
181.961
188.339
194.715
201.089
207.461
213.831
220.198
226.562
232.924
239.282
245.638
251.991
258.340
264.688
271.032
277.373
283.712
290.048
296.382
302.713
309.042
315.368
321.692
328.014
334.333
340.651
346.966
353.279
359.591
(г)
'°@) = 1252.821
-645.6286
-317.1920
-208.8464
-207.4837
-152.5389
-119.5263
-97.4916
-81.7362
-69.9090
-60.7032
-53.3338
-47.301!
-42.2718
-38.0147
-34.3649
-31.2012
-28.4325
-25.9894
-23.8176
-21.8744
-20.1255
-18.5433
-17.1049
-15.7917
-14.5880
¦13.4807
-12.4586
-11.5J2
-10.6335
-9.8154
-9.0519
-8.3377
-7.6681
-7.0391
-6.4470
-5.8888
-5.3616
-4.8628
-4.3902
-3.9418
-3.5157
-3.1103
-2.7242
-2.3559
-2.0043
-1.6682
-1.3466
-1.0386
-.7433
-.4599
-.1877
.0739
.3256
.5680
.8015
1.0266
1.2439
1.4537
1.6565
1.8525
2.0421
кДж • моль
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л
-1
с;
о
о
п- о
¦* о
^ о
S и ¦
11 о
О
о
а; (
+
н -
« |
О
+ ~
i в
О (*¦)
О m
О СЛ
о Я
1 ГО
Н +
с
ю *}<
3 ">
чо m
с— К
~ч 00
-! ?
II +
0
и
§
¦
О
1!
Я
00
Z
у
э
ч
<1
ца425
л
с;
о
s
i
2
II
а.
0 04
я
о
о
§
V
V
о
¦л
•о
ь,
II
217

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300'
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
35.318
41.446
45.049
45.111
48.308
51.068
53.288
55.015
56.344
57.371
58.172
58.803
59.308
59.716
60.049
60.325
60.555
60.749
60.914
61.055
61.177
61.283
61.375
61.456
61.527
61.591
61.647
61.698
61.743
61.784
61.821
61.854
61.885
61.913
61.938
61.961
61.983
62.003
62.021
62.038
62.053
62.068
62.081
62.094
62.106
62.117
62.127
62.137
62.146
62.154
62.162
62.170
62.177
62.184
62.190
62.196
62.202
62.207
62.212
62.217
62.222
К°(Т) = р\Ор(
Ф°(Г)
Дж ¦ К~! .моль
157.520
180.923
195.610
195.846
207.120
216.318
224.159
231.032
237.172
242.731
247.816
252.507
256.861
260.926
264.739
268.330
271.723
274.940
277.998
280.912
283.696
286.360
288.915
291.369
293.730
296.004
298.199
300.318
Л^\^\ А Л ft
302.368
304.352
306.276
308.142
309.953
311.713
313.425
315.091
316.714
318.296
319.838
321.343
322.813
324.249
325.652
327.025
328.368
329.683
330.970
332.232
333.468
334.681
335.870
337.037
338.183
339.308
340.413
341.498
342.566
343.615
344.647
345.662
346.661
ДИКАРБИД
N).p-'(CNC)
sV)
189.850
216.460
233.708
233.987
247.410
258.496
268.011
276.361
283.798
290.496
296.584
302.159
307.298
312.062
316.500
320.652
324.553
328.231
331.708
335.005
338.140
341.127
343.980
346.710
349.328
351.840
354.257
356.585
358.829
360.997
363.092
365.120
367.084
368.989
370.837
372.633
374.379
376.078
377.731
379.342
380.913
382.446
383.942
385.403
386.830
388.226
389.592
390.928
392.236
393.517
394.773
396.004
397.212
398.396
399.558
400.699
401.820
402.921
404.003
405.067
406.14 2
АЗОТА CNC
(г)
Д/.Я°@)= 1243.
Я°(Г)-Я°@)
кДж ¦ моль
3.233
7.107
11.359
11.442
16.116
21.089
26.312
31.730
37.301
42.989
48.768
54.618
60.524
66.476
72.465
78.484
84.529
90.594
96.677
102.776
108.888
115.011
121.144
127.286
133.435
139.591
145.753
151.920
158.092
164.268
170.449
176.632
182.819
189.009
195.202
201.397
207.594
213.793
219.994
226.197
232.402
238.608
244.816
251.024
257.234
263.445
269.657
275.871
282.085
288.300
294.516
300.732
306.950
313.168
319.386
325.606
331.826
338.046
344.267
350.488
356.710
XgK°(T)
-640.2456
-314.3605
-206.8851
-205.5336
-151.0420
-118.3093
-96.4675
-80.8547
-69.1381
-60.0208
-52.7240
-46.7519
-41.7738
-37.5604
-33.9482
-30.8171
-28.0769
-25.6587
-23.5089
-21.5851
¦19.8535
-18.2866
-16.8620
-15.5612
-14.3685
-13.2712
-12.2581
-11.3199
-10.4486
-9.6373
-8.8799
-8.1712
-7.5067
-6.8824
-6.2946
-5.7403
-5.2166
-4.7211
-4.2516
-3.8059
-3.3825
-2.9795
-2.5956
-2.2294
-1.8797
-1.5454
-1.2254
-.9190
-.6252
-.3432
-.0723
.1880
.4385
.6797
.9121
1.1362
1.3524
1.5612
1.7629
1.9580
2.1466
188 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
-1
i
1
1
о
оо Ц
(N О
О VJ
ОО
СЛ II
" о
и
о
>.
<]
J1"
V
"" 'й
«*> о
-* 2
N+ «¦
1 '^
^ m
о ^
1
х 
- Я г,
оо <§
04 00
оо* ^
, 1
+ 1
>Л СЧ
оо °5
II +
о
'C
о
и
Я
оо'
U
у"
Z
и
0
а»
¦ч
ца426
"л
g
1
^"
.
о
II
о Э
о
8
VO
V
V
8
?
*•*
II
218

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
. 3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
34.688
40.913
44.577
44.637
47.651
50.235
52.380
54.113
55.494
56.591
57.467
58.172
58.745
59.216
59.609
59.943
60.232
60.487
60.717
60.929
61.127
61.316
61.498
61.676
61.851
62.024
62.195
62.366
62.535
62.704
62.872
63.039
63.205
63.369
63.532
63.694
63.853
. 64.011
64.167
64.321
64.472
64.622
64.769
64.913
65.055
65.194
65.331
65.465
65.597
65.725
65.851
65.974
66.094
66.21
66.325
66.436
66.544
66.649
66.750
66.849
66.944
*°(П=Р>(С).,
- Ф°(Г)
Дж ¦ К • моль
163.445
186.680
201.216
201.449
212.605
221.699
229.443
236.226
242.281
247.763
252.778
257.404
261.701
265.713
269.478
273.025
276.378
279.559
282.584
285.468
288.224
290.863
293.395
295.828
298.171
300.429
302.609
304.716
306.755
308.730
310.646
312.506
314.313
316.070
317.781
319.447
321.072
322.656
324.203
325.713
327.189
328.633
330.045
331.427
332.781
334.108
335.409
336.684
337.935
339.163
340.369
341.553
342.717
343.860
344.985
346.091
347.179
348.250
349.304
350.341
351.363
НИТРИД ДИУГЛЕРОДА CCN (г)
,(N).P-4CCN)
S°(T)
1
195.693
221.862
238.919
239.195
252.460
263.378
272.734
280.943
288.262
294.864
300.874
306.385
311.473
316.194
320.597
324.721
328.599
332.259
335.723
339.011
342.142
345.129
347.985
350.723
353.352
355.880
358.316
360.666
362.937
365.135
367.264
369.328
371.332
373.279
375.173
377.017
378.814
380.566
382.275
383.944
385.574
387.168
388.727
390.252
391.747
393.210
394.644
396.051
397.431
398.784
400.113
401.419
402.701
403.961
405.200
406.418
407.616
408.795
409.955
411.097
412.221
V
Я°(Л-Я°@)
кДж . моль"
3.225
7.036
11.241
11.324
15.942
20.840
25.974
31.302
36.785
42.391
48.096
53.879
59.726
65.625
71.567
77.545
83.554
89.590
95.650
101.733
107.836
113.958
120.099
126.257
132.434
138.628
144.839
151.067
157.312
163.574
169.852
176.148
182.460
188.789
195.134
201.495
207.873
214.266
220.675
227.099
233.539
239.994
246.463
252.947
259.445
265.958
272.484
279.024
285.577
292.144
298.722
305.314
311.917
318.532
325.159
331.797
338.446
345.106
351.776
358.456
365.145
Г°@)= 1293.
о
-666.6720
-327.7198
-215.9376
-214.5318
-157.8577
-123.8138
-101.0963
-84.8569
-72.6696
-63.1855
-55.5949
-49.3820
-44.2030
-39.8195
-36.0613
-32.8035
-29.9523
-27.4362
-25.1993
-23.1976
-21.3959
-19.7655
-18.2832
-16.9296
-15.6887
-14.5470
-13.4930
-12.5169
¦11.6105
-10.7665
-9.9787
-9.2417
-8.5506
-7.9014
-7.2903
-6.7140
-6.1697
-5.6548
-5.1668
-4.7039
-4.2640
-3.8455
-3.4469
-3.0667
-2.7038
-2.3569
-2.0250
-1.7072
-1.4026
-1.1103
-.8297
-.5600
-.3006
-.0509
.1896
.4215
.6451
.8609
1.0694
1.2709
1.4657
188 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
Т
§
2
•
А
X
О
О
1- О
оо о-
о 2
m "
11 о
^ С
О
У.
о
<
+
"""! §
- s
+ „¦
7 i
к ьй
°. IN
1 °^
X ~
оо ^
чо °?
00
+ 1
о х
ГО ГО
гч" °5
СП t-t
II +
о
'л
о
2
л
*
00
3
II
я
оо
С
•?
и
W
О
Ц;
¦ч.
о
ца 427
т
§
1
о
и
ч
0 Ж
to
-ч
я
о
о
ЧО
V
V
8
V"
'о
к.
II
219

Класс точности
11 D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
36.760
49.299
57.084
57.197
62.092
65.614
68.524
71.064
73.294
75.237
76.918
78.366
79.613
80.690
81.623
82.437
83.151
83.781
84.341
84.842
85.294
85.704
86.078
86.422
86.739
87.035
87.311
87.570
87.815
88.047
88.269
88.481
88.684
88.880
89.070
89.254
89.432
89.607
89.778
89.945
90.110
90.272
90.431
90.589
90.745
90.900
91.053
91.205
91.357
91.508
91.658
91.808
91.958
92.107
92.257
92.406
92.556
92.706
92.856
93.007
93.158
ДИЦИАН C2N2 (г)
К°(Т)= р2(С)-р2(Ю-р'\С2Щ
Ф°(Т)
— 1 ~
Дж ¦ К . моль
160.035
183.517
199.446
199.710
212.614
223.480
232.921
241.300
248.857
255.754
262.109
268.008
273.519
/ 278.692
283.570
288.187
292.570
296.743
300.72/
304.537
308.191
311.699
315.074
318.326
321.463
324.494
327.426
330.265
333.017
335.687
338.281
340.802
343.255
345.643
347.9/0
350.239
352.452
354.613
356.724
358.788
360.806
362.780
364.713
366.606
368.461
370.279
372.062
373.812
375.528
377.214
378.870
380.496
382.095
383.667
385.212
386.733
388.229
389.702
391.152
392.580
393.987
5°(Г)
1
191.232
220.827
242.092
242.445
259.619
273.868
286.095
296.853
306.491
315.239
323.255
330.656
337.529
343.945
349.960
355.620
360.963
366.024
370.828
375.402
379.766
383.937
387.933
391.767
395.452
398.999
402.418
405.718
408.907
411.993
414.982
417.879
420.692
423.424
426.080
428.664
431.181
433.634
436.026
438.360
440.640
442.867
445.044
447.173
449.258
451.299
453.299
455.258
457.180
459.065
460.916
462.732
464.516
466.269
467.993
469.687
471.353
472.993
474.606
476.195
477.759
Таблиц а 428
) Д Я°@) = 2056.852 кДж • моль
кДж . моль
3.120
7.462
12.715
12.821
18.802
25.194
31.905
38.887
46.107
53.536
61.146
68.912
76.812
84.829
92.946
101.149
109.430
117.777
126.183
134.643
143.150
151.701
160.290
168.915
177.573
186.262
194.980
203.724
212.493
221.286
230.102
238.940
247.798
256.676
265.574
274.490
283.424
292.376
301.346
310.332
319.335
328.354
337.389
346.440
355.507
364.589
373.686
382.800
391.928
401.071
410.229
419.403
428.591
437.794
447.012
456.246
465.494
474.757
484.035
493.328
502.636
Т
К
-1059.6560 100
-520.5179 200
-342.7182 298.15
-340.4821 300
-250.3461 400
-196.2078 500
-160.0847 ' 600
-134.2639 700
-114.8870 800
-99.8088 900
-87.7416 1000
-77.8654 1100
-69.6334 1200
-62.6667 1300
-56.6944 1400
-51.5181 1500
-46.9886 1600
-42.992! 1700
-39.4396 1800
-36.2613 1900
-33.4009 . 2000
¦30.8133 2100
-28.4611 2200
-26.3136 2300
-24.3454 2400
-22.5349 2500
-20.8639 2600
-19.3169 2700
-17.8806 2800
-16.5435 2900
•15.2958 3000
-14.1288 3100
-13.0348 3200
-12.0073 3300
-11.0404 3400
-10.1288 3500
-9.2680 3600
-8.4539 3700
-7.6826 3800
-6.9510 3900
-6.2561 4000
-5.5951 4100
-4.9656 4200
-4.3654 4300
-3.7926 4400
-3.2452 4500
-2.7217 4600
-2.2204 4700
-1.7400 4800
-1.2792 4900
-.8368 5000
-.4118 5100
-.0030 5200
.3903 5300
.7691 5400
1.1342 5500
1.4862 5600
1.8260 5700
2.1541 5800
2.4712 5900
2.7777 6000
-
_ о
i и ^
з | ;;
•* с' 'v;
U-i гЛ "?
? 5 ¦— zt
3 m i>S ^
Ч-) ~ г?
II ° §5 С-
44 Ч "
™ ~Z_ о а:
о *—'
—
+ 7
— ? °
Я — V
о •~| .
• Р! ""*
к + V
-5 ~
5 Я. т-
+ i
ос >, ^
О ? II
It 4-
ь
о
о
220

Класс точности
V 1
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
г
32.151
35.641
40.103
40.179
43.875
46.963
49.535
51.643
53.352
54.732
55.848
56.754
57.496
58.108
58.617
59.043
59.403
59.710
59.972
60.198
60.394
60.566
60.716
60.848
60.965
61.070
61.163
61.246
61.322
61.389
61.451
61.507
61.558
61.604
61.647
61.686
61.722
61.755
61.786
61.814
61.841
61.865
61.888
61.909
61.929
61.948
61.965
61.981
61.997
62.011
62.025
62.038
62.050
62.061
62.072
62.082
62.092
62.101
62.110
62.118
62.126
ОКСИД-НИТРИД УГЛЕРОДА
К°(Т) = р (С) ¦ р (О) • р (N) • p-'(NCO) Дг h
Ф°(Т)
"~ 1 ¦¦
Дж • К . моль
162.631
184.696
197.990
198.202
208.342
216.633
223.732
229.985
235.599
240.708
245.403
249.753
253.809
257.609
261.186
264.565
267.768
270.813
273.715
276.487
279.140
281.684
284.128
286.479
288.745
290.931
293.043
295.086
297.064
298.981
300.840
302.646
304.402
306.108
307.770
309.388
310.965
312.504
314.005
315.471
316.904
318.304
319.674
321.014
322.326
323.611
324.870
326.103
327.314
328.501
329.665
330.809
331.932
333.035
334.119
335.184
336.232
337.262
338.276
339.273
340.254
S°(T)
1
194.112
217.180
232.272
232.520
244.602
254.734
263.531
271.331
278.343
284.709
290.536
295.902
300.873
305.501
309.826
313.885
317.708
321.318
324.739
327.988
331.080
334.031
336.852
339.554
342.146
344.637
347.034
349.344
351.573
353.726
355.808
357.824
359.778
361.673
363.513
365.300
367.039
368.730
370.377
371.983
373.548
375.075
376.566
378.023
379.446
380.838
382.200
383.533
384.838
386.116
387.369
388.598
389.802
390.984
392.145
393.284
394.403
395.501
396.582
397.644
398.687
Н°(Г)-Н°@)
кДж .моль
3.148
6.497
10.221
10.296
14.504
19.051
23.880
28.942
34.195
39.602
45.132
50.764
56.478
62.259
68.096
73.980
79.903
85.859
91.843
97.852
103.882
109.930
115.994
122.072
128.163
134.265
140.377
146.497
152.626
158.761
164.903
171.051
177.204
183.363
189.525
195.692
201.862
208.036
214.213
220.393
226.576
232.761
238.949
245.139
251.331
257.525
263.720
269.918
276.117
282.317
288.519
294.722
300.926
307.132
313.339
319.546
325.755
331.964
338.175
344.386
350.599
NCO (г)
'°@) = 1251
\gK°(T)
-644.8702
-316.6918
-208.3944
-207.0320 .
-152.0969
-1 19.0844
-97.0480
-81.2911
-69.4631
-60.2567
-52.8871
-46.8543
-41.8246
-37.5671
-33.9165
-30.7517
-27.9818
-25.5372
-23.3637
-21.4186
-19.6677
-18.0833
-16.6427
-15.3271
-14.1210
-13.0113
-11.9867
-11.0379
-10.1568
-9.3362
-8.5703
-7.8537
-7.1817
-6.5504
-5.9561
-5.3956
-4;8662
-4.3652
-3.8905
-3.4401
-3.0120
-2.6047
-2.2167
-1.8467
-1.4933
-1.1555
-.8323
-.5227
-.2259
.0589
.3325
.5955
.8484
1.0920
1.3266
1.5529
1.7712
1.9819
2.1855
2.3824
2.5728
.786 кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
1
|
а
X
о
о
о ^
5 "
И о
§ и
о"
2.
с;
^ °
X
со H
о -*
t I~H
* +
Я „
о *2
ГО ^
о —*.
+ 1
I— X.
t-- —i
~< m
v> О
II +
0
?b
о
ос
11
я
ОС
с
о
а;
а 429
>л
с;
о
2
л
i
о
м
0 Ц
to
?
о
о
о
V
(-
V
о
о
'о
*—*
II
221

Класс точности
II—-Е
Т
к
too
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
29.164
31.716
35.857
35.928
39.233
41.739
43.820
45.662
47.336
48.863
50.251
51.504
52.631
53.639
54.540
55.344
56.063
56.705
57.280
57.797
58.262
58.681
59.061
59.406
59.721
60.008
60.271
60.512
60.735
60.941
61.131
61.308
61.473
61.626
61.770
61.905
62.031
62.150
62.262
62.368
62.468
62.563
62.653
62.739
62.821
62.899
62.973
63.044
63.113
63.178
63242
63.303
63.362
63.419
63.474
63.528
63.581
63.633
63.684
63.734
63.783
СИНИЛЬНАЯ
КИСЛОТА
Ko(r) = P(H)-p(C)-p(N).p~1(HCN) Ar
Ф°(П
Дж . К • моль
138.443
158.683
170.736
170.927
180.075
187.537
193.908
199.506
204.521
209.081
213.272
217.158
220.788
224.196
227.412
230.460
233.357
236.119
238.760
241.291
243.720
246.057
248.309
250.482
252.581
254.612
256.578
258.485
260.336
262.134
263.883
265.584
267.240
268.855
270.429
271.966
273.466
274.932
276.364
277.766
279.137
280.479
281.794
283.082
284.345
285584
286.799
287.992
289.162
290.312
291.442
292.552
293.643
294.716
295.772
296.810
297.832
298.839
299.829
300.805
301.766
S°(T)
1
167.492
188.263
201.711
201.933
212.746
221.780
229.579
236.474
242.683
248.348
253.569
258.418
262.949
267.202
271.211
275.001
278.597
282.015
285.273
288.384
291.360
294.213
296.952
299.585
302.120
304.564
306.923
309.202
311.407
313.542
315.611
317.618
319.568
321.461
323.303
325.096
326.841
328.543
330.202
331.820
333.400
334.944
336.453
337.928
339.372
340.784
342.167
343.523
344.851
346.152
347.430
348.683
349.912
351.120
352.306
353.471
354.616
355.742
356.849
357.938
359.009
Н°(Т)-Н°@)
кДж • моль
2.905
5.916
9.235
9.302
13.068
17.122
21.402
25.878
30.529
35.340
40.297
45.386
50.594
55.908
61.318
66.813
72.384
78.023
83.723
89.477
95.280
101.128
107.015
112.939
118.895
124.882
130.896
136.935
а л л ало
142.998
149.082
155.185
161.307
167.447
173.602
179.772
185.955
192.152
198.361
204.582
210.813
217.055
223.307
229.568
235.837
242.115
248.401
254.695
260.996
267.304
273.618
279.939
286.266
292.600
298.938
305.283
311.633
317.988
324.349
330.715
337.085
343.461
HCN (г)
Я°@)= 1265.653
1$К°(Т)
-653.0781
-321.2440
-211.7283
-210.3506
-154.7848
-121.3838
-99.0800
-83.1255
-71.1439
-61.8139
-54.3421
-48.2230
-43.1194
-38.7977
-35.0909
-31.8764
-29.0621
-26.5778
-24.3685
-22.3909
-20.6105
-18.9991
-17.5337
-16.1954
-14.9683
-13.8391
-12.7966
-11.8310
-10.9343
-10.0993
-9.3197
-8.5904
-7.9065
-7.2640
-6.6591
-6.0887
-5.5500
-5.0402
-4.5572
-4.0989
-3.6634
-3.2491
-2.8545
-2.4781
-2.1187
-!.773
-1.4467
-1.1320
-.8303
-.5409
-.2629
.0042
.2611
.5084
.7466
.9763
1.1978
1.4116
1.6182
1.8178
2.0109
кДж ¦ моль
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
л
о
, s
¦ *
X ^
00 2
я 2 "
^ II ' н
II s °°
* к" "
z" и
Р я
т- *
•^ 0
>-. >
О ч
+
V
Ж "
5 в
" 1
о
+ 7
04 S
jo ^
о >с
1 »
ч +
7150
806л
6 о
, 1
+ 1
Ч© ^
Г*1) *~^
Ф\ О
1 +
Ь-
о
в
ца430
i
о
1
k
чо
V")
r-i
II
оЭ
со
я
о
g
V
s-
V
1
*"*
г
о
II
222

СИНИЛЬНАЯ КИСЛОТА HCN (г)
Таблица430
(окончание)
С°р(Т)
Ф°(Т)
к
Дж . К -моль
Я°(Г)-Я°(О)
кДж . моль
-1
lg/C°(T)
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
63.881
63.979
64.078
64.179
64.284
64.393
64.507
64.629
64.757
64,894
65.040
65.195
65.360
65.535
65.721
65.918
66.126
66.344
66.573
66.813
303.646
305.474
307.251
308.981
310.666
312.308
313.910
315.473
317.000
318.491
319.950
321.377
322.773
324.141
325.480
326.793
328.08.1
329.344
330.584
331.800
36;. 102
363.132
365.102
367.016
368.877
370.689
372.455
374.176
375.855
377.495
379.098
380.665
382.199
383.701
385.173
386.616
388.033
389.423
390.789
392:131
356.227
369.011
381.816
394.639
407.483
420.347
433.232
446.140
459.071
472.027
485.009
498.019
511.059
524.129
537.233
550.371
563.546
576.759
590.012
603.307
К
2.3785
2.7235
3.0479
3.3536
3.6420
3.9148
4.1731
4.4181
4.6509
4.8722
5.0831
5.2842
5.4761
5.6596
5.8352
6.0033
6.1646
6.3193
6.4678
6.6107
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
бо ¦ ы
' 1 V
V
- й
J5 S
СО ^н
223

Класс точности
V-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
29.921
35.863
40.032
40.089
42.489
44.202
45.670
47.020
48.286
49.472
50.575
51.593
52.524
53.370
54.136
54.827
55.449
56.007
56.510
56.962
57.368
57.735
58.066
58.365
58.636
58.882
59.106
59.310
59.496
59.667
59.823
59.967
60.099
60.221
60.334
60.438
60.535
60.625
60.708
60.786
60.858
60.926
60.989
61.048
61.104
61.156
61.205
61.251
61.295
61.336
61.375
61.411
61.446
61.479
61.510
61.539
61.567
61.594
61.619
61.643
61.666
ГИДРИД-КАРБИД АЗОТА
*-G-,=P(H,.,(N
Ф°(Т)
Дж • К . моль
138.210
158.910
171.736
171.942
181.836
189.912
196.777
202.772
208.110
212.934
217.344
221.412
225.193
228.730
232.054
235.194
238.169
240.999
243.697
246.276
248.748
251.120
253.402
255.601
257.721
259.770
261.752
263.672
265.533
267.338
269.092
270.797
272.456
274.072
275.646
277.180
278.678
280.140
281.568
282.964
284.329
285.664
286.972
288.252
289.507
290.736
291.942
293.124
294.285
295.424
296.543
297.642
298.722
299.783
300.826
301.852
302.862
303.856
304.833
305.796
306.744
) • Р (С) ¦ р~
S°(T)
167.429
189.917
205.097
205.345
217.233
226.905
235.096
242.239
248.601
254.358
259.628
264.496
269.026
273.264
277.248
281.007
284.566
287.944
291.160
294.228
297.160
299.968
302.662
305.249
307.739
310.138
312.452
314.686
316.847
318.937
320.963
322.927
324.833
326.684
328.484
330.234
331.938
333.598
335.216
336.794
338.334
339.837
341.306
342.742
344.146
345.520
346.865
348.181
349.471
350.736
351.975
353.191
354.384
355.555
356.704
357.833
358.942
360.032
361.103
362.157
363.193
'(HNC) i-
Я°G>Я°
кДж . моль
2.922
6.201
9.947
10.021
14.159
18.497
22.991
27.627
32.393
37.281
42.284
47.393
52.600
57.895
63.271
68.720
74.235
79.808
85.434
91.108
96.825
102.580
108.371
114.192
120.043
125.919
i31.818
137.739
143.680
149.638
155.613
161.602
167.606
173.622
179.650
185.688
191.737
197.795
203.862
209.936
216.019
222.108
228.204
234.306
240.413
246.526
252.644
258.767
264.894
271.026
277.162
283.301
289.444
295.590
301.739
307.892
314.047
320.205
326.366
332.529
338.695
HNC (г)
^Я°@) = 1098.037
@)
"'
-565.5136
-277.4797
-182.4154
-181.2194
-132.9887
-103.9973
-84.6378
-70.7886
-60.3873
-52.2872
-45.7995
-40.4858
-36.0535
-32.2997
¦29.0796
-26.2808
¦23.8415
-21.6825
-19.7623
-18.0433
-16.4954
-15.0944
¦13.8201
¦12.6562
-11.5888
-10.6065
-9.6994
-8.8593
-8.0789
-7.3520
-6.6734
-6.0384
-5.4429
-4.8833
-4.3565
-3.8596
-3.3902
-2.9460
-2.5250
-2.1255
-1.7458
-1.3845
-1.0403
-.7120
-.3985
-.0988
.1880
.4627
.7261
.9789
1.2217
1.4550
1.6796
1.8957
2.1040
2.3048
2.4985
2.6856
2.8663
3.0410
3.2100
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
-1
'л
- о
1 2
О "
• ft
ч Щ
* о
2 °
О гп
ЧО О
m 2 N
• СО Ьч
55 и |2
" ° Sn
и и
| у
X Z
о"" Ж
+
X -н
—< Л
m о
m %
о
+ т
н
in ^
о ^
V) го
О ч©
О °1
1 о
н +
° 00
°> см'
•* "~>
+ 1
~-< Н
00 ОО
о <"i
О ОО
II +
о
©
ца 431
с:
1
|
.
г-
id
о tu
я
о
о
о
V
V
о
о
»'"
то
II
224

Класс точности
VI-C
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ЛЛЛЛ
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
32.427
45.969
54.237
54.356
59.673
63.604
66.715
69.264
71.403
73.224
74.788
76.140
77.311
78.329
79.216
79.990
80.668
81.263
81.787
82.251
82.662
83.027
83.354
83.645
83.908
84.144
84.357
84.550
&А ТОК
8^884
85.030
85.163
85.285
85.397
85.500
85.596
85.684
85.765
85.841
85.911
85.976
86.037
86.094
86.147
86.197
86.244
86.288
86.329
86.368
86.404
86.43*9
86.471
86.502
86.531
86.558
86.584
86.609
86.633
86.655
86.676
86.696
ГИДРИД-НИТРИД
фО(Т-)
•p2(C)p(N)-
S°(T)
Дж ¦ к . моль
163.978
185.882
200.686
200.932
213.022
223.276
232.240
240.236
247.472
254.094
260.205
265.887
271.199
276.189
280.898
285.356
289.590
293.623
297.473
301.157
304.690
308.083
311.347
314.492
317.527
320.458
323.294
326.040
ЧОЯ 7Л9
331.284
333.792
336.229
338.600
340.908
343.157
345.348
347.486
349.573
351.611
353.602
355.549
357.453
359.317
361.142
362.929
364.680
366.397
368.080
369.732
371.353
372.945
374 508
376.043
377.552
379.036
380.494
381.929
383.340
384.729
386.096
387.442
193.665
220.438
240.483
240.819
257.230
270.986
282.868
293.350
302.742
311.260
319.058
326.251
332.927
339.157
344.995
350.487
355.672
360.580
365.240
369.675
373.904
377.947
381.817
385.528
389.094
392.524
395.828
399.016
40в!070
407.950
410.740
413.446
416.072
418.623
421.103
423.516
425.864
428.152
430.383
432.559
434.683
436.757
438.783
440.764
442.702
444.598
446.454
448.272
450.053
451.799
453.511
455.191
456.839
458.456
460.045
481.605
463.138
464.645
466.127
467.584
ДИУГЛЕРОДА
p-'CHCCN) Д^
Н°(Т)-Н°@)
кДж . моль
2.969
6.911
11.866
11.966
17.683
23.855
30.377
37.180
44.216
51.450
58.852
66.400
74.074
81.858
89.736
97.697
105.730
113.828
121.981
130.183
138.429
146.714
155.033
163.384
171.761
180.164
188.589
197.035
AAV 4QQ
213.979
222.475
230.985
239.507
248.041
256.586
265.141
273.705
282.278
290.858
299.446
308.040
3N.641
325.248
333.860
342.477
351.099
359.725
368.356
376.991
385.630
394.272
402.917
411.566
420.218
428.872
437.529
446.189
454.851
463.516
472.182
480.851
НССГГ(г)
Я°@)= 1649.222
lgAT°G-)
•848.9552
-416.1960
-273.3840
-271.5875
-199.1523
-155.6282
-126.5775
-105.8063
-90.2148
-78.0794
-68.3653
-60.4135
-53.7841
-48.1727
-43.3615
-39.1908
-35.5407
-32.3196
-29.4560
-26.8937
-24.5873
-22.5006
-20.6035
-18.8713
-17.2834
-15.8226
-14.4742
-13.2256
-103868
-9.9794
-9.0370
-8.1534
-7.3234
-6.5422
-5.8057
-5.1100
-4.4519
-3.8285
-3.2369
-2.6749
-2.1403
-1.6311
-1.1455
-.6819
-.2389
.1849
.5908
.9798
1.3530
1.7113
2.0557
2.3869
2.7056
3.0127
3.3086
3.5941
3.8696
4.1357
4.3929
4.6416
кДж • моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
оолл
JtOXfXt
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл и
i
о

8
о
о ¦*
• II
О> .
II °.
^ U
. 2"
8
Б
о
+
7
& 7
в
1 1
+ -*
7 и
О <г>
о °°
ч -^
jg „
оо X
* 2
*°~ !>
VO "*
+ 1
«4 U
t.767:
,7051;
и •¦•
0
©
i
г
00
»-н
*О
II
Я
v>
ОС
8
?
о
ч.
ца 432
7
1
I
^*
i
II
oS
<*>
я
I
чо
V
V
g
«о
..
1
-.
11
0-
15 Ш4
225

Класс точности
III—F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<п
ФТОРЦИАН
FCN (г)
К"(Г) = Р (F) • р (С) • р (N) • р~ '(FCN) A, Л
Ф°(Г)
S°(T)
Дж . К . моль
30.169
36.710
41.761
41.839
45.394
48.052
50.183
51.956
53.451
54.716
55.785
56.692
57.462
58.119
58.684
59.172
59.596
59.967
60.294
60.584
60.844
61.077
61.288
61.479
61.655
61.817
61.966
62.106
62.236
62.358
62.473
62.582
62.685
62.784
62.879
62.970
63.057
63.141
63.223
63.303
63.380
63.455
63.529
63.601
63.672
63.741
63.810
63.877
63.943
64.009
64.074
64.138
64.202
64.265
64.327
64.389
64.451
64.512
64.573
64.634
64.695
156.716
177.520
190.521
190.732
200.860
209.220
216.403
222.731
228.407
233.566
238.301
242.684
246.765
250.588
254.184
257.580
260.798
263.857
266.772
269.557
272.222
274.779-
277.236
279.600
281.878
284.077
286.202
288.258
290.249
292.179
294.053
295.873
297.642
299.363
301.039
302.672
304.265
305.818
307.335
308.817
310.265
311.681
313.067
314.423
315.751
317.052
318.328
319.579
320.806
322.010
323.192
324.353
325.494
326.614
327.716
328.799
329.864
330.913
331.944
332.960
333.960
185.968
208.831
224.495
224.753
237.304
247.732
256.687
264.560
271.598
277.969
283.791
289.151
294.118
298.744
303.072
307.138
310.971
314.595
318.032
321.300
324.414
327.389
330.235
332.964
335.584
338.104
340.532
342.873
345.134
347.320
349.436
351.486
353.475
355.405
357.281
359.105
360.880
362.609
364.294
365.937
367.541
369.107
370.637
372.132
373.596
375.027
376.429
377.802
379.147
380.467
381.760
383.030
384.276
385.499
386.701
387.882
389.043
390.184
391.307
392.411
393.498
Я°(Л-Я°@)
кДж • моль"
2.925
6.262
10.129
10.206
14.578
19.256
24.171
29.280
34.553
39.963
45.490
51.115
56.823
62.603
68.444
74.337
80.276
86.255
92.268
98.312
104.384
110.480
116.599
122.737
128.894
135.068
141.257
147.461
153.678
159.908
166.149
172.402
178.665
184.939
191.222
197.514
203.816
210.126
216.444
222.770
229.104
235.446
241.795
248.152
254.516
260.886
267.264
273.648
280.039
286.437
292.841
299.251
305.668
312.092
318.521
324.957
331.399
337.847
344.302
350.762
357.228
Г°@)= 1225.278
-630.7286
-309.4578
-203.4446
-202.1110
-148.3362
-116.0215
-94.4507
-79.0263
-67.4474
-58.4346
-51.2195
-45.3129
-40.3884
-36.2196
-32.6451
-29.5462
-26.8339
-24.4402
-22.3119
-20.4073
•18.6929
-17.1416
-15.7310
-14.4430
•13.2622
-12.1758
-11.1728
-10.2441
-9.3816
-8.5785
-7.8290
-7.1277
-6.4702
-5.8525
-5.2711
-4.7228
-4.2050
-3.7151
-3.2510
¦2.8106
-2.3922
-1.9941
-1.6149
-1.2534
-.9082
-.5782
-.2626
.0396
.3294
.6073
.8742
1.1307
1.3774
1.6149
1.8436
2.0641
2.2767
2.4820
2.6803
2.8719
3.0572
кДж ¦ моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
T аб л и
i
?
А
X
о
5 ?
ч- »
II О
2*
ъ
а;
7
?• "л
00 о
"! S
«—f .
+ т
й *
00 |~ч
2 "з
о -<
J ^J
х +
Я «,
I- &
1— *О
-J о
1/1 ">
>о X
f- On
II +
V
0
i
¦о
R
О
.
<N
ГЛ
¦ч-'
II
Я
ю
00
2*
Ъ
Q
а;
ц а 433
'л
g
S
•
—
к
о Э
я
о
о
VO
V
V
§
*'"
'о
II
а
226

Класс точности
III-D
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
31.269
39.534
44.966
45.043
48.336
50.577
52.324
53.782
55.023
56.079
56.979
57.744
58.398
58.957
59.439
59.857
60.222
60.543
60.827
61.080
61.307
61.513
61.699
61.870
62.028
62.173
62.309
62.436
62.555
62.668
62.775
62.877
62.974
63.068
63.158
63.244
63.328
63.410
63.489
63.567
63.642
63.716
63.789
63.860
63.931
64.000
64.068
64.135
64.202
64.268
64.334
64.399
64.463
64.527
64.591
64.654
64.717
64.780
64.842
64.905
64.967
ХЛОРЦИАН
К°G~) = Р (CD р(С)-р (N) • р~'
Ф°(Г)
Дж ¦ К • моль
165.378
186.644
200.246
200.468
211.170
220.024
227.620
234.296
240.265
245.674
250.625
255.195
259.441
263.408
267.132
270.644
273.966
277.119
280.119
282.981
285.718
288.340
290.858
293.278
295.609
297.856
300.027
302.125
304.156
306.124
308.033
309.886
311.687
313.439
315.143
316.803
318.422
320.000
321.540
323.044
324.514
325.951
327.356
328.732
330.078
331.397
332.690
333.957
335.200
336.420
337.616
338.792
339.946
341.080
342.195
343.290
344.368
345.428
346.472
347.498
348.509
S°(T)
1
194.866
219.139
236.032
236.310
249.755
260.795
270.176
278.354
285.619
292.162
298.119
303.586
308.639
313.336
317.724
321.839
325.714
329.375
332.843
336.139
339.278
342.274
345.140
347.887
350.523
353.058
355.499
357.853
360.126
362.323
364.450
366.510
368.508
370.447
372.331
374.163
375.946
377.682
379.374
381.024
382.635
384.207
385.743
387.245
388.714
390.152
391.559
392.938
394.288
395.613
396.912
398.187
399.438
400.666
401.873
403.059
404.224
405.371
406.497
407.607
408.698
CICN (г)
CICN) ArH°@)= H68
Я°(Г)-Я°@)
н^Дж . моль
2.949
6.499
10.669
10.753
15.434
20.385
25.533
30.841
36.283
41.839
47.493
53.230
59.038
64.907
70.827
76.793
82.797
88.836
94.904
101.000
107.120
113.261
119.421
125.600
131.795
138.005
144.229
150.467
156.716
162.978
169.250
175.532
181.825
188.127
194.438
200.759
207.087
213.424
219.769
226.122
232.482
238.850
245.226
251.608
257.997
264.394
270.797
277.208
283.624
290.048
296.478
302.915
309.358
315.807
322.263
328.725
335.194
341.669
348.150
354.637
361.131
0
-600.9179
-294.6106
¦193.5587
-192.2878
-141,0430
-110.2542
-89.7040
-75.0102
-63.9800
-55.3943
-48.5211
-42.8943
-38.2030
-34.2317
-30.8264
-27.8742
-25.2903
-23.0098
-20.9822
-19.1677
-17.5344
-16.0564
•14.7127
-13.4856
-12.3606
-11.3256
-10.3700
-9.4852
-8.6635
-7.8985
-7.1843
¦6.5162
-5.8899
-5.3014
-4.7475
-4.2252
-3.7319
¦3.2652
-2.8230
-2.4035
-2.0049
-1.6256
-1.2644
-.9200
-.5911
-.2769
.0238
.3118
.5878
.8525
1.1068
1.3511
1.5861
1.8123
2.0302
2.2402
2.4428
2.6384
2.8272
3.0097
3.1863
.118 кДж -моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500 .
5600
5700
5800
5900
6000
Таб
-
3
2
*
=3
с
ч —
II С
§ -'
z'
к
У-
о
+
1
vo 7
5 [2
! i
+ ' V
i
О ^
о4 "*
§ К
q On
I о
н +
s гГ
00 ¦*
u-> ™
<*> X
* с*»
ii +
о
л и
_
'л
§
8
ii
Я
—.
00
rj
-*
z'
к
ц а 434
S
1
о
S
i
|
—i
гч
о
чО
II
0 05
Я
о
о
о
V
V
о
о
¦Л
о
S-1
II
227

Класс точности
1-Е
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
О
29.105
29.206
29.910
29.930
31.154
32.389
33.425
34.245
34.889
35.410
35.858
36.271
36.682
37. ЮР
37.568
38.058
38.579
39.124
39.685
40.253
40.817
41.369
41.899
42.402
42.871
43.303
43.694
44.045
44.354
44.621
44.849
45.039
45.193
45.314
45.404
45.467
45.504
45.519
45.515
45.492
45.455
45.405
45.344
45.273
45.195
45.11
45.021
44.927
44.829
44.730
44.628
44.525
44.421
44.317
44.213
44.108
44.004
43.900
43.796
43.692
43.589
ФОСФИД УГЛЕРОДА СР (г)
KV)=P(Cbp
Ф°(Л
Дж ¦ К ¦ моль
155.117
175.276
186.914
187.094
195.545
202.187
207.700
212.436
216.602
220.327
223.701
226.788
229.636
232.281
234.752
237.073
239.263
241.336
243.308
245.187
246.985
248.709
250.366
251.961
253.500
254.988
256.428
257.823
259.177
260.492
261.771
263.016
264.228
265.409
266.562
267.686
268.785
269.858
270.907
271.933
272.937
273.919
274.881
275.824
276.748
277.653
278.541
279.412
280.266
281.105
281.928
282.736
283.531
284.311
285.078
285.832
286.574
287.303
288.020
288.726
289.421
(Р)р"'(СР)
1
184.188
204.376
216.145
216.330
225.102
232.189
238.190
243.406
248.023
252.163
255.918
259.355
262.528
265.481
268.248
270.856
273.329
275.684
277.936
280.097
282.176
284.181
286.118
287.992
289.806
291.565
293.271
294.927
296.535
298.096
299.612
301.086
302.519
303.911
305.266
306.583
307.864
309.111
310.325
311.507
312.658
313.780
314.873
315.940
316.980
317.994
318.985
319.952
320.897
321.820
322.723
323.606
324.469
325.314
326.142
326.952
327.746
328.524
329.287
330.034
330.768
Д А
г
Н°(Г)-Н°@)
кДж • моль
2.907
5.820
8.715
8.771
11.823
15.001
18.294
21.679
25.137
28.653
32.217
35.823
39.471
43.160
46.894
50.675
54.506
58.391
62.332
66.329
70.382
74.492
78.655
82.871
87.135
91.444
95.794
100.181
1 Л Л ЛЛ 1
104.601
109.050
113.524
118.019
122.531
127.057
131.593
136.137
140.685
145.237
149.788
154.339
158.886
163.430
167.967
172.498
177.021
181.537
186.043
190.541
195.029
199.507
203.975
208.432
212.880
217.316
221.743
226.159
230.565
234.960
239.344
243.719
248.083
г°@) = 509.000
\е.К°(Т)
-268.1637
-135.4457
-91.8294
-91.2818
-69.2402
-56.0423
-47.2640
-41.0094
-36.3311
-32.7026
-29.8083
-27.4474
-25.4861
г23.8319
-22.4187
-21.1981
-20.1338
-19.1981
-18.3696
-17.6311
-16.9691
-16.3726
-15.8327
-15.3419
-14.8940
-14.4838
-14.1069
-13.7596
- \oA6oi
-13.1414
-12.8653
-12.6083
-12.3686
-12.1446
-11.9348
-11.7381
-11.5533
-11.3794
-11.2155
-11.0608
-10.9147
-10.7764
-10.6454
-10.5211
-10.4031
-10.2910
-10.1843
-10.0827
-9.9858
-9.8934
. -9.8051
-9.7207
-9.6401
-9.5628
-9.4888
-9.4179
-9.3499
-9.2846
-9.2219
-9.1616
-9.1036
кДж • моль"'
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ОЙАЛ
ZOxJK)
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 435
'й
- 3
'i l тй
•с -5- R
* ЕЦ О
к * s
EJ v? -1*
оо О
00 ,?. ГЧ
ел ? " ^
ц II V> f*
^ О 00*
с s "
CU и о З
w a." ^
0 {J
as о
¦-, >
< '-,
+
7
•о —
(N О
d S
1 —'
4 • 2
\О 74 О
S "ч *°
° ¦* ^
ч + V
го Н \п
г- °^
с*, о ъ
1 1
оо О »
S ч . з
00 *~<
II +
к,
о
¦©¦
228

Класс точности
V-E
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1690
1690
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
С°(Т)
7.280
15.650
19.789
19.855
22.301
23.610
24.472
25.124
25.662
26.135
26.568
26.974
27.362
27.737
28.103
28.462
28.816
29.131
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200"
27.200
27.200'
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
27.200
*°(r)=P(Si)
Ф°(Г)
Дж . К~ . моль
1.158
4.431
8.020
8.087
11.582
14.797
17.731
20.410
22.870
25.140
27.247
29.213
31.056
32.791
34.430
35.985
37.464
38.737
38.737
39.050
42.036
44.788
47.336
49.707
51.920
53.995
55.947
57.787
59.528
61.179
62.748
64.242
65.667
67.030
68.336
69.587
70.790
71.947
73.061
74.135
75.172
76.174
77.143
78.082
78.992
79.875
80.732
81.564
82.374
83.161
83.928
84.675
85.404
86.114
86.807
87.485
88.146
88.793
КРЕМНИЙ
3.828
11.657
18.810
18.933
25.023
30.152
34.537
38.361
41.752
44.802
47.578
50.130
52.493
54.698
56.767
58.719
60.567
62.152
91.862
92.023
93.577
95.048
96.443
97.770
99.036
100.245
101.402
102.513
103.580
104.606
105.595
106.550
107.472
108.364
109.227
110.064
110.876
111.665
112.431
113.176
113.902
114.608
115.297
115.969
116.624
117.264
117.889
118.501
119.098
119.683
120.256
120.817
121.366
121.905
122.433
122.951
123.460
123.959
Si (к, ж)
Д #°@) = 445.667
S
Н°(Г)-Н°@)
кДж . моль""
.267
1.443
3.217
3.254
5.377
7.678
10.084
12.565
15.105
17.695
20.331
23.008
25.725
28.480
31.272
34.100
36.964
39.572
89.782
90.054
92.774
95.494
98.214
100.934
103.654
106.374
109.094
111.814
114.534
117.254
119.974
122.694
125.414
128.134
130.854
133.574
136.294
139.014
141.734
144.454
147.174
149.894
152.614
155.334
158.054
160.774
163.494
166.214
168.934
171.654
174.374
177.094
179.814
182.534
185.254
187.974
190.694
193.414
-226.9278
-109.7210
-71.0510
-70.5648
-50.9746
-39.2217
-31.3903
-25.8005
-21.6119
-18.3576
-15.7571
-13.6320
-11.8635
-10.3692
-9.0903
-7.9836
-7.0168
¦6.2463
-6.2463
-6.1744
-5.5042
-4.9054
-4.3672
-3.8810
-3.4395
-3.0370
-2.6684
-2.3298
-2.0176
-1.7289
-1.4611
-1.2121
-.9799
-.7630
-.5599
-.3692
-.1900
-.0213
.1380
.2884
.4308
.5658
.6938
.8155
.9313
1.0416
1.1467
.2470
.3429
.4346
.5224
.6066
.6872
.7646
.8390
.9105
.9792
2.0454
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1690
1690
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3590
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
ос
С
и
+
а
ч»
"О
О
1
¦Й
V
§
о
I
>¦
(X
С*
:*
р*
II
Та
о
°
X
С/5
О
5;
t.
¦^
О
2
v>
ми
+
с
блица
о
II
Ьй
~«
00
OJ
и*
_
1
о
*
1
Я к
1 а
VO -
V 2
\ / W
V '
« х
оо ?
?! <1
Т +
7 Я
II ^*
- и
fa
«.
436
I
л
о
к
"
.а-
^3
о
•Л
V
V
о
О\
ЧО
^н
V*
о
II
229

Класс точности
I
КРЕМНИЙ Si (г)
Таблица 437
К
S°(T)
Дж . К~! . моль
Я'
кДж • моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
28.022
23.796
22.251
22.234
21.613
21.316
21.153
21.057
21.000
20.971
20.968
20.989
21.033
21.099
21.183
21.282
21,394
21.513
21.638
21.764
21.889
22.011
22.129
22.241
22.346
22.444
22.535
22.617
22.692
22.759
22.819
22.872
22.918
22.958
22.992
23.021
23.046
23.065
23.080
23.092
23.100
23.106
23.108
23.109
23.107
23.104
23.099
23.093
23.086
23.078
23.070
23.061
23.052
23.044
23.036
23.028
23.021
23.015
23.009
23.005
23.003
113.368
132.193
142.546
142.703
149.858
155.245
159.553
163.136
166.200
168.876
171.251
173.384
175.322
177.096
178.733
180.252
181.671
183.001
184.253
185.438
186.561
187.629
188.648
189.621
190.555
191.450
192.312
193.141
193.941
194.714
195.462
196.186
196.888
197.569
198.230
198.873
199.499
200.108
200.701
201.279
201.844
202.394
202.932
203.458
203.972
204.476
204.968
205.450
205.922
206.385
206.838
207.283
207.720
208.148
208.568
208.981
209.387
209.786
210.178
210.563
210.942
140.776
158.707
167.870
168.007
174.306
179.094
182.964
186.217
189.025
191.496
193.706
195.705
197.533
199.219
200.785
202.250
203.627
204.928
206.161 .
207.334
208.454
209.525
210.551
211.537
212.486
213.400
214.283
215.135
215.959
216.756
217.529
218.278
219.005
219.711
220.396
221.063
221.712
222.344
222.959
223.559
224.144
224.714
225.271
225.815
226.346
226.865
227.373
227.870
228.356
228.832
229.298
229.755
230.202
230.641
231.072
231.495
231.909
232.317
232.717
233.110
233.497
2.741
5.303
7.550
7.591
9.780
11.924
14.047
16.157
18.260
20.358
22.455
24.552
26.653
28.760
30.874
32.997
35.131
37.276
39.433
41.603
43.786
45.981
48.188
50.407
52.636
54.876
57.125
59.382
61.648
63.921
66.199
68.484
70.774
73.067
75.365
77.666
79.969
82.275
84.582
86.891
89.200
91.511
93.821
96.132
98.443
100.754
103.064
105.373
107.682
109.991
112.298
114.604
116.910
U9.215
121.519
123.822
126.125
128.426
130.728
133.028
135.329
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
о
о
оо
о
1
1
X
о
СП
О
0.0
х
_с
18.2
+
т
0.5
+
5.24
i
х
00
я
О
О
о
V
V
о
о
in
1
О
t
(-N
II
X
230

КРЕМНИЙ Si (г)
Таблица 437
(окончание)
с; (Г)
к
Дж ¦ к
кДж . моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
23.002
23.007
23.021
23.043
23.075
23.118
23.171
23.236
23.312
23.401
23.503
23617
23.743
23.882
24.034
24.197
24.373
24.559
24.757
24.965
211.682
212.399
213.094
213.769
214.424
215.062
215.682
216.286
216.875
217.449
218.010
218.558
219.093
219.616
220.129
220.630
221.122
221.603
222.076
222.540
234.251
234.982
235.690
236.377
237.046
237.696
238.330
238.949
239.554
240.145
240.724
241.292
241.849
242.396
242.935
243.465
243.987
244.502
245.011
245.513
139.929
144.530
149.132
153.739
158.350
162.970
167.598
172.239
176.893
181.564
186.255
190.966
195.702
200.464
205.256
210.079
214.936
219.828
224.760
229.732
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
+
1
к
о
0.03i
I
X
3!
.52
>о
сч
+
те
л
с:
о
i
-0.16'
1
"s
о
гч
о
§
о
V
V
§
о
231

Класс точности
I--A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
C°pV)
24.338
24.304
22.943
22.201
21.773
21.509
21.337
21.219
21.134
21.072
21.025
20.989
20.960
20.937
20.918
20.903
20.890
20.879
20.870
20.862
20.855
20.849
20.844
20.839
20.835
20.831
20.828
20.825
20.823
20.820
20.818
20.816
20.814
20.813
20.811
20.810
20.809
20.808
20.807
20.807
20.806
20.806
20.806
20.806
20.806
20.807
20.808
20.809
20.811
20.813
20.815
20.819
20.822
20.827
20.832
20.838
20.844
20.852
20.860
ПОЛОЖИТЕЛЬНЫЙ ИОН
*-(г,-,(а,.р->
Ф°(Г)
Дж - К .моль
138.688
138.840
145.894
151.290
155.634
159.258
162.362
165.074
167.479
169.640
171.600
173.393
175.046
176.579
178.007
179.344
180.601
181.786
182.908
183.973
184.987
185.953
186.877
187.761
188.610
189.425
190.210
190.966
191.696
192.401
193.083
193.743
194.384
195.004
195.608
196.194
196.764
197.318
197.859
198.386
198.899
199.401
199.890
200.369
200.836
201.294
201.741
202.179
202.608
203.028
203.441
203.845
204.241
204.630
205.012
205.387
205.755
206.117
206.473
(e>.p-W>
S°(T)
163.316
163.467
170.252
175.284
179.290
182.625
185.486
187.991
190.222
¦ 192.234
194.065
195.747
197.301
198.746
200.097
201.364
202.559
203.688
204.759
205.777
206.747
207.674
208.561
209.412
210.229
211.016
211.773
212.504
213.210
213.893
214.554
215.194
215.816
216.419
217.005
217.575
218.130
218.671
219.198
219.712
220.213
220.702
221.181
221.648
222.106
222.553
222.991
223.420
223.841
224.253
224.657
225.053
225.443
225.825
226.200
226.569
226.931
227.288
227.638
Н°(Т)-Н
КРЕМНИЯ Si+ (г)
Д //с@)= 786.515
°@)
кДж . моль
7.343
7.388
9.743
11.997
14.194
16.357
18.499
20.626
22.743
24.854
26.958
29.059
31.156
33.251
35.344
37.435
39.525
41.613
43.701
45.787
47.873
49.958
52.043
54.127
56.211
58.294
60.377
62.460
64.542
66.624
68.706
70.788
72.869
74.951
77.032
79.113
81.194
83.275
85.356
87.436
89.517
91.597
93.678
95.759
97.839
99.920
102.001
104.081
106.162
108.243
110.325
112.407
114.489
116.571
118.654
120.738
122.822
124.906
126.992
137.9896
137.1334
102.5907
81.8066
67.9124
57.9613
50.4781
44.6424
39.9616
36.1219
32.9140
30.1925
27.8539
25.8220
24.0397
22.4631
21.0582
19.7982
18.6614
17.6305
16.6910
15.8312
15.0412
14.3128
13.6388
13.0134
12.4313
11.8881
11.3800
10.9037
10.4561
10.0347
9.6372
9.2617
8.9062
8.5692
8.2493
7.9451
7.6555
7.3795
7.1160
6.8643
6.6234
6.3928
6.1718
5.9597
5.7560
5.5603
5.3719
5.1906
5.0159
4.8474
4.6848
4.5278
4.3761
4.2295
4.0875
3.9501
3.8171
кДж ¦ моль
Т
к
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
i
л
о
X
X
«¦> S
<? 2
оо гч'
я я
оо ._, ¦
U
52
0
<
+
f
X
гч
00
СО 1
гч ¦*¦
2 §
1 2
1 |
§ ->
о #
+ ^
о
2 а
го го
Р
0
©
i
§
1
¦
X
о
¦ч-
It
2
—<
00
гч
и
+55
•у
0
ч
<]
Л 1 Q
ц а 43о
_
л
о
S
-'
.X
it
%?
g
О
V
S-,
V
о
¦о
II
232

ПОЛОЖИТЕЛЬНЫЙ ИОН КРЕМНИЯ Si+ (г)
Таблица 438
(окончание)
S°(T)
к
6200
6400
6600
6890
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
_ ,.-1 -1
Дж ¦ К ¦ моль
Н°(Т)-Н°@)
кДж • моль
-1
К
20.880
20.905
20.934
20.968
21.008
21.055
21.107
21.167
21.233
21.307
21.388
21.476
21.572
21.676
21.787
24.906
22.032
22.165
22.306
22.454
207.167
207.838
208.489
209.J20
209.732
210.328
210.907
211.470
212.019
212.554
213.076
213.585
214.083
214.569
215.045
215.511
215.966
216.413
216.851
217.280
228.323
228.986
229.629
230.255
230.863
231.456
232.033
232.597
233.148
233.686
234.213
234.730
235.236
235.733
236.222
236.702
237.174
237.640
238.098
238.550
131.166
135.344
139.528
143.718
147.916
152.122
156.338
160.565
164.805
169.059
173.328
177.615
181.920
186.244
190.590
194.960
199.353
203.773
208.220
212.696
3.5630
3.3238
3.0982
2.8850
2.6831
2.4917
2.3099
2.1370
.9723
.8152
.6652
.5217
.3844
.2528
.1265
.0053
.8888
.7767
.6688
.5648
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о 5
о *7
§ ч
О m
5
ё
О
О
О
V
«' v
г-
"*.
ГЦ
II
+
<3\
¦*
1
¦о
II
я
233

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
i 5400
5500
5600
5700
5800
5900
6000
С°(Т)
п
г
ДИКРЕМНИЙ Si2 (г)
К°(Г)= p2(Si)p"'(Si2)
Ф°(Г)
S°(T)
Дж . К~ . моль"
29.412
32.185
34.470
34.505
36.303
38.165
40.062
41.761
43.098
44.033
44.607
44.899
44.990
44.949
44.828
44.662
44.477
44.287
44.103
43.928
43.767
43.619
43.485
43.364
43.256
43.158
43.070
42.989
42.915
42.845
42.778
42.713
42.647
42.579
42.509
42.434
42.354
42.269
42.176
42.076
41.969
41.853
41.729
41.597
41.456
41.308
41.151
40.987
40.816
40.639
40.455
40.265
40.070
39.870
39.667
39.459
39.248
39.035
38.820
38.603
38.384
166.071 195.208
186.457 216.379
198.618 229.687
198.810 229.900
207.905 240.075
215.192 248.374
221.330 255.501
226.670 261.808
231.423 267.476
235.719 272.610
239.645 277.282
243.263 281.549
246.619 285.461
249.747 289.061
252.676 292.388
255.427 295.475
258.021 298.352
260.474 301.043
262.798 303.569
265.007 305.948
267.111 308.198
269.119 310.329
271.039 312.355
272.877 314.286
274.641 316.129
276.336 317.892
277.967 319.584
279.539 321.207
281.055 322.769
282.520 324.274
283.936 325.726
285.307 327.127
286.635 328.482
287.923 329.794
289.173 331.064
290.388 332.295
291.568 333.489
292.717 334.648
293.836 335.774
294.925 336.869
295.987 337.932
297.023 338968
298.033 339.975
299.020 340.955
299.984 341.910
300.926 342.840
301.847 343.746
302.748 344.629
303.630 345.490
304.493 346.330
305.338 347.149
306.165 347.948
306.976 348.728
307.771 349.490
308.551 350.233
309.315 350.959
310.065 351.668
310.801 352.361
311.524 353.038
312.233 353.700
312.929 354.347
А Я°@)= 330.000 кДж • моль"
Н°(Г)-Н°@)
кДж . моль
2.914
5.984
9.263
9.327
12.868
16.591
20.503
24.596
28.843
33.202
37.637
42.114
46.610
51.108
55.597
60.072
64.529
68.967
73.387
77.788
82.173
86.542
90.897
95.239
99.570
103.891
108.202
112.505
116.800
121.088
125.369
129.644
133.912
138.173
142.428
146.675
150.914
155.146
159.368
163.581
167.783
171.974
176.153
180.319
184.472
188.610
192.733
196.840
200.930
205.003
209.058
213.094
217.111
221.108
225.084
229.040
232.976
236.890
240.783
244.654
248.503
lg.K°(T)
-169.2032
-82.1155
-53.2970
-52.9341
-38.2974
-29.4966
-23.6215
-19.4220
-16.2720
-13.8228
-11.8646
-10.2637
-8.9307
-7.8038
-6.8387
-6.0029
-5.2720
-4.6274
-4.0546
-3.5423
-3.0813
-2.6641
-2.2849
-1.9385
-1.6209
-1.3286
-1.0586
-.8085
-.5761
-.3596
-.1573
.0321
.2098
.3769
.5343
.6828
.8233
.9563
1.0826
1.2023
1.3163
1.4249
1.5284
1.6272
1.7217
1.8121
1.8987
1.9817
2.0614
2.1379
2.2115
2.2824
2.3506
2.4164
2.4798
2.5411
2.6002
2.6574
2.7128
2.7664
2.8183
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 439
1
¦ -
о
'л ?
1 А '-
• X §
X "> ^
R * -'
^ ¦*' 'а
f-t СЛ ^ Jg
"! vo i^ "
SO "Л V On
"¦> и 5) 2
н Jl; -j <*.
^ о °о *°
"< „ СТ\
fc.CN Ч
¦" ^1 0 Э
1
« т
Ч f
+1 ¦
<ч V
'к а
о К ^
1? Ч о
о- s v
1
* °\ V
•S _. о
О> X °
2 3 ^
00 М V"
3 2 ^
СП (N
II 1
0
234

Класс точности
VI-F
ТРИКРЕМНИЙ Si3 (г)
Таблица 440
Ar°G-)=p3(Si)p(Si3)
: 702.001 кДж • моль"
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Ф°(Г)
S°(T)
Дж -К .моль
Н°(Т)-Н°@)
кДж . моль
1?АГ°(Г)
44.624
52.821
56.863
56.915
58.961
60.069
60.727
61.167
61.529
61.916
62.403
63.041
63.849
64.820
65.926
67.126
68.372
69.618
70.820
71.943
72.961
73.858
74.626
75.264
75.778
76.177
76.473
76.679
76.809
76.876
76.891
76.867
76.811
76.733
76.638
76.533
76.420
76.305
76.188
76.072
75.958
75.846
75.738
75.632
75.529
75.428
75.330
75.233
75.138
75.043
74.950
74.856
74.762
74.667
74.572
74.476
74.378
74.279
74.179
74.077
73.973
177.927
205.253
223.130
223.420
237.310
248.616
258.167
266.442
273.743
280.279
286.196
291.606
296.593
301.223
305.547
309.609
313.443
317.078
320.536
323.837
326.998
330.031
332.949
335.760
338.474
341.096
343.634
346.093
348.478
350.793
353.042
355.229
357.356
359.427
361.445
363.412
365.331
367.203
369.030
370.816
372.561
374.267
375.936
377.569
379.169
380.735
382.269
383.773
385.248
386.695
388.114
389.507
390.874
392.217
393.537
394.834
396.108
397.361
398.593
399.806
400.998
214.240
247.996
269.934
270.286
286.971
300.259
311.274
320.670
328.861
336.130
342.677
348.654
354.172
359.320
364.164
368.753
373.124
377.307
381.321
385.180
388.897
392.479
395.933
399.265
402.479
405.581
408.575
411.465
414.256
416.953
419.560
422.080
424.520
426.883
429.172
431.392
433.546
435.639
437.672
439.650
441.574
443.448
445.275
447.056
448.793
450.489
452.146
453.765
455.348
456.896
458.412
459.895
461.347
462.771
464.165
465.533
466.874
468.190
469.480
470.748
471.992
3.631
8.549
13.954
14.060
19.865
25.821
31.864
37.960
44.095
50.266
56.481
62.752
69.095
75.527
82.064
88.716
95.490
102.390
109.412
116.551
123.797
131.139
138.565
146.060
153.613
161.212
168.845
176.504
184.179
191.863
199.552
207.240
214.924
222.602
230.270
237.929
245.577
253.213
260.838
268.451
276.052
283.642
291.221
298.790
306.348
313.896
321.433
328.962
336.480
343.989
351.489
358.979
366.460
373.932
381.393
388.846
396.289
403.722
411.144
418.557
425.960
-358.2115
-173.3477
-112.3038
-111.5359
-80.5834
-61.9956
-49.5967
-40.7369
-34.0901
-28.9193
-24.7821
-21.3969
-18.5759
-16.1891
-14.1438
-12.3718
-10.8219
-9.4552
-8.2413
-7.1560
-6.1801
-5.2981
-4.4972
-3.7668
-3.0980
-2.4835
-1.9170
-1.3931
-.9072
-.4554
-.0343
.3592
.7277
1.0735
1.3985
1.7047
1.9935
2.2664
2.5247
2.7695
3.0019
3.2226
3.4327
3.6328
3.8237
4.0059
4.1800
4.3466
4.5061
4.6590
4.8056
4.9463
5.0815
5.2116
5.3367
5.4571
5.5732
5.6851
5.7930
5.8973
5.9979
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
и в
— о ¦
о
а:
3
1
ГО
ГО
rs
о
о
*
,4
X
^1
rs
¦JJ
¦ч-
V
V
То
235

Класс точности
1-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
520ft
5300
5400
5500
5600
5700
5800
5900
6000
п
г
29.105
29.204
29.901
29.921
31.139
32.370
33.405
34.220
34.852
35.344
35.731
36.040
36.291
36.498
36.671
36.818
36.944
37.055
37.152
37.238
37.317
37.388
37.453
37.513
37.570
37.623
37.673
37.721
37.767
37.811
37.855
37.897
37.939
37.981
38.024
38.067
38.112
38.158
38.207
38.260
38.316
38.377
38.443
38.515
38.595
38.682
38.778
38.884
39.001
39.129
39.270
39.424
39.592
39.775
39.973
40.189
40.421
40.670
40.938
41.225
41.530
ОКСИД КРЕМНИЯ SiO (г)
/:oG-) = p(Si)p@)-p(Si0)
Ф°(Г)
Дж • К~ . моль"
150.461
170.621
182.259
182.440
190.890
197.530
203.042
207.777
211.941
215.664
219.036
222.121
224.964
227.603
230.066
232.375
234.549
236.603
238.550
240.401
242.164
243.849
245.461
247.008
248.493
249.922
251.299
252.628
253.912
255.154
256.356
257.522
258.652
259.751
260.819
261.857
262.868
263.853
264.814
265.750
266.665
267.558
268.431
269.285
270.120
270.938
271.739
272.523
273.293
274.047
274.787
275.514
276.227
276.928
277.617
278.294
278.960
279.616
280.261
280.896
281.522
S°(T)
1
179.535
199.722
211.489
211.674
220.443
227.527
233.523
238.736
243.349
247.484
251.228
254.649
257.796
260.709
263.420
265.956
268.336
270.579
272.700
274.711
276.623
278.445
280.186
281.852
283.450
284.985
286.461
287.884
289.257
290.583
291.865
293.107
294.311
295.479
296.614
297.717
298.790
299.834
300.853
301.846
302.815
303.762
304.688
305.593
306.479
307.348
308.199
309.034
309.854
310.659
311.451
312.230
312.997
313.753
314.499
315.234
315.960
316.678
317.388
318.090
318.785
Дг Я°@) = 792.450 кДж • моль"'
Я°(Г)-Я°@)
кДж • моль
2.907
5.820
8.715
8.770
11.821
14.998
18.289
21.672
25.127
28.637
32.192
35.781
39.398
43.038
46.697
50.371
54.059
• 57.760
61.470
65.190
68.917
72.653
76.395
80.143
83.897
87.657
91.422
95.191
98.966
102.745
106.528
110.316
114.107
117.903
121.704
125.508
129.317
133.131
136.949
140.772
144.601
148.436
152.277
156.124
159.980
163.844
167.716
171.600
175.494
179.400
183.320
187.254
191.205
195.173
199.160
203.168
207.199
211.253
215.333
219.441
223.579
\е.К°(Т}
-409.9227
-202.2149
-133.6777
-132.8156
-98.0519
-77.1618
-63.2171
-53.2454
-45.7592
-39.9314
-35.2653
-31.4447
-28.2585
-25.5606
-23.2466
-21.2397
-19.4826
-17.9311
-16.5512
-15.3157
-14.2030
-13.1956
-12.2791
-11.4418
-10.6738
-9.9667
-9.3135
-8.7083
-8.1459
-7.6219
-7.1325
-6.6744
-6.2445
-5.8405
-5.4599
¦5.1008
-4.7614
-4.4401
-4.1355
-3.8463
-3.5713
-3.3096
-3.0602
-2.8221
-2.5948
-2.3774
-2.1692
-1.9698
-1.7786
-1.5950
-1.4187
-1.2492
-1.0860
-.9290
-.7776
-.6317
-.4909
-.3550
-.2236
-.0967
.0261
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
1
Таблица 441 ¦
Т
§ ' -
? ч '*
* * о
*? ^ •
¦ч 00 ~ч
О 00 1. .
о о-. а
ON Ч 1
^ О и К
о. 2 ^ ч
¦* II *2 12
" я 2 «•
|§ о °°
U О" * 5
СЛ W С^э
%* w
< *Ц
? 7
я а
4 i
О 2
с* 1
¦« *
7310.
Дж-
эоок;
S пн
Ш ° v
i 12
¦* + v
? n о
,_ W О
о *2 "о
р *. ¦'"
S 2 'о
+ i Т
Г- X ^
W) 00
с- О II
II +
/».
(^
О
236

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
848
848
900
1000
1100
1200
1200
1300
1400
1500
1600
1700
1800
1900
1996
1996
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
Ф°(Г)
с;(г)
15.690
32.640
44.602
44.719
53.422
60.585
64.522
68.063
76.391
84.070
67.446
67.953
68.941
69.940
70.947
71.199
71.743
72.249
72.739
73.232
73.740
74.271
74.832
75.403
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
83.500
= -406.6634-
*V) = p(SiO2)
Ф°(Г)
Дж • К~ . моль
3.334
10.607
18.264
18.408
26.021
. 33.262
40.106
46.535
52.582
55.378
55.378
58.351
63.765
68.822
73.567
73.567
78.182
82.533
86.648
90.552
94.265
97.808
101.194
104.312
104.312
104.449
107.803
111.033
114.148
117.154
120.059
122.868
125.589
128.226
130.784
133.267
135.680
138.026
140.309
142.533
144.699
146.812
148.872
150.884
152.849
154.769
156.647
158.483
160.281
162.041
163.765
165.454
167.110
ДИОКСИД
S°{T)
1
9.694
26.087
41.460
41.736
55.743
68.500
79.929
90.118
99.662
104.319
104.803
108.832
116.042
122.660
128.789
130.672
136.393
141.728
146.730
151.440
155.895
160.124
164.155
167.857
172.667
172.834
176.908
180.792
184.504
188.058
191.466
194.741
197.893
200.929
203.860
206.690
209.428
212.079
214.649
217.141
219.562
221.914
224.202
226.429
228.598
230.712
232.774
234.786
236.750
238.670
240.547
242.382
244.177
- 122.698 lnx+ 0.0148775* - 3
- 46540.75л:3 + 295207.4х4 Дж • К • моль (х =
Ф°(Л
(х = Т-
КРЕМНИЯ SiO2 (к, ж)
н°(Т)-нЧо)
кДж • моль
.636
3.096
6.916
6.999
11.889
17.619
23.894
30.508
37.664
41.503
41.913
45.433
52.278
59.222
66.266
68.526
75.673
82.873
90.123
97.421
104.769
112.170
119.625
126.836
136.436
136.770
145.120
153.470
161.820
170.170
178.520
186.870
195.220
203.570
211.920
220.270
228.620
236.970
245.320
253.670
262.020
270.369
278.719
287.069
295.419
303.769
312.119
320.469
328.820
337.169
345.520
353.869
362.219
Г°@)= 585.000
«V,
-297.4608
-143.9481
-93.3478
-92.7119
-67.0935
-51.7353
-41.5120
-34.2231
-28.7684
-26.6125
¦26.6125
-24.5403
-21.1660
-18.4101
-16.1178
¦16.1178
-14.4001
-12.7379
-11.3000
-10.0443
-8.9387
-7.9579
-7.0824
-6.1809
¦6.1809
-6.2966
-5.5994
-4.9680
-4.3938
-3.8694
-3.3889
-2.9471
-2.5395
-2.1626
-1.8130
-1.4880
-1.1852
-.9025
-.6379
-.3899
-.1570
.0621
.2685
.4633
.6473
.8214
.9863
1.1428
1.2913
1.4325
1.5669
1.6949
1.8169
.12166л: + 2962.835Х - 6132
Г-10; 298.15
< Т < 848К
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
848
848
900
1000
1100
1200
1200
1300
1400
1500
1600
1700
1800
1900
1996
1996
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
85л:2 -
)
= 181.9124 + 58.422 1пх+ 0.0009635х~2 + 1.11147л: + 51.63л: Дж • К- моль
10; 848 < Т
< 1200К)
С)
ОС
р
II
Т
1
1
+
<ч
'к
00
*Л
сч
гч
о
X.
в
оо
«о
с—
+
О\
т.
сч
II
?
о
Л
W
Таблица
_
i
§
2
О
1
о
X
О
0
'л
1
'а
(Ч
00
¦ч-
к
«о
о
со
1
с;
о
1
о
о
II
я
ц
X
ГЧ
(Ч
о
а;
_
'л
о
1
~
Я 7
о? m
°^ m
сч
V °.
f-c +
V х
о -3
гч •
~* 00
1 <N
О ГЧ
г" О1
*"*¦ гч
II «N
•~ II
0
442
-
'л
о
1
к
ОС
Г4!
ГО*
о а;
Со
Я
о
¦ч-
v
V
OV
СЛ
ЧГ
1
О
II
237

Класс точности
V-I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900 .
6000
С°(Т)
31.218
38.782
44.054
44.140
48.261
51.419
53.775,
55.520
56.821
57.805
58.559
59.147
59.613
59.987
60.291
60.541
60.749
60.924
61.073
61.199
61.308
61.403
61.485
61.557
61.621
61.678
61.728
61.773
61.813
61.849
61.882
61.912
61.939
61.964
61.986
62.007
62.026
62.044
62.060
62.075
62.089
62.101
62.113
62.125
62.135
62.145
62.154
62.162
62.170
62.178
62.185
62.192
62.198
62.204
62.210
62.215
62.220
62.225
62.229
62.234
62.238
К°(Т)= p(Si)p
Ф°G)
Дж ¦ К ¦ моль
158.542
179.768
193.250
193.469
204.038
212.806
220.372
227.060
233.069
238.534
243.549
248.185
252.497
256.528
260.313
263.880
267.255
270.456
273.500
276.402
279.176
281.831
284.378
286.824
289.179
291.448
293.637
295.752
297.798
299.779
301.698
303.561
305.370
307.127
308.837
310.500
312.121
313.701
315.241
316.745
318.213
319.647
321.049
322.421
323.762
325.076
326.362
327.623
328.858
330.070
331.258
332.424
333.569
334.694
335.798
336.883
337.949
338.998
340.029
341.044
342.042
ДИОКСИД
2(O)-/T'(SiO2
sV)
1
188.028
212.090
228.609
228.882
242.169
253.294
262.888
271.315
278.818
285.570'
291.701
297.311
302.478
307.265
311.722
315.890
319.804
323.493
326.979
330.285
333.427
336.420
339.279
342.014
344.635
347.151
349.572
351.902
354.149
356.319
• 358.416
360.446
362.412
364.318
366.168
367.965
369.713
371.412
373.067
374.679
376.251
377.784
379.281
380.743
382.171
383.568
384.933
386.270
387.579
388.861
390.117
391.349
392.557
393.741
394.904
396.046
397.167
398.268
399.350
' 400.414
401.460
КРЕМНИЯ SiO2
) \»<
Я°(Г)-Я°@)
кДж ¦ моль
2.949
6.464
10.542
10.624
15.252
20.244
25.509
30.979
36.599
42.332
48.152
54.039
59.977
65.958
71.972
78.014
84.079
90.163
96.263
102.377
108.503
114.638
120.783
126.935
133.094
139.259
145.429
151.604
157.784
163.967
170.153
176.343
182.536
188.731
194.928
201.128
207.330
213.533
219.738
225.945
232.153
238.363
244.574
250.785
256.998
263.212
269.427
275.643
281.860
288.077
294.295
300.514
306.734
312.954
319.175
325.396
331.617
337.840
344.062
350.286
356.509
(г)
@)= 1259
lgAT°G-)
-648.5962
-318.0328
-208.9261
-207.5536
-152.2138
-118.9660
-96.7787
-80.9184
-69.0160
-59.7540
-52.3415
-46.2747
-41.2176
-36.9374
-33.2678
-30.0869
-27.3031
-24.8463
-22.6621
-20.7075
-18.9481
-17.3559
-15.9082
-14.5862
-13.3741
¦12.2588
-11.2290
-10.2754
-9.3897
-8.5649
-7.7949
-7.0745
-6.3989
-5.7641
-5.1665
-4.6030
-4.0706
-3.5668
-3.0895
-2.6365
-2.2060
-1.7964
-1.4062
-1.0341
-.6787
-.3391
-.0141
.2972
.5956
.8819
1.1568
1.4211
1.6753
1.9199
2.1557
2.3829
2.6021
2.8136
3.0180
3.2155
3.4065
.950 кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
-1
-
п
о
g
В О
Г- CN
~- (N
d 1
«* ?! ii
СО ~
о 1 д
^ И ¦ 1/1
И О 00
^ и сч
9 «
^* s
5; о""
*—* j;
|
Я '-
3. |
V 's/
is ч
О 00
о ">
° 5
X +
? сч
г- J2
О оо
± j
•* н
ON "Л
¦л ¦*.
m 2
II +
fc.
0
0
ц а 443
-
'л
о
i
00
fN
ГЛ
1)
о ?
I
V
&"
V
о
i
о
t
*-
II
238

Класс точности
И-С
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
, 4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
32.349
30.750
30.054
30.048
30.027
30.472
31.172
31.954
32.719
33.422
34.053
34.617
35.124
35.588
36.021
36.432
36.829
37.218
37.602
37.983
38.362
38.739
39.115
39.489
39.858
40.223
40.582
40.932
41.273
41.601
41.916
42.214
42.495
42.755
42.994
43.209
43.398
43.562
43.698
43.807
43.887
43.939
43.963
43.959
43.927
43.870
43.787
43.679
43.549
43.398
43.227
43.037
42.830
42.608
42.372
42.124
41.864
41.595
41.318
41.034
40.744
K°(T) = p(Si)-p(
Ф°(Г)
Дж . К~' . моль
133.751
154.985
167.271
167.461
176.258
183.056
188.610
193.322
197.429
201.078
204.369
207.372
210.137
212.702
215.096
217.343
219.461
221.465
223.368
225.180
226.912
228.570
230.161
231.691
233.165
234.588
235.963
237.293
238.584
239.836
241.052
242.235
243.386
244.508
245.602
246.670
247.713
248.732
249.728
250.703
251.657
252.591
253.506
254.403
255.283
256.145
256.992
257.822
258.637
259.438
260.224
260.996
261.756
262.501
263.234
263.955
264.664
265.360
266.046
266.720
267.384
ГИДРИД
Н>.,-'(ЯН
sV)
163.911
185.821
197.943
198.129
206.756
213.498
219.113
223.977
228.294
232.189
235.744
239.016
242.051
244.880
247.534
250.033
252.397
254.642
256.780
258.823
260.781
262.662
264.472
266.219
267.908
269.542
271.127
272.665
274.160
275.614
277.030
278.409
279.754
281.065
282.345
283.595
284.815
286.006
287.170
288.306
289.416
290.501
291.560
292.594
293.605
294.592
295.555
296.495
297.413
298.310
299.185
300.039
300.873
301.687
302.481
303.256
304.013
304.751
305.473
306.176
306.864
КРЕМНИЯ
)
Н°(Г)-Н
SiH (г)
ДгЯ°@)= 294.760
°@)
кДж . моль
3.016
6.167
9.145
9.200
12.199
15.221
18.302
21.458
24.692
28.000
31.374
34.808
38.296
41.832
45.412
49.035
52.698
56.401
60.142
63.921
67.738
71.593
75-486
79.416
83.384
87.388
91.428
95.504
99.614
103.758
107.934
112.141
116.376
120.639
124.926
129.237
133.567
137.916
142.279
146.654
151.039
155.431
159.826
164.222
168.617
173.007
177.390
181.763
186.125
190.473
194.804
199.117
203.411
207.683
211.932
216.157
220.356
224.529
228.675
232.793
236.882
-151.3150
-73.7058
-48.0309
-47.7075
-34.6505
-26.7836
-21.5186
-17.7444
-14.9045
-12.6891
-10.9119
-9.4541
-8.2365
-7.2039
-6.3170
-5.5469
-4.8719
-4.2752
-3.7440
-3.2679
-2.8388
-2.4501
-2.0962
-1.7727
-1.4758
-1.2024
-.9498
-.7157
-.4981
-.2954
-.1061
.0710
.2372
.3934
.5404
.6791
.8101
.9340
1.0514
1.1628
.2686
.3693
.4652
.5566
.6438
.7272
.8070
.8833
.9565
2.0267
2.0941
2.1589
2.2212
2.2811
2.3389
2.3946
2.4483
2.5002
2.5503
2.5988
2.6457
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
i
А
- О
I 5
\а .
| i
m on «
О чо ^
Я || ' й
II ,-. -!
^ - ON
См (N
ЕС *-
S?. X
о с/э
^ о
<" Ч
+
I I
о
+ 7
<ч а
Н "
СЧ "
ON (*1
о ё
о оо
° r-i
1 *—1
я J
г- X
t— о
^ !2
ГО «-И
ON Я
гч 2
И +
?¦,
0
ц а 444
-
'л
о
%
«л
оо
II
о §
to
о
V
fr-
V
о
о
«о
t
239

Класс точности
IV-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
i 3200
: ззоо
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
j 5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<7)
33.259
33.599
35.502
35.557
39.385
44.077
48.434
51.834
54.209
55.752
56.709
57.284
57.619
57.810
57.916
57.971
57.998
58.010
58.014
58.015
58.015
58.016
58.018
58.022
58.029
58.037
58.048
58.062
58.077
58.094
58.113
58.134
58.156
58.179
58.204
58.230
58.257
58.284
58.312
58.341
58.369
58.399
58.428
58.457
58.486
58.515
58.544
58.573
58.601
58.628
58.656
58.682
58.708
58.734
58.759
58.783
58.806
58.829
58.851
58.872
58.893
ДИГВДРИД КРЕМНИЯ SiH2
К°(Т)= p(Si)-J
Ф°(Г)
Дж . К . моль"
137.371
160.430
173.778
173.986
183.785
191.649
198.364
204.315
209.704
214.649
219.224
223.484
227.469
231.210
234.734
238.065
241.220
244.219
247.073
249.797
252.401
254.895
257.288
259.588
261.801
263.935
265.993
267.981
269.904
271.767
273.572
275.322
277.022
278.674
280.281
281.845
283.368
284.853
286.301
287.714
289.094
290.442
291.760
293.048
294.309
295.544
296.753
297.938
299.100
300.239
301.356
302.452
303.529
304.586
305.625
306.645
307.649
308.635
309.605
310.560
311.499
(г)
^(Hj-p'^SiHj) Д Я°@)= 630.735
Г
S°(T)
1
Я°(Г)-Я°@)
кДж . моль
170.629 3.326
193.733 6.661
207.438 10.036
207.657 10.101
218.374 13.836
227.663 18.007
236.096 22.639
243.831 27.662
250.919 32.972
257.399 38.476
263.327 44.103
268.761 49.805
273.761 55.551
278.382 61.324
282.670 67.111
286.668 72.905
290.410 78.704
293.927 84.504
297.243 90.306
300.380 96.107
303.355 101.909
306.186 107.710
308.885 113.512
311.464 119.314
313.933 125.116
316.302 130.920
318.579 136.724
320.770 142.529
322.882 148.336
324.920 154.145
326.890 159.955
328.796 165.767
330.642 171.582
332.432 177.399
334.169 183.218
335.856 189.039
337.497 194.864
339.094 200.691
340.648 206.520
342.163 212.353
343.641 218.189
345.082 224.027
346.490 229.868
347.865 235.713
349.209 241.560
350.524 247.410
351.810 253.263
353.070 259.119
354.303 264.977
355.512 270.839
356.697 276.703
357.859 282.570
358.998 288.439
360.117 294.312
361.215 300.186
362.293 306.063
363.353 311943
364.394 317.824
365.417 323.708
366.423 329.595
367.413 335.483
-323.2824
-157.2696
-102.3308
-101.6386
-73.6972
-56.8691
-45.6171
-37.5618
-31.5100
-26.7970
-23.0225
-19.9316
-17.3537
-15.1707
-13.2981
-11.6741
-10.2519
-8.9962
-7.8791
-6.8788
-5.9777
-5.1619
-4.4195
-3.7412
¦3.1188
-2.5457
-2.0162
-1.5254
-1.0693
-.6443
-.2472
.1246
.4735
.8016
1.1107
1.4024
1.6782
1.9392
2.1868
2.4220
2.6455
2.8584
3.0613
3.2550
3.4400
3.6170
3.7864
3.9488
4.1045
4.2541
4.3977
4.5359
4.6689
4-7969
4.9204
5.0394
5.1543
5.2652
5.3724
5.4761
5.5764
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 445
'л
§
¦ ? f §
•& **"! |
О "^ Nt4
О **
S 5 " '5
О || . кг} ^***
1| О 00* ^
i i" о«
о 5 со
о от.
*-• "а:
1
55 i
Я §
гч .
+ Т
~ 1
'я
* й §
оо ^ 2
•п m 2
§ « v
, О S-,
н 7 v
J-t о
Я <$ ">
45 СЛ ¦»'"
+ + т
2 ё ^
2 ? "
Р"» СО
II 1
о
240

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
ззоо-
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;т
ТРИГИДРИД КРЕМНИЯ SiH3
К°(Т) = p(Si)-p3(H)-p~\SiH3)
Ф°(Г)
S°(T)
Дж • К . моль
33.264
34.543
38.920
39.018
44.518
49.850
54.675
58.869
62.420
65.381
67.837
69.870
71.559
72.969
74.151
75.150
75.999
76.725
77.349
77.890
78.360
78.772
79.134
79.453
79.737
79.990
80.216
80.419
80.602
80.767
80.917
81.054
81.178
81.292
81.396
81.492
81.580
81.661
81.736
81.806
81.871
81.931
81.987
82.039
82.088
82.133
82.176
82.216
82.254
82.289
82.323
82.354
82.384
82.412
82.439
82.464
82.488
82.510
82.532
82.552
82.571
145.324 178.582
168.404 201.851
181.918 216.387
182.131 216.628
192.291 228.602
200.624 239.116
207.845 248.640
214.306 257.392
220.204 265.492
225.660 273.020
230.751 280.040
235.533 286.604
240.048 292.758
244.327 298.543
248 396 303.995
252.276 309.146
255.984 314.024
259.536 318.653
262.944 323.057
266.213 327.254
269.371 331.261
272.410 335.095
275.344 338.768
278.178 342.293
280.921 345.680
283.577 348.941
286.152 352.082
288.650 355.113
291.076 358.041
293.435 360.873
295.728 363.614
297.961 366.269
300.136 368.844
302.256 371.344
304.324 373.773
306.342 376.133
308.313 378.430
310.239 380.667
312.121 382.845
313.962 384.970
315.763 387.041
317.526 389.064
319.253 391.039
320.945 392.969
322.603 394.855
324.229 396.701
325.825 398.506
327.390 400.274
328.926 402.005
330.435 403.702
331.917 405.364
333.373 406.995
334.805 408.594
336.212 410.164
337.596 411.705
338.957 413.218
340.296 414.704
341.614 416.164
342.912 417.599
344.190 419.010
345.449 420.398
(г)
ДгЯ°@) = 878.769
Я°(Л-Я°@)
кДж • моль
3.326
6.689
10.277
10.349
14.525
19.246
24.477
30.160
36.230
42.624
49.289
56.178
63.252
70.480
77.838
85.304
92.863
100.500
108.205
115.967
123.780
131.637
139.533
147.462
155.422
163.409
171.419
179.451
187.502
195.571
203.655
211.754
219.866
227.989
236.124
244.268
252.422
260.584
268.754
276.931
285.115
293.305
301,501
309.702
317.909
326.120
334.335
342.555
350.778
359.006
367.236
375.470
383.707
391.947
400.189
408.434
416.682
424.932
433.184
441.438
449.694
-449.5411
-217.9979
-141.3093
-140.3427
-101.3113
-77.7875
-62.0453
-50.7646
-42.2810
-35.6673
-30.3658
-26.0209
-22.3947
-19.3224
-16.6861
-14.3988
-12.3957
-10.6267
-9.0530
-7.6440
-6.3750
-5.2261
-4.1810
-3.2263
-2.3506
-1.5446
-.8002
-.1105
.5302
1.1269
1.6842
2.2058
2.6949
3.1547
3.5875
3.9959
4.3816
4.7467
5.0927
5.4211
5.7332
6.0302
6.3132
6.5831
6.8408
7.0872
7.3229
7.5487
7.7651
7.9728
8.1722 ¦
8.3639
8.5483
8.7258
8.8967
9.0615
9.2204
9.3739
9.5220
9.6652
9.8037
кДж ¦ моль
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 446
'>а
§
'л S
1 * Тё
к ^ *
X m. I
О ° ¦
0*1 О ^ «^
1Л " >¦—}¦
Н. М V (N
¦ '¦"' и* i*~i О
m " 2 en
'' ® ек <n
^ С <N
го (-T
Яи *" ^
ГЭ гО OR
ГО м r ^
SS 3 ч
0 Й
+
1
04 'л
40 §
+ 7'
2 П о
^ «> Я
¦* х °
я <¦*¦* \ /
о °°. . V
i я ^
х + V
•S <м о
<7> X О
о <* ""
• 2 S о
+ i 7
ГО О
m t-
II +
0
е
241

Класс точности
V-E
7"
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
п
и
33.269
35.504
42.787
42.945
51.426
59.103
65.837
71.680
76.683
80.921
84.489
87.486
90.006
92.130
93.928
95.458
96.766
97.891
98.863
99.708
100.446
101.094
101.665
102.170
102.620
103.021
103.381
103.704
103.996
104.260
104.499
104.717
104.917
105.099
105.266
105.419
105.561
105.692
105.813
105.925
106.029
106.125
106.216
106.300
106.378
106.452
106.521
106.586
106.646
106.704
106.758
106.808
106.856
106.902
106.945
106.985
107.024
107.060
107.095
107.128
107.159
К°(Т) = р (Si)-р
Ф°(Г)
Дж . к . моль"
131.974
155.076
168.76*
168.981
179.547
188.465
196.382
203.606
210.305
216.581
.222.502
228.114
233.454
238.550
243.424
248.096
252.581
256.895
261.049
265.056
268.924
272.663
276.281
279.785
283.183
286.479
289.681
292.793
295.820
298.766
301.635
304.432
307.160
309.821
312.420
314.959
317.440
319.866
322.240
324.564
326.839
329.068
331.253
333.394
335.495
337.556
339.579
341.565
343.515
345.431
347.314
349.165
350.986
352.776
354.537
356.271
357.977
359.657
361.311
362.940
364.546
СИЛАН
4(H)-p(SiH4)
S°(T)
i
165.233
188.668
204.097
204.362
217.889
230.207
241.592
252.190
262.097
271.381
280.097
288.294
296.018
303.308
310.204
316.738
322.941
328.842
334.465
339.834
344.968
349.884
354.601
359.131
363.489
367.687
371.734
375.642
379.419
383.073
386.612
390.042
393.370
396.601
399.741
402.795
405.766
408.660
411.481
414.231
416.914
419.533
422.092
424.592
427.036
429.428
431.768
434.060
436.305
438.504
440.661
442.775
444.850
446.885
448.884
450.847
452.775
454.669
456.532
458.363
460.164
SiH4 (г)
ArH°@) = 1265.485 кДж ¦ моль
Н°(Т)-Н°@)
кДж • моль
3.326
6.718
10.535
10.614
15.337
20.871
27.126
34.009
41.434
49.320
57.596
66.199
75.077
84.187
93.492
102.963
112.576
122.310
132.149
142.079
152.087
162.165
172.303
182.496
192.736
203.018
213.338
223.693
234.078
244.491
254.929
265.390
275.872
286.373
296.891
307.426
317.975
328.537
339.113
349.700
360.298
370.905
381.522
392.148
402.782
413.424
424.072
434.728
445.389
456.057
466.730
477.408
488.092
498.780
509.472
520.168
530.869
541.573
552.281
562.992
573.706
lgK°(T)
Т
К
-647.1264 100
-313.8330 200
-203.4715 298.15
-202.0808 300
-145.9252 400
-112.0899 500
-89.4529 600
-73.2352 700
-61.0413 800
-51.5371 900
-43.9201 1000
-37.6787 1100
-32.4709 1200
-28.0595 1300
-24.2748 1400
-20.9921 1500
-18.1178 1600
-15.5802 1700
-13.3234 1800
¦11.3032 1900
-9.4843 2000
-7.8381 2100
-6.3411 2200
-4.9738 2300
-3.7202 2400
-2.5667 2500
-1.5016 2600
-.5153 2700
.4007 2800
1.2536 2900
2.0498 3000
2.7947 3100
3.4931 3200
4.1492 3300
4.7668 3400
5.3492 3500
5.8992 3600
6.4195 3700
6.9124 3800
7.3801 3900
7.8244 4000
8.2471 4100
8.6496 4200
9.0334 4300
9.3997 4400
9.7498 4500
10.0847 4600
10.4052 4700
10.7125 4800
11.0071 4900
11.2900 5000
11.5618 5100
11.8231 5200
12.0745 5300
12.3166 5400
12.5499 5500
12.7748 5600
12.9919 5700
13.2014 5800
13.4038 5900
13.5995 6000
Таблица 447
-1
-
'а
"й 1
§ л i
- sJ s
t~j" ^ *¦*'
- 5 д. п
1 t Q оо
ГЧ || t/i f*"~
m ,-ч о
И О od ч>
w ЭС to
% ?
+
s a
ел —'
+ 1
s ъ I
сч ас ^д
°- Т*. V
<=> г- J
| СП Ьч
'2 "+ v
U ? §
Р °\ 2
+ 1* •
О ? En
О О)
О VO II
VO СО
? я S
II +
W
0
242

Класс точности
II-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400 г
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
ФТОРИД КРЕМНИЯ SiF (г)
А:°G-)= p(Si)p(F)-p(SiF)
Ф° (Г)
SV)
Дж . К • моль
32.815
31.869
32.653
32.675
33.877
34.840
35.537
36.039
36.410
36.692
36.913
37.093
37.242
37.369
37.480
37.579
37.669
37.751
37.829
37.902
37.972
38.040
38.106
38.171
38.235
38.298
38.362
38.426
38.491
38.557
38.624
38.693
38.764
38.837
38.913
38.992
39.074
39.160
39.249
39.342
39.439
39.541
39.646
39.757
39.871
39.989
40.112
40.239
40.369
40.503
40.641
40.781
40.924
41.069
41.215
41.363
41.512
41.661
41.809
41.957
42.104
159.700
181.350
193.962
194.158
203.334
210.549
216.526
221.644
226.129
230.123
233.724
237.009
240.028
242.822
245.422
247.854
250.138
252.293
254.331
256.266
258.107
259.863
261.541
263.150
264.693
266.176
267.605
268.982
270.312
271.597
272.841
274.046
275.215
276.350
277.453
278.525
279.569
280.586
281.577
282.544
283.487
284.409
285.309
286.190
287.052
287.895
288.722
289.531
290.325
291.103
291.867
292.617
293.354
294.077
294.788
295.487
296.175
296.851
297.517
298.172
298.817
190.465
212.847
225.678
225.880
235.447
243.115
249.532
255.050
259.888
264.193
268.071
271.598
274.832
277.818
280.592
283.181
285.609
287.895
290.055
292.103
294.049
295.903
297.674
299.370
300.995
302.557
304.061
305.510
АЛЛ /\f\rt
306.908
308.260
309.568
310.836
312.066
313.260
314.420
315.549
316.649
317.721
318.766
319.787
320.784
321.759
322.713
323.647
324.563
325.460
326.340
327.204 -
328.053
328.887
329.706
330.512
331.306
332.087
332.856
333.613
334.360
335.096
335.822
336.538
337.244
АгЯ°@)= 550.000
Я°(Г)-Я°@)
кДж • моль
3.077 -283.7774
6.299 -139.5183
9.456 -91.8977
9.517 -91.2985
12.845 -67.1334
16.283 -52.6071
19.804 -42.9078
23.384 -35.9703
27.007 -30.7609
30.663 -26.7048
34.347 -23.4564
38.048 -20.7962
41.765 -18.5774
45.495 -16.6983
49.238 -15.0863
52.991 13.6880
56.754 -12.4634
60.525 -11.3820
64.304 -10.4200
68.090 -9.5585
71.884 -8.7825
75.685 -8.0798
79.492 -7.4404
83.306 -6.8561
87.126 -6.3201
90.953 -5.8264
94.786 -5.3704
98.625 -4.9478
102.471 -4.5549
106.323 -4.1889
110.182 -3.8470
114.048 -3.5268
117.921 -3.2264
121.801 -2.9439
125.688 -2.6779
129.584 -2.4268
133.487 -2.1894
137.399 -1.9647'
141.319 -1.7517
145.248 -1.5494
149.188 -1.3571
153.136 -1.1740
157.096 -.9995
161.066 -.8330
165.047 -.6739
169.040 -.5218
173.045 -.3763
177.063 -.2368
181.093 -.1030
185.137 .0253
189.194 .1486
193.265 .2672
197.350 .3812
201.450 .4910
205.564 .5968
209.693 .6987
213.837 .7971
217.996 .8921
222.169 .9838
226.357 1.0724
230.560 1.1582
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 448
7
о
1 2
А
• * §
3 2 т'
о 9° <ч v
'.0839
-27.05
С) = -
Дж •!
* - ' ¦ Л оо
"* и "^ гп
11 *~? г-~
§ ° On 00 .
С м II
& - 0 Э
\^/ тИ Со
о 52-
*Ч 0
^«
<i
+
7
к
00
О\
го 7
о s
+ 1
х 7 g
Я • 8
я й s
s \ Y
н " v
с м о
Л , о
On + «О
§ <*? *
? s. 2
? |> "
5 § а.
СП Tt
II +
О
243

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°[Т)
Р
ДИФТОРИД КРЕМНИЯ SiF2
К°(Т) = р (Si) •p2(F).p(SiF2)
Ф°(Г)
SV)
Дж • К . моль
34.719
39.648
44.509
44.593
48.456
51.105
52.886
54.106
54.964
55.586
56.049
56.401
56.674
56.891
57.065
57.206
57.324
57.421
57.504
57.574
57.634
57.686
57.731
57.770
57.805
57.836
57.863
57.887
57.909
57.929
57.946
57.962
57.977
57.990
58.002
58.013
58.024
58.033
58.042
58.050
58:057
58.064
58.071
58.077
58.082
58.087
58.092
58.097
58.101
58.105
58.109
58.112
58.116
58.119
58.122
58.125
58.127
58.130
58.132
58.135
58.137
180.620 214.168
204.373 239.720
218.897 256.476
219.129 256.752
230.265 270.141
239.384 281.258
247.173 290.743
253.999 298.993
260.088 306.277
265.588 312.789
270.607 318.671
275.224 324.030
279.498 328.950
283.479 333.495
287.204 337.717
290.705 341.660
294.006 345.355
297.130 348.834
300.095 352.118
302.916 355.229
305.606 358.184
308.177 360.997
310.639 363.682
313.002 366.249
315.272 368.708
317.457 371.068
319.563 373.338
321.595 375.522
Л ПА р р Л^ А ^9 ^9 А Л«
323.559 377.627
325.458 379.660
327.298 381.624
329.081 383.524
330.812 385.365
332.492 387.149
334.125 388.880
335.714 390.562
337.260 392.196
338.766 393.786
340.235 395.334
341.667 396.842
343.065 398.312
344.430 399.745
345.764 401.144
347.067 402.511
348.343 403.846
349.591 405.152
350.812 406.428
352.009 407.678
353.182 408.901
354.331 410:099
355.458 411.273
356.564 412.424
357.649 413.552
358.714 414.659
359.760 415.746
360.788 416.812
361.798 417.859
362.7.90 418.888
363.766 419.899
364.726 420.893
365.671 421.870
V
Я°GУ-Я°@)
кДж ¦ моль
3.355
7.070
11.204
11.287
15.950
20.937
26.142
31.496
36.952
42.481
48.064
53.687
59.341
65.020
70.718
76.432
82.158
87.896
93.642
99.396
105.157
110.923
116.693
122.469
128.247
134.029
139.814
145.602
151.392
157.184
162.977
168.773
174.570
180.368
186.168
191.968
197.770
203.573
209.377
215.182
220.987
226.793
232.600
238.407
244.215
250.024
255.832
261.642
267.452
273.262
279.073
284.884
290.695
296.507
302.319
308.131
313.944
319.757
325.570
331.383
337.197
(Г)
Таблица 449
!°@)= 1192.217 кДж -моль
«V,
-614.3958
-301.7554
-198.5678
-197.2696
-144.9221
-113.4653
-92.4684
-77.4556
-66.1864
¦57.4148
-50.3929
-44.6441
-39.8506
-35.7924
-32.3121
-29.2943
-26.6524
-24.3201
-22.2460
-20.3882
-18.7173
-17.2039
-15.8273
-14.5698
-13.4165
-12.3549
-11.3745
-10.4662
-9.6224
-8.8363
-8.1022
-7.4152
-6.7707
-6.1649
-5.5945
-5.0564
-4.5479
-4.0666
-3.6104
-3.1774
-2.7658
-2.3740
-2.0007
-1.6446
-1.3045
-.9793
-.6681
-.3700
-.0841
.1902
.4537
.7070
.9507
1.1853
1.4114
1.6293
1.8396
2.0426
2.2387
2.4283
2.6116
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
i
л
" 1
* х °
гч °° ^
X оо —
о гч' '
О On -Ь
ОС Г/-и —*
О > ,—ч ^-1
sD ^ с
ЧО II 1О •Л
II О ос —
^ ' ON
•<, ¦ — гч „
г II
55 -« ° *
C/J llm 0"}
0 СЛ
>- ^
**ч О
_+
С")
гч
—н с;
, о
1 _ ¦
s s 1
§ Ч, v
ч ^ V
? ~* о
Г4- "*"
{— О) "^
-. Н
¦ с-1 |
1/1 .
<? 23
II +
р
0
е
244

Класс точности
VI -С
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
36.849
49.104.
58.728
58.883
65.879
70.582
73.731
75.886
77.404
78.504'
79.323
79.947
80:432
80.816
81.125
81.377
81.585
81.758
81.904
82.029
82.136
82.228
82.308
82.378
82.440
82.494
82.543
82.586
82.625
82.660
82.691
82.720
82.746
82.769
82.791
82.811
82.829
82.846
82.861
82.875
82.888
82.901
82.912
82.923
82.933
82.942
82.951
82.959
82.966
82.973
82.980
82.987
82.993
82.998
83.004
83.009
83.013
83.018
83.022
83.026
83.030
ТРИФТОРИД КРЕМНИЯ SiF3
*V>-p<so.,
Ф°(Г)
Дж • К . моль
194.843
219.647
235.995
236.265
249.515
260.772
270.636
279.442
287.405
294.675
301.365
307.560
313.329
318.728
323.799
328.580
333.103
337.394
341.476
345.368
349.086
352.646
356.060
359.340
362.496
365.537
368.472
371.306
374.047
376.701
379.273
381.768
384.190
386.544
388.834
391.062
393.232
395.347
397.409
399.422
401.387
403.307
405.184
407.019
408.814
410.572
412.293
413.980
415.633
417.254
418.843
420.404
421.935
423.439
424.916
426.367
427.793
429.195
430.574
431.931
433.266
>3(F).p-'(SiF3)
SV)
1
228.792
258.169
279.658
280.022
297.983
313.224
326.390
337.927
348.165
357.349
365.664
373.255
380.233
386.687
392.688
398.294
403.553
408.504
413.181
417.613
421.823
425.833
429.660
433.321
436.828
440.195
443.431
446.547
449.551
452.451
455.254
457.966
460.592
463.139
465.610
468.010
470.344
472.613
474.823
476.975
479.074
481.120
483.119
485.069
486.976
488.840
490.663
492.447
494.194
495.904
497.581
499.224
500.836
502.416
503.968
505.491
506.987
508.456
509.900
511.319
512.715
(г)
А Н°@) = 1670.492
tf°GV"°@)
кДж . моль
3.395
7.704
13.018
13.127
19.387
26.226
33.452
40.939
48.608
56.406
64.300
72.265
80.285
88.348
96.445
104.571
112.719
120.886
129.070
137.267
145.475
153.693
161.920
170.154
178.395
186.642
194.894
203.151
211.411
219.675
227.943
236.214
244.487
252.763
261.040
269.321
277.603
285.886
294.172
302.458
310.747
319.036
327.327
335.619
343.911
352.205
360.500
368.795
377.092
385.388
393.686
401.984
410.283
418.583
426.883
435.184
443.485
451.786
460.088
468.391
476.694
lgAr°(r)
-859.0322
-420.7717
-276.1070
-274.2872
-200.9016
-156.8080
-127.3818
-106.3467
-90.5608
-78.2771
-68.4462
-60.4002
-53.6933
-48.0169
-43.1504
-38.9319
-35.2401
-31.9821
-29.0857
-26.4937
-24.1606
-22.0494
-20.1298
-18.3768
-16.7698
-15.2910
-13.9258
-12.6615
-11.4874
-10.3940
-9.3734
-8.4185
-7.5231
-6.6819
-5.8900
-5.1432
-4.4379
-3.7705
-3.1382
-2.5382
-1.9681
-1.4257
-.9091
-.4164
.0539
.5035
.9335
1.3453
1.7400
2.1Г86
2.4822
2.8315
3.1675
3.4908
3.8022
4.1024
4.3918
4.6711
4.9409
5.2015
5.4535
кДж • моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б
i
-о
с;
о
о
о
о о
1 i
S3 ii
11 S
5- u-
m
U.
GO
0
<
1
i~
ЧО _
О ' j
+ °
2
S i
2 с
О п
О X
8 «
"-* +
4D м^
Г^ "
О ^
¦ г-
°° ЧО
^. 1
-«З- 00
°° S
II +
_
О
л и
i
А
О
*?
г-
vo'
OV
1
II
00
С-1
и"
ч
ц а 450
1
к
о
1
^.
О
0 <К
со
Я
8
ЧО
V
V
о
о
¦*"
'о

.а
245

Класс точности
VI -1
7
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
41.815
60.878
73.621
73.825
83.143
89.626
94.090
97.207
99.433
101.063
102.285
103.221
103.952
104.532
105.000
105.383
105.699
105.963
106.186
106.376
106.540
106.681
106.803
106.911
107.005
107.089
107.163
107.230
1 Л *щ Л "Л Л
107.289
107.343
107.391
107.435
107.475
107.511
107.544
107.574
107.602
107.628
107.652
107.674
107.694
107.713
107.730
107.747
107.762
107.776
107.789
107.802
107.814
107.825
107.835
107.845
107.854
107.863
107.871
107.879
107.886
107.893
107.900
107.906
107.912
ТЕТРАФТОРИД КРЕМНИЯ SiF4
*«47-)-,(Si).p
Ф°(Г)
-* 1 -
Дж ¦ К . моль
185.336
212.224
231.148
231.467
247.280
260.941
273.044
283.935
293.842
302.931
311.327
319.127
326.411
333.240
339.669
345.741
351.494
356.958
362.162
367.128
371.878
376.430
380.799
384.998
389.042
392.941
396.704
400.341
403.861
407.270
410.575
413.782
416.897
419.925
422.871
425.739
428.533
431.257
433.913
436.507
439.040
441.514
443.934
446.301
448.617
450.884
453.105
455.281
457.415
459.507
461.560
463.574
465.552
467.494
469.402
471.276
473.119
474.931
476.713
478.466
480.192
-W(sr4
S°(T)
1
220,561
255.834
282.651
283.107
305.699
324.993
341.753
356.505
369.639
381.449
392.164
401.958
410.972
419.317
427.081
434.339
441.150
447.566
453.630
459.376
464.837
470.038
475.004
479.754
484.306
488.676
492.878
496.923
500.824
504.590
508.230
511.752
515.163
518.471
521.681
524.799
527.830
530.779
533.649
536.445
539.172
541.832
544.427
546.962
549.440
551.861
554.230
556.549
558.818
561.041
563.220
565.355
567.450
569.504
571.520
573.500
575.444
577.353
579.230
581.074
582.888
Я°G>Я°@)
кДж . моль
3.522
8.722
15.356
15.492
23.367
32.026
41.225
50.799
60.637
70.666
80.836
91.114
101.474
111.899
122.377
132.896
143.451
154.034
164.642
175.271
185.916
196.578
207.252
217.938
228.634
239.339
250.051
260.771
271.497
282.228
292.965
303.706
314.452
325.201
335.954
346.710
357.469
368.230
378.994
389.761
400.529
411.299
422.072
432.845
443.621
454.398
465.176
475.956
486.736
497.518
508.301
519.085
529.870
540.656
551.443
562.230
573.018
583.807
594.597
605.387
616.178
(г)
'@) = 2364.206
о
1214.9608
-594.8683
-390.2438
-387.6699
-283.8918
-221.5486
-179.9506
•150.2194
-127.9111
-110.5547
-96.6665
-85.3015
-75.8297
-67.8146
-60.9442
-54.9897
-49.7795
-45.1824
-41.0962
-37.4402
-34.1499
-31.1730
-28.4670
-25.9963
-23.7317
-21.6483
-19.7252
-17.9447
-16.2915
-14.7523
-13.3158
-11.9721
-10.7124
-9.5291
-8.4155
-7.3656
-6.3740
-5.4361
-4.5476
-3.7047
-2.9040
-2.1424
-1.4171
-.7256
-.0655
.5651
1.1684
1.7459
2.2993
2.8301
3.3397
3.8292
4.2998
4.7527
5.1888
5.6090
6.0141
6.4050
6.7825
7.1470
7.4994
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4.100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
~л
¦к
- о
о «
? ч
ч °
О rj чо
5? о 1
О *> II
S 7 *
!L 3 %
sis ,_¦»
0 ^,
а; о
<1 ч
+
1
ё
!2 -
rs о
+ 2
чо Ьй
•ч Ч
S •"*
о ^
? +
чо °*
2 °
о ^
+ 1
О X
Tf- чо
г— чо
fi °°.
II +
с
О
ца 451
i
л
о
S
1
г-
сч
о
чо
II
О К
to
—>
я
о
о-
о
V
V
§
•г"
'о
II
is
246

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
33.267
34.488
37.792
37.859
41.311
44.195
46.554
48.516
50.207
51.733
53.167
54.552
55.899
57.205
58.455
59.630
60.712
61.688
62.550
63.292
63.916
64.427
64.831
65.138
65.358
65.501
65.577
65.596
65.567
65.499
65.399
65.273
65.127
64.966
64.793
64.613
64.427
64.240
64.051
63.863
63.678
63.495
63.317
63.143
62.973
62.809
62.650
62.496
62.348
62.206
62.069
61.937
61.810
61.688
61.571
61.459
61.351
61.248
61.149
61.054
60.963
ГИДРИД-ФТОРИД КРЕМНИЯ SiHF (г)
А* G*) = р (Si) •
Ф°G-)
Дж • К • моль
167.692
190.775
204.271
204.484
214.536
222.646
229.532
235.561
240.951
245.842
250.330
254.487
258.364
262.003
265.437
268.691
271.788
274.743
277.572
280.285
282.894
285.407
287.831
290.172
292.436
294.628
296.752
298.812
300.812
302.754
304.643
306.480
308.268
310.009
311.706
313.360
314.974
316.548
318.086
319.588
321.056
322.491
323.894
325.268
326.612
327.928
329.218
330.481
331.720
332.935
334.126
335.295
336.443
337.569
338.676
339.762
340.831
341.880
342.912
343.927
344.926
D(H)-p(F)-p l(SfflF) ArH°@)= 911.000
S°(T)
l
Я°(Г)-Я°@)
кДж • моль"
о
200.950 3.326 -469.0451
224.229 6.691 -229.8258
238.583 10.230 -150.7804
238.817 10.300 -149.7853
250.193 14.263 -109.6399
259.732 18.543 -85.4899
268.005 23.084 -69.3546
275.333 27.840 -57.8077
281.924 32.778 -49.1335
287.927 37,876 -42.3773
293.452 43.122 -36.9657
298.585 48.508 -32.5333
303.389 54.031 -28.8363
307.916 59.687 -25.7058
312.201 65.470 -23.0207
316.275 71.375 -20.6926
320.158 77.393 -18.6547
323.869 83.514 -16.8560
327.420 89.727 -15.2570
330.822 96.020 -13.8261
334.085 102.381 -12.5383
337.216 108.799 -11.3732
340.223 115.263 -10.3141
343.112 • 121.762 -9.3472
345.889 128.288 -8.4610
348.560 134.831 -7.6458
351.131 141.386 -6.8934
353.606 147.945 -6.1968
355.992 154.503 -5.5501
358.291 161.057 -4.9481
360.510 167.602 -4.3862
362.653 174.136 -3.8607
364.723 180.656 -3.3681
366.724 187.161 -2.9053
368.661 193.649 -2.4698
370.537 200.119 -2.0592
372.354 206.571 -1.6713
374.117 213.005 -1.3045
375.828 219.419 -.9569
377.489 225.815 -.6272
379.104 232.192 -.3139
380.674 238.551 -.0158
382.202 244.891 .2681
383.690 251.214 .5388
385.139 257.520 .7973
386.552 263.809 1.0443
387.931 270.081 1.2807
389.277 276.339 1.5070
390.591 282.581 1.7240
391.875 288.809 1.9321
393.131 295.022 2.1320
394.358 301.223 2.3241
395.560 307.410 2.5088
396.736 313.585 2.6867
397.888 319.748 2.8580
399.017 325.899 3.0231
400.123 332.040 3.1824
401.208 338.170 3.3361
402.273 344.289 3.4846
403.317 350.400 3.6281
404.342 356.500 3.766$
кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 452
I
i **
л
S Ч i
? X g
Д К |
х "°-
СП ^ч
J* Г~| 1
о я 7
2 ? » х
« 7 2 m
" » -. ?
II ?S оо Tj-"
3 ь" о 5
о~^ от
a; ow
>¦> а»
< <-.
7 7
43 g
"¦~ 1
О
О |
1 Ьй
Н ¦ ЕЗ ч>
I "з §
_н ОО 43
О 45 . .
О оо V
О •? (,
* "» V
й ? 1
чо о ^.*"
ON ' •""• О
^ 5 ^
Г"- V) "
гч оо ^
О и*>
II +
с
W
о
247

Класс точности
I-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
ХЛОРИД КРЕМНИЯ SiCl (г]
К°(Т)= р (Si)-p (CD-p~l(SiC\)
Ф°(Г)
S°(T)
Дж -К .моль
32.753
34.717
35.783
35.799
36.447
36.840
37.097
37.278
37.416
37.526
37.620
37.702
37.777
37.846
37.913
37.977
38.039
38.101
38.162
38.224
38.285
38.348
38.411
38.476
38.542
38.609
38.679
38.751
38.825
38.902
38.982
39.064
39.149
39.236
39.326
39.418
39.512
39.608
39.705
39.802
39.900
39.998
40.094
40.190
40.284
40.375
40.464
40.549
40.630
40.708
40.781
40.850
40.914
40.972
41.026
41.074
41.117
41.154
41.186
41.213
41.235
169.927 200.235
191.551 223.651
204.577 237.728
204.783 237.949
214.432 248.344
222.061 256.523
228.383 263.264
233.786 268.996
238.505 273.984
242.697 278.397
246.467 282.356
249.896 285.946
253.039 289.229
255.940 292.256
258.636 295.063
261.152 297.681
263.513 300.134
265.736 302.442
267.836 304.621
269.827 306.686
271.719 308.649
273.523 310.518
275.245 312.303
276.894 314.012
278.475 315.651
279.994 317.226
281.455 318.741
282.863 320.203
284.222 321.613
285.535 322.977
286.805 324.297
288.035 325.577
289.228 326.818
290.385 328.024
291.510 329.197
292.603 330.338
293.667 331.450
294.703 332.534
295.712 333.592
296.697 334.624
297.657 335.633
298.596 336.619
299.513 337.584
300.409 338.529
301.286 339.454
302.144 340.360
302.985 341.249
303.808 342.120
304.615 342.974
305.407 343.813
306.183 344.636
306.945 345.444
307.693 346.238
308.428 347.018
309.149 347.785
309.859 348.538
310.556 349.278
311.242 350.006
311.916 350.722
312.580 351.427
313.233 352.120
V
Н°(Т)-Н°@)
кДж . моль
3.031
6.420
9.884
9.950
13.565
17.231
20.929
24.648
28.383
32.130
35.889
39.655
43.429
47.210
50.998
54.793
58.593
62.400
66.214
70.033
73.858
77.690
81.528
85.372
89.223
93.081
96.945
100.816
104.695
108.582
112.476
116.378
120.289
124.208
128.136
132.073
136.020
139.976
143.941
147.917
151.902
155.897
159.901
163.916
167.939
171.972
176.014
180.065
184.124
188.191
192.265
196.347
200.435
204.529
208.629
212.734
216.844
220.958
225.075
229.195
233.317
1°@) = 425.000 кДж ¦ моль"'
-218.6138
-107.0099
-70.1734
69.7100
-51.0225
-39:7898
-32.2887
-26.9221
-22.8912
-19.7515
-17.2363
-15.1759
-13.4567
-12.0002
-10.7503
-9.6659
-8.7159
-7.8767
-7.1300
-6.4611
-5.8584
-5.3125
-4.8156
-4.3615
-3.9447
-3.5608
-3.2060
-2.8772
-2.5715
-2.2866
-2.0203
. -1.7710
-1.5370
-1.3169
-1.1096
-.9139
-.7289
-.5537
-.3876
-.2298
-.0798
.0631
.1992
.3292
.4533
.5720
.6857
.7946
.8990
.9993
1.0956
1.1882
1.2773
1.3631
1.4457
1.5255
1.6024
1.6766-
1.7484
1.8177
1.8848
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 453
|
g
1 ^ -ч
о * р:
2 Ч о.
• * 1
'—1 ГО |
•^ гч &,
s 2 T a
iq Tf О Tf
г—i ИМ О
СП и->
«> « —1 1
11 s "°° 2
^ - CN
1н ^ II
у _- о §
$?. .У <*>
4; ^
< X
• i
+ о
" S
Д ""'
ОО ¦*• А
Z 1 §
тг * о
g п
ОС V
•а З v
 м О
¦" | о
°5 * *'"
? I -'о
^- + К
оо го
II '
!^
0
0
248

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
38.152
46.328
51.273
51.339
53.911
55.310
56.135
56.656
57.004
57.248
57.424
57.556
57.658
57.737
57.800
57.851
57.893
57.928
57.957
57.982
58.003
58.021
58.037
58.051
58.063
58.074
58.084
58.092
58.100
58.106
58.113
58.118
58.123
58.128
58.132
58.136
58.140
58.143
58.146
58.149
58.151
58.154
58.156
58.158
58.160
58.162
58.163
58.165
58.166
58.168
58.169
58.170
58.171
58.173
58.174
58.175
58.176
58.176
58.177
58.178
58.179
ДИХЛОРИД КРЕМНИЯ SiCl2
К^-р^.р
Ф°(Г)
— 1 -
Дж • К . моль
198.179
223.404
239.473
239.733
252.223
262.433
271.093
278.620
285.280
291.254
296.671
301.625
306.190
310.423
314.369
318.064
321.539
324.817
327.921
330.868
333.672
336.3-48
338.906
341.356
343.708
345.968
348.143
350.240
352.265
354.221
356.113
357.946
359.724
361.448
363.123
364.751
366.334
367.876
369.378
370.842
372.270
373.664
375.025
376.356
377.656
378.928
380.173
381.392
382.586
383.756
384.903
386.027
387.130
388.213
389.276
390.320
391.346
392.353
393.344
394.318
395.276
>(Cl).p->(SiCl2)
S°(T)
I
Я°(Г)-Я°@)
кДж . моль"
232.914 3.473
261.969 7.713
281.495 12.529
281.812 12.624
296.974 17.900
309.169 23.368
319.332 28.943
328.027 34.585
335.617 40.269
342.346 45.982
348.387 51.716
353.866 57.466
358.879 63.226
363.497 68.996
367.779 74.773
371.768 80.556
375.503 86.343
379.014 92.134
382.326 97.929
385.460 103.726
388.435 109.525
391.265 115.326
393.964 121.129
396.545 126.933
399.016 132.739
401.386 138.546
403.664 144.354
405.856 150.163
407.969 155.972
410.008 161.783
411.978 167.594
413.884 173.405
415.729 179.217
417.517 185.030
419.253 190.843
420.938 196.656
422.576 202.470
424.169 208.284
425.719 214.098
427.230 219.913
428.702 225.728
430.138 231.543
431.540 237.359
432.908 243.175
434.245 248.990
435.552 254.807
436.830 260.623
438.081 266.439
439.306 272.256
440.505 78.072
441.680 283.889
442.832 289.706
443.962 295.523
445.070 301.340
446.157 307.158
447.225 312.975
448.273 318.793
449.303 324.610
450.314 330.428
451.309 336.246
452.287 342.064
(г)
Г°@)= 848.107
-434.7600
-212.0885
-138.5977
-137.6733
-100.3989
-78.0006
-63.0482
-52.3546
-44.3253
-38.0736
-33.0673
-28.9674
-25.5478
-22.6518
-20.1676
-18.0128
-16.1259
-14.4598
-12.9776
-11.6505
-10.4552
-9.3728
-8.3882
-7.4885
-6.6631
-5.9032
-5.2011
-4.5506
-3.9461
-3.3829
-2.8567
-2.3642
-1.9021
-1.4676
-1.0584
-.6722
-.3072
.0383
.3659
.6769
.9726
1.2541
1.5224
1.7784
2.0230
2.2569
2.4808
2.6953
2.9010
3.0985
3.2883
3.4707
3.6462
3.8153
3.9782
4.1353
4.2869
4.4333
4.5747
4.7115
4.8438
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
.2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 454
. '§
I S
i i >.
X g
"is-2
о 2 k
<ч i
2 3" d
ъ. Т Я >п
СО || *О СП
11 о g ?
§ с ^
** иГ "
У -5* о «
о со
Э; о
""¦-1 &
\|
о ~
«-. 'g
+ 2
7* 7'
1 к 1
§ & Y
1 ? к
2 2 • v
* ? S
s -
оо ? 'о
*О —Г ,—I
(N m II
•* о
II +
0
V
249

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
: 3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
! 4800
; 4900
5000
5100
5200
\ 5300
5400
i 5500
5600
i 5700
5800
5900
6000
Р
46.013
61.847
70.562
70.678
75.279
77.814
79.321
80.279
80.922
81.372
81.700
81.944
82.132
82.280
82.397
82.492
82.570
82.635
82.690
82.736
82.775
82.809
82.839
82.865
82.887
82.908
82.925
82.941
82.955
82.968
82.980
82.990
82.999
83.008
83.016
83.023
83.030
83.036
83.041
83.047
83.051
83.056
83.060
83.064
83.068
83.071
83.074
83.077
83.080
83.082
83.085
83.087
83.089
83.091
83.093
83.095
83.097
83.098
83.100
83.102
83.103
ТРИХЛОРИД КРЕМНИЯ SiCl3
К°(Т) = р (Si)-р
Ф°(Т)
Дж ¦ К • моль
215.881
244.364
264.020
264.346
280.280
293.629
305.134
315.248
324.271
332.415
339.837
346.652
352.954
358.813
364.2Й7
369.425
374.264
378.837
383.173
387.294
391.221
394.971
398.559
402.000
405.303
408.480
411.541
414.493
417.344
420.10J
422.769
425.354
427.861
430.296
432.660
434.960
437.197
439.376
441.500
443.570
445.591
447.563
449.490
451.373
453.214
455.016
456.779
458.506
460.197
461.855
463.480
465.075
466.639
468.175
469.682
471.163
472.618
474.047
475.453
476.835
478.195
3(Cl)-p~1(SiCl3) Д,А
S°(T)
1
253.028
290.232
316.736
317.172
338.204
355.301
369.632
381.937
392.701
402.260
410.851
418.650
425.788
432.369
438.471
444.159
449.485
454.493
459.218
463.690
467.935
471.974
475.827
479.510
483.037
486.421
489.673
492.803
495.820
498.731
501.544
504.265
506.900
509.455
511.932
514.339
516.678
518.953
521.168
523.325
525.427
527.478
529.480
531.434
533.344
535.211
537.036
538.823
540.572
542.285
543.964
545.609
547.222
548.805
550.358
551.883
553.380
554.851
556.296
557.717
559.114
Н°(Т)-Н°@)
кДж ¦ моль
3.715
9.174
15.717
15.848
23.170
30.836
38.699
46.682
54.744
62.860
71.015
79.197
87.402
95.6-22
103.857
112.101
120.354
128.615
136.881
145.152
153.428
161.707
169.990
178.275
186.562
194.852
203.144
211.437
219.732
228.028
236.326
244.624
252.924
261.224
269.525
277.827
286.130
294.433
302.737
311.041
319.346
327.652
335.957
344.264
352.570
360.877
369.184
377.492
385.800
394.108-
402.416
410.725
419.034
427.343
435.652
443.961
452.271
460.581
468.891
477.201
485.511
(г)
Таблица 455
г°@)= 1199.527 кДж-моль
-612.9104
-297.8757
-193.9224
-192.6149
-139.9056
-108.2431
-87.1141
-72.0091
-60.6721
-51.8487
-44.7861
-39.0047
-34.1848
-30.1048
-26.6064
-23.5735
-20.9188
-18.5758
-16.4926
-14.6281
-12.9496
-11.4306
-10.0494
-8.7879
-7.6313
-6.5669
-5.5842
-4.6740
-3.8286
-3.0414
-2.3064
-1.6187
-.9738
-.3679
.2026
.7406
1.2488
1.7297
2.1853
2.6177
3.0286
3.4195
3.7919
4.1471
4.4862
4.8103
5.1204
5.4173
5.7020
5.9750
6.2373
6.4892
6.7316
6.9649
7.1895
7.4061
7.6149
7.8165
8.0111
8.1992
8.3811
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500-i
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
'-о
с
__ о
1 *
моль
:Дж-
¦ о 5
? О
а ? 2
о м V> ¦
•о Я . 1 .
2 " —' m
" ° ? й
й -* о э
ся У со
0 w ,
It rs
"*ч О
.>• а:
н
Si
о _,
. О
сч S
Ю65Г
Дж •
6000
"—' СП \ /
о g V
н * V
? ° о
00 м "^
§ °° V
Г; ¦* 1
00 • _ .
± •
-* оо II
00 00
? -;
II +
0
©
250

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
1 6000
С°(Т)
57.413
78.780
90.404
90.562
96.893
100.449
102.586
103.954
104.875
105.523
105.995
106.349
106.620
106.833
107.003
107.141
107.254
107.348
107.427
107.494
107.552
107.601
107.644
107.682
107.714
107.744
107.769
107.792
107.813
107.831
107.848
107.863
107.877
107.890
107.901
107.912
107.921
107.930
107.938
107.946
107.953
107.959
107.965
107.971
107.976
107.981
107.985
107.990
107.994
107.998
108.001
108.004
108.008
108.01
108.013
108.016
108.019
108.021
108.023
108.025
108.027
ТЕТРАХЛОРИД
К°(Т)= p(S\)-i
Ф°(П
Дж • К . моль
208.612
242.010
266.087
266.491
286.344
303.130
317.685
330.532
342.029
352.432
361.928
370.663
378.748
386.274
393.313
399.923
406.153
412.045
.417.633
422.947
428.013
432.853
437.485
441.928
446.196
450.301
454.257
458.073
461.760
465.324
468.775
472.120
475.364
478.514
481.574
484.551
487.448
490.269
493.018
495.700
498.316
500.871
503.366
505.806
508.191
510.526
512.810
515.048
517.240
519.389
521.495
523.562
525.589
527.580
529.534
531.454
533.340
535.194
537.017
538.809
540.572
Acd-p^
S°(T)
1
250.392
297.484
331.340
331.900
358.912
380.950
399.468
415.392
429.337
441.729
452.873
462.993
472.258
480.801
488.725
496.112
503.031
509.536
515.674
521.484
527.000
532.248
537.255
542.041
546.624
551.022
555.248
559.316
— Л A f\t\ ^
563.236
567.020
570.676
574.213
577.637
580.957
584.178
587.306
590.346
593.303
596.182
598.985
601.718
604.384
606.986
609.526
612.008
614.435
616.808
619.131
621.404
623.631
625.813
627.952
630.049
632.107
634 ! 25
636.108
638.054
639.966
641.844
643.691
645.507
КРЕМНИЯ SiCl4
>iCl4) V
Я°(Л-Я°@)
кДж . моль
4.178
11.095
19.455
19.623
29.027
38.910
49.070
59.402
69.846
80.368
90.945
101.563
112.212
122.885
133.577
144.285
155.005
165.735
176.474
187.220
197.972
208.730
219.492
230.259
241.028
251.801
262.577
273.355
284.135
294.918
305.702
316.487
327.274
338.063
348.852
359.643
370.435
381.227
392.020
402.815
413.610
424.405
435.201
445.998
456.796
467.593
478.392
489.190
499.990
510.789
521.589
532.389
543.190
553.991
564.792
575.594
586.395
597.197
608.000
618.802
629.605
(г)
г°@)= 1584.225
\f.K"(T)
-807.1386
91.1363
-253.9029
-252.1771
-182.6090
-140.8289
-112.9545
-93.0320
-78.0827
¦66.4508
-57.1424
-49.5245
-43.1751
-37.8017
-33.1955
-29.2032
-25.7098
-22.6272
-19.8871
-17.4355
-15.2291
-13.2328
-11.4180
-9.7611
-8.2424
•-6.8451
-5.5555
-4.3613
-3.2526
-2.2203
-1.2569
-.3557
.4891
1.2827
2.0295
2.7337
3.3987
4.0277
4.6236
5.1888
5.7258
6.2365
6.7229
7.1867
7.6293
8.0522
8.4567
8.8440
9.2151
9.5710
9.9127
10.2409
10.5565
10.8601
11.1525
11.4342
IJ.7059
11.9679
12.2209
12.4654
12.7016
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
in
I—
ON
00
—
1!
+
1
Г—
о
г~>
оо
+
1
X
1
О
р
°
с
00
""!
о
+
00
in
-о
-•
in
0
©
t
§
¦
ОС
г~
°.
о
1!
О
О
-
'л
о
1
Ы
Ъ
ОС
О
ОС
о
г^
оо
1
ГЧ
о
¦
X
о
о
'"I
-о
II
я
ОС
гч
'-'
_?
а:
<г
ца 456
7
к
1
_•
1
'
0 К
Я
О
о
о
чО
V
f-
V
о
о
in
V
т
о
1!
251

Класс точности
V-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
33.524
36.985
41.015
41.081
44.141
46.459
48.320
49.848
51.104
52.136
52.984
53.683
54.261
54.743
55.146
55.486
55.775
56.022
56.235
56.419
56.580
56.721
56.846
56.959
57.061
57.155
57.242
57.326
57.406
57.485
57.565
57.646
57.729
57.816
57.906
58.002
58.103
58.210
58.324
58.444
58.570
58.703
58.843
58.989
59.142
59.300
59.464
59.634
59.809
59.988
60.171
60.358
60.547
60.740
60.934
61.130
61.327
61.525
61.723
61.920
62.116
ГИДРИД-
ХЛОРИД
Л'°(Г)= p(Si)p(H)-p(Cl)-p
Ф°(Г)
Дж -К .моль
178.254
201.523
215.450
215.672
226.210
234.755
242.008
248.342
253.984
259.084
263.744
268.040
272.026
275.747
279.237
282.526
285.634
288.581
291.385
294.058
296.612
299.057
301.404
303.658
305.828
307.919
309.937
311.888
313.775
315.602
317.374
319.094
320.764
322.387
323.967
325.505
327.003
328.464
329.890
331.282
332.642
333.971
335.271
336.543
337.789
339.009
340.204
341.377
342.526
343.655
344.762
345.850
346.919
347.969
349.002
350.018
351.017
352.000
352.968
353.922
354.861
S°(T)
211.546
235.674
251.222
251.476
263.736
273.845
282.486
290.053
296.794
302.875
308.413
313.497
318.194
322.556
326.628
330.445
334.036
337.424
340.633
343.678
346.576
349.340
351.982
354.511
356.938
359.269
361.512
363.674
365.761
367.776
369.727
371.615
373.447
375.225
376.952
378.632
380.267
381.861
383.414
384.931
386.412
387.860
389.276
390.663
392.021
393.352
394.657
395.937
397.195
398.430
399.644
400.837
402.011
403.166
404.303
405.423
406.526
407.613
408.685
409.742
410.784
КРЕМНИЯ
"'(SiflCl)
Я°G>ЯС
SiHCI (г)
Д Я°@) = 739.000
'@)
кДж . моль
3.329
6.830
10.665
10.741
15.010
19.545
24.287
29.198
34.248
39.411
44.669
50.003
55.401
60.852
66.347
71.879
77.443
83.033
88.646
94.279
99.929
105.594
111.273
116.963
122.664
128.375
134.095
139.823
145.560
151.305
157.057
162.818
168.586
174.363
180.149
185.945
191.750
197.566
203.392
209.231
215.081
220.945
226.822
232.714
238.620
244.542
250.480
256.435
262.407
268.397
274.405
280.431
286.476
292.541
298.625
304.728
310.851
316.993
323.156
329.338
335.540
-379.3485
-185.0709
-120.8515
-120.0429
-87.4217
-67.7939
-54.6762
-45.2858
-38.2293
-32.7312
-28.3257
-24.7160
-21.7038
¦19.1519
-16.9619
-15.0618
-13.3974
-11.9273
-10.6192
-9.4476
-8.3922
-7.4364
-6.5666
-5.7716
-5.0423
-4.3706
-3.7501
-3.1749
-2.6404
¦2.1422
-1.6769
-1.2411
-.8323
-.4478
,0857
.2561
.5791
.8850
1.1750
1.4504
1.7122
1.9614
2.1990
2.4256
2.6422
2.8492
3.0474
3.2373
3.4194
3.5942
3.7621
3.9235
4.0788
4.2283
4.3723
4.5112
4.6451
4.7744
4.8994
5.0201
5.1368
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
1
л
- 3
г 2
л
о ?
¦ х
х 5
¦* ГЧ -^
¦*' И ^
^? ЭО
II Ch
3; ~ "
и '-.
и С
о Vj^
о "V
<\
1
г- 1
-О Ч
о 2
— „¦
+ 1
чО ^
s i
§ 5
н +
X
in
Г- ОО
1П CN
¦ о
СП ГЧ
И +
0
45 7
i
С
„¦
1
.
о
ее
ГЧ
II
о 5
to
я
О
чО
V
V
о
о
*'"
1
о
II
252

Класс точно
V-I-"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ста
с;сл
36.568
42.778
47.493
47.567
50.802
52.889
54.254
55.174
55.816
56.278
56.621
56.880
57.082
57.241
57.369
57.473
57.559
57.631
57.691
57.742
57.786
57.824
57.857
57.886
57.912
57.934
57.954
57.972
57.988
58.002
58.015
58.027
58.037
58.047
58.056
58.064
58.071
58.078
58.085
58.091
58.096
58.101
58.106
58.110
58.114
58.118
58.121
58.125
58.128
58.131
58.134
58.136
58.139
58.141
58.143
58.145
58.147
58.149
58.151
58.153
58.154
ФТОРИД-ХЛОРИД
К°(Т)= p(Si)-
Ф° G)
— 1 ~
Дж ¦ К • моль
195.575
220.072
235.345
235.590
247.360
256.978
265.161
272.302
278.640
284.357
289.552
294.319
298.722
302.814
306.636
310.222
313.600
316.792
319.817
322.693
325.433
328.050
330.555
332.956
335.261
337.479
339.616
341.676
343.667
345.591
347.454
349.259
351.009
352.709
354.360
355.966
357.529
359.050
360.533
361.979
363.391
364.768
366.114
367.429
368.716
369.974
371.206
372.412
373.594
374.753
375.888
377.002
378.095
379.168
380.222
381.256
382.273
383.272
384.255
385.221
386.171
*<F>.P(C1,.,
S°(T)
1
229.700
257.020
275.032
275.326
289.486
301.063
310.835
319.272
326.684
333.286
339.234
344.644
349.602
354.177
358.424
362.386
366.098
369.590
372.886
376.006
378.969
381.789
384.480
387.053
389.517
391.881
394.154
396.341
398.450
400.485
402.452
404.354
406.197
407.983
409.716
411.399
413.035
414.626
416.175
417.684
419.154
420.589
421.989
423.357
424.692
425.998
427.276
428.526
429.750
430.948
432.123
433.274
434.403
435.510
436.597
437.664
438.712
439.741
440.752
441.746
442.724
КРЕМНИЯ
"' (SiFCl)
Н°(Т)-Н'
SiFCl (г)
Д.Я°@) = 1020.000
'@)
кДж . моль
3.412
7.390
11.833
11.921
16.851
22.043
27.405
32.879
38.430
44.036
49.682
55.357
61.056
66.772
72.503
78.245
83.997
89.757
95.523
101.295
107.071
112.852
118.636
124.423
130.213
136.005
141.800
147.596
153.394
159.194
164.994
170.796
176.600
182.404
188.209
194.015
199.822
205.629
211.437
217.246
223.056
228.865
234.676
240.487
246.298
252.109
257.921
263.734
269.546
275.359'
281.172
286.986
292.800
298.614
304.428
310.242
316.057
321.872
327.687
333.502
339.317
-524.8162
-257.2029
-168.8762
-167.7651
-122.9589
-96.0331
-78.0591
-65.2061
-55.5567
-48.0449
-42.0305
-37.1059
-32.9992
-29.5219
-26.5394
-23.9529
-21.6883
-19.6889
-17.9106
-16.3185
-14.8847
-13.5867
-12.4059
-11.3272
-10.3378
-9.4269
-8.5856
-7.8061
-7.0818
-6.4071
-5.7769
¦5.1870
-4.6336
-4.1135
-3.6236
-3.1614
-2.7246
-2.3111
-1.9192
-1.5471
-1.1934
-.8567
-.5359
-.2298
.0626
.3422
.6098
.8661
1.1119
1.3479
1.5745
1.7924
2.0021
2.2039
2.3985
2.5860
2.7670
2.9417
3.1105
3.2737
3.4315
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та б
t
А
О
_ Г-
Ch с^
Я |
гч' И
II °
у
•-'
И?
i
<*. 'л
° О
\J ,
1 *
о =*
О <п
1 2
со
• 00
10 гч
» j
r-t ГЧ
^N О
Tj- ГЧ
II +
о
V
л и
я
о
S
¦**
гч
I—
г-
1
II
я
1/1
ОС
ON
ГЧ
G
ч.
ца 458
т
i
ОС
ОС
¦*'
сч
II
о g
<*>
S
о
о
о
V
(-
V
о
о
«t
I
о
II
is
253

Класс точности 1
IV- F 1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С(Т)
30.548
36.606
38.711
38.727
39.015
38.902
38.751
38.634
38.559
38.519
38.506
38.514
38.538
38.575
38.622
38.678
38.742
38.813
38.891
38.975
39.064
39.160
39.263
39.372
39.489
39.614
39.747
39.888
40.040
40.200
40.371
40.551
40.742
40.941
41.149
41.364
41.586
41.813
42.044
42.276
42.509
42.741
42.969
43.192
43.409
43.616
43.813
43.998
44.170
44.328
44.469
44.594
44.702
44.792
44.864
44.917
44.952
44.967
44.965
44.944
44.906
БРОМИД КРЕМНИЯ SiBr (г)
К°(Т) = р (Si) ¦ р (Вг) ¦ p'Vsfflr)
Ф° G-) '
Дж • К . моль
179.555
200.498
213.520
213.728.
223.615
231.518
238.092
243.714=
248.624
252.979
256.892
260.445
263.697
266.697
269.480
272.076
274.509
276.798
278.960
281.008
282.954
284.807
286.577
288.271
289.894
291.454
292.955
294.401
295.796
297.145
298.450
299.715
300.941
302.131
303.288
304.413
305.509
306.576
307.618
308.634
309.626
310.596
311.545
312.473
313.382
314.272
315.145
316.001
316.841
317.665
318.475
319.270
320.051
320.819
321.574
322.317
323.048
323.768
324.476
325.173
325.860
5°(Г)
1
208.890
232.064
247.176
247.416
258.615
267.312
274.391
280.355
285.508
290.047
294.105
297.775
301.127
304.213
307.074
309.740
312.238
314.589
316.810
318.915
320.916
322.824
324.649
326.396
328.074
329.689
331.245
332.748
О ** Л АЛ 1
334.201
335.609
336.975
338.301
339.592
340.848
342.074
343.270
344.438
345.580
346.699
347.794
348.867
349.920
350.952
351.966
352.962
353.939
354.900
355.844
356.773
357.685
358.582
359.464
360.331
361.183
362.021
362.845
363.654
364.450
365.232
366.001
366.756
Д Я°@) = 383.000
Я°Ш-Я°@)
кДж . моль"
2.934
6.313
10.035
10.106
14.000
17.897
21.780
25.648
29.508
33.361
37.213
41.063
44.916
48.771
52.631
56.496
60.367
64.245
68.130
72.023
75.925
79.836
83.757
87.689
91.632
95.587
99.555
103.537
107.533
111.545
115.574
119.620
123.684
127.768
131.873
135.998
140.146
144.316
148.508
152.724
156.964
161.226
165.512
169.820
174.150
178.501
182.873
187.263
191.672
196.097
200.537
204.990
209.455
213.930
218.413
222.902
227.396
231.892
236.388
240.884
245.376
-196.6490
-95.9791
-62.7560
-62.3382
-45.4973
-35.3836
-28.6354
-23.8113
-20.1901
-17.3710
-15.1137
-13.2650
-11.7228
-10.4164
-9.5954
-8.3227
-7.4705
-6.7176
-6.0474
-5.4470
-4.9059
-4.4157
-3.9693
.-3.5612
-3.1866
-2.8415
-2.5224
-2.2266
-1.9515
-1.6951
-1.4554
-1.2309
-1.0202
-.8220
-.6352
-.4590
-.2923
-.1345
.0151
.1572
.2922
.4208
.5433
.6602
.7719
.8786
.9807
1.0786
1.1723
1.2623
1.3487
1.4317
1.5115
1.5883
1.6623
1.7336
1.8023
1.8686
1.9327
1.9945
2.0543
кДж • моль
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 459
с
7 1
R L ~
§ Ч "°
. х В
^ СО ?
-> § ? *
00 ¦ II ^
"~-* — я 5
¦ 2 и 12 *°
" о °° о
§ - Я м
^ .. и
S к" о «
сл П со
о 52-
*^« о
"-• а:
< ^
1
V
оо 7
г! п
о
о s
+ „¦
>2 • Я
00 ? О
чо г^ О
О *\(
о 3 V
т ¦*• *-
' °° V
л ' °
СЛ К 
5 г~ »¦"
-t .« io
¦* 2 —
? ? "
II 1
0
е
254

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
41.257
49.663
53.587
53.635
55.444
56.376
56.909
57.241
57.460
57.613
57.723
57.805
57.867
57.916
57.955
57.987
58.012
58.034
58.052
58.067
58.080
58.091
58.101
58.109
58.117
58.123
58.129
58.134
58.139
58.143
58.147
58.150
58.154
58.156
58.159
58.161
58.163
58.165
58.167
58.169
58.171
58.172
58.173
58.175
58.176
58.177
58.178
58.179
58.180
58.181
58.181
58.182
58.183
58.184
58.184
58.185
58.185
58.186
58.186
58.187
58.187
ДИБРОМИД КРЕМНИЯ SiBr2
К°(Т)= p(Si)-f
Ф°(Г)
Дж . К~' . моль"
216.069
242.778
259.899
260.176
273.402
284.134
293.178
300.999
307.890
314.050
319.619
324.702
329.375
333.701
337.728
341.494
345.031
348.365
351.518
354.510
357.355
360.068
362.659
365.140
367.520
369.806
372.006
374.126
376.171
378.147
380.058
381.908
383.701
385.441
387.130
388.771
390.368
391.921
393.435
394.910
396.348
397.752
399.123
400.462
401.771
403.052
404.305
405.531
406.732
407.909
409.062
410.193
411.303
412.392
413.460
414.510
415.540
416.553
417.549
418.528
419.491
(Г)
>2(Br)-p-'(SiBr2) Дг#°@)= 718.093 кДж • моль"
S°(T)
1
252.459
283.897
304.564
304.896
320.604
333.087
343.416
352.216
359.875
366.652
372.728
378.234
383.266
387.900
392.193
396.193
399.936
403.454
406.771
409.911
412.889
415.723
418.426
421.009
423.482
425.855
428.134
430.328
432.443
434.483
436.454
438.361
440.207
441.996
443.733
445.419
447.057
448.651
450.202
451.713
453.186
454.622
456.024
457.393
458.730
460.037
461.316
462.568
463.792
464.992
466.167
467.320
468.449
469.558
470.645
471.713
472.761
473.791
474.803
475.798
476.776
Н°(Г)-Н°@)
кДж • моль
3.639
8.224
13.317
13.416
18.881
24.476
30.143
35.852
41.587
47.342
53.109
58.885
64.669
70.458
76.252
82.049
87.849
93.651
99.456
105.262
111.069
116.877
122.687
128.498
134.309
140.121
145.934
151.747
157.560
163.374
169.189
175.004
180.819
186.635
192.450
198.266
204.083
209.899
215.716
221.532
227.349
233.167
238.984
244.801
250.619
256.436
262.254
268.072
273.890
279.708
285.526
291.344
297.162
302.981
308.799
314.618
320.436
326.255
332.073
337.892
343.711
Т
к
-366.7243 100
-178.0869 200
-115.8344 298.15
-115.0515 300
-83.4866 400
-64.5267 500
-51.8752 600
-42.8310 700
-36.0426 800
-30.7586 900
-26.5281 1000
-23.0639 1100
-20.1746 1200
-17.7276 1300
-15.6281 . 1400
-13.8067 1500
-12.2113 1600
-10.8020 1700
¦9.5478 1800
-8.4243 1900
-7.4120 2000
-6.4949 2100
-5,6601 2200
-4.8969 2300
-4.1964 2400
-3.5510 2500
-2.9546 2600
-2.4015 2700
t Л rt *V Л Л Л Л Л
-1.8873 2800
-1.4079 2900
т.9599 3000
-.5402 3100
-.1462 3200
.2244 3300
.5737 3400
.9034 3500
1.2153 3600
1.5106 3700
1.7908 3800
2.0570 3900
2.3101 4000
2.5512 4100
2.7812 4200
3.0007 4300
3.2104 4400
3.4111 4500
3.6033 4600
3.7876 4700
3.9644 4800
4.1341 4900
4.2973 5000
4.4542 5100
4.6053 5200
4.7508 5300
4.8912 5400
5.0265 5500
5.1572 5600
5.2834 5700
5.4054 5800
5.5234 5900
5.6376 6000
Таблица 460
1
i
л
— о
1 5
л
о х 7
5 Н А
* § i
;*; ^ —• *
? ^ Ь?
СО j ™
" ю ». *
№ п ^ ё^
г-' ' in м
2 " "" ^>
'' ^ ON ГП
¦З >-• о eg
"?, <S to
t*""% a;
ON
° 5
+ s
'x "'
о Ч '¦о
§ тн , V
si v
¦ s ? §
P n "">
oo' <N "o
О —i
oo ><
оо чо II
is s
5 d
0
©
255

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°{Т)
53.678
68.603
75.233
75.314
78.396
79.992
80.911
81.483
81.862
82.125
82.316
82.457
82.566
82.650
82.718
82.772
82.817
82.854
82.885
82.912
82.934
82.954
82.971
82.985
82.998
83.010
83.020
83.029
83.037
83.044
83.051
83.057
83.062
83.067
83.071
83.075
83.079
83.083
83.086
83.089
83.091
83.094
83.096
83.099
83.101
83.103
83.104
83.106
83.108
83.109
83.110
83.112
83.113
83.1! 4
83.115
83.116
83.117
83.118
83.119
83.120
83.121
ТРИБРОМИД КРЕМНИЯ SiBr3
К°(Т) =р (Si)-p
Ф°(Т)
Дж • К . моль
238.587
270.746
292.780
293.143
310.691
325.171
337.506
348.250
357.768
366.311
374.060
381.149
387.682
393.740
399.387
404.675
409.648
414.340
418.781
422.998
427.011
430.840
434.500
438.006
441.370
444.603
447.716
450.716
453.611
456.410
459.117
461.739
464.280
466.747
469.142
471.470
473.735
475.940
478.088
480.182
482.224
484.217
486.164
488.066
489.926
491.745
493.525
495.268
496.975
498.647
500.287
501.895
503.472
505.020
506.540
508.033
509.499
510.940
512.356
513.748
515.118
s°cn
1
Н°(Т)-Н°@)
кДж ¦ моль
280.147 4.156
322.539 10.359
351.344 17.461
351.810 17.600
373.951 25.304
391.633 33.231
406.306 41.280
418.825 49.402
429.732 57.570
439.390 65.771
448.053 73.993
455.905 82.232
463.085 90.483
469.697 98.744
475.825 107.013
481.534 115.288
486.877 123.567
491.899 131.851
496.636 140.138
501.118 148.428
505.371 156.720
509.418 165.014
513.277 173.311
516.966 181.608
520.498 189.908
523.886 198.208
527.142 206.509
530.276 214.812
533.295 223.115
536.209 231.419
539.025 239.724
541.748 248.029
544.385 256.335
546.94! 264.642
549.421 272.948
551.829 281.256
554.169 289.563
556.446 297.872
558.662 306.180
560.820 314.489
562.924 322.798
564.975 331.107
566.977 339.416
568.933 347.726
570.843 356.036
572.711 364.346
574.537 372.657
576.325 380.967
578.074 389.278
579.788 397.589
581.467 405.900
583.113 414.211
584.727 422.522
586.310 430.833
587.864 439.145
589.389 447.456
590.886 455.768
592.357 464.080
593.803 472.392
595.224 480.704
596.621 489.016
(г)
°@) = 1002.900 кДж • моль
ЫК°(Т)
Т
К
-509.8022 100
-246.3139 200
-159.3979 298.15
-158.3051 300
-114.2564 400
-87.8118 500
-70.1753 600
-57.5743 700
-48.1214 800
-40.7675 900
-34.8830 1000
-30.0671 1100
-26.0526 1200
-22.6544 1300
-19.7405 1400
-17.2139 1500
-15.0020 1600
-13.0492 1700
-11.3123 1800
-9.7573 1900
-8.3568 2000
-7.0888 2100
-5.9353 2200
-4.8813 2300
-3.9144 2400
-3.0242 2500
-2.2019 2600
-1.4399 2700
-.7318 2800
-.0720 2900
.5443 3000
1.1213 3100
1.6626 3200
2.1714 3300
2.6507 3400
3.1030 3500
3.5304 3600
3.9350 3700
4.3186 3800
4.6827 3900
5.0289 4000
5.3584 4100
5.6724 4200
5.9720 4300
6.2582 4400
6.5319 4500
6.7938 4600
7.0447 4700
7.2852 4800
7.5161 4900
7.7379 5000
7.9512 5100
8.1563 5200
8.3538 5300
8.5441 5400
8.7275 5500
8.9045 5600
9.0754 5700
9.2405 5800
9.4000 5900
9.5543 6000
11
Таблица 461
о
V
« *
* ° о
so 2
s я ^
f*1 II ¦>
о _ Д
<N СГ Ч
| ? <=>
я »• S-
- °^ vn
го ^ "
с/3 <Й ° *
Л ^
О ч^>
< <-,
^\
_+
к
00
°\ А
° О
н Т ^
2 * 1
S Ч VO
S '"* V
1 ° *""
Я 5 о
s i ?.
СП "«* О
00 • vm
| F*
О Н
От II
v~> О
И -f-
0
256

Класс точности
VI-1
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
70.690
88.479
97.008
97.116
101.316
103.552
104.856
105.676
106.222
106.603
106.879
107.085
107.243
107.366
107.464
107.544
107.609
107.663
107.709
107.747
107.780
107.809
107.833
107.855
107.874
107.890
107.905
107.918
107.930
107.941
107.950
107.959
107.967
107.974
107.981
107.987
107.992
107.997
108.002
108.006
108.010
108.014
108.017
108.021
108.024
108.026
108.029
108.031
108.034
108.036
108.038
108.040
108.042
108.043
108.045
108.047
108.048
108.049
108.051
108.052
108.053
ТЕТРАБРОМИД КРЕМНИЯ SiBr4
К°(Т)= р (Si) •
Ф°(Г)
Дж • К . моль
235.982
276.334
304.417
304.881
327.343
345.926
361.786
375.620
387.889
398.910
408.914
418.072
426.516
434.349
441.654
448.497
454.933
461.007
466.759
472.220
477.419
482.380
487.123
491.666
496.027
500.219
504.254
508.144
511.899
515.528
519.039
522.439
525.736
528.936
532.043
535.064
538.002
540.863
543.650
546.367
549.017
551.604
554.131
556.600
559.013
561.374
563.685
565.947
568.163
570.334
572.463
574.550
576.598
578.608
580.581
582.519
584.422
5S6.293
588.132
589.940
591.718
р4(Вг) ¦ р" '(SiBr.
S°{T)
-1
286.971
342.132
379.256
379.857
408.438
431.310
450.315
466.545
480.694
493.228
504.475
514.672
523.996
532.586
540.546
547.963
554.906
561.431
567.587
573.411
578.939
584.198
589.214
594.008
598.599
603.002
607.234
611.307
615.232
619.020
622.679
626.219
629.646
632.969
636.192
639.322
642.365
645.324
648.204
651.009
653.744
656.411
659.014
661.556
664.039
666.466
668.841
671.164
673.439
675.666
677.849
679.988
682.086
684.144
686.164
688.146
690.093
692.006
693.885
695.732
697.548
.)
Я°(Г)-Я°@)
кДж . моль
5.099
13.159
22.313
22.493
32.438
42.692
53.118
63.647
74.244
84.886
95.561
106.260
116.977
127.707
138.449
149.199
159.957
170.721
181.489
192.262
203.039
213.818
224.600
235.385
246.171
256.959
267.749
278.540
289.333
300.126
310.921
321.716
332.513
343.310
354.108
364.906
375.705
386.504
397.304
408.105
418.906
429.707
440.508
451.310
462.112
472.915
483.718
494.521
505.324
516.128
526.93!
537.735
548.539
559.343
570.148
580.952
591.757
602.562
613.367
624.172
634.977
(г)
@)= 1303.215
о
-659.6682
-317.422!
-204.5686
-203.1499
-145.9734
-111.6575
-88.7783
¦72.4364
-60.1808
-50.6495
-43.0249
•36.7869
-31.5884
-27.1895
-23.4185
•20.1499
-17.2892
-14.7644
-12.5195
-10.5102
-8.7013
-7.0640
-5.5749
-4.2148
-2.9675
-1.8195
-.7594
.2226
1.1349
1.9847
2.7781
3.5206
4.2171
4.8716
5.4878
6.0690
6.6182
7.1378
7.6303
8.0977
8.5419
8.9645
9.3672
9.7512
10.1179
10.4684
10.8037
11.1248
11.4327
11.7280
12.0116
12.2841
12.5462
12.7985
13.0415
13.2756
13.5015
13.7195
13.9299
14.1333
14.3299
кДж • молъ
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
'л
о
1 "*
л
О н—}
5 ^^
it О
Ё? со
* 1Л
in 5
и-1 °°. !
О « "
I— СО '—
5 „' 2
и о S
а *
о"' 5S
Э; о
<J Ч
+
}
Ч
тг _
~* ' ^
+ О
О! S
| ,
X -
о *
о ^
° пн
Ч го
-— О
°°. о
о J2
J^ i
I— ч
^ -
чО О
1! +
0
V
ц а 462
1 л
§
s
-'
'ы
Р!
л
о К
to
я
о
о
V
V
о
о
Tf""
'о
II
1? 1034
257

Класс точности
V — L
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
30.408
35.416
38.796
38.838
40.227
40.521
40.391
40.143
39.893
39.679
39.509
39.380
39.286
39.223
39.185
39.168
39.168
39.183
39.212
39.253
39.304
39.365
39.435
39.513
39.598
39.690
39.787
39.888
39.992
40.097
40.202
40.303
40.401
40.492
40.576
40.650
40.712
40.763
40.800
40.822
40.828
40.819
40.793
40.751
40.692
40.617
40.526
40.419
40.297
40.161
40.01
39.849
39.675
39.490
39.294
39.090
38.878
38.658
38.432
38.201
37.965
ИОДИД КРЕМНИЯ Sil (г)
А"°G~) = р (Si) ¦ р (I) • р~ '(Sil)
Ф°(Г)
Дж • К . моль
186.674
207.501
220.318
220.524
230.307
238.204
244.828
250.525
255.517
259.955
263.948
267.574
270.895
273.957
276.798
279.446
281.927
284.260
286.462
288.547
290.527
292.411
294.210
295.930
297.579
299.161
300.683
302.149
303.563
304.929
306.250
307.528
308.768
309.971
311.139
312.274
313.379
314.454
315.502
316.523
317.520
318.493
319.443
320.372
321.280
322.168
323.037
323.889
324.722
325.539
326.339
327.124
327.893
328.648
329.388
330.115
330.829
331.530
332.218
332.894
333.559
S°(T)
1
216.019
238.632
253.479
253.719
265.120
274.140
281.520
287.728
293.072
297.758
301.929
305.688
309.111
312.253
315.158
317.861
320.388
322.763
325.004
327.125
329.140
331.059
332.892
334.646
336.330
337.948
339.507
341.010
342.463
343.868
345.229
346.549
347.830
349.075
350.285
351.462
352.608
353.724
354.812
355.872
356.906
357.914
358.897
359.856
360.792
361.706
362.598
363.468
364.318
365.147
365.957
366.748
367.520
368.274
369.010
369.729
370.431
371.117
371.788
372.443
373.082
V
Н°(Т)-Н°@)
кДж . моль"
2.935
6.226
9.887
9.959
13.925
17.968
22.015
26.042
30.044
34.022
37.981
41.925
45.859
49.784
53.704
57.621
61.538
65.456
69.375
73.298
77.226
81.160
85.100
89.047
93.003
96.967
100.941
104.925
108.919
112.923
116.939
120.964
124.999
129.044
133.097
137.159
141.227
145.301
149.379
153.460
157.542
161.625
165.705
169.782
173.854
177.920
181.977
186.024
190.060
194.082
198.091
202.083
206.059
210.017
213.956
217.875
221.773
225.649
229.503
233.334
237:142
Г°@) = .290.000
-148.1419
-71.7547
-46.5168
-46.1993
-33.4011
-25.7160
-20.5897
-16.9261
-14.1769
-12.0372
-10.3242
-8.9216
-7.7518
-6.7612
-5.9112
-5.1739
-4.5281
-3.9576
-3.4500
-2.9952
-2.5854
-2.2141
-1.8762
-1.5672
-1.2835
-1.0222
-.7805
-.5565
-.3481
-.1538
.0279
.1980
.3579
.5082
.6500
.7839
.9105
1.0304
1.1443
1.2525
1.3554
1.4535
1.5470
1.6364
1.7218
1.8036
1.8819
1.9570
2.0292
2.0985
2.1651
2.2293
2.2911
2.3507
2.4082
2.4638
2.5174
2.5693
2.6195
2.6682
2.7153
кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 463
1.
-
'л
__ о
'-о • 7
"* v §
^ о — '
"Я OS I
О rJ
О О sc
с*. ^ и сЗ
"* гч — гч
~ ^ i? ?
5 о S
гч н
я' С. 0 3
СО К C/J
о"' *?
**ч 0
1
1
о т
""" ?
¦* с
с
"*" 1
г) *>
1 
^ "З о
§ g v
+ гч' t
- с с
— ас
""! "¦* 1
+ + •
3 о !|
W*"> Г4)
ГО —<
II i
ь
о
©
258

Класс
\
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
470С
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
гочности
1 - F
со
1
44.960
52.785
55.475
55.505
56.620
57.169
57.476
57.665
57.789
57.874
57.936
57.982
58.016
58.043
58.065
58.083
58.097
58.109
58.119
58.127
58.134
58.140
58.146
58.150
58.155
58.158
58.161
58.164
58.167
58.169
58.171
58.173
58.175
58.176
58.178
58.179
58.180
58.181
58.182
58.183
58.184
58.185
58.186
58.186
58.187
58.188
58.188
58.189
58.189
58.190
58.190
58.191
58.191
58.191
58.192
58.192
58.192
58.193
58.193
58.193
58.193
ДИИОДИД КРЕМНИЯ Sil2
A'V>-,(*>-,
Ф°(Г)
Дж • К~' . моль"
229.627
258.208
276.497
276.79.1
290.778
302.028
311.445
319.546
326.655
332.989
338.700
343.901
348.674
353.086
357.186
361.017
364.611
367.996
371.195
374.227
377.108
379.854
382.476
384.985
387.391
389.701
391.923
394.062
396.127
398.120
400.047
401.913
403.721
405.474
407.176
408.829
410.437
412.002
413.526
415.010
416.458
417.871
419.250
420.598
421.914
423.202
424.462
425.695
426.903
428.086
429.245
430.382
431.497
432.591
433.665
434.719
435.755
436.772
437.772
438.756
439.722
2(l)-psil2)
S°(T)
1
268.283
302.303
323.966
324.310
340.451
353.151
363.603
372.479
380.187
386.999
393.100
398.624
403.671
408.316
412.618
416.625
420.374
423.896
427.218
430.360
433.342
436.179
438.884
441.468
443.943
446.317
448.599
450.794
452.909
454.950
456.922
458.829
460.676
462.467
464.204
465.890
467.529
469.123
470.675
472.186
473.659
475.096
476.498
477.867
479.205
480.512
481.791
483.043
484.268
485.468
486.643
487.796
488.925
490.034
491.121
492.189
493.238
494.268
495.280
496.275
497.253
А,
Н°(Т)-Н°@)
кДж • моль
3.866
8.819
14.153
14.256
19.869
25.561
31.295
37.053
42.826
48.609
54.400
60.196
65.996
71.799
77.604
83.412
89.221
95.031
100.843
106.655
112.468
118.282
124.096
129.911
135.726
141.542
147.358
153.174
* Р Л Г\ Г\ /к
158.990
164.807
170.624
176.441
182.259
188.076
193.894
199.712
205.530
211.348
217.166
222.984
228.803
234.621
240.440
246.258
252.077
257.896
263.715
269.533
275.352
281.171
286.990
292.809
298.628
304.447
310.267
316.086
321.905
327.724
333.544
339.363
345.182
(Г)
Я°@)= 564.733
1е.К°(Т)
-286.7238
-138.2371
-89.2310
-88.6146
-63.7649
-48.8375
-38.8757
-31.7536
-26.4073
-22.2457
-18.9136
-16.1852
-13.9096
-11.9826
-10.3295
-8.8956
-7.6398
-6.5308
-5.5440
¦4.6603
-3.8640
-3.1428
-2.4864
-1.8864
-1.3357
-.8284
-.3595
.0753
.4796
.8566
1.2090
1.5391
1.8491
2.1408
2.4158
2.6755
2.9211
3.1539
3.3748
3.5847
3.7845
3.9748
4.1564
4.3299
4.4957
4.6545
4.8066
4.9525
5.0925
5.2272
5.35*56
5.4811
5.6011
5.7168
5.8283
5.9360
6.0400
6.1405
6.2377
6.3318
6.4229
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
. 2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б
_
о
2
5
X
5 чО
ОС ^"'
ГЧ ,;
И —.
™
СЛ
о
<
+
1
^г _
Ч ' л
л. О
+ 2
к Т
00
s >=t
О го
о *
1 п
X ®
? +
со
о ^н
оо о
+
г- г-
о' °
*t о
II +
V
о
лиц
-
о
г
п
о
о
м
ее
гч
ГД
¦—
О
а 464
.а
о
7
¦f
s
о
г~1
II
Ч
о Ж
я
о
о
о
чО
V
к.
V
о
«'"
1)
is
259

toiac
Г
К
100
200
298
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с точности
VI Г
1'
58.973
72.431
15 77.567
77.627
79.862
80.986
81.623
82.017
82.276
82.455
82.584
82.68!
82.754
82.811
82.857
82.894
82.924
82.949
82.970
82.988
83.003
83.016
83.027
83.037
83.046
83.054
83.060
83.066
83.072
83.077
83.081
83.085
83.089
83.092
83.095
83.098
83.100
83.103
83.105
83.107
83.109
83.110
83.112
83.113
83.115
83.116
83.117
83.118
83.120
83.120
83.121
83.122
83.123
83.124
83.125
83.125
83.126
83.127
83.127
83.128
83.128
л {Т i - р (Si
Ф°(Г)
Дж К " . мо
255.719
290.820
314.508
314.895
333.489
348.674
361.513
372.635
382.446
391.222
399.161
406.409
413.075
419.248
424.994
430.368
435.417
440.176
444.678
448.949
453.011
456.884
460.585
464.128
467.527
470.791
473.933
476.960
479.88!
482.703
485.432
488.074
490.635
493.120
495.532
497.877
500.157
502.376
504.538
506.644
508.699
510.704
512.663
514.575
516.445
518.274
520.064
521.815
523.53!
525.212
526.860
528.475
530.060
531.615
533.142
534.641
536.113
537.560
538.982
540.380
541.756
ТРИИОДИД
• /K<1! • ,'>"VSiI
S°(T)
-1
301.233
346.935
376.965
377.445
400.123
418.077
432.904
445.518
456.488
466.190
474.884
482.760
489.957
496.584
502.722
508.440
513.791
518.819
523.561
528.047
532.304
536.354
540.216
543.907
547.442
550.832
554.089
557.224
560.246
563.161
565.977
568.701
571.339
573.896
576.377
578.786
581.126
583.404
585.620
587.778
589.883
591.935
593.937
595.893
597.804
599.672
601.498
603.286
605.036
606.750
608.429
610.075
611.689
613.273
614.826
616.352
617.850
619.321
620.767
622.187
623.585
КРЕМНИЯ Sil3
) Л,
H°iT) //°@]
-1
кЛж • моль
4.551
1 1.223
18.622
18.765
26.653
34.702
42.835
51.018
59.234
67.471
75.723
83.987
92.258
100.537
108.820
117.108
125.399
133.692
141.988
150.286
158.586
166.887
175.189
183.492
191.796
200.101
208.407
216.713
225.020
233.328
241.636
249.944
258.253
266.562
274.871
283.181
291.491
299.801
308.1 11
316.422
324.733
333.043
341.355
349.666
357.977
366.289
374.600
382.912
391.224
399.536
407.848
416.161
424.473
432.785
441.098
449.410
457.723
466.035
474.348
482.661
490.974
(г)
Я°@)= 779
-392.9226
-188.0232
-120.4303
-119.5804
-85.3256
-64.7613
-51.0469
-41.2485
-33.8984
-2$. 1808
-23.6063
-19.8631
-16.7434
-14.1035
-11.8405
-9.8789
-8.1623
-6.6473
-5.3004
-4.0950
-3.0097
-2.0275
-1.1342
-.3182
.4302
1.1190
1.7553
2.3448
2.8926
3.4030
3.8797
4.3260
4.7447
5.1384
5.5093
5.8593
6.1902
6.5035
6.8006
7.0827
7 3509
7.6064
7.8499
8.0824
6.3045
8.5169
8.7203
8.9153
9.1023
9.2819
9.4545
9.6205
9.7802
9.934!
10.0825
10.2255
10.3637
10.4971
10.6260
10.7507
! 0.8713
156 кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4^00
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Та
_
1
7,
'
о ?
со "Т
5? и
г*"
с/5
о
1
+
1
о
+
1
го
Г—
о
н
В
ГА
ОС
О
_ф-
О
00
r-j
СО
II
?
О
А
б
~*
*\
г~-
со
о
°
о
о
1
о
+
лиц
'л
о
—f
с
m
^>
~~
1
я
ОС
я
с
55
0
а:
а 465
1
•А
о
S
_,'
\О
г--
N
о К
¦
о
о
о
V
V
о
¦'"
'о
II
—
260

Класс точности
VI-F
Т
К
100
1'Ю
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
78.596
94.048
100.574
100.652
103.613
105.129
105.996
106.534
106.889
107.136
107.314
107.447
107.548
107.627
107.690
107.741
107.782
107.817
107.846
107.871
107.892
107.910
107.926
107.939
107.951
107.962
107.971
107.980
107.987
107.994
108.000
108.006
108.011
108.015
108.019
108.023
108.027
108.030
108.033
108.036
108.038
108.041
108.043
108.045
108.047
108.049
108.050
108.052
108.053
108.055
108.056
108.057
108.058
108.059
108.06.0
108.061
108.062
108.063
108.064
108.065
108.066
ТЕТРАИОДИД КРЕМНИЯ Sil4
A°G-)=p(Si)-f
Ф°(Г)
"* 1 ~
Дж • К • моль
258.765
304.365
335.167
335.669
359.825
379.545
396.216
410.658
423.398
434.796
445.106
454.519
463.178
471.196
478.660
485.642
492.200
498.384
504.232
509.781
515.059
520.091
524.900
529.503
533.919
538.161
542.243
546.177
549.972
553.639
557.185
560.619
563.947
567.176
570.311
573.358
576.321
579.205
582.014
584.752
587.423
590.028
592.573
595.059
597.489
599.866
602.192
604.468
606.698
608.883
611.024
613.124
615.184
617.205
6(9.189
621.137
623.051
624.932
626.780
628.598
630.385
(г)
4(I)p !(SU4) Д^Я°@) = 981.909
S°(T)
1
Я°(Г)~-Я°@)
кДж • моль
317.475 5.871
377.381 14.603
416.331 24.199
416.954 24.385
446.366 34.616
469.666 45.061
488.917 55.621
505.300 66.249
519.550 76.922
532.155 87.624
543.452 98.346
553.687 109.085
563.041 119.835
571.652 130.594
579.631 141.360
587.062 152.131
594.017 162.907
600.553 173.687
606.716 184.471
612.548 195.256
618.081 206.045
623.346 216.835
628.366 227.626
633.164 238.420
637.758 249.214
642.165 260.010
646.400 270.807
650.475 281.604
oo4.4Ua *y*.4Uo
658.191 303.202
661.852 314.001
665.394 324.802
668.823 335.602
672.147 346.404
675.372 357.205
678.503 368.008
681.546 378.810
684.506 389.613
687.387 400.416
690.193 411.220
692.928 422.023
695.596 432.827
698.200 443.632
700.742 454.436
703.226 465.240
705.654 476.045
708.029 486.850
710.352 497.655
712.627 508.460
714.855 519.266
717.039 530.072
719.178 540.877
721.276 551.683
723.335 562.489
725.355 573.295
727.338 584.101
729.285 594.907
731.197 605.713
733.077 616.520
734.924 627.326
736.740 638.132
-491.8219
-233.7654
-148.6787
-147.6091
-104.5069
-78.6420
-61.3996
-49.0857
-39.8524
-32.6730
-26.9311
-22.2348
-18.3224
-15.0131
-12.1774
-9.7205
-7.5713
-5.6754
-3.9906
-2.4833
-1.1269
.1002
1.2157
2.2342
3.1679
4.0270
4.8201
5.5547
ft OtftQ
О.^оОУ
6.8723
7.4655
8.0207
8.5413
90306
9.4914
9.9260
10.3366
10.7253
11.0937
11.4435
11.7759
12.0933
12.3938
12.6814
12.9562
13.2189
13.4703
13.7112
13.9422
14.1639
14.3768
14.5816
14.7785
14.9682
15.1509
15.3272
15.4972
15.6613
15.8199
15.9732
16.1215
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 466
-
'л
7 2
¦Д 2
О v """
i? О
А ° s
!й О ¦-(
О <-Л !(
W1 ""* ""**
с") С— 1 ^
^ ~ Я S
in ц •Л "Л
" =• 2 3
S ° <К ¦
С <"^_ и
¦f и ч
S3 Л 0 «
СЛ —j Со
о "•
о ,
„+
'к
ON
О
¦з- _,
о 7
+ i
'н -'
и 'w Я
vi О
\О ' О
о ¦ ^ ,
6 « V
1 m S-
* 2 V
S о о
со v")
°i «2 ¦'"
г- m I
О г<1 ?Э
*~^ О .
со г- "
2 2
II -Ь
0
е
261

Класс точности
VII-F
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1363
1363
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
со(Г)
45.000
45.028
46.530
48.033
49.536
51.038
52.541
54.043
55.546
57.049
58.551
60.054
61.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
СУЛЬФИД
K°G-)=p(SiS)
Ф°(Л
Дж . К • моль
32.814
33.001
42.285
50.204
57.093
63.198
68.690
73.694
78.298
82.570
86.563
90.317
92.575
92.575
94.469
99.335
103.872
108.122
112.119
115.891
119.462
122.853
126.081
129.160
132.104
134.924
137.631
140.232
142.737
145.151
147.481
149.733
151.912
154.022
156.068
158.053
SV)
1
63.000
63.278
76.438
86.982
95.873
103.621
110.535
116.810
122.582
127.946
132.975
137.720
140.585
163.329
165.123
169.745
174.070
178.131
181.961
185.584
189.020
192.289
195.406
198.384
201.236
203.971
206.599
209.127
211.564
213.915
216.186
218.383
220.511
222.572
224.572
226.515
КРЕМНИЯ SiS (к,
л, и-
Н°(Т)-Н°@)
кДж . моль
9.000
9.083
13.661
18.389
23.268
28.296
33.475
38.805
44.284
49.914
55.694
61.624
65.437
96.437
98.916
105.616
112.316
119.016
125.716
132.416
139.116
145.816
152.516
159.216
165.916
172.616
179.316
186.016
192.716
199.416
206.116
212.816
219.516
226.216
232.916
239.616
ж)
@) = 277.000
о
-40.1299
-39.8307
-27.8023
-20.6186
-15.8525
-12.4654
-9.9391
-7.9858
-6.4333
-5.1719
-4.1287
-3.2531
-2.7709
-2.7709
-2.5406
-1.9801
-1.4961
-1.0747
-.7051
-.3769
-.0894
.1689
.4004
.6088
.7970
.9677
1.1229
1.2644
1.3939
1.5125
1.6215
1.7219
1.8144
1.9000
1.9791
2.0525
кДж • моль
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1363
1363
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
о
VO
II
5;
_+
00
го
о
X
?

О
.3364 +
= 160.
g
о
Таблица
¦|
S
¦
00
сч
о
1
1
II
о
а
И
а;
1
-
н
+ 75.1
-
Й
о
2?
J<
г-
р-
00
00
«-Н
1
II
5
So
00
а
о
а;
S
-¦
~ «9
а ~
S '*
2 S
V ?
к О
V '
н
S 9
ГЦ «5
? ?
с! &
g
о
467
i
о
S
i
а
00
°°.
II
ьа
500К)
ел
V
V
3
То
п
262

1 Класс точности
II-D
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
29.127
30.260
32.272
32.307
33.900
34.954
35.650
36.125
36.462
36.712
36.903
37.054
37.178
37.281
37.369
37.446
37.515
37.577
37.634
37.687
37.737
37.785
37.831
37.876
37.920
37.965
38.011
38.059
38.109
38.165
38.225
38.293
38.370
38.457
38.557
38.670
38.800
38.949
39.117
39.307
39.521
39.761
40.028
40.323
40.647
41.002
41.389
41.807
42.257
42.740
43.253
43.799
44.374
44.979
45.612
46.271
46.955
47.662
48.389
49.134
49.894
СУЛЬФИД КРЕМНИЯ SiS (г)
К°(Т)= р (Si) - j
Ф°(П
Дж . К~' .моль"
161.581
181.788
193.603
193.788
202.520
209.466
215.269
220.265
224.660
228.585
232.134
235.373
238.354
241.115
243.686
246.093
248.355
250.489
252.508
254.426
256.250
257.9«1
259.655
261.249
262.780
264.251
265.667
267.032
268.351
269.625
270.858
272.053
273.212
274.337
275.430
276.492
277.527
278.535
279.517
280.476
281.411
282.326
283.219
284.094
284.950
285.788
286.610
287.416
288.206
288.983
289.746
290.496
291.234
291.960
292.675
293.379
294.073
294.757
295.432
296.099
296.757
о (S). р~ 1(SiS)
S°(T)
1
190.674
211.101
223.561
223.761
233.288
240.974
247.412
252.946
257.793
262.102
265.981
269.505
272.735
275.715
278.481
281.062
283.481
285.757
287.907
289.943
291.877
293.720
295.478
297.161
298.774
300.323
301.813
303.248
304.633
305.971
307.266
308.521
309.738
310.920
312.069
.313.188
314.280
315.345
316.386
317.404
318.402
319.381
320.342
321.287
322.218
323.135
324.041
324.935
325.820
326.696
327.565
328.427
329.283
330.134
330.980
331.823
332.663
333.500
334.336
335.169
336.001
Я°(П-Я°@)
кДж . моль"
2.909
5.863
8.932
8.992
12.307
15.754
19.286
22.876
26.507
30.166
33.847
37.545
41.257
44.980
48.713
52.454
56.202
59.956
63.717
67.483
71.254
75.030
78.811
82.596
86.386
90.180
93.979
97.783
101.591
105.405
109.224
113.050
116.883
120.724
124.575
128.436
132.310
136.197
140.100
144.021
147.962
151.926
155.915
159.933
163.981
168.063
172.182
176.342
180.545
184.794
189.094
193.446
197.855
202.322
206.851
211.445
216.106
220.837
225.640
230.516
235.467
Г°@) = 613.700 кДж • моль
-316.7106
-155.7354
-102.5889
-101.9201
-74.9511
-58.7404
-47.9171
-40.1763
-34.3642
-29.8390
-26.2154
-23.2480
-20.7731
-18.6772
-16.879t
-15.3198
-13.9541
-12.7482
-11.6753
-10.7146
-9.8493
-9.0657
-8.3527
-7.7011
-7.1032
-6.5527
-6.0440
-5.5726
-5.1344
-4.7259
-4.3444
-3.9871
-3.6517
-3.3364
-3.0392
-2.7588
-2.4937
-2.2426
-2.0045
-1.7784
-1.5634
-1.3587
-1.1635
-.9772
-.7993
-.6291
-.4662
-.3101
-.1605
-.0168
.1212
.2538
.3814
.5042
.6224
.7364
.8463
.9523
1.0547
1.1535
1.2490
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 468
7
ё
f i I
<N § *
vo s - Д
^ • II ЕЯ
3 о J S
40 и 2 °°-
? <*"* II
й ? 0 g
*Ч о
'н —
1350
:оль~
О *
+ 7
'* к <-* *
ОО ~ 2
о w S
S § ч/
1 ** ¦ *""
х + V
" 1 т"
«8 'о
+ ' 7
3 ? t"
II +
?
О
A
263

Класс точности
VII-
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1363
1363
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
Р
30.520
50.190
61.630
61.681
64.439
67.197
69.956
72.714
75.472
78.230
80.988
83.746
86.504
89.262
91.000
100.000
100.000
ЮО.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
ДИСУЛЬФИД
| Ф° (Г)
Дж • К ¦ моль
11.460
26.265
39.362
39.594
51.363
61.675
70.802
78.993
86.437
93.278
99.620
105.547
111.121
116.392
119.576
119.576
121.734
127.354
132.689
137.764
142.602
147.224
151.646
155.886
159.957
163.871
167.640
171.275
174.784
178.175
S°(T)
1
26.770
54.470
76.860
77.24!
95.364
110.039
122.535
133.525
143.415
152.464
160.849
168.697
176.102
183.135
187.400
199.872
202.551
209.450
215.904
221.966
227.682
233.089
238.218
243.097
247.749
252.195
256.450
260.533
264.455
268.229
КРЕМНИЯ SiS2
(к, ж)
Д #°@)= 293.000
Я°G>Я°<0)
кДж . моль
1.531
5.641
11.180
11.294
17.600
24.182
31.040
38.173
45.582
53.267
61.228
69.465
77.977
86.766
92.444
109.444
113.144
123.144
133.144
143.144
153.144
163.144
173.144
183.144
193.144
203.144
213.144
223.144
233.144
243.144
-144.5493
-67.5722
-42.2555
-41.9379
-29.1590
-21.5161
-16.4382
-12.8252
-10.1277
-8.0408
-6.3815
-5.0335
-3.9190
-2.9845
-2.4703
-2.4703
-2.2088
-i:5729
- .0249
-.5487
-.1319
.2351
.5603
.8497
1.1085
1.3409
1.5504
1.7398
1.9115
2.0678
кДж • моль"'
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1363
1363
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
с;
г*
II
5
X
гч
о
о
?
о
ГО
+
8348
(Ч
о
It
?
о
Т л
I а
"л
с
X
о
ос
1
и
о
§
Ъ4
н
О
О\
Г-
СП
Г-Н
б л и ц а
i
§
¦
X
О
о
о
оо
ГМ
1
II
я
00
сч
X
ГЧ
~* а^
о
id.
л 1
13бзк;
,68559*
V ?
V о
о
in О
—| О
298.
100.
¦ - +
2 S
II ГЧ
?
О
469
i
л
о
.
1
к
О\
It
о 5
«о
r0OK)
V
V
СП
чо
СП
'о
II
264

Класс точности
VI-I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
.6000
С°р(Т)
37.062
46.366
51.813
51.892
55.271
57.349
58.670
59.547
60.152
60.585
60.904
61.145
61.331
61.478
61.596
61.692
61.771
61.837
61.892
61.939
61.979
62.014
62.044
62.071
62.094
62.114
62.133
62.149
62.164
62.177
62.188
62.199
62.209
62.218
62.226
62.233
62.240
62.246
62.252
62.257
62.262
62.267
62.271
62.275
62.279
62.282
62.286
62.289
62.292
62.294
62.297
62.299
62.301
62.303
62.305
62.307
62.309
62.311
62.312
62.314
62.315
ДИСУЛЬФИД КРЕМНИЯ SiS
г (г)
K°(J)= p(Si)-p2(S)-p"'(SiS2) Д/.Я°@)=. 988.376 кДж • моль"
Ф°(Г)
— 1 -
Дж • К ¦ моль
174.112
197.618
213.121
213.375
225.625
235.757
244.432
252.030
258.795
264.894
270.448
275.546
280.259
284.640
288.733
292.574
296.192
299.612
302.854
305.936
308.872
311.677
314.361
316.934
319.405
321.782
324.072
326.281
328.414
330.477
332.473
334.408
336.284
338.106
339.876
341.597
343.272
344.903
346.493
348.043
349.555
351.032
352.474
353.884
355.263
356.612
357.932
359.225
360.492
361.733
362.950
364.144
365.316
366.466
367.595
368.704
369.793
370.864
371.917
372.952
373.971
5°(Г)
1
Я°(Г)-Я°@)
кДж • моль
205.571 3.146
234.436 7.364
254.050 12.203
254.371 12.299
269.802 17.671
282.377 23.310
292.958 29.116
302.072 35.029
310.066 41.016
317.177 47.054
323.578 53.129
329.394 59.232
334.723 65.357
339.638 71.497
344.198 77.651
348.452 83.816
352.436 89.989
356.183 96.170
359.719 102.356
363.066 108.548
366.244 114.744
369.269 120.944
372.155 127.146
374.913 133.352
377.556 139.561
380.091 145.771
382.527 151.983
384.872 158.197
387.133 164.413
389.315 170.630
391.423 176.848
393.462 183.068
395.437 189.288
397.351 195.509
399.209 201.732
401.013 207.955
402.766 214.178
404.471 220.403
406.132 226.628
407.748 232.853
409.325 239.079
410.862 245.305
412.363 251.532
413.828 257.760
415.260 263.987
416.660 270.215
418.028 276.444
419.368 282.672
420.679 288.902
421.964 295.131
423.222 301.360
424.456 307.590
425.666 313.820
426.852 320.050
428.017 326.281
429.161 332.511
430.283 338.742
431.386 344.973
432.470 351.204
433.535 357.436
434.582 363.667
Т
К
-506.7062 100
-247.2811 200
-161.6549 298. IS
-160.5778 300
-117.1455 400
-91.0515 500
-73.6387 600
-61.1918 700
-51.8515 800
-44.5834 900
-38.7668 1000
-34.0064 1100
-30.0383 1200
-26.6799 1300
-23.8007 1400
-21.3048 1500
-19.1205 1600
-17.1928 1700
-15.4790 1800
-13.9452 1900
-12.5645 2000
-11.3150 2100
-10.1788 2200
-9.1410 2300
-8.1895 2400
-7.3138 2500
-6.5052 2600
-5.7562 2700
-5.0604 2800
-4.4123 2900
-3.8072 3000
-3.2408 3100
-2.7096 3200
-2.2104 3300
-1.7403 3400
-1.2967 3500
-.8776 3600
-.4810 3700
-.1050 3800
.2519 3900
.5912 4000
.9141 4100
1.2219 4200
1.5155 4300
1.7959 4400
2.0641 4500
2.3208 . 4600
2.5667 4700
2.8025 4800
3.0288 4900
3.2462 5000
3.4553 5100
3.6564 5200
3.8501 5300
4.0367 5400
4.2167 5500
4.3903 5600
4.5580 5700
4.7200 5800
4.8766 5900
5.0281 6000
Таблица 470
1
i
с;
¦" О
с; • ' _д
* 2
К ГП -'
E-i ^Ч |
X О ^
с 3 1? i
ГЧ °° ^ r?j
Ss || U-i J?
|| о 2 2
^ u "
ел ct
СЛ ^ ° ^
О СЛ
S 0
 >-,
_+
1
к
о
о
ON |
л
° к
? k I
S ч °
° nH V
* i v
[— H • »•
- 1 ?o
g 3
о ""! ""
и +
о
©
265

Класс точности
II-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
sO(r)
29.106
29.268
30.169
30.192
31.553
32.820
33.834
34.610
35.202
35.660
36.022
36.320
36.578
36.814
37.044
36.612
37.523
37.785
38.066
38.368
38.688
39.015
39.373
39.732
40.097
40.464
40.830
41.191
41.545
41.889
42.221
42.540
42.843
43.131
43.402
43.657
43.896
44.117
44.323
44.514
44.690
44.852
45.001
45.137
45.262
45.376
45.480
45.575
45.661
45.740
45.812
45.877
45.937
45.991
46.040
46.084
46.125
46.161
46.194
46.223
46.249
НИТРИД КРЕМНИЯ SiN (г)
K°(T) = p(Si)-p(N).p~\SiN)
Ф G")
— 1 -
Дж • К . моль
155.601
175.763
187.412
187.593
196.070
202.748
208.299
213.072
217.272
221.028
224.430
227.541
230.409
233.071
235.555
237.884
240.078
242.151
244.118
245.989
247.774
249.481
251.117
252.689
254.202
255.661
257.069
258.432
259.752
261.032
262.274
263.482
264.658
265.802
266.918
268.007
269.069
270.108
271.123
272.115
273.087
274.039
274.971
275.885
276.781
277.660
278.523
279.370
280.203
281.020
281.824
282.614
283.391
284.155
284.907
285.647
286.376
287.093
287.800
288.496
289.183
S°(T)
1
184.675
204.873
216.701
216.888
225.758
232.939
239.016
244.293
248.955
253.128
256.905
260.353
263.524
266.461
269.198
271.762
274.092
276.458
278.625
280.692
282.668
284.563
286.387
288.145
289.843
291.488
293.082
294.630
296.134
297.598
299.024
300.413
301.769
303.092
304.383
305.645
306.878
308.084
309.263
310.417
311.547
312.652
313.735
314.795
315.834
316.853
317.851
318.830
319.791
320.733
321.658
322.566
323.457
324.333
325.193
326.038
326.869
327.685
328.489
329.279
330.056
Д/.Я°@)= 514.000
Н°(Г)-И°@)
кДж . моль
2.907
5.822
8.733
8.788
11.875
15.095
18.430
21.854
25.346
28.890
32.475
36.093
39.738
43.407
47.100
50.816
54.556
58.321
62.114
65.935
69.788
73.673
77.593
81.548
85.540
89.568
93.633
97.734
101.871
106.042
110.248
114.486
118.756
123.054
127.381
131.734
136.112
140.513
144.935
149.377
153.837
158.315
162.807
167.314
171.834
176.366
180.909
185.462
190.024
194.594
199.172
203.756
208.347
212.943
217.545
222.151
226.761
231.376
235.994
240.614
245.238
-264.9584
-130.0346
-85.4770
-84.9163
-62.2995
-48.7005
-39.6180
-33.1204
-28.2404
-24.4400
-21.3961
-18.9030
-16.8232
-15.0616
-13.5502
-12.2391
-11.0908
-10.0767
-9.1746
-8.3667
-7.6391
-6.9802
-6.3808
-5.8332
-5.3309
-4.8685
-4.4415
-4.0459
-3.6784
-3.3361
-3.0165
-2.7174
-2.4370
-2.1735
-1.9255
-1.6916
-1.4707
-1.2617
-1.0636
-.8758
-.6973
-.5275
-.3658
-.2116
-.0644
.0763
.2108
.3397
.4631
.5816
.6953
.8046
.9097
1.0108
1.1082
1.2021
1.2927
1.3801
1.4645
1.5461
1.6250
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
ПЛЛЛ
2оОО
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 471
•
Т
7 §
g • -
1 ! i
х ^ 7
S3 S *
я " 7 *
о о — ^
^ 7 Й ?!
" s » d
^ С <Ч к
" II
0 s_*
¦^ о
1)
1
Ч о
О ?
<* 7
2 й §
§ ? v
•g - V
JS i о
-л О
O-i ГО .*
VI ¦ Ч '
СО СЧ *"*
2 + к
(S чо ||
О1* «О
g 5ч S
СО -ч
II 1
с
0
266

Класс точности
V1-I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
!>
19.500
60.020
93.010
93.466
Hi.607
. 123.061
131.676
138.777
144.929
150.406
155.361
159.887
164.045
167.879
171.423
174.704
177.746
180.569
183.193
185.636
187.914
190.044
192.041
193.922
195.701
197.393
199.015
200.579
202.101
203.596
205.078
206.562
208.061
209.592
211.167
212.802
214.51
216.307
218.207
220.223
222.370
ТЕТРАНИТРИД ТРИКРЕМНИЯ Si3
A"GW(S.>y<
фО(Т-)
Дж • К • моль
3.601
12.678
25.438
25.690
39.700
53.689
67.126
79.866
91.903
103.281
114.056
124.286
134.023
143.314
152.201
160.720
168.902
176.775
184.364
191.690
198.772
205.626
212.270
218.715
224.974
231.059
236.980
242.745
248.364
253.845
259.194
264.418
269.525
274.518
279.405
284.191
288.879
293.475
297.983
302.407
306.751
N)
sV)
9.581
35.648
66.065
66.642
96.266
122.475
145.703
166.549
185.490
202.882
218.990
234.013
248.106
261.389
273.962
285.902
297.276
308.137
318.534
328.504
338.085
347.306
356.193
364.771
373.063
381.086
388.860
396.400
403.722
410.840
417.768
424.516
431.098
437.524
443.804
449.949
455.967
461.869
467.663
473.356
478.959
А,
//°m-//°(o
кДж . моль
.618
4.594
12.113
12.285
22.626
34.393
47.146
60.678
74.870
89.642
104.934
120.700
136.899
153.498
170.465
187.774
205.398
223.316
241.505
259.948
278.627
297.526
316.631
335.930
355.412
375.068
394.889
414.869
435.003
455.288
475.722
496.304
517.035
537.917
558.955
580.152
601.517
623.058
644.782
666.703
688.831
N4 (к)
Я°@)= 3993.
о
-2045.3043
-996.9179
-650.9086
-646.5560
-471.1008
-365.7280
-295.4365
-245.2091
-207.5312
-178.2251
-154.7829
-135.6071
-119.6328
-106.1219
-94.5473
-84.5222
-75.7562
-68.0273
-61.1628
-55.0263
-49.5085
-44.5211
-39.9917
-35.8605
-32.0778
-28.6016
-25.3966
-22.4326
• 19.6837
-17.1276
-14.7450
-12.5191
-10.4352
-8.4803
-6.6430
-4.9132
-3.2819
-1.7412
-.2838
1.0966
2.4059
197 кДж • моль
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
' 1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
Таблиц
'л
— О
1 2
Л
с;
О S
X О
ж °°
• i
?! ™ "
о и ^
"• о °°
И % г-)
5 * X
z ^
0 ^
S: г,
^ о
+
-
U-) о
00 *
+ 7
« s
О Н
rs О
о g
О -н
1 +
1 ?
98.87
-353.'
8 Й
1П О\
00* ОО
Г*- 00
(N ГО
fl +
0
е
а 472
1
А
о
.
1
о
гч
II
а
0 К
оэ
Q
о
о
V
V
298.1.
i
о
II
267

Класс точности
IV- F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3103
3103
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
С°р(Т)
4.180
16.230
26.777
26.965
34.192
38.370
41.243
43.412
45.138
46.551
47.724
48.705
49.526
50.213
50.787
51.265
51.662
51.994
52.275
52.518
52.736
52.941
53.147
53.365
53.607
53.887
54.215
54.604
55.065
55.612
56.255
57.006
57.030
63.000
63.000
•63.000
63.000
63,000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
КАРБИД КРЕМНИЯ SiC
К°(Т)= p(SiC)
Ф°(Г)
Дж < К ¦ моль
.364
2.369
5.581
5.649
9.517
13.542
17.506
21.320
24.958
28.414
31.698
34.818
37.788
40.619
43.321
45.905
48.380
50.753
53.033
55.226
57.338
59.374
61.340
63.239
65.078
66.858
68.585
70.261
71.889
73.473
75.015
76.519
76.563
76.563
78.623
80.679
82.670
84.600
86.473
88.292
90.060
91.779
93.454
95.085
96.675
98.225
99.739
101.217
102.662
104.074
105.455
106.806
108.130
109.426
110.696
111.941
113.161
114.359
115.534
116.688
117.821
S°(T)
1
1.414
7.954
16.485
16.651
25.512
33.625
40.888
47.416
53.330
58.730
63.697
68.293
72.568
76.560
80.303
83.823
87.145
90.287
93.267
96.100
98.800
101.378
103.845
106.213
108.489
110.683
112.802
114.856
116.849
118.791
120.687
122.543
122.599
143.546
145.485
147.424
149.305
151.131
152.906
154.632
156.312
157.948
159.543
161.099
162.617
164.099
165.548
166.964
168.348
169.703
171.029
172.328
173.601
174.849
176.072
177.272
178.450
179.606
180.741
181.856
182.952
Н°(Г)-Н'
(к, ж)
Д^Я°@) = 800.884
'@)
кДж . моль
.105
1.117
3.251
3.301
6.398
10.041
14.030
18.267
22.697
27.284
32.000
36.823
41.735
46.723
51.774
56.878
62.025
67.208
72.422
77.662
82.924
88.208
93.513
98.838
104.187
109.561
114.966
120.406
* ЛГ О 0f\
125.889
131.422
137.014
142.676
142.847
207.847
213.958
220.258
226.558
232.858
239.158
245.458
251.758
258.058
264.358
270.658
276.958
283.258
289.558
295.858
302.158
308.458
314.758
321.058
327.358
333.658
339.958
346.258
352.558
358.858
365.158
371.458
377.758
-410.2238
-200.1093
-130.8118
-129.9405
-94.8387
-73.7836
-59.7562
-49.7458
-42.2462
-36.4204
-31.7661
-27.9636
-24.7997
-22.1269
-19.8398
-17.8610
-16.1326
-14.6103
-13.2596
-12.0532
-10.9694
-9.9906
-9.1023
-8.2927
-7.5518
-6.8714
-6.2444
-5.6649
-5.1277
•4.6283
-4.1632
-3.7288
¦3.1469
-3.1469
-3.3556
-3.0070
-2.6799
-2.3723
-2.0826
-1.8093
-1.5511
-1.3068
-1.0754
-.8558
-.6472
-.4488
-.2600
-.0800
.0917
.2557
.4125
.5625
.7061
.8437
.9757
1.1024
1.2240
1.3410
1.4535
1.5618
1.6660
кДж • моль '
Т
К
100
200
298.15
300
400
500 .
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3103
3103
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
чо
о
II
+
7
1062
+
чэ
о
о
ч
?
с*
S
со
оо
«Л
»/¦)
со
го
ро
II
g
о
Та
§
¦
¦ч-
ОО
0.8
1
и
s
•У
о
ч.
<3
„
'л
§
2
—'
ы
5
-1
ГО
7*
с*
<3
00
о
(N
1
X
00
СП
+
б л и
'л
§
2
а
О
О
|
II
Я
оо'
О\
гч
X
СЛ
0
"* *t
ч
СП
о
СП
V
V
00
О\
(N
'о
II
н,
ца
§
2
—'
•
-
00
СП
_;
я
СП
о
S
it
о
473
'л
§
S
_'
'it!
п
СП
II
-
о
00
V
*"•
V
о
*""
о
II
268

Класс точности
V-F
Т
К
100
200
298.! 5
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
КАРБИД КРЕМНИЯ SiC (г)
К°(Т) = p(Si)-p(C)p~\SiC)
Ф°G)
5°G)
Дж - К . морь
30.990
30.008
31.031
31.057
32.505
33.727
34.662
35.389
35.989
36.520
37.015
37.490
37.952
38.402
38.839
39.259
39.660
40.040
40.396
40.728
41.035
41.316
41.574
41.807
42.018
42.207
42.376
42.527
42.661
42.780
42.884
42.976
43.057
43.127
43.188
43.242
43.288
43.327
43.361
43.389
43.413
43.431
43.445
43.454
43.459
43.459
43.455
43.446
43.432
43.414
43.390
43.361
43.326
43.286
43.240
43.188
43.130
43.066
42.996
42.920
42.837
160.871 192.966
182.810 213.961
195.184 226.100
195.375 226.292
204.292 235.426
211.281 242.817
217.070 249.052
222.033 254.452
226.389 259.218
230.278 263.488
233.796 267.361
237.011 270.912
239.974 274.194
242.725 277.249
245.295 280.112
247.707 282.805
249.980 285.352
252.133 287.768
254.177 290.067
256.124 292.260
257.984 294.357
259.764 296.366
261.472 298.294
263.113 300.147
264.694 301.931
266.218 303.650
267.690 305.309
269.113 306.911
270.490 308.460
271.826 309 959
273.121 311.412
274.379 312.819
275.602 314.185
276.791 315.511
277.949 316.799
279.077 318.052
280.177 319.271
281.249 320.457
282.296 321.613
283.319 322.740
284.319 323.839
285.296 324.911
286.251 325.958
287.186 326.980
288.102 327.979
289.000 328.956
289.878 329.911
290.740 330.846
291.585 331.760
292.414 332.655
293.228 333.532
294.027 334.391
294.811 335.233
295.581 336.058
296.339 336.866
297.083 337.659
297.814 338.437
298.534 339.200
299.241 339.948
299.937 340.683
300.622 341.403
АгИ°@)= 426.852
Н°(Т)-Н°{0)
кДж . моль
3.209 -219.6336
6.230 -107.4797
9.218 -70.4238
9.275 -69.9574
12.454 -51.1421
15 768 -39.8264
19.189 -32.2678
22.693 -26.8596
26.263 -22.7974
29.889 -19.6336
33.566 -17.0996
37.291 -15.0240
41.063 -13.2926
44.881 -11.8263
48.743 -10.5685
52.649 -9.4776
56.595 -8.5225
60.580 -7.6792
64.602 -6.9292
68.658 -6.2578
72.747 -5.6533
76.864 -5.1062
81.007 -4.6086
85.178 -4.1541
89.370 -3.7373
93.581 -3.3538
97.810 -2.9996
102.056 -2.6716
106.315 -2.3668
110.587 -2.0830
114.871 -1.8181
119.164 -1.5701
123.466 -1.3376
127.775 -1.1190
132.091 -.9133
136.412 -.7192
140.739 -.5358
145.070 -.3623
149.404 -.1978
153.742 -.0417
158.082 .1066
162.424 .2478
66.768 .3824
171.113 .5107
175.458 .6333
179.804 .7504
184.150 .8626
188.495 .9700
192.839 1.0730
197.181 1.1719
201.522 1.2668
205.859 1.3581
210.193 1.4459
214.524 1.5305
218.850 1.6120
223.172 1.6905
227.488 1.7663
231.797 1.8395
236.101 1.9103
240.396 1.9786
244.684 2.0448
кДж • моль"'
7
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
. 3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 474
7
7 1
Л
К 1, .4
о X г
k s *
? з -•
§ S 'а
2 § ¦- •
2; • || ^
С^ О *
о . m ,-*, Н"
/¦¦N Г-~ *V
5 Т « s
A Л , • «/>
?Г" оО
¦ г" ГЯ II
Ен * ^ II
За и °ъ*
л"' СО
О ^Д
4; о
+
7
2 ~*
S §
о S
+ _"
7 'а
ё • 2
1 Ъ v
н Т V
с о
н °
<^ Б v*
О О\ о
" Т *т
5 * II
II +
с
о
А
269

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
г
ДИКАРБИД КРЕМНИЯ SiC2
К°(Т) = р (Si)-р
Ф°(Г)
2(C)-p~'(SiC2)
S°(T)
Дж • К~ . моль"
40.710
44.950
47.560
47.607
49.980
52.047
53.792
55.225
56.384
57.315
58.066
58.677
59.182
59.611
59.988
60.338
60.678
61.028
61.402
61.812
62.268
62.779
63.349
63.981
64.678
65.439
66.261
67.141
68.074
69.053
70.070
71.118
72.187
73.268
74.350
75.424
76.480
77.509
78.501
79.449
80.346
81.186
81.963
82.673
83.314
83.883
84.379
84.803
85.156
85.439
85.653
85.803
85.891
85.921
85.896
85.821
85.700
85.536
85.334
85.098
84.831
165.575
190.721
206.627
206.881
218.991
228.777
237.044
244.234
250.616
256.364
261.600
266.412
270.868
275.017
278.902
282.555
286.003
289.268
292.370
295.325
298.147
300.849
303.441
305.933
308.334
310.650
312.888
315.056
317.157
319.197
321.181
323.112
324.994
326.830
328.624
330.377
332.093
333.774
335.421
337.037
338.623
340.180
341.711
343.216
344.696
346.152
347.586
348.997
350.387
351.757
35Э.107
354.438
355.749
357.043
358.318
359.576
360.817
362.042
363.249
364.442
365.6 J 8
199.500
229.291
247.734
248.028
262.056
273.437
283.085
291.489
298.941
305.638
311.717
317.281
322.409
327.163
331.595
335.746
339.651
343.340
346.839
350.169
353.351
356.401
359.335
362.164
364.902
367.557
370.140
372.657
375.115
377.521
379.879
382.194
384.468
386.706
388.910
391.080
393.220
395.329
397.410
399.461
401.484
403.478
405.444
407.381
409.289
411.168
413.017
414.837
416.626
418.385
420.113
421.811
423.478
425.115
426.721
428.296
429.841
431.357
432.843
434.300
435.728
H°(T)-H°(Q)
кДж ¦ моль
3.393
7.714
12.256
12.344
17.226
22.330
27.625
33.078
38.660
44.347
50.117
55.956
61.849
67.790
73.770
79.786
85.837
91.922
98.043
104.204
110.407
116.659
122.965
129.331
135.764
142.269
148.853
155.523
1 ? Л ЛАП
162.283
169.139
176.095
183.154
190.319
197.592
204.973
212.462
220.057
227.757
235.558
243.456
251.446
259.523
267.681
275.913
284.213
292.573
300.987
309.447
317.945
326.476
335.031
343.604
352.190
360.781
369.372
377.958
386.535
395.097
403.640
412.162
420.659
(г)
г°@)= 1248.037
1е.К°(Т)
-643.0062
-315.7157
-207.7800
-206.4227
-151.7024
-118.8347
-96.9037
-81.*2274
-69.4631
-60.3086
-52.9819
-46.9852
-41.9865
¦37.7555
-34.1282
-30.9837
-28.2318
-25.8032
-23.6440
-21.7118
-19.9726
-18.3988
-16.9680
-15.6615
-14.4638
-13.3620
-12.3449
-11.4033
-10.5290
-9.7152
-8.9559
-8.2457
-7.5802
-6.9553
-6.3675
-5.8136
-5.2908
-4.7966
•4.3289
-3.8855
-3.4646
-3.0647
-2.6842
-2.3219
-1.9764
-1.6466
-1.3316
-1.0303
-.7420
-.4659
-.20 П
.0529
.2969
.5313
.7567
.9736
1.1825
1.3838
1.5779
1.7652
1.9460
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица
i
в
о
о
i §.
и S
ы
С/Э
о
1
7
«S 7
00 j3
2 i
«ч -.'
+ v^
¦> &
s ^
О ¦—t
4 '
•* |2
О X
00 00
II 1
о
©
оль"
2
*
m
с?*
<s
II
я
«о
оо
с
я
0
*"t
<t
475
чио
S
-¦
1
Ч
II
oS
05
Я
О
VO
V
V
8
чг
'о
(^
и
270

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
36.875
44.813
49.011
49.074
51.996
54.198
55.870
57.135
58.095
58.832
59.407
59.867
60.252
60.591
60.914
61.242
61.596
61.993
62.443
62.958
63.542
64.199
64.929
65.731
66.600
67.531
68.516
69.547
70.615
71.708
72.816
73.928
75.031
76.115
77.170
78.185
79.152
80.062
80.909
81.688
82.394
83.024
83.577
84.052
84.449
84.771
85.019
85.196
85.306
85.353
85.340
85.273
85.156
84.993
84.790
84.550
84.277
83.977
83.652-
83.306
82.943
К°(Т) = p2(Si)
Ф°(Г)
Дж • К~ . моль
167.904
191.292
206.516
206.763
218.64!
228.387
236.700
243.972
250.449
256.295
261.627
266.530
271.070
275.298
279.255
282.975
286.486
289.810
292.967
295.975
298.847
301.598
304.237
306.776
309.221
311.582
313.866
316.078
318.224
320.309
322.337
324.313
326.240
328.121
329.960
331.758
333.518
335.243
336.933
338.592
340.220
341.819
343.390
344.934
346.452
347.946
349.416
350.862
352.286
353.688
355.069
356.429
357.769
359.089
360.390
361.672
362.936
364.183
365.411
366.622
367.817
КАРБИД ДИКРЕМНИЯ Si2C
p(C)-p(Si2C)
S°(T)
-1
199.336
227.685
246.425
246.728
261.267
273.118
283.154
291.866
299.560
306.448
312.677
318.361
323.588
328.424-
332.926
337.140
341.103
344.849
348.405
351.795
355.039
358.154
361.157
364.061
366.877
369.614
372.282
374.887
377.435
379.932
382.382
384.788
387.152
389.478
391.766
394.017
396.234
398.415
400.561
402.673
404.751
406.793
408.800
410.773
412.710
414.611
416.477
418.308
420.103
421.862
423.587
425.276
426.931
428.551
430.138
431.692
433.213
434.702
436.160
437.587
438.984
Д,яс
Я°(Г)-Я°@)
кДж . моль"
3.143
7.279
11.899
11.990
17.051
22.365
27.872
33.526
39.289
45.137
51.050
57.015
63.021
69.064
75.139
81.247
87.388
93.567
99.789
106.058
112.382
118.769
125.225
131.757
138.373
145.079
151.881
158.784
165.792
172.908
180.134
187.471
194.919
202.476
210.141
217.909
225.776
233.738
241.787
249.917
258.122
266.393
274.724
283.106
291.532
299.994
308.484
316.995
325.521
334.054
342.589
351.120
359.642
368.150
376.640
385.107
393.548
401.961
410.343
418.691
427.004
(Г)
@)= 1062.519
0
-546.1126
-267.0344
-174.9344
-173.7760
-127.0723
-99.0176
-80.2980
-66.9177
-56.8770
-49.0641
-42.8115
-37.6942
-33.4286
-29.8183
-26.7232
-24.0401
-21.6920
-19.6197
-17.7774
-16.1287
-14.6447
-13.3019
-12.0810
-10.9663
-9.9445
-9.0045
-8.1369
-7.3337
-6.5882
-5.8942
-5.2468
-4.6415
-4.0744
-3.5420
-3.0413
-2.5696
-2.1246
-1.7040
-1.3060
-.9289
-.5711
-.2311
.0922
.4001
.6935
.9735
1.2409
1.4965
1.7411
1.9754
2.1999
2.4154
2.6222
2.8208
3.0119
3.1957
3.3727
3.5432
3.7077
3.8663
4.0194
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
>
1 2
О S
s i
к "о
ЕЗ —<
520
О.ООС
= 54
=-35 ?
II о °°
1§ С <ч
и с
й Ч,
о -Ci
5; q
1
1—1 »**
+ '^
i *
К ас
о 2
О ел
« !
оо *-*
Я а!
°* VO
оо х
СО О
^* О>
II I
?
0
©
а 476
_
'л
q
О
•
о
40
II
Я
О
о
VD
V
V
g
...
то
и
а,
271

Класс точности
YI-Г
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1210.4
1210.4
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
)
К°(Т)= p(Ge)
Ф°(Г)
ГЕРМАНИЙ Ge (к, ж)
V
S°(T)
Дж К .моль
13.820
21.130"
23.222
23.249
24.310
24.962
25.452
25.867
26.240
26.591
26.926
27.252
27.571
27.604
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
27.600
3.666
10.000
15.541
15.637
20.427
24.526
28.096
31.254
34.085
36.653
39.003
41.171
43.185
43.386
43.386
47.173
50.971
54.395
57.505
60.351
62.971
65.396
67.651
69.757
71.732
73.589
75.342
77.000
78.573
80.069
81.495
82.856
84.159
85.407
86.604
87.756
88.864
89.932
90.963
Я°(П-Я°@)
кДж . моль
9.866 .620
22.175 2.435
31.090 4.636
31.234 4.679
38.083 7.062
43.582 9.528
48.178 12.050
52.133 14.616
55.612 17.222
58.723 19.863
61.542 22.539
64.124 25.248
66.509 27.989
66.747 28.276
97.340 65.306
99.311 67.779
01.357 70.539
03.261 73.299
05.042 76.059
06.715 78.819
08.293 81.579
09.785 84.339
11.201 87.099
12.547 89.859
13.831 92.619
15.058 95.379
16.233 98.139
17.360 100.899
18.442 103.659
19.484 106.419
20.487 109.179
21.456 111.939
22.392 114.699
23.297 117.459
24.173 120.219
25.022 122.979
25.846 125.739
26.646 128.499
27.424 131.259
91.959 128.180 134.019
92.921 1
93.854 1
28.916 136.779
29.633 139.539
94.757 130.332 142.299
95.633 1
31.013 145.059
96.483 131.678 147.819
97.309 132.328 150.579
98.112 132.962 153.339
98.894 133.583 156.099
99.655 134.189 158.859
100.396 134.783 161.619
101.118 135.364 164.379
101.823 135.933 167.139
¦
Г°@}= 369.037
-186.7536
-89.9281
¦57.9962
-57.5945
-41.3957
-31.6586
-25.1576
-20.5093
-17.0209
-14.3071
-12.1363
-10.3609
-8.8824
-8.7428
-8.7428
-7.7426
-6.7786
-5.9441
-5.2148
-4.5721
-4.0016
-3.4918
-3.0337
-2.6197
-2.243b
-1.901 1
-1.5874
-1.2992
¦1.0335
-.7877
-.5599
-.3480
-.1505
.0340
.2068
.3689
.5212
.6647
.8000
.9278
.0488
.1634
.2722
.3755
.4737
.5673
.6565
.7416
.8229
1.9006
1.9751
2.0463
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1 100
1200
1210.4
1210.4
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
Таблице 477
i
!
S - -
w М ^
"*. 0
+
pi о
о г
О ^
я з -~ ^
О ™' 3"- т-f
о _ V х \/
о | , ~: , ¦
I I f- ^ ^
х | V . V
С] *Ч
— —" "^ -S ¦**
чО Т "*ч """ О
^ у со ^ -
~ 3^. г- г-1
5 з *"-" ¦"
ЧО го *""* О "**
х- ^ fcl » k.
as " ^ г-1 ^
ос —< и —< и
., + -л „ а
272

Класс точности
I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
21.314
27.485
30.733
30.757
31.071
30.361
29.266
28.102
27.029
26.108
25.349
24.741
24.264
23.898
23.624
23.426
23.287
23.197
23.143
23.117
23.112
23.123
23.143
23.171
23.201
23.234
23.266
23.297
23.326
23.351
23.374
23.393
23.408
23.420
23.428
23.433
23.435
23.434
23.430
23.424
23.416
23.405
23.393
23.379,
23.363
23.347
23.329
23.311
23.292
23.272
23.253
23.233
23.213
23.194
23.175
23.157
23.140
23.124
23.109
23.095
23.084
Ф°(Т)
Дж ¦ К ¦ моль
118.698
133.540
142.978
143.132
150.512
156.507
161.523
165.806
169.523
172.790
175.695
178.303
180.664
182.818
184.796
186.622
188.318
189.900
191.382
192.776
194.091
195.336
196.518
197.643
198.716
199.742
200.725
201.668
202.575
203.448
204.289
205.102
205.887
206.647
207.383
208.096
208.789
209.461
210.115
210.752
211.371
211.975
212.563
213.137
213.697
214.244
214.779
215.301
215.813
216.313
216.803
217.282
217.752
218.213
218.664
219.108
219.542
219.969
220.388
220.800
221.204
ГЕРМАНИЙ Ge (г)
S°{T)
1
139,550
156.064
167.792
167.983
176.912
183.780
189.222
193.646
197.327
200.455
203.165
205.552
207.683
209.610
2U.371
212.993
214.501
215.909
217.234
218,484
219.670
220.798
221.874
222.903
223.890
224.838
225.749
226.628
227.476
228.295
229.087
229.854
230.596
231.317
232.016
232.696
233.356
233.998
234.623
235.231
235.824
236.402
236.966
237.516
238.054
238.579
239.092
239.593
240.084
240.564
241.034
241.494
241.945
242.387
242.820
243.245
243.662
244.072
244.474
244.869
245.257
tf°GV//°@)
кДж ¦ моль
Т
к
2.085 — 100
4.505 — 200
7.398 — 298.15
7.455 — 300
10.560 — 400
13.637 — 500
16.620 — 600
Таблица 478
I
с;
« о
f * 'ц
Г Su S
19.488 — 700 ! й о
22.243 — 800
24.899 — 900
27.470 — 1000
29.973 — П 00
32.423 — 1200
34.830 — 1300
37.205 — 1400
39.557 — 1500
41.892 — 1600
44.216 — 1700
46.533 — !800
48.846 — '900
51.157 — 2000 •
53.469 — 2! 00
55.782 — 2200
58.098 — 2300
60.416 — 2400
62.738 — 2500
65.063 — 2600
67.391 — 2700
69.722 — 2800
72.056 — 2900
74.392 — 3000
76.731 — 3100
79.07! — 3200
81.412 — 3300
83.755 — 3400
86.098 — 3500
88.441 — 3600
90.785 — 3700
93.128 — 3800
95.471 — 3900
97.813 — 4000
100.154 — 4100
102.494 — 4200
104.832 — 4300
107Л69 — 4400
109.505 — 4500
111.839 — 4600
114.171 — 4700
116.501 — 4800
118.829 — 4900
121.155 — 5000
123.480 — 5100
125.802 — 5200
128.122 — 5300
130.441 — 5400
132.758 — 5500
135.072 — 5600
137.386 — 5700
139.697 , — 5800
142.007 — 5900
144.316 — 6000
И 1
г- ??
О - Л
" г~ ""• rt
5 ° ON
а; о"
1
ч
к 'а
•Л о
о 2
1 •
<ч 1
? Ч о
2 тх ^°
о °
+ S ^"
* 1 V
о о
in со *о
+ + т
?о ч &-
2 _ и
II 1
0
273

ГЕРМАНИЙ Ge (г)
Таблица 478
(окончание)
т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
с; m
23.065
23.056
23.056
23.068
23.093
23.132
23.18*
23.260
23.350
2?.459
23.588
23.737
23.908
24.101
24.315
24.55!
24.809
25.089
25.390
25.712
Ф°(Л
— 1
Дж ¦ К - моль
221.992
222.754
223.492
224.207
224.901
225.574
226.228
226.865
227.484
228.087
228.676
229.250
229.810
230.358
230.893
231.417
231.930
232.432
232.925
233.408
246.013
246.746
247.455
248.143
248.812
249.464
250.098
250.717
251.323
251.915
252.496
253.066
253.627
254.178
254.722
255.259
255.790
256.315
256.836
257.352
Н°(Т)-1/°@)
кДж . моль
148.931
153.543
158.154
162.766
167.382
172.004
176.636
181.280
185.941
190.622
195.326
200.058
204.822
209.623
214.464
219.350
224.286
229.275
234.323
239.433
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9900
9200
9400
9600
9800
10000
о"
+
X
О
ЧО
0.0
1
X
с
rN
On
ЧО
«О
ш
о
1
ы
- 0.25^
1
VD
о
с
100
V
к.
V
о
g
о
•е-
274

Класс
I
7
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
очности
А
21.025
21.035
21.943
23.381
24.859
26.021
26.748
27.076
27.100
26.920
26.618
26.254
25.866
25.480
25.109
24.761
24.441
24.147
23.880
23.638
23.420
23.222
23.043
22.881
22.735
22.602
22.481
22.371
22.271
22.179
22.095
22.018
21.948
21.883
21.823
21.768
21.717
21.669
21.625
21.585
21.547
21.511
21.478
21.447
21.419
21.392
21.366
21.343
21.320
21.300
21.280
21.262
21.245
21.229
21.214
21.200
21.187
21.175
21.164
ПОЛОЖИТЕЛЬНЫЙ ИОН ГЕРМАНИЯ Ge+ (г)
А°G) = /?(Ge)-
Ф°(Г)
— 1 -
Дж ¦ К . моль
147.163
147.292
153.297
158.009
161.933
165.329
168.341
171.056
173.529
175.799
177.894
179.839
181.649
183.342
184.929
186.423
187.831
189.162
190.424
191.622
192.763
193.851
194.891
195.885
196.838
197.753
1 Л\ А ^ *^ f\
198.633
199.480
200.296
201.083
201.843
202.579
203.290
203.980
204.648
205.297
205.927
206.539
207.135
207.715
208.280
208.830
209.367
209.891
210.402
210.901
211.390
211.867
212.334
212.791
213.238
213.677
214.106
214.527
214.940
215.345
215.743
216.133 '
216.516
р '(c)/j '(Ge+
1
167.977
168.107
1 74.266
179.31 1
183.708
187.632
191.159
194.332
197.188
199.764
202.094
204.210
206.142
207.913
209.546
211.057
212.463
213.777
215.008
216.168
217.262
218.299
219.283
220.221
221.115
221.971
222.790
223.577
224.334
225.063
22J5.765
226.444
227.100
227.736
228.351
228.948
229.528
230.092
230.640
231.173
231.693
232.200
232.694
233.176
233.647
234.108
234.558
234.998
235.429
235.851
236.264
236.669
237.067
237.456
237.839
238.214
238.583
238.945
239.301
) Дг//°@)= -762.180
//°(П-//°@)
кДж - моль
6.206
6.245
8.387
10.651
13.065
15.612
18.254
20.948
23.659
26.362
29.039
31.683
34.289
36.856
39.386
41.879
44.339
46.768
40.169
51.545
53.898
56.229
58.543
60.839
63.119
65.386
67.640
69.883
• 72.115
74.337
76.551
78.756
80.955
83.146
85.331
87.511
89.685
91.854
94.019
96.179
98.336
100.489
102.638
104.785
106.928
109.068
111.206
113.342
115.475
117.606
119.735
121.862
123.987
126.111
128.233
130.354
132.473
134.591
136.708
133.3062
132.4773
99.0604
78.9793
65.5678
55.9678
48.7504
43.1220
38.6067
34,9016
31.8050
29.1770
26.9178
24.9540
23.2308
21.7060
20.3468
19.1272
18.0267
17.0282
16.1181
15.2850
14.5194
13.8131
13.1596
12.5530
11.9883
11.4613
10.9682
10.5058
10.0713
9.6622
9.2762
8.9115
8.5662
8.2388
7.9279
7.6323
7.3509
7.0825
6.8264
6.5817
6.3475
6.1233
5.9083
5.7020
5.5039
5.3134
5.1302
4.9537
4.7837
4.6197
4.4615
4.3087
4.1610
4.0182
3.8800
3.7462
3.6166
кДж • моль
Т '
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а
о
¦
X
„^
as —<
GO еъ
г- 1!
О
о
<
1
1
ё ¦
fN
ГО
б л и
о
S
СО
об
ГО
II
1
С")
w
О
ч.
о
f
+ —
00
го f
р
О
1
J3
\О
го
оо
оо*
00
и
о
А
a:
?
о
г^
'
я
<п
•¦о
JC?
1
ц а 479
л
о
1
i
«о
гп
II
Ц
о к
|
V
*¦*
V
о
о
t"
'о
II
-is
275

ПОЛОЖИТЕЛЬНЫЙ ИОН ГЕРМАНИЯ Ge+ (г)
Таблица 479
(окончание)
Ф°(Т)
S°(T)
к
Дж . К
Н°(Т)-Н°@)
кДж . моль
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
21.145
21.129
21.118
21.109
21.105
21.104
21.107
21.115
21.127
21.144
21.165
21.192
21.224
21.261
21.304
21.352
21.407
21.467
21.534
21.607
217.262
217.983
218.680
219.355
220.010
220.644
221.260
221.859
222.441
223.008
223.560
224.098
224.623
225.135
225.635
226.124
226.601
227.068
227.526
227.974
239.994
240.665
241.315
241.946
242.557
243.152
243.730
244.293
244.842
245.377
245.899
246.410
246.909
247.397
247.875
248.344
248.804
249.255
249.698
250.134
140.939
145.167
149.391
153.614
157.835
162.056
166.277
170.499
174.723
178.950
183.181
187.417
191.658
195.907
200.163
204.428
208.704
212.992
217.292
221.606
3.3692
3.1362
2.9164
2.7087
2.5120
2.3254
2.1482
1.9796
1.8191
1.6659
1.5196
1.3797
1.2458
1.1175
.9944
.8762
.7626
.6534
.5482
.4469
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
о
н
В
о
00
g
о
¦е-
о
о
I.
те
v
V
о
о
о
276

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
ДИГЕРМАНИЙ Ge2 (г)
К {Т) = р (Ge) • р (Ge2)
Ф°(Г)
S°(T)
Дж • К . моль
32J599
45.557
48.681
48.664
46.715
44.734
43.316
42.318
41.597
41.065
40.665
40.363
40.134
39.963
39.836
39.746
39.686
39.650
39.636
39.641
39.662
39.696
39.743
39.800
39.866
39.938
40.015
40.094
40.174
40.251
40.325
40.393
40.452
40.501
40.539
40.563
40.574
40.568
40.547
40.509
40.455
40.383
40.295
40.190
40.070
39.934
39.784
39.620
39.443
39.254
39.054
38.844
38.626
38.399
38.165
37.925
37.680
37.430
37.177
36.921
36.663
177.947 207.849
199.952 234.553
214.662 253.657
214.904 253.958
226.482 267.718
235.794 277.919
243.508 285.942
250.055 292.540
255.724 298.141
260.714 303.008
265.163 307.313
269.173 311.174
272.821 314.676
276.166 317.881
279.252 320.838
282.117 323.583
284.790 326.146
287.294 328.551
289.650 330.817
291.873 332.960
293.979 334.994
295.978 336.930
297.882 338.777
299.699 340.545
301.436 342.240
303.101 343.869
304.700 345.437
306.237 346.949
307.717 348.408
309.144 349.820
310.523 351.185
311.856 352.509
313.147 353.792
314.398 355.037
315.611 356.247
316.789 357.423
317.933 358.566
319.047 359.677
320.130 360.759
321.185 361.812
322.214 362.837
323.217 363.835
324.196 364.807
325.151 365.754
326.085 366.676
326.996 367.575
327.888 368.451
328.760 369.305
329.614 370.138
330.449 370.949
331.267 371.740
332.068 372.511
332.853 373.263
333.623 373.997
334.377 374.713
335.117 375.411
335.842 376.092
336.554 376.756 .
337.25" 377.405
337.93» 378.039
338.612 378.657
А Я°@)= 257.000
Я°(Л-Я°@)
. кДж • моль
2.990 -131.1360
6.920 -63.6142
11.626 -41.3008
11.716 -41.0197
16.495 -29.6666
21.062 -22.8147
25.461 -18.2189
29.740 14.9173
33.934 -12.4280
38.065 -10.4828
42.151 -8.9201
46.202 -7.6368
50.226 -6.5637
54.230 -5.6529
58.220 -4.8699
62.199 -4.1895
66.170 -3.5926
70.137 -3.0646
74.101 -2.5941
78.065 -2.1721
82.030 -1.7915
85.997 -1.4462
89.967 -1.1316
93.946 -.8437
97.930 -.5791
101.920 -.3352
105.917 -.1095
109.923 .1000
113.936 .2950
117.957 .4769
121.986 .6471
126.022 .8067
130.064 .9566
134.112
138.164
142.220
146.277
150.334
154.390
158.443
162.491
.0978
.2310
.3568
.4759
.5888
.6960
.7979
.8949
166.533 1.9875
170.567 2.0757
174.591 2.1601
178.604 2.2409
182.604 2.3182
186.590 2.3923
190.561 2.4634
194.514 2.5318
198.449 2.5975
202.364 2.6607
206.259 2.7216
210.132 2.7803
213.984 2.8369
217.812 2.8916
221.616 2.9445
225.396 2.9956
229.152 3.0450
232.882 3.0929
236.587 3.1393
240.266 3.1843
кДж • моль"'
T
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 480
'л
§
7 2
ё i >л
S Ч о
S °°
¦* аз
» ч I j|
? 3 « 3
J ;¦ « я
11 Q 00 ?
^ .- <N
о о> о ts
О *> Со
?-¦ о
о ^
5; ' о
< aU
1
'ч
2 "
т. о
1 _•
н . ^
S « §
1 пё *
+ 5 *¦*
«7 v
s
m н ">
г- О ,.'"
§ -2 'о
+ сч —•
V + с"
S Й »
m "? ~
SO tn
ГО i"H
II 1
0
277

Класс точности
П-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;(г)
29.106
29.475
30.809
30.838
32.392
33.645
34.567
35.236
35.729
36.101
36.387
36.614
36.797
36.949
37.076
37.186
37.281
37.366
37.441
37.510
37.574
37.633
37.688
37.741
37.792
37.841
37.890
37.939
37.988
38.040
38.094
38.151
38.213
38.282
38.358
38.443
38.538
38.646
38.767
38.903
39.056
39.227
39.418
39.631
39.866
40.125
40.408
40.717
41.053
41.416
41.806
42.224
42.669
43.143
43.643
44.169
44.721
45.298
45.899
46.522
47.165
ОКСИД ГЕРМАНИЯ GeO (г]
К°(Т) = р (Ge) • р (О) ¦ р~'(GeO)
Ф°(Г)
Дж ¦ К • моль
162.466
182.637
194.323
194.505
203.052
209.813
215.447
220.298
224.566
228.384
231.839
234.998
237.908
240.606
243.122
245.479
247.697
249.791
251.774
253.658
255.453
257.166
258.805
260.375
261.884
263.334
264.732
266.080
ллн л а 1
267.381
268.640
269.859
271.040
272.185
273.297
274.378
275.430
276.454
277.451
278.423
279.371
280.297
281.202
282.086
282.952
283.798
284.627
285.440
286.236
287.018
287.785
288.539
289.279
290.006
290.722
291.426
292.119
292.802
293.475
294.139
294.793
295.439
S°(T)
1
191.549
211.784
223.779
223.970
233.059
240.428
246.648
252.029
256.768
260.999
264.818
268.297
271.491
274.443
277.186
279.748
282.151
284.413
286.551
288.577
290.503
292.338
294.090
295.766
297.373
298.917
300.403
301.833
Л ft ft ' Л ¦' J
303.214
304.548
305.839
307.088
308.301
309.477
310.621
311.735
312.819
313.876
314.908
315.917
316.904
317.871
318.818
319.748
320.662
321.560
322.445
323.318
324.178
325.028
325.869
326.701
327.525
328.342
329.153
329.959
330.760
331.557
332.350
333.139
333.927
Д/.Я°@)= 653.320 кДж-моль
Я°(Л-Я°@)
кДж • моль
2.908
5.829
8.782
8.839
12.003
15.307
18.720
22.212
25.762
29.354
32.979
36.630
40.300
43.988
47.689
51.403
55.126
58.859
62.599
66.347
70.101
73.861
77.627
81.399
85.175
88.957
92.744
96.535
i ^\ Л rt Л Л
100.332
104.133
107.940
111.752
115.570
119.395
123.227
127.067
130.915
134.775
138.645
142.528
146.426
150.340
154.272
158.225
162.199
166.199
170.225
174.281
178.369
182.492
186.653
190.855
195.099
199.389
203.728
208.119
212.563
217.064
221.624
226.245
230.929
о
-337.5981
-166.4355
-109.9106
-109.1990
-80.4847
-63.2028
-51.6499
-43.3780
-37.1609
-32.3165
-28.4346
-25.2537
-22.5994
-20.3506
-18.4209
-16.7466
-15.2801
-13.9847
-12.8322
-11.8000
-10.8701
-10.0280
-9.2617
-8.5614
-7.9189
-7.3272
-6.7805
-6.2739
-5.8030
-5.3642
-4.9543
-4.5705
-4.2103
-3.8717
-3.5527
-3.2516
-2.9671
-2.6976
-2.4422
-2.1996
-1.9689
-1.7494
-1.5401
-1.3404
-1.1496
-.9672
-.7926
-.6253
-.4649
-.3109
-.1631
-.0209
.1158
.2474
.3742
.4964
.6143
.7280
.8378
.9439
1.0464
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600 .
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 481
i
о
А
? 1 '|
% «о ?
* 5 т
© ? и
О |
°^ • II S
1/5 7 ? 2
ОО 1 им ^О
°° " 2 ?
II Q об ^
и- - II
55- % ч
о •?,
а; о
+
~н
ft? R
О
о .
н ^-*
О- 5? ?й
s ^ 1
Or- "*
О On W
О чо *
н 7 V
5 мх °
S Я 2
+ i
о 2 ~
ел
II +
о
о
278

Класс точности
VI-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1308
1308
1388
1388
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
сЦт)
13.710
35.740
50.166
50.475
61.281
66.273
69.089
70.974
72.449
73.764
75.049
76.378
77.796
79.332
79.460
80.075
81.297
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
78.500
Ф°
Ф°
*V) = P(Ge
Ф°(Г)
ДИОКСИД ГЕРМАНИЯ GeO
о2)
S°(T)
Дж • К . моль
1.598
7.732
15.460
15.611
23.775
31.731
39.249
46.269
52.804
58.895
64.589
69.931
74.962
79.718
80.087
80.087
84.650
84.650
85.418
91.552
97.246
102.560
107.539
112.224
116.647
120.836
124.814
128.602
132.216
135.671
138.982
142.159
145.214
148.154
150.988
153.724
156.369
158.927
161.405
163.807
166.138
168.402
170.603
172.743
(Г) = 225.8666
- 50.395* +
(* = Г-1(Г4
(Т) = ,202.1698
- 0.58589*"
(* = Г-10~4
5.874
22.502
39.710
40.021
56.248
70.519
82.872
93.671
103.247
111.857
119.696
126.910
133.616
139.903
140.390
156.827
161.617
174.009
174.684
180.100
185.167
189.926
194.413
198.657
202.683
206.513
210.165
213.655
216.996
220.200
223.279
226.242
229.096
231.851
234.512
237.086
239.579
241.994
244.338
246.613
248.825
250.976
253.069
255.108
+ 78.195 In* -
153.833*2 Дж
; 298.15 < Г
+ 62.208 In* -
'' +71.15* Дж
; 1308 < Г <
2 (К, Ж)
Aj#°@)= 470.000 кДж • моль"
Я°(Г)-Я°@)
кДж . моль"
.428
2.954
7.230
7.323
12.989
19.394
26.173
33.182
40.355
47.666
55.107
62.677
70.385
78.240
78.876
100.376
106.830
124.030
124.972
132.822
140.672
148.522
156.372
164.222
172.072
179.922
187.772
195.622
203.472
211.322
219.172
227.022
234.872
242.722
250.572
258.422
266.272
274.122
281.972
289.822
297.672
305.522
313.372
321.222
-236.8741
-113.2816
-72.5253
-72.0132
-51.3920
-39.0448
-30.8345
-24.9864
-20.6129
-17.2216
-14.5170
-12.3115
-10.4800
-8.9361
-8.8230
-8.8230
¦7.8154
-7.8154
-7.6801
-6.6387
-5.7313
-4.9340
-4.2281
-3.5992
-3.0355
-2.5276
-2.0677
-1.6496
-1.2679
-.9182
-.5967
-.3002
-.0261
.2281
.4643
.6843
.8898
1.0820
1.2621
1.4312
1.5902
1.7400
1.8813
2.0147
0.011487* + 2.34229*"' -
•К-моль
< 13О8К)
0.0063825* -
•К"'моль
1388К)
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1308
1308
1388
1388
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
Табл и
1
'а
— о
1 5
й •
о К
• Ж
.М °
и ^
sU <~»
<м о
• !
<^ Г^ "
СО ^* ,—ч
Я " 2
о *"
"н g> ОО
г* *
% о
О <ц
Г о
§
2
а
i СУ
я 1
о «*>
2 v
1 Г
Г8.5 In* -
[388 < 1
+ .-
О ^
II •"
о
на 482
'й
о
к
оо
•""'
11
1?
279

Класс точности
V-F
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
СЦТ)
A'°(D=p(Ge)
Ф°(Г)
ДИОКСИД ГЕРМАНИЯ GeO2
•p2@)-p~!(Ge02) ArHc
S°(T)
Дж • К . моль
34.085
41.977
47.058
47.143
51.132
53.994
55.994
57.400
58.409
59.149
59.706
60.132
60.466
60.731
60.945
61.119
61.264
61.385
61.487
61.574
61.649
61.713
61.770
61.819
61.862
61.900
61.934
61.965
61.992
62.017
62.039
62.059
62.077
62.094
62.109
62.123
62.136
62.147
62.158
62.168
62.178
62.186
62.194
62.202
62.209
62.215
62.221
62.227
62.253
62.238
62.242
62.247
62.251
62.255
62.259
62.262
62.266
62.269
62.272
62.275
62.278
166.720
188.994
203.375
203.609
214.891
224.232
232.266
239.341
245.676
'251.415
256.665
261.504
265.992
270.178
274.100
277.789
281.272
284.571
287.704
290.687
293.533
296.256
298.864
301.368
303.776
306.093
308.328
310.485
312.571
314.589
316.544
318.439
320.278
322.065
323.802
325.492
327.137
328.740
330.303
331.828
333.316
334.770
336.190
337.579
338.938
340.267
341.569
342.845
344.094
345.320
346.521
347.700
348.857
349.993
351.109
352.204
353.282
354.340
355.382
Э56.406
357.413
197.034
223.387
241.134
241.425
255.562
267.298
277.330
286.073
293.807
300.732
306.994
312.705
317.952
322.803
327.312
331.523
335.472
339.190
342.702
346.028
349.189
352.198
355.070
357.817
360.449
362.975
365.404
367.742
369.996
372.172
374.274
376.309
378.280
380.190
382.044
383.844
385.595
387.297
388.955
390.569
392.144
393.679
395.178
396.641
398.072
399.469
400.837
402.175
403.485
404.768
406.026
407.258
408.468
409.653
410.817
411.959
413.081
414.183
415.266
416.331
417.378
H°(T)-H°@)
кДж • моль
3.031
6.879
11.258
11.345
16.269
21.533
27.039
32.712
38.505
44.385
50.329
56.322
62.352
68.413
74.497
80.600
86.720
92.852
98.996
105.149
111.311
117.479
! 23.653
129.832
136.017
142.205
148.396
154.591
160.789
166.990
173.192
179.397
185.604
191.813
198.023
204.235
210.448
216.662
222.877
229.093
235.311
241.529
247.748
253.968
260.188
266.409
272.631
278.853
285.077
291.300
297.524
303.748
309.973
316.199
322.424
328.651
334.877
341.104
347.331
353.558
359.786
(г)
@) = 966.715
lgK°(T)
-495.5766
-241.8605
-158.0595
-157.0048
-114.4545
-88.8632
-71.7690
-59.5393
-50.3549
-43.2038
-37.4776
-32.7891
-28.8794
-25.5693
-22.7307
-20.2695
-18.1150
-16.2133
-14.5224
-13.0089
-11.6463
-10.4131
-9.2916
-8.2674
-7.3282
-6.4639
-5.6658
-4.9267
-4.240!
-3.6006
-3.0036
-2.4450
-1.9211
-1.4287
-.9652
-.5280
-.1150
.2759
.6463
.9979
1.3320
1.6499
1.9528
2.2417
2.5177
2.7814
3.0338
3.2756
3.5074
3.7298
3.9434
4.1488
4.3463
4.5365
4.7197
4.8964
5.0668
5.2313
5.3902
5.5438
5.6924
кДж ¦ моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т аб л
'-а
g
'
¦ гч
**•
оо 2
5 '
О II
II °
5- и_
о"
О
0
а;
<
J"
'О _
+ I
1> f
OS
8 5
О (П
| 00
Н •
з ~
00
о г2
? а
ОО <N
00 .
II +
g
0
©
и
•А
О
2
%
t--
О
I
II
Я
in
00
On
и
сч
§
5;
ца 483
_
g
2
—'
А
(N
00
го
II
>>
§
о
о
о
V
*"¦•
V
§
¦о
«'"
ь.
II
280

Класс точности
1-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.167
31.231
34.783
34.846
37.562
39.051
39.711
39.920
39.909
39.804
39.669
39.532
39.407
39.299
39.209
39.135
39.077
39.034
39.002
38.981
38.969
38.966
38.971
38.982
38.999
39.022
39.050
39.083
39.121
39.163
39.209
39.260
39.315
39.374
39.437
39.505
39.576
39.651
39.729
39.811
39.897
39.985
40.077
40.170
40.266
40.364
40.463
40.564
40.664
40.765
40.866
40.965
41.064
41.160
41.255
41.347
41.436
41.521
41.603
41.681
41.755
ФТОРИД ГЕРМАНИЯ GeF (г)
AfV)=p(Ge).
Ф°(Г)
Дж . К . моль"
170.997
191.247
203.229
203.419
212.442
219.744
225.919
231.279
236.013
240.251
244.085
247.583
250.798
253.771
256.535
259.118
261.541
263.823
265.979
268.022
269.964
271.813
273.579
275.268
276.887
278.442
279.936
281.376
282.765
284.106
285.403
286.658
287.875
289.055
290.200
291.314
292.396
293.450
294.477
295.478
296.454
297.407
298.338
299.248
300.138
301.008
301.860
302.695
303.513
304.314
305.101
305.872
306.630
307.373
308.103
308.821
309.527
310.220
310.903
311.574
312.235
p(F)-p-1(GeF)
S°(T)
l
200.093
220.762
233.897
234.112
244.540
253.102
200.289
266.430
271.761
276.457
280.644
284.418
287.852
291.002
293.911
296.613
299.137
301.505
303.735
305.843
307.842
309.744
311.556
313.289
314.948
316.541
318.072
319.546
320.968
322.342
323.670
324.957
326.204
327.415
328.591
329.735
330.849
331.935
332.993
334.026
335.035
336.021
336.986
337.930
338.855
339.761
340.649
341.520
342.375
343.215
344.039
344.850
345.646
346.429
347.199
347.957
348.703
349.437
350.160
350.872
351.573
v
Н°(Г)-Н°@)
кДж • моль
2.910
5.903
9.144
9.208
12.839
16.679
20.622
24.606
28.599
32.585
36.559
40.519
44.465
48.401
52.326
56.243
60.153
64.059
67.961
71.860
75.757
79.654
83.551
87.448
91.347
95.248
99.152
103.058
106.969
110.883
114.801
118.725
122.654
126.588
130.529
134.476
138.430
142.391
146.360
150.337
154.322
158.316
162.319
166.332
170.354
174.385
178.427
182.478
186.539
190.611
194.692
198.784
202.885
206.996
211.117
215.247
219.386
223.534
227.690
231.854
236.026
г°@)= 513.000
-264.7626
-130.3016
-85.8770
-85.3176
-62.7432
-49.1562
-40.0744
-33.5731
-28.6879
-24.8820
-21.8327
-19.3346
-17.2503
-15.4847
-13.9696
-12.6552
-11.5039
-10.4871
-9.5824
-8.7721
-8.0422
-7.3811
-6.7796
-6.2298
-5.7254
-5.2609
-4.8317
-4.4340
-4.0642
-3.7197
-3.3978
-3.0964
-2.8136
-2.5477
-2.2972
-2.0608
-1.8374
-1.6258
-1.4252
-1.2347
-1.0536
-.8812
-.7169
-.5601
-.4103
-.2670
-.1299
.0014
.1274
.2483
.3644
.4760
.5835
.6869
.7865
.8826
.9752
.0647
1.1511
1.2347
.3154
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 484
'л
— о
'л
° к Т.
2 Ч Й
X О
ч <^ _•
х ч2 ~
оо *¦? .
ОО чо II Д
¦^ ^ я ¦*
ON " ^ Г-J
II о оо 2
^ • ьГ Я
II
<D - Ч
О tin 0 ВЧ
Si U Ь,
о w
а-
¦*ч О
<
1
7
я 1
о S
+ „¦
ю • Q
г; ? о
<=>. в v
° » ^
X *° V
•S „' §
ОО X хп
г~4 О
+ +
об °°. ?
tr> ЧО
II !
о
281

¦Класс tv.
VI
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ности
С°(Т)
Р
36.185
42.550
47.846
47.927
51.346
53.415
54.709
55.555
56.134
56.544
56.845
57.072
57.247
57.384
57.494
57.584
57.657
57.718
57.770
57.813
57.851
57.883
57.911
57.935
57.957
57.976
57.993
58.008
ео лО1
Эо.021
58.033
58.044
58.054
58.063
58.071
58.079
58.086
58.092
58.098
58.103
58.108
58.113
58.117
58.121
58.124
58.128
58.131
58.134
58.137
58.139
58.142
58.144
58.146
58.149
58.151
58.152
58.154
58.156
58.157
58.159
58.160
58.162
ДИФТОРИД ГЕРМАНИЯ GeF2 (г)
KV) = p(Ge).
Ф G")
•* 1 ~
Дж • К . моль
191.606
215.953
231.136
231.380
243.129
252.761
260.972
268.143
274.517
280.255
285.475
290.264
294.687
298.798
302.636
306.237
309.628
312.832
315.869
318.755
321.504
324.130
326.642
329.050
331.363
333.587
335.730
337.796
ЗЗУ.791
341.721
343.588
345.397
347.152
348.855
350.510
352.120
353.685
355.210
356.696
358.145
359.559
360.939
362.288
363.605
364.894
366.155
367.389
368.597
369.781
370.941
372.078
373.194
374.289
375.363
376.418
377.454
378.473
379.473
380.457
381.424
382.376
Таблица 4К5
02(F)-p~'(GeF2) ДгЯ°@)= 1095.913 кДж • моль
S°(T)
1
225.605
252.630
270.670
270.966
285.263
296.962
306.824
315.325
322.784
329.420
335.394
340.823
345.797
350.385
354.642
358.611
362.330
365.827
369.128
372.253
375.219
378.042
380.736
383.310
385.777
388.143
390.417
392.606
1ЛЛ 71ft
ЗУ 4.7 ID
396.752
398.720
400.623
402.466
404.253
405.987
407.671
409.307
410.899
412.448
413.958
415.429
416.864
418.264
419.632
420.968
422.275
423.552
424.803
426.027
427.225
428.400
429.552
430.681
431.788
432.875
433.942
434.990
436.020
437.031
438.025
439.003
Я°(П-Я°@)
кДж . моль
3.400
7.335
11.787
11.876
16.854
22.100
27.511
33.027
38.613
44.248
49.919
55.615
61.331
67.063
72.807
78.561
84.324
90.092
95.867
101.646
107.429
113.216
119.006
124.798
130.593
136.389
142.188
147.988
1 КО 7QO
1 DO./ОУ
159.592
165.396
171.201
177.007
182.813
188.621
194.429
200.238
206.048
211.858
217.668
223.479
229.291
235.102
240.915
246.727
252.540
258.353
264.167
269.981
275.795
281.609
287.424
293.238
299.053
304.869
310.684
316.499
322.315
328.131
333.947
339.763
Г
К
-564.3886 ¦ 100
-277.1384 200
-182.3128 298.15
-181.1195 300
-132.9842 400
-104.0375 500
-84.7025 600
-70.8688 700
-60.4786 800
-52.3873 900
-45.9071 1000
-40.5998 1100
-36.1730 1200
-32.4242 1300
-29.2085 1400
-26.4194 1500
-23.9772 1600
-21.8209 1700
-19.9029 1800
-18.1857 1900
-16.6393 2000
-15.2392 2100
-13.9656 2200
-12.8020 2300
-11.7348 2400
-10.7523 2500
-9.8448 2600
-9.0040 2700
о OQQQ ООЛЛ
-O.ZZZO ZOUU
-7.4950 2900
-6.8153 3000
-6.1790 3100
-5.5822 3200
-5.0212 3300
-4.4928 3400
-3.9944 3500
-3.5233 3600
-3.0774 3700
-2.6548 3800-
-2.2535 3900
-1.8721 4000
-1.5091 4100
-1.1631 4200
-.8331 4300
-.5178 4400
-.2164 4500
.0721 4600
.3484 4700
.6135 4800
.8678 4900
1.1121 5000
1.3470 5100
1.5730 5200
1.7905 5300
2.0002 5400
2.2023 5500
2.3973 5600
2.5856 5700
2.7675 5800
2.9433 5900
3.1134 6000
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282

Класс точности
Vl-I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
42.687
56.836
66.179
66.316
72.021
75.412
77.515
78.885
79.820
80.482
80.967
81.331
81.612
81.833
82.010
82.153
82.271
82.370
82.452
82.522
82.582
82.634
8^.679
82.718
82.753
82.783
82.810
82.834
82.856
82.875
82.893
82.909
82.923
82.936
82.948
82.959
82.969
82.979
82.987
82.995
83.003
83.009
83.016
83.022
83.027
83.032
83.037
83.041
83.046
83.050
83.053
83.057
83.060
83.063
83.066
83.069
83.072
83.074
83.077
83.079
83.081
ТРИФТОРИД ГЕРМАНИЯ GeF3
Ф°G)
— 1 -
Дж ¦ К . моль
202.943
230.001
248.377
248.682
263.592
276.159
287.060
296.699
305.340
313.172
320.334
326.931
333.044
338.742
344.075
349.088
353.817
358.292
362.539
366.581
370.435
374.119
377.648
381.032
384.285
387.416
390.432
393.344
396.157
398.878
401.513
404.068
406.546
408.952
411.291
413.566
415.780
417.937
420.040
422.091
424.092
426.046
427.956
429.822
431.648
433.435
435.183
436.896
438.575
440.220
441.833
443.416
444.968
446.493
447.990
449.461
450.906
452.326
453.723
455.096
456.447
о\\)р '(Gel'3) Д^/
S°{T)
1
238.787
273.031
297.607
298.016
317.948
334.415
348.364
360.424
371.022
380.464
388.970
396.704
403.794
410.335
416.406
422.069
427.376
432.366
437.077
441.537
445.771
449.802
453.647
457.323
460.844
464.223
467.470
470.596
473.609
476.517
479.327
482.045
484.677
487.229
489.705
492.110
494.447
496.721
498.933
501.089
503.191
505.240
507.241
509.194
511.103
512.969
514.794
516.580
518.328
520.040
521.718
523.363
524.976
526.558
528.111
529.635
531.132
532.602
534.047
535.467
536.863
/Г(Т) //°@)
кДж . моль
3.584
8.606
14.678
14.800
21.742
29.128
36.782
44.607
52.545
60.562
68.636
76.751
84.899
93.072
101.264
109.473
117.694
125.926
134.168
142.416
150.672
158.933
167.198
175.468
183.742
192.018
200.298
208.580
216.865
225.152
233.440
241.730
250.022
258.315
266.609
274.904
283.201
291.498
299.796
308.095
316.395
324.696
332.997
341.299
349.601
357.904
366.208
374.512
382.816
391.121
399.426
407.732
416.037
424.344
432.650
440.957
449.264
457.571
465.879
474.187
482.495
(Г)
1°Ц)) = 1350.667 кДж ¦ моль"
о
Т
К
-692.1198 100
-337.7136 200
-220.7003 298.15
-219.2278 300
-159.8384 400
-124.1343 500
-100.2939 600
-83.2433 700
-70.4420 800
-60.4769 900
-52.4992 1000
-45.9680 1100
-40.5226 1200
-35.9129 1300
-31.9602 1400
-28.5333 1500
-25.5338 1600
-22.8864 1700
-20.5326 1800
-18.4260 1900
-16.5295 2000
-14.8133 2100
-13.2528 2200
-11.8276 2300
-10.5208 2400
-9.3184 2500
-8.2082 2600
-7.1800 2700
-6.2250 2800
-5.3357 2900
-4.5055 3000
-3.7287 3100
-3.0002 3200
-2.3158 3300
-1.6715 3400
-1.0639 3500
-.4899 3600
.0532 3700
.5678 3800
1.0561 3900
1.5201 4000
1.9615 4100
2.3820 4200
2.7831 4300
3.1660 4400
3.5319 4500
3.8820 4600
4.2173 4700
4.5386 4800
4.8469 4900
5.1430 5000
5.4275 5100
5.7010 5200
5.9644 5300
6.2180 5400
6.4624 5500
6.6981 5600
6.9256 5700
7.1453 5800
" 7.3576 5900
7.5629 6000
1 а Г» )\ и ц ;i 486
-1
г;
- О
'л 5
о ?
^ 'л
С * ^
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Ч о Ж
о ;; у
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? •? ~ 3
Я и !о о
-н ^ * °°.
1, О 00 О
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ГО Сщ "
и. -
a m 2
О U. ск
о" О
а: о4" .
о
_+
i^.
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00 
7 §
1 -.'
Н 1 '—*
й * ?
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II °
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1 й W
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to Т
гч m О
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00 <1 И
00 ГЦ
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Ч- IN
II +
t
PN
О
в
283

Класс точн
VI-D
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600 .
1700
1800
1900
2000
2100
2200
2300-
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ости
С°(Т)
49.707
69.284
81.601
81.790
90.032
95.250
98.610
100.852
102.405
103.517
104.337
104.958
105.438
105.817
106.121
106.368
106.572
106.741
106.884
107.006
107.109
107.199
107.277
107.345
107.405
107.458
107.505
107.547
107.585
107.619
107.649
107.677
107.702
107.725
107.746
107.765
107.783
107.799
107.814
107.827
107.840
107.852
107.863
107.873
107.883
107.892
107.900
107.908
107.916
107.922
107.929
107.935
107.941
107.946
107.952
107.956
107.961
107.965
107.970
107.974
107.977
ТЕТРАФТОРИД
К (Т) = p(Ge) •
Ф°(Т)
Дж ¦ К . моль
192.542
222.451
243.815
244.174
261.903
277.062
290.356
302.205
312.898
322.640
331.585
339.854
347.541
354.722
361.459
367.803
373.798
379.479
384.879
390.022
394.933
399.632
404.135
408.459
412.617
416.622
420.484
424.213
427.818
431.306
434.686
437.964
441.145
.444.236
447.240
450.164
453.011
455.785
458.489
461.128
463.704
466.219
468.678
471.082
473.434
475.736
477.989
480.197
482.361
484.482
486.563
488.604
490.607
492.574
494.506
496.404
498.269
500.103
501.906
503.679
505.424
S°(T)
1
230.529
271.-705
301.792
302.320
327.067
347.761
365.446
380.826
394.401
406.530
417.481
427.456
436.610
445.065
452.918
460.249
467.120
473.586
479.692
485.474
490.965
496.194
501.182
505.952
510.522
514.908
519.124
523.182
527.093
530.869
534.518
538.048
541.468
544.782
547.998
551.122
554.158
557.111
559.986
562.787
565.517
568.180
570.779
573.317
575.798
578.222
580.593
582.914
585.186
587.411
589.592
591.729
593.825
595.881
597.899
599.880
601.825
603.736
605.614
607.459
609.274
ГЕРМАНИЯ GeF4
jeF4) &rH
Л°G>«°<0)
кДж . моль
3.799
9.851
17.280
17.444
26.066
35.350
45.054
55.035
65.202
75.501
85.896
96.362
106.883
117.446
128.044
138.668
149.316
159.982
170.663
181.358
192.064
202.779
213.503
224.234
234.972
245.715
256.463
267.216
277.973
288.733
299.496
310.262
321.031
331.803
342.576
353.352
364.129
374.908
385.689
396.471
407.255
418.039
428.825
439.612
450.400
461.188
471.978
482.768
493.560
504.352
515.144
525.937
536.731
547.525
558.320
, 569.116
579.912
590.708
601.504
612.302
623.099
(г)
@)= 1863
о
-953.4123
-464.5086
-303.1261
-301.0957
-219.2098
-169.9955
-137.1442
-1 13.6562
-96.0271
-82.3079
¦71.3278
-62.3412
-54.8505
-48.5111
-43.0766
-38.3663
-34.2445
-30.6075
-27.3745
-24.4818
-21.8784
-19.5230
-17.3818
-15.4268
-13.6348
-11.9862
-10.4645
-9.0556
-7.7473
-6.5294
-5.3926
-4.3293
-3.3325
-2.3961
-1.5149
-.6840
.1006
.8428
1.5459
2.2129
2.8465
3.4492
4.0231
4.5703
5.0926
5.5917
6.0690
6.5260
6.9639
7.3839
7.7871
8.1744
8.5468
8.9051
9.2501
9.5826
9.9031
10.2124
10.5110
10.7994
11.0783
.293 кДж • моль
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
• .2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
-1
00
об
—1
II
+
1
X
VO
ч
+
1
ё
ГА
00
<ч
«о
о
о
1
ч
?
8
•о
8
г-
i
j,
0
е
_
о
; 1
X, —"•
-*. ~
ОС ц
i Я
II ?
л" ОО
О ^
U <^
^- ti
О *к
о Й
ч-> "а:
1 л
к
о
2
'
1
>о
•А
1
о

VO
+
ц а 487
i
л
о
S
i
.
I—f
1—А
1/-J
II
0 В!
to
Я
1
V
V
§
V)
с
и
284

Класс точности
III—F
t
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
29.962
33.833
36.984
37.034
39.170
40.287
40.716
40.768
40.644
40.454
40.252
40.063
39.897
39.757
39.643
39.552
39.482
39.430
39.394
39.373
39.364
39.367
39.380
39.402
39.434
39.473
39.521
39.576
39.639
39.710
39.789
39.876
39.971
40.074
40.185
40.304
40.431
40.566
40.708
40.857
41.013
41.175
41.342
41.514
41.689
41.867
42.047
42.228
42.408
42.587
42.764
42.938
43.107
43.271
43.430
43.581
43.725
43.861
43.988
44.106
44.214
ХЛОРИД ГЕРМАНИЯ GeCl (г)
К°(Т)= p(Ge)-p(Cl)-p(GeCl) АгИ°@)= 416.000
Ф°(Г)
Дж ¦ К . моль
180.428
201.054
213.563
213.762
223.241
230.900
231.355
242.939 ,
247.857
252.248
256.211
259.821
263.132
266.191
269.031
271.681
274.165
276.502
278.709
280.798
282.782
284.671
286.473
288.197
289.848
291.433
292.957
294.424
295.839
297.205
298.525
299.804
301.042
302.243
303.410
304.543
305.646
306.719
307.765
308.784
309.779
310.750
311.699
312.627
313.534
314.422
315.292
316.144
316.979
317.799
318.603
319.392
320.167
320.928
321.677
322.412
323.136
323.848
324.548
325.238
325.917
5°(Г)
1
209.673
231.624
245.750
245.979
256.952
265.829
273.220
279.504
284.941
289.717
293.969
297.796
301.275
304.463
307.405
310.136
312.687
315.079
317.332
319.461
321.480
323.400
325.232
326.983
328.661
330.271
331.820
333.313
334.753
336.145
337.493
338.799
340.067
341.298
342.496
343.663
344.800
345.909
346.993
348.052
349.089
350.103
351.098
352.073
353.029
353.968
354.890
355.796
356.687
357.563
358.425
359.274
360.110
360.932
361.742
362.541
363.327
364.102
364.866
- 365.619
366.361
Н°(Г)-Н°@)
кДж . моль
2.924 -214.1827
6.114 -105.0853
9.597 -69.0434
9.665 -68.5896
13.485 -50.2732
17.465 -39.2453
21.519 -31.8709
25.596 -26.5892
29.667 -22.6185
33.722 -19.5236
37.758 -17.0430
41.773 -15.0100
45.771 -13.3131
49.753- -11.8751
53.723 -10.6409
57.683 -9.5697
61.634 -8.6313
65.580 -7.8022
69.521 ' -7.0644
73.459 -6.4034
77.396 -5.8078
81.332 -5.2683
85.269 -4.7773
89.208 -4.3284
93.150 -3.9165
97.095 -3.5371
101.045 -3.1865
105.000 -2.8615
108.961 -2.5594
112.928 -2.2778
116.903 -2.0147
120.886 -1.7683
124.878 -1.5371
128.881 -1.3197
132.894 -1.1148
136.918 -.9215
140.955 -.7387
145.004 -.5657
149.068 -.4016
153.146 -.2458
157.240 -.0977
161.349 .0433
165.475 :1776
169.618 .3059
173.778 .4283
177.956 .5454
182.151 .6575
186.365 .7648
190.597 .8677
194.846 .9665
199.114 1.0613
203.399
207.701
212.020
216.355
220.706
225.071
229.450
233.843
238.248
242.664
.1525
.2402
.3245
.4058
.4841
.5597
.6326
.7029
.7709
.8367
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 488
1
i
л
7 о
A 2
о 1 Т,
Еч О
й я -*
* о Т
?> р .
? ^ 1 X
со „ !з? w
-* д —. о.
II ° ОС (Л
!§ U. Я м •
Я, "" "*
О о ° "
ч""' ZJ Со
а:
*—• &
о ^
1
т
н
3 |
О ?
+ _•
1 1 1
О "w \ /
о н V
О 2 *ч
¦s J §
чо X ю
Si чо **"
m о °
+ + к
—i 43 II
00 ОО X
m 4 w
in о
" 1
0
285

Клас
Т
К
100
200
298
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с точности
V-E
C°iT)
40.781
49.882
15 53.784
53.831
55.581
56.473
56.980
57.295
57.503
57.647 .
57.750
57.828
57.887
57.933
57.969
57.999
58.023
58.044
58.060
58.075
58.087
58.098
58.107
58.115
58.122
58.128
58.133
58.138
58.143
58.147
58.150
58.153
58.156
58.159
58.161
58.164
58.166
58.168
58.169
58.171
58.172
58.174
58.175
58.176
58.177
58.178
58.179
58.180
58.181
58.182
58.183
58.183
58.184
58.185
58.185
58.186
58.186
58.187
58.187
58.188
58.188
ДИХЛОРИД ГЕРМАНИЯ GeCl2
Л-°(Г) = Р(Се),
Ф°(Г)
Дж • К . моль
207.780
234.150
251.185
251.461
264.661
275.384
284.426
292.247
299.138
305.300
310.870
315.954
320.629
324.956
328.984
332.751
336.289
339.624
342.778
345.770
348.616
351.329
353.922
356.404
358.784
361.071
363.271
365.391
367.437
369.413
371.324
373.175
374.968
376.708
378.398
380.039
381.636
383.190
384.704
386.179
387.618
389.022
390.393
391.732
393.042
394.322
395.575
396.802
398.003
399.180
400.333
401.464
402.574
403.663
404.732
405.782
406.812
407.826
408.821
409.800
410.763
02(CDp~\GeCl2) &rH°
5°(Г)
1
243.544
274.960
295.715
296.048
311.805
324.313
334.658
343.467
351.132
357.914
363.993
369.501
374.535
379.171
383.465
387.466
391.210
394.728
398.046
401.186
404.165
407.000
409.702
412.285
414.759
417.132
419.412
421.606
Л Л *\ *V ПА
423.720
425.760
427.732
429.639
431.485
433.275
435.011
436.697
438.335
439.929
441.480
442.991
444.464
445.900
447.302
448.671
450.009
451.316
452.595
453.846
455.071
456.271
457.446
458.598
459.728
460.836
461.924
462.992
464.040
465.070
466.082
467.077
468.055
Н°(Г)-Н°@)
кДж . моль
3.576
8.162
13.277
13.376
18.857
24.465
30.139
35.854
41.595
47.353
53.123
58.902
64.688
70.479
76.274
82.073
87.874
93.677
99.482
105.289
111.097
116.906
122.717
128.528
134.340
140.152
145.965
151.779
157.593
163.407
169.222
175.037
180.853
186.668
192.484
198.301
204.117
209.934
215.751
221.568
227.385
233.202
239.020
244.837
250.655
256.473
262.290
268.108
273.926
279.744
285.563
291.381
297.199
303.018
308.836
314.655
320.474
326.292
332.111
337.930
343.748
(г)
@) = 778.737
о
-398.7482
-194.4621
-127.0338
-126.1852
-91.9557
-71.3642
-57.6026
-47.7505
-40.3462
-34.5767
-29.9533
-26.1648
-23.0033
-20.3248
-18.0261
-16.0316
-14.2845
-12.7414
-11.3683
-10.1385
-9.0307
-8.0273
-7.1144
-6.2800
-5.5145
-4.8095
-4.1582
-3.5546
-2.9936
-2.4708
-1.9824
-1.5251
-1.0960
-.6925
-.3124
.0462
.3853
.7063
1.0106
1.2997
1.5745
1.8361
2.0855
2.3235
2.5508
2.7683
2.9765
3.1759
3.3673
3.5509
3.7274
3.8971
4.0604
4.2177
4.3693
4.5154
4.6565
4.7927
4.9244
5.0516
5.1748
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
*оиО
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Табл
-
'л
о
f
v
О
О
2 7
СП II
*""* О
(U
О
о
а:
+
ОО
° °
Н |
—Ч Ж
S п
О m
1 оо
' О
G =>
00 22
^ 1
00 ¦*
^ CN
Tf О
II +
О
и ц а
л
о
о
о
о
1
II
«о
эо*
-
ч
э
489
о
„¦
1
.
II
0 К
to
я
о
1
V
t-
V
§
»'"
'о
286

Класс точности
VI-G
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
53.284
69.915
76.257
76.331
79.091
80.479
81.266
81.752
82.072
82.293
82.453
82.572
82.662
82.733
82.789
82.835
82.872
82.903
82.929
82.951
82.970
82.986
83.000
83.012
83.023
83.032
83.041
83.048
83.055
83.061
83.066
83.071
83.076
83.080
83.084
83.087
83.090
83.093
83.096
83.098
83.100
83.102
83.104
83.106
83.108
83.110
83.111
83.112
83.114
83.115
83.116
83.117
83.118
83.119
83.120
83.121
83.122
83.123
83.123
83.124
83.125
*-(П-Р(Се),
Ф°(П
Дж ¦ К . моль
222.369
254.110
276.199
276.564
294.230
308.816
321.239
332.055
341.631
350.222
358.011
365.135
371.698
377.781
383.451
388.759
393.749
398.457
402.913
407.142
411.167
415.006
418.676
422.191
425.563
428.804
431.924
434.930
Л Л Т А Л ^\
437.832
440.636
443.348
445.975
448.522
450.Э93
453.392
455.724
457.993
460.201
462.352
464.449
466.495
468.491
470.441
472.346
474.208
476.029
477.812
479.557
481.266
482.940
484.582
486.192
487.771
489.321
490.843
492.337
493.805
495.247
496.664
498.059
499.430
ТРИХЛОРИД
ГЕРМАНИЯ
o\c\)-p~\G*c\3) Arh
S°(T)
l
262.908
305.806
335.092
335.564
357.951
375.764
390.513
403.080
414.018
423.698
432.378
440.242
447.431
454.050
460.184
465.897
471.244
476.269
481.009
485.493
489.748
493.797
497.658
501.348
504.881
508.270
511.527
514.661
517.681
520.596
523.412
526.136
528.773
531.330
533.810
536.218
538.559
540.836
543.052
545.210
547.314
549.366
551.369
553.324
555.235
557.102
558.929
560.716
562.466
564.180
565.859
567.505
569.119
570.702
572.256
573.781
575.279
576.750
578.196
579.617
581.014
Я°(Г>-Я°@)
кДж . моль
4.054
10.339 .
17.559
17.700
25.488
33.474
41.565
49.717
57.910
66.128
74.366
82.618
90.880
99.150
107.426
115.707
123.992
132.281
140.573
148.867
157.163
165.461
173.760
182.061
190.362
198.665
206.969
215.273
АЛЛ ^ЧА
223.578
231.884
240.191
248.497
256.805
265.112
273.421
281.729
290.038
298.347
306.657
314.966
323.276
331.587
339.897
348.207
356.518
364.829
373.140
381.451
389.762
398.074
406.385
414.697
423.009
431.321
439.633
447.945
456.257
464.569
472.881
481.194
489.506
GeCl3 (г)
Таблица 490
Г°@) = 1047.897 кДж • моль
Т
К
-533.7685 100
-258.7131 200
-167.9714 298.15
-166.8299 300
-120.7994 400
-93.1300 500
-74.6520 600
-61.4329 700
-51.5050 800
-43.7742 900
-37.5830 1000
-32.5130 1100
-28.2846 1200
-24.7042 1300
-21.6334 1400
-18.9705 1500
-16.6393 1600
-14.5813 1700
-12.7512 1800
-11.1130 1900
-9.6380 2000
-8.3030 2100
-7.0889 2200
-5.9800 2300
•4.9631 2400
-4.0272 2500
-3.1631 2600
-2.3626 2700
1 ^ 1 Л 1 ПА/\/Ъ
-1.6191 2800
-.9267 2900
-.2802 3000
.3248 3100
.8922 3200
1.4253 3300
1.9273 3400
2.4007 3500
2.8479 3600
3.2711 3700
3.6722 3800
4.0528 3900
4.4144 4000
4.7586 4100
5.0864 4200
5.3991 4300
5.6976 4400
5.9830 4500
6.2560 4600
6.5175 4700
6.7682 4800
7.0086 4900
7.2396 5000
7.4615 5100
7.6750 5200
7.8804 5300
8.0783 5400
8.2690 5500
8.4530 5600
8.6306 5700
8.8021 5800
8.9678 5900
9.1280 6000
'л
о
л 2
с •
3 *
к ^ '*
о о
О сч -
О го 1
о 1 *4
°^ ГО "
? s —: о
и °- " 2
--Г u II
и
% о^
**ч 0
_+
'н
О\
го Т
* 1
с*
'* Т
Я и Я
ООЗЗО
'Дж-
: боос
° й У
i 8 *-
2 S v
« + 8
о ¦* V
S -3 о
+ 
S * *""
II +
р
0
•
287

Класс точности
VI-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
63.796
85.933
95.917
96.041
100.749
103.206
104.623
105.509
106.096
106.505
106.800
107.020
107.188
107.320
107.424
107.509
107.579
107.636
107.685
' 107.726
107.761
107.791
107.817
107.840
107.860
107.878
107.894
107.908
107.920
107.932
107.942
107.951
107.959
107.967
107.974
107.980
107.986
107.992
107.997
108.001
108.005
108.009
108.013
108.016
108.020
108.023
108.025
108.028
108.030
108.033
108.035
108.037
108.039
108.041
108.042
108.044
108.046
108.047
108.048
108.050
108.051
ТЕТРАХЛОРИД
А:°(Г)=Р(Се)-р4(С1).р~1(С
Ф°(Г)
Дж • К . моль
214.641
251.110
277.391
277.830
299.277
317.220
332.640
346.156
358.183
369.014
378.864
387.896
396.234
403.978
411.205
417.981
424.358
430.380
436.086
441.506
446.667
451.594
456.306
460.821
465.156
469.324
473.337
477.206
480.943
484.554
488.048
491.433
494.716
497.902
500.996
504.005
506.932
509.782
512.559
515.266
517.907
520.485
523.003
525.464
527.870
530.224
532.528
534.783
536.992
539.157
541.280
543.362
545.404
547.409
549.377
551.310
553.209
555.075
556.909
558.713
560.488
S°(T)
1
259.926
311.848
348.281
348.875
377.228
400.000
418.953
435.152
449.282
461.803
473.041
483.231
492.550
501.135
509.092
516.507
523.448
529.971
536.125
541.948
547.475
552.733
557.748
562.542
567.132
571.535
575.767
579.839
583.763
587.551
591.210
594.749
598.177
601.499
604.722
607.852
610.894
613.853
6П 6.733
619.539
622.273
624.940
627.543
630.084
632.568
634.995
637.369
639.692
641.967
644.195
646.377
648.516
650.614
652.672
654.692
656.674
658.621
660.534
662.413
664.260
666.076
ГЕРМАНИЯ GeCl
5еС14) Д Н
Н°(Т)-Н°@)
кДж . моль
4.529
12.148
21.136
21.314
31.180
41.390
51.788
62.297
72.880
83.511
94.177
104.868
115.579
126.305
137.042
147.789
158.543
169.304
180.070
190.841
201.615
212.393
223.173
233.956
244.741
255.528
266.317
277.107
287.898
298.691
309.484
320.279
331.075
341.871
352.668
363.466
374.264
385.063
395.863
406.663
417.463
428.264
439.065
449.866
460.668
471.470
482.273
493.075
503.878
514.681
525.485
536.288
547.092
557.896
568.700
579.504
590.309
601.114
611.918
622.723
633.528
4 (Г)
°@)= 1345.657 кДж • моль
о
-682.5618
-329.2346
-212.6752
-211.2091
-152.0970
-116.5762
-92.8639
-75.9067
-63.1762
-53.2666
-45.3335
-38.8392
-33.4249
-28.8419
-24.9125
-21.5062
-18.5251
-15.8944
-13.5557
-11.4630
-9.5794
-7.8751
-6.3257
-4.9110
-3.6142
-2.4211
-1.3198
-.3000
.6469
1.5284
2.3512
3.1209
3.8425
4.5203
5.1582
5.7597
6.3277
6.8650
7.3739
7.8568
8.3155
8.7518
9.1672
9.5634
9.9415
10.3028
10.6483
10.979!
11.2961
11.6001
11.8920
12.1724
12.4419
12.7013
12.9511
13.1917
13.4237
13.6476
13.8637
14.0725
14.2743
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б
-
'л
о
о
00
о ¦*
¦*' II
II
5
0
О
3;
<!
+
j
00
^ 'л
к -'
о
о Ч
о «
1 -9
Я 2
•д о
о +
ОО ^
о JS
-"¦' о
? '
о ^
Tf Г-
ос г*-
чо о
II +
0
лиц
%
о
о
о
о
о
i
II
ОО
С-1
^-
О
о
а 491
7
л
о
1
о
ОО
II
0 g
1>3
я
о
о
ЧО
V
V
S
«'"
'о
II
288

Класс точности
VI-D
Г
К
100
200
298.15
300
400
500
600
700
800
900
931
931
1000
1100
1200
1300
1400
1500
1600
1700
с°рт
29.500
43.300
47.782
47.820
49.860
51.900
53.940
55.980
58.020
60.060
60.692
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
СУЛЬФИД ГЕРМАНИЯ GeS
,-<г>-Р«ЗД
Ф°(Г)
~ 1 ¦*¦
Дж • К ¦ моль
8.790
22.440
34.090
34.291
44.238
52.722
60.118
66.689
72.619
78.040
79.632
79.632
84.637
91.287
97.337
102.886
108.010
112.771
117.216
121.385
S°(T)
1
22.570
48.220
66.480
66.776
80.812
92.157
101.800
110.268
117.876
124.828
126.872
149.751
154.541
160.927
166.757
172.120
177.085
181.707
186.031
190.093
Д А
s
//°(Л-Я°@)
кДж . моль"
1.378
5.156
9.657
9.745
14.629
19.717
25.009
30.505
36.205
42.109
43.981
65.281
69.904
76.604
83.304
90.004
96.704
103.404
110.104
116.804
(к, ж)
'°@)= 170.301
-80.4049
-35.5800
-20.9185
-20.7350
-13.3738
-8.9960
-6.1055
-4.0628
-2.5488
-1.3866
-1.0798
¦1.0798
-.5533
.0807
.5973
1.0246
1.3823
1.6850
1.9435
2.1659
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
931
931
1000
1100
1200
1300
1400
1500
1600
1700
Таблица 492
i
л
1
Л
* * 1
* о 1
J5 О
Et ¦*. _"
X с> i
О 1 . •
О . .-;
1 ^ в, «
II 5 оо |О
* м II
ОТ* * я
X от о §
0 !~.
"'• моль"'
: Дж ¦ К"
• моль"
102 .Од
ж К"
+ Ч
'ч 55 * Q
s s i §
m V гч -^
в К о V
н V н ^
Л ^ •? V
С-;  О _,
* | ? S
+ .•,+ ¦-
о\ Т ¦ ¦? 1_
t^ о —i О
—« ^^ 00 ^^
«О • —< .'
^О Ьч ¦«*¦ *-"•
-1 II М »
и ,?*, и w-
S €
о о
UH
289

Класс точности
II С
7
К
С°р(Т)
100 29.254
200 31.488
298.15 33.710
300 33.743
400 35.089
500 35.879
600 36.370
700 36.695
800 36.925
900 37.096
!000 37.228
1100 37.335
1200 37.425
1300 37.502
1400 37.570
1500 37.631
1600 37.687
1700 37.740
1800 37.790
1900 37.838
2000 37.884
2100 37.930
2200 37.976
2300 38.023
2400 38.071
2500 38.123
2600 38.179
2700 38.241
2800 38.310
2900 38.389
3000 38.479
3100 38.584
3200 38.705
3300 38.846
3400 39.007
3500 39.193
3600 39.404
3700 39.645
3800 39.916
3900 40.220
4000 40.558
4100 40.931
4200 41.341
4300 41.789
4400 42.274
4500 42.798
4600 43.358
4700 43.955
4800 44.588
4900 45.255
5000 45.955
5100 46.684
5200 47.442
5300 48.225
5400 49.030
5500 49.853
5600 50.693
5700 51.544
5800 52.404
5900 53.269
6000 54.134
СУЛЬФИД ГЕРМАНИЯ GeS
К°(Т)--=Р(С,е)-
Ф°(Т)
— 1 ~
Дж • К . моль
172.475
192.779
204.806
204.996
213.955
221.100
227.065
232.196
236.700
240.719
244.346
247.653
250.642
253.503
256.119
258.566
260.8СЗ
263.029
265.078
267.021
268.870
270.633
272.318
273.931
275.479
276.966
278.398
279.778
281.110
282.398
283.643
284.850
286.020
287.156
288.260
289.333
290.378
291.396
292.389
293.358
294.304
295.228
296.133
297.018
297.885
298.735
299.568
300.387
301.190
301.980
302.756
303.521
304.273
305.014
305.745
305.466
307.177
307.879
308.572
309.257
309.935
p(S)-p '(GeS)
S°(T)
1
201.588
222.447
235.465
235.674
245.583
253.506
260.094
265.726
270.642
275.00!
278.917
282.470
285.723
288.722
291.503
294.098
296.528
298.814
300.973
303.017
304.959
306.809
308.574
310.264
31 i .883
313.438
314.934
316.376
317.768
319.114
320.417
321.680
322.907
324.100
325.262
326.396
327.003
328.585
329.646
330.687
331.709
332.716
333.706
334.684
335.651
336.607
337.553
338.492
339.424
340.350
341.271
342.189
343.102
344.014
344.923
345.829
346.736
347.640
348 544
349.447
350.350
(Г)
Д Я°@)= 547.530 кДж ¦ моль"
Я°(Л-Я°@)
кДж . моль
2.911
5.934
9.141
9.204
12.651 .
16.203
19.817
23.471
27.153
30.855
34.571
38.299
42.038
45.784
49.538
53.298
57.064
60.835
64.612
68.393
72.179
75.970
79.765
83.565
87.370
91.179
94.994
98.815
102.643
106.478
110.321
114.174
118.038
121.916
125.808
129.718
133.648
137.600
141.578
145.584
149.623
153.697
157.810
161.966
166.169
170.423
174.730
179.095
183.522
188.014
192.574
197.206
201.912
206.695
211.558
216.502
221.529
226.641
231.838
237.122
242.492
«V,
Т
К
-282.4379 100
-138.9574 200
-91.5589 298.15
-90.9621 300
-66.8734 400
-52.3695 500
-42.6698 600
-35.7224 700
-30.4992 800
-26.4280 900
-23.1648 1000
-20.4904 1100
-18.2582 1200
-16.3667 1300
-14.7432 1400
-13.3343 1500
-12.1001 1600
-11.0097 1700
-10.0393 1800
-9.1701 1900
-8.3870 2000
-7.6776 2100
¦7.0319 2200
-6.4417 2300
-5.9001 2400
-5.4012 2500
-4.9402 2600
-4.5128 2700
-4.1155 2800
-3.7451 2900
-3.3990 3000
-3.0748 3100
-2.7706 3200
-2.4844 3300
-2.2148 3400
_
-
-
1.9603 3500
1.7196 3600
1.4917 3700
1.2756 3800
1.0703 3900
-.8751 4000
-.6892 4100
-.5121 4200
-.3430 4300
-.1815 4400
-.0271 4500
.1207 4600
.2623 4700
.3980 4800
.5283 4900
.6533 5000
.7735 5100
.8890 5200
.0001 5300
.107! 5400
.2101 5500
.3095 5600
.4052 5700
.4976 5800
.5867 5900
.6728 6000
Таблица 493
^ о
к U л
§ 1 1
| » т'
*° ?Г II J-j-
1 S 2 я
Н ^ сю "л"
^ *=> " — ¦
и. • "
со" u и
& С2 ° к
¦-Ц 0
< \
<3
+
1
m о
о 2
X .
СО „ jj
Д m О
о х «
* 7
•S <N О
? ? ""
00 -н _""
00 т-i j
С*1 | ^
о оо *""
? н "
m +
и
-~
fc-
о
е
290

Класс точности
VII Г
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1113
1113
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
С°р(Т)
36.010
56.820
65.700
65.759
68.210
69.930
71.362
72.659
73.882
75.064
76.220
77.359
77.506
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
Ф° G)
ДИСУЛЬФИД
eS2)
S°(T)
*** 1 "~ 1
Дж • К . моль
17.830
35.650
50.836
51.101
64.339
75.721
85.653
94.453
102.355
109.529
1 16.104
122.177
122.934
122.934
128.948
135.464
141.599
147.393
152.879
158.088
163.045
167.773
172.291
176.618
180.767
36.61.0
69.000
93.600
94.007
1 13.288
128.701
141.580
152.680
162.462
171.233
179.202
186.520
187.429
202.074
209.601
217.605
225.016
231.915
238.369
244.431
250.147
255.554
260.683
265.562
270.214
ГЕРМАНИЯ GeS
Д?/
//°(Л-//°@)
кДж ¦ моль
1.878
6.670
12.750
12.872
19.580
26.490
33.556
40.758
48.086
55.533
63.098
70.777
71.783
88.083
96.783
106.783
1 16.783
126.783
136.783
146.783
156.783
166.783
176.783
186.783
196.783
; (К, Ж)
Гс@) = 240.000
-116.8361
-53.7665
-33.0562
-32.7966
-22.3581
-16.1232
-11.9856
-9.0443
-6.8497
-5.1520
-3.8019
-2.7043
-2.5-66
-2..~766
-1.8546
-1.1559
-.5681
-.0680
.3612
.7326
1.0563
1.3401
1.5903
1.8119
2.0092
кДж • моль
Т
К
100
200
298 15
300
400
500
600
700
800
900
1000 .
1100
; /13
1113
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
T a Ci л и
- ' 2
Hi
s °
-< о
„ с-
? —
Si
2 _
— _ ^
,4 -Si
¦— 'S
<1 "X
г- \
ос
о
^ —-
g V
о - ^
'• ф v
2 о
— s 12
44 -' i
чС V ^1
r-i ? ¦*'"
— -S l
чС >^ '
ГП 'Я
il -»- —'
0
U a
1 ¦ моль
!
>.3216<
+
g
0
0
+
чС
—
;!
о
494
7
о
i
—
0 К
s~.
0
0
¦~l
V
V
^2
—
ь
il
291

Класс точности
VI-G
ДИСУЛЬФИД ГЕРМАНИЯ GeS2 (г)
Таблица 495
tfo(r)=p(Ge)-p2(S)-
г Я°@) = 827.897 кДж • моль
-1
К
100
200
298.15
300
40Q
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
Ф°(Г)
S°(T)
Дж • К~ . моль"
Н°(Т)-Н°@)
кДж . моль"
lg,K°(T)
40.793
49.637
54.754
54.823
57.580
59.112
60.027
60.610
61.001
61.276
61.475
61.625
61.740
61.830
61.901
61.959
62.007
62.047
62.080
62.108
62.133
62.153
62.171
62.187
62.201
62.213
62.224
62.234
62.243
62.250
62.257
62.264
62.270
62.275
62.280
62.284
62.288
62.292
62.295
62.298
62.301
62.304
62.307
62.309
62.311
62.313
62.315
62.317
62.319
62.320
62.322
62.323
62.324
62.326
62.327
62.328
62.329
62.330
62.331
62.332
62.333
181.042
206.307
222.950
223.221
236.300
247.047
256.192
264.159
271.220
277.562
283.317
288.685
293.443
297.949
302.152
306.090
309.794
313.290
316.600
319.744
322.736
325.592
328.323
330,939
333.450
335.864
338.187
340.428
342.590
344.681
346.703
348.662
350.561
352.404
354.194
355.934
357.627
359.276
360.881
362.447
363.974
365.464
366.920
368.343
369.734
371.094
372.426
373.730
375.007
376.258
377.484
378.688
379.868
381.026
382.164
383.280
384.378
385.456
386.516
387.558
388.583
214.684
245.903
266.779
26Z.117
283.307
296.336
307.201
316.501
324.622
331.823
338.290
344.157
349.524
354.470
359.054
363.327
367.328
371.088
374.635
377.993
381.179
384.211
387.103
389.867
392.514
395.053
397.494
399.842
402.105
404.290
406.400
408.442
410.419
412.335
414.194
416.000
417.754
419.461
421.122
422.740
424.318
425.856
427.357
428.824
430.256
431.656
433.026
434.366
435.678
436.963
438.222
439.456
440.666
441.854
443.019
444.162
445.286
446.389
447.473
448.538
449.586
3.364
7.919
13.068
13.169
18.803
24.645
30.605
36.639
42.721
48.836
54.974
61.129
67.298
73.476
79.663
85.856
92.054
98.257
104.464
110.673
116.885
123.099
129.316
135.534
141.753
147.974
154.196
160.419
166.642
172.867
179.092
185.318
191.545
197.772
204.000
210.228
216.457
222.686
228.915
235.145
241.375
247.605
253.836
260.066
266.297
272.529
¦278.760
284.992
291.224
297.456
303.687
309.920
316.152
322.385
328.617
334.850
341.083
347.316
353.549
359.782
366.015
-422.9653
-205.7525
-134.0309
-133.1282
-96.7128
-74.8104
-60.1793
-49.7110
-41.8488
-35.7268
-30.8244
-26.8101
-23.4625
-20.6282
-18.1975
-16.0898
-14.2448
-12.6161
-11.1677
-9.8713
-8.7041
-7.6476
-6.6867
5.8090
-5.0041
-4.2632
-3.5790
-2.9451
-2.3562
-1.8075
-1.2952
-.8156
-.3658
.0571
.4554
.8311
1.1862
1.5224
1.8411
2.1437
2.4314
2.7052
2.9662
3.2152
3.4531
3.6807
3.8984
4.1071
4.3073
4.4994
4.6840
4.8615
5.0324
5.1969
5.3554
5.5083
5.6559
5.7983
5.9360
6.0692
6.1980
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
о
00
+ g
i *
о
о
292

Класс точности
VI-C
Т
К
100
200
298.15
300
400
500
505.118
505.118
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
С°{Т)
ОЛОВО Sn (к, ж)
К°(Т)= p(Sn)
Ф°(Г)
5°(Г)
Дж . К . моль
22.210
25.500
27.112
27.147
28.903
31.033
31.160
29.415
28.663
28.249
28.043
27.957
27.945
27.979
28.044
28.130
28.229
28.339
28.455
28.575
28.698
28.822
28.947
29.071
29.195
29.318
29.439
29.559
29.676
29.792
29.905
30.015
30.123
30.228
30.331
30.431
30.528
30.622
30.713
30.801
30.886
30.968
31.047
31.123
31.196
31.266
31.333
31.396
31.457
31.514
10.840 24.020
21.970 40.670
29.973 51.180
30.104 51.348
36.459 59.398
41.730 66.065
41.979 66.381
41.979 80.626
48.498 85.619
54.123 90.003
58.848 93.760
62.914 97.057
66.478 100.002
69.649 102.666
72.503 105.103
75.099 107.351
77.478 109.439
79.674 111.391
81.714 113.223
83.619 114.952
85.406 116.589
87.088 118.144
88.678 119.625
90.186 121.041
91.619 122.396
92.986 123.696
94.292 124.947
95.542 126.151
96.742 127.313
97.895 128.435
99.005 129.520
100.076 130.571
101.109 131.591
102.109 132.580
103.076 133.542
104.013 134.477
104.923 135.386
105.806 136.273
106.664 137.137
107.499 137.979
108.312 138.802
109.104 139.605
109.877 140.390
110.630 141.158
111.366 141.909
112.085 142.644
112.788 143.363
113.475 144.068
114.148 144.759
114.806 145.436
АуЯ°@)= 301.308
Я°(Г)-Я°@)
кДж ¦ моль
1.318
3.740
6.323
6.373
9.176
12.167
12.326
19.521
22.273
25.116
27.929
30.729
33.523
36.319
39.120
41.929
44.746
47.575
50.414
53.266
56.129
59.005
61.894
64.795
67.708
70.634
73.572
76.521
79.483
82.457
85.441
88.438
91.444
94.462
97.490
100.528
103.576
106.633
109.700
112.776
115.860
118.953
122.054
125.162
128.278
131.401
134.531
137.668
140.811
143.959
-151.4311
-72.5675
-46.6463
-46.3209
-33.2225
-25.3793
-25.0609
-25.0609
-20.2762
-16.6377
-13.9073
-11.7810
-10.0773
-8.6810
-7.5153
-6.5274
-5.6793
-4.9434
-4.2989
-3.7297
-3.2235
-2.7705
-2.3627
-1.9938
-1.6584
-1.3524
-1.0720
-.8142
-.5765
-.3566
-.1525
.0372
.2141
.3793
.5340
.6791
.8154
.9438
1.0648
1.1790
.287!
1.3894
1.4864
.5784
.6659
.7492
.8285
.9041
.9762
2.0451
кДж • моль"'
Т
К
100
200
298.15
300
400
500
505.118
505.118
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
О\
»с
ОС
II
1
1
•ч-
ОО
ГО
о
+
1
н
S
го
—1
о
о
о
S
с-
i
II
?
0
•9"
Таблица 496
I
л
о
1
О !^
|| Ч
о -Я Р
11 - 5
t—f ™ •*"*
X <N II
С *. 0 W '
от сГ to
о 5^
а; о
•
+
о\
«—)
00
1 1
с: 0" гч _
'•МО
.1181
Lх~
)ЛЬ~
ООК)
l s г s ;
К V | Г" V
-Ч w I 1 V
? v -s « „
\Л |/Ч ^ Г* ^Ц
Т ^J 2L V .
"! 1 °° р 1
\О ОО . ^н »П
^* О\ Ю Г^- О
00 ГЧ (N * >О
+ • •» + . • »¦
н Т г- ' «
ОО 2 <* «О 2
Г-- *^ т-j (N *^
Tf f*4 ro О ^
i З и + 3
0
•е-
293

Класс точности
I
ОЛОВО Sn (г)
Таблица 497
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
, 1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
9200
2300
2400
2500
2600
2700
2800"
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;т
S°(T)
Дж • К . моль
Я°(Г)-Я°@)
кДж • моль
20.786
20.805
21.259
21.277
22.887
25.327
27.880
30.057
31.652
32.640
33.096
33.134
32.880
32.439
31.896
31.312
30.728
30.169
29.648
29.172
28.740
28.353
28.006
27.695
27.417
27.166
26.940
26.735
26.548
26.376
26.218
26.071
25.934
25.805
25.684
25.569
25.461
25.357
25.258
25.164
25.073
24.986
24.902
24.821
24.744
24.669
24-.5Э7
24.529
24.463
24.399
24.339
24.282
24.227
24.175
24.127
24.081
24.039
24.000
23.964
23.932
23.903
124.822
139.230
147.536
147.665
153.694
158.467
162.497
166.039
169.233
172.157
174.859
177.371
179.715
181.909
183.969
185.905
187.731
189.454
191.085
192.631
194.099
195.496
196.827
198.098
199.313
200.477
201.593
202.665
203.695
204.687
205.644
206.566
207.458
208.320
209.154
209.962
210.746
211.506
212.244
212.962
213.660
214.339
215.000
215.644
216.272
216.8Я5
217.483
218.067
218.637
219.195
219.740
220.274
220.796
221.307
221.807
222.298
222.779 .
223.250
223.713
224.167
224.612
145.608
160.017
168.380
168.512
174.825
I80.18S
185.032
189.500
193.625
197.416
200.882
204.041
206.915
209.530
211.915
214.096
216.098
217.944
219.653
221.243
222.728
224.121
225.432
226.670
227.843
228.957
230.018
231.031
232.000
232.928
233.820
234.677
235.502
236.298
237.067
237.810
238.528
239.225
239.900
240.554
241.190
241.808
242.409
242.994
243.564
244.119
244.661
245.189
245.705
246.208
246.701
247.182
247.653
248.114
248.566
249.008
249.441
249.867
250.284
250.693
251.095
2.079
4.158
6.215.
6.254
8.453
10.859
13.521
16.423
19.513
22.733
26.023
29.338
32.641
35.908
39.125
42.285
45.387
48.432
51.422
54.363
57.258
60.113
62.930
65.715
68.470
71.199
73.905
76.588
79.252
81.898
84.528
87.142
89.742
92.329
94.904
97.466
100.018
102.559
105.089
107.610
110.122
112.625
115.119
И 7.605
120.084
! 22.5-54
125.018
127.474
129.923
132.367
134.803
137.234
139.660
142.080
144.495
146.905
149.311
151.713
154.111
156.506
158.898
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
II
о
с"
00
298
Sn. г.
и
о К
to
о
V
V
о
294

ОЛОВО Sn (г)
Т а О л и ц а 497
(окончание)
т
к
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
с; сп
23.856
23.823
23.807
23.806
23.821
23.853
23.902
23.968
24.050
24.150
24.266
24.398
24.546
24.709
24.886
25.077
25.281
25.496
25.723
25.960
Ф°(Г)
Дж . К • моль
225.479
226.316
227.125
227.907
228.665
229.399
230.112
230.804
231.477
232.131
232.769
233.390
233.996
234.587
235.164
235.729
236.281
236.821
237.350
237.868
S°(T)
251.878
252.635
253.368
254.078
254.768
255.440
256.094
256.732
257.356
257.966
258.564
259.150
259.726
260.292
260.849
261.398
261.940
262.474
263.002
263.524
Н°(Т)-Н°@)
кДж . моль"
163.674
168.441
173.204
177.965
182.727
187.494
192.270
197.056
201.858
206.678
211.519
216.385
221.279
226.204
231.164
236.160
241.195
246.273
251.395
256.563
К
6200
6400
6600
680П
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
о
о
к
t
m
ci"
m
+
^o
сг%
ё
¦*
о
г-
о
о
Е-ч О
Я 2
5 V
V
о
о
о
295

Класс точности
I-A
ПОЛОЖИТЕЛЬНЫЙ ИОН ОЛОВА Sn+ (r)
Таблица 498
Ar№@) = -708.580 кДж • моль
с°рт
Ф° (Г)
5°(Г)
Дж • К . моль
Я°(Г)-Я°@)
кДж . моль
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
20.786
20.786
20.787
20.798
20.851
20.989
21.250
21.641
22.146
22.733
23.363
23.999
24.609
25.169
25.663
26.083
26.426
26.694
26.890
27.022
27.096
27.120
27.102
27.048
26.966
26.860
26.736
26.599
.26.451
26.296
26.137
25.976
25.814
25.652
25.493
25.336
25.183
25.033
24.888
24.747
24.61)
24.480
24.353
24.232
24.115
24.003
23.895
23.792
23.693
23.599
23.508
23.422
23.340
23.261
23.187
23.115
23.048
22.984
22.923
153.292
153.421
159.401
164.039
167.829
171.035
173.816
176.275
178.483
180.491
182.337
184.049
185.648
187.152
188.572
189.919
191.202
192.428
193.601
194.726
195.807
196.848
197.852
198.820
199.756
200.660
201.536
202.384
203.206
204.003
204.778
205.530
206.260
206.971
207.663
208.337
208.993
209.632
210.256
210.864
211.457
212.037
212.603
213.157
213.698
214.227
214.745
215.252
215.748
216.234
216.710
217.177
217.635
218.084
218.524
218.956
219.381
219.798
220.207
174.078
174.207
180.187
184.826
188.621
191.845
194.663
197.187
199.492
201.630
203.635
205.530
207.331
209.049
210.689
212.258
213.759
215.195
216.570
217.885
219.144
220.349
221.503
222.609
223.668
224.684
225.658
226.594
227.494
228.358
229.191
229.992
230.766
231.512
232.232
232.928
233.602
234.254
234.886
235.499
236.093
236.671
237.232
237.778
238.310
238.827
239.331
239.823
240.303
240:771
241.228
241.675
242.112
242.540
242.958
243.368
243.769
244.163
244.548
6.197
6.236
8.314
10.394
12.475
14.567
16.677
18.821
21.009
23.253
25.557
27.926
30.356
32.846
35.388
37.976
40.602
43.259
45.938
48.634
51.341
54.052
56.763
59.471
62.172
64.864
67.544
70.210
72.863
75.500
78.122
80.728
83.317
85.890
88.448
90.989
93.515
96.026
98.522
101.003
103.471
105.926
108.367
110.797
113.214
115.620
118.015
120.399
122.773
125.138
127.493
129.839
132.178
134.508
136.830
139.145
141.453
143.755
146.050
123.8337
123.0615
91.9085
73.1673
60.6445
51.6823
44.9496
39.7055
35.5045
32.0626
29.1902
26.7559
24.6659
22.8512
21,2601
19.8532
18.5997
17.4756
16.4613
15.5413
14.7027
13.9349
13.2293
12.5783
11.9757
11.4163
10.8953
10.4089
9.9537
9.5266
9.1252
8.7470
8.3901
8.0527
7.7332
7.4301
7.1422
6.8684
6.6075
6.3587
6.1211
5.8940
5.6767
5.4684
5.2687
5.0771
4.8929
4.7158
4.5453
4.3812
4.2229
4.0702
3.9229
3.7805
3.6429
3.5098
3.3809
3.2561
3.1352
298.15
300
400
500
600
700
800
900
1000
I 100
1200
1300
1400
1500
1600
1700
1800
1900
2000.
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
ОС
ОС
ОС
Os'
о
о
II
о
о
о
о
о
006
о .
н
JS
.765
ГЛ
V
V
о
о
ЧО
О
296

ПОЛОЖИТЕЛЬНЫЙ ИОН ОЛОВА Sn+ (г)
Таблица 4^
(окончание)
Ф°(П
S°(T)
к
п 1/-"
Дж . К
кДж • моль
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
22.81 1
22.712
22.625
22.550
22.486
22.434
22.393
22.363
22.344
22.336
22.339
22.352
22.377
22.413
22.459
22.515
22.583
22.661
22.749
22.848
221.004
221.775
222.520
223.242
223.941
224.620
225.278
225.918
226.540
227.145
227.735
228.309
228.869
229.416
229.949
230.470
230.979
231.477
231.965
232.442
245.298
246.021
246.718
247.393
248.045
248,678
249.292
249.889
250.470
251.035
251.587
252.125
252.651
253.166
253.670
254.164
254.649
255.126
255.594
256.054
150.623
155.175
159.709
164.226
168.729
173.221
177.703
182.179
186.649
191.117
195.584
200.053
204.526 .
209.005
213.492
217.989
222.499
227.023
231.564
236.123
2.9043
2.6867
2.4814
2.2872
2.1032
.9287
.7629
.6050
.4546
.3110
.1739
.0427
.9171
.7967
.6811
.5701
.4634
.3607
.2618
.1665
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
X
о
и,
о
о
V
V
297

Класс точности
VK
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
33.929
36.460
37.859
37.897
40.777
44.625
48.022
50.182
51.093
51.097
50.567
49.785
48.924
48.083
47.310
46.625 -
46.031
45.522
45.091
44.726
44.414
44.145
43.908
43.692
43.487
43.287
43.085
42.874
42.652
42.416
42.162
41.892
41.604
41.298
40.976
40.639
40.289
39.927
39.555
39.176
38.789
38.399
38.006
37.61
37.217
36.825
36.435
36.049
35.668
35.292
34.922
34.559
34.203
33.854
33.514
33.181
32.857
32.541
32.233
31.933
31.642
К°(Т)= p2(Sn)
Ф°(Г)
Дж • К . миль
190.576
212.731
226.224
226.437
236.511
244.613
251.507
257.575
263.022
267.970
272.496
276.660
280.507
284.077
287.401
290.508
293.421
296.160
298.744
301.188
303.505
305.708
307.806
309.808
311.722
313.556 •
315.316
317.006
318.632
320.199
321.710
323.169
324.579
325.943
327.264
328.543
329.784
330.988
332.157
333.293
334.397
335.470
336.515
337.533
338.524
339.490
340.431
341.350
342.246
343.120
343.975
344.809
345.624
346.421
347.200
347.962
348.708
349.438
350.152
350.852
351.538
ДИОЛОВО Sn2 (г)
p"'(Sn2)
sV)
1
221.369
245.877
260.670
260.904
272.162
281.671
290.122
297.704
304.477
310.502
315.861
320.646
324.941
328.823
332.358
335.598
338.588
341.362
343.952
346.380
348.666
350.826
352.874
354.821
356.676
358.447
360.141
361.763
363.319
364.812
366.245
367.623
368.949
370.224
371.452
372.635
373.775
374.874
375.934
376.957
377.944
378.897
379.817
380.707
381.567
382.399
383.204
383.983
384.738
385.470
386.179
386.867
387.535
388.183
388.812
389.424
390.019
390.598
391.161
391.709
392.244
Д А
г
//°(Л-Я°@)
кДж . моль
3.079
6.629
10.270
10.340
14.260
18.529
23.169
28.091
33.164
38.279
43.366
48.384
53.320
58.170
62.939
67.635
72.267
76.844
81.374
85.864
90.321
94.749
99.151
.103.531
107.890
112.229
116.547
120.845
125.122
129.375
133.604
137.807
141.982
146.127
150.241
154.322
158.368
162.379
.166.353
170.290
174.188
178.047
181.868
185.648
189.390
193.092
196.754
200.379
203.964
207.512
211.022
214.496
217.934
221.337
224.705
228.040
231.341
234.611
237.849
241.057
244.236
Г°@)= 186.000
-94.0698
-45.1443
-28.9898
-28.7865
-20.5866
-15.6534
-12.3540
-9.9877
-8.2036
-6.8072
-5.6819
-4.7538
-3.9739
-3.3083
-2.7329
-2.2302
-1.7869
-1.3927
-1.0398
-.7219
-.4339
-.1717
.0681
.2883
.4912
.6789
.8531
1.0151
1.1663
1.3078
1.4404
1.5651
1.6825
1.7933
1.8981
1.9973
2.0915
2.1810
2.2661
2.3473
2.4249
2.4989
2.5699
2.6378
2.7030
2.7656
2.«259
2.8838
2.9397
2.9935
3.0455
3.0958
3.1444
3.1914
3.2369
3.2811
3.3239
3.3655
3.4059
3.4451
3.4833
кДж ¦ моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 499
i
А
™ О
с; ¦ 7
2 а к
х °
х <~* Т
2 — "^
СО ЧО "* ^
? ;? д 5
гч и «-> 5 ¦
и ^— ""¦ _;
О СО ^
S - о* m
"Н 1 Г ||
" М ^
-
X _,
~~* ' л
"" О
+ 7
I
7 а
i
? s| ¦§
О СО \ /
do V
1 $ *-
с ' V
—' гч &
он °
О ГЧ ^
--< о . „
СО 00 V
\О ¦ •* 'о
чо ^-
+ + 
О К f«.
р о> "
^ о\ ^
¦* *"
II 1
ь.
о
298

Класс точжн
VII-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1250
1250
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
•3000
3100
3200
"ГИ
с;(г)
24.160
39.860
47.783
47.808
49.164
50.520
51.876
53.232
54.588
55.944
57.300
58.656
60.012
60.690
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
63.000
Л°(Г) = РC„О)
Ф°(Г)
Дж • К . моль
6.510
17.680
27.869
28.051
37.222
45.207
52.224
58.476
64.118
69.266
74.007
78.408
82.520
84.481
84.481
87.238
92.419
97.209
101.663
105.824
109.729
113.408
116.884
120.180
123.312
126.297
129.147
131.874
134.488
136.998
139.412
141.738
143.981
146.146
148.241
ОКСИД
S°(T)
1
17.430
39.540
57.170
57.466
71.405
82.521
91.852
99.950
107.147
113.655
119.619
125.144
130.306
132.770
154.930
157.401
162.069
166.416
170.482
174.301
177.902
181.308
184.540
187.614
190.544
193.345
196.026
198.598
201.069
203.447
205.738
207.948
210.084
212.150
214.150
ОЛОВА SnO (к
, ж)
Д^Я°@) = 302.482
Я°G*)-Я°@)
кДж . моль**
1.092
4.373
8.736
8.824
13.673
18.657
23.777
29.032
34,423
39.950
45.612
51.410
57.343
60.361
88.061
91.211
97.511
103.811
ПОЛИ
116.411
122.711
129.011
135.311
141.611
147.911
154.211
160.511
166.811
173.111
179.411
185.711
192.011
198.311
204.611
210.911
-149.4397
69.9712
-43.8835
-43.5566
-30.4169
-22.5748
-17.3748
-13.6811
-10.9271
-8.7983
-7.1066
-5.7322
-4.595 5
¦4.0984
-4.0984
-3.6859
-2.95 50
-2.3278
-1.7846
-1.3103
-0.8929
-0.5234
-0.1943
0.1003
0.3653
0.6046
0.8216
1.0191
1.1994
1.3645
1.5161
1.6557
1.7844
1.9036
2.0138
кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1250
1250
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
1
оо
С")
и
•§.
+ 0.49078л"' +
ч
S
о
г-
со
= 1бз.о:
g
о
¦е-
Та
i
л
с;
|
ОО
г--
00
г-
1
II
о
X
с
Е/Э
0
<*.
<]
моль"
1
л
ОО
блица
i
А
О
к
X
о
О
оо
1
II
я
«о
ОО*
сч
О
С
С/3
0
7
g
v g
"ч 6
оо- Я
CN Ч©
'° m
*г °^
II СЧ
"-^ II
g
О
S00
i
л
К
о
1
CN
VO
II
о §
to
< 32ООК)
V
О
сч
То
и
299

Класс точности
П-Е
Г
К .
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
29.115
29.933
31.759
31.794
33.421
34.563
35.343
35.885
36.275
36.566
36.790
36.968
37.113
37.235
37.339
37.431
37.512
37.586
37.654
37.718
37.778
37.837
37.895
37.954
38.015
38.080
38.149
38.226
38.313
38.411
38.523
38.652
38.800
38.970
39.164
39.385
39.636
39.918
40.233
40.583
40.970
41.394
41.856
42.357
42.897
43.474
44.089
44.740
45.425
46.143
46.891
47.667
48.467
49288
50.128
50.982
51.846
52.718
53.592
54.465
55.332
ОКСИД ОЛОВА SnO (г)
К°(Т) = р (Sn) • р (О) • р~ '(SnO)
Ф°(Г)
Дж . К • моль
170.361
190.516
202.265
202.449
211.106
217.984
223.727
228.673
233.026
236.916
240.436
243.650
246.609
249.351
251.906
254.298
256.548
258.670
260.680
262.588
264.405
266.139
267.797
269.386
270.911
272.377
273.790
275.152
276.467
277.739
278.970
280.164
281.321
282.445
283.538
284.601
285.637
286.646
287.631
288.592
289.531
290.449
291.348
292.228
293.091
293.936
294.766
295.581
296.382
297.170
297.944
298.707
299.459
300.200
300.930
301.651
302.363
303.066
303.760
304.447
305.126
S°(T)
1
199.380
219.719
232.003 ¦
232.200
241.581
249.169
255.544
261.036
265.854
270.144
274.009
277.524
280.748
283.723
286.486
289.066
291.484
293.760
295.911
297.948
299.884
301.729
303.491
305.176
306.793
308.346
309.841
311.282
312.674
314.020
315.324
316.589
317.819
319.015
320.181
321.320
322.433
323.522
324.591
325.640
326.673
327.690
328.693
329.683
330.663
331.634
332.596
333.551
334.500
335.444
336.384
337.320
338.253
339.184
340.113
341.041
341.967
342.892
343.817
344.741
345.663
ДгЯ°@)= 524.391
Я°(Г)-Я°@)
кДж • моль
2.902 -270.3461
5.841 -132.8775
8.866 -87.4999
8.925 -86.9289
12.190 -63.9030
15.593 -50.0583
19.091 -40.8074
22.654 -34.1826
26.263 -29.1999
29.905 -25.3125
33.574 -22.1928
37.262 -19.6321
40.966 -17.4915
44.684 -15.6746
48.413 -14.1126
52.151 -12.7550
55.898 -11.5640
59.653 -10.5104
63.415 -9.5715
67.184 -8.7295
70.959 -7.9700
74.740 -7.2814
78.526 -6.6541
82.319 -6.0802
86.117 -5.5532
89.922 -5.0674
93.733' -4.6182
97.552 -4.2015
101.379 -3.8139
105.215 -3.4525
109.061 -3.1147
112.920 -2.7981
116.792 -2.5010
120.681 -2.2214
124.587 -1.9579
128.514 -1.7091
132.465 -1.4738
136.443 -1.2510
140.450 -1.0397
144.490 -.8390
148.568 -.6481
152.686 -.4663
156.848 -.2931
161.058 -.1278
165.321 .0301
169.639 .1811
174.017 .3255
178.458 .4639
182.966 .5966
187.544 .7238
192.196 .8460
196.923 .9633
201.730 1.0761
206.617 1.1846
211.588 1.2891
216.643 1.3896
221.785 1.4865
227.013 1.5799
232.328 1.6700
237.731 1.7569
243.221 1.8408
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 501
-
'-0
1 -
¦а ? Т.
• мол
кДж
МОЛ1
ч °, '
О f^l '
00 (^ || ?^
i> «з я я
—1 II "> —<
" S « 2
^ uT ^
5 <-Г о «
? с to
о 52-
а: о
7
j* i
t- о
"*. S
о
+ 7
? ь*
с * Я
? Е[ О
On §
§ s v
¦* 5 v
? г, О
о ? "¦>
. 1
"Т" I •
Pi "*¦ " ¦
*¦< rt -is
го "^ W
0
в
300

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
1903
1903
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
С°р(Т)
19.250
40.380
53.219
53.540
65.087
70.827
74.281
76.656
78.457
79.922
81.180
82.303
83.332
84.297
85.215
86.098
86.954
87.789
88.609
89.416
89.440
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
92.000
ДИОКСИД ОЛОВА SnO2 (к,
К°(Т)= p(SnO2)
Ф°(Г)
Дж • К~ . моль™
3.072
11.589
20.890
21.064
30.319
39.120
47.353
55.007
62.119
68.742
74.930
80.732
86.191
91.345
96.226
100.863
105.278
109.495
113.529
117.399
117.512
117.512
121.715
125.858
129.823
133.625
137.277
140.790
144.175
147.440
150.593
153.643
156.594
159.455
162.229
164.922
167.539
170.084
172.560
174.971
177.322
179.613
181.849
184.032
186.165
188.249
190.287
5°(Г)
10.012
30.284
49.010
49.340
66.547
81.749
94.990
106.629
116.987
126.315
134.803
142.593
149.799
156.508
162.789
168.698
174.282
179.579
184.620
189.433
189.574
201.870
206.444
210.933
215.213
219.302
223.218
226.973
230.582
234.054
237.400
240.628
243.747
246.764
249.684
252.515
255.262
257.929
260.520
263.041
265.495
267.884
270.214
272.485
274.702
276.867
278.982
Я°(Г>-Я°@)
кДж ¦ моль
.694
3.739
8.384
8.483
14.491
21.315
28.583
36.136
43.895
51.816
59.872
68.047
76.330
84.712
93.188
101.754
110.406
119.144
127.964
136.865
137.133
160.533
169.457
178.657
187.857
197.057
206.257
215.457
224.657
233.857
243.057
252.257
261.457
270.657
279.857
289.057
298.257
307.457
316.657
325.857
335.057
344.257
353.457
362.657
371.857
381.057
390.257
Ж)
'°@) = 531.009
«V,
-268.4509
-129.0043
-83.0502
-82.4728
-59.2245
-45.3048
-36.0507
-29.4613
-24.5360
-20.7190
-17.6770
-15.1978
-13.1404
-11.4070
-9.9279
-8.6519
-7.5408
-6.5652
-5.7026
-4.9348
-4.9131
-4.9131
-4.2789
-3.6901
-3.1583
-2.6758
-2.2363
-1.8347
-1.4663
-I.I275
-.8149
-.5258
-.2577
-.0087
.2232
.4396
.6419
.8313
.0090
.1759
.3328
.4807
.6202
.7520
.8765
.9944
2.1062
кДж • моль
т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
1903
1903
2000
2100
=8200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
Ov
00
¦ с
II
1
СП
с
1
—
С
1
ч
J5
3
Г*-
CN
•Л
г-
г*
(N
II
Табли
ОЛЬ
%
L
м
о
«о
1
II
о
1
1
о
S
1
н
+ 36.82
Р
*••
О
i
ч
2
¦
X
о
vq
с^
t—
v>
1
II
я
1—1
00
„
С
Й
Q
а:
<J
3
о
2
V
t-i
V
00
гч
?о
Е-,
II
ца
—1
§
-'
¦
'>(
(S
«о
+
X
о
r-j
О\
сч
fN
гч
II
О
502
"л
В
о
i
00
"
о S
1
¦ч-
V
V
То .
II
301

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сп
36.296
44.181
49.547
49.633
53.465
55.971
57.614
58.722
59.494
60.050
60.462
60.774
61.016
61.207
61.361
61.486
61.589
61.675
61.747
61.809
61.861
61.907
61.946
61.981
62.01
62.038
62.062
62.084
62.103
62.120
62.135
62.149
62.162
62.174
62.184
62. .94
62.203
62.211
62.219
62.226
62.232
62.238
62.244
62.249
62.254
62.259
62.263
62.267
62.271
62.274
62.278
62.281
62.284
62.286
62.289
62.291
62 294
62.296
62.298
62.300
62.302
ДИОКСИД ОЛОВА SnO2 (г)
,V) = P(Sn).
Ф°(Г)
Дж . К . моль
173.754
196.889
211.935
212.179
224.006
233.792
242.189
249.564
256.146
262.093
267.519
272.509
277.129
281.429
285.452
289.230
292.793
296.163
299.360
302.402
305.302
308.073
310.726
313.271
315.716
318.069
320.337
322.525
324.639
326.683
328.663
330.582
332.443
334.251
336.007
337.716
339.379
340.999
342.577
344.117
345.620
347.08"
348.521
349.922
351.293
352.634
353.947
355.233
356.493
357.728
358.939
360.126
361.292
362.436
363.560
364.664
365.748
366.815
367.863
368.893
369.908
p2(O)-p~'(SnO2) Дг#°@) = 834.874
S°(T)
1
204.944
232.806
251.496
251.803
266.644
278.864
289.224
298.194
306.088
313.129
319.479
325.256
330.555
335.447
339.989
344.227
348.198
351.935
355.462
358.802
361.974
364.993
367.874
370.629
373.267
375.799
378.233
380.576
382.834
385.013
387.120
389.157
391.131
393.044
394.900
396.703
398.455
400.159
401.818
403.435
405.010
406.547
408.047
409.511
410.943
412.341
413.710
415.049
416.360
417.644
418.902
420.135
421.345
422.531
423.696
424.839
425.961
427.064
428.147
42С212
430.259
Н °(Т)-Н ° @)
кДж • моль
3.119 -426.7584
7.183 -207.5427
11.795 -135.1709
11.887 -134.2604
17.055 -97.5480
22.536 -75.4871
28.221 -60.7589
34.041 -50.2231
39.954 -42.3087
45.933 -36.1428
51.959 -31.2017
58.022 -27.1521
64.112 -23.7719
70.223 -20.9071
76.352 -18.4479
82.495 -16.3135
88.648 -14.4434
94.812 -12.7912
100:983 -11.3209
107.161 . -10.0038
113.344 -8.8173
119.533 -7.7427
125.726 -6.7648
131.922 -5.8712
138.122 -5.0513
144.324 -4.2965
150.529 -3.5991
156.736 -2.9529
162.946 -2.3524
169.157 -1.7930
175.370 -1.2704
181.584 -.7813
187.800 -.3224
194.016 .1090
200.234 .5152
206.453 .8985
212.673 1.2608
218.894 1.6036
225.115 1.9286
231.338 2.2372
237.560 2.5305
243.784 2.8097
250.008 3.0757
256.233 3.3295
262.458 3.5719
268.684 3.8038
274.910 4.0256
281.136 4.2382
287.363 4.4420
293.590 4.6376
299.818 4.8256
306.046 5.0062
312.274 5.1801
318.502 5.3475
324.731 5.5088
330.960 5.6643
337.189 5.8144
343.419 5.9593
349649 6.0993
355.879 6.2346
362.109 6.3656
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2Э00
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 503
i
А
С
т §
ё
? я.
X о |
О ^f Ьй
О ! .
1 ? 1 &
1 ,! g 5
¦-* г-. *"^ <N
11 °. ' о? ^
^ U (N ""¦
ri U "
О - _г
? о °«
0 С/3
< *-.
+
00 ^
- §
+ 1
? -.¦
Я '* Я
"t О
w-> * О
От \/
я ~ |
2 s 'о
1 " К
»¦ г -
OS Ч
II +
0
в
302

Класс точности
Н-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5510
5600
5700
5800
5900
6000
С°(Л
Р
29.250
31.455
33.704
33.738
35.233
36.375
37.401
38.346
39.178
39.871
40.416
40.823
41.108
41.295
41.403
41.451
41.457
41.431
41.386
41.327
41.261
41.193
41.126
41.062
41.002
40.949
40.902
40.863
40.832
40.810
40.795
40.790
40.792
40.804
40.823
40.851
40.887
40.931
40.983
41.04!
41.107
41.179
41.257
41.341
41.430
41.523
41.620
41.720
41.823
41.928
42.034
42.141
42.248
42.354
42.46и
42.563
42.564
42.76°
42.857
42.948
43.034
К (Т) - р (Sn) •
Ф°(Л
Дж • К . моль
178.543
198.842
210.864
211.053
220.010
227.160
233.146
238.315
242.879
246.974
250.693
254.104
257.256
260.187
262.926
265.497
267.920
270.210
272.382
274.445
276.412
278.289
280.085
281.805
283.457
285.046
2Я6.574
288.048
289.471
290.846
292.176
293.464
294.714
295.925
297.102
298.246
299.359
300.442
301.498
302.527
303.531
304.511
305.468
306.404
307.318
308.214
309.090
309.948
310.789
31 1.613
312.422
313.215
313.994
314.759
315.510
316.248
316.974
317.687
318.389
319.080
319.759
ФТОРИД ОЛОВА SnF (г)
o(F).p~\SnF)
5°(Л
1
207.654
228.499
241.506
241.715
251.639
259.627
266.351
272.188
277.364
282.020
286.251
290.123
293.688
296.986
300.051
302.909
305.585
308.098
310.464
312.701
314.819
316.830
318.745
320.572
322.318
323.991
325.596
327.139
328.624
330.057
331.440
332.777
334.072
335.328
336.546
337.730
338.881
340.002
341.094
342.160
343.200
344.216
345.209
346.180
347.132
348.064
348.978
349.874
350.753
351.617
352.465
353.298
354.118
354.923
355.716
356.496
357.264
358.020
358.764
359.498
360.220
Я°(Г)-Я°@)
кДж . моль
2.911
5.931
9.136
9.199
12.652
16.234
19.923
23.711
27.588
31.542
35.558
39.621
43.718
47.839
51.975
56.118
60.263
64.408
68.549
72.685
76.814
80.937
85.053
89.162
93.265
97.363
101.455
105.543
109.628
113.710
117.790
121.870
125.949
130.028
134.1 10
138.193
142.280
146.371
150.467
154.568
158.675
162.789 '
166.91 1
171.041
175.180
179.327
183.484
187.651
191.828
196.016
200.214
204.423
208.642
212.872
217.113
221.364
225.625
229.897
234.178
238.468
242.767
<°@) = 472.000
«V,
-243.4211
-119.6932
-78.8548
-78.3410
-57.6183
-45.1580
-36.8317
-30.8690
¦26.3846
-22.8866
-20.0800
-17.7771
-15.8526
-14.2199
-12.8169
-11.5981
-10.5293
-9.5842
8.7425
-7.9880
-7.3077
-6.6912
-6.1298
-5.6164
-5.1451
-4.7108
-4.3094
-3.9372
-3.5912
-3.2685
-2.9670
-2.6846
-2.4195
-2.1702
-
-
-
-
.9353
.7136
.5039
.3054
.1 171
-.9383
-.7683
-.6064
-.4521
-.3048
-.164!
-.0295
.0993
.2227
.3410
.4546
.5638
.6687
.7696
.8668
.9604
.0507
.1378
.2218
.3030
.3815
.4574
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 504
i
к
^ i 7
§ 5 ~
L * 1
Ъ? (—
-м °- 7
* J ii J| .
И ^ ¦ —
-— и
*С ^J OK
'С. "с ^
'—• 5:
1
1
-о
ОС
-а- -
о ^
1 О
1 „¦ ^
г~- • О
S с* "°
= m V
О 1 ^
i « v
с те о
— о
" S ,
0
303

Класс точности
VII -Е
ДИФТОРИД ОЛОВА SnF2 (к, ж)
Таблица 505
К°(Т)= p(SnF2)
Д5//°@) = 168.000 кДж ¦ моль"
C°iT)
Ф°(Г)
S°(T)
Дж ¦ К ¦ моль
Я°(Г)-Я°@)
кДж . моль
298.15
300
400
488.2
488.2
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
72.395
72.505
78.450
83.693
100.000
100.000
100.000
100.000
100.000
юо-.ооо
100.000
100.000
100.000
100.000
100.000
100.000
100.000
100.000
48.573
48.868
63.616
74.990
74.990
76.929
92.065
105.269
116.964
127.452
136.956
145.643
153.640
161.049
167.949
174.407
180.473
186.194
96.200
96.648
118.321
134.458
155.965
158.354
176.586
192.001
205.354
217.132
227.668
237.199
245.900
253.905
261.315
268.215
274.669
280.731
14.200
14.334
21.882
29.032
39.532
40.712
50.712
60.712
70.712
80.712
90.712
100.712
110.712
120.712
130.712
140.712
150.712
160.712
19.3839
19.2045
12.0251
-8.1918
-8.1918
-7.8120
-5.2351
-3.4501
-2.1524
-1.1746
-.4175
.1816
.6639
1.0578
1.3832
1.6547
1.8831
2.0764
298.15
300
400
488.2
48t>.2
500
600
700
800
900
1000
1100'
1200
1300
1400
1500
1600
1700
x
о
о
о
II'
2
00 _
U. о «
а;
<
г V
н
I
V
V 00
Л ON
в."
о
+
о
+
Zi м
V
V
То
304

Класс точности
V Г
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
37.842
44.612
49.679
49.751
52.730
54.445
55.487
56.158
56.611
56.931
57.164
57.339
57.473
57.579
57.663
57.731
57.787
57.834
57.873
57.906
57.935
57.959
57.981
57.999
58.016
58.030
58.043
58.054
58.065
58.074
58.082
58.090
58.096
58.103
58.108
58.113
58.118
58.123
58.127
58.130
58.134
58.137
58.140
58.143
58.146
58.148
58.150
58.152
58.154
58.156
58.158
58.160
58.161
58.163
58.164
58.165
58.167
58.168
58.169
58.170
58.171
ДИФТОРИД ОЛОВА SnF2 (г)
К°{Т)= p(.Sn)-
Ф°(П
— 1 ""
Дж • К . моль
200.146
225.197
240.950
241.204
253.399
263.370
271.841
279.218
285.757
291.630
296.963
301.846
306.351
310.531
314.431
318.085
321.524
324.770
327.845
330.766
333.547
336.201
338.739
341.172
343.506
345.751
347.912
349.996
352.008
353.952
355.834
357.657
359.424
361.140
362.806
364.426
366.002
367.536
369.031
370.489
371.911
373.299
374.654
375.979
377.275
378.542
379,782
380 996
382.186
383.352
384.494
385.615
386.715
387.794
388.853
389.894
390.916
391.921
392.908
393.880
394.835
p2(F)-p '(SnF2) Д #°@) = 936.910
S°(T)
1
234.858
263.175
282.013
282.320
297.081
309.048
319.074
327.682
335.212
341.899
347.910
353.367
358.362
362.967
367.237
371.218
374.946
378.451
381.757
384.887
387.858
390.685
393.382
395.960
398.429
400.798
403.074
405.265
407.376
409.414
411.383
413.287
415.132
416.919
418.654
420.339
421.976
423.568
425.118
426.628
428.100
429.536
430.936
432.305
433:64!
434.948
436.226
437.477
438.701
439.900
441.075
442.227
443.356
444.464
445.551
446.619
447.667
448.696
449.708
450.702
451.680
Н°(Т)-Н°@)
кДж • моль
3.471 -481.4611
7.596 -235.7974
12.243 -154.7312
12.335 -153.7114
17.473 -112.5910
22.839 -87.8786
28.340 -71.3771
33.924 -59.5703
39.564 -50.6992
45.242 -43.7864
50.948 -38.2454
56.673 -33.7032
62.414 -29.9107
68.167 -26.6958
73.929 -23.9353
79.699 -21.5388
85.475 -19.4384
91.256 -17.5823
97.041 -15.9300
102.830 -14.4495
108.622 -13.1152
114.417 -11.9064
120.214 -10.8062
126.013 -9.8004
131.814 -8.8773
137.616 -8.0271
143.420 -7.2414
149.225 -6.5131
155.031 -5.8362
160.838 -5.2052
166.646 -4.6158
172.454 -4.0638
178.263 -3.5457
184.073 -3.0587
189.884 -2.5998
195.695 -2.1667
201.507 -1.7573
207.319 -1.3697
213.131 -1.0022
218.944 -.6532
224.757 -.3214
230.571 -.0055
236.385 .2957
242.199 .5830
248.013 -8576
253.828 1.1201
259.643 1.3715
265.458 1.6123
271.273 1.8433
277.089 2.0651
282.904 2.2781
288.720 2.4830
294.536 2.6801
300.352 2.8699
306.169 3.0528
311.985 3.2293
317.802 3.3995
323.619 3.5639
329.436 3.7227
335.252 3.8763
341.069 4.0249
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100.
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 5 06
'л
~ о
1 2
1 *
2 Ч
<N CC О
°. т . .
*—- т~Г tr is
^ Т ? р-
— " —. rf
II О g J^
5 с ""ч
С (Г* О <Я
ел ^ с^
1_ —
<! ч-.
+
н
¦S '-о
о ~
+ S
1 -.'
<~~ о
S ч §
к "*• V
с ° о
+ о
t— ,~
00 "Ч
о ч
ON f- *
|-- ¦ <& 'о
_, ! к
оо -S il
чо On
г-! ' " Й
5- —«
II +
о
305

Класс точности
II-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
ЗГОО
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
И
30.535
34.224
35.836
35.856
36.697
37.397
38.133
38.888
39.597
40.213
40.71
41.090
41.360
41.539
41.646
41.696
41.705
41.684
41.644
41.593
41.535
41.476
41.419
41.366
41.319
41.279
41.248
41.226
41.214
41.212
41.219
41.237
41.264
41.301
41.346
41.400
41.462
41.531
41.607
41.687
41.772
41.861
41.952
42.045
42.138
42.230
42.322
42.411 .
42.497
42.579
42.656
42.728
42.794
42.853
42.906
42.951
42.989
43.019
43.041
43.054
43.060
ХЛОРИД ОЛОВА SnCl (г)
К°(Т) =p(Sn) -p(Cl) -p'^SnCl)
Ф°(Г)
S°(D
Дж К .моль
187.481 216.865
208.314 239.292
220.953 253.301
221.153 253.523
230.608 263.962
238.133 272.225
244.404 279.108
249.796 285.043
254.535 290.283
258.773 294.984
262.610 299.247
266.121 303.146
269.358 306.734
272.362 310.052
275.165 313.134
277.794 316.010
280.267 318.701
282.603 321.229
284.816 323.611
286.917 325.861
288.918 327.993
290.828 330.018
292.653 331.946
294.402 333.786
296.080 335.546
297.692 337.231
299.244 338.850
300.740 340.406
302.184 341.905
303.579 343.351
304.928 344.748
306.234 346.100
307.501 347.410
308.729 348.680
309.923 349.914
311.082 351.113
312.211 352.280
313.309 353.417
314.379 354.526
315.423 355.608
316.441 356.664
317.434 357.697
318.405 358.707
319.354 359.695
320.282 360.663
321.189 361.611
322.078 362.540
322.949 363.451
323.802 364.345
324.638 365.222
325.459 366.083
326.264 366.928
327.054 367.758
327.829 368.574
328.591 369.376
329.340 370.163
330.076 370.937
330.800 371.699
331.511 372.447
332.211 373.183
332.900 373.906
ДгЯ°@) = 385.000 кДж • моль
Я°(Г)-Я°@)
кДж . моль
2.938
6.196
9.645
9.711
13.341
17.046
20.822
24.673
28.598
32.590
36.637
40.728
44.851
48.997
53.157
57.324
61.494
65.664
69.831
73.993
78.149
82.300
86.444
90.583
94.718
98.847
102.974
107.097
111.219
115.341
119.462
123.585
127.710
131.838
135.970
140.108
144.251
148.401
152.558
156.722
160.895
165.077
169.267
173.467
177.676
181.895
186.122
190.359
194.604
198.858
203.120
207.389
211.665
215.947
220.235
224.528
228.824
233.125
237.428
241.732
246.038
1еК°(Т)
-198.0387
-97.0711
-63.7604
-63.3414
-46.4437
-36.2823
-29.4895
-24.6219
-20.9584
-18.0983
-15.8017
-13.9157
-12.3385
-10.9994
-9.8479
-8.8469
-7.9686
-7.1917
-6.4993
-5.8784
-5.3183
-4.8105
-4.3479
-3.9248
-3.5362
-3.1780
-2.8469
-2.5397
-2.2541
-
-
1.9877
1.7387
1.5054
1.2864
1.0804
-.8863
-.7030
-.5297
-.3655
-.2098
-.0620
.0787
.2126
.3402
.4620
.5784
.6897
.7963
.8984
.9963
.0902
.1805
.2673
.3508
.4312
.5086
.5833
.6554
.7249
.7921
.8570
.9198
Г
К
100
200
298.15
300
400
500
600
700
800
900
• юоо
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 507
-
'л
- 1
• 'а • ¦ т-
о * et
? 1 1
* о ¦
Д \о 7
» ^ ж
2 ' S5 " Д
3; ? Я s
2 „ ¦ К 2
11 о °° Р!
w ° С* m
.? с <ч
.. - "
? 5 о §
•^ч О
< <ь
<J
1
^>
s ¦*
? §
« s
1 —'
3 \t Я
О\ • О
§ 5 2
°. « V
•s r 8
00 П
о х ••
оо <Ч У
« 3 <=
Z + ь
ГЛ СП "
W» СО ,
« § а
«л .
И 1
*•¦¦•>
w
0
306

Класс точности
VII-E
Т
К
100
200
298.15
300
400
500
520.2
520.2
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
С°р(Т)
58.500
72.750
78.051
78,150
83.532
88.913
90.001
110.000
110.000
110.000
110.000
110.000
110.000
110.00.0
110.000
110.000
110.000
110.000
110.000
110.000
110.000
ДИХЛОРИД ОЛОВА
K°(r)=p(SnCl2)
Ф°(Г)
Дж . К~1 . моль
25.690
54.415
75.975
76.335
93.906
108.659
111.382
111.382
125.364
140.723
154.212
166.235
177.079
186.953
196.016
204.390
212.173
219.442
226.262
232.683
238.752
S°(T)
Н
SnCI2 (к,
ж)
Д^,Я°@)= 134.000
°(П-Я°@)
кДж • моль
57.680
104.000
134.100
134.583
157.803
177.020
180.563
208.475
224.174
241.131
255.819
268.775
280.365
290.849
300.420
309.225
317.377
324.966
332.065
338.734
345.021
3.199
9.917
17.330
17.474
25.559
34.181
35.988
50.508
59.286
70.286
81.286
92.286
103.286
114.286
125.286
136.286
147.286
158.286
169.286
180.286
191.286
-60.1090
-25.1852
-13.8709
-13.7301
-8.1065
-4.8044
-4.2995
-4.2995
-2.8624
-1.5826
-.6720
-.0018
.5040
.8930
1.1965
1.4359
1.6262
1.7781
1.8997
1.9971
2.0747
кДж • моль"'
Т
К
100
200
298.15
300
400
500
520.2
520.2
600
700
800
900
1000
1 100
1200
1300
1400
1500
1600
1700
!800
с\
"">
00
II
3-
ч
1
н
кг
с.
1
и~
С
О
г—
ос
г-
rj
и
?
0
Та
-
О
'ж
00
m
!
"
О
[3
с
ел
0
1
т
¦
ее
р
ЧО
+
б Л И
с;
о
о
о
о
СП
1
II
'•/")
00
о.
ел
0
ч
:2О.2К
V
V
,
со
'2
[•-.
и
н
Ц а
О
Щ
i
¦4J*
i
+
о
о
О'
li
ь
0
508
7
я
о
„¦
1
го
оо
II
о ет
-
00К)
ОС
V
V
о
1
2
1!
307

Класс точности
V-F
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Ср(Т)
42.729
51.310
54.635
54.673
56.109
56.828
57.234
57.485
57.649
57.764
57.846
57.907
57.953
57.990
58.019
58.042
58.061
58.077
58.090
58.102
58.111
58.120
58.127
58.133
58.139
58.143
58.148
58.152
58.155
58.158
58.161
58.164
58.166
58.168
58.170
58.172
58.173
58.175
58.176
58.177
58.178
58.179
58.180
58.181
58.182
58.183
58.184
58.185
58.185
58.186
58.186
58.187
58.188
58.188
58.189
58.189
58.189
58.190
58.190
58.191
58.191
*V,-p(Sn),
Ф°(Г)
Дж ¦ К • моль
214.923
242.252
259.859
260.143
273.709
2Й4.679
263.898
301.852
308.847
315.090
320.728
325.867
330.589
334.957
339.020
342.817
346.381
349.740
352.916
355.927
358.790
361.520
364.126
366.621
369.013
371.311
373.522
375.651
377.706
379.690
381.609
383.467
385.268
387.014
388.709
390.357
391.959
393.518
395.036
396.516
397.959
399.367
400.742
402.086
403.399
404.683
405.939
407.169
408.373
409.553
410.709
411.843
412.955
414.047
415.118
416.170
417.203
418.218
419.2-16
42С.197
421.162
ДИХЛОРИД
5°(Г)
1
251.880
284.540
305.747
306.085
322.036
334.642
345.042
353.885
361.572
368.369
374.460
379.976
385.016
389.657
393.955
397.959
401.706
405.226
408.546
411.687
414.668
417.503
420.207
422.791
425.265
427.639
429.919
432.114
434.229
436.269
438.241
440.148
441.995
443.785
445.521
447.207
448.846
450.440
451.992
453.503
454.976
456.412
457.814
459.183
460.521
461.828
463.107
464.359
465.584
466.783
467.959
469.111
470.241
471.349
472.437
473.505
474.553
475.583
476.595
477.590
478.568
ОЛОВА SnCl2
H°{T)-H°{Q)
кДж . моль
3.696
8.458
13.681
13.783
19.331
24.981
30.686
36.423
42.180
47.951
53.732
59.520
65.313
71.110
76.910
82.713
88.519
94.325
100.134
105.943
111.754
117.566
123.378
129.191
135.005
140.819
146.633
152.448
158.264
164.079
169.895
175.711
181.528
187.344
193.161
198.979
204.796
210.613
216.431
222.248
228.066
233.884
239.702
245.520
251.338
257.156
262.975
268.793
274.612
280.430
286.249
292.068
297.886
303.705
309.524
315.343
321.162
326.981
332.800
338.619
344.438
(г)
Г°@) = 741.375
¦"•<•>
-379.2858
-184.8302
-120.7032
-119.8967
-87.3832
. -67.8443
-54.7939
-45.4521
-38.4290
-32.9528
-28.5604
-24.9572
-21.9469
-19.3934
-17.1995
-15.2938
-13.6227
-12.1451
-10.8291
-9.6495
-8.5859
-7.6219
-6.7442
-5.9414
-5.2045
-4.5254
-3.8977
-3.3157
-2.7745
-2.2699
-1.7983
-1.3566
-.9420
-.5520
-.1845
.1624
.4904
.8011
1.0957
1.3756
1.6417
1.8952
2.1368
2.3675
2.5879
2.7987
3.0006
3.1941
3.3797
3.5579
3.7292
3.8939
4.0524
4.2051
4.3523
4.4943
4.6313
4.7636
4.8915
5.0152
5.1349
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 509
1
g
7 2
5 х
S 1 "
; Z *
| S i
f~ 0 Т
С* rs| с>
s 7 «
| § • *
2 " * -
00 (| JO rrj
И ® " 2
^ ьГ <ч
Ч -? о g
и. U со
о" 1/3
< ^
+
1
<й
ОО
2 |
+ s
V «1*
? и я
Si I
1 пн v
I «л
¦ § v
-s ? §
- „+ °
OO T-l О
¦A. ^ *"*
ro <S II
0 Tfr
• 2ч it
0 °^ -
¦* 0
II +
0
©
308

Класс точности
VI-Е
Т
К
100
200
298.15
300
400
500
600
700
800
875
875
900
1000
1100
1154
1154
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
С°(Т)
Ф°(Г)
СУЛЬФИД ОЛОВА SnS (к, ж)
iS)
S°(T)
Дж -К .моль
34.140
45.560
49.245
49.265
51.006
53.410
56.075
58.864
61.719
63.886
54.614
55.005
56.570
58.135
58.980
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
74.900
Ф°(Г>
Ф°G)
12.460
28.680
41.682
41.901
52.626
61.636
69.433
76.343
82.578
86.903
86.903
88.304
93.584
98.419
100.874
100.874
103.951
110.233
116.030
121.411
126.432
131.137
135.565
139.746
143.706
147.467
151.048
154.466
157.735
160.867
163.874
166.765
= 163.8166
+ 148.805Х
(х = Т- 10~4
= 181.6563
°(Л-Я°@)
кДж ¦ моль
29.900
57.980
77.000
77.305
91.690
103.323
113.294
122.146
130.192
135.818
136.584
138.128
144.005.
149.470
152.276
179.659
182.586
188.581
194.132
199.300
204.134
208.674
212.956
217.005
220.847
224.502
227.986
231.315
234.503
237.561
240.498
243.325
1.744
5.860
10.530
10.621
15.626
20.843
26.316
32.063
38.091
42.801
43.471
44.842
50.420
56.156
59.318
90.918
94.363
101.853
109.343
116.833
124.323
131.813
139.303
146.793
154.283
161.773
169.263
176.753
184.243
191.733
199.223
206.713
Г°@)= 221.588
-107.0117
-48.9202
-29.9104
-29.6723
-20.1107
-14.4142
-10.6465
-7.9794
-5.9996
-4.8241
-4.8241
-4.4784
-3.2764
-2.3020
¦1.8498
-1.8498
-1.5537
-.9915
-.5204
-.1214
.2196
.5134
.7682
.9906
1.1856
1.3574
1.5095
1.6445
1.Z648
1.8723
1.9685
2.0550
+ 37.513 Ых + 0.0012705* + ОЛШОх +
Дж • К"' • моль"'
; 298.15 < Г < 875К)
+ 40.92 Ых- 0.16753а
+ 78.25* Дж • К"' • моль"'
(х = Т- 10~4
; 875 < Т < 1154К)
•-> +
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
800
875
875
900
1000
1100
1154
1154
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
Таблица
-
'л
о
~
*
v, оо
^ о
— II
II *-.
-
С
<~^
1
а
0.44831*'
< 2700К
1 Ь-
+ 74.9 In*
; 1154 <
* То
чо ^
с
О
"л
5
О
i|
X
о
о
о
о
II
я
00
сч
1
~*^
ц.
"^
510
¦у
о
7
R"
00
00
1
0 К
to
309

Класс точности
l-D
Г
К
!00
300
298.15
300
400
500
600
700
8U0
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
; 4700
4800
4900
1 5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;сп
29.487
32.424
34.537
34.565
35.692
36.319
36.701
36.953
37.132
37.267
37.373
37.461
37.536
37.602
37.662
37.718
37.770
37.820
37.870
37.919
37.970
38.024
38.082
38.146
38.219
38.303
38.401
38.515
38.649
38.805
38.987
39.199
39.442
39.720
40.036
40.391
40.787
41.226
41.709
42.237
42.809
43.424
44.082
44.781
45.520
46.294
47.102
47.940
48.804
49.689
50.592
51.508
52.431
53.357
54.281
55.198
56.103
56.991
57.858
58.699
59.510
СУЛЬФИД ОЛОВА SnS (г)
*o(r) = p(Sn)-p(S).p~l(SnS) &rH°
Ф°(Г)
Дж • К~ . моль"
179.635
200.058
212.267
212.460
221.583
228.856
234.923
240.133
244.703
248.775
252.447
255.791
258.862
261.702
264.343
266.812
269.128
271.312
273.376
275.334
277.196
278.971
280.667
282.291
283.848
285.345
286.786
288.174
289.515
290.810
292.064
293.279
294.457
295.601
296.714
297.796
298.851
299.879
300.882
301.862
302.820
303.758
304.676
305.575
306.458
307.324
308.175
309.012
309.835
310.645
311.443
312.229
313.005
313.770
314.526
315.273
316.010
316.740
317.462"
318.176
318.882
•1
Н°(Г)-Н°@)
кДж . моль"
208.788 2.915
230.081 6.005
243.464 9.301
243.678 9.365
253.793 12.884
261.831 16.487
268.489 20.140
274.166 23.823
279.113 27.528
283.495 31.248
287.427 34.980
290.993 38.722
294.256 42.472
297.263 46.229
300.052 49.992
302.652 53.761
305.088 57.536
307.380 61.315
309.543 65.100
311.592 68.889
313.538 72.684
315.392 76.483
317.162 80.288
318.856 84.100
320.481 87.918
322.043 91.744
323.547 95.579
324.998 99.425
326.401 103.283
327.760 107.155
329.079 111.045
330.360 114.954
331.609 118.885
332.827 122.843
334.017 126.831
335.183 130.852
336.326 134.910
337.449 139.011
338.555 143.157
339.645 147.354
340.722 151.606
341.786 155.917
342.840 160.292
343.886 164.735
344.924 169.250
345.955 173.840
346.982 178.510
348.004 183.261
349.022 188.098
350.037 193.023
351.050 198.037
352.061 203.142
353.070 208.339
354.078
355.083
213.628
219.010
356.088 224.484
357.091 230.049
358.092 235.704
359.090 241.447
360.087 247.275
361.080 253.185
@)» 463.
0
-238.4957
•117.04*21
-76.9540
-76.4496
-56.1065
¦43.8729
-35.6966
-29.8396
-25.4327
-21.9934
¦19.2320
-16.9645
-15.0682
-13.4581
-12.0733
-10.8693
-9.8127
-8.8776
-8.0441
-7.2963
-6.6216
-6.0097
-5.4520
-4.9417
-4.4729
-4.0407
-3.6408
-3.2698
-2.9247
-2.6027
-2.3016
-2.0194
-1.7543
-1.5049
-1.2698
-1.0478
-.8378
-.6389
-.4502
-.2709
-.1005
.0619
.2166
.3642
.5052
.6399
.7689
.8924
1.0107
1.1241
1.2330
1.3375
1.4380
1.5345
1.6273
1.7167
1.8027
1.8856
1.9654
2.0424
2.1167
300 кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700 '
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т а б л и
1
7
го
г- ^'
о —
UO *~"
"™ II
С/Э
с
¦~-
а;
i
-
гО
о 7
СО ft
1 ' Л
*О 0
о 2
(N ]
го i^
i ~2
.а т
г^ Ч
о; гч
© ¦ ~
¦* о
СО +
О* Н
го Ю
II
0
7
¦в
|
О*
го
~
II
v>
эс
&
с
<J
ua 511
0
^'
1
ОС
ж
"
0 К
to
—,
2
о
•о
V
V
v>
¦'*
1
о
II
310

Класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1143
С°р(Т)
ДИСУЛЬФИД
K°(r)=P(SnS2)
Ф°(Г)
5°(Г)
Дж ¦ К . моль
37.490
61.420
70.123
70.147
71.727
73.565
' 75.506
77.494
79.509
81.538
83.576
85.621
86.501
10.030 26.450
27.280 61.330
42.758 87.400
43.035 87.834
56.895 108.220
68.834 124.420
79.260 138.004
88.512 149.792
96.838 160.271
104.421 169.753
111.395 178.449
117.862 186.510
120.507 189.810
ОЛОВА SnS2
(к)
Д,Я°@) = 221.163
Я°(Г)-Я°@)
кДж . моль"
1.642
6.811
13.310
13.440
20.530
27.793
35.246
42.896
50.746
58.798
67.054
75.514
79.214
-106.2606
-48.0187
-28.9034
-28.6641
-19.0503
-13.3166
-9.5181
-6.8234
-4.8177
-3.2709
-2.0450
-1.0524
-.6821
кДж • моль
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1143
ос
ОС
II
1
X
ГО
О
чО
о
i
к
ON
О
о
X
?
.86
2
+
сч
чО
Г-;
С*">
(N
11
?
0
Таблица 512
7^
с
— о
1 ¦
^ о о
?3 о 2
гу- ОС -'
чО ~ \j
— II %
Т G ^
II «О OS
к, 0)
298.
19.'
0 И .
а; ?"
я
гл
7 V
1 *,
? V
п ^.„
оо '°
р 
О S"*
—1 II
+ -2-
311

Класс точности
VI-(
Т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
' 2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Р
42.904
51.841
56.435
56.493
58.749
59.945
60.641
61.078
61.368
61.571
61.717
61.826
61.910
61.976
62.028
62.070
62.105
62.133
62.157
62.178
62.195
62.210
62.223
62.235
62.245
62.254
62.262
62.269
62.275
62.280
62.286
62.290
62.294
62.298
62.302
62.305
62.308
62.310
62.313
62.315
62.317
62.319
62.321
62.323
62.324
62.326
62.327
62.328
62.330
62.331
62.332
62.333
62.334
62.335
62.336
62.336
62.337
62.338
62.339
02.339
62.340
К°(Т) = р(Ь,п)-
Ф° (Г)
Дж К . моль
187.335
213.793
231.197
231.480
245.090
256.217
265644
273.828
281.059
287.538
293.407
298.770
303.709
308.285
312.548
316.539
320.289
323.827
327.175
330.352
333.375
336.259
339.015
341.654
344.186
346.620
348.962
351.219
353.397
355.502
357.538
359.510
361.421
363.276
365.077
366.827
368.530
370.187
371.802
373.375
374.910
376.408
377.871
379.301
380.698
382.065
383.402
384.712
385.994
387.251
388.483
389.69!
390.875
392.038
393.180
394.301
395.402
396.484
397.548
398.594
399.622
ДИСУЛЬФИД ОЛОВА SnS2 (г)
,W(SnS,
S°(T)
1
222.526
255.262
276.928
277.277
293.875
307.126
318.122
327.505
335.681
342.921
349.416
355.304
360.687
365.646
370.240
374.521
378.528
382.294
385.847
389.208
392.398
395.432
398.327
401.093
403.742
406.283
408.725
411.075
413.339
415.525
417.636
419.679
421.656
423.573
425.433
. 427.239
428.994
430.702
432.364
433.982
435.560
437.099
438.600
440.067
441.499
442.900
444.270
445.61 1
446.923
448.208
449.467
450.702
451.912
453.099
454.264
455.408
456.531
457.635
458.719
459.785
460.832
Д #°@)= 745.878
//°(Г)-Я°@)
кДж • моль
3.519 ' -380.1323
8.294 184.4253
13.635 -119.8544
13.739 -119.0422
19.514 -86.2953
25.454 -66.6187
31.487 -53.4819
37.574 -44.0836
43.697 -37.0227
49.845 -31.5208
56.010 -27.1110
62.187 -23.4962
68.374 -20.4782
74.568 -17.9200
80.769 -15.7236
86.974 -13.8169
93.182 -12.1460
99.394 -10.6696
105.609 -9.3555
1! 1.826 -8.1782
118.044 -7.1173
124.265 -6.1563
130.486 -5.2817
136.709 -4.4822
142.933 -3.7486
149.158 -3.0730
155.384 -2.4487
161.611 -1.8700
167.838 -1.3321
174.065 -.8308
180.294 -.3624
186.523 .0762
192.752 .4878
198.981 .8748
205.211 1.2395
211.442 1.5837
217.672 1.9090
223.903 2.2171
230.134 2.5093
236.366 2.7868
242.597 3.0507
248.829 3.3020
255.061 3.5415
261.293 3.7702
267.526 3.9886
273.758 4.1976
279.991 4.3977
286.224 4.5895
292.456 4.7735
298.690 4.9501
304.923 5.1199
311.156 5.2831
317.389 5.4402
323.623 5.5916
329.856 5.7375
336.090 5.8782
342.323 6.0141
348.557 6.1453
354.791 6.2721
361.025 6.3947
367.259 6.5134
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 513
Л
с;
— о
1 л ?
о ^ 7
С^ с;
^ оо
« § S -
оо ю н Д.
й ; 2 г»
»-¦ ¦ ¦ ^J pj
И О ОО* ON
со nt
с 5? о сч
w ^ ^°
О С/Э
•^ о
1
45 -
о §
+ 2
i ~
п ^ S
ЧО ь- О
n q Co
О V
1 VO '
Д О Q
— + о
О V)
1 "$ т"
оо 1
(No-, О
^ О "**'
-н ! "^
о 5 ~
¦«¦ о
II +
tr.
о
312

Класс точности
Vl-C
Т
К
100
200
298.15
300
400
500
600
600.65
600.65
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
С°р(Т)
24.430
25.770
26.650
26.673
27.788
28.785
29.736
29.742
30.627
30.313
29.979
29.660
29.369
29.116
28.903
28.731
28.602
28.513
28.463
28.451
28.475
28.532
28.620
28.737
28.881
29.048
29.238
29.446
29.671
29.909
30.160
30.419
30.684
30.953
31.223
31.492
31.757
32.015
32.264
а:о(Г)=р(рь)
Ф°G-)
Дж -К ¦ моль
19.239
32.901
41.758
41.900
48.686
54.158
58.771
58.799
58.799
63.920
68.331
72.179
75.588
78.645
81.413
83.941
86.265
88.416
90.418
92.288
94.044
95.698
97.262
98.745
100.155
101.500
102.786
104.017
105.199
106.336
107.431
108.488
109.509
110.497
111.455
112.384
113.287
114.165
115.019
СВИНЕЦ РЬ (к, ж)
S°(T)
1
Я°(Г)-Я°@)
кДж . моль"
36.899 1-766
54.346 4.289
64.800 6.870
64.965 6.919
72.795 9.644
79.105 12.473
84.437 15.399
84.469 15.419
92.481 20.231
97.146 23.258
101.172 26.273
104.684 29.255
107.794 32.206
110.581 35.130
113.105 38.030
115.411 40.912
117.535 43.778
119.505 46.633
121.344 49.482
123.069 52.327
124.695 55.173
126.236 58.023
127.702 60.881
129.101 63.748
130.441 66.629
131.729 69.525
132.969 72.439
134.167 75.373
135.326 78.329
136.450 81.308
137.542 84.311
138.605 87.340
139.641 90.395
140.651 93.477
141.638 96.586
142.603 99.722
143.547 102.884
144.471 106.073
145.377 109.287
Г°@) = 195.873
о
-96.434!
-45.2391
-28.4278
-28.2169
-19.7330
-14.6610
-11.2936
-11.2749
-11.2749
-8.9591
-7.2176
-5.8697
-4.7965
-3.9226
-3.1975
-2.5867
-2.0653
-1.6152
-1.2229
-.8779
-.5723
-.2996
-.0548
.1662
.3667
.5495
.7169
.8708
1.0129
1.1444
1.2667
1.3806
1.4870
1.5867
1.6803
1.7684
1.8514
1.9299
2.0042
кДж ¦ моль"
Т
К
100
200
298.15
300
400
500
600
600.65
600.65
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
с^
с
<N
II
+
О
00
о
1
н
000226
о
I
к
оо
+
Ш7
II
g
о
Таблица 514
'л
g
S
i
и*
и ^
" 2 о
ON „
* *
ja ^ о 3
2U- .о ^
*% 0
1
X
»о ^
о g
боо.б;
001579
Дж-К
3600В
V 6«н V
'i v i | v
* <Л Г- | ю
— * ^ °° ^э
1 оо' tN. "^ О
^ ^ * 5 °
к'о р + 'о
c-J rt о» X "^
Т|- II ^Н U-) ||
g ¦
о
313

Класс точности
I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
с;<п
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.790
20.801
20.829
20.888
20.991
21.155
21.394
21.717
22.132
22.640
23.239
23.922
24.679
25.498
26.364
27.261
28.173
29.083
29.978
30.844
31.669
32.443
33.159
33.812
34.396
34.912
35.357
35.734
36.044
36.290
36.477
36.608
36.688
36.721
36.713
36.667
36.590
36.484
36.355
36.207
36,042
35.865
35.679
35.487
35.292
35.097
34.903
34.713
34.530
34.354
34.188
34.034
33.893
Ф°(Г)
~ 1 ~
Дж ¦ К . моль
131.771
146.178
154.478
154.606
160.586
165.224
169.014
172.218
174.994
177.442
179.632
181.614
183.424
185.090
186.635
188.076
189.427
190.700
191.906
193.053
194.149
195.199
196.208
197.182
198.124
199.038
199.926
200.791
201.636
202.460
203.268
204.058
204.834
205.595
206.342
207.076
207.798
208.508
209.207
209.894
210.570
211.236
211.891
212.536
213.172
213.797
214.413
215.019
215.617
216.205
216.784
217.355
217.917
218.471
219.016
219.553
220.083
220.604
221.118
221.625
222.124
СВИНЕЦ РЬ (г)
S°(T)
1
152.557
166.964
175.270
175.392
181.372
186.010
189.800
193.004
195.780
198.229
200.422
202.410
204.232
205.918
207.494
208.980
210.395
211.751
213.062
214.336
215.582
216.806
218.012
219.203
220.383
221.551
222.710
223.857
224.994
226.119
227.231
228.329
229.412
230.479
231.528
232.558
233.569
234.560
235.531
236.480
237.408
238.315
239.199
240.063
240.905 -
241.726
242.527
243.307
244.068
244.809
245.532
246.236
246.923
247.594
248.248
248.887
249.511
250.120
250.716
251.299
251.870
Я°(Г)-Я°@)
кДж . моль
Т
К
2.079 — 100
4.157 — 200
6.197 — 298.15
6.236 — 300
8.314 — 400
10.393 — 500
12.472 — 600
14.550 — 700
16.629 — 800
18.708 — 900
20.790 — 1000
22.875 — 1100
24.969 — 1200
27.076 — 1300
29.202 — 1400
31.357 — 1500
33.549 — 1600
35.787 — 1700
38.080 — 1800
40.437 — 1900
42.867 — 2000
45.375 — 2100
47.968 — 2200
50.649 — 2300
53.421 — 2400
56.283 — 2500
59.237 — 2600
62.278 — 2700
65.404 — 2800
68.610 — 2900
71.891 — 3000
75.240 — 3100
78.651 — 3200
82.117 — 3300
85.631 — 3400
89.186 — 3500
92.775 — 3600
96.393 — 3700
100.032 — 3800
103.686 — 3900
107.351 — 4000
111.022 — 4100
114.694 — 4200
118.364 — 4300
122.027 — 4400
125.681 — 4500
129.323 ' — 4600
132.951 — 4700
136.563 — 4800
140.159 — 4900
143.736 — 5000
147.295 — 5100
150.834 — 5200
154.353 — 5300
157.853 — 5400
161.334 — 5500
164.796 — 5600
168.240 — 5700
171.667 — 5800
175.078 — 5900
178.474 — 6000
Таблица 515
-
§
1 * I
2 d |
56 о -'
гч °°. ""* Ч
^ •> " ***
гч йь с)
и " !2 о
§ о оо' ""
С гл "
? с og
0 В.
t п
*ч О
+
? г
,_, 1
00 °
О 7
J Т
? 56 ?
« d §
о ч *°
So V
н 7 v
я' 8
* ?
1—1 00 ¦*>
.СО . 00 |
О ГО ^
+ + ^
\о оо
Г^ 00 *{
О го
II +¦
ь
0
в
314

СВИНЕЦ РЬ (г)
Таблица 515
(окончание)
Ф°(Г)
S°(T)
к
Дж . К~' .моль
Н°(Т)-Н°@)
кДж . моль
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
33.654
33.483
33.387
33.374
33.448
33.613
33.874
34.230
34.682
35.228
35.867
36.593
37.402
38.287
39.240
40.253
41.316
42.420
43.553
44.704
223.102
224.052
224.977
225.877
226.753
227.607
228.441
229.255
230.050
230.827
231.588
232.334
233.065
233.783
234.488
235.182
235.864
236.537
237.200
237.854
252.977
254.043
255.072
256.068
257.036
257.980
258.905
259.813
260.707
261.592
262.470
263.342
264.213
265.083
265.954
266.827
267.704
268.585
269.472
270.363
185.228
191.940
198.626
205.301
211.981
218.686
225.433
232.242
239.131
246.121
253.229
260.473
267.872
275.439
283.191
291.139
299.295
307.668
316.265
325.091
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
X
X
t—
оо
•ч-
+
Tf-
V
V
4
315

Класс точности
I-A
Т
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.786
20.787
20.788
20.790
20.794
20.802
20.813
20.830
20.854
20.886
20.927
20.979
21.041
21.116
21.202
21.301
21.411
21.534
21.667 .
21.81
21.964
22.126
22.295
22.472
22.653
22.839
23.028
23.220
23.413
23.606
23.798
23.988
24.177
24.362
24.543
24.720
24.892
25.059
25.220
25.374
25.523
25.665
25.799
25.928
26.049
26.163
26.270
26.370
26.464
ПОЛОЖИТЕЛЬНЫЙ
fCTWCFbW
Ф°(Г)
Дж ¦ К • моль
160.241
160.370
166.349
170.988
174.777
177.981
180.757
183.205
185.395
187.376
189.185
190.849
192.389
193.823
195.165
196.425
197.613
198.737
199.804
200.818
201.786
202.711
203.596
204.446
205.263
206.050
206.809
207.542
208.250
208.937
209.602
210.248
210.876
211.486
212.080
212.660
213.225
213.776
214.315
214.842
215.358
215.862
216.357
216.841
217.317
217.783
218.241
218.691
219.133
219.568
219.996
220.416
220.830
221.238
221.640
222.035
222.425
222.809
223.188
rW(Pb-)
5° (Г)
1
181.027
181.156
187.135
191.774
195.563
198.768
201.543
203.991
206.181
208.162
209.971
211.635
213.175
214.610
215.952
217.212
218.402
219.527
220.596
221.615
222.587
223.519
224.413
225.273
226.103
226.905
227.681
228.435
229.167
229.880
230.575
231.253
231.916
232.565
233.201
233.824
234.435
235.036
235.626
236.207
236.778
237.340
237.894
238.439
238.977
239.506
240.029
240.544
241.052
241.552
242.047
242.534
243.015
243.490
243.958
244.420
244.876
245.326
245.770
ИОН СВИНЦА
V
Я°(Г)-Я°@)
кДж . моль
6.197
6.236
8.314
10.393
12.472
14.550
16.629
18.707
20.786
22.865
24.943
27.022
29.101
31.179
33.259
35.338
37.419
39.501
41.585
43.672
45.763
47.8^8
49.959
52.067
54.183
56.308
58.443
60.590
62.750
64.924
67.113
69.317
71.538
73.776
76.033
78.307
80.601
82.913
85.245
87.596
89.966
92.355
94.763
«7.190
99.636
102.099
104.579
107.077
109.591
112.121
114.666
117.225
119.798
122.385
124.984
127.594
130.216
132.848
135.490
РЬ+ (г)
г°@)= -715.559 кДж- моль
125.0560
124.2762
92.8168
73.8863
61.2296
52.1630
45.3437
40.0246
35.7573
32.2560
29.3300
26.8473
24.7134
22.8590
21.2321
19.7928
18.5103
17.3599
16.3221
15.3811
14.5238
13.7394
13.0190
12.3551
11.7412
11.1719
10.6425
10.1489
9.6876
9.2555
8.8500
8.4687
8.1094
7.7703
7.4498
7.1462
6.8584
6.5851
6.3252
6.0777
5.8418
5.6167
5.4015
5.1957
4.9986
4.8097
4.6284
4.4543
4.2870
4.1260
3.9710
3.8217
3.6777
3.5387
3.4044
3.2747
3.1492
3.0278
2.9103
Г
К
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
J500
5600
5700
5800
5900
6000
Таблица 516
-1
-
о
'¦* . —
о И 'л
? ь; О
3 я т'
м «з М
2 - !L ^
О О\ - JjcJ *"*
ГЦ и ,л •—'
w, с? ОО ^
С (N II
+ * С ч
о"' а.
^ 0
*-> а=
1
1
S _,
I 'а
—i о
о S
г>+ Т
7855;
Дж •
ЗООК]
о "х
Ш ° v
Я ' о
? ^ °
оо оо ¦ • •.
m os 'o
+ -Г "
2 3 **•
О to II
гч os
OS <*> Ц
<N —I
II !
0
©
316

ПОЛОЖИТЕЛЬНЫЙ ИОН СВИНЦА РЬ+ (г)
Таблица 516
(окончание)
Ф°(Г)
S°(T)
к
Дж .К .моль
Н°(Т)-Н°@)
кДж .моль
К
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
26.630
26.771
26.887
26.980
27.051
27.104
27.139
27.159
27.165
27.160
27.145
27.122
27.092
27.058
27.021
26.982
26.943
26.904
26.868
26.834
223.931
224.654
225.358
226.045
226.716
227.371
228.010
228.635
229.247
229.845
230.431
231.005
231.567
232.117
232.657
233.187
233.706
234.216
234.716
235.208
246.640
247.488
248.314
249.118
249.901
250.664
251.407
252.131
252.837
253.524
254.195
254.849
255.487
256.109
256.716
257.310
257.890
258.457
259.011
259.554
140.800
146.140
151.506
156.893
162.297
167.712
173.137
178.567
184.000
189.432
194.863
200.289
205.711
211.126
216.534
221.934
227.327
232.712
238.089
243.459
2.6860
2.4750
2.2761
2.0883
1.9105
1.7421
1.5821
1.4301
1.2854
1.1475
1.0159
.8902
.7700
.6550
.5448
.4392
.3380
.2408
.1474
.0577
6200
6400
6600
6800
7000
7200
7400
7600
7800
8000
8200
8400
8600
8800
9000
9200
9400
9600
9800
10000
vq
1
ч
t
о
00
<>
¦ч-
s
о
+
н
1869 1
10.
+
гп
о
о
%
н
in
О
—
ос
t-^
1
к
ос
45
ОС
о
V
V
о
о
о
о
317

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
35.753
37.139
37.524
37.529
37.760
37.955
38.150
38.360
38.587
38.824
39.059
39.281
39.490
39.699
39.928
40.202
40.545
40.976
41.506
42.136
42.857
43.654
44.502
45.375
46.245
47.081
47.858
48.553
49.147
49.626
49.982
50.211
50.313
50.294
50.159
49.918
49.581
49.161
48.668
48.115
47.512
46.871
46.199
45.506
44.800
44.088
43.374
42.664
41.961
41.270
40.593
39.931
39.287
38.662
38.056
37.470
36.905
36.359
35.834
35.330
34.844
AVW(Pb).p-
Ф°(Г)
Дж . К . моль
205.019
228.184
242.141
242.360
252.634
260.706
267.360
273.027
277.963
282.340
286.274
289.848
293.124
296.150
298.962
301.589
304.056
306.381
308.582
310.673
312.666
314.571
316.397
318.153
319.844
321.477
323.057
324.588
326.074
327.518
328.923
330.291
331.624
332.924
334.192
335.430
336.639
337.820
338.973
340.100
341.202
342.279
343.332
344.361
345.368
346.352
347.315
348.257
349.179
350.081
350.964
351.828
352.674
353.502
354.313
355.108
355.886
356.649
357.396
358.128
358.846
ДИСВИНЕЦ РЬ2 (г)
'(РЬ2)
S°(T)
237.303
262.644
277.555
277.787
288.616
297.063
304.001
309.897
315.034
319.592
323.695
327.429
330.855
334.025
336.975
339.738
342.344
344.814
347.171
349.431
351.611
353.721
355.771
357.768
359.718
361.622
363.484
365.304
367.081
368.814
370.503
372.146
373.742
375.290
376.790
378.240
379.642
380.995
382.300
383.557
384.768
385.933
387.054
388.133
389.171
390.170
391.131
392.056
392.947
393.805
394.632
395.429
396.199
396.941
397.658
398.351
399.021
399.669
400.297
400.905
401.495
д л
г
Н°(Т)-На@)
кДж • моль
3.228
6.892
10.559
10.628
14.393
18.179
21.984
25.809
29.657
33.527
37.421
41.339
45.277
49.237
53.218
57.224
61.260
65.336
69.459
73.640
77.889
82.214
86.621
91.115
95.696
100.363
105.110
109.932
114.818
119.757
124.739
129.749
134.777
139.808
144.831
149.836
154.812
159.749
164.641
169.481
174.262
178.982
183.635
188.221
192.736
197.180
201.553
205.855
210.086
214.248
218.341
222.367
226.327
230.224
234.060
237.836
241.555
245.218
248.827
252.385
255.894
г°@)= 83.000
о
-40.2973
-18.3251 •
-11.0511
-10.9594
-7.2585
-5.0279
-3.5344
¦2.4634
-1.6571
-1.0279
-.5228
-.1083
.2380
.5320
.7847
1.0044
1.1973
1.3683
1.5210
1.6584
1.7828
1.8962
2.0001
2.0959
2.1845
2.2669
2.3438
2.4160
2.4839
2.5481
2.6088
2.6666
2.7217
2.7744
2.8248
2.8733
2.9200
2.9650
3.0086
3.0508
3.0917
3.1314
3.1700
3.2077
3.2443
3.2802
3.3151
3.3493
3.3828
3.4156
3.4477
3.4792
3.5100
3.5403
3.5701
3.5993
3.6281
3.6563
3.6841
3.7114
3.7384
кДж • моль
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблиц
7
ЧО
Tf ОО
¦* en
II II
5 о
i
о
1
m А
» О
о S
С* 1
ы
ОО Л
О со
+ ^
? 1
СЧ г*
00 Н
ТГ ГО
- . (—
сч v>
+ +¦
е- о
\ф [-*¦
о
II +
0
А
i
V)
О
ГЛ
II
OS
?
о
а 517
i
А
г:
о
i
ГО
ГЧ
О
II
о «
. ^5
Я
О
1
у
V
о
о
«¦'"
'о
II
318

Класс точности
VI -Е
Г
К
100
200
298.15
300
400
500
600
700
762
762
800
900
1000
1100
1160
1160
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
С°р(Т)
27.070
40.330
46.414
46.459
48.728
50.854
52.922
54.964
56.222
54.588
55.137
56.555
57.948
59.323
60.142
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
65.000
Ф°
Ф°
ОКСИД СВИНЦА РЬО (к,
К°(Т)= p(l'bO)
| Ф°(Л
S°(T)
Дж • К • моль
12.290
25.800
36.899
37.091
46.628
54.808
61.966
68.342
71.981
71.981
74.120
79.403
84.259
88.759
91.312
91.312
93.697
99.304
104.467
109.252
113.710
117.882
121.803
125.502
129.002
132.324
135.484
138.498
141.378
144.137
146.783
149.326
151.774
154.132
156.408
158.607
160.735
(Г) = 164.7614
+ 100.05л-
27.0.40
50.440
67.840
68.127
81.809
92.912
102.367
110.679
115.396
115.659
1 18.329
124.905
130.936
136.523
139.696
161.747
163.951
169.154
173.971
178.455
182.650
186.591
190.306
193.820
197.155
200.326
203.350
206.239
209.005
211.659
214.208
216.661
219.025
221.306
223.510
225.641
227.705
\
НЧТ) я°(о
кДж ¦ моль
1.475
4.928
9.225
9.311
14.072
19.052
24.241
29.636
33.082
33.282
35.367
40.952
46.677
52.541
56.125
81.705
84.305
90.805
97.305
103.805
110.305
116.805
123.305
129.805
136.305
142.805
149.305
155.805
162.305
168.805
175.305
181.805
188.305
194.805
201.305
207.805
214.305
ж)
Я°@) = 287.000
)
1
-141.2650
-65.9592
-41.2453
-40.9355
-28.4833
-21.0505
-16.1228
-12.6243
-10.9263
-10.9263
-10.0185
-8.0064
-6.4081
-5.1104
-4.4439
-4.4439
-4.0763
-3.2634
-2.5745
-1.9843
-1.4738
-1.0287
-.6377
-.2919
.0155
.2903
.5371
.7596
.9611
1.1441
1.3109
1.4635
1.6033
1.7318
1.8502
1.9595
2.0607
+ 41.07 1пл: - 0.0002765х + 0.40949л: +
Дж ¦ К • моль
(х = Т- 10~4; 298.15 < Т
(Г) = 176.0934
+ 66.335л
(х = Т ¦ 10"'
+ 44.96 Ых- 0
Дж • К ¦ моль
к, 762 < Т <
-1
< 762К)
.001397л: + 0.51955л: +
"'"
1160К)
•
кДж • моль"'
Т
К
100
200
298.15
300
400
500
600
700
762
762
800
900
1000
1100
1160
1160
1200
1300
1400
1500
1600-
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
Таблица 518
-
-
§
7 2
л
о ^ —
X g
& § 1
*• 2 7
3 7 *
S 7 Q ?
rs II ^ m
По00' О
¦5 v Я -1 ¦
- II
? О ° °*
w Л -^
I
л
с;
о
2
-'
3050л: Д
3200К)
2 v
15.0 1пл:-
.160 < 1
+ .-
1 Т2
m с-ч
II s-'
g
0
319

Класс точности
I - Е
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°р(Т)
29.136
30.426
32.510
32.545
34.122
35.146
35.818
36.277
36.605
36.850
37.041
37.194
37.322
37.431
37.528
37.614
37.695
37.771
37.846
37.921
37.999
38.083
38.175
38.278
38.394
38.528
38.681
38.858
39.062
39.295
39.560
39.859
40.196
40.571
40.986
41.443
41.941
42.480
43.061
43.681
44.340
45.035
45.764
46.523
47.310
48.120
48.949
49.794
50.649
51.510
52.371
53.229
54.078
54.913
55.731
56.526
57.294
58.032
58.736
59.403
60.030
ОКСИД СВИНЦА РЬО (г)
АГ°(Г)=р(РЪН
Ф°(Г>
Дж . К~ . моль"
177.817
198.033
209.875
210.060
218.826
225.804
231.634
236.654
241.068
245.012
248.576
251.830
254.824
257.597
260.179
262.596
264.868
267.011
269.039
270.964
272.798
274.546
276.219
277.82!
279.359
280.839
282.263
283.638
284.965
286.249
287.493
288.699
289.870
291.008
292.114
293.193
294.244
295.270
296.272
297.252
298.211
299.150
300.071
300.974
301.860
302.732
303.588
304.431
305.260
306.078
306.884
307.678
308.462
309.236
310.001
310.756
311.503
312:242
312.973
313.696
314.412
0(О).р-'(РЬО)
5°(Г)
1
206.909
227.386
239.931
240.132
249.726
257.458
263.930
269.488
274.354
278.681
282.573
286.111
289.353
292.345
295.122
297.715
300.145
302.432
304.593
306.642
308.588
310.444
312.218
313.917
315.549
317.119
318.633
320.096
321.513
322.887
324.224
325.526
326.796
328.039
329.256
330.451
331.625
332.782
333.922
335.049
336.163
337.266
338.360
339.446
340.524
341.596
342.663
343.725
344.782
345.835
346.885
347.930
348.972
350.010
351.044
352.074
353.100
354.120
355.136
356.145
357.149
Н°(Т)-Н°@)
кДж . моль
2.909
5.871
8.961
9.021
12.360
15.827
19.378
22.984
26.629
30:302
33.997
37.709
41.435
45.173
48.921
52.678
56.443
60.217
63.998
67.786
71.582
75.386
79.199
83.021
86.855
90.701
94.561
98.438
102.334
106.251
110.194
114.164
118.167
122.205
126.282
130.403
134.572
138.793
143.070
147.406
151.807
156.276
160.815
165.429
170.121
174.892
179.745
184.682
189.704
194.812
200.006
205.286
210.652
216.101
221.634
227.247
232.938
238.705
244.543
250.451
256.423
Г°@)= 372.270
-190.9138
-93.1778
-60.8841
-60.4776
-44.0816
-34.2221
-27.6369
-22.9255
-19.3867
-16.6306
-14.4228
-12.6142
-11.1052
-9.8269
-8.7298
-7.7779
-6.9438
-6.2069
-5.5509
-4.9630
-4.4329
-3.9524
-3.5146
-3.1140
-2.7458
-2.4061
-2.0917
-1.7997
-1.5276
-1.2734
-1.0353
-.8118
-.6014
-.4031
-.2157
-.0383
.1298
.2895
.4413
.5858
.7236
.8551
.9808
1.1009
1.2159
1.3261
1.4317
1.5331
1.6304
1.7239
S.8138
1.9003
1.9836
20637
2.1409
2.2154
2.2872
2.3564
2.4232
2.4878
2.5501
кДж • моль"'
Т
К
100
200
298.15
" 300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5S00
6000
Таблица 519
-
'а
о
Л . *"*
2 Л 6
о 2 7
О " II ?
m ° "• Ч
я "»" ¦ з SS
11 о оо о
5- . On _
. . - »
? о о «
О ^,
^ О
< ^
1
Тч
=*? О
о s
? <? °
° ч ^
ч * V
S о
го оо •«
+ + т
го ^
{1 1
ь
0
©
320

Класс точности
V-G
ДИОКСИД СВИНЦА РЬО2 (г)
Таблица 520
A-°G-) =p(Pb) • р2(О) • p"'(PbOj)
ДгЯ°@) = 679.439 кДж • моль"
Ср°(Г)
Ф°(Г)
S°(T)
Дж . К .моль
кДж . моль
-1
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
37.888
46.138
51.720
51.803
55.328
57.453
58.779
59.647
60.240
60.661
60.969
61.202
61.381
61.521
61.634
61.726
61.801
61.863
61.916
61.961
61.999
62.032
62.061
62.086
62.108
62.127
62.145
62.160
62.174
62.186
62.198
62.208
62.217
62.225
62.233
62.240
62.246
62.252
62.258
62.263
62.268
62.272
62.276
62.280
62.283
62.287
62.290
62.292
62.295
02.298
62.300
62.302
62.304
62.306
62.308
62.310
62.312
62.313
62.315
62.316
62.318
180.458
204.292
219.889
220.143
232.432
242.589
251.284
258.900
265.679
271.791
277.355
282.463
287.184
291.572
295.672
299.519
303.143
306.567
309.813
312.899
315.839
318.647
321.334
323.910
326.384
328.764
331.056
333.266
335.402
337.466
339.464
341.400
343.279
345.102
346.873
348.595
350.272
351.904
353.495
355.046
356.559
358.036
359.480
360.891
362.270
363.620
364.941
366.235
367.502
368.744
369.962
371.157
372.329
373.479
374.609
375.719
376.809
377.880
378.934
379.970
380.988
212.421
241.440
260.977
261.298
276.726
289.320
299.921
309.052
317.058
324.178
330.586
336.409
341,742
346.661
351.224
355.480
359.466
363.215
366.752
370.101
373.280
376.306
379.192
381.952
384.595
387.130
389.567
391.913
394.174
396.356
398.464
400.504
402.479
404.394
406.251
408.056
409.809
411.515
413.175
414.792
416.368
417.906
419.407
420.872
422.304
423.704
425.073
426.412
427.724
429.008
430.267
431.501
432.710
433.897
435.062
436.205
437.328
438.431
439.515
440.580
441.627
3.196
7.430
12.251
12.346
17.718
23.366
29.182
35.106
41.103
47.149
53.231
59.340
65.470
71.615
77.773
83.941
90.117
96.301
102.490
108.684
114.882
121.083
127.288
133.495
139.705
145.917
152.131
158.346
164.563
170.781
177.000
183.220
189.441
195.663
201.886
208.110
214.334
220.559
226.785
233.011
239.237
245.464
251.692
257.919
264.148
270.376
276.605'
282.834
289.063
295.293
301.523
307.753
313.983
320.214
326.445
332.676
338.907
345.138
351.369
357.601
363.833
-345.5558
-166.9716
-107.9925
-107.2505
-77,3306
-59.3556
-47.3618
-38.7894
-32.3570
-27.3522
-23.3472
-20.0695
-17.3375
-15.0254
-13.0432
-11.3249
•9.8210
-8.4937
-7.3134
-6.2570
-5.3056
-4.4443
-3.6608
-2.9448
-2.2877
-1.6826
-1.1234
-.6048
-.1226
.3271
.7476
1.1416
1.5118
1.8602
2.1887
2.4992
2.7931
3.0717
3.3363
3.5879
3.8275
4.0559
4.2740
4.4824
4.6818
4.8728
5.0560
5.2318
5.4006
5.5630
5.7192
5.8696
6.0146
6.1544
6.2893
6.4197
6.5456
6.6675
6.7853
6.8994
7.0100
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
I
It
.3
ё
о
о
I
X
00
>?>
00
•о
о
О
+
321

Класс точности
Н-Е
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
р
29.425
32.233
34.404
34.434
35.632
36.314
36.740
37.029
37.240
37.406
37.547
37.674
37.797
37.925
38.062
38.212
38.377
38.558
38.755
38.967
39.191
39.428
39.673
39.926
40.183
40.444
40.706
40.969
41.229
41.487
41.741
41.990
42.233
42.469
42.698
42.918
43.130
43.331 .
43.522
43.702
43.871
44.027
44.171
44.302
44.420
44.524
44.615
44.692
44.756
44.806
44.842
44.866
44.876
44.874
44.859
44.833
44.795
44.746
44.687
44.618
44.540
ФТОРИД СВИНЦА PbF (г)
A:o(r)=p(Pb)p(F).p~1(PbF)
Ф°(Г)
Дж ¦ К ¦ моль
186.265
206.627
218.786
218.979
228.064
235.312
241.362
246.561
251.124
255.191
258.861
262.206
265.280
268.122
270.768
273.242
275.566
277.758
279.832
281.802
283.677
285.466
287.179
288.821
290.399
291.917
293.381
294.794
296.161
297.484
298.766
300.011
301.220
302.396
303.541
304.656
305.743
306.804
307.840
308.852
309.842
310.810
311.757
312.685
313.594
314.485
315.359
316.217
317.058
317.884
318.696
319.493
320.276
321.046
321.803
322.548
323.281
324.002
324.712
325.411
326.099
S°(T)
1
215.342
236.537
249.852
250.065
260.152
268.184
274.845
280.531
285.490
289.886
293.835
297.419
300.703
303.733
306.549
309.180
311.651
313.983
316.192
318.293
320.298
322.216
324.055
325.824
327.529
329.175
330.766
332.307
333.802
335.253
336.664
338.037
339.374
340.677
341.948
343.189
344.401
345.586
346.744
347.877
348.985
350.070
351.133
352.174
353.194
354.193
355.173
356.133
357.075
357.998
358.904
359.792
360.664
361.518
362.357
363.180
363.987
364.780
365.557
366.320
367.070
А Я°@)= 343.000
Я°G>-Яо@)
кДж • моль
2.908 -176.0797
5.982 -86.0459
9.262 -56.3061
9.326 -55.9318
12.835 -40.8336
16.436 -31.7545
20.090 -25.6901
23.779 -21.3510
27.493 -18.0917
31.226 -15.5529
34.973 -13.5192
38.734 -11.8530
42.508 -10.4628
46.294 -9.2850
50.093 -8.2743
53.907 -7.3972
57.736 -6.6287
61.583 -5.9498
65.448 -5.3454
69.334 -4.8038
73.242 -4.3156
77.173 -3.8730
81.128 -3.4699
85.108 -3.1011
89.113 -2.7622
93.145 -2.4497
97.202 -2.1604
101.286 -1.8918
105.396 -1.6417
109.532 -1.4081
П3.693 -1.1893
117.880 -.9840
122.091 , -.7908
126.326 -.6087
130.585 -.4367
134.865 -.2739
139.168 -.1496
143.491 .0268
147.834 .1661
152.195 .2988
156.574 .4252
160.969 .5460
165.379 .6614
169.803 .7718
174.239 .8775
178.686 .9789
183.143 1.0762
187.608 1.1697
192.081 1.2596
196.559 1.3460
201.042 1.4293
205.527 1.5095
210.014 1.5869
214.502 1.6616
218.988 1.7337
223.473 1.8033
227.954 1.8707
232.431 1.9359
236.903 1.9990
241.368 2.0601
245.826 2.1193
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 521
'л
о
7 ^
о * "л
s g §
¦ z %
а °° —'
"О !
•2 7 я -*
fN II 12 On
II ^~. CO* ">
с
sg И." о «
w ? ^
a; (T'
J-. a;
< <•-.
i
V
VO _
О 'j,
С4* О
о S
+ „"
cs 1
ё * я
s 5 §
-н m чО
о к
О in V
О ^" ?^
1 *
1 ' 1
СП СО *"
Г-- *0 О
СО СО -<
m + *-•
о Ч и
•ч- •? "
12 со а
со СО
II 1'
11 1
g
о
в
322

Класс точности
VII 1
Т
К
298.15
300
400
500
583
583
600
700
716
716
800
900
1000
1100
1103
1103
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
С°(Т)
Р
72.259
72.317
75.762
79.504
82.701
82.007
91.410
137.846
149.581
149.579
109.368
92.070
92.675
101.724
102.060
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
109.000
Ф°{Т)
Ф°(Т)
ДИФТОРИД
tf°G-)=p(PbF2)
Ф°(Г)
Дж ¦ к . моль
55.690
56.001
71.378
84.425
93.954
93.954
95.863
106.571
108.238
108.238
116.885
126.483
135.204
143.188
143.419
143.419
151.704
159.638
167.039
173.973
180.494
186.649
192.477
198.010
203.276
208.301
213.105
217.707
222.123
226.367
230.453
234.391
238.192
241.865
245.419
248.860
252.197
= 243.1422 + 59.067
+ 199.83* Дж-К
(x = 7"-10~4; 298.15
5°(Г)
106.000
106.447
127.712
145.017
157.465
159.969
162.469
179.807
183.044
183.044
197.159
208.803
218.42*6
227.643
227.921
241.249
250.436
259.161
267.238
274.759
281.793
288.401
294.632
300.525
306.116
311.434
316.505
321.350
325.989
330.439
334.714
338.828
342.791
346.616
350.312
353.886
357.346
СВИНЦА PbF2
(к, ж)
As Я°@) = 250.000 кДж . моль"
Н°(Т)-Н°@)
кДж . моль
15.000
15.134
22.534
30.296
37.027
38.487
39.964
51.265
53.561
53.561
64.220
74.088
83.223
92.900
93.206
107.906
118.479
129.379
140.279
151.179
162.079
172.979
183.879
194.779
205.679
216.579
227.479
238.379
249.279
260.179
271.079
281.979
292.879
303.779
314.679
325.579
336.479
33.6880
-33.4205
-22.6879
-16.3067
-12.7064
-12.7064
-12.0992
-9.1565
¦8.7684
-8.7684
-7.0159
-5.3918
-4.1138
-3.0852
-3.0575
-3.0575
-2.3025
-
-
.6590
.1222
-.6697
-.2849
.0448
.3292
.5758
.7907
.9788
.144U
.2896
.4183
.5322
.6333
.7231
.8029
.8740
.9373
.9936
2.0437
tax + 0.000567х + 0.40068Х +
• моль"'
<Т<
= 26517.17 +9595.057 to*-:
- 100317.9х+201410.9л-2 Дж
(х = Г-10~4; 583 <
583К)
.268752х +406.5305Х -
•К-моль
Т < 716К)
Т
К
298.15
300
400
500
583
583
600
700
716
716
800
900
1000
1100
1103
1103
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
Таблица
ь
моль"
§ ч
X
О чо
rf II ¦ Zl
ii ° §
:= х м
i i
о ™.
а; 0
<1
+
V
¦^j- i
о л
•ч- с;
¦* О
<о 2
о
'* 'а а;
? g ч
г * тн
2 "С ? §
* п м
4- О m
' S * 1 1
3 * V о
7 S s. s
чо | ¦- *
«S » ON
^ 'о ?
S м • ri
Ч S fx Й
1 г- ii m
11 + W "
g g
522
"wa
5
^"
1
.
II
О в?
оз
200 к;
m
V
ь,
V
поз
1
о
К
и
-is
323

Класс точности
, V-V.
т
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
Г)
t*
38.887
46.143
50.979
51.045
53.674
55.132
55.999
56.551
• 56.921
57.181
57.369
57.510
57.618
57.703
57.771
57.825
57.870
57.908
57.939
57.966
57.989
58.008
58.025
58.040
58.053
58.065
58.075
58.084
58.092
58.099
58.106
58.112
58.118
58.123
58.127
58.131
58.135
58.139
58.142
58.145
58.147
58.150
58.152
58.155
58.157
58.159
58.160
58.162
58.164
58.165
58.167
58.168
58.169
58.170
58.172
58.173
58.174
58.175
58.175
58.176
58.177
ДИФТОРИД СВИНЦА PbF2
К°(Т) = р (РЬ) • p2(F) • р~ '(PbF2 j
Ф°(Г)
Дж • К ¦ моль
207.527
233.083
249.249
249.510
262.025
272.238
280.894
288.415
295.068
301.036
306.447
311.396
315.956
320.185
324.127
327.819
331.290
334.566
337.667
340.611
343.414
346.087
348.644
351.092
353.442
355.701
357.875
359.971
361.994
363.949
365.840
367.672
369.448
371.172
372.846
374.473
376.056
377.597
379.098
380.561
381.989
383.382
384.743
386.073
" 387.373
388.644
389.889
391.107
392.300
393.470
394.616
395.740
396.843
397.926
398.988
400.032
401.057
402.065
403.055
404.029
404.987
S°(T)
1
242.774
271.997
291.416
291.732
306.816
318.964
329.099
337.776
345.353
352.073
358.108
363.583
368.592
373.207
377.486
381.473
385.207
388.716
392.027
395.161
398.134
400.964
403.663
406.243
408.713
411.083
413.361
415.553
417.665
419.704
421.674
423.579
425.424
427.213
428.948
430.633
432.270
433.864
435.414
436.924
438.396
439.832
441.234
442.602
443.939
445.246
446.524
447.775
449.000
450.199
451.374
452.526
453.655
454.763
455.851
456.918
457.966
458.996
460.008
461.002
461.980
(г)
Таблица 523
Д Я°@)= 775.728 кДж • моль '
Я°(Г)-Я°@)
кДж • моль
3.525
7.783
12.572
12.667
17.916
23.363
28.923
34.553
40.227
45.933
51.661
57.405
63.162
68.928
74:702
80.482
86.267
92.056
97.848
103.643
109.441
115.241
121.043
126.846
132.651
138.457
144.264
150.072
155.880
161.690
167.500
173.311
179.123
184.935
190.747
196.560
202.373
208.187
214.001
219.815
225.630
231.445
237.260
243.075
248.891
254.707
260.522
266.339
272.155
277.971
283.788
289.605
295.422
301.238
307.056
312.873
318.690
324.508
330.325
336.143
341.960
\vK°(T)
Т
К
-397.2922 , 100
-193.7506 200
-126.5640 298.15
-125.7187 300
-91.6337 400
-71.1505 500
-57.4776 600
-47.7005 700
-40.3607 800
-34.6470 900
-30.0723 1000
-26.3265 1100
-23.2027 1200
-20.5577 1300
-18.2888 1400
-16.3211 1500
-14.5980 1600
-13.0764 1700
11.7228 1800
-10.5105 1900
-9.4184 2000
-8.4293 2100
-7.5290 2200
-6.7059 2300
-5.9504 2400
-5.2543 2500
-4.6107 2600
-4.0138 2700
-3.4585 2800
-2.9405 2900
-2.4561 3000
-2.0020 3100
-1.5754 3200
-1.1737 3300
-.7948 3400
-.4368 3500
-.0978 3600
.2236 3700
.5289 3800
.8192 3900
1.0956 4000
1.3592 4100
1.6109 4200
1.8514 4300
2.0816 4400
2.3021 4500
2.5135 4600
2.7163 4700
2.9112 4800
3.0986 4900
3.2788 5000
3.4524 5100
3.6197 5200
3.7810 5300
3.9367 5400
4.0871 5500
4.2324 5600
4.3729 5700
4.5088 5800
4.6404 5900
4.7678 6000
1 к
ж 9 "
t я ¦ -*
rr in г~"
11 О gj -н'
S, ? ° *
о"" Си
^ о
JT- а;
_+
00
12 -
? о
'й i я
^ к §
о |=[ ^
° & *,
1 00
¦S ? §
ОО "О
11 \
о ф
1 ^
2 $ "
m """:
¦ч- о
и +
ь
о
©
324

Класс точности
111 I
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
Р
31.233
34.886
36.229
36.245
36.836
37.155
37.357
37.503
37.619
37.719
37.812
37.905
38.003
38.112
38.235
38.375
38.533
38.710
38.904
39.116
39.342
39.580
39.829
40.087
40.350
40.617
40.885
41.153
41.419
41.680
41.935
42.183
42.421
42.650
42.866
43.070
43.260
43.435
43.595
43.740
43.868
43.979
44.075
44.153
44.215
44.261
44.291
44.306
44.306
44.292
44.264
44.223
44.170
44.105
44.030
43.945
43.851
43.748
43.638
43.520
43.397
ХЛОРИД СВИНЦА PbCl (г)
К°(Т) = р (РЬ) • р (С1) ¦ Р~ '(PbCl)
Ф°(Г)
Дж ¦ К ¦ моль
194.563
215.647
228.486
228.689
238.279
245.893
252.215
257.624
262.353
266.555
270.336
273.774
276.927
279.838
282.543
285.070
287.441
289.675
291.787
293.790
295.697
297.515
299.254
300.920
302.520
304.060
305.543
306.975
308.359
309.698
310.997
312.256
313.479
314.669
315.826
316.954
318.052
319.124
320.171
321.193
322.192
323.169
324.125
325.061
325.978
326.877
327.757
328.621
329.469
330.300
331.117
331.919
332.706
333.480
334.241
334.989
335.724
336.447
337.159
337.860
338.549
S°(T)
1
224.148
247.109
261.32.9
261.554
272.072
280.328
287.122
292.892
297.907
302.344
306.323
309.931
313.234
316.280
319.109
321.751
324.233
326.574
328.792
330.901
332.913
334.839
336.685
338.462
340.173
341.826
343.424
344.972
346.474
347.932
349.349
350.728
352.071
353.380
354.656
355.902
357.118
358.306
359.466
360.600
361.710
362.794
363.855
364.893
365.909
366.903
367.87
368.829
369.762
370.676
371.570
372.446
373.304
374.145
374.969
375.776 .
376.567
377.342
378.102
378.847
379.577
Д/.Я°@)= 305.000
Я°(Г)-Я°@)
кДж ¦ моль
2.959 -156.2586
6.292 -76.1976
9.792 -49.7757
9.859 -49.4433
13.517 -36.0376
17.218 -27.9772
20.944 -22.5925
24.687 18.7385
28.444 -15.8424
32.211 -13.5857
35.987 -11.7772
39.773 -10.2950
43.568 -9.0578
47.374 -8.0093
51.191 -7.1092
55.022 -6.3278
58.867 -5.6431 .
62.729 -5.0379
66.610 -4.4990
70.511 -4.0160
74.433 -3.5804
78.379 -3.1855
82.350 -2.8256
86.345 -2.4963
90.367 -2.1936
94.416 -1.9143
98.491' -1.6557
102.593 -1.4155
106.721 -1.1918
110.876 -.9827
115.057 -.7869
119.263 -.6030
123.493 -.4299
127.747 -.2667
132.023 -.1125
136.320 .0335
140.636 .1720
144.971 .3035
149.323 .4287
153.690 .5478
158.070 .6615
162.463 .7701
166.866 .8739
171.277 .9733
175.696 1.0686
180.120 1.Г599
184.547 1.2477
188.977 1.3320
193.408 1.4131
197.838 1.4911
202.266 1.5663
206.690 1.6388
211.110 1.7088
215.524 1.7763
219.930 1.8416
224.329 1.9047
228.719 1.9657
233.099 2.0248
237.468 2.0820
241.826 2.1375
246.172 2.1913
кДж • моль"
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 524
'л
Г §
к 2 Т
° ¦* ч
ОС А
***** 00 '
8. ч u а
гч' 2 О" „,
гч и ' JQ J*
Ч ^ ОО чо
^ <~ м il
II
—¦ U
л —" о «
w ?> ^
Э; о^
Jr- а;
1
•о
о
m 'л
 О
о S
+ *
OS • t^
Om S
8 1 ^
ч - V
5 cJ |
оо "ч ""
СУ* 00 —Г
О г-* Т
od *2 'о
гл jq —
rt + ^.
OO VI
* о ч
S5 гч ^
CO 00
II 1
о
325

Класс точности
VII-E
Т
К
100
200
298.15
300
400
500
600
700
774
774
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
С°{Т)
57.500
70.100
76.985
77.071
80.726
83.417
85.727
87.858
89.371
111.000
111.000
111.000
111.000
111.000
111.000
111.000
111.000
111.000"
111.000
111.000
111.000
111.000
111.000
111.000
111.000
111.000
ДИХЛОРИД СВИНЦА РЬС12
*°(Г) = Р(РЬС12
Ф°(Г)
Дж . К • моль
28.350
57.700
78.479
78.835
96.198
110.685
123.139
134.083
141.418
141.418
144.789
156.882
167.793
177.731
186.854
195.286
203.124
210.446
217.316
223.786
229.900
235.695
241.202
246.450
251.461
256.255
)
5°(Г)
1
63.500
107.400
136.000
136.476
159.186
177.499
192.916
206.292
215.196
243.297
246.964
260.038
271.733
282.313
291.971
300.855
309.081
316.740
323.904
330.633
336.977
342.979
348.672
354.088
359.252
364.186
(к, ж)
Д Я°@)= 187.000
Я°(Г)-Я°@)
кДж . моль"
3.515
9.940
17.150
17.292
25.195
33.407
41.866
50.547
57.104
78.854
81.740
92.840
103.940
115.040
126.140
137.240
148.340
159.440
170.540
181.640
192.740
203.840
214.940
226.040
237.140
248.240
lg.K°(T)
-87.5441
-38.7717
-22.8361
-22.6375
-14.6810
-9.9706
-6.8764
-4.7015
-3.4728
-3.4728
-3.1469
-2.0924
-1.2798
-.6402
-.1282
.2873
.6282
.9105
.1459
.3435
.5101
.6511
.7707
.8723
.9588
2.0322
кДж • моль"
Г
К
100
200
298.15
300
400
500
600
700
774
774
«00
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
Таблица 525
1
'ё
— о
i S
А .
К
о *
• и Т
К О R
EJ О О
° <3 i
О II •
rt со ,_ %
ОО II « —1
гч О оо" t
¦? D о «
С- л to
о s-
а; о""
"^
О 'j^
00 ^-v 7
S ^ ^s g
§ p s I
° 7 v *~ <¦»
r ^ + V
Л 1 V g h
CO _• UO -" \/
о 7 -1 о v
^ И И н *
h 2 ° 2
CO CN CO
¦ и °! / e /
П » I * N
II + ^ || 3
s s
о о
326

Класс точности
V-E
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
44.276
52.454
55.298
55.330
56.515
57.099
57.427
57.629
57.761
57.852
57.918
57.967
58.004
58.033
58.056
58.074
58.090
58.102
58.113
58.122
58.130
58.136
58.142
58.147
58.151
58.155
58.159
58.162
58.164
58.167
58.169
58.171
58.173
58.175
58.176
58.178
58.179
58.180
58.181
58.182
58.183
58.184
58.185
58.185
58.186
58.187
58.187
58.188
58.188
58.189
58.189
58.190
58.190
58.191
58.191
58.191
58.192
58.192
58.192
58.193
58.193
*-(Г)-„(РЬ
Ф°(Г)
ДИХЛОРИД
)V(ci).P-(Pb
S°(T)
Дж . К~' . моль
222.347
250.428
268.489
268.780
282.636
293.801
303.159
311.217
318.293
324.601
330.291
335.474
340.233
344.632
348.722
352.543
356.129
359.507
362.699
365.725
368.601
371.343
373.960
376.465
378.867
381.174
383.392
385.529
387.591
389.582
391.507
393.370
395.176
396.927
398.627
400.279
401.885
403.449
404.971
406.454
407.901
409.312
410.690
412.036
413.352
414.639
415.898
417.130
418.337
419.519
420.677
421.813
422.928
424.021
425.094
426.148
427.183
428.200
429.199
430.182
431.148
260.220
293.889
315.453
315.795
331.897
344.577
355.019
363.888
371.592
378.401
384.500
390.023
395.068
399.712
404.014
408.020
411.768
415.290
418.612
421.754
424.735
427.572
430.276
432.861
435.336
437.710
439.99!
442.186
444.301
446.342
448.314
450.221
452.068
453.858
455.595
457.281
458.920
460.515
462.066
463.577
465.050
466.487
467.889
469.258
470.596
471.904
473.183
474.434
475.659
476.859
478.034
479.187
480.317
481.425
482.513
483.580
484.629
485.659
486.671
487.666
488.644
СВИНЦА РЬС12
С12) ДГА
Я°(Г)-Я°@)
кДж . моль"
3.787
8.692
14.002
14.105
19.704
25.388
31.116
36.869
42.639
48.420
54.209
60.003
65.802
71.604
77.408
83.215
89.023
94.833
100.643
106.455
112.268
118.081
123.895
129.709
135.524
141.340
147.155
152.971
158.788
164.604
170.421
176.238
182.055,
187.873
193.690
199.508
205.326
211.144
216.962
222.780
228.598
234.416
240.235
246.053
251.872
257.690
263.509
269.328
275.147
280.965
286.785
292.603
298.423
304.242
310.061
315.880
321.699
327.518
333.337
339.157
344.976
(г)
Г°@)= 608.613
\g.K°(T)
-309.9638
-150.2211
-97.5323
-96.8697
-70.1528
-54.0984
-43.3794
-35.7118
-29.9532
-25.4683
-21.8759
-18.9331
-16.4780
-14.3983
-12.6137
-11.0654
-9.7091
-8.5109
-7.4446
-6.4894
-5.6284
-4.8483
-4.1381
-3.4884
-2.8918
-2.3419
-1.8332
-1.3611
-.9217
-.5116
-.1279
.2321
.5705
.8892
1.1901
1.4747
1.7442
2.0000
2.2430
2.4743
2.6947
2.9050
3.1059
3.2981
3.4821
3.6584
3.8276
3.9901
4.1462
4.2964
4.4411
4.5804
4.7148
4.8444
4.9696
5.0906
5.2075
5.3207
5.4302
5.5363
5.6391
кДж • моль '
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Т л ft
1 а о
—
'л
о
S
¦<¦
о
•о
Г-
^ч !
00 II
5ч <¦"•
II °.
5| - ¦
U
?
<
+
7
0.42
оль"
+ 2
ё '«
3 ^
О (Г,
1 m
* l
^ Н
""*¦ 00
со о
? d
+ 1
ON К
2 g
Tf О
II +
0
лица
\з
о
*f
00
•*
•/¦>'
,_ц
1
II
„
и"
ь
>¦-.
526
(
К
1
II
О К
to
1
V
V
§
»'*
"о
II
327

Класс точности
VI-D
7"
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1386.5
1386.5
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
Ср°(Г)
39.750
47.610
49.499
49.566
51.664
52.396
52.752
53.072
53.497
54.096
54.904
55.941
57.220
58.749
60.276
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
67.000
СУЛЬФИД СВИНЦА PbS (к, ж)
К°(Т)= p(PbS)
Ф°(Т)
Дж • К~' .моль"
18.630
38.280
52.595
52.834
64.403
73.946
82.066
89.127
95.374
100.977
106.063
110.723
115.032
119.044
122.312
122.312
123.151
129.070
134.529
139.593
144.312
148.731
152.885
156.802
160.509
164.025
167.370
170.559
173.606
176.523
179.319
182.006
184.590
А Я°@) = 229.500 кДж • моль
S
S°(T)
1
Я°(Г)-Яо@)
кДж ¦ моль
41.310 2.268
71.940 6.732
91.200 11.510
91.506 11.602
106.109 16.683
117.729 21.891
127.316 27.150
135.471 32.441
142.584 37.768
148.917 43.146
154.657 48.594
159.936 54.134
164.857 59.790
169.496 65.587
173.328 70.733
208.957 120.133
209.606 121.038
214.229 127.738
218.553 134.438
222.615 141.138
226.444 147.838
230.067 154.538
233.504 161.238
236.772 167.937
239.889 174.637
242.868 181.337
245.719 188.037
248.454 194.737
(k«i Л А А ЛЛ 1 JO?
251.082 201.437
253.611 208.137
256.047 214.837
258.398 221.537
260.670 228.237
-111.0948
-51.1094
-31.4797
-31.2340
-21.3654
-15.4852
-11.5927
-8.8321
-6.7766
-5.1896
-3.9298
-2.9073
-2.0625
-1.3543
-.8288
-.8288
-.7712
-.3797
-.0436
.2475
.5012
.7238
.9202
1.0942
.2493
1.3878
1.5122
.6241
TOR I
.7Zo\
.8166
.8997
.9752
2.0441
Г
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1386.5
1386.5
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
ZdOO
2700
2800
2900
3000
ЧО
О1
rv
II
Si
1
1—
s
оо
d
г»
'а
СП
о
О
О
1
t
?
ON
о
VD
СП
On
vO
ОС
V
rs
II
ь
Таблица 527
1
о
"л s
g Л -
? 3 §
ц 2 . т
* о"! 7
^" 1
-99.8
К) =-
1Дж
11 ' 2 2
сГ оо (Ч
_ * у" _,
от •*• ct
•° ** о в?
Ъ ?> Ъ
°Х о"
1
1
'« i " !•
1 2 S 5Q'
" V « V
'« ь 2 к.
* v н V
* 5 о 2
R as г^ гл
сП d \О •—«
5 т* » т"
« 2 S 2
°- С - к
ON || СЧ ||
| >—' II ~—'
?
0 •
328

Класс точности
I-D
'/
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Ср°(Г)
29.788
33.141
35.087
35.111
36.076
36.599
36.918
37.131
37.284
37.403
37.500
37.583
37.656
37.723
37.786
37.847
37.908
37.971
38.037
38.1
1
38.194
38.289
38.400
38.531
38.684
38.864
39.074
39.318
39.598
39.919
40.281
40.687
41.139
41.637
42.181
42.772
43.407
44.086
44.806
45.563
46.355
47.177
48.024
48.893
49.777
50.671
51.570
52.468
53.360
54.238
55.099
55.937
56.746
57.523
58.263
58.961
59.616
60.223
60.781
61.287
61.739
л (/) * р (РЬ) •
Ф°(Г)
Дж ¦ К . моль
186.757
207.308
219.673
219.869
229.119
236.488
242.628
247.897
252.513
256.623
260.327
263.699
266.795
269.655
272.315
274.800
277.132
279.329
281.406
283.376
285.250
287.036
288.742
290.376
291.943
293.450
294.900
296.300
297.650
298.957
300.222
301.449
302.640
303.799
304.926
306.024
307.095
308.141
309.163
310.163
311.142
312.101
313.043
313.967
314.875
315.768
316.646
V7.5I1
318.363
319.203
320.032
320.850
321.657
322.454
323.242
324.021
324.792
325.554
326.308
327.054
327.792
СУЛЬФИД СВИНЦА PbS (г)
D(S)-p(PbS)
S°(T)
1
215.967
237.662
251.303
251.520
261.768
269.880
276.583
282.291
287.260
291.658
295.604
299.183
302.456
305.473
308.270
310.880
313.324
315.624
317.796
319.855
321.812
323.677
325.461
327.171
328.814
330.397
331.925
333.404
rt Л Л ЛЛУ\
334.839
336.234
337.593
338.921
340.219
341.493
342.744
343.975
345.189
346.387
347.572
348-746
349.909
351.064
352.211
353,351
354.485
355.614
356.737
357.856
358.970
360.079
361.18*
362.2S3
363.377
364.465
365.548
366.623
367.692
368.752
369.805
370.848
371.882
Д,А
Н°(Т)-Н°@)
кДж ¦ моль
2.921
6.071
9.430
9.495
13.060
16.696
20.373
24.076
27.797
31.532
35.277
39.032
42.794
46.563
50.338
54.120
57.907
61.701
65.502
69.309
73.124
76.948
80.783
84.629
88.489
92.367
96.263
100.183
104.128
108.104
112.113
116.161
120.252
124.390
128.581
132.828
137.137
141.51!
145.955
150.474
155.069
159.746
164.505
169.351
174.284
179.307
184.419
189.621
194.912
200.292
20S.759
2П.311
216.946
222.659
228.449
234.311
240.240
246.232
252.283
258.386
264.538
Г°@) = 341.000 кДж ¦ моль
-174.6227
-85.1169
-55.5521
-55.1800
-40.1696
-31.1422
-25.1117
-20.7961
-17.5545
-15.0292
-13.0061
-11.3485
-9.9653
-8.7933
-7.7874
-6.9145
-6.1495
-5.4735
-4.8716
-4.3321
-3.8456
-3.4044
-3.0024
-2.6344
-2.2961
-1.9839
-1.6947
-1.4261
-1.1.757
-.9417
-.7224
-.5164
-.3225
-.1396
.0332
.1969
.3521
.4995
.6397
.7732
.9005
.0220
.1381
.2491
.3554
.4572
.5548
.64Б4
1.7383
1.8248
1.9076
1.9874
2.0642
2.1381
2.2093
2.2779
2.3440
2.4078
2.4693
2.5287
2.5860
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500 '
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 528
Й i, 'л
2 Д §
• и г
X оо 1
00 Г- ~
уо ^ 7 Л
? - я я
'l - "
ел ^ Я
? 2 Ъ5
О й*
¦Ч о
¦-> а: ¦
< ^
1
н
ГО 1
Ov JS
00 О
о 2
+ —
о к Я
? пч §
§ й *°
о оо \/
н t *
•a J 8
ON Ц \Г)
•* ? „.'-
*О рС О
¦ч- ю -¦
+ + L*
о х к
? g II
" to
It 1
0
©
329

класс точности
VI-G
Т
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
С°(Т)
ДИСУЛЬФИД
К°(Т) =p(Pb) •p2(S)-p(PbS)
Ф°(Г)
S°(T)
Дж • К • моль
44.291
53.390
57.510
57.560
59.459
60.438
60.999
61.348
61.579
61.739
61.855
61.941
62.007
62.058
62.099
62.132
62.160
62.182
62.201
62.217
62.231
62.243
62.253
62.262
62.270
62.276
62.283
62.288
62.293
62.297
62.301
62.305
62.308
62.31
62.314
62.316
62.319
62.321
62.323
62.324
62.326
62.328
62.329
62.330
62.332
62.333
62.334
62.335
62.336
62.337
62.338
62.338
62.339
62.340
62.341
62.341
62.342
62.342
62.343
62.343
62.344
193.821 230.004
221.072 263.828
238.998 286.025
239.289 286.380
253.258 303.232
264.637 316.616
274.250 327.689
282.574 337.120
289.917 345.328
296.485 352.591
302.427 359.102
307.851 365.002
312.842 370.394
317.462 375.360
321.764 379.960
325.788 384.246
329.569 388.257
333.133 392.026
336.504 395.581
339.703 398.944
342.746 402.136
345.647 405.172
348.419 408.068
351.073 410.836
353.618 413.485
356.064 416.028
358.418 418.470
360.686 420.821
362.874 423.086
364.988 425.272
367.033 427,384
369.013 429.427
370.932 431.405
372.794 433.323
374.602 435.183
376.359 436.989
378.067 438.745
379.730 440.452
381.350 442.114
382.929 443.733
384.469 445.312
385.972 446.850
387.439 448.352
388.873 449.819
390.275 451.252
391.645 452.653
392.986 454.023
394.299 455.364
395.585 456.676
396.845 457.961
398.080 459.220
399.291 460.455
400.479 461.665
401.645 462.853
402.789 464.018
403.913 465.162
405.016 466.285
406.101 467.389
407.167 468.473
408.215 469.539
409.246 470.587
{ СВИНЦА PbS2 (г)
АгН°@)= 625.443
Я°(Г)-Я°@)
кДж ¦ моль
3.618 -317.2002
8.551 -152.9887
14.021 -98.7999
14.127 -98.1182
19.990 -70.6350
25.989 -54.1240
32.064 -43.1063
38.182 -35.2308
44.329 -29.3209
50.496 -24.7223
56.676 -21.0420
62.866 -18.0299
69.063 -15.5192
75.267 -13.3941
81.475 -11.5722
87.686 -9.9928
93.901 -8.6104
100.118 -7.3902
106.337 -6.3051
112.558 -5.3336
118.781 -4.4588
125.004 -3.6666
131.229 -2.9458
137.455 -2.2869
143.681 -1.6822
149.909 -1.1251
156.137 • -.6101
162.365 -.1324
168.594 .3120
174.824 ' .7267
181.054 1.1145
187.284 1.4781
193.515 1.8198
199.746 2.1416
205.977 2.4453
212.208 2.7324
218.440 3.0043
224.672 3.2623
230.904 3.5074
237.137 3.7405
243.369 3.9627
249.602 4.1747
255.835 4.3772
262.068 4.5708
268.301 4.7562
274.534 4.9338
280.767 5.1043
287.001 5.2680
293.234 5.4253
299.468 5.5766
305.702 5.7223
311.935 5.8627
318.169 5.9980
324.403 6.1286
330.637 6.2547
336.871 6.3766
343.105 6.4944
349.340 6.6084
355.574 6.7188
361.808 6.8256
368.043 6.9292
кДж • моль
Г
к
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
2600
2700
2800
2900
3000
3100
3200
3300
3400
3500
3600
3700
3800
3900
4000
4100
4200
4300
4400
4500
4600
4700
4800
4900
5000
5100
5200
5300
5400
5500
5600
5700
5800
5900
6000
Таблица 529
-
_ о
1 2
А
§ х Т
* §
9 Я _¦
а «= L.
§ - *
О
—' — S 2
С~- II 1П г^
ГЧ ^ —;; о
II О g> ^
^ U ГЧ ~™
? й? ° «
Ъ 2 ^
о С-
*С о
>-. а;
_+
i
го
+ 1
? ; §
гч Д §
о ¦-»
а п у
о Ь-
* 5 v
с ° о
~ + о
ГЧ !/">
о ^
о Д ^*-
^i го 1
гч гч О
*> 6
_ ' к.
ее Н ц
<** S ^
tJ" О
II +
5^
о
330

ДОПОЛНЕНИЕ

Таблица Д. 27
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
УГЛЕРОД С (к, алмаз)
М =12.011
Таблица Д. 28
ДИОКСИД КРЕМНИЯ SiO2 (к, кварц)
М =60.0843
Ср(Т) Ф°(Г) S°(T)
ДжК моль
.260
2.350
6.109
6.201
10.321
13.404
15.885
17.930
19.619
21.006
22.129
23.020
23.709
24.222
24.585
24.824
24.964
25.030
25.045
25.034
25.021
25.031
25.087
25.214
25.436
25.776
.012
.177
.608
.619
1.352
2.301
3.379
4.527
5.707
6.898
8.084
9.256
10.406
11.532
12.630
13.699
14.737
15.745
16.723
17.672
18.591
19.482
20.347
21.186
22.001
22.793
.072
.757
Я°(Г)-#°@)
кДж • моль
-1
2.40
4.783
7.431
10.102
12.709
15.217
17.611
19.884
22.037
24.071
25.990
27.799
29.504
31.111
32.627
34.058
35.412
36.696
37.916
39.082
40.200
41.277
42.322
.006
, .116
.523
.534
1.373
2.565
4.034
5.728
7.608
9.641
11.800
14.059
16.397
18.795
21.237
23.708
26.198
28.699
31.203
33.707
36.209
38.712
41.217
43.731
46.263
48.822
К
Ф°(Г)
S°(T)
ДжК моль
100
200
298.15
300
400
500
600
700
800
848
848
900
1000
1100
1200
1300
1400
1500
1600
1696
15.690
32.640
44.602
44.719
53.422
60.585
64.522
68.063
76.391
84.070
67.446
67.953
68.941
69.940
70.947
71.960
72.977
73.997
75.019
76.002
3.334
10.607
18.264
18.408
26.021
33.262
40.106
46.535
52.582
55.378
55.378
58.351
63.765
68.822
73.567
78.037
82.265
86.276
90.094
93.597
9.694
26.087
41.460
41.736
55.743
68.500
79.929
90.118
99.662
104.319
104.803
108.832
116.042
122.660
128.789
134.507
139.877
144.947
149.755
154.155
Н°(Т)-Наф)
кДж • моль"
.636
3.096
6.916
6.999
11.889
17.619
23.894
30.508
37.664
41.503
41.913
45.433
52.278
59.222
66.266
73.411
80.658
88.007
95.457
102.706
332

Таблица Д. 29
ДИОКСИД КРЕМНИЯ SiO2 (к, кристобалит)
М =6С.О843
К
Ф°(Г)
S°(T)
Дж • К~' ¦ моль"'
100
200
298.15
300
400
500
543
543
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
1996
16.000
43.000
44.937
44.925
52.892
70.866
115.330
59.998
62.567
65.602
67.542
68.867
69.831
70.580
71.199
71.743
72.249
72.739
73.232
71710
74.271
74.832
75.403
4.387
11.958
19.798
19.945
27.681
34.975
38.060
38.060
42.138
48.839
55.038
60.799
66.174
71.207
75.937
80.396
84.612
88.611
92.413
96.037
99.499
102.815
105.871
11.247
27.878
43.400
43.680
57.889
70.495
77.893
77.893
84.015
93.906J
102.802
110.838
118.146
124.838
131.007
136.728
142.063
147.064
151.775
156.229
.160.459
164.490
168.192
Н°(Т)-Н°@)
кДж ¦ моль
.686
3.184
7.037
7.120
12.083
17.760
21.629
21.629
25.126
31.547
38.211
45.03*5
51.972
' 58.994
66.084
73.231
80.431
871681
94.979
102.328
109.728
117.183
124.394
Таблица Д. 30
ДИОКСИД КРЕМНИЯ SiO2 (к, тридимит)
М = 60.0843
Ф°(Г)
Дж • К"' • моль"
100
200
298.15
300
388
388
400
433
433
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
1953
16.230
33.260
44.642
44.961
56.403
56.402
56.980
58.571
58.571
60.401
63.122
65.423
67.178
68.414
69.225
69.735
70.084
70.423
70.907
71.695
72.949
74.829
77.500
81.125
83.490
4.280
11.940
19.794
19.941
26.843
26.843
27.792
30.370
30.370
35.492
42.668
49.302
55.447
61.161
66.494
71.487
76.176
80.594
84.769
88.724
92.485
96.071
99.504
102.802
104.502
11.280
27.980
43.510
43.787
56.890
57.586
59.312
63.892
64.238
72.791
84.048
93.958
102.815
110.803
118.056
124.680
130.763
136.386
141.621
146.538
151.202
155.678
160.026
164.309
166.572
Н°(Т)-Н°@)
кДж • моль"
.700
3.208
7.071
7.154
11.658
11.928
12.608
14.515
14.665
18.649
24.828
31.260
37.894
44.678
51.563
58.513
65.504
72.529
79.594
86.721
93.948
101.331
108.940
116.863
121.224

ДИОКСИД КРЕМНИЯ SiO2
М =60.0843
Таблица Д. 31
(стекл.)
Таблица Д. 32
КАРБИД КРЕМНИЯ SiC (к, куб.)
М = 40.0965
К
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
1996
Ср(Т)
5° (Г)
Дж • К"' • моль
16.040
32.720
43.991
44.215
52.801
57.831
61.410
64.263
66.690
68.835
70.775
72.552
74.193
75.713
77.123
78.431
79.642
80.760
81.786
82.723
83.541
9.091
16.689
24.479
24.624
32.288
39.527
46.284
52.577
58.446
63.939
69.098
73.964
78.569
82.941
87.105
91.082
94.888
98.539
102.049
105.428
108.559
16.021
2.574
47.860
48.133
62.164
74.525
85.400
95.088
103.831
111.812
119.166
125.997
132.381
138.380
144.043
149.409
154.510
159.373
164.018
168.466
1Т2.564
Н°(Т)-Н°@)
кДж • моль
-1
.693
3.177
6.971
7.053
11.950
17.499
23.469
29.757
36.308
43.086
50.068
57.236
64.574
72.070
79.713
87.491
95.396
103.417
111.545
119.771
127.752
К
Ф°(Г)
S (Т)
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1400
1500
1600
1700
1800
1900
2000
2100
2200
2300
2400
2500
4.260
16.300
26.860
27.046
34.208
38.396
41.296
43.493
45.238
46.659
47.830
48.797
49.594
50.246
50.776
51.203
51.543
51.812
52.025
52.197
52.342
52.475
52.608
52.755
52.930
53.147
Дж
т
К ' • моль"'
.330
2.383
5.636
5.704
9.592
13.629
17.602
21.425
25.070
28.534
31.824
34.951
37.927
40.763
43.471
46.059
48.537
50.913
53.195
55.389
57.500
59.536
61.499
63.397
65.231
67.007
1.460
8.033
16.610
16.777
25.649
33.766
41.036
47.574
53.500
58.913
63.892
68.497
72.778
76.774
80.518
84.036
87.352
90.485
93.453
96.271
98.952
101.509
103.953
106.295
108.544
110.708
Н°(Т)-Н°@)
кДж • моль
.113
1.130
3.272
3.322
6.423
10.068
14.060
18.304
22.744
27.341
32.067
36.900
41.821
46.814
51.866
56.966
62.104
67.272
72.464
77.676
82.903
88.144
93.398
98.666
103.950
109.253
334

диоксид
ПРМАНИЯ GeO2
М = 104.5X9
Та б л и цаД. 33
(к. гекс.)
ДИОКСИД
ГЕРМАНИЯ GcO2
М = 104.589
Т а б л и ц а Д. 34
(стекл.)
К
Ср(Т) Ф°(Г) S°(T)
Дж ¦ К ¦ моль
Н°(Т)~Н°@)
кДж ¦ моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1388
22.560
40.670
52.091
52.294
59.922
64.217
67.200
69.564
71.597
73.439
75.161
76.806
78.398
79.952
81.297
5.330
15.690
25.771
25.954
35.443
44.139
52.083
59.363
66.067
72.278
78.064
83.482
88.579
93.396
97.427
14.970
36.710
55.270
55.593
71.809
85.678
97.662.
108.204
117.629
126.170
133.997
141.238
147.990
154.327
159.607
.964
4.205
8.795
8.892
14.547
20.770
27.348
34.189
41.249
48.502
55.933
63.532
71.293
79.210
86.305
Ср(Т,
Ф°(Г)
S°(T)
H°(T)-H°W>
Дж • К ' ¦ моль"'
100
20U
298.15
300
400
500
600
700
800
900
1000
1100
1200
1300
1388
23.180
41.670
53.004
53.149
59.301
63.625
67.043
#9.870
Г2.239
74.213
75.824
77.093
78.030
78.641
78.915
17.990
28.910
39.389
39.578
49.300
58.112
66. Ив
73.433
80.171
86.416
92.238
97.691
102.820
107.661
111.705
кДж • моль
28.630
50.880
69.800
70.128
86.327
100.046
111.959
122.512
132.001
.140.628
148.533
155.822
162.573
168.844
174.006
1.064
4.379
9.067
9.165
14.810
20.967
27.506
34.356
41.465
48.790
' 56.295
63.944
71.703
79.539
86.473
335

Т а б л и ц а Д. 35
ОКСИД СВИНЦА РЬО (к. ромб.)
М =223.20
Таблиц а. Д. 36
ДИОКСИД СВИНЦА РЬО2
М = 239.20
(к)
Ф°(Г)
К
Дж • К ¦ моль
100
200
298.15
300
400
500
600
700
800
900
1000
1100
1160
27.700
40.040
45.772
45.836
48.521
50.476
52.144
53.677
55.137
56.555
57.948
59.323
60.142
12.708
26.600
37.716
37.908
47!439
55.603
62.736
69.078
74.795
80.009
84.809
89.264
91.794
28.078
51.590
68.700
68.983
82.565
93.610
102.963
111.118
118.381
124.957
130.988
136.576
139 748
Н°(Т)~Н°(Т)
кДж • моль
1.537
4.999
9.238
9.323
14.050
19.004
24.136
29.428
34.869
40.454
46.179
52.043
55.627
К
С°(Т) Ф°(Г) S°(T)
Дж • К • моль '
100
?00
298.15
300
400
500
600
700
800
900
1000
29.870
49.960
60.997
61.302
72.199
77.466
80.517
82.522
83.969
85.092
86.014
8.420
22.380
35.153
35.381
47.079
57.708
67.384
76.217
84.319
91.789
98.712
22.140
49.680
71.920
72.298
91.642
108.379
122.794
135.366
146.484
156.442
165.456
Н°(Т)-Н°(Т)
кДж • моль
1.372
5.460
10.962
11.075
17.825
25.335
33.246
41.404
49.732
58.188
66.744
336

ТаблицаД. 37
ТРИОКСИД ДИСВИНЦА РЬ2О3 (к)
М =462.40
Та б л ицаД. 38.
ТЕТРОКСИД ТРИСВИНЦА РЬ3О4 (к)
М =685.60
К
Дж • К • моль"
100
200
298.15
300
400
500
600
700
800
900
1000
60.330
92.010
107.701
108.166
126.089
136.816
144.710
151.268
157.112
162.542
167.714
27.000
56.850
81.868
82.302-
104.195
123.645
141.186
157.168
171.862
185.477
198.176
59.100
111.900
151.900
152.568
186.416
215.781
241.451
264.263
284.849
303.671
321.066
Н°(Т)-Н°@)
кДж • моль
3.210
11.010
20.880
21.080
32.888
46.068
60.159
74.966
90.389
106.375
122.889
К
100
200
298.
300
400
500
600
700
800
900
1000
Ф°(Т)
Дж • К"' • моль '
15
86.730
130.000
146.705
147.659
181.990
199.115
209.466
216.620
222.069
226.527
230.370
29.900
74.300
111.250
111.869
143.017
170.782
195.941
218.911
240.014
259.518
277.641
79.500
155.000
211.300
212.210
260.051
302.685
339.969
372.825
402.120
428.541
452.611
кДж • моль"
4.960
16.156
29.830
30.102
46.814
65.951
86.417
107.740
129.685
152.121
174.970
337

КОНСТАНТЫ АППРОКСИМАЦИОННОГО УРАВНЕНИЯ
B* = L6tT"*+ Д(Т);
Вещество
С
СО
СО2
СН4
с2н2
С2Н4
с2н6
СН3ОНа
С2Н5ОНа
CF4
C2F4
CH3F
CH2F2
CHF3
Q2H3F
1,1-C2H2F2
ССЦ
C2C14
COC12
CH3C1
CH2C12
CHC13
C2H3C1
1,1-C2H2C12
цис-С2Н2С12
гране-С2Н2С12
C2HC13
CF3C1
CF2C12
CFCI3
C2F3C1
CHF2C1
CHFC12
C2HF2C1
CH3Br
CF3Br
CF2ClBr
CH3I
CS2
COS
C2N2
HCN
SiH4
SiF4
S1CI4
SiBr4
Sil4
GeCL,
SnCl4
аДля паров СН3ОН
Температурный
интервал,К
5000-17000
300-1000
270-1300
90-650
200-2000
240-450
270-620
420-570
330-475
270-1200
290-370
240-1000
250-500
230-800
290-370
270-370
300-1000
490-1500
230-1000
300-700
280-700
300-2000
290-370
390-1230
320-370
320-370
320-370
200-470
240-470
240-470
300-800
270-800
300-800
300-430
300-1000
200-550
270-500
300-1000
300-1000
300-1500
300-1000
300-385
200-1000
300-1500
400-1300
600-1500
700-2000
500-1200
500-1200
и С2Н5ОН в
к6
6810
132,91
304,19
190,555
308,33
282,35
305,37
_
_
322
306,45
317,75
351,55
100
327,88
302,85
497
613,15
455,15
416,25
510
1062
429,65
494,15
544,15
516,15
571,15
301,99
385,15
1000
378,95
369,30
100
400,55
482,6
340,05
426,88
617,5
696
378,8
489
456,65
269,65
621
508,1
663,15
850
553,2
591,9
дм • моль"
0,2540
0,0931
0,0940
0,0989
0,1197
0,1310
0,1484
0,1166
0,1669
0,1188
0,1724
0,1134
0,1210
0,1346
0,1430
0,1547
0,2390
1,1383
0,1902
0,1391
0,181
0,0334
0,1689
0,7861
0,220
0,220
0,2561
0,1888
0,2268
0,2480
0,7803
0,1682
0,1972
0,1974
0,0493
0,2077
0,2457
0,0593.
0,0656
0,4961
0,2577
0,1386
0,4627
0,0882
1,1758
1,3175
1,6566
1,1913
1,3127
таблице приведены данные для
учитывающей отклонение от свойств идеальной реагирующей смеси
Для SiH4 коэффициент Ь$ = —0
0005183.
V
0,225625
0,348696503
0,36187401
-0,133485596
0,580577
-0,700912774
0,582509996
0,6430425
0,71892
0,671946301
—
1,106917
-0,076719
0,615157765
_
1,2776
-0,745163311
0,225625
1,0087707
-1,925744
0,8794698
0,392443876
_
0,225625
_
_
-
1,4331744
2,2334876
1,5851452
0,225625
7,945819661
1,220839837
1,4488348
0,721712592
3,294414
0,7594939
0,777144162
0,716049204
0,15151
0,752303907
0,5231
0,149683
0,817950899
0,1614725
0,225625
0,225625
0,225625
0,225625
"физической" части
(см. раздел П3.5) .
-0,5625
1,032066850
-0,156319876
-4,212595607
-1,254930
4,749994920
-1,300120410
_
_
-0,548824381
_
-2,425223
-0,0736611
-4,709339766
_
-2,5135
2,22279903
-0,5625
-2,2606808
14,5545
-1,9116436
-0,934893157
¦ _
-0,5625
-
—
-
-4,0163674
-6,1242285
-1,0554625
-0,5625
. -30,23932921
-1,594122118
-2,7372032
-2,095480280
-10,278123
-1,1983505
-2,405677800
-2,11584611
-0,28584
-0,684348295
—
-0,29734
-0,454903761
-0,22305
-0,5625
-0,5625
-0,5625
-0,5625
второго вириалытого
Ьг
_
-15,62792150
-1,666161034
1,218381935
_
-9,871453780
-0,123116286
_
. -
-1,517444330
-
-
-0,5121074
3,640675073
_
_
1,08562259
_
-
-39,200524
—
-2,70381851
. _
_
-
-
-
2,8283709
4,6107181
-0,1149106
-
41,33521489
-1,137497409
_
-1,993518040
10,383809
-0,7653288
-0,839085662
-1.22455220
-0,18650
-0,426198445
-
-0,1740
-0,368800739
-0,25475
—
-
-
-
коэффициента,
338

ДЛЯ ВТОРОГО ВИРИАЛЬНОГО КОЭФФИЦИЕНТА
В* = B/Vo; т =Т/Т0
Таблица Д.39
-
1
60,9205150
0,013536087
-0,567664714
3,207143270
-0,532262218
1,880940430
-0,246847949
-0,135198853
46,277174
0,927533883
-
-1,4061183
-1,8752383
-25,76767957
0,576635353
0,282423126
-5,8042368
-0,463080676
-0,210666861
-0,0214 i 2
0,030867435
-0,018987
0,151822989
-0,0346525
*4
-136,9859080
0,191964155
-0,482550
5,980399390
0,260794012
-1,785966590
-0,8936611
-85,01252927
0,110045601
-27,063555
-0,2254457
-0,264955598
_
1 1 1 1
5,490918398
-0,300312886
-0,398016241
1,057367
0,267712074
-0,124504044
0,073906133
-0,102076564
160,7551420
0,139674374
-6,360398060
-0,076287900
0,876880459
-23,07108747
-
6,034419
_
1 1 l I
_
-0,141708132
-0,213992877
-0,115539231
0,024717085
вДля81С14 коэффициент b$ = —0,0016972.
г Для COS коэффициент bg = -0,0007.
-77,20521470
-0,149156928
1,797866380
-0,181902664
-0,212691
377,2730345
-0,0203208
_
1 1 1 1
_
0,086811906
0,056430196
0,050697177
-0,003291843
*7
1 l l l l l l I
-378,7575051
-
l I I I I l
-
1 1 1 1
_
-0,036153601
-0,008755204
г
-0,008351401
~б
в
Д(т)
2,573954837т/2
-60,640e-3'9l8689r
-35,702в-3'Г7О599:г
-
1 —С Д7СТ
20,124409- - е э'4
-8,073e-ll72~2896T
-31,074e-3'27S783T
-45,9417f-34'834^84T
-
_
-
-0,061 e5'064/r
339

КРИТИЧЕСКИЕ ПОСТОЯННЫЕ
Таблица Д. 40
Вещество
Гкр
К
МПа
кр
дм ¦ моль
Вещество
кр
К
кр
МПа
кр
ДМ ¦
с
СО
со2
сн4
с2н2
C2ft»
с2н6
СН3ОН
C2HSOH
CF4
C2F4
CH3F
CH2F2
CHF3
C2H3F
1,1-C2H2F2
ССЦ
C2Cl4
COC12
CH3C1
CH2C12
CHC13
C2H3C1
1,1-C2H2C12
4iic-C2H2Cl2
грвкс-С2Н2С12
6810
132,91
304,20
190,555
308,33
282,35
305,33
512,65
516,3
227,5
306,45
317,70
351,55
299,40
327,88
302,85
556,6
613,15
455,15
416,25
510
536,5
429,65
494,15
544,15
516,15
223
3,499
7,383
4,595
6,138
5,042
4,871
8,103
6,383
3,745
3,942
5,874
5,830
4,87
5,114
4,464
4,616
4,482
5,674
6,679
6,080
5,450
5,592
5,226
5,860
5,516
0,0188
0,0931
0,0940
0,0989
0,1197
0,1310
0,1471
0,1166
0,1669
0,1406
0,1724
0,1135
0,1210
0,1341
0,1430
0,1547
0,2760
0,2894
0,1902
0,1391
0,181
0,2388
0,1689
0,2203
0,2203
0,2203
Критические постоянные элементов получены оценкой.
C2HC13
CF3C1
CF2C12
CFC13
C2F3C1
CHF2C1
CHFC12
C2HF2C1
CH3Br
CF3Br
CF2ClBr
CH3
CS2
COS
C2N2
HCN
SiH4
SiF4
SiCL,
Sfflr4
Sil4
Gea
Sna
SnCl4
Pba
571,15
301,88
385,15
471,15
378,95
369,30
451,60
400,55
465
340,05
426,88
528
552,15
378,8
400
456,65
269,65
259
508,1
663,15
850
9170
553,2
8200
591,9
4980
4,895
3,880
4,131
4,381
4,063
4,988
5,190
4,469
6,941
3,958
4,254
6,718
7,903
6,349
5,978
5,390
4,846
3,715
3,593
4,185
4,266
490
3,861
335
3,749
184
0,2561
0,1794
0,2268
0,2480
0,2118
0,1682
0,1957
0,1974
0,206
0,2077
0,2457
0,1710
0,1730
0,1351
0,1386
0,3261
0,382
0,378
0,0443
0,3302
0,0579
0,351
0,0638
340

СОДЕРЖАНИЕ
ВВЕДЕНИЕ 5
УКАЗАТЕЛЬ ТАБЛИЦ 6
ТАБЛИЦЫ ТЕРМОДИНАМИЧЕСКИХ СВОЙСТВ 9
ДОПОЛНЕНИЕ 331

ТЕРМОДИНАМИЧЕСКИЕ
СВОЙСТВА
ИНДИВИДУАЛЬНЫХ
ВЕЩЕСТВ
Том II
Книга 2
Утверждено к печати
Институтом высоких температур
Академии наук СССР
Редактор издательства В.П. Сироткина
Художник В.Г. Виноградов
Художественный редактор Т.П. Поленова
Технический редактор Н.А. Посканная
Оригинал-макет издания подготовлен
с применением наборно-печатающей техники
В.В. Тарасовой и В.В. Несновой
по технологии, разработанной
В.И. Васильевым,
на основе таблиц, полученных фотонабором с ЭВМ
ИБ№ 16593
Подписано к печати 25.12.79. Т - 22215
Формат 84 х 108 1/16. Бумага типографская № 1
Печать офсетная. Усллечл. 36,1. Уч.-издл. 55,3
Тираж 7100 экз. Тип зак. 1034.
Цена II т. (кн. 1 и 2) 8р. 10 к.
Издательство "Наука", 117864 ГСП-7, Москва В-485,
Профсоюзная ул., д. 90;
Ордена Трудового Красного Знамени
1-я типография издательства "Наука", 199034, Ленинград,
В-34, 9-я линия, 12

ИСПРАВЛЕНИЯ И ОПЕЧАТКИ
К ТОМУ 1 КН. 2 "ТЕРМОДИНАМИЧЕСКИЕ СВОЙСТВА
ИНДИВИДУАЛЬНЫХ ВЕЩЕСТВ"
Страница
27
29
29
29
29
37
99
128
144
145
165
Строка
38 сн.
19 сн.
18 сн.
17 сн.
16 сн.
Боковик,
2 сн.
Боковик,
3 сн.
Боковик,
2сн.
Боковик,
1 сн.
Боковик
Боковик,
Напечатано
25.8761
2.3730
2.4173
2.2626
2.3085
-10.714Х3
+0.0021118х~2
2.1503
20000 К
20000 К
Должно быть
27.8761
2.2719
2.3184
2.3635
2.4071
+10.714*3
-0.0021 118jc~2
2.150х3
6000 К
Ф°B1 = 205.4227+19.03131п* +
+ 0.0052176jc - 0.19147jc™1 +
+ 2.835 Зх- 1:438х2 + 0.332*3
(x=jT-10~4; 1000<Г<20000К)
6000 К
166
168
180
212
234
240
250
253
253
253
254
1 сн.
Боковик
Боковик,
2 сн.
Боковик,
Зсн.
Боковик,
Зсн.
Боковик,
Зсн.
Боковик,
2 сн.
Боковик,
2 сн.
1 св.
2 св.
2 св.
Боковик,
2сн.
.-2
+0.137х3
57.56681iu
+0.004673 \х
+0.0263714д:
1.309х3
13.327Х2
Гидрид-фторид
азота NHF (г)
p(N)-p(H)-p(F)-p
(NHF)
694.175 кДж • моль 1144.590 кДж • моль
-1
-1
Ф°(Л =235.2617+27.34011пх-
- 0.0404248л:+ 1.33318Х -
- 10.4303*+ 0.987л:2 + 1.215л:3
(дс=Г-10~4; 1000<Г<20000К)
-0.137*3
157,56681лх
-0.0046731л:
-0.0263714*
16.309л:3
13.827л-2
Диоксид-фторид азота FNO2 (г)
p<F)-p(N)p2(O)p(FNO2)
-1
1.927JT
10.927л3

Страница
264
280
285
286
294
300
323
Строка
Боковик,
2 и 3 сн.
Пен.
Боковик,
Зсн.
Боковик,
2 и 3 сн.
1 св.
16 сн.
10 сн.
справа
Напечатано
Ф° (Г) =305.7304 +
+ 36.2305 lnx-
-0.0027581х~2 +
+ 0.37249х""' +
+ 8.6030х-11.278х2+
+ 9.260Х3
981.421
-0.00022635*
Ф° (Т) =347.247+
+57.13641пх-
-О.ОО83223х~2 +
+ 1.11820х~1 +
+ 4.0957х-3.606х2+
+ 1.562Х3
РС13
537.207
62,117
Должно быть
Ф° (Г) =306.8157+36.7616 Jnx -
-0.0032978х + 0.41451Х +
+ 6.1567Х- 10.015х2 + 10.806х3
931.421
-0.0022635х
Ф°(Г) =397.1186+57.13461пх-
-0.0083208х + 1.11808Х +
+ 4.1025Х- ?.613х2 + 1.565x5
РС13 (г)
537.297
26,117